FR2357321A1 - Wear resistant hard metal article - coated with adherent layers of carbide, nitride, oxide, etc. - Google Patents

Wear resistant hard metal article - coated with adherent layers of carbide, nitride, oxide, etc.

Info

Publication number
FR2357321A1
FR2357321A1 FR7720723A FR7720723A FR2357321A1 FR 2357321 A1 FR2357321 A1 FR 2357321A1 FR 7720723 A FR7720723 A FR 7720723A FR 7720723 A FR7720723 A FR 7720723A FR 2357321 A1 FR2357321 A1 FR 2357321A1
Authority
FR
France
Prior art keywords
carbide
nitride
wear resistant
coated
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7720723A
Other languages
French (fr)
Other versions
FR2357321B3 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
STELLRAM SA
Original Assignee
STELLRAM SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH855176A external-priority patent/CH609381A5/en
Priority claimed from CH855076A external-priority patent/CH609380A5/en
Priority claimed from CH715377A external-priority patent/CH621579A5/en
Application filed by STELLRAM SA filed Critical STELLRAM SA
Publication of FR2357321A1 publication Critical patent/FR2357321A1/en
Application granted granted Critical
Publication of FR2357321B3 publication Critical patent/FR2357321B3/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
    • B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
    • B23B27/148—Composition of the cutting inserts
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/308—Oxynitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/32—Carbides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/34—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/36—Carbonitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/38—Borides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40—Oxides
    • C23C16/403—Oxides of aluminium, magnesium or beryllium
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40—Oxides
    • C23C16/405—Oxides of refractory metals or yttrium
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Vapour Deposition (AREA)
  • Physical Vapour Deposition (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)

Abstract

Wear resistant piece made from hard metal, such as a cutting tool or blade, e.g. for machining steels and other hard materials is covered in those places where the wear occurs when is use, with >=2 layers of carbide or carbonitride, and carbonitrids, nitride or oxynitride of gps. III-VI metal selected from Ti, Hf, Zr, Al, Cr and Be. The layers are free of binder metal and differ from one another only in the contents of C, N and O. The double coating exhibits improved resistance to removal by lifting and reduces the incidence of wear by pitting compared with the application of a single coating as in prior art.
FR7720723A 1976-07-05 1977-06-29 Wear resistant hard metal article - coated with adherent layers of carbide, nitride, oxide, etc. Granted FR2357321A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH855176A CH609381A5 (en) 1976-07-05 1976-07-05 Process for improving the wear resistance properties of an article made of hard metal, especially of a cutting tool
CH855076A CH609380A5 (en) 1976-07-05 1976-07-05 Process for improving the wear resistance properties of an article made of hard metal, especially of a cutting tool
CH715377A CH621579A5 (en) 1977-06-10 1977-06-10 Hard metal wear piece, especially for tools

Publications (2)

Publication Number Publication Date
FR2357321A1 true FR2357321A1 (en) 1978-02-03
FR2357321B3 FR2357321B3 (en) 1980-04-04

Family

ID=27175713

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7720723A Granted FR2357321A1 (en) 1976-07-05 1977-06-29 Wear resistant hard metal article - coated with adherent layers of carbide, nitride, oxide, etc.

Country Status (4)

Country Link
DE (1) DE2730355A1 (en)
ES (1) ES460647A1 (en)
FR (1) FR2357321A1 (en)
IT (1) IT1082111B (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2393852A1 (en) * 1977-06-09 1979-01-05 Sandvik Ab BODY OF SINED CARBIDE INCLUDING A COATING AND METHOD OF MANUFACTURING
FR2442718A1 (en) * 1978-11-29 1980-06-27 Krupp Gmbh COMPOSITE ELEMENT FOR USE AS A WEAR FOR THE MACHINING OF METAL PARTS
FR2454903A1 (en) * 1979-04-28 1980-11-21 Krupp Gmbh COMPOSITE BODY CONSISTING OF A BASE BODY AND ONE OR MORE LAYERS OF HARD MATERIAL FREE OF BONDING METALS
EP0031805A1 (en) * 1979-12-28 1981-07-08 Vereinigte Edelstahlwerke Aktiengesellschaft (Vew) Hard body, especially hard metal wearing part, and process for its production
US4337300A (en) * 1979-08-09 1982-06-29 Mitsubishi Kinzoku Kabushiki Kaisha Surface-coated blade member for cutting tools and process for producing same
US4341834A (en) * 1976-07-10 1982-07-27 Mitsubishi Kinzoku Kabushiki Kaisha Coated super-hard alloy articles
WO1984001587A1 (en) * 1982-10-10 1984-04-26 Vni Instr Wear-resistant single-layer coating of metal cutting tool
WO1985001461A1 (en) * 1983-09-30 1985-04-11 Vsesojuzny Nauchno-Issledovatelsky Instrumentalny Metal-cutting tool and method for manufacture thereof
US4592964A (en) * 1984-06-09 1986-06-03 Goetze Ag Wear-resistant coating
EP0310043A2 (en) * 1987-10-01 1989-04-05 Gte Laboratories Incorporated Oxidation resistant, high temperature thermal cycling resistant coating on silicon-based substrates and process for the production thereof
EP0347399A1 (en) * 1988-06-13 1989-12-20 Sandvik Aktiebolag A diffusion barrier coating material
US4950558A (en) * 1987-10-01 1990-08-21 Gte Laboratories Incorporated Oxidation resistant high temperature thermal cycling resistant coatings on silicon-based substrates and process for the production thereof
US5246787A (en) * 1989-11-22 1993-09-21 Balzers Aktiengesellschaft Tool or instrument with a wear-resistant hard coating for working or processing organic materials

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4437053A1 (en) * 1994-10-18 1996-02-08 Widia Gmbh Tungsten@ carbide hard alloy with good mechanical properties
DE10017909B4 (en) * 1999-04-13 2009-07-23 Mitsubishi Materials Corp. Coated cemented carbide cutting tool element
DE102010052687A1 (en) * 2010-11-26 2012-05-31 GFE Gesellschaft für Fertigungstechnik u. Entwicklung Schmalkalden e.V. Multi-layer, oxynitride layer system with cubic aluminum nitride and aluminum oxynitride on substrate such as hard metal, comprises a first layer, a second layer, an oxygen-containing third layer, and an oxygen-containing oxynitride layer

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4341834A (en) * 1976-07-10 1982-07-27 Mitsubishi Kinzoku Kabushiki Kaisha Coated super-hard alloy articles
US4463033A (en) * 1976-07-10 1984-07-31 Mitsubishi Kinzoku Kabushiki Kaisha Process for production of coated super-hard alloy articles
FR2393852A1 (en) * 1977-06-09 1979-01-05 Sandvik Ab BODY OF SINED CARBIDE INCLUDING A COATING AND METHOD OF MANUFACTURING
FR2442718A1 (en) * 1978-11-29 1980-06-27 Krupp Gmbh COMPOSITE ELEMENT FOR USE AS A WEAR FOR THE MACHINING OF METAL PARTS
FR2454903A1 (en) * 1979-04-28 1980-11-21 Krupp Gmbh COMPOSITE BODY CONSISTING OF A BASE BODY AND ONE OR MORE LAYERS OF HARD MATERIAL FREE OF BONDING METALS
US4337300A (en) * 1979-08-09 1982-06-29 Mitsubishi Kinzoku Kabushiki Kaisha Surface-coated blade member for cutting tools and process for producing same
EP0031805A1 (en) * 1979-12-28 1981-07-08 Vereinigte Edelstahlwerke Aktiengesellschaft (Vew) Hard body, especially hard metal wearing part, and process for its production
WO1984001587A1 (en) * 1982-10-10 1984-04-26 Vni Instr Wear-resistant single-layer coating of metal cutting tool
WO1985001461A1 (en) * 1983-09-30 1985-04-11 Vsesojuzny Nauchno-Issledovatelsky Instrumentalny Metal-cutting tool and method for manufacture thereof
GB2156388A (en) * 1983-09-30 1985-10-09 Vni Instrument Inst Metal-cutting tool and method for manufacture thereof
US4592964A (en) * 1984-06-09 1986-06-03 Goetze Ag Wear-resistant coating
EP0310043A2 (en) * 1987-10-01 1989-04-05 Gte Laboratories Incorporated Oxidation resistant, high temperature thermal cycling resistant coating on silicon-based substrates and process for the production thereof
EP0310043A3 (en) * 1987-10-01 1989-09-06 Gte Laboratories Incorporated Oxidation resistant, high temperature thermal cycling resistant coating on silicon-based substrates and process for the production thereof
US4950558A (en) * 1987-10-01 1990-08-21 Gte Laboratories Incorporated Oxidation resistant high temperature thermal cycling resistant coatings on silicon-based substrates and process for the production thereof
EP0347399A1 (en) * 1988-06-13 1989-12-20 Sandvik Aktiebolag A diffusion barrier coating material
US5246787A (en) * 1989-11-22 1993-09-21 Balzers Aktiengesellschaft Tool or instrument with a wear-resistant hard coating for working or processing organic materials

Also Published As

Publication number Publication date
ES460647A1 (en) 1978-11-16
FR2357321B3 (en) 1980-04-04
IT1082111B (en) 1985-05-21
DE2730355A1 (en) 1978-01-12

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