Calcium nitrite

Last updated
Calcium nitrite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.008 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-424-2
PubChem CID
UNII
  • InChI=1S/Ca.2HNO2/c;2*2-1-3/h;2*(H,2,3)/q+2;;/p-2
    Key: AONJRPXZCVADKF-UHFFFAOYSA-L
  • N(=O)[O-].N(=O)[O-].[Ca+2]
Properties
Ca(NO
2
)
2
Density 2.26 g/cm3
Melting point 390 °C (734 °F; 663 K)
Hazards
GHS labelling:
GHS-pictogram-rondflam.svg GHS-pictogram-skull.svg GHS-pictogram-exclam.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Danger
H272, H301, H302, H311, H319, H340, H361, H371, H372, H373, H410
P201, P202, P210, P220, P221, P260, P264, P270, P273, P280, P281, P301+P310, P301+P312, P302+P352, P305+P351+P338, P308+P313, P309+P311, P312, P314, P321, P322, P330, P337+P313, P361, P363, P370+P378, P391, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Calcium nitrite is an inorganic compound with the chemical formula Ca(NO
2
)
2
. In this compound, as in all nitrites, nitrogen is in a +3 oxidation state. It has many applications such as antifreeze, rust inhibitor of steel and wash heavy oil. [1]

Contents

Properties

At room temperature and pressure, the compound is an odorless white or light yellowish powder. It is freely soluble in water with a density of 2.26 g/cm3. Its melting point is of 390 °C and it is stable under ordinary conditions of use and storage. It is also characterized for its strong oxidizing character, [2] which arises from the nitrite anion.

Synthesis

Calcium nitrite can be produced by different synthesis processes. One is by reacting hydrated lime with NOX gas, which typically comes from a nitric acid plant. At the acid plant, ammonia is burned to produce the NOX gas for acid as well as calcium nitrite. [3]

Also, it can be prepared as detailed below, forming a solution of sodium nitrite and calcium nitrate; cooling the solution to precipitate sodium nitrate; forming a double salt of calcium nitrite/calcium hydroxide; and in the presence of water, decomposing double salt to form a solution of calcium nitrite and insolubilize calcium hydroxide. Essentially the function of calcium hydroxide is to carry calcium nitrite; calcium hydroxide forms the insolubilized double salt which can be used to separate from calcium nitrite portions from the solution. After, the double salt is dissolved liberating calcium nitrite and regenerating the calcium hydroxide. [4]

1. Precipitation of double salt

Ca(NO
2
)
2
+ Ca(OH)
2
+ H
2
O
Ca(NO
2
)
2
•Ca(OH)
2
•H
2
O

2. Liberation of calcium nitrite

Ca(NO
2
)
2
•Ca(OH)
2
•H
2
O--H
2
O
Ca(NO
2
)
2
(aq) + Ca(OH)
2
+ H
2
O

Uses

Calcium nitrite has a great variety of uses. It can be use as antifreeze due to its high solubility, either in solution or powder. It can promote the hydration of minerals in cement using this antifreeze at sub freezing temperature, the operative temperature can be reduced to −20 °C. It also work as metal corrosion inhibitor, so it can protect steel in concrete buildings and structures from rust, to extend life of specific buildings. [5] Nitrite's success as a corrosion inhibitor for the protection of embedded steel in reinforced concrete comes from the "smart" behavior of the AFm phase (AFm is shorthand for a family of hydrated calcium aluminate hydrate phases: aluminate-ferrite-monosubstituent phases); normally it stores nitrite in preference to sulfate, carbonate, and hydroxyl ions so that the nitrite concentrations of pore fluid are low. However, if chloride ingress occurs in service (from sea water or de-icing salt), the AFm undergoes ion exchange, gaining chloride and forming Friedel's salt (Cl-AFm), while releasing soluble nitrite ions to the pore fluid. As a result, the aqueous ratio of [NO2]/[Cl] increases which assures corrosion inhibition of embedded steel. [6] The corrosion inhibition mechanism of nitrite in concrete is twofold: on one hand, the concentration of the very corrosive chloride anions (responsible for the pitting corrosion of steel rebars) in the concrete pore water decreases after their uptake into the AFm phases and on the other hand, nitrites also oxidize the Fe2+ ions present around the corroding rebars leading to the precipitation of poorly soluble iron oxy-hydroxides onto the steel surface contributing to its passivation.

Calcium nitrite is widely used in concrete for high-rise construction, highways, bridges, railroads, airports, and large-scale hydraulics. It also might enable coastal areas to use chloride-containing sea sand in concrete. [7]

Calcium nitrite is also used as a heavy oil detergent and in pharmaceuticals, dyes and metallurgy industries. It can substitute for sodium nitrite, a product often used as a heat transfer fluid in thermal energy storage units for large air-conditioning or process cooling applications.

Safety

It is a poisonous inorganic oxidiser, which can not be mixed with organic ammonium salt, acid or cyanide. It has to be kept in heat-proof place, because when the temperature is higher than 220 °C it will reduce and decompose into nitrous oxide. During transportation it is important to protect it from rain and insolation, and protect its package from breakage. Also, the warehouse should be ventilated and dry. [5]

See also

Related Research Articles

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The term chloride refers either to a chloride ion, which is a negatively charged chlorine atom, or a non-charged chlorine atom covalently bonded to the rest of the molecule by a single bond. Many inorganic chlorides are salts. Many organic compounds are chlorides. The pronunciation of the word "chloride" is.

<span class="mw-page-title-main">Base (chemistry)</span> Type of chemical substance

In chemistry, there are three definitions in common use of the word "base": Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rouelle in the mid-18th century.

<span class="mw-page-title-main">Calcium hydroxide</span> Inorganic compound of formula Ca(OH)2

Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca(OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed with water. It has many names including hydrated lime, caustic lime, builders' lime, slaked lime, cal, and pickling lime. Calcium hydroxide is used in many applications, including food preparation, where it has been identified as E number E526. Limewater, also called milk of lime, is the common name for a saturated solution of calcium hydroxide.

Classical qualitative inorganic analysis is a method of analytical chemistry which seeks to find the elemental composition of inorganic compounds. It is mainly focused on detecting ions in an aqueous solution, therefore materials in other forms may need to be brought to this state before using standard methods. The solution is then treated with various reagents to test for reactions characteristic of certain ions, which may cause color change, precipitation and other visible changes.

<span class="mw-page-title-main">Calcium nitrate</span> Chemical compound

Calcium nitrate, also called Norgessalpeter or Norwegian salpeter, is an inorganic compound with the formula Ca(NO3)2(H2O)x. The anhydrous compound, which is rarely encountered, absorbs moisture from the air to give the tetrahydrate. Both anhydrous and hydrated forms are colourless salts. Calcium nitrate is mainly used as a component in fertilizers, but it has other applications. Nitrocalcite is the name for a mineral which is a hydrated calcium nitrate that forms as an efflorescence where manure contacts concrete or limestone in a dry environment as in stables or caverns. A variety of double salts are known including calcium ammonium nitrate decahydrate (NH4NO3·5Ca(NO3)2·10H2O) and calcium potassium nitrate (Ca(NO3)2·4KNO3).

<span class="mw-page-title-main">Pitting corrosion</span> Form of insidious localized corrosion in which a pit develops at the anode site

Pitting corrosion, or pitting, is a form of extremely localized corrosion that leads to the random creation of small holes in metal. The driving power for pitting corrosion is the depassivation of a small area, which becomes anodic while an unknown but potentially vast area becomes cathodic, leading to very localized galvanic corrosion. The corrosion penetrates the mass of the metal, with a limited diffusion of ions.

Sorel cement is a non-hydraulic cement first produced by the French chemist Stanislas Sorel in 1867.

<span class="mw-page-title-main">Iron(III) oxide-hydroxide</span> Hydrous ferric oxide (HFO)

Iron(III) oxide-hydroxide or ferric oxyhydroxide is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH).

<span class="mw-page-title-main">Aluminium nitrate</span> Chemical compound

Aluminium nitrate is a white, water-soluble salt of aluminium and nitric acid, most commonly existing as the crystalline hydrate, aluminium nitrate nonahydrate, Al(NO3)3·9H2O.

An AFm phase is an "alumina, ferric oxide, monosubstituted" phase, or aluminate ferrite monosubstituted, or Al2O3, Fe2O3 mono, in cement chemist notation (CCN). AFm phases are important hydration products in the hydration of Portland cements and hydraulic cements.

<span class="mw-page-title-main">Alkali–silica reaction</span> Chemical reaction damaging concrete

The alkali–silica reaction (ASR), also commonly known as concrete cancer, is a deleterious swelling reaction that occurs over time in concrete between the highly alkaline cement paste and the reactive amorphous silica found in many common aggregates, given sufficient moisture.

Lithium nitrite is the lithium salt of nitrous acid, with formula LiNO2. This compound is hygroscopic and very soluble in water. It is used as a corrosion inhibitor in mortar. It is also used in the production of explosives, due to its ability to nitrosate ketones under certain conditions.

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<span class="mw-page-title-main">Concrete degradation</span> Damage to concrete affecting its mechanical strength and its durability

Concrete degradation may have many different causes. Concrete is mostly damaged by the corrosion of reinforcement bars due to the carbonatation of hardened cement paste or chloride attack under wet conditions. Chemical damages are caused by the formation of expansive products produced by various chemical reactions, by aggressive chemical species present in groundwater and seawater, or by microorganisms. Other damaging processes can also involve calcium leaching by water infiltration and different physical phenomena initiating cracks formation and propagation. All these detrimental processes and damaging agents adversely affects the concrete mechanical strength and its durability.

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<span class="mw-page-title-main">Sodium hyponitrite</span> Chemical compound

Sodium hyponitrite is a solid ionic compound with formula Na
2
N
2
O
2
or (Na+
)2[ON=NO]2−.

Cobalt compounds are chemical compounds formed by cobalt with other elements.

AFt Phases refer to the calcium Aluminate Ferrite trisubstituted, or calcium aluminate trisubstituted, phases present in hydrated cement paste (HCP) in concrete.

References

  1. "Calcium nitrite" . Retrieved 6 October 2012.
  2. "Calcium nitrite MSDS sheet; Manufacturers" . Retrieved 6 October 2012.
  3. "Calcium nitrite; a definition". Archived from the original on 17 July 2009. Retrieved 6 October 2012.
  4. Gaidis, James M.; Arnold M. Rosenberg (23 September 1980). "Process for forming calcium nitrite". United States Patent.
  5. 1 2 "Calcium nitrite". Archived from the original on 14 January 2013. Retrieved 6 October 2012.
  6. Balonis, Magdalena; Glasser, Fredrik P. (2011). "Calcium nitrite corrosion inhibitor in Portland cement: Influence of nitrite on chloride binding and mineralogy". Journal of the American Ceramic Society. 94 (7): 2230–2241. doi:10.1111/j.1551-2916.2010.04362.x. ISSN   0002-7820.
  7. "Nitrous acid calcium". Archived from the original on 31 January 2012. Retrieved 6 October 2012.