Metamorphic rock | |
Composition | |
---|---|
Mostly calcite or dolomite | |
Physical Characteristics | |
Fabric | Typically not foliated |
Relationships | |
Protoliths | carbonate minerals, Limestone, Dolomite |
Marble is a metamorphic rock consisting of carbonate minerals (most commonly calcite (CaCO3) or dolomite (CaMg(CO3)2) that have recrystallized under the influence of heat and pressure. [1] It has a crystalline texture, and is typically not foliated (layered), although there are exceptions.
In geology, the term marble refers to metamorphosed limestone, but its use in stonemasonry more broadly encompasses unmetamorphosed limestone. [2] Marble is commonly used for sculpture and as a building material.
The word "marble" derives from the Ancient Greek μάρμαρον (mármaron), [3] from μάρμαρος (mármaros), "crystalline rock, shining stone", [4] [5] perhaps from the verb μαρμαίρω (marmaírō), "to flash, sparkle, gleam"; [6] R. S. P. Beekes has suggested that a "Pre-Greek origin is probable". [7]
This stem is also the ancestor of the English word "marmoreal", meaning "marble-like." [8] While the English term "marble" resembles the French marbre, most other European languages (with words like "marmoreal") more closely resemble the original Ancient Greek. [9]
Marble is a rock resulting from metamorphism of sedimentary carbonate rocks, most commonly limestone or dolomite. Metamorphism causes variable re-crystallization of the original carbonate mineral grains. The resulting marble rock is typically composed of an interlocking mosaic of carbonate crystals. Primary sedimentary textures and structures of the original carbonate rock (protolith) have typically been modified or destroyed.
Pure white marble is the result of metamorphism of a very pure (silicate-poor) limestone or dolomite protolith. The characteristic swirls and veins of many colored marble varieties, sometimes called striations, are usually due to various mineral impurities such as clay, silt, sand, iron oxides, or chert which were originally present as grains or layers in the limestone. Green coloration is often due to serpentine resulting from originally magnesium-rich limestone or dolomite with silica impurities. These various impurities have been mobilized and recrystallized by the intense pressure and heat of the metamorphism.[ citation needed ]
Acids react with the calcium carbonate in marble, producing carbonic acid (which decomposes quickly to CO2 and H2O) and other soluble salts : [10]
Outdoor marble statues, gravestones, or other marble structures are damaged by acid rain whether by carbonation, sulfation or the formation of "black-crust" (accumulation of calcium sulphate, nitrates and carbon particles). [10] Vinegar and other acidic solutions should be avoided in the cleaning of marble products.
Crystallization refers to a method of imparting a glossy, more durable finish on to a marble floor (CaCO3). It involves polishing the surface with an acidic solution and a steel wool pad on a flooring machine. The chemical reaction below shows a typical process using magnesium fluorosilicate (MgSiF6) and hydrochloric acid (HCl) taking place.
The resulting calcium hexafluorosilicate (CaSiF6) is bonded to the surface of the marble. This is harder, more glossy and stain resistant compared to the original surface.
The other often used method of finishing marble is to polish with oxalic acid (H2C2O4), an organic acid. The resulting reaction is as follows:
In this case the calcium oxalate (CaC2O4) formed in the reaction is washed away with the slurry, leaving a surface that has not been chemically changed. [11]
The haloalkaliphilic methylotrophic bacterium Methylophaga murata was isolated from deteriorating marble in the Kremlin. [12] Bacterial and fungal degradation was detected in four samples of marble from Milan Cathedral; black Cladosporium attacked dried acrylic resin [13] using melanin. [14]
Marble is a rock composed of calcium and magnesium carbonate, mostly white and pink. [1] Common marble varieties are granular limestone or dolomite. The hardness of marble is very high, because the internal structure of the rock is very uniform after long-term natural aging, and the internal stress disappears, so the marble will not be deformed due to temperature, and has strong wear resistance. It is a very popular building material.
The following table is a summary of the features of Marble. [17]
Colour | White, Pink, Black etc |
---|---|
Texture | granular |
Grain size | medium grained |
Mineralogy | calcite |
Hardness | hard |
Other features | generally gritty to touch |
Uses | building stone |
White marble has been prized for its use in sculptures [18] since classical times. This preference has to do with its softness, which made it easier to carve, relative isotropy and homogeneity, and a relative resistance to shattering. Also, the low index of refraction of calcite allows light to penetrate 12.7 to 38 millimeters into the stone before being scattered out, resulting in the characteristic waxy look which brings a lifelike luster to marble sculptures of any kind, which is why many sculptors preferred and still prefer marble for sculpting the human form. [19]
Construction marble is a stone which is composed of calcite, dolomite or serpentine that is capable of taking a polish. [20] More generally in construction, specifically the dimension stone trade, the term marble is used for any crystalline calcitic rock (and some non-calcitic rocks) useful as building stone. For example, Tennessee marble is really a dense granular fossiliferous gray to pink to maroon Ordovician limestone, that geologists call the Holston Formation.
Ashgabat, the capital city of Turkmenistan, was recorded in the 2013 Guinness Book of Records as having the world's highest concentration of white marble buildings. [21]
The extraction of marble is performed by quarrying. Blocks are favoured for most purposes, and can be created through various techniques, including drilling and blasting, water jet and wedge methods. [22] Limestones are often commercially and historically referred to as marble, which differs from the geological definition.
In 1998, marble production was dominated by 4 countries that accounted for almost half of world production of marble and decorative stone. Italy and China were the world leaders, each representing 16% of world production, while Spain and India produced 9% and 8%, respectively. [23]
In 2018 Turkey was the world leader in marble export, with 42% share in global marble trade, followed by Italy with 18% and Greece with 10%. The largest importer of marble in 2018 was China with a 64% market share, followed by India with 11% and Italy with 5%. [24]
White marbles throughout the Mediterranean basin were widely utilized during the Roman period. Extraction centers were unevenly distributed across the Italian Peninsula, mainland Greece, the Aegean Islands, Asia Minor, and smaller hubs like those in the Iberian Peninsula. The need for extensive trade arose due to this imbalance, leading to the widespread exchange of marble objects, including building elements, sculptures, and sarcophagi. There was a significant increase in the distribution of white marble from the late 1st century BC to the end of the 2nd century AD. A gradual decline in distribution started in the third century AD. [25]
According to the United States Geological Survey, U.S. domestic marble production in 2006 was 46,400 tons valued at about $18.1 million, compared to 72,300 tons valued at $18.9 million in 2005. Crushed marble production (for aggregate and industrial uses) in 2006 was 11.8 million tons valued at $116 million, of which 6.5 million tons was finely ground calcium carbonate and the rest was construction aggregate. For comparison, 2005 crushed marble production was 7.76 million tons valued at $58.7 million, of which 4.8 million tons was finely ground calcium carbonate and the rest was construction aggregate. U.S. dimension marble demand is about 1.3 million tons. The DSAN World Demand for (finished) Marble Index has shown a growth of 12% annually for the 2000–2006 period, compared to 10.5% annually for the 2000–2005 period. The largest dimension marble application is tile.
The stone and marble industry is one of the largest industries in Palestine, contributing 20-25% of its total industrial revenues, generating USD $400–$450 million in revenue annually. The industry employs 15,000–20,000 workers across the West Bank across 1200–1700 facilities, and amounts to 4.5% of the nation's GDP. The vast majority of the industry's exports are to Israel.[ citation needed ]
Marble in the geologic sense does not naturally outcrop in Palestine, and that the vast majority of commercially labeled marble produced in Palestine produced would be geologically considered limestone. [26]
Particulate air pollution exposure has been found to be elevated in the marble production industry. Exposure to the dust produced by cutting marble could impair lung function or cause lung disease in workers, such as silicosis. Skin and eye problems are also a potential hazard. Mitigations such as dust filters, or dust suppression are suggested, but more research needs to be carried out on the efficacy of safety measures. [27] [26]
In the United States, the Occupational Safety and Health Administration (OSHA) has set the legal limit (permissible exposure limit) for marble exposure in the workplace as 15 mg/m3 total exposure and 5 mg/m3 respiratory exposure over an 8-hour workday. The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit (REL) of 10 mg/m3 total exposure and 5 mg/m3 respiratory exposure over an 8-hour workday. [28] [ non sequitur ]
Dust, debris and temperature fluctuations from working marble can endanger the eye health of employees. [29] For the staff involved in marble processing, it is necessary to provide eye protection equipment, and it is recommended to improve the education of all workers on occupational health risks and strengthen preventive measures. [29]
As the favorite medium for Greek and Roman sculptors and architects (see classical sculpture), marble has become a cultural symbol of tradition and refined taste. Its extremely varied and colorful patterns make it a favorite decorative material. [30]
Places named after the stone include Marblehead, Massachusetts; Marblehead, Ohio; Marble Arch, London; the Sea of Marmara; India's Marble Rocks; and the towns of Marble, Minnesota; Marble, Colorado; Marble Falls, Texas, and Marble Hill, Manhattan, New York. The Elgin Marbles are marble sculptures from the Parthenon in Athens that are on display in the British Museum. [31]
Total world quarrying production in 2019 was approximately 316 million tonnes; however, quarrying waste accounted for 53% of this total production. [29] In the process of marble mining and processing, around half or the excavated material will be waste, this is often then used as chips for flooring or wall finish, and uses for which high-calcium limestone is suitable. [1]
Marble [1] sludge waste can be used as a mineral filler in water-based paints. [32] Using ground calcium carbonate as a filler in paint production can improve the brightness, hiding power and application performance of paint, and can also replace expensive pigments such as titanium dioxide. [32] Recycling of marble waste leads to a large amount of waste not being land-filled, reducing environmental pollution, thereby realizing the sustainability of marble. Converting waste to generate economic income and restore degraded soil can improve the environment.
The nature of marble is soft and porous, so it is easily stained by colored liquids and scratches easily. Maintenance and cleaning is particularly important. [33]
Alabaster is a mineral and a soft rock used for carvings and as a source of plaster powder. Archaeologists, geologists, and the stone industry have different definitions for the word alabaster. In archaeology, the term alabaster includes objects and artefacts made from two different minerals: (i) the fine-grained, massive type of gypsum, and (ii) the fine-grained, banded type of calcite.
A carbonate is a salt of carbonic acid, H2CO3, characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO2−3. The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate groupO=C(−O−)2.
Limestone is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of CaCO3. Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life.
Calcite is a carbonate mineral and the most stable polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses.
Calcium carbonate is a chemical compound with the chemical formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skeletons and pearls. Materials containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is produced when calcium ions in hard water react with carbonate ions to form limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues.
Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Chalk is common throughout Western Europe, where deposits underlie parts of France, and steep cliffs are often seen where they meet the sea in places such as the Dover cliffs on the Kent coast of the English Channel.
Dolomite is an anhydrous carbonate mineral composed of calcium magnesium carbonate, ideally CaMg(CO3)2. The term is also used for a sedimentary carbonate rock composed mostly of the mineral dolomite (see Dolomite (rock)). An alternative name sometimes used for the dolomitic rock type is dolostone.
Calcium oxide, commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term lime connotes calcium-containing inorganic compounds, in which carbonates, oxides, and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, quicklime specifically applies to the single compound calcium oxide. Calcium oxide that survives processing without reacting in building products, such as cement, is called free lime.
Travertine is a form of terrestrial limestone deposited around mineral springs, especially hot springs. It often has a fibrous or concentric appearance and exists in white, tan, cream-colored, and rusty varieties. It is formed by a process of rapid precipitation of calcium carbonate, often at the mouth of a hot spring or in a limestone cave. In the latter, it can form stalactites, stalagmites, and other speleothems. It is frequently used in Italy and elsewhere as a building material. Similar deposits formed from ambient-temperature water are known as tufa.
Magnesium carbonate, MgCO3, is an inorganic salt that is a colourless or white solid. Several hydrated and basic forms of magnesium carbonate also exist as minerals.
A speleothem is a geological formation by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depending on their depositional history and environment. Their chemical composition, gradual growth, and preservation in caves make them useful paleoclimatic proxies.
Hard water is water that has a high mineral content. Hard water is formed when water percolates through deposits of limestone, chalk or gypsum, which are largely made up of calcium and magnesium carbonates, bicarbonates and sulfates.
Oolite or oölite is a sedimentary rock formed from ooids, spherical grains composed of concentric layers. Strictly, oolites consist of ooids of diameter 0.25–2 millimetres; rocks composed of ooids larger than 2 mm are called pisolites. The term oolith can refer to oolite or individual ooids.
Wollastonite is a calcium inosilicate mineral (CaSiO3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature and pressure, which sometimes occurs in the presence of silica-bearing fluids as in skarns or in contact with metamorphic rocks. Associated minerals include garnets, vesuvianite, diopside, tremolite, epidote, plagioclase feldspar, pyroxene and calcite. It is named after the English chemist and mineralogist William Hyde Wollaston (1766–1828).
Dolomite (also known as dolomite rock, dolostone or dolomitic rock) is a sedimentary carbonate rock that contains a high percentage of the mineral dolomite, CaMg(CO3)2. It occurs widely, often in association with limestone and evaporites, though it is less abundant than limestone and rare in Cenozoic rock beds (beds less than about 66 million years in age). One of the first geologists to distinguish dolomite from limestone was Déodat Gratet de Dolomieu; a French mineralogist and geologist whom it is named after. He recognized and described the distinct characteristics of dolomite in the late 18th century, differentiating it from limestone.
Lime is an inorganic material composed primarily of calcium oxides and hydroxides. It is also the name for calcium oxide which occurs as a product of coal-seam fires and in altered limestone xenoliths in volcanic ejecta. The International Mineralogical Association recognizes lime as a mineral with the chemical formula of CaO. The word lime originates with its earliest use as building mortar and has the sense of sticking or adhering.
Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and dolomite rock (also known as dolostone), which is composed of mineral dolomite (CaMg(CO3)2). They are usually classified based on texture and grain size. Importantly, carbonate rocks can exist as metamorphic and igneous rocks, too. When recrystallized carbonate rocks are metamorphosed, marble is created. Rare igneous carbonate rocks even exist as intrusive carbonatites and, even rarer, there exists volcanic carbonate lava.
Carbonate minerals are those minerals containing the carbonate ion, CO2−
3.
Crushed stone or angular rock is a form of construction aggregate, typically produced by mining a suitable rock deposit and breaking the removed rock down to the desired size using crushers. It is distinct from naturally occurring gravel, which is produced by natural processes of weathering and erosion and typically has a more rounded shape.
Calthemite is a secondary deposit, derived from concrete, lime, mortar or other calcareous material outside the cave environment. Calthemites grow on or under man-made structures and mimic the shapes and forms of cave speleothems, such as stalactites, stalagmites, flowstone etc. Calthemite is derived from the Latin calx "lime" + Latin < Greek théma, "deposit" meaning ‘something laid down’, and the Latin –ita < Greek -itēs – used as a suffix indicating a mineral or rock. The term "speleothem", due to its definition can only be used to describe secondary deposits in caves and does not include secondary deposits outside the cave environment.
white marble prized for use to make sculptures.