USRE4557E - Improvement in treating linseed and other oils for paints - Google Patents
Improvement in treating linseed and other oils for paints Download PDFInfo
- Publication number
- USRE4557E USRE4557E US RE4557 E USRE4557 E US RE4557E
- Authority
- US
- United States
- Prior art keywords
- linseed
- oil
- gum
- oils
- paints
- Prior art date
Links
- 239000003921 oil Substances 0.000 title description 24
- 239000003973 paint Substances 0.000 title description 8
- 235000004431 Linum usitatissimum Nutrition 0.000 title description 6
- 240000006240 Linum usitatissimum Species 0.000 title description 6
- 235000004426 flaxseed Nutrition 0.000 title description 6
- 229920000591 gum Polymers 0.000 description 32
- 235000019198 oils Nutrition 0.000 description 22
- 239000000944 linseed oil Substances 0.000 description 20
- 235000021388 linseed oil Nutrition 0.000 description 20
- 241000779819 Syncarpia glomulifera Species 0.000 description 16
- 229940036248 Turpentine Drugs 0.000 description 16
- 239000001739 pinus spp. Substances 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 10
- 239000003925 fat Substances 0.000 description 10
- 239000000344 soap Substances 0.000 description 10
- 235000015096 spirit Nutrition 0.000 description 10
- 239000000203 mixture Substances 0.000 description 8
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 8
- 239000003513 alkali Substances 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 6
- 229910052748 manganese Inorganic materials 0.000 description 6
- 239000011572 manganese Substances 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
- CBQYNPHHHJTCJS-UHFFFAOYSA-N Alline Chemical compound C1=CC=C2C3(O)CCN(C)C3NC2=C1 CBQYNPHHHJTCJS-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 235000012343 cottonseed oil Nutrition 0.000 description 4
- 239000002385 cottonseed oil Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- 239000003981 vehicle Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Definitions
- This invention consists in a metalline gum prepared of a stron g all'cali, linseed-oil or its equivalent, and nitrate of lead or copper, or sulphate of zinc.
- the invention also consists in a compound of an insoluble soap or metalline' gum with linseed or other oils or fat, and with or Without turpentine, benzine, or other liquids of a similar nature, in such a manner thata vehicle for paint is obtained which materially increases the durability of the paint, and particularly the quality, to withstand the influence of at mosphcric clmnges. compound produced by mixing the in ci'alline gum and linseed-oil with spirits of turpentine or ben- ZlllO.
- I then take nitrate of lead or copper, or sulphate of zinc, or any equivalent metallic salt in a solution of2el Beaum and mix this solution with the soap prepared as above stated in such proportion that the nitric or sulphuric acid of the metal salt will combine with the alkali of the soap, leaving the fatty acid of the soap combined with the metallicoxide, (of zinc, lead, or copper,) as the compound which I term metalline gum.
- This metalline gum I mix with linseed or other oils or fats in the following manner: I take two hundred and fifty pounds of gum and place it in a tank or vat provided with a steam-coil, so that the gum can become heated. As soon as the gum is melted I add thereto fifty gallons of raw linseed-oil and boil the mass for two hours.
- the invention consists, finally, in a the compound of two hundred and fifty pounds of metalline gum and fifty gallons of linseed-oil has been prepared as above stated, I add to the same one hundred and thirty gallons of spirits of turpentine or benzine, or part of each, and stir it for half an hour, and then let it stand until it has cleareditself, and finally draw off the clear liquid and barrel it ready for the market.
- I take fifty pounds ofmetalline gum, fifty gallons of linseed-0il, six pounds of binoxide of manganese, twenty pounds of litharge, and twenty-six gallons of spirits of turpentine or benzine, or part of each. I place the gum in a vat and melt as before. I place the linseed-oil, manganese,
Description
UNITED STATES PATENT OFFICE.
DAVID E. BREINIG, OF NEW YORK, N. Y., ASSIGNOR, BY MESNE ASSIGNMENTS.
TO ANNA S. BREINIG, CHARLES TAYLOR, ANDJOHN H. WELLES.
- IMPROVEMENT IN TREATING LINSEED AND OTHER OILS FOR PAINTS, &c.
Specification forming part of Letters Patent No. 61,653, dated J anuary 29, 1867 reissue No'. 4,557, dated SeptembenlQ, 1871 To all whom it may concern:
Be it known that I, DAVID E. BREINIG, of the city, county, and State of New York, have invented a new and Improved Vehicle for Paint; and I do hereby declare the following to be a full, clear, and exact description thereof, which will enable those skilled in the art to make and use the same.
This invention consists in a metalline gum prepared of a stron g all'cali, linseed-oil or its equivalent, and nitrate of lead or copper, or sulphate of zinc. The invention also consists in a compound of an insoluble soap or metalline' gum with linseed or other oils or fat, and with or Without turpentine, benzine, or other liquids of a similar nature, in such a manner thata vehicle for paint is obtained which materially increases the durability of the paint, and particularly the quality, to withstand the influence of at mosphcric clmnges. compound produced by mixing the in ci'alline gum and linseed-oil with spirits of turpentine or ben- ZlllO.
In preparingthe metalline gum, I take fiftysix pounds of a strong alkali, such as caustic soda or potash, dissolve it in forty-eight gallons of water, eitherby the aid of dry or ofsteam heat, and to this solution I add twenty-eight gallons of linseed-oil, or cottonseed oil, or of any drying oils, or their equivalents in fats. This mixture I boil until the ingredients are united to soap. I then take nitrate of lead or copper, or sulphate of zinc, or any equivalent metallic salt in a solution of2el Beaum and mix this solution with the soap prepared as above stated in such proportion that the nitric or sulphuric acid of the metal salt will combine with the alkali of the soap, leaving the fatty acid of the soap combined with the metallicoxide, (of zinc, lead, or copper,) as the compound which I term metalline gum. This metalline gum I mix with linseed or other oils or fats in the following manner: I take two hundred and fifty pounds of gum and place it in a tank or vat provided with a steam-coil, so that the gum can become heated. As soon as the gum is melted I add thereto fifty gallons of raw linseed-oil and boil the mass for two hours.
The invention consists, finally, in a the compound of two hundred and fifty pounds of metalline gum and fifty gallons of linseed-oil has been prepared as above stated, I add to the same one hundred and thirty gallons of spirits of turpentine or benzine, or part of each, and stir it for half an hour, and then let it stand until it has cleareditself, and finally draw off the clear liquid and barrel it ready for the market. For heavy or double-boiled oil, for oil-cloth manufacturers, I take fifty pounds ofmetalline gum, fifty gallons of linseed-0il, six pounds of binoxide of manganese, twenty pounds of litharge, and twenty-six gallons of spirits of turpentine or benzine, or part of each. I place the gum in a vat and melt as before. I place the linseed-oil, manganese,
.and litharge in another tank and boil it for four hours;- I then draw it oil and place it in the vat to the gum and boil it again for two hours; I then add the spirits of turpentine or benzine and let it cool, and finally barrel it for use. For printers ink I use seventy-five pounds of gum and prepare in the same manner as the doubleboiled. oil. For varnish I place thc clear oil (either single or double-boiled) in a still and distil over all the spirits of turpentine or henzine, and then draw off the residuum into suitable vessels, and let it stand uncovered, to absorb the oxygen from the air, eight days; I then add spirits of turpentine sufficient so it will iiow easy under the brush. In some cases I add borate of manganese, to produce a quick-drying varnish. Instead of linseed-oil other quick-drying oils, such as cotton-seed oil, may be substituted in the above process, or quick-dryin g properties maybe imparted to other oils or fats by means of oxidizing agents and then such oils or fats may be substituted for linseed-oil.
I do not confine myself strictly to the proper tions above given, since the same may be varied for various purposes.
What I claim as new, and desire to secure by Letters Patent, is-
1. A compound obtained by treating linseedoil or its chemical equivalent with an alkali, and exposing the product to the action of a solunamed mixture of linseed-oil and metalline gum tion of sulphate of zinc, or its chemical equivawith spirits of turpentine or benzine, substanlent, substantially as described. tially in the nmnner described.
2. A compound obtained by treating the met- This specification signed by me this 18th day alline gum hereinbefore described with linseedof August, 1871. oil 01' its chemical equivalent, substantially in the manner set forth. Witnesses:
3. Aeompound obtained by treatingthe a-bme- W. HAUFF,
E. F. KAsTENHUBER. (77.)
D. E. BREINIG.
Family
ID=
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