JP5371375B2 - Wiping fabric - Google Patents
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- JP5371375B2 JP5371375B2 JP2008279140A JP2008279140A JP5371375B2 JP 5371375 B2 JP5371375 B2 JP 5371375B2 JP 2008279140 A JP2008279140 A JP 2008279140A JP 2008279140 A JP2008279140 A JP 2008279140A JP 5371375 B2 JP5371375 B2 JP 5371375B2
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Description
本発明は、吸水性、吸油性が良く、優れた拭き取り性能を有するワイピング用布帛に関する。 The present invention relates to a wiping fabric having good water absorption and oil absorption and excellent wiping performance.
従来よりワイピング材は、メガネやカメラのレンズ等のガラス、プラスチック製品や、貴金属や光沢装飾品等の曇りや汚れを落とす拭き取り用途等に広く用いられている。 Conventionally, wiping materials have been widely used for wiping off glass and plastic products such as glasses and camera lenses, and wiping to remove fogging and dirt such as precious metals and glossy ornaments.
これらワイピング材の素材として、ポリエステルの割繊糸が広く用いられているが、吸油性に優れ油性の汚れ拭き取り性には優れるものの、吸水性に劣るため、水滴等の水分拭き取り性に問題がある。 Polyester splitting yarn is widely used as a material for these wiping materials, but it has excellent oil absorbency and excellent oil-based dirt wiping properties, but has poor water absorption, so there is a problem with water wiping properties such as water droplets. .
また、吸湿性素材である綿や麻、レーヨン等の紡績糸と合成繊維を複合した素材を用い、前記吸水性を改良したワイピング材が提案されているが、短繊維の毛羽が拭き取り対象物へ付着し易く、清掃性能に問題がある。 In addition, a wiping material with improved water absorption has been proposed using a composite material of spun yarn such as cotton, hemp, and rayon, which are hygroscopic materials, and synthetic fibers, but the fluff of short fibers has been wiped away. It tends to adhere and has a problem in cleaning performance.
該問題を解決するために、例えば特開平3−1831号公報(特許文献1)において、13重量%以上のアセテート長繊維と単糸繊度が0.5d以下の極細長繊維との組合せ糸からなる布帛であって、アルカリ処理によって、布帛表面に2重量%以上減量加工された極細長繊維を配し、布帛内部に13重量%以上減量加工されたアセテート長繊維を配し、該布帛の保水率が210重量%以上、吸水速度が3秒以下である吸水性能を有するワイピングクロスが提案されているが、布帛の安定性が悪く改良の余地があり、未だ満足できるものとはいえない。
本発明は、従来技術における上記問題点を解決するためになされたものであり、具体的な目的は吸湿性、吸油性の両性能に優れ、布帛の安定性及び拭き取り性にも優れたワイピング用布帛を提供することにある。 The present invention has been made to solve the above-mentioned problems in the prior art, and its specific purpose is excellent in both hygroscopic and oil-absorbing performances, and has excellent fabric stability and wiping performance. It is to provide a fabric.
本発明は上記課題を達成するもので、次の構成を備えている。
すなわち、本発明は少なくともセルロース系繊維とポリエステル繊維の複合糸からなり、以下の要件を満足することを特徴とするワイピング用布帛を提供する。
(1) 剛軟度が30mm以下であり、
(2) 摩擦係数が0.2〜0.3であって、
(3) カバーファクターが1700〜2500である。
The present invention achieves the above-mentioned problems and has the following configuration.
That is, the present invention provides a wiping fabric comprising at least a composite yarn of cellulosic fibers and polyester fibers and satisfying the following requirements.
(1) The bending resistance is 30 mm or less,
(2) The coefficient of friction is 0.2 to 0.3,
(3) Cover factor is 1700-2500.
本発明のワイピング用布帛は、上記構成を備えていることにより、吸水性及び吸油性に優れ、布帛の安定性があり、優れた拭き取り性能を有している。 The cloth for wiping of the present invention has the above-described configuration, so that it has excellent water absorbency and oil absorbability, has a stable cloth, and has excellent wiping performance.
以下、本発明の好適な実施の形態について具体的に説明する。
本発明のワイピング用布帛は、少なくともセルロース系繊維とポリエステル繊維の複合糸からなり、以下の要件を満足することが必要である。
(1) 剛軟度が30mm以下、
(2) 摩擦係数が0.2〜0.3、
(3) カバーファクターが1700〜2500である。
Hereinafter, preferred embodiments of the present invention will be specifically described.
The wiping fabric of the present invention comprises at least a composite yarn of cellulosic fibers and polyester fibers, and it is necessary to satisfy the following requirements.
(1) The bending resistance is 30 mm or less,
(2) Friction coefficient is 0.2-0.3,
(3) Cover factor is 1700-2500.
本発明に用いるセルロース系繊維は、セルロースを原料として、再生或いは半合成された繊維のフィラメント糸であればよく、再生繊維としては、例えばビスコースレーヨン、リヨセル等が挙げられ、半合成繊維としては、例えばセルロースジアセテート繊維、セルローストリアセテート繊維等が挙げられるが、その製法や種類を特に限定するものではなく、また、単糸の断面形状、表面形状、艶、繊度等を特に限定するものではなく、得ようとするワイピング用布帛を考慮して任意に選定すればよいが、好ましくは吸水性、布帛の安定性の観点から次の構成が採用できる。 Cellulosic fibers used in the present invention may be filament yarns of fibers regenerated or semi-synthesized using cellulose as a raw material, and examples of regenerated fibers include viscose rayon and lyocell. For example, cellulose diacetate fiber, cellulose triacetate fiber and the like are mentioned, but the production method and type thereof are not particularly limited, and the cross-sectional shape, surface shape, gloss, fineness, etc. of the single yarn are not particularly limited. The wiping fabric to be obtained may be arbitrarily selected in consideration of the wiping fabric to be obtained, but preferably the following configuration can be adopted from the viewpoint of water absorption and fabric stability.
例えば、セルロースジアセテート繊維、セルローストリアセテート繊維に鹸化加工することにより、通常のレーヨンよりも吸水効果の高い繊維とすると、ワイピング布帛への静電気によるホコリ等の吸着を防止し、拭き取り対象物に対してもホコリ等を付着させることが無いことから好ましい。 For example, by saponifying cellulose diacetate fiber and cellulose triacetate fiber, if the fiber has a higher water absorption effect than ordinary rayon, it prevents dust and the like from being adsorbed on the wiping fabric, and prevents the object to be wiped off. Is also preferable because dust and the like are not attached.
本発明に用いる合成繊維はその製法や種類を特に限定するものではなく、単糸の断面形状、表面形状、艶、繊度、収縮性、伸縮性、染料染着特性等を特に限定するものではない。また、2種類以上の合成繊維を複合したものであってもよく、好ましくは汚れ拭き取り性の観点から次の構成が採用される。
例えば、ポリエステル系繊維とポリアミド系繊維とからなる分割型原糸が、原糸の形状がエッジを有することによる汚れ掻き取り性に優れており、特にマルチフィラメント化が容易であることから好ましく用いられる。
The production method and type of the synthetic fiber used in the present invention are not particularly limited, and the cross-sectional shape, surface shape, gloss, fineness, shrinkage, stretchability, dye dyeing characteristics, etc. of the single yarn are not particularly limited. . Moreover, what combined 2 or more types of synthetic fibers may be sufficient, Preferably the following structure is employ | adopted from a viewpoint of dirt wiping off property.
For example, split-type raw yarns composed of polyester fibers and polyamide fibers are preferably used because they have excellent dirt scraping properties due to the shape of the raw yarn having edges, and are particularly easy to make multifilaments. .
本発明に用いるセルロース系繊維とポリエステル繊維の複合糸は、その製法を特に限定するものではなく目的とする織物の風合いや意匠性により任意に選定すればよいが、次の構成を採用することが好ましい。 The cellulosic fiber and polyester fiber composite yarn used in the present invention is not particularly limited in its production method, and may be arbitrarily selected depending on the texture and design of the target woven fabric. preferable.
例えば、インターレースによるエア混繊加工により、セルロース系繊維と合成繊維を適度に交絡することで好適な加工糸を得ることができる。インターレースの交絡個数は60〜110が好ましい。
交絡個数が60以下となると、布帛としたときのセルロース系繊維と合成繊維の色差による杢が表出し易く、110以上となると複合糸の曲剛性が高くなり、布帛のドレープ性が低くなってワイピングし易さが低下するとともに、交絡部部分が粗硬となり、拭き取り時にムラ拭きになり易くなる。
For example, a suitable processed yarn can be obtained by appropriately entanglement of a cellulosic fiber and a synthetic fiber by air-mixing using interlace. The number of interlaced entanglements is preferably 60 to 110.
When the number of entanglement is 60 or less, wrinkles due to the color difference between the cellulosic fibers and the synthetic fiber are easily revealed, and when it is 110 or more, the bending rigidity of the composite yarn is increased and the drape of the fabric is decreased. However, the entangled portion becomes hard and easy to wipe unevenly when wiping.
また、インターレース混繊の前に、セルロース系繊維、合成繊維のそれぞれに、若しくはその片方に仮撚捲縮を施してもよく、この場合、ワイピング用布帛に適度なフクラミと、密度感を付与できる。 Further, before interlace blending, each of the cellulosic fibers and synthetic fibers or one of them may be subjected to false twist crimp, and in this case, an appropriate flaming and a sense of density can be imparted to the wiping fabric. .
該複合糸を用い、布帛とした後にアルカリ処理により、セルロースアセテート繊維の鹸化と合成繊維の割繊とが同時に実施できるので、好適なワイピング性能をもった布帛を効率的に得ることができる。この工程を取ることにより、合成繊維による糸収縮と、セルロースアセテート繊維の鹸化収縮とが制御でき、複合糸外層には比較的多くの合成繊維を配置し、内層へは比較的多くの鹸化されたセルロースアセテート繊維を配置することが可能となり、外層の合成繊維による油分に対する拭き取り性能、内層の鹸化されたセルロースアセテートによる吸水、吸湿性能が発揮でき好ましい効果を得ることができる。
また、前記インターレースによるエア混繊した複合糸に撚を施してもよく、この追撚により更なる顕著な外層、内層の効果を発揮することが可能となる。
Saponification of cellulose acetate fibers and splitting of synthetic fibers can be carried out simultaneously by alkali treatment after using the composite yarn as a fabric, so that a fabric having suitable wiping performance can be obtained efficiently. By taking this step, the yarn shrinkage due to the synthetic fiber and the saponification shrinkage of the cellulose acetate fiber can be controlled. A relatively large amount of synthetic fiber is disposed in the outer layer of the composite yarn, and a relatively large amount of saponification is applied to the inner layer. It becomes possible to dispose cellulose acetate fibers, and it is possible to exhibit a wiping performance against oil by the synthetic fibers of the outer layer and water absorption and moisture absorption performance of the saponified cellulose acetate of the inner layer, and a favorable effect can be obtained.
Further, the air-mixed composite yarn by the interlace may be twisted, and by this additional twist, it becomes possible to exhibit further remarkable effects of the outer layer and the inner layer.
本発明のワイピング用布帛は、剛軟度が30mm以下であることが必要である。
剛軟度が30mmを越えると、布帛として硬く、ワイピングするときに曲がりづらく拭き取り作業がしづらくなる。
The wiping fabric of the present invention needs to have a bending resistance of 30 mm or less.
When the bending resistance exceeds 30 mm, the cloth is hard and difficult to bend when wiping, making it difficult to wipe.
本発明のワイピング用布帛は、摩擦係数が0.2〜0.3の範囲であることが必要である。
摩擦係数が0.2未満であると、対象物のワイピング時にエッジ効果、すなわち拭き取り性が悪くなる。また、摩擦係数が0.3を越えると、対象物のワイピング時に、対象物を傷つけてしまう虞れや、その引っ掛かりから、ハンドリングの不快感を生じてしまう。
The wiping fabric of the present invention needs to have a friction coefficient in the range of 0.2 to 0.3.
When the friction coefficient is less than 0.2, the edge effect, that is, the wiping property is deteriorated when the object is wiped. On the other hand, if the friction coefficient exceeds 0.3, the object may be damaged when the object is wiped, and handling may be uncomfortable due to the catch.
本発明のワイピング用布帛は、カバーファクターが1700〜2500の範囲であることが必要である。
カバーファクターが1700未満であると、ワイピング時にスナッグ等の問題を起こし易い。また、カバファクターが2500を超えると、布帛が硬くなり、ワイピングするときに曲がりづらく拭き取り作業がしづらくなる。
以上の構成を採用することにより、別段特殊な後加工をせずとも、ワイピング性能に優れた、ワイピング用布帛を得ることが出来る。
The wiping fabric of the present invention needs to have a cover factor in the range of 1700-2500.
If the cover factor is less than 1700, problems such as snag are likely to occur during wiping. On the other hand, when the cover factor exceeds 2500, the fabric becomes hard, and it is difficult to bend and wipe off when wiping.
By adopting the above configuration, a wiping fabric excellent in wiping performance can be obtained without special post-processing.
本発明のワイピング布帛の吸水速度は特に規定するものではないが、5秒以下であることが好ましい。吸水速度が5秒を越えると、瞬時に水滴等の水分を吸い取れず、ワイピング性能が悪くなる。 The water absorption rate of the wiping fabric of the present invention is not particularly limited, but is preferably 5 seconds or less. If the water absorption speed exceeds 5 seconds, moisture such as water droplets cannot be absorbed instantly, resulting in poor wiping performance.
本発明のワイピング布帛の保水率、保油率は特に指定するものではないが、10分後の保水率及び保油率が200%以上、脱水後の保水率が50%以上、脱水後の保油率が70%以上であることが好ましい。これらの数値を下回ると、せっかくワイピングによって除去した水分や油分等の汚れを、再度拭き取り対象物に付着させることとなる。 The water retention rate and oil retention rate of the wiping fabric of the present invention are not particularly specified, but the water retention rate and oil retention rate after 10 minutes are 200% or more, the water retention rate after dehydration is 50% or more, and the water retention rate after dehydration. The oil ratio is preferably 70% or more. Below these values, dirt such as moisture and oil removed by wiping is attached to the object to be wiped again.
本発明の布帛の形態は、織物、編物と特に指定するものではなく、本発明の範囲内であれば、組織も自由に選択してよいが、本発明の布帛にあっては、平織りや綾織りからなる単純な織物においても優れた効果を発揮する。 The form of the fabric of the present invention is not particularly specified as a woven fabric or a knitted fabric, and the structure may be freely selected within the scope of the present invention. However, in the fabric of the present invention, plain weave and twill Even in simple fabrics made of weaving, it has an excellent effect.
以下、本発明を実施例に基づいて具体的に説明する。また、その評価は次のように実施した。
1. 剛軟度
「JIS L1096 剛軟性 A法」により、経方向と緯方向の剛軟度を測定し、平均値を算出した。
2. 摩擦係数
KES表面試験器によりMIUを測定した。
3. カバーファクター
以下の式(I) 〜(III) により、計算した。
カバーファクター=経のカバーファクター+緯のカバーファクター …(I)
経のカバーファクター=経糸の繊度(dTex)1/2×経糸密度(本/2.54cm) …(II)
緯のカバーファクター=緯糸の繊度(dTex)1/2×緯糸密度(本/2.54cm) …(III)
4. 吸水性
「JIS L1907 滴下法」により、吸水性を測定した。
5.10分後の保水率及び保油率
「JIS L1996 乾燥性 B法」により、保水率及び保油率を測定した。
6.脱水後の保水率及び保油率
遠心脱水機(2000rpm)にて、2分脱水後の保水率及び保油率を測定した。
Hereinafter, the present invention will be specifically described based on examples. Moreover, the evaluation was implemented as follows.
1. Bending softness According to "JIS L1096 Bending Softness A Method", the bending resistance in the warp direction and the weft direction was measured, and the average value was calculated.
2. Coefficient of friction MIU was measured with a KES surface tester.
3. Cover factor The cover factor was calculated according to the following formulas (I) to (III).
Cover factor = Cover factor of longitude + Cover factor of latitude… (I)
Cover factor of warp = Fineness of warp (dTex) 1/2 x Warp density (main / 2.54cm)… (II)
Weft cover factor = Weft fineness (dTex) 1/2 x Weft density (main / 2.54cm)… (III)
4). Water absorption Water absorption was measured by the “JIS L1907 dropping method”.
5. Water retention and oil retention after 10 minutes The water retention and oil retention were measured according to “JIS L1996 Drying Method B”.
6). Water retention and oil retention after dehydration The water retention and oil retention after 2-minute dehydration were measured with a centrifugal dehydrator (2000 rpm).
〔実施例1〕
単糸菊型断面のトリアセテートマルチフィラメント糸(三菱レイヨン社製、ブライト110dTex/64フィラメント(f) 酢化度61.2)と、ポリエステル及びポリアミドからなる分割型複合フィラメント糸(クラレ社製 CR−950 KN 84dTex/24f)を用い、インタレースエア混繊糸を作成した。
[Example 1]
Tri-acetate multifilament yarn with a single yarn chrysanthemum cross section (manufactured by Mitsubishi Rayon Co., Ltd., Bright 110dTex / 64 filament (f) degree of acetylation 61.2) and split composite filament yarn made of polyester and polyamide (CR-950 made by Kuraray Co., Ltd.) KN 84dTex / 24f) was used to produce an interlaced air-mixed yarn.
この混繊糸を、織物の経糸および緯糸に用い、平織りの織物を作成した。得られた織物の生機を、常法により精練後、苛性ソーダ26%owf溶液により105℃にて減量、鹸化処理し、生機より32.3%減量した布帛を常法により染色加工して、ライトブルーに染色仕上げし、仕上げ経密度が83本/2.54cm、仕上げ緯密度が73本/2.54cmの平織り物を得た。
得られた織物の物性は表1に記載した。得られた織物は、水分や油分の拭き取り性に優れ、布帛の適度な柔らかさにより拭き心地の良いものであった。
A plain weave fabric was prepared by using the mixed yarn for warp and weft of the fabric. The raw fabric of the resulting fabric was scoured by a conventional method, then reduced in weight by a caustic soda 26% owf solution at 105 ° C. and saponified, and the fabric reduced by 32.3% from the raw fabric was dyed and processed by a conventional method. A plain weave with a finishing warp density of 83 / 2.54 cm and a finished weft density of 73 / 2.54 cm was obtained.
The physical properties of the resulting fabric are shown in Table 1. The obtained woven fabric was excellent in wiping properties of moisture and oil, and was comfortable to wipe due to appropriate softness of the fabric.
〔実施例2〕
単糸菊型断面のトリアセテートマルチフィラメント糸(三菱レイヨン社製、ブライト110dTex/64フィラメント(f) 酢化度61.2)と、ポリエステル及びポリアミドからなる分割型複合フィラメント糸(クラレ社製 CR−950 KN 84dTex/24f)の仮撚加工糸とを用い、インタレースエア混繊糸を作成した。
[Example 2]
Tri-acetate multifilament yarn with a single yarn chrysanthemum cross section (manufactured by Mitsubishi Rayon Co., Ltd., Bright 110dTex / 64 filament (f) degree of acetylation 61.2) and split composite filament yarn made of polyester and polyamide (CR-950 made by Kuraray Co., Ltd.) KN 84dTex / 24f) false twisted yarn was used to produce an interlaced air mixed yarn.
この混繊糸を、織物の経糸および緯糸に用い、平織りの織物を作成した。得られた織物の生機を、常法により精練後、苛性ソーダ26%owf溶液により105℃にて減量、鹸化処理し、生機より32.2%減量した布帛を常法により染色加工して、ライトブルーに染色仕上げし、仕上げ経密度が83本/2.54cm、仕上げ緯密度が73本/2.54cmの平織り物を得た。
得られた織物の物性は表1に記載した。得られた織物は、仮撚糸を用いたことにより実施例1よりも水分や油分の拭き取り性に優れ、布帛の適度な柔らかさにより拭き心地の良いものであった。
A plain weave fabric was prepared by using the mixed yarn for warp and weft of the fabric. The raw fabric of the resulting fabric was scoured by a conventional method, then reduced in weight by a caustic soda 26% owf solution at 105 ° C. and saponified, and the fabric reduced by 32.2% from the raw fabric was dyed and processed by a conventional method. A plain weave with a finishing warp density of 83 / 2.54 cm and a finished weft density of 73 / 2.54 cm was obtained.
The physical properties of the resulting fabric are shown in Table 1. The obtained woven fabric was superior in wiping property of moisture and oil as compared with Example 1 due to the use of false twisted yarn, and was comfortable in wiping due to appropriate softness of the fabric.
〔実施例3〕
実施例2にて作成した混繊糸を用い、織物の経糸および緯糸に用い、2/1右上がりの綾織りの織物を作成した。
得られた織物の生機を、常法により精練後、苛性ソーダ26%owf溶液により105℃にて減量、鹸化処理し、生機より30.1%減量した布帛を常法により染色加工し、ライトブルーに染色仕上げし、仕上げ経密度が110本/2.54cm、仕上げ緯密度が94本/2.54cmの綾織り物を得た。
得られた織物の物性は表1に記載した。得られた織物は、綾織り組織を用いたことにより実施例2よりも水分や油分の拭き取り性に優れ、布帛の適度な柔らかさより拭き心地の良いものであった。
Example 3
A twill-woven fabric that was raised 2/1 to the right was prepared by using the mixed yarn prepared in Example 2 for warp and weft of the fabric.
After scouring the raw fabric of the obtained woven fabric by a conventional method, the fabric was reduced and saponified by a caustic soda 26% owf solution at 105 ° C., and the fabric reduced by 30.1% from the raw fabric was dyed and processed to light blue. By dyeing, a twill weave with a finishing warp density of 110 pieces / 2.54 cm and a finished weft density of 94 pieces / 2.54 cm was obtained.
The physical properties of the resulting fabric are shown in Table 1. The resulting woven fabric was superior to Example 2 in wiping moisture and oil due to the use of the twill weave structure, and was more comfortable to wipe than moderate softness of the fabric.
〔比較例1〕
単糸丸型断面のポリエステルマルチフィラメント糸(84T/18f)を織物の経糸に用い、ポリエステルフィラメント糸(220T/34f)の仮撚糸を織物の緯糸に用い2/1の綾織の織物を作成した。得られた織物の生機を常法により精練後、苛性ソーダ26%owf溶液により105℃で減量処理し、生機より30.6%減量した布帛を常法により染色加工して、ライトブルーに染色仕上げし、仕上げ経密度が144本/2.54cm、仕上げ緯密度が112本/2.54cmの綾織物を得た。
[Comparative Example 1]
A polyester multifilament yarn (84T / 18f) having a single yarn round cross section was used as the warp of the fabric, and a false twisted yarn of the polyester filament yarn (220T / 34f) was used as the weft of the fabric to prepare a 2/1 twill fabric. After scouring the raw fabric of the obtained fabric by a conventional method, the fabric was reduced in weight by a caustic soda 26% owf solution at 105 ° C., and the fabric reduced by 30.6% from the raw fabric was dyed by a conventional method and dyed and finished in light blue. A twill woven fabric having a finishing warp density of 144 pieces / 2.54 cm and a finished weft density of 112 pieces / 2.54 cm was obtained.
得られた織物の物性は表1に記載した。得られた織物は、油分の拭き取りには申し分無いものであったが、水分の拭き取り性に劣るものであった。また、摩擦係数が高いため、拭き取り対象物に若干のスリキズが見られた。 The physical properties of the resulting fabric are shown in Table 1. The resulting woven fabric was satisfactory for wiping off oil, but was inferior in moisture wiping. Moreover, since the coefficient of friction was high, some scratches were observed on the object to be wiped.
Claims (2)
(1) 剛軟度 30mm以下
(2) 摩擦係数 0.2〜0.3
(3) カバーファクター 1700〜2500 A wiping fabric comprising a composite yarn of at least a cellulosic fiber and a synthetic fiber and satisfying the following requirements.
(1) Bending softness 30mm or less
(2) Coefficient of friction 0.2-0.3
(3) Cover factor 1700-2500
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TW539539B (en) * | 1999-04-28 | 2003-07-01 | Asahi Chemical Ind | Undergarment composed of a fabric with comfortable touch for skin |
JP4214625B2 (en) * | 1999-07-08 | 2009-01-28 | 東レ株式会社 | Wiping cloth and manufacturing method thereof |
JP2005027843A (en) * | 2003-07-11 | 2005-02-03 | Morito Co Ltd | Cleansing sheet |
JP2008202204A (en) * | 2007-01-24 | 2008-09-04 | Toray Ind Inc | Production method of ultrafine fiber fabric |
JP5151341B2 (en) * | 2007-01-31 | 2013-02-27 | 東レ株式会社 | Wiping cloth |
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Publication number | Priority date | Publication date | Assignee | Title |
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US9666772B2 (en) | 2003-04-30 | 2017-05-30 | Cree, Inc. | High powered light emitter packages with compact optics |
US8901585B2 (en) | 2003-05-01 | 2014-12-02 | Cree, Inc. | Multiple component solid state white light |
US8617909B2 (en) | 2004-07-02 | 2013-12-31 | Cree, Inc. | LED with substrate modifications for enhanced light extraction and method of making same |
US9431589B2 (en) | 2007-12-14 | 2016-08-30 | Cree, Inc. | Textured encapsulant surface in LED packages |
US10615324B2 (en) | 2013-06-14 | 2020-04-07 | Cree Huizhou Solid State Lighting Company Limited | Tiny 6 pin side view surface mount LED |
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