Polarimetry is the measurement and interpretation of the polarization of transverse waves, most notably electromagnetic waves, such as radio or light waves. Typically polarimetry is done on electromagnetic waves that have traveled through or have been reflected, refracted or diffracted by some material in order to characterize that object. [1] [2]
Plane polarized light: According to the wave theory of light, an ordinary ray of light is considered to be vibrating in all planes of right angles to the direction of its propagation. If this ordinary ray of light is passed through a nicol prism, the emergent ray has its vibration only in one plane.
Polarimetry of thin films and surfaces is commonly known as ellipsometry.
Polarimetry is used in remote sensing applications, such as planetary science, astronomy, and weather radar.
Polarimetry can also be included in computational analysis of waves. For example, radars often consider wave polarization in post-processing to improve the characterization of the targets. In this case, polarimetry can be used to estimate the fine texture of a material, help resolve the orientation of small structures in the target, and, when circularly-polarized antennas are used, resolve the number of bounces of the received signal (the chirality of circularly polarized waves alternates with each reflection).
In 2003, a visible-near IR (VNIR) Spectropolarimetric Imager with an acousto-optic tunable filter (AOTF) was reported. [3] These hyperspectral and spectropolarimetric imager functioned in radiation regions spanning from ultraviolet (UV) to long-wave infrared (LWIR). In AOTFs a piezoelectric transducer converts a radio frequency (RF) signal into an ultrasonic wave. This wave then travels through a crystal attached to the transducer and upon entering an acoustic absorber is diffracted. The wavelength of the resulting light beams can be modified by altering the initial RF signal. [3] VNIR and LWIR hyperspectral imaging consistently perform better as hyperspectral imagers. [4] This technology was developed at the U.S. Army Research Laboratory. [3]
The researchers reported visible near infrared system (VISNIR) data (.4-.9 micrometers) which required an RF signal below 1 W power. The reported experimental data indicates that polarimetric signatures are unique to manmade items and are not found in natural objects. The researchers state that a dual system, collecting both hyperspectral and spectropolarimetric information, is an advantage in image production for target tracking. [3]
Polarimetric infrared imaging and detection can also highlight and distinguish different features in a scene and give unique signatures of different objects. A nano-plasmonic chirped metal structure for polarimetric detection in the mid-wave and long-wave infrared dual bands can give unique characteristics about the different detected materials, objects, and surfaces. [5]
Gemologists use polariscopes to identify various properties of gems under examination. Proper examination may require the gem to be inspected in various positions and angles. [6] A gemologist's polariscope is a vertically oriented device, usually with two polarizing lenses with one over the other with some space in between. A light source is built into the polariscope underneath the bottom polarizing lens and pointing upwards. A gemstone will be placed on top of the lower lens and may be properly examined by looking down at it through the top lens. To operate the polariscope, a gemologist may turn the polarizing lenses by hand to observe various characteristics about a gemstone. Polariscopes make use of their polarizing filters to reveal properties of a gem about how it affects light waves passing through it.
A polariscope may be first used to determine the optic character of a gem and whether it is singly refracting (isotropic), anomalously doubly refracting (isotropic), doubly refracting (anisotropic), or aggregate. If the stone is doubly refracting and is not an aggregate, the polariscope may be used to further determine the optic figure of the gemstone, or whether it is uniaxial or biaxial. This step may require use of a loupe, also known as a conoscope. [7] Finally, a polariscope can be used to detect the pleochroism of a gemstone, although a dichroscope may be preferred for this purpose as it may show pleochroic colors side by side for easier identification.
A polarimeter is the basic scientific instrument used to make these measurements, although this term is rarely used to describe a polarimetry process performed by a computer, such as is done in polarimetric synthetic aperture radar.
Polarimetry can be used to measure various optical properties of a material, including linear birefringence, circular birefringence (also known as optical rotation or optical rotary dispersion), linear dichroism, circular dichroism and scattering. [8] To measure these various properties, there have been many designs of polarimeters, some archaic and some in current use. The most sensitive are based on interferometers, while more conventional polarimeters are based on arrangements of polarising filters, wave plates or other devices.
Polarimetry is used in many areas of astronomy to study physical characteristics of sources including active galactic nuclei and blazars, exoplanets, gas and dust in the interstellar medium, supernovae, gamma-ray bursts, stellar rotation, [9] stellar magnetic fields, debris disks, reflection in binary stars [10] and the cosmic microwave background radiation. Astronomical polarimetry observations are carried out either as imaging polarimetry, where polarization is measured as a function of position in imaging data, or spectropolarimetry, where polarization is measured as a function of wavelength of light, or broad-band aperture polarimetry.
Optically active samples, such as solutions of chiral molecules, often exhibit circular birefringence. Circular birefringence causes rotation of the polarization of plane polarized light as it passes through the sample.
In ordinary light, the vibrations occur in all planes perpendicular to the direction of propagation. When light passes through a Nicol prism its vibrations in all directions except the direction of axis of the prism are cut off. The light emerging from the prism is said to be plane polarised because its vibration is in one direction. If two Nicol prisms are placed with their polarization planes parallel to each other, then the light rays emerging out of the first prism will enter the second prism. As a result, no loss of light is observed. However, if the second prism is rotated by an angle of 90°, the light emerging from the first prism is stopped by the second prism and no light emerges. The first prism is usually called the polarizer and the second prism is called the analyser.
A simple polarimeter to measure this rotation consists of a long tube with flat glass ends, into which the sample is placed. At each end of the tube is a Nicol prism or other polarizer. Light is shone through the tube, and the prism at the other end, attached to an eye-piece, is rotated to arrive at the region of complete brightness or that of half-dark, half-bright or that of complete darkness. The angle of rotation is then read from a scale. The same phenomenon is observed after an angle of 180°. The specific rotation of the sample may then be calculated. Temperature can affect the rotation of light, which should be accounted for in the calculations.
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Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultraviolet, and infrared light. Because light is an electromagnetic wave, other forms of electromagnetic radiation such as X-rays, microwaves, and radio waves exhibit similar properties.
In optics, the refractive index of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium.
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity. Optical activity occurs only in chiral materials, those lacking microscopic mirror symmetry. Unlike other sources of birefringence which alter a beam's state of polarization, optical activity can be observed in fluids. This can include gases or solutions of chiral molecules such as sugars, molecules with helical secondary structure such as some proteins, and also chiral liquid crystals. It can also be observed in chiral solids such as certain crystals with a rotation between adjacent crystal planes or metamaterials.
Polarization is a property of transverse waves which specifies the geometrical orientation of the oscillations. In a transverse wave, the direction of the oscillation is perpendicular to the direction of motion of the wave. A simple example of a polarized transverse wave is vibrations traveling along a taut string (see image); for example, in a musical instrument like a guitar string. Depending on how the string is plucked, the vibrations can be in a vertical direction, horizontal direction, or at any angle perpendicular to the string. In contrast, in longitudinal waves, such as sound waves in a liquid or gas, the displacement of the particles in the oscillation is always in the direction of propagation, so these waves do not exhibit polarization. Transverse waves that exhibit polarization include electromagnetic waves such as light and radio waves, gravitational waves, and transverse sound waves in solids.
Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent. The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress.
An optical prism is a transparent optical element with flat, polished surfaces that are designed to refract light. At least one surface must be angled — elements with two parallel surfaces are not prisms. The most familiar type of optical prism is the triangular prism, which has a triangular base and rectangular sides. Not all optical prisms are geometric prisms, and not all geometric prisms would count as an optical prism. Prisms can be made from any material that is transparent to the wavelengths for which they are designed. Typical materials include glass, acrylic and fluorite.
Optics is the branch of physics which involves the behavior and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behavior of visible, ultraviolet, and infrared light. Because light is an electromagnetic wave, other forms of electromagnetic radiation such as X-rays, microwaves, and radio waves exhibit similar properties.
The Faraday effect or Faraday rotation, sometimes referred to as the magneto-optic Faraday effect (MOFE), is a physical magneto-optical phenomenon. The Faraday effect causes a polarization rotation which is proportional to the projection of the magnetic field along the direction of the light propagation. Formally, it is a special case of gyroelectromagnetism obtained when the dielectric permittivity tensor is diagonal. This effect occurs in most optically transparent dielectric materials under the influence of magnetic fields.
A Faraday rotator is a polarization rotator based on the Faraday effect, a magneto-optic effect involving transmission of light through a material when a longitudinal static magnetic field is present. The state of polarization is rotated as the wave traverses the device, which is explained by a slight difference in the phase velocity between the left and right circular polarizations. Thus it is an example of circular birefringence, as is optical activity, but involves a material only having this property in the presence of a magnetic field.
Ellipsometry is an optical technique for investigating the dielectric properties of thin films. Ellipsometry measures the change of polarization upon reflection or transmission and compares it to a model.
In materials science, photoelasticity describes changes in the optical properties of a material under mechanical deformation. It is a property of all dielectric media and is often used to experimentally determine the stress distribution in a material.
A Nicol prism is a type of polarizer. It is an optical device made from calcite crystal used to convert ordinary light into plane polarized light. It is made in such a way that it eliminates one of the rays by total internal reflection, i.e. the ordinary ray is eliminated and only the extraordinary ray is transmitted through the prism.
A polarizer or polariser is an optical filter that lets light waves of a specific polarization pass through while blocking light waves of other polarizations. It can filter a beam of light of undefined or mixed polarization into a beam of well-defined polarization, that is polarized light. The common types of polarizers are linear polarizers and circular polarizers. Polarizers are used in many optical techniques and instruments, and polarizing filters find applications in photography and LCD technology. Polarizers can also be made for other types of electromagnetic waves besides visible light, such as radio waves, microwaves, and X-rays.
A polarimeter is a scientific instrument used to measure the angle of rotation caused by passing polarized light through an optically active substance.
A photoelastic modulator (PEM) is an optical device used to modulate the polarization of a light source. The photoelastic effect is used to change the birefringence of the optical element in the photoelastic modulator.
A Fresnel rhomb is an optical prism that introduces a 90° phase difference between two perpendicular components of polarization, by means of two total internal reflections. If the incident beam is linearly polarized at 45° to the plane of incidence and reflection, the emerging beam is circularly polarized, and vice versa. If the incident beam is linearly polarized at some other inclination, the emerging beam is elliptically polarized with one principal axis in the plane of reflection, and vice versa.
A petrographic microscope is a type of optical microscope used to identify rocks and minerals in thin sections. The microscope is used in optical mineralogy and petrography, a branch of petrology which focuses on detailed descriptions of rocks. The method includes aspects of polarized light microscopy (PLM).
Scanning laser polarimetry is the use of polarised light to measure the thickness of the retinal nerve fiber layer (RNFL) as part of a glaucoma workup. The GDx-VCC is one example.
A polarization rotator is an optical device that rotates the polarization axis of a linearly polarized light beam by an angle of choice. Such devices can be based on the Faraday effect, on birefringence, or on total internal reflection. Rotators of linearly polarized light have found widespread applications in modern optics since laser beams tend to be linearly polarized and it is often necessary to rotate the original polarization to its orthogonal alternative.
Anisotropic terahertz microspectroscopy (ATM) is a spectroscopic technique in which molecular vibrations in an anisotropic material are probed with short pulses of terahertz radiation whose electric field is linearly polarized parallel to the surface of the material. The technique has been demonstrated in studies involving single crystal sucrose, fructose, oxalic acid, and molecular protein crystals in which the spatial orientation of molecular vibrations are of interest.