Yttrium(III) fluoride

Last updated
Yttrium(III) fluoride
Kristallstruktur Yttrium(III)-fluorid.png
Names
Other names
yttrium trifluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.855 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-257-5
PubChem CID
UNII
  • InChI=1S/3FH.Y/h3*1H;/q;;;+3/p-3 Yes check.svgY
    Key: RBORBHYCVONNJH-UHFFFAOYSA-K Yes check.svgY
  • InChI=1/3FH.Y/h3*1H;/q;;;+3/p-3
    Key: RBORBHYCVONNJH-DFZHHIFOAP
  • F[Y](F)F
Properties
YF3
Molar mass 145.90 g mol−1
Appearancewhite powder
Density 4.01 g cm−3
Melting point 1,387 °C (2,529 °F; 1,660 K)
Boiling point 2,230 °C (4,050 °F; 2,500 K)
insoluble
Solubility in acid soluble
1.51 (500 nm)
Structure
Orthorhombic, oP16, SpaceGroup = Pnma, No. 62
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H302, H312, H315, H319, H332, H335
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
Flash point Non-flammable
Related compounds
Other anions
Yttrium(III) chloride
Yttrium(III) bromide
Yttrium(III) iodide
Other cations
Scandium(III) fluoride
Lutetium(III) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Yttrium(III) fluoride is an inorganic chemical compound with the chemical formula Y F3. It is not known naturally in 'pure' form. The fluoride minerals containing essential yttrium include tveitite-(Y) (Y,Na)6Ca6Ca6F42 and gagarinite-(Y) NaCaY(F,Cl)6. Sometimes mineral fluorite contains admixtures of yttrium. [1] [2]

Contents

Synthesis

YF3 can be produced by reacting fluorine with yttria or yttrium hydroxide with hydrofluoric acid. [3]

Y(OH)3 + 3HF → YF3 + 3H2O

Properties

Yttrium(III) fluoride has a refractive index of 1.51 at 500 nm [4] and is transparent in the range from 193 nm to 14,000 nm (i.e. from the UV to IR range).

Pure yttrium can be obtained from yttrium(III) fluoride by reduction with calcium.

Yttrium(III) fluoride crystallizes in the orthorhombic crystal system, with space group Pnma (space group no. 62), with the lattice parameters a = 6.3537 Å, b = 6.8545 Å, c = 4.3953 Å. [5] Yttrium is nine times coordinated by fluorine atoms.

Occurrence and uses

It occurs as the mineral waimirite-(Y). [6]

Yttrium(III) fluoride can be used for the production of metallic yttrium, [7] thin films, glasses [8] and ceramics.

Hazards

Conditions/substances to avoid are: acids, active metals and moisture.

Related Research Articles

<span class="mw-page-title-main">Erbium</span> Chemical element, symbol Er and atomic number 68

Erbium is a chemical element; it has symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare-earth element, originally found in the gadolinite mine in Ytterby, Sweden, which is the source of the element's name.

<span class="mw-page-title-main">Terbium</span> Chemical element, symbol Tb and atomic number 65

Terbium is a chemical element; it has symbol Tb and atomic number 65. It is a silvery-white, rare earth metal that is malleable, and ductile. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas. Terbium is never found in nature as a free element, but it is contained in many minerals, including cerite, gadolinite, monazite, xenotime and euxenite.

<span class="mw-page-title-main">Hydrofluoric acid</span> Solution of hydrogen fluoride in water

Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepressant medication fluoxetine (Prozac) and the material PTFE (Teflon). Elemental fluorine is produced from it. It is commonly used to etch glass and silicon wafers.

<span class="mw-page-title-main">Group 3 element</span> Group of chemical elements

Group 3 is the first group of transition metals in the periodic table. This group is closely related to the rare-earth elements. It contains the four elements scandium (Sc), yttrium (Y), lutetium (Lu), and lawrencium (Lr). The group is also called the scandium group or scandium family after its lightest member.

<span class="mw-page-title-main">Manganese(III) fluoride</span> Chemical compound

Manganese(III) fluoride (also known as Manganese trifluoride) is the inorganic compound with the formula MnF3. This red/purplish solid is useful for converting hydrocarbons into fluorocarbons, i.e., it is a fluorination agent. It forms a hydrate and many derivatives.

<span class="mw-page-title-main">Xenon hexafluoride</span> Chemical compound

Xenon hexafluoride is a noble gas compound with the formula XeF6. It is one of the three binary fluorides of xenon that have been studied experimentally, the other two being XeF2 and XeF4. All known are exergonic and stable at normal temperatures. XeF6 is the strongest fluorinating agent of the series. It is a colorless solid that readily sublimes into intensely yellow vapors.

<span class="mw-page-title-main">Lithium fluoride</span> Chemical compound

Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid that transitions to white with decreasing crystal size. Its structure is analogous to that of sodium chloride, but it is much less soluble in water. It is mainly used as a component of molten salts. Partly because Li and F are both light elements, and partly because F2 is highly reactive, formation of LiF from the elements releases one of the highest energies per mass of reactants, second only to that of BeO.

<span class="mw-page-title-main">Iron(III) fluoride</span> Chemical compound

Iron(III) fluoride, also known as ferric fluoride, are inorganic compounds with the formula FeF3(H2O)x where x = 0 or 3. They are mainly of interest by researchers, unlike the related iron(III) chloride. Anhydrous iron(III) fluoride is white, whereas the hydrated forms are light pink.

<span class="mw-page-title-main">Hydrogen fluoride</span> Chemical compound

Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula HF. It is a very poisonous, colorless gas or liquid that dissolves in water to yield an aqueous solution termed hydrofluoric acid. It is the principal industrial source of fluorine, often in the form of hydrofluoric acid, and is an important feedstock in the preparation of many important compounds including pharmaceuticals and polymers, e.g. polytetrafluoroethylene (PTFE). HF is also widely used in the petrochemical industry as a component of superacids. Due to strong and extensive hydrogen bonding, it boils at near room temperature, much higher than other hydrogen halides.

<span class="mw-page-title-main">Fluorine</span> Chemical element, symbol F and atomic number 9

Fluorine is a chemical element; it has symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. Fluorine is extremely reactive, as it reacts with all other elements except for the light inert gases.

<span class="mw-page-title-main">Yttrium</span> Chemical element, symbol Y and atomic number 39

Yttrium is a chemical element; it has symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals and is never found in nature as a free element. 89Y is the only stable isotope and the only isotope found in the Earth's crust.

<span class="mw-page-title-main">Thiophosphoryl fluoride</span> Chemical compound

Thiophosphoryl fluoride is an inorganic molecular gas with formula PSF3 containing phosphorus, sulfur and fluorine. It spontaneously ignites in air and burns with a cool flame. The discoverers were able to have flames around their hands without discomfort, and called it "probably one of the coldest flames known". The gas was discovered in 1888.

<span class="mw-page-title-main">Fluorine azide</span> Chemical compound

Fluorine azide or triazadienyl fluoride is a yellow green gas composed of nitrogen and fluorine with formula FN3. Its properties resemble those of ClN3, BrN3, and IN3. The bond between the fluorine atom and the nitrogen is very weak, leading to this substance being very unstable and prone to explosion. Calculations show the F–N–N angle to be around 102° with a straight line of 3 nitrogen atoms.

Yttrium oxyfluoride is an inorganic chemical compound with the formula YOF. Under normal conditions, the compound is a colorless solid.

<span class="mw-page-title-main">Fluorocarbonate</span> Class of chemical compounds

A carbonate fluoride, fluoride carbonate, fluorocarbonate or fluocarbonate is a double salt containing both carbonate and fluoride. The salts are usually insoluble in water, and can have more than one kind of metal cation to make more complex compounds. Rare-earth fluorocarbonates are particularly important as ore minerals for the light rare-earth elements lanthanum, cerium and neodymium. Bastnäsite is the most important source of these elements. Other artificial compounds are under investigation as non-linear optical materials and for transparency in the ultraviolet, with effects over a dozen times greater than Potassium dideuterium phosphate.

Thullium(III) fluoride is an inorganic compound with the chemical formula TmF3.

<span class="mw-page-title-main">Lutetium(III) fluoride</span> Chemical compound

Lutetium(III) fluoride is an inorganic compound with a chemical formula LuF3.

The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.

<span class="mw-page-title-main">Terbium compounds</span> Chemical compounds with at least one terbium atom

Terbium compounds are compounds formed by the lanthanide metal terbium (Tb). Terbium generally exhibits the +3 oxidation state in these compounds, such as in TbCl3, Tb(NO3)3 and Tb(CH3COO)3. Compounds with terbium in the +4 oxidation state are also known, such as TbO2 and BaTbF6. Terbium can also form compounds in the 0, +1 and +2 oxidation states.

Lutetium compounds are compounds formed by the lanthanide metal lutetium (Lu). In these compounds, lutetium generally exhibits the +3 oxidation state, such as LuCl3, Lu2O3 and Lu2(SO4)3. Aqueous solutions of most lutetium salts are colorless and form white crystalline solids upon drying, with the common exception of the iodide. The soluble salts, such as nitrate, sulfate and acetate form hydrates upon crystallization. The oxide, hydroxide, fluoride, carbonate, phosphate and oxalate are insoluble in water.

References

  1. Dinér, Peter (February 2016). "Yttrium from Ytterby". Nature Chemistry. 8 (2): 192. Bibcode:2016NatCh...8..192D. doi: 10.1038/nchem.2442 . ISSN   1755-4349. PMID   26791904.
  2. "Tiny particles produce huge photon avalanches". Physics World. 2021-01-21. Archived from the original on 2022-01-19. Retrieved 2021-06-11.
  3. SCHENK, P.W.; BRAUER, G. (1963), "Preparative Methods", Handbook of Preparative Inorganic Chemistry, Elsevier, pp. 3–107, doi:10.1016/b978-0-12-395590-6.50008-9, ISBN   978-0-12-395590-6, archived from the original on 2024-03-05, retrieved 2023-12-24
  4. "General Reserch Institute Nonferrous Metals". 2007-09-28. Archived from the original on 2007-09-28. Retrieved 2023-12-24.
  5. Cheetham, A. K.; Norman, N.; Hope, Håkon; Kjekshus, Arne; Klewe, Bernt; Powell, D. L. (1974). "The Structures of Yttrium and Bismuth Trifluorides by Neutron Diffraction". Acta Chemica Scandinavica. 28a: 55–60. doi: 10.3891/acta.chem.scand.28a-0055 . ISSN   0904-213X.
  6. "Waimirite-(Y): Mineral information, data and localities". Archived from the original on 2022-01-11. Retrieved 2017-03-10.
  7. "Yttrium Fluoride, YF3 - For Optical Coating" (PDF). Archived from the original (PDF) on 2010-07-05. Retrieved 2023-12-24.
  8. "Yttrium Fluoride 99%-99.999% from Metall Rare Earth Limited". www.metall.com.cn. Archived from the original on 2023-12-24. Retrieved 2023-12-24.