Variscite

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Variscite
Variscite-Pyrite-179447.jpg
General
Category Phosphate minerals
Formula
(repeating unit)
AlPO4·2H2O
IMA symbol Var [1]
Strunz classification 8.CD.10
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Pbca
Identification
ColorPale to emerald-green (pale green in transmitted light), green, blue green, yellow green, pale shades of brown or yellow, rarely red and colourless to white
Crystal habit Encrustations and reniform masses
Cleavage [010] perfect
Fracture Conchoidal to splintery
Mohs scale hardness4.5
Luster Vitreous to waxy
Streak White
Diaphaneity Transparent to translucent
Specific gravity 2.57 to 2.61
Optical propertiesBiaxial (−)
Refractive index nα = 1.563 nβ = 1.588 nγ = 1.594
Birefringence δ = 0.031
References [2] [3] [4]

Variscite is a hydrated aluminium phosphate mineral (AlPO4·2H2O). It is a relatively rare phosphate mineral. It is sometimes confused with turquoise; however, variscite is usually greener in color. The green color results from the presence of small amounts of trivalent chromium (Cr3+
). [5]

Contents

Geology

Variscite is a secondary mineral formed by direct deposition from phosphate-bearing water which has reacted with aluminium-rich rocks in a near-surface environment. [6] It occurs as fine-grained masses in nodules, cavity fillings, and crusts. Variscite often contains white veins of the calcium aluminium phosphate mineral crandallite.

It was first described in 1837 and named for the locality of Variscia, the historical name of the Vogtland, in Germany. At one time, variscite was called Utahlite. At times, materials which may be turquoise or may be variscite have been marketed as "variquoise". Appreciation of the color ranges typically found in variscite have made it a popular gem in recent years. [7]

Variscite from Nevada typically contains black spiderwebbing in the matrix and is often confused with green turquoise. Most of the Nevada variscite recovered in recent decades has come from mines located in Lander County [8] and Esmeralda County, specifically in the Candelaria Hills.

Notable localities are Lucin, Snowville, and Fairfield in Utah, United States. Most recently found in Wyoming as well. It is also found in Germany, Australia, Poland, Spain, [9] Italy (Sardinia), and Brazil.

Jewelry

Variscite has been used in Europe to make personal ornaments, especially beads, since Neolithic times. Its use continued during the Bronze Age and in Roman times although it was not until the 19th century that it was determined that all variscite used in Europe came from three sites in Spain, Gavá (Barcelona), Palazuelo de las Cuevas (Zamora), and Encinasola (Huelva). [10]

Variscite is sometimes used as a semi-precious stone, and is popular for carvings and ornamental use due to its beautiful and intense green color, and is commonly used in silversmithing in place of turquoise. Variscite is more rare and less common than turquoise, but because it is not as commonly available as turquoise or as well known to the general public, raw variscite tends to be less expensive than turquoise. [7] [5] [11]

See also

Related Research Articles

<span class="mw-page-title-main">Amblygonite</span>

Amblygonite is a fluorophosphate mineral, (Li,Na)AlPO4(F,OH), composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage and flame test for lithium are diagnostic. Amblygonite forms a series with montebrasite, the low fluorine endmember. Geologic occurrence is in granite pegmatites, high-temperature tin veins, and greisens. Amblygonite occurs with spodumene, apatite, lepidolite, tourmaline, and other lithium-bearing minerals in pegmatite veins. It contains about 10% lithium, and has been utilized as a source of lithium. The chief commercial sources have historically been the deposits of California and France.

<span class="mw-page-title-main">Beryl</span> Gemstone: beryllium aluminium silicate

Beryl ( BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.

<span class="mw-page-title-main">Titanite</span> Nesosilicate mineral

Titanite, or sphene (from Ancient Greek σφηνώ (sphēnṓ) 'wedge'), is a calcium titanium nesosilicate mineral, CaTiSiO5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly replaced by thorium.

<span class="mw-page-title-main">Topaz</span> Silicate mineral

Topaz is a silicate mineral made of aluminum and fluorine with the chemical formula Al2SiO4(F, OH)2. It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can make it pale blue or golden brown to yellow-orange. Topaz is often treated with heat or radiation to make it a deep blue, reddish-orange, pale green, pink, or purple.

<span class="mw-page-title-main">Tourmaline</span> Cyclosilicate mineral group

Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.

<span class="mw-page-title-main">Chrysoberyl</span> Mineral or gemstone of beryllium aluminate

The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely different gemstones, although they both contain beryllium. Chrysoberyl is the third-hardest frequently encountered natural gemstone and lies at 8.5 on the Mohs scale of mineral hardness, between corundum (9) and topaz (8).

<span class="mw-page-title-main">Turquoise</span> Opaque, blue-to-green mineral

Turquoise is an opaque, blue-to-green mineral that is a hydrous phosphate of copper and aluminium, with the chemical formula CuAl6(PO4)4(OH)8·4H2O. It is rare and valuable in finer grades and has been prized as a gemstone for millennia due to its hue.

<span class="mw-page-title-main">Andalusite</span> Aluminium nesosilicate mineral

Andalusite is an aluminium nesosilicate mineral with the chemical formula Al2SiO5. This mineral was called andalousite by Delamétherie, who thought it came from Andalusia, Spain. It soon became clear that it was a locality error, and that the specimens studied were actually from El Cardoso de la Sierra, in the Spanish province of Guadalajara, not Andalusia.

<span class="mw-page-title-main">Vivianite</span> Fe(II) phosphate mineral

Vivianite (Fe(II)
3
(PO
4
)
2
·8H
2
O
) is a hydrated iron(II) phosphate mineral found in a number of geological environments. Small amounts of manganese Mn2+, magnesium Mg2+, and calcium Ca2+ may substitute for iron Fe2+ in its structure. Pure vivianite is colorless, but the mineral oxidizes very easily, changing the color, and it is usually found as deep blue to deep bluish green prismatic to flattened crystals. Vivianite crystals are often found inside fossil shells, such as those of bivalves and gastropods, or attached to fossil bone. Vivianite can also appear on the iron coffins or on the corpses of humans as a result of a chemical reaction of the decomposing body with the iron enclosure.

<span class="mw-page-title-main">Chrysocolla</span> Phyllosilicate mineral

Chrysocolla ( KRIS-ə-KOL) is a hydrous copper phyllosilicate mineral and mineraloid with the formula Cu
2 – x
Al
x
(H
2
Si
2
O
5
)(OH)
4
nH
2
O
(x < 1) or (Cu, Al)
2
H
2
Si
2
O
5
(OH)
4
nH
2
O)
.

<span class="mw-page-title-main">Wardite</span>

Wardite is a hydrous sodium aluminium phosphate hydroxide mineral with formula: NaAl3(PO4)2(OH)4·2(H2O). Wardite is of interest for its rare crystallography. It crystallizes in the tetragonal trapezohedral class and is one of only a few minerals in that class. Wardite forms vitreous green to bluish green to white to colorless crystals, with pyramidal {102} or {114} faces and with {001} usually present masses. Also appears as fibrous encrustations. It has a Mohs hardness of 5 and a specific gravity of 2.81–2.87.

<span class="mw-page-title-main">Brazilianite</span> Yellow-green phosphate mineral

Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.

<span class="mw-page-title-main">Cordierite</span> Mg, Fe, Al cyclosilicate mineral

Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present, and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings. Cordierite is also synthesized and used in high temperature applications such as catalytic converters and pizza stones.

Turquoise is a cyan color, based on the mineral of the same name. The word turquoise dates to the 17th century and is derived from the French turquois, meaning 'Turkish', because the mineral was first brought to Europe through Turkey from mines in the historical Khorasan province of Iran (Persia) and Afghanistan today. The first recorded use of turquoise as a color name in English was in 1573.

<span class="mw-page-title-main">Grossular</span> Garnet, nesosilicate mineral

Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the gooseberry, grossularia, in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Grossular is a gemstone.

<span class="mw-page-title-main">Wavellite</span> Aluminium phosphate basic hydrate mineral

Wavellite is an aluminium basic phosphate mineral with formula Al3(PO4)2(OH, F)3·5H2O. Distinct crystals are rare, and it normally occurs as translucent green radial or spherical clusters.

<span class="mw-page-title-main">Aheylite</span>

Aheylite is a rare phosphate mineral with formula (Fe2+Zn)Al6[(OH)4|(PO4)2]2·4(H2O). It occurs as pale blue to pale green triclinic crystal masses. Aheylite was made the newest member of the turquoise group in 1984 by International Mineralogical Association Commission on New Minerals and Mineral Names.

<span class="mw-page-title-main">Howlite</span> Inoborate mineral

Howlite, a calcium borosilicate hydroxide (Ca2B5SiO9(OH)5), is a borate mineral found in evaporite deposits.

<span class="mw-page-title-main">Plumbogummite</span> Alunite supergroup, phosphate mineral

Plumbogummite is a rare secondary lead phosphate mineral, belonging to the alunite supergroup of minerals, crandallite subgroup. Some other members of this subgroup are:

<span class="mw-page-title-main">Axinite-(Mg)</span>

Axinite-(Mg) is a borosilicate mineral of aluminum, calcium and magnesium of the axinite group, with magnesium as the dominant cation in the place of the structure that can also be occupied by iron and manganese. It was discovered in gem material from Merelani Hills, Lelatema Mts, Manyara Region, Tanzania, which is consequently its type locality. It was initially called magnesioaxinite, referring to its membership in the axinite group and the role of magnesium as the dominant cation. The International Mineralogical Association (IMA) later changed its name to axinite-(Mg). Occasionally it has been carved as a collection gem.

References

  1. Warr, L. N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine . Vol. 85, no. 3. Mineralogical Society of Great Britain and Ireland. pp. 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Variscite" (PDF). Handbook of Mineralogy. RRUFF Project.
  3. Variscite, Mindat.org
  4. Variscite Mineral Data, WebMineral.com
  5. 1 2 "Variscite Gemstone Information".
  6. Roncal-Herrero, T.; Rodríguez-Blanco, J. D.; Benning, L. G.; Oelkers, E. H. (2009). "Precipitation of Iron and Aluminum Phosphates Directly from Aqueous Solution as a Function of Temperature from 50 to 200 °C". Crystal Growth & Design. 9 (12): 5197–5205. doi:10.1021/cg900654m.
  7. 1 2 Minerals of Nevada – Nevada Bureau of Mines Special Pub. 31 University of Nevada Press, 2004 Pages 78–81
  8. Gemstones of North America Volume III by John Sinkankas – Geoscience Press 1997
  9. "www.patrimonigava.cat". www.patrimonigava.cat.
  10. Calvo Rebollar, Miguel (2015). Minerales y Minas de España. Vol. VII. Fosfatos, Arseniatos y Vanadatos (in Spanish). Madrid: Escuela Técnica Superior de Ingenieros de Minas de Madrid. Fundación Gómez Pardo. pp. 260–276.
  11. "Variscite Value, Price, and Jewelry Information – International Gem Society".