Sylvite | |
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General | |
Category | Halide mineral |
Formula (repeating unit) | KCl |
IMA symbol | Syl [1] |
Strunz classification | 3.AA.20 |
Crystal system | Isometric |
Crystal class | Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m) |
Space group | Fm3m |
Unit cell | a = 6.2931 Å; Z = 4 |
Identification | |
Formula mass | 74.55 g/mol |
Color | Colorless to white, pale gray, pale blue; may be yellowish red to red due to hematite inclusions |
Crystal habit | As cubes and octahedra; columnar, in crusts, coarse granular, massive |
Cleavage | Perfect on [100], [010], [001] |
Fracture | Uneven |
Tenacity | Brittle to ductile |
Mohs scale hardness | 2 |
Luster | Vitreous |
Streak | White |
Diaphaneity | Transparent to translucent |
Specific gravity | 1.993 |
Optical properties | Isotropic |
Refractive index | 1.4903 |
Pleochroism | Visible in colored crystals |
Ultraviolet fluorescence | None |
Solubility | Soluble in water |
Other characteristics | Salty to bitter taste |
References | [2] [3] [4] |
Sylvite, or sylvine, is potassium chloride (KCl) in natural mineral form. It forms crystals in the isometric system very similar to normal rock salt, halite (NaCl). The two are, in fact, isomorphous. [5] Sylvite is colorless to white with shades of yellow and red due to inclusions. It has a Mohs hardness of 2.5 and a specific gravity of 1.99. It has a refractive index of 1.4903. [6] Sylvite has a salty taste with a distinct bitterness.
Sylvite is one of the last evaporite minerals to precipitate out of solution. As such, it is found only in very dry saline areas. Its principal use is as a potassium fertilizer.
Sylvite is found in many evaporite deposits worldwide. Massive bedded deposits occur in New Mexico and western Texas, and in Utah in the US, but the largest world source is in Saskatchewan, Canada. The vast deposits in Saskatchewan were formed by the evaporation of a Devonian seaway. Sylvite is the official mineral of Saskatchewan.
Sylvite was first described in 1832 at Mount Vesuvius near Napoli in Italy and named after historical KCl designations sal degistivum Sylvii and sal febrifugum Sylvii, [7] which are named after the Dutch physician and chemist François Sylvius de le Boe (1614–1672). [2]
Sylvite, along with quartz, fluorite and halite, is used for spectroscopic prisms and lenses. [8]
Kainite ( or ) (KMg(SO4)Cl·3H2O) is an evaporite mineral in the class of "Sulfates (selenates, etc.) with additional anions, with H2O" according to the Nickel–Strunz classification. It is a hydrated potassium-magnesium sulfate-chloride, naturally occurring in irregular granular masses or as crystalline coatings in cavities or fissures. This mineral is dull and soft, and is colored white, yellowish, grey, reddish, or blue to violet. Its name is derived from Greek καινος [kainos] ("(hitherto) unknown"), as it was the first mineral discovered that contained both sulfate and chloride as anions. Kainite forms monoclinic crystals.
Potash includes various mined and manufactured salts that contain potassium in water-soluble form. The name derives from pot ash, plant ashes or wood ash soaked in water in a pot, the primary means of manufacturing potash before the Industrial Era. The word potassium is derived from potash.
Potassium chloride is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt-like taste. Potassium chloride can be obtained from ancient dried lake deposits. KCl is used as a fertilizer, in medicine, in scientific applications, domestic water softeners, and in food processing, where it may be known as E number additive E508.
An evaporite is a water-soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocean deposits, and non-marine, which are found in standing bodies of water such as lakes. Evaporites are considered sedimentary rocks and are formed by chemical sediments.
Halite, commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride (NaCl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on inclusion of other materials, impurities, and structural or isotopic abnormalities in the crystals. It commonly occurs with other evaporite deposit minerals such as several of the sulfates, halides, and borates. The name halite is derived from the Ancient Greek word for "salt", ἅλς (háls).
Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.
Kieserite, or magnesium sulfate monohydrate, is a hydrous magnesium sulfate mineral with formula (MgSO4·H2O).
Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium (baryte) and strontium (celestine) sulfates, as might be expected from the chemical formulas. Distinctly developed crystals are somewhat rare, the mineral usually presenting the form of cleavage masses. The Mohs hardness is 3.5, and the specific gravity is 2.9. The color is white, sometimes greyish, bluish, or purple. On the best developed of the three cleavages, the lustre is pearly; on other surfaces it is glassy. When exposed to water, anhydrite readily transforms to the more commonly occurring gypsum, (CaSO4·2H2O) by the absorption of water. This transformation is reversible, with gypsum or calcium sulfate hemihydrate forming anhydrite by heating to around 200 °C (400 °F) under normal atmospheric conditions. Anhydrite is commonly associated with calcite, halite, and sulfides such as galena, chalcopyrite, molybdenite, and pyrite in vein deposits.
Thermonatrite is a naturally occurring evaporite mineral form of sodium carbonate, Na2CO3·H2O.
Aphthitalite is a potassium sulfate mineral with the chemical formula: (K,Na)3Na(SO4)2.
Polyhalite is an evaporite mineral, a hydrated sulfate of potassium, calcium and magnesium with formula: K2Ca2Mg(SO4)4·2H2O. Polyhalite crystallizes in the triclinic system, although crystals are very rare. The normal habit is massive to fibrous. It is typically colorless, white to gray, although it may be brick red due to iron oxide inclusions. It has a Mohs hardness of 3.5 and a specific gravity of 2.8. It is used as a fertilizer.
Carnallite (also carnalite) is an evaporite mineral, a hydrated potassium magnesium chloride with formula KCl.MgCl2·6(H2O). It is variably colored yellow to white, reddish, and sometimes colorless or blue. It is usually massive to fibrous with rare pseudohexagonal orthorhombic crystals. The mineral is deliquescent (absorbs moisture from the surrounding air) and specimens must be stored in an airtight container.
Hanksite is a sulfate mineral, distinguished as one of only a handful that contain both carbonate and sulfate ions (a sulfate carbonate). It has the chemical formula Na22K(SO4)9(CO3)2Cl.
Sylvinite is a sedimentary rock made of a mechanical mixture of the minerals sylvite and halite. Sylvinite is the most important source for the production of potash in North America, Russia and the UK. Most Canadian operations mine sylvinite with proportions of approximately 31% KCl and 66% NaCl with the balance being insoluble clays, anhydrite and in some locations carnallite. Other deposits of sylvinite are located in Belarus, Brazil, France, Germany, Kazakhstan, Slovakia and Spain.
Langbeinite is a potassium magnesium sulfate mineral with the chemical formula K2Mg2(SO4)3. Langbeinite crystallizes in the isometric-tetartoidal (cubic) system as transparent colorless or white with pale tints of yellow to green and violet crystalline masses. It has a vitreous luster. The Mohs hardness is 3.5 to 4 and the specific gravity is 2.83. The crystals are piezoelectric.
Halide minerals are those minerals with a dominant halide anion. Complex halide minerals may also have polyatomic anions.
Chambersite is a manganese borate mineral with formula Mn3B7O13Cl. It is a member of the borate mineral series that includes other minerals such as ericaite and boracite. When chambersite was first discovered, it was the second chemical analogue of boracite to be found in nature. It was discovered as a mineral at Barber's Hill salt dome in Texas in 1957 and in 1971 at the Dongshuichang deposit in Jixian, Tianjin, China. Chambersite occurs associated with the evaporite minerals halite, anhydrite, and gypsum.
Syngenite is an uncommon potassium calcium sulfate mineral with formula K2Ca(SO4)2·H2O. It forms as prismatic monoclinic crystals and as encrustations.
Piypite is a rare potassium, copper sulfate mineral with formula: K2Cu2O(SO4)2. It crystallizes in the tetragonal system and occurs as needlelike crystals and masses. Individual crystals are square in cross-section and often hollow. It is emerald green to black in color with a vitreous to greasy luster.
The Prairie Evaporite Formation, also known as the Prairie Formation, is a geologic formation of Middle Devonian (Givetian) age that consists primarily of halite and other evaporite minerals. It is present beneath the plains of northern and eastern Alberta, southern Saskatchewan and southwestern Manitoba in Canada, and it extends into northwestern North Dakota and northeastern Montana in the United States.
Chisholm, Hugh, ed. (1911). . Encyclopædia Britannica (11th ed.). Cambridge University Press.