This article relies largely or entirely on a single source .(October 2011) |
Volatiles are the group of chemical elements and chemical compounds that can be readily vaporized. In contrast with volatiles, elements and compounds that are not readily vaporized are known as refractory substances.
On planet Earth, the term 'volatiles' often refers to the volatile components of magma. In astrogeology volatiles are investigated in the crust or atmosphere of a planet or moon. Volatiles include nitrogen, carbon dioxide, ammonia, hydrogen, methane, sulfur dioxide, water and others.
Planetary scientists often classify volatiles with exceptionally low melting points, such as hydrogen and helium, as gases, whereas those volatiles with melting points above about 100 K (–173 °C, –280 °F) are referred to as ices. The terms "gas" and "ice" in this context can apply to compounds that may be solids, liquids or gases. Thus, Jupiter and Saturn are gas giants, and Uranus and Neptune are ice giants, even though the vast majority of the "gas" and "ice" in their interiors is a hot, highly dense fluid that gets denser as the center of the planet is approached. Inside of Jupiter's orbit, cometary activity is driven by the sublimation of water ice. Supervolatiles such as CO and CO2 have generated cometary activity as far out as 25.8 AU (3.86 billion km). [1]
In igneous petrology the term more specifically refers to the volatile components of magma (mostly water vapor and carbon dioxide) that affect the appearance and explosivity of volcanoes. Volatiles in a magma with a high viscosity, generally felsic with a higher silica (SiO2) content, tend to produce eruptions that are explosive eruption. Volatiles in a magma with a low viscosity, generally mafic with a lower silica content, tend to vent as effusive eruption and can give rise to a lava fountain.
Some volcanic eruptions are explosive because of the mixing between water and magma reaching the surface, which releases energy suddenly. However, in some cases, the eruption is caused by volatiles dissolved in the magma itself. [2] Approaching the surface, pressure decreases and the volatiles come out of solution, creating bubbles that circulate in the liquid. The bubbles become connected together, forming a network. This promotes the fragmentation into small drops or spray or coagulate clots in gas. [2]
Generally, 95-99% of magma is liquid rock. However, the small percentage of gas present represents a very large volume when it expands on reaching atmospheric pressure. Gas is thus important in a volcano system because it generates explosive eruptions. [2] Magma in the mantle and lower crust has a high volatile content. Water and carbon dioxide are not the only volatiles that volcanoes release; other volatiles include hydrogen sulfide and sulfur dioxide. Sulfur dioxide is common in basaltic and rhyolite rocks. Volcanoes also release a large amount of hydrogen chloride and hydrogen fluoride as volatiles. [2]
There are three main factors that affect the dispersion of volatiles in magma: confining pressure, composition of magma, temperature of magma. Pressure and composition are the most important parameters. [2] To understand how the magma behaves rising to the surface, the role of solubility within the magma must be known. An empirical law has been used for different magma-volatiles combination. For instance, for water in magma the equation is n=0.1078 P where n is the amount of dissolved gas as weight percentage (wt%), P is the pressure in megapascal (MPa) that acts on the magma. The value changes, for example for water in rhyolite n = 0.4111 P and for the carbon dioxide n = 0.0023 P. These simple equations work if there is only one volatile in a magma. However, in reality, the situation is not so simple because there are often multiple volatiles in a magma. It is a complex chemical interaction between different volatiles. [2]
Simplifying, the solubility of water in rhyolite and basalt is function of pressure and depth below the surface in absence of other volatiles. Both basalt and rhyolite lose water with decreasing pressure as the magma rises to the surface. The solubility of water is higher in rhyolite than in basaltic magma. Knowledge of the solubility allows the determination of the maximum amount of water that might be dissolved in relation with pressure. [2] If the magma contains less water than the maximum possible amount, it is undersaturated in water. Usually, insufficient water and carbon dioxide exist in the deep crust and mantle, so magma is often undersaturated in these conditions. Magma becomes saturated when it reaches the maximum amount of water that can be dissolved in it. If the magma continues to rise up to the surface and more water is dissolved, it becomes supersaturated. If more water is dissolved in magma, it can be ejected as bubbles or water vapor. This happens because pressure decreases in the process and velocity increases and the process has to balance also between decrease of solubility and pressure. [2] Making a comparison with the solubility of carbon dioxide in magma, this is considerably less than water and it tends to exsolve at greater depth. In this case water and carbon dioxide are considered independent. [2] What affects the behavior of the magmatic system is the depth at which carbon dioxide and water are released. Low solubility of carbon dioxide means that it starts to release bubbles before reaching the magma chamber. The magma is at this point already supersaturated. The magma enriched in carbon dioxide bubbles, rises up to the roof of the chamber and carbon dioxide tends to leak through cracks into the overlying caldera. [2] Basically, during an eruption the magma loses more carbon dioxide than water, that in the chamber is already supersaturated. Overall, water is the main volatile during an eruption. [2]
Bubble nucleation happens when a volatile becomes saturated. Actually, the bubbles are composed of molecules that tend to aggregate spontaneously in a process called homogeneous nucleation. The surface tension acts on the bubbles shrinking the surface and forces them back to the liquid. [2] The nucleation process is greater when the space to fit is irregular and the volatile molecules can ease the effect of surface tension. [2] The nucleation can occur thanks to the presence of solid crystals, which are stored in the magma chamber. They are perfect potential nucleation sites for bubbles. If there is no nucleation in the magma the bubbles formation might appear really late and magma becomes significantly supersaturated. The balance between supersaturation pressure and bubble's radii expressed by this equation: ∆P=2σ/r, where ∆P is 100 MPa and σ is the surface tension. [2] If the nucleation starts later when the magma is very supersaturated, the distance between bubbles becomes smaller. [2] Essentially if the magma rises rapidly to the surface, the system will be more out of equilibrium and supersaturated. When the magma rises there is competition between adding new molecules to the existing ones and creating new ones. The distance between molecules characterizes the efficiency of volatiles to aggregate to the new or existing site. Crystals inside magma can determine how bubbles grow and nucleate. [2]
In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. These surrounded solute particles then move away from the solid solute and out into the solution. The mixing process of a solution happens at a scale where the effects of chemical polarity are involved, resulting in interactions that are specific to solvation. The solution usually has the state of the solvent when the solvent is the larger fraction of the mixture, as is commonly the case. One important parameter of a solution is the concentration, which is a measure of the amount of solute in a given amount of solution or solvent. The term "aqueous solution" is used when one of the solvents is water.
A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface.
Magma is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and gas bubbles.
In physical chemistry, supersaturation occurs with a solution when the concentration of a solute exceeds the concentration specified by the value of solubility at equilibrium. Most commonly the term is applied to a solution of a solid in a liquid, but it can also be applied to liquids and gases dissolved in a liquid. A supersaturated solution is in a metastable state; it may return to equilibrium by separation of the excess of solute from the solution, by dilution of the solution by adding solvent, or by increasing the solubility of the solute in the solvent.
Volcanism, vulcanism, volcanicity, or volcanic activity is the phenomenon where solids, liquids, gases, and their mixtures erupt to the surface of a solid-surface astronomical body such as a planet or a moon. It is caused by the presence of a heat source, usually internally generated, inside the body; the heat is generated by various processes, such as radioactive decay or tidal heating. This heat partially melts solid material in the body or turns material into gas. The mobilized material rises through the body's interior and may break through the solid surface.
A stratovolcano, also known as a composite volcano, is a conical volcano built up by many layers (strata) of hardened lava and tephra. Unlike shield volcanoes, stratovolcanoes are characterized by a steep profile with a summit crater and periodic intervals of explosive eruptions and effusive eruptions, although some have collapsed summit craters called calderas. The lava flowing from stratovolcanoes typically cools and solidifies before spreading far, due to high viscosity. The magma forming this lava is often felsic, having high to intermediate levels of silica, with lesser amounts of less viscous mafic magma. Extensive felsic lava flows are uncommon, but have traveled as far as 15 km (9 mi).
In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled below 0 °C, it will tend to freeze into ice, but volumes of water cooled only a few degrees below 0 °C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay.
An effusive eruption is a type of volcanic eruption in which lava steadily flows out of a volcano onto the ground.
In volcanology, an explosive eruption is a volcanic eruption of the most violent type. A notable example is the 1980 eruption of Mount St. Helens. Such eruptions result when sufficient gas has dissolved under pressure within a viscous magma such that expelled lava violently froths into volcanic ash when pressure is suddenly lowered at the vent. Sometimes a lava plug will block the conduit to the summit, and when this occurs, eruptions are more violent. Explosive eruptions can expel as much as 1,000 kg (2,200 lb) per second of rocks, dust, gas and pyroclastic material, averaged over the duration of eruption, that travels at several hundred meters per second as high as 20 km (12 mi) into the atmosphere. This cloud may subsequently collapse, creating a fast-moving pyroclastic flow of hot volcanic matter.
Volcanic gases are gases given off by active volcanoes. These include gases trapped in cavities (vesicles) in volcanic rocks, dissolved or dissociated gases in magma and lava, or gases emanating from lava, from volcanic craters or vents. Volcanic gases can also be emitted through groundwater heated by volcanic action.
A soda geyser is a physical reaction between a carbonated beverage, usually Diet Coke, and Mentos mints that causes the beverage to be expelled from its container. The candies catalyze the release of gas from the beverage, which creates an eruption that pushes most of the liquid up and out of the bottle. Lee Marek and "Marek's Kid Scientists" were the first to publicly demonstrate the experiment on the Late Show with David Letterman in 1999. Steve Spangler's televised demonstration of the eruption in 2005 became popular on YouTube, launching a chain of several other Diet Coke and Mentos experiment viral videos. Experiments carried out at altitudes ranging from below sea level in Death Valley to the summit of Pikes Peak have demonstrated that the reaction works better at higher elevations.
Several types of volcanic eruptions—during which material is expelled from a volcanic vent or fissure—have been distinguished by volcanologists. These are often named after famous volcanoes where that type of behavior has been observed. Some volcanoes may exhibit only one characteristic type of eruption during a period of activity, while others may display an entire sequence of types all in one eruptive series.
Submarine eruptions are volcano eruptions which take place beneath the surface of water. These occur at constructive margins, subduction zones and within tectonic plates due to hotspots. This eruption style is far more prevalent than subaerial activity. For example, it is believed that 70 to 80% of the Earth's magma output takes place at mid-ocean ridges.
Volcanic activity, or volcanism, has played a significant role in the geologic evolution of Mars. Scientists have known since the Mariner 9 mission in 1972 that volcanic features cover large portions of the Martian surface. These features include extensive lava flows, vast lava plains, and the largest known volcanoes in the Solar System. Martian volcanic features range in age from Noachian to late Amazonian, indicating that the planet has been volcanically active throughout its history, and some speculate it probably still is so today. Both Mars and Earth are large, differentiated planets built from similar chondritic materials. Many of the same magmatic processes that occur on Earth also occurred on Mars, and both planets are similar enough compositionally that the same names can be applied to their igneous rocks.
Magmatic water, also known as juvenile water, is an aqueous phase in equilibrium with minerals that have been dissolved by magma deep within the Earth's crust and is released to the atmosphere during a volcanic eruption. It plays a key role in assessing the crystallization of igneous rocks, particularly silicates, as well as the rheology and evolution of magma chambers. Magma is composed of minerals, crystals and volatiles in varying relative natural abundance. Magmatic differentiation varies significantly based on various factors, most notably the presence of water. An abundance of volatiles within magma chambers decreases viscosity and leads to the formation of minerals bearing halogens, including chloride and hydroxide groups. In addition, the relative abundance of volatiles varies within basaltic, andesitic, and rhyolitic magma chambers, leading to some volcanoes being exceedingly more explosive than others. Magmatic water is practically insoluble in silicate melts but has demonstrated the highest solubility within rhyolitic melts. An abundance of magmatic water has been shown to lead to high-grade deformation, altering the amount of δ18O and δ2H within host rocks.
Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava.
A gas slug is a conglomerate of high pressure gas bubbles that forms within certain volcanoes, the agitation of which is a driving factor in Strombolian eruptions. They start out as small bubbles of gas inside of volcanic magma. These accumulate into one large bubble, which starts to rise through the lava plume. Gas slugs also consist of many chemical properties that assist scientists in monitoring volcanic eruptions.
Tectonic–climatic interaction is the interrelationship between tectonic processes and the climate system. The tectonic processes in question include orogenesis, volcanism, and erosion, while relevant climatic processes include atmospheric circulation, orographic lift, monsoon circulation and the rain shadow effect. As the geological record of past climate changes over millions of years is sparse and poorly resolved, many questions remain unresolved regarding the nature of tectonic-climate interaction, although it is an area of active research by geologists and palaeoclimatologists.
The physiology of decompression is the aspect of physiology which is affected by exposure to large changes in ambient pressure. It involves a complex interaction of gas solubility, partial pressures and concentration gradients, diffusion, bulk transport and bubble mechanics in living tissues. Gas is breathed at ambient pressure, and some of this gas dissolves into the blood and other fluids. Inert gas continues to be taken up until the gas dissolved in the tissues is in a state of equilibrium with the gas in the lungs, or the ambient pressure is reduced until the inert gases dissolved in the tissues are at a higher concentration than the equilibrium state, and start diffusing out again.
A crystal mush is magma that contains a significant amount of crystals suspended in the liquid phase (melt). As the crystal fraction makes up less than half of the volume, there is no rigid large-scale three-dimensional network as in solids. As such, their rheological behavior mirrors that of absolute liquids.