DE10330247A1 - Cosmetic composition in single-serving packs - Google Patents

Abstract

The present invention relates to cosmetic compositions K which are packaged in portions in single-serving packs 1 and can optionally be free of preservatives. The cosmetic compositions K preferably contain at least one polymer. Due to the packaging as a single-serving portion pack 1 or a plurality of single-serving portion packs 1 which are attached to one another, the cosmetic compositions K contained therein can be easily transported by the consumer at any time and can be used in a simple manner in the correct dosage.

Description

The The present invention relates to cosmetic compositions, in particular Hair treatment agents which are used as a flowable, pasty, liquid or gel-like preparation, or as a powder, as a granulate or as a shaped body. The present The invention further relates to a method for treating skin, nails and keratin fibers with these cosmetic compositions.

cosmetic Agent for the care and maintenance of the natural functions of the skin and hair are becoming more and more important. To contribute under others the changed Consumer habits and fashion trends. For example through the intensive use of tanning salons skin and hair in their Structure stronger sustained by UV light impaired. These impairments show up on the skin like the hair, for example by a Loss of elasticity.

Farther leads the extensive physical activity at leisure in a frequent intensive cleaning of skin and hair. This allows the protective film from sebum, which is continuously produced by the numerous sebum glands is, or the sebum production of the sebaceous glands themselves are severely impaired. As As a result, oily skin and hair appear.

Fashion trends with current colors for "make-up", lipsticks for To dye of the lips and mascara as well as hair dye and waving agents if the skin is stressed and the hair is pre-stressed, a remainder impairment of the natural Condition of skin and hair. It is therefore not surprising if the proportion of consumers with sensitive, less elastic, dryness and irritated skin as well as combability, the shine, the elasticity, of brittleness and the maximum tear strength Hair increases rapidly.

It has therefore not lacked attempts to remedy these abuses. Here were et al Emulsions for skin care with regard to their irritant potential further optimized by selecting suitable emulsifiers. For cleaning skin and hair use mild tensides to skin and hair not additionally to charge. With moisturizing Trying to stimulate sebum production at the substances To avoid cleaning. UV stabilizers and vitamins such as vitamin E are said to be disadvantageous Reduce the effects of UV light. Protein hydrolyzates become Balancing the internal structure of skin and hair. With Plant and algae extracts can be used, for example, in the moisture balance influenced by skin and hair become.

Farther cosmetic active ingredients are increasingly used in agents for Cleaning and care of surfaces such as glass, porcelain, leather, textiles, floors of all kinds in the home and Commercial, in addition to the skin of the user of such products strain. So are hand dishwashing detergents with nourishing additives like proteins or lipid-replenishing Substances available on the market.

Often, however is the cause of irritation of the skin, nails or the hair, not the cosmetic product as such, but rather individual ingredients of the respective compositions. Very often is this for the preservatives contained in the cosmetic products applicable. Let yourself be the manufacture and packaging of cosmetic products Precautions on the part of the manufacturer of the means for an aseptic Make production, so the cosmetic product in question generally at the latest at the consumer during which often lasts for weeks prolonged use of the same container contaminated with germs. For a long time there has therefore been almost nothing on the consumer side unfulfilled Desire for cosmetic preparations free of preservatives.

It are now in recent Time a number of developments in the cosmetic field that a need for novel active ingredients or combinations of active ingredients, new forms of formulation or new forms of administration to have. Many of these developments are not exclusively based on technical disadvantages or inadequacies of the known Medium, but e.g. on environmental protection aspects, legal Requirements or other "non-technical" causes.

For example, in the past, water-based agents have replaced volatile organic compounds. This created the problem of the lower volatility of water compared to alcohols, which is reflected in the longer drying times on the hair. Furthermore, due to the often poorer solubility of polymeric compounds in aqueous systems, this changeover is often associated with the disadvantage that when the desired amount of polymer is applied to the hair, water inevitably reaches the hair in such amounts that the drying times are unacceptable become long. These disadvantages in connection with strong fluctuations in the dosage of the cosmetic agents by the consumer can be a problem for the consumer, possibly even several times a day.

Further Hair care products for hair styling, which have these disadvantages occur to a particular degree can, are hair waxes. Hair waxes contain as a shaping component usually vegetable, animal or mineral waxes and are used as solid formulations, usually in relatively large crucibles, offered. For the application is removed from the crucible a certain amount, then rubbed in the hand and spread on the hair. Through these hair waxes is based on natural Raw materials a good hold of the hair causes at the same time stronger Brilliance. Still can the hair waxes on the market meet the wishes of the users simple application and easier distribution on the hair not completely to satisfy. So here is the exact, simple and consistent reproducible dosing a problem. The usual crucibles and tubes become frequently either too much or too little product removed. In addition, leads in particular expressing of a strand from the tubes often to product loss and contamination of the immediate Surroundings. Furthermore, there are always problems with removing the last one Product residues from the tube.

On Another disadvantage is that cosmetic products are often in relatively large Containers are packed. This is not just the one mentioned above Disadvantage regarding the problems that arise during removal with increasing emptying, but it is also extremely inappropriate in today's way of life if Large containers are always carried on a short trip have to. So leads especially the changed one The lifestyle of the consumer means that the consumer of one cosmetic products today both simple, uniform and good dosage for a quick at any time Application of cosmetic products, as well as a problem-free limitation of the must accompany Product for Applications in the respectively required Number expected.

task The present invention is therefore based on appropriate means develop on the one hand in terms of application technology Properties of a cosmetic product are those set by the consumer Meet expectations and on the other hand the cosmetic product is easy to handle, precisely dosed and for one application each in a sufficiently portioned amount available do. The cosmetic product is intended to be used individually for each application and be easily removable in full without residual losses, as well at any time simply and easily only in the required amount carried and can be applied.

This The task is achieved by a cosmetic composition in a single-serving pack according to claim 1 solved. Particularly advantageous refinements and developments of the invention result from the dependent Claims.

Essential in the solution of the invention The task is to ensure that the cosmetic composition, which is flowable, pasty, liquid or gel Preparation, or as a powder, as granules or as a shaped body can, is introduced into a single-serving pack, the single-serving pack a container part comprises a cup-like shape with an opening and has a closure flange, which the opening as at least substantially radially outwards protruding collar surrounds, and wherein the single-serving pack further comprises a cover which with the closure flange of the container part is connected and the opening of the container part closes and which through a peelable or peelable and / or push-through sealing film is formed.

Surprisingly it has now been found that by this invention Packaging of a cosmetic composition in single-serving packs the task was solved in an excellent way.

The main advantage is that it is particularly user-friendly for the consumer in several ways. The cosmetic composition is available in precisely portioned amounts for each application and can be removed quickly and completely by the consumer in a particularly simple manner. For this he only needs to pull off or press in the sealing film and can take the exactly metered amount of the cosmetic agent through the then opened opening of the container part. Losses in the removal of the last remaining quantities from larger tubes or crucibles no longer occur. In addition, even on short trips, the consumer can only carry the cosmetic products in the amount actually required, so that the problems associated with transporting large containers back and forth are eliminated. The application-related properties of the cosmetic expected by the consumer The product is retained in full even in the case of small containers which advantageously contain the amount of the respective cosmetic product packaged for an application.

As It has also proven to be particularly advantageous that the packs according to the invention are in single-serving packs dosed cosmetic compositions free of preservatives could be.

Single-use portion packs as such are, for example, from the German published documents DE 44 29 503 A1 . DE 24 04 232 A1 , the German utility model DE 299 18 595 U1 . DE 299 07 740 U1 . DE 299 07 744 U1 , the German patent specification DE 43 17 326 C1 , the U.S. writings US 3,759,371 . US 4,574,954 . US 6,443,307 , the European patent application EP 0 563 934 A1 or the international applications WO 02/062665, WO 98/43893 known per se. Reference is expressly made to the above-mentioned documents since they relate to aspects of the present invention. Push-through packs represent an embodiment of the single-use packs according to the invention. Often these are also referred to as blister packs or skin packs and serve in the pharmaceutical and ecotrophological field as containers for accommodating corresponding products such as capsules, dragees, tablets, active ingredient balls, etc. Such a push-through pack contains the lumpy product within the container part, the opening of which is sealed by the sealing film. The product is thus protected against environmental influences such as moisture and dirt and gives the consumer the guarantee of the durability and original condition of the packaged product.

Once sachets in a wide variety of configurations, for example used in pharmacy for packaging tablets, coated tablets or suppositories. In the food industry, for example, in such packaging Packed condensed milk.

The Design of push-through packaging and the selection of plastic films to form the container part heard of sealing films on the tools of professionals in the field of packaging technology. In general, the "Packaging Handbook 1999", publisher for chemical Industrie, Augsburg, in particular pages 211 to 213, 388 to 413 to get expelled. There are extensive explanations of those concerned Parameters, the plastics used, etc.

in the Within the scope of the present invention is a single-serving pack a so-called "unit-dose packaging" understood. Not expressly according to the invention in the sense of the present invention are single-serving packs such as four-edge sealed packaging, bag, Tubular bags, stand-up bags, tubes or small jars as packaging, which are distributed to consumers in particular as product samples. In such packaging not used according to the invention For example, shampoos or bath products are packaged. This packaging however, have the significant disadvantage that they are often difficult to especially with wet hands in the bathroom, open it leave and above all are not completely emptied.

It however, gives no indication among the aforementioned documents on the use of the single-serving packs used according to the invention to such packaging of cosmetic products that the cosmetic preparations packaged therein simply and easily and convenient anytime, anywhere taken along and in the exact and constant dosage and can be used without product loss.

Out Japanese Patent Application No. 11180467 A is a blister pack known for cosmetics, however, here the cosmetic compositions are first described in packed a large number of separate containers, which in turn are then packed in a blister pack. The consumer must So at least two packages open to the cosmetic Approach composition, which significantly reduces comfort and easy and quick handling, for example in the shower excludes. Moreover can here too problems with the desired complete emptying of the individual containers occur.

Furthermore, it is from the German published application DE 43 01 010 A1 known to fill cosmetic products in portions in bags, preferably in linen bags. Such bags, which are used here as a bath additive for consumers with dermatological problems, are expressly not the subject of the present invention, since not only problems with complete emptying occur here, but also general handling, in particular when opening the bags, is difficult.

Furthermore are from the German utility model DE 202 03 811 U1 Foil packs with an absorbent insert are known, the insert being impregnated with a flowable or spreadable cosmetic agent. Apart from the fact that such four-edge sealed packaging, which is used as an advertising medium for gluing or inserting in magazines, is also not part of the subject matter of the present invention, they require an additional auxiliary body with the absorbent insert, which on the one hand causes additional costs and on the other hand the application to liquid or semi-liquid resources. This type of packaging cannot be used for powdered, granular or solid cosmetic products.

Also, for example, are from the DE 38 74 714 T2 so-called disposable make-up sets are known, which can be packaged as trial sets in blister packs. In this case, however, an additional distribution member is required as an applicator for applying the cosmetic make-up product, which is packaged together with the make-up agent. The packaging is therefore particularly complex due to an additional constriction zone to be provided between the distribution element and the handle of the distribution element, and it requires additional space for the distribution element, which is no longer available for the make-up agent. Similar to the aforementioned document, the make-up agent is included in the distribution element as an additional body, so that this is also not suitable for powdery, granular or solid cosmetic agents on the packaging.

The two utility models also disclose in a similar way DE 201 02 282 U1 and DE 299 13 844 U1 Packaging for cosmetic or pharmaceutical products, the packaging each comprising applicator means for applying the product. In addition, these packages are much more complex and therefore more expensive to manufacture and more difficult to handle for the consumer. So the consumer has to pack according to the DE 201 02 282 U1 fold the packaging to break open a specially shaped delivery channel. The removal then takes place as with a tube with the disadvantages already mentioned with regard to a desirable complete emptying. In the packaging used in particular for the application of temporary tattoos according to DE 299 13 844 U1 the removal opening in the application base for the product, which can only be used in liquid or paste form, is spatially separated from the product chamber, so that a connection area to an additionally required distribution chamber is necessary. Both the connection area and the distribution chamber must be formed separately, which requires a particularly complex and expensive construction of the packaging. In addition, handling by the consumer is also relatively cumbersome and difficult, which makes it impossible to use this packaging in the sense of the present invention.

Finally is from the German patent DE 42 39 082 C1 a device for receiving fragrant fragrances such as perfume known, but which does not allow controlled removal of the product filled therein. Rather, only the smallest quantities of perfume can be filled here, which should be released in an undefined manner to the surroundings, in particular to the clothing of the consumer located above, when the container is destroyed. Use in the sense of the present invention is therefore also not possible with this device.

The packaging according to the present invention, in contrast, is a structurally simple and therefore inexpensive to produce single-dose pack, in which not only liquid, flowable, gel-like or pasty cosmetic preparations, but also cosmetic products in the form of powder, granules or solid moldings in the desired amount have it packed. Because the disposable portion pack has a container part with a cup-like shape, the consumer can remove the respective product from the container part without any problems. The consumer can also easily open the single-use portion pack, since the opening of the container part is completely surrounded by a collar-shaped closure flange to which the closure film is attached, which can either be peeled off to open it or pressed in. Likewise, the closure film can be designed so that it can be pushed through not only in the case of solid cosmetic moldings, but also in the case of flowable, gel-shaped, granular or powder-form cosmetic products, so that when the consumer presses the container part flexibly, at least in this case, via the cosmetic composition is pushed outwards. Preferably, the container part of the disposable portion pack is specifically provided with certain contours for the formation of one or more crease lines, which are designed and arranged in such a way that a constriction, in the case of a push-through packaging or push-through packaging or press-through packaging with a push-through sealing film the opening for the exit of a lumpy product is avoided. The weak points in the container part formed by the kink lines at the same time reduce the effort required when pushing the base area in the direction of the opening, so that even delicate, lumpy products with such a part Push-through packaging can be optimally delivered. For the design of the push-through packaging in detail, reference may also be made to the specialist knowledge documented in the "Packaging Handbook 1999", which is also applicable in the present case.

Especially It is advantageous if the cosmetic composition at least a natural or contains synthetic polymer, the polymer or polymers preferably in an amount from 0.01 to 30% by weight of the total cosmetic composition is included. Polymeric compounds are used in cosmetic products used many times and with increasing importance. You own numerous functions and effects, often they are multifunctional themselves and show several desired effects in a single structure for the cosmetic products concerned. So polymers can be cosmetic products thicken, that means, for example, that they can bind water and thereby viscosity build up. At the same time, bound water means in cosmetic Means also a reduction in water activity, which is responsible for the contamination of the agent in question may be important. If the activity of the free Water is too low, so can germs no longer dissolve in it and develop. The agent in question does not have to or conserved at least significantly less.

polymers are used, for example, in hair-setting formulations. An appealing looking hairstyle is now generally considered indispensable Part of a neat exterior viewed. Due to current fashion trends, hairstyles always apply as chic, which can only be used with certain hair types using certain Build strengthening active ingredients or maintain them for a longer period to let. These firming agents, which are usually are polymeric compounds, can be used in conventional hair cleaning or -conditioning agents are incorporated. In many cases but it is advantageous to use them in the form of special agents such as hair fixers, Apply hair gels, hair waxes or hair sprays.

In the case of a flowable or liquid cosmetic composition, it is particularly advantageous if it has a viscosity in the range from 100 mPas to 10 ⁵ mPas. In principle, however, the teaching according to the invention can also be applied to cosmetic products with a viscosity of below 100 mPas or above 10 ⁵ mPas.

If the cosmetic composition as a powdery or granular or solid molded body it is particularly favorable if they have at least one resolution accelerator contains.

For a special one inexpensive to produce The invention proposes that the single-serving pack a cup-like container part has, which is formed from a film, in particular deep-drawn is. Depending on the application, however, the container part can also be cast or be injected, for example to achieve a higher strength.

According to one particularly preferred and inexpensive to produce The invention provides that the opening is round, preferably circular, oval or elliptical is formed and that at least the side walls, preferably also the bottom area, the cup-like shape of the container part exclusively are round, in particular rotationally symmetrical. Such Round or rounded shapes facilitate complete removal of a cosmetic product. It is particularly advantageous to use the cup-like Forming the container part at least in a lower part at least approximately as a segment of a hollow sphere or to form as a segment of a hollow ellipsoid of revolution. In particular can the container part at least approximately hemispherical be trained. In this way, the consumer can also flow, gel or powdery cosmetic products particularly light and without any problems from the container part remove since there are no straight surfaces or corners make removal difficult. In principle, however, other shapes can also be used for the Cup-like shape of the container part be considered. In particular, the cup-like shape also with an oval or elliptical base or Cross sectional area accomplished his. In the case of solid cosmetic compositions, the shape is Cup-like shape of the container part preferably adapted to the shape of the cosmetic molding, also straight walls and angular shapes can be used in addition or alternatively, the wall of the cup-like shape of the container part also include an area that is at least approximately in the form of a hollow cylinder or a hollow truncated cone is formed. Also a conical one Form, especially above a hollow spherical segment-shaped bottom of the container part can be connected, allows easy and complete removal of the cosmetic product.

It is also particularly advantageous if the closure flange of the container part has a straight line edge and is designed in particular with rounded corners. This configuration enables a simple connection of several single-serving packs to one another even with a round opening and round designs of the cup-like shape of the container part.

Inexpensive for optimal It is fastening the sealing film with the sealing flange continue if the outer contour the sealing film with the outer contour of the closure flange matches.

For a particularly easy removal possibility, in particular of gel-like or pasty cosmetic compositions, it is proposed that the opening have an area of 1 to 20 cm ² , preferably 6 to 12 cm ² . In particular if this surface is round, the consumer can easily remove the product from the cup-like shape of the container part with one or two fingers.

Especially advantageous with the single-serving pack according to the invention It is also cosmetic composition if the cosmetic Composition in an amount with a weight between 0.1 and 40 g, preferably between 3 and 12 g and / or with a volume between 0.1 and 40 ml, preferably between 3 and 12 ml. This amount is particularly important for shampoos or hair styling products one for application is sufficient dosage.

For the sealing film the single-serving pack according to the invention preferably a metal foil, in particular aluminum foil, possibly proposed in a multilayer composite film, the one Has a thickness of 0.05 to 0.5 mm. However, it is also possible that Closure film made of plastic film, in particular a PE film, a PET film, a PVC film or a multilayer Foil, for example made of PE / PP, PE / aluminum, PET / aluminum, PE / PET / aluminum, PP / PET / PE, PET / aluminum / PE or PET / aluminum / PP can be.

The Wall of the cup-like shape of the container part can advantageously have a thickness of 0.2 to 1.5 mm, preferably 0.5 to 1 mm. In particular, the container part from a plastic film, possibly in a multilayer composite film be educated. Therefor a PE film or a PVC film is particularly suitable, however a metal foil can also be used. Preferably, the Wall of the cup-like shape of the container part here approximately three to four times the thickness of the sealing film.

Either where the container parts forming films as well as the sealing films can - if they than executed as plastic films are - general between water-insoluble and water soluble Differentiate foils. Both types of film can be used equally. water Films are made from, for example, PVC, PE, PP, and mixtures made of PE and polystyrene. water-soluble Films are made, for example, from polyvinyl alcohol, starch, cellulose, Gelatin (with appropriate reactive internals). As a sealing film comes naturally in particular the metal foil already mentioned above, in particular one Aluminum foil as water-insoluble Slide in question.

According to one particularly preferred embodiment the invention provides that the cup-like shape of the container part is formed from a transparent or translucent material. In this way, the consumer can determine the filling level of the single-serving pack and the optical nature of the cosmetic composition detect. In particular can different colors of the cosmetic composition recognized and used for differentiation purposes. Likewise Is it possible, for the Sealing film use a transparent or transparent film. Particularly in the case of light-sensitive cosmetic compositions can both the cup-like shape of the container part and the sealing film from an opaque Material be formed.

Especially It is also advantageous if the closure film over the entire scope of opening through an adhesion promoter and / or through a seal connection and / or welded joint cohesively with the closure flange is connected. So that the single-serving pack nevertheless opened particularly easily can be, the closure flange preferably has at least an edge area in which it is not with the as a tear tab trained area of above lying sealing film is connected. With such a peel-off packaging will open the sealing film subtracted upwards. In any case, however, the sealing film is before opening tightly connected to the sealing flange, so that the single-serving pack sealed, in particular airtight.

So that the consumer can easily open a peel-off packaging even with wet hands, for example in the shower, it is further proposed that the closure film be at least in one position tear tab formed area roughened on one or both sides and / or coated, in particular rubberized

For advertising or informational purposes, it is still possible to use the sealing film the single-use portion pack directly or in particular via stickers to be printed indirectly.

advantageously, can the single-serving pack according to the invention also be a blister pack, in particular a printed and / or peelable blister pack can act. As well can the single-serving portion pack as push-through packaging or press-through packaging accomplished be, with the packaging mentioned here being designed that the compositions to be recorded are each in their own Receiving trough of a container part the packaging are included.

According to one further particularly preferred embodiment variant of the present The invention provides several single-serving packs with cosmetic Combine composition into a packaging unit, where two or more single-serving packs in at least one row arranged side by side and over their closure flanges are connected. Show the cup-like formations of the container parts in the same direction. In particular can the single-serving packs in several parallel rows be arranged side by side, a particularly preferred combination six single-serving packs in two rows of three packs each having. Each single-serving sachet contains a cosmetic one Composition.

Especially It is advantageous here if the individual single-serving packs in a known manner by means of predetermined breaking points releasably together are connected so that the individual units are easily separated from each other let separate. The consumer can, for example, take a short trip needed Divide the amount of the cosmetic product and save weight and space take.

Preferably can different cosmetic compositions in the related Single-serving packs of a packaging unit may be included. According to one particularly preferred embodiment for example arranged one behind the other in a first row One-time serving packs of a shampoo and in a second row of single-serving packs arranged one behind the other, which next to the first row is arranged, a hair conditioner packaged his. In the case of the example, shampoo and care products are given to the consumer thereby the advantage of a classic "2 in 1" shampoo, ie hair cleaning and care, but not in a recipe with the disadvantages known to the person skilled in the art, but a full hair shampoo and a full care product in a package for sequential use. Of course but also other combinations of cosmetic compositions conceivable in this form, for example hair care and hair styling, UV skin protection and après-sun Care, facial cleansing and facial care, etc.

In particular if the sealing film and / or the cup-like shape of the container part are formed from a transparent or translucent material it’s particularly cheap if the different cosmetic compositions are different Show colors. additionally or alternatively can but also the sealing films for the various cosmetic ones Compositions can be colored differently.

object The present invention is also a kit containing at least a single-serving pack with cosmetic composition and / or at least one packaging unit of the type described above, one preferably consisting of plastic, cardboard or cardboard Outer packaging is provided in which the single-serving portion (s) and / or packaging units) held or completely included is or are. Instructions for use may also be preferred included in the kit.

According to a further particularly preferred embodiment of the present invention, the outer packaging is formed by a flat envelope with two opposing side walls, between which the closure flanges of several single-serving packs, in particular one packaging unit, are accommodated, one side wall containing a plurality of openings, through each of which a cup-like shape of the A portion of a single-serving pack protrudes through the container. This type of outer packaging represents a product presentation that is particularly appealing to the consumer, especially if the exposed shapes of the individual proton packs are transparent or see-through. Of course, the envelope itself can be printed in. The sealing films are also in this way additionally protected against unintentional opening.

The The present invention further relates to a method for cosmetic Treatment of skin, nails or keratin-containing fibers, one or more single servings of one cosmetic composition from a single-serving pack of to be described above and if necessary be dissolved in a medium to form the preparation, and wherein the single portion according to the invention or if applicable the preparation on the skin, the nails or the keratin fibers is applied and, if necessary, after after an exposure time becomes.

Finally concerns the present invention also provides a method of making a Single-use portion pack or for the production of a packaging unit the above-described An that the process steps of a Deformation of a thermoformed film, the filling of the resulting container part with a cosmetic composition, which as a flowable, pasty, liquid or gel Composition, or as a powder, as granules or as a shaped body, closing, preferably sealing with a sealing film and for final shaping and / or a punching process for separating the individual portion packs includes.

in the The invention is based on the following only exemplary embodiments illustrative drawings explained. Show:

1 : Cross section through a first embodiment variant of a single-portion pack according to the invention,

2 : Top view of the single-serving pack 1 .

3 : three-dimensional view of the single-serving pack 1 .

4 : Cross-section through an embodiment variant designed as a packaging unit of 6 single-serving packs according to the invention

5 : Top view of the packaging unit 4 .

6 : three-dimensional view of the packaging unit 4 .

7 : three-dimensional view of a packaging unit filled with a cosmetic gel, and

8th : Outer packaging for the packaging unit from the 4 to 7 ,

In the in the 1 to 6 illustrated single-serving packs according to the invention 1 All cosmetic compositions K, which are present as a flowable, pasty, liquid or gel-like preparation, or as a powder, as granules or as shaped bodies, can be packaged.

The single-serving pack 1 has a container part deep-drawn from a transparent plastic film 2 and a cover formed from an aluminum foil as a cover 3 , The container part 2 has a cup-like shape 4 with a circular opening at the top 5 and a substantially square closure flange 6 with rounded corners 7 on the opening 5 in the plane of the opening 5 surrounds as a radially projecting collar. The sealing film 3 is over the entire perimeter of the opening 5 with the closure flange 6 of the container part 2 connected to the opening 5 of the container part 2 close tightly. To open the single-serving pack 1 can the sealing film 3 be peeled off (peel-off).

The bowl-like shape 4 of the container part 2 is essentially hemispherical, so that the consumer can remove the cosmetic composition K contained therein without any problems. In particular, the predominant lower part 8th the cup-like shape 4 of the container part 2 Convex in the form of a segment of a hollow ball, on the upper edge of which is in the closure flange 6 continuous concave curved, rotationally symmetrical area 9 followed.

In the in the 4 to 6 The variant shown are six single-serving packs 1 into a coherent packaging unit 10 summarized, each single serving pack 1 each contains a cosmetic composition K. The single-serving packs 1 are in two rows arranged to three pieces, each over the edges 11 their closure flanges 6 are releasably connected. The contact lines of the contiguous edges are stamped 12 as a predetermined breaking point for easy separation of the individual single-serving packs 1 executed.

In the 2 and 3 such as 5 and 6 the tear-open tabs are particularly good 13 to peel up the individual single-serving packs 1 recognizable that not with the underlying sealing flange 6 are connected.

Of course, the surfaces of the packaging 1 respectively. 10 both on the top 14 or front as well as on the bottom 15 or the reverse side can be printed using all of the customary methods known to those skilled in the art.

In 7 is a packaging unit filled with a cosmetic agent K in the form of a gel 10 shown, this packaging from one with six molded-in cup-like receiving troughs 4 provided packaging-forming plastic film and one of the receiving troughs 4 closing sealing film 3 consists, and wherein the gel K in the receiving wells 4 , protected by the sealing film 3 , is arranged. The bowl-like receiving troughs 4 consist of a transparent or transparent plastic through which the cosmetic compositions K packed therein can be recognized.

Of course, the single-serving packs 1 or the packaging units 10 themselves in turn are packed in appropriate outer packaging, which are known to those skilled in the art as such. It is also possible according to the invention in this outer packaging to provide the buyer with a detailed description of the ingredients and instructions for use for the use of the cosmetic compositions K. According to the invention, it is also possible for these outer packaging to contain single-serving packs with several different cosmetic compositions K. In particular, this is also an equivalent alternative according to the invention to a blister card with different cosmetic compositions on this one blister card itself.

In 8th is a particularly preferred outer packaging 16 for one packaging unit 10 according to the 4 to 7 shown. It is through a flat envelope with two opposite side walls 17a and 17b formed between which the closure flanges 6 a packaging unit 10 or the blister card of a blister pack can be picked up. The side wall 17a contains six circular openings 18 , each with a cup-like shape 4 a single-serving pack 1 can protrude through.

The cosmetic composition K according to the invention for packaging in single-serving packs 1 is described below. The individual components of the composition K naturally depend on the type of cosmetic composition K to be packaged. In principle, of course, any cosmetic composition K, be it a shampoo, a shower bath, a facial cleanser, a hair treatment to rinse out, a hair treatment to stay the hair, a hair fixative, a hair wax, a hair gel, a skin cream, etc. are suitable. Cosmetic compositions which are usually used by the consumer in amounts of 0.1 g to 40 g per individual application and which are not mixed directly with other cosmetic compositions to achieve special effects are particularly suitable. Therefore, cosmetic compositions for the reductive or oxidative treatment of skin, nails or keratin fibers are possible in principle within the meaning of the invention, but are less suitable. Furthermore, cosmetic products which are distributed to consumers in small packaging such as bags or jars, for example as product samples, are not according to the invention. Of course, cosmetic compositions K, which have been pressed into shaped bodies, are a particular embodiment of the present invention.

A first embodiment of the present invention are cosmetic compositions which in liquid Form. These are particularly well suited if they are a viscosity have in the range of 10 mPas up to 1,000,000 mPas. The viscosity of the compositions depending on the final viscosity of the cosmetic products the usual and known methods at 25 ° C. measured. The measurement methods to be taken as a basis are known to the expert for example for a shampoo or an O / W emulsion or a W / O emulsion. In this context, for example, the DIN standard 53015 referred in their entirety.

Depending on the type of cosmetic composition K and the desired viscosity, the person skilled in the art will set the required viscosity using the customary methods for the respective cosmetic formulations Make methods. In the case of surfactant formulations, for example, the viscosity can be adjusted using electrolytes such as NaCl, MgSO ₄ , citrate, phosphate etc. However, the use of special thickening substances or substance mixtures such as fatty alcohol alkoxylates, alkoxylated glycerol fatty acid esters etc. is also familiar to the person skilled in the art. Furthermore, natural and synthetic polymers are increasingly used for the targeted adjustment of viscosities in cosmetic preparations. Polymers in particular are often used in cosmetic preparations because they are often multifunctional. Multifunctional means that the use of a polymeric raw material in a composition K fulfills several functions at the same time.

So can the polymer of the invention (G) can be both a setting and / or film-forming polymer also a polymer with conditioning or conditioning and / or thickening properties. It can in a preferred embodiment also be advantageous, at least one advanced and / or at least a film-forming, setting polymer and / or at least one thickening Formulate polymer. Among polymers are both natural and also synthetic polymers, which are anionic, cationic, amphoteric can be charged or non-ionic, to understand.

Under film-forming polymers are to be understood as those polymers which when drying a continuous film on the skin, hair or the nails leave. Such film formers can be used in many different ways cosmetic products such as face masks, make-up, Hair fixers, hair sprays, hair gels, hair waxing, hair treatments, shampoos or nail polishes can be used.

Examples of common film formers are Abies Balsamea (Balsam Canada) Resin, Acetylenediurea / Formaldehyde / Tosylamide Crosspolymer, Acrylamide / Ammonium Acrylate Copolymer, Acrylamides Copolymer, Acrylamides / DMAPA Acrylates / Methoxy PEG Methacrylate Copolymer, Acrylamide / Sodium Acrylate Copolymer, Acrylamidopropyltrimonium Chloride / Acrylamide Chloride / Acrylamide Chloride / Acrylamide Copolymer , Acrylamidopropyltrimonium Chloride / Acrylates Copolymer, Acrylates / Acetoacetoxyethyl Methacrylate Copolymer, Acrylates / Acrylamide Copolymer, Acrylates / Ammonium Methacrylate Copolymer, Acrylates / Behenyl Methacrylate / Dimethicone Methacrylate Copolymer, Acrylates / t-Butylacrylamide Copolymer, Acrylates Copolymer, Acrylates / Diacetoneacrylamide Copolymer, Acrylates / Dimethicone Copolymer, Acrylates / Dimethicone Methacrylate Copolymer, Acrylates / Dimethiconol Acrylate Copolymer, Acrylates / Dimethylaminoethyl Methacrylate Copolymer, Acrylates / Ethylhexyl Acrylate Copolymer, Acrylates / Ethylhexyl Acrylate / HEMA / Styrene Copolymer, Acrylates / Ethylhex yl Acrylate / Styrene Copolymer, Acrylates / Hydroxyesters Acrylates Copolymer, Acrylates / Lauryl Acrylate / Stearyl Acrylate / Ethylamine Oxide Methacrylate Copolymer, Acrylates / Octylacrylamide Copolymer, Acrylates / Propyl Trimethicone Methacrylate Copolymer, Acrylates / Stearyl Acrylate / Dimethicone Methacrylate Copolymer, Acrylates / Stearyl Acrylate / Ethylamine Oxide Methacrylate Copolymer, Acrylates / TDI / Trimethylolpropane Copolymer, Acrylates / VA Copolymer, Acrylates / VA Crosspolymer, Acrylates / VP Copolymer, Acrylates / VP / Dimethylaminoethyl Methacrylate / Diacetone Acrylamide / Hydroxypropyl Acrylate Copolymer, Acrylic Acid / Acrylonitrogens Copolymer, Adipic Acid / CHDM / MA / Neopentyl Glycol / Trimellitic Anhydride Copolymer, Adipic Acid / Diethylene Glycol / Glycerin Crosspolymer, Adipic Acid / Diethylenetriamine Copolymer, Adipic Acid / Dilinoleic Acid / Hexylene Glycol Copolymer, Adipic Acid / Dimethylaminohydroxypropyl Diethylenetriamid Copolymer / Epoxiamine Acid Copolymer / Epoxiamyl Acid Copolymer / Epoxiamine Acid Copolymer , Adipic Acid / Fuma ric Acid / Phthalic Acid / Tricyclodecane Dimethanol Copolymer, Adipic Acid / Isophthalic Acid / Neopentyl Glycol / Trimethylolpropane Copolymer, Adipic Acid / Neopentyl Glycol / Trimellitic Anhydride Copolymer, Adipic Acid / PPG-10 Copolymer, Albumen, Allyl Stearate / VAens Copolymer, Alumen Leaf Polysaccharides, Aminoethylacrylate Phosphate / Acrylates Copolymer, Aminoethylpropanediol-Acrylates / Acrylamide Copolymer, Aminoethylpropanediol-AMPD-Acrylates / Diacetoneacrylamide Copolymer, Ammonium Acrylates / Acrylonitrogens Copolymer, Ammonium Acrylates Copolymer, Ammonium Alginate, Ammonium Polyacrylate, Ammonium Styrene / Acrylates Acrylates Copolymer, AMPD-Acrylates / Diacetoneacrylamide Copolymer, AMP-Acrylates / Allyl Methacrylate Copolymer, AMP-Acrylates / C1-18 Alkyl Acrylates / C1-8 Alkyl Acrylamide Copolymer, AMP-Acrylates Copolymer, AMP-Acrylates / Diacetoneacrylamide Copolymer, AMP-Acrylates / Dimethylaminoethyl methacrylate copolymer, Astragalus Gummifer Gum, Avena Sativa (Oat) cores l Protein, Behenyl Methacrylate / Perfluorooctylethyl Methacrylate Copolymer, Benzoguanamine / Formaldehyde / Melamine Crosspolymer, Benzoic Acid / Phthalic Anhydride / Pentaerythritol / Neopentyl Glycol / Palmitic Acid Copolymer, Bis-Hydrogenated Tallow Amine Dilinoleic Acid / Ethylenediamine 15 Copolymer, Bis-PEG IPDI Copolymer, Bis-PPG-15 Dimethicone / IPDI Copolymer, Bis-Stearyl Dimethicone, Brassica Campestris / Aleurites Fordi Oil Copolymer, Butadiene / Acrylonitrile Copolymer, 1,4-Butanediol / Succinic Acid / Adipic Acid / HDI Copolymer, Butoxy Chitosan, Butyl Acrylate Crosspolymer, Butyl Acrylate / Ethylhexyl Methacrylate Copolymer, Butyl Acrylate / Hydroxyethyl Methacrylate Copolymer, Butyl Acrylate / Hydroxypropyl Dimethicone Acrylate Copolymer, Butyl Acrylate / Styrene Copolymer, Butylated Polyoxymethylene Urea, Butylated PVP, Butyl Benzoic Acid / Phthalic Anhydride / Trimethylolethane Copolymer, Ethylene / Propylene Copolymer, Butyl Ester of Ethylene / MA Copolymer, Bu tyl Ester of PVM / MA Copolymer, Butylethylpropanediol Dimer Dilinoleate, Butyl Methacrylate / DMAPA Acrylates / Vinylacetamide Crosspolymer, C23-43 Acid Pentaerythritol Tetraester, Calcium Carboxymethyl Cellulose, Calcium Carrageenan, Calcium Potassium Carbomer, Calcium / Sodium PVM / MA Copolymer, C5-6 Alkanes / Cycloalkanes / Terpenes Copolymer, C30-45 Alkyl Dimethicone / Polycyclohexene Oxide Crosspolymer, C1-5 Alkyl Galactomannan, Candelilla Wax Hydrocarbons, Carboxybutyl Chitosan, Carboxymethyl Chitosan, Carboxymethyl Chitosan Succinamide, Carboxymethyl Dextry, Carboxymethyl Carboxylym, Carboxymethyl Carboxylym, Carboxymethyl Carboxylym, Carboxymethyl Carboxylym, Carboxymethyl Cellulose Copolymer Acetate, Cellulose Acetate Butyrate, Cellulose Acetate Propionate, Cellulose Acetate Propionate Carboxylate, Cellulose Gum, Cetearyl Dimethicone / Vinyl Dimethicone Crosspolymer, Chitosan, Chitosan Adipate, Chitosan Ascorbate, Chitosan FORMATS, Chitosan Glycolate, Chitositanananananocanate , C5-6 olefin / C8-10 naphtha olefin Copolymer, Collodion, Copaifera Officinalis (Balsam Copaiba) Resin, Copal, Corn Starch / Acrylamide / Sodium Acrylate Copolymer, Corn Starch Modified, C6-14 Perfluoroalkylethyl Acrylate / HEMA Copolymer, DEA-Styrene / Acrylates / DVB Copolymer, Dibutylhexyl IPDI, Didecyltetradecyl IPDI , Diethylene Glycolamine / Epichlorohydrin / Piperazine Copolymer, Diethylhexyl IPDI, Diglycol / CHDM / Isophthalates / SIP Copolymer, Diglycol / Isophthalates / SIP Copolymer, Dihydroxyethyl Tallowamine / IPDI Copolymer, Dilinoleic Acid / Glycol Copolymer, Dilinoleic Acid / Sebacic Acid / Piperazine / Ethyleneediamine , Dilinoleyl Alcohol / IPDI Copolymer, Dimethicone PEG-8 Polyacrylate, Dimethicone / Vinyltrimethylsiloxysilicate Crosspolymer, Dimethiconol / IPDI Copolymer, Dimethylamine / Ethylenediamine / Epichlorohydrin Copolymer, Dioctyldecyl IPDI, Dioctyldodecyl IPDI, Di-Ether Adethane-Divide, Div-Ethyl Adyl-Divide, Div-Ethyl Adyl-Divide, Div-Ethyl Adyl-Divide, Div / Ethyl Adyl-Divide Divinyldimethicone / Dimethicone Crosspolymer, DMAPA Acrylates / Acrylic Acid / Acrylonitrogens Cop polymer, Dodecanedioic Acid / Cetearyl Alcohol / Glycol Copolymer, Ethyl Cellulose, Ethylene / Acrylic Acid Copolymer, Ethylene / Acrylic Acid / VA Copolymer, Ethylene / Calcium Acrylate Copolymer, Ethylene / MA Copolymer, Ethylene / Magnesium Acrylate Copolymer, Ethylene / Methacrylate Copolymer, Ethylene / Octene Copolymer, Ethylene / Propylene Copolymer, Ethylene / Sodium Acrylate Copolymer, Ethylene / VA Copolymer, Ethylene / Zinc Acrylate Copolymer, Ethyl Ester of PVM / MA Copolymer, Euphorbia Cerifera (Candelilla) Wax, Euphorbia Cerifera (Candelilla) Wax Extract, Fibroin / PEG-40 / Sodium Acrylate Copolymer, Flexible Collodion, Formaldehyde / Melamine / Tosylamide Copolymer, Galactoarabinan, Glycereth-7 Hydroxystearate / IPDI Copolymer, Glycerin / MA / Rosin Acid Copolymer, Glycerin / Phthalic Acid Copolymer, Glycerin / Phthalic Acid Copolymer Castorate, Glycerin / Succinic Acid Copolymer Castorate, Glyceryl Diricinoleate / IPDI Copolymer, Glyceryl Polyacrylate, Glyceryl Polymethacrylate, Glyceryl Undecyl Dimethicone, Glycidyl C8-11 Acidate / Glycerin / Phthalic Anhydride Copolymer, Glycol Rosinate, Gutta Percha, Hexylene Glycol / Neopentyl Glycol / Adipic Acid / SMDI / DMPA Copolymer, Hydrogenated Brassica Campestris / Aleurites Fordi Oil Copolymer, Hydrogenated Caprylyl Olive Esters, Hydrogenated Cetyl Olive Esters, Hydrogenated Decyl Olive Esters, Hydrogenated Hexyl Olive Esters, Hydrogenated Lauryl Olive Esters, Hydrogenated Myristyl Olive Esters, Hydrogenated Rosin, Hydrogenated Styrene / Butadiene Copolymer, Hydrolyzed Candelilla Wax, Hydrolyzed Carnauba Wax, Hydrolyzed Chitosan, Hydrolyzed Gadidae Protein, Hydrolyzed Jojoba Esters, Hydrolyzed Sunflower Seed Hydrolyzed Wheat Protein, Hydrolyzed Wheat Protein / Cystine Bis-PG-Propyl Silanetriol Copolymer, Hydrolyzed Wheat Protein / Dimethicone PEG-7 Acetate, Hydrolyzed Wheat Protein / Dimethicone PEG-7 Phosphate Copolymer, Hydrolyzed Wheat Protein / PVP Crosspolymer, Hydroxybutyl Methylcellulose, Hydroxyethylcellulose, Hydroxyethyl chitosan, hydroxyethyl ethyl cellulose, hydrox yethyl / methoxyethyl acrylate / butyl acrylate copolymer, hydroxyethyl / methoxyethyl acrylate copolymer, hydroxypropyl cellulose, hydroxypropyl chitosan, hydroxypropyl guar, hydroxypropyl methyl cellulose, hydroxypropyl methyl cellulose acetate / succinate, hydroxypropyl oxidized starch, hydroxypropyl trimonium hyaluronate, hydroxypropyl isobutylimide / copolymer, Isobutylene / MA Copolymer, Isobutylene / Sodium Maleate Copolymer, Isobutyl Methacrylate / Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isomerized Linoleic Acid, Isophorone Diamine / Cyclohexylamine / Isophthalic Acid / Azelaic Acid Copolymer, Isophoronediamine / Isophthalic Acid / Isoophophthalic Acid / Pentaeryophorone Diamine Trimethylolpropane copolymer, isopropyl ester of PVM / MA copolymer, 4,4'-isopropylidenediphenol / epichlorohydrin copolymer, lauryl acrylate / VA copolymer, lauryl methacrylate / glycol dimethacrylate crosspolymer, maltodextrin, Mannan, Melia Azadirachta Conditioned Me dia / Culture, Methacrylic Acid / Sodium Acrylamidomethyl Propane Sulfonate Copolymer, Methacryloyl Ethyl Betaine / Acrylates Copolymer, Methacryloyl Propyltrimethoxysilane, Methoxypolyoxymethylene Melamine, Methyl Ethyl Cellulose, Methyl Methacrylate / Acrylonitrile Copolymer, Methyl Methacrylate Crosspolymer, Methyl Methacrylate / Glycol Dimethacrylate, Glycol Dimethacrylate (Glycol Dimberry Acrylate) ) Fruit Wax, Myroxylon Balsamum (Balsam Tolu) Resin, Myroxylon Pereirae (Balsam Peru) Resin, Nitrocellulose, Nylon-12/6/66 Copolymer, Octadecene / MA Copolymer, Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer, Oxymethylene / Melamine Copolymer, Palmitic Acid / Pentaerythritol / Stearic Acid / Terephthalic Acid Copolymer, PEG-150 / Decyl Alcohol / SMDI Copolymer, PEG-7 Dimethicone, PEG / PPG-25/25 Dimethicone / Acrylates Copolymer, PEG-150 / Stearyl Alcohol / SMDI Copolymer, Pentaerythritol / Terephthalic Acid Copolymer, Pentaerythrityl Cyclohexane Dicarboxylate, Perfluorononylethyl Stearyl Dimethicone, Phenylpropyl dimethylsiloxysilicate, Phthalic Acid Denatured With Epoxy Resin Alkyd Resin, Phthalic Anhydride / Adipic Acid / Castor Oil / Neopentyl Glycol / PEG-3 / Trimethylolpropane Copoly mer, Phthalic Anhydride / Benzoic Acid / Glycerin Copolymer, Phthalic Anhydride / Benzoic Acid / Trimethylolpropane Copolymer, Phthalic Anhydride / Butyl Benzoic Acid / Propylene Glycol Copolymer, Phthalic Anhydride / Glycerin / Glycidyl Decanoate Copolymer, Phthalic Anhydride / Trimellsitic Anhydride / Glylene / Butene / Pentene Copolymer, Piperylene / Butene / Pentene / Pentadiene Copolymer, Pistacia Lentiscus (Mastic) Gum, Polianthes Tuberosa Extract, Polyacrylamide, Polyacrylamidomethylpropane Sulfonic Acid, Polyacrylate-1, Polyacrylate-2, Polyacrylate-5, Polyacrylate-6, Polyacrylic Acid , Polyamide-1, Polybeta-Alanine, Polybeta-Alanine / Glutaric Acid Crosspolymer, Polybutyl Acrylate, Polybutylene Terephthalate, Polychlorotrifluoroethylene, Polydiethyleneglycol Adipate / IPDI Copolymer, Polydimethylaminoethyl Methacrylate, Polyester-1, Polyester-2, Polyester-3, Polyethylacrylate Polyethylene naphthalates, polyethylene terephthalates, polyethyl glutamates, polyethyl methacrylates, polyg lucuronic acid, polyglyceryl-2 diisostearate / IPDI copolymer, polyisobutenes, polylysines, polymethacrylamides, polymethacrylamidopropyltrimonium methosulphates, polymethacrylic acid, polymethyl acrylates, polymethylglutamates, polymethyl methacrylates, polyoxyisobutylenes, polymethyl urethane peroxide, methylene urethyperoxy melamine, methylene urethyperoxy melamine, methylene urethyperoxy melamine, methylene urethyperoxy melamine, methylene urethyperoxy melamine, methoxy urethane melamine, methylene methylene melamine, methoxy urethane peroxy methylene melamine -Phenylene terephthalamide, polyphosphorylcholine glycol acrylate, polyquaternium-1, polyquaternium-2, polyquaternium-4, polyquaternium-5, polyquaternium-6, polyquaternium-7, polyquaternium-8, polyquaternium-9, polyquaternium-11, polyquaternium 12, Polyquaternium-13, Polyquaternium-14, Polyquaternium-15, Polyquaternium-16, Polyquaternium-17, Polyquaternium-18, Polyquaternium-19, Polyquaternium-20, Polyquaternium-22, Polyquaternium-24, Polyquaternium-27, Polyquaternium-28 Polyquaternium-29, Polyquaternium-30, Polyquaternium-31, Polyquaternium-32, Polyquaternium-33, Pol yquaternium-34, Polyquaternium-35, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-43, Polyquaternium-44, Polyquaternium-45, Polyquaternium-46, Polyquaternium-47, Polyquaternium-48, Polyquaternium-49, 50, Polyquaternium-51, Polyquaternium-56, Polyquaternium-57, Polyquaternium-61, Polysilicone-6, Polysilicone-8, Polysilicone-11, Polysilicone-14, Polystyrene, Polyurethane-1, Polyurethane-2, Polyurethane-4, Polyurethane- 5, Polyurethane-6, Polyurethane-7, Polyurethane-8, Polyurethane-10, Polyurethane-11, Polyurethane-12, Polyurethane-13, Polyvinylacetal Diethylaminoacetate, Polyvinyl Acetate, Polyvinyl Alcohol, Polyvinyl Butyral, Polyvinylcaprolactam, Polyvinyl Chloride, Polyvinyl Imidazolinium Acetate , Polyvinyl Isobutyl Ether, Polyvinyl Laurate, Polyvinyl Methyl Ether, Polyvinyl Stearyl Ether, Potassium Acrylates / Acrylamide Copolymer, Potassium Acrylates / C10-30 Alkyl Acrylate Crosspolymer, Potassium Acrylates / Ethylhexyl Acrylate Copolymer, Potassium Butyl Ester of PVM / MA Copolymer, Potassium Carbomer, Potassium Carrageenan, Potassium Ethyl Ester of PVM / MA Copolymer, PPG-26 / HDI Copolymer, PPG-17 / IPDI / DMPA Copolymer, PPG-12 / SMDI Copolymer, PPG-7 / Succinic Acid Copolymer, PPG-26 / TDI Copolymer, PPG-10 Tocophereth-30, PPG-20 Tocophereth-50, Propylene Glycol Diricinoleate / IPDI Copolymer, Pseudotsuga Menziesii (Balsam Oregon) Resin, Pullulan, PVM / MA Copolymer, PVM / MA Decadiene Crosspolymer, PVP, PVP Montmorillonite, PVP / VA / Itaconic Acid Copolymer, PVP / VA / Vinyl Propionate Copolymer, Quaternium-22, Rhizobian Gum, Rosin, Rubber Latex, Serum Albumin, Shellac, Sodium Acrylates / Acrolein Copolymer, Sodium Acrylates / Acrylonitrogens Copolymer, Sodium Acrylates / C10-30 Alkyl Acrylates Crosspolymer, Sodium Acrylates Copolymer, Sodium Acrylate / Vinyl Alcohol Copolymer, Sodium Butyl Ester of PVM / MA Copolymer, Sodium Carbomer, Sodium Carboxymethyl Chitin, Sodium Carboxymethyl Starch, Sodium Carrageenan, Sodium C4- 12 Olefin / Maleic Acid Copolymer, Sodium DVB / Acrylates Copolymer, Sodium Ethyl Ester of PVM / MA Copolymer, Sodium Isooctylene / MA Copolymer, Sodium MA / Diisobutylene Copolymer, Sodium MA / Vinyl Alcohol Copolymer, Sodium PG-Propyldimethicone Thiosulfate Copolymer, Sodium Polyacrylate, Sodium Polymethacrylate, Sodium Polystyrene Sulfonate, Sodium PVM / MA / Decadiene Crosspolymer, Sodium Styrene / Acrylates Copolymer, Sodium Tauride Acrylates / Acrylic Acid / Acrylonitrogens Copolymer, Starch / Acrylates / Acrylamide Copolymer, Starch Diethylaminoethyl Ether, Stearamidopropyl Dimethicone, Steareth-10 Alkyl Ether / Acrylates Copolymer, Stearoyl Epoxy Resin , Stearyl HDI / PEG-50 copolymer, stearyl methacrylate / perfluorooctylethyl methacrylate copolymer, stearyl vinyl ether / MA copolymer, styrax benzoin gum, styrene / acrylates / acrylonitrile copolymer, styrene / acrylates / ammonium methacrylate copolymer, styrene / acrylates copolymer, styrene / allyl benzoates Copolymer, styrene / DVB crosspolymer, styrene / isoprene copolymer, styrene / MA copolymer, styrene / methacrylic amide / Acrylates Copolymer, Styrene / Methylstyrene / Idene Copolymer, Styrene / VA Copolymer, Styrene / VP Copolymer, Sucrose Benzoate / Sucrose Acetate Isobutyrate / Butyl Benzyl Phthalate Copolymer, Sucrose Benzoate / Sucrose Acetate Isobutyrate / Butyl Benzyl Phthalate / Methyl Methacrylate Copolymer, Sucrose Benzoate / Sucrose Acetate Isobutyrate Copolymer, TEA-Acrylates / Acrylonitrogens Copolymer, TEA-Diricinoleate, TEA-Diricinoleate / IPDI Copolymer, Terephthalic Acid / Isophthalic Acid / Sodium Isophthalic Acid Sulfonate / Glycol Copolymer, Tetradecyloctadecyladateylateateate, Titanate , Tosylamide / Epoxy Resin, Tosylamide / Formaldehyde Resin, Tricontanyl PVP, Triethylene Glycol Rosinate, Trimethylol Propane Cyclohexene Dicarboxylate, Trimethylolpropane Triacrylate, Trimethylpentanediol / Isophthalic Acid / Trimellitic Anhydride Copolymer, Trimethylsiloxy-Soloxyl-Siloxyl-Silicamyl-Glyoxyl-Silicyl-Dimethylsiloxyl-Silicyl-Triloyl-Glyoxyl-Silicate-Triloyl-Silicon-Glycol-Glycol-Triloyl-Silicon-Glycol-Silicon-Glycol-Silicon-Glycol-Silicate heat) Protein, Tromethamine Acrylates / Acrylonitrogens Copolymer, VA / Butyl Maleate / Isobornyl Acrylate Copolymer, VA / Crotonates Copolymer, VA / Crotonates / Me thacryloxybenzophenone-1 copolymer, VA / Crotonates / Vinyl Neodecanoate Copolymer, VA / Crotonates / Vinyl Propionate Copolymer, VA / Crotonic Acid / PEG-20M Copolymer, VA / DBM Copolymer, VA / Isobutyl Maleate / Vinyl Neodecanoate Copolymer, VA / Vinyl Butyl Benzoate / Crotonates Copolymer, VA / Vinyl Chloride Copolymer, Vinyl Acetate, Vinylamine / Vinyl Alcohol Copolymer, Vinyl Caprolactam / VP / Dimethylaminoethyl Methacrylate Copolymer, Vinyl Chloride / Vinyl Laurate Copolymer, VP / Dimethiconylacrylate / Polycarbamyl / Polyglycol Ester, VP / Dimethylaminoethylmethacrylate Copolymer, VP / Dimethylaminoethyl methacrylate / Polycarbamyl Polyglycol Ester, VP / Eicosene Copolymer, VP / Hexadecene Copolymer, VP / Polycarbamyl Polyglycol Ester, VP / VA Copolymer, Welan Gum, Yeast Beta-Glucan, Yeast Polysaccharides, Zein.

polymers which fix the hair, the so-called setting polymers, contribute to the hold and / or build up of the hair volume, the fullness of the Overall hairstyle at. Film-forming polymers and gums are therefore general typical substances for hair treatment agents such as hair fixers, hair foams, hair waxes, Hairsprays. Substances that keep the hair hydrophobic lend are preferred here because they have the tendency of hair Reduce moisture, i.e. absorb water. This will the limp hanging down of strands of hair is reduced and thus a long-lasting hair style build-up and maintenance guaranteed. As a test method for this becomes common the so-called curl retention test applied. These polymeric substances can continue to be successful incorporated in leave-on and rinse-off hair treatments or shampoos become.

Examples of common setting polymers are acrylamides / ammonium acrylate copolymers, acrylamides / DMAPA acrylates / methoxy PEG methacrylate copolymers, acrylamidopropyltrimonium chlorides / acrylamides copolymers, acrylamidopropyltrimonium chlorides / acrylates copolymers, acrylates / acetoacetoxyethyl methacrylates copolymers, acrylates / acrylamides copolymers, acrylates / ammonium methacrylates copolymers , Acrylates / t-Butylacrylamide Copolymer, Acrylates Copolymer, Acrylates / C1-2 Succinates / Hydroxyacrylates Copolymer, Acrylates / Lauryl Acrylate / Stearyl Acrylate / Ethylamine Oxide Methacrylate Copolymer, Acrylates / Octylacrylamide Copolymer, Acrylates / Octylacrylamide / Diphenyl Amodimethicone Copolymer, Acrylates / Stearyl Acrylate / Ethylamine Oxide Methacrylate Copolymer, Acrylates / VA Copolymer, Acrylates / VP Copolymer, Adipic Acid / Diethylenetriamine Copolymer, Adipic Acid / Dimethylaminohydroxypropyl Diethylenetriamine Copolymer, Adipic Acid / Epoxypropyl Diethylenetriamine Copolymer, Adipic Acid / Isophthalic A cid / Neopentyl Glycol / Trimethylolpropane Copolymer, Allyl Stearate / VA Copolymer, Aminoethylacrylate Phosphate / Acrylates Copolymer, Aminoethylpropanediol-Acrylates / Acrylamide Copolymer, Aminoethylpropanediol-AMPD-Acrylates / Diacetoneacrylamide Copolymer, Ammonium VA / Acrylates Copolymer, AMPD-Acrylcrylamide / Diac -Acrylates / Allyl Methacrylate Copolymer, AMP-Acrylates / C1-18 Alkyl Acrylates / C1-8 Alkyl Acrylamide Copolymer, AMP-Acrylates / Diacetoneacrylamide Copolymer, AMP-Acrylates / Dimethylaminoethylmethacrylate Copolymer, Bacillus / Rice Bran Extract / Soybean Extract Ferment Filtrate, Bis -Butyloxyamodimethicone / PEG-60 Copolymer, Butyl Acrylate / Ethylhexyl Methacrylate Copolymer, Butyl Acrylate / Hydroxypropyl Dimethicone Acrylate Copolymer, Butylated PVP, Butyl Ester of Ethylene / MA Copolymer, Butyl Ester of PVM / MA Copolymer, Calcium / Sodium PVM / MA Copolymer, Corn Starch / Acrylamide / Sodium Acrylate Copolymer, Diethylene Glycolamine / Epichlorohydrin / Piperazine Copolymer, Dimethic one cross polymer, diphenyl amodimethicone, ethyl ester of PVM / MA copolymer, hydrolyzed wheat protein / PVP cross polymer, isobutylene / ethyl maleimide / hydroxyethyl maleimide copolymer, isobutylene / MA copolymer, isobutyl methacrylate / bis-hydroxypropyl dimethicone acrylate copolymer, isopropyl ester of PVM / MA copolymer, Lauryl Acrylate Crosspolymer, Lauryl Methacrylate / Glycol Dimethacrylate Crosspolymer, MEA-Sulfite, Methacrylic Acid / Sodium Acrylamidomethyl Propane Sulfonate Copolymer, Methacryloyl Ethyl Betaine / Acrylates Copolymer, Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer, PEG / PPG-25/25 Dimethicone / Acryl , PEG-8 / SMDI copolymer, polyacrylamide, polyacrylate-6, polybeta-alanine / glutaric acid crosspolymer, polybutylene terephthalate, polyester-1, polyethylacrylate, polyethylene terephthalate, polymethacryloyl ethyl betaine, polypentaerythrityl terephthalate, polyperfluorene-1-polyhydrogenated, , Polyquaternium-4, Polyquaternium -5, Polyquaternium-6, Polyquaternium-7, Polyquaternium-8, Polyquaternium-9, Polyquaternium-10, Polyquaternium-11, Polyquaternium-12, Polyquaternium-13, Polyquaternium-14, Polyquaternium-15, Polyquaternium-16, Polyquaternium-17 , Polyquaternium-18, Polyquaternium-19, Polyquaternium-20, Polyquaternium-22, Polyquaternium-24, Polyquaternium-27, Polyquaternium-28, Polyquaternium-29, Polyquaternium-30, Polyquaternium-31, Polyquaternium-32, Polyquaternium-33 -34, Polyquaternium-35, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-45, Polyquaternium-46, Polyquaternium-47, Polyquaternium-48, Polyquaternium-49, Polyquaternium-50, Polyquaternium-55, Polyquaternium 56 , Polysilicone-9, Polyurethane-1, Polyurethane-6, Polyurethane-10, Polyvinyl Acetate, Polyvinyl Butyral, Polyvinylcaprolactam, Polyvinylformamide, Polyvinyl Imidazolinium Acetate, Polyvinyl Methyl Ether, Potassium Butyl Ester of PVM / MA Copolymer, Potassium Ethyl Ester of PVM / MA copolymer, PPG-70 Po lyglyceryl-10 ether, PPG-12 / SMDI copolymer, PPG-51 / SMDI copolymer, PPG-10 sorbitol, PVM / MA copolymer, PVP, PVP / VA / Itaconic Acid Copolymer, PVP / VA / Vinyl Propionate Copolymer, Rhizobian Gum, Rosin Acrylate, Shellac, Sodium Butyl Ester of PVM / MA Copolymer, Sodium Ethyl Ester of PVM / MA Copolymer, Sodium Polyacrylate, Sterculia Urens Gum, Terephthalic Acid / Isophthalic Acid / Sodium Isophthalic Acid Sulfonate / Glycol Copolymer, Trimethylolpropane Triacrylate, Trimethylsiloxysilylcarbamoyl Pullulan, VA / Crotonates Copolymer, VA / Crotonates / Methacryloxybenzophenone-1 Copolymer, VA / Crotonates / Vinyl Neodecanoate Copolymer, VA / Crotonates Copolymer, VA / Crotonates Copolymer, VA / Crotonates Copolymer, VA / Crotonates Copolymer, VA / Crotonates / DBM copolymer, VA / vinyl butyl benzoate / crotonates copolymer, vinylamine / vinyl alcohol copolymer, vinyl caprolactam / VP / dimethylaminoethyl methacrylate copolymer, VP / acrylates / lauryl methacrylate copolymer, VP / dimethylaminoethyl methacrylate copolymer, VP / DMAPA acrylates copolymer, VP / hexadecenes Copolymer, VP / VA Copolymer, VP / Vinyl Caprolactam / DMAPA Acrylates Copolymer, Yeast Palmitate.

Of course, count too the emulsion-stabilizing polymers to the preferred according to the invention Polymers. These are understood to mean polymers, which are the structure and the stabilization of emulsions (O / W and W / O as well as multiple Emulsions). Surfactants and emulsifiers are of course the essential components, however, the stabilizing polymers carry through a positive Influencing the continuous or the disperse phase to one Reduce the coalescence of the emulsified droplets. This positive Influencing can be due to an electrical repulsion, an increase in the viscosity or film formation on the droplet surface.

Examples of such polymers are acrylamide / sodium acryloyldimethyltaurate copolymer, acrylates / aminoacrylates / C10-30 alkyl PEG-20 itaconate copolymer, acrylates / C10-30 alkyl acrylate crosspolymer, acrylates / stearyl methacrylate copolymer, acrylates / vinyl isodecanoate crosspolymer, alcaligenes polysaccharides, allyl Methacrylates Crosspolymer, Ammonium Acryloyldimethyltaurate / Beheneth-25 Methacrylate Crosspolymer, Ammonium Acryloyldimethyltaurate / Vinyl Formamide Copolymer, Ammonium Alginate, Ammonium Phosphatidyl Rapeseedate, Ammonium Polyacrylate, Ammonium Polyacryloyldimethyl Taurate, Ammonium Shellacate, Arachidyl Alcohol, Bentonethyl Methyloxoxum, Astragalus cellulose rubber , Calcium Carrageenan, Calcium Potassium Carbomer, Calcium Starch Octenylsuccinate, C1-5 Alkyl Galactomannan, C18-38 Alkyl Hydroxystearoyl Stearate, Carbomer, Carboxymethyl Hydroxyethylcellulose, Carboxymethyl Hydroxypropyl Guar, Cellulose Acetate Propionate Carboxylate, Cellulose Gu m, Ceratonia Siliqua Gum, Cetyl Hydroxyethylcellulose, Chitosan Lauroyl Glycinate, Cholesterol, Cholesterol / HDI / Pullulan Copolymer, Corn Starch / Acrylamide / Sodium Acrylate Copolymer, C12-14 Sec-Pareth-3, C12-14 Sec-Pareth-5, C12 -14 Sec-Pareth-7, C12-14 Sec-Pareth-8, C12-14 Sec-Pareth-9, C12-14 Sec-Pareth-12, C12-14 Sec-Pareth-15, C12-14 Sec-Pareth -20, C12-14 Sec-Pareth-30, C12-14 Sec-Pareth-40, C12-14 Sec-Pareth-50, Cyamopsis Tetragonoloba (Guar) Gum, Dimethicone Crosspolymer, Dimethicone Crosspolymer-2, Dimethicone Ethoxy Glucoside, Euphorbia Cerifera (Candelilla) Wax, Gellan Gum, Hydrolyzed Beeswax, Hydrolyzed Candelilla Wax, Hydrolyzed Carnauba Wax, Hydrolyzed Collagen PG-Propyl Dimethiconol, Hydrolyzed Sunflower Seed Wax, Hydroxyeutyl Methylcellulose, Hydroxyethyl Acrylate / Sodium Acryloyldimethyl Taurate Copolymer, Hydroxyethylethylcellulose, Hydroxyethylethylcellulose Isopropanolamine, hydroxypropyl cellulose, hydroxypropyl cyclodextrin, hydroxypropyl guar, H. ydroxypropyl methyl cellulose, hydroxypropyl xanthan gum, isopropyl ester of PVM / MA copolymer, lanolin, lanolin alcohol, magnesium alginate, maltodextrin, methoxy PEG-17 / dodecyl glycol copolymer, methoxy PEG-22 / dodecyl glycol copolymer, methyl cellulose, methyl hydroxyethyl cellulose, microcrystalline cell , Microcrystalline Wax, Montmorillonite, Moroccan Lava Clay, Myrica Cerifera (Bayberry) Fruit Wax, Octadecene / MA Copolymer, Oleic / Linoleic / Linolenic Polyglycerides, Ozokerite, Pectin, PEG-350, PEG-400, PEG-500, PEG-12 Carnauba , PEG-12 Dimethicone Crosspolymer, PEG-22 / Dodecyl Glycol Copolymer, PEG-45 / Dodecyl Glycol Copolymer, PEG-6 Hydrogenated Palmamide, PEG-100 / IPDI Copolymer, PEG-2M, PEG-5M, PEG-7M, PEG- 9M, PEG-14M, PEG-20M, PEG-23M, PEG-25M, PEG-45M, PEG-65M, PEG-90M, PEG-115M, PEG-160M, PEG / PPG-20/23 Dimethicone, PEG / PPG -23/6 Dimethicone, PEG / PPG-8/3 Laurate, PEG / PPG-10/3 Oleyl Ether Dimethicone, Polyacrylic Acid, Polyethylene, Polyethylene / Isopropyl Maleate / MA Copolyol, Polygly ceryl-2 Diisostearate / IPDI Copolymer, Polypropylene Terephthalate, Polysilicone-16, Polyvinyl Acetate, Potassium Alginate, Potassium Carbomer, Potassium Carrageenan, Potassium Dextrin Octenylsuccinate, Potassium Polyacrylate, Potassium Undecylenoyl Alginate, Potassium Undecylenoyl Undecoyloyl undoyloyl undoyloylll undageyloyl, Potassium Hydrolyzed Soy Protein, Potassium Undecylenoyl Hydrolyzed Wheat Protein, PPG-3 C12-14 Sec-Pareth-7, PPG-4 C12-14 Sec-Pareth-5, PPG-5 C12-14 Sec-Pareth-7, PPG-5 C12 -14 Sec-Pareth-9, PPG-2 Tocophereth-5, PPG-5 Tocophereth-2, PPG-10 Tocophereth-30, PPG-20 Tocophereth-50, PVM / MA Copolymer, PVP, PVP / Decene Copolymer, PVP Montmorillonite , Pyrus Malus (Apple) Fiber, Saccharated Lime, Sclerotium Gum, Sodium Acrylate / Acryloyldimethyl Taurate Copolymer, Sodium Acrylates / Vinyl Isodecanoate Crosspolymer, Sodium Acrylate / Vinyl Alcohol Copolymer, Sodium Carbomer, Sodium Carboxymethyl Dextran, Sodium Carboxymethyl Starch, Sodium Carrageenan, Sodium Cellulose Sulfate, Sodium C4-12 Olefin / Maleic Acid Copolymer, Sodium Cyclodextrin Sulfate, Sodium Dextrin Octenylsuccinate, Sodium Polyacrylate, Sodium Polyacrylate Starch, Sodium Polyacryloyldimethyl Taurate, Sodium Polymethacrylate, Sodium Polynaphthalenesulfonate, Sodium Polystyrene Sulfonate, Sodium Starch Octenylsuccinate, Sodium / TEA-Undecylenoyloylate-Aloylate-Starocelloyl-Alocanoyl-Aloylate-Alginate-Aloyl-Al-Staro Hydroxypropyltrimonium Chloride, Stearylvinyl Ether / MA Copolymer, Sterculia Urens Gum, Styrene / MA Copolymer, Sucrose Polypalmate, Synthetic Beeswax, Synthetic Wax, Tamarindus Indica Seed Gum, TEA-Alginate, TEA-Dextrin Octenylsuccinate, Undecylenoyl Inulin, Gechanumum, Xec , Xanthan Gum, Zinc Undecylenoyl Hydrolyzed Wheat Protein.

Polymers can increase the viscosity of aqueous and non-aqueous phases in cosmetic preparations. In aqueous phases, their viscosity-increasing function is based on their solubility in water or their hydrophilic nature. They are used in both surfactant and emulsion systems. Some examples of typical polymeric thickeners for aqueous systems are listed below:
Acrylamide / Copolymer, Acrylamide / Sodium Acrylate Copolymer, Acrylamide / Sodium Acryloyldimethyltaurate Copolymer, Acrylates / Acetoacetoxyethyl Methacrylate Copolymer, Acrylates / Beheneth-25 Methacrylate Copolymer, Acrylates / C10-30 Alkyl Acrylate Crosspolymer, Acrylates / Ceteth-20 Itaconate Copolymer, Acrylates / Ceteth- 20 methacrylate copolymer, acrylates / laureth-25 methacrylate copolymer, acrylates / palmeth-25 acrylate copolymer, acrylates / palmeth-25 itaconate copolymer, acrylates / steareth-50 acrylate copolymer, acrylates / steareth-20 itaconate copolymer, acrylates / steareth-20 methacrylate Copolymer, Acrylates / Stearyl Methacrylate Copolymer, Acrylates / Vinyl Isodecanoate Crosspolymer, Acrylic Acid / Acrylonitrogens Copolymer, Agar, Agarose, Alcaligenes Polysaccharides, Algin, Alginic Acid, Ammonium Acrylates / Acrylonitrogens Copolymer, Ammonium Acrylates Copolymer, Ammonium Acryloyldimethyltaurate / Vinyl Formamide Copolymer Acryloyldimethyltaurate / VP copolymer, ammonium alginate, ammoni um Polyacryloyldimethyl Taurate, Amylopectin, Ascorbyl Methylsilanol Pectinate, Astragalus Gummifer Gum, Attapulgite, Avena Sativa (Oat) Kernel Flour, Bentonite, Butoxy Chitosan, Caesalpinia Spinosa Gum, Calcium Alginate, Calcium Carboxymethyl Cellulose, Calcium Carrageenomeran, Calcium Potage Carrageenomer, Calcium Potchomethane, Calcium Potassium Carrageenomer, Calcium Potage Carrageenomer, Calcium Potchomate Carbohydrate , C20-40 Alkyl Stearate, Carbomer, Carboxybutyl Chitosan, Carboxymethyl Chitin, Carboxymethyl Chitosan, Carboxymethyl Dextran, Carboxymethyl Hydroxyethylcellulose, Carboxymethyl Hydroxypropyl Guar, Cellulose Acetate Propionate Carboxylate, Cellulose Gum, Ceratonia Siliqua Hydroxy / Copolymer, HDI / Cellulose Cholesterol, Cellulose Cholesterol / Cellulose Cholesterol / Cellulose Cholesterol, Cellulose Cholesterol / Cellulose Cholesterol, Cellulose Gum, Cellulose Cholesterol Cholesteryl Hexyl Dicarbamate Pullulan, Cyamopsis Tetragonoloba (Guar) Gum, Diglyco / CHDM / Isophthalates / SIP Copolymer, Dihydrogenated Tallow Benzylmonium Hectorite, Dimethicone Crosspolymer-2, Dimethicone Propyl PG-Betaine, DMAPA Acrylates / Acrylic Acid / Acrylonitrogen Sodium Copolymer Copolymer, gelatin , Gellan Gum, Glyceryl Alginate, Glycine Soybean (Soybean) Flour, Guar Hydroxypropyltrimonium Chloride, Hectorite, Hydrated Silica, Hydrogenated Potato Starch, Hydroxybutyl Methylcellulose, Hydroxyethyl Acrylate / Sodium Acryloyldimethyl Taurate Copolymer, Hydroxyethylcellulose, Hydroxyethyl Hydroxychylylulose, Hydroxyethyl Chitosyl cellulose , Hydroxypropyl ethylenediamine carbomer, hydroxypropyl guar, hydroxypropyl methyl cellulose, hydroxypropyl methyl cellulose stearoxy ether, hydroxypropyl starch, hydroxypropyl starch phosphate, hydroxypropyl xanthan gum, hydroxystearamide MEA, isobutylene / sodium maleate copolymer, lithium magnesium silicate, lithium magnesium sodium silicate, macrocystis pyrifera , Magnesium Alginate, Magnesium Aluminum Silicate, Magnesium Silicate, Magnesium Trisilicate, Methoxy PEG-22 / Dodecyl Glycol Copolymer, Methylcellulose, Methyl Ethylcellulose, Methyl Hydroxyethylcellulose, Microcrystalline Cellulose, Montmorillonite, Morocc on Lava Clay, Natto Gum, Nonoxynyl Hydroxyethylcellulose, Octadecene / MA Copolymer, Pectin, PEG-800, PEG-Crosspolymer, PEG-150 / Decyl Alcoho / SMDI Copolymer, PEG-175 Diisostearate, PEG-190 Distearate, PEG-15 Glyceryl Tristearate , PEG-140 Glyceryl Tristearate, PEG-240 / HDI Copolymer Bis-Decyltetradeceth-20 Ether, PEG-100 / IPDI Copolymer, PEG-180 / Laureth-50 / TMMG Copolymer, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-2M, PEG-5M, PEG-7M, PEG-9M, PEG-14M, PEG-20M, PEG-23M, PEG-25M, PEG-45M, PEG-65M, PEG-90M, PEG- 115M, PEG-160M, PEG-120 methyl glucose trioleate, PEG-180 / octoxynol-40 / TMMG copolymer, PEG-150 pentaerythrityl tetrastearate, PEG-4 rapeseedamide, PEG-150 / stearyl alcohol / SMDI copolymer, polyacrylate-3, polyacrylic Acid, Polycyclopentadiene, Polyether-1, Polyethylene / Isopropyl Maleate / MA Copolyol, Polymethacrylic Acid, Polyquaternium-52, Polyvinyl Alcohol, Potassium Alginate, Potassium Aluminum Polyacrylate, Potassium Carbomer, Potassium Carrageenan an, Potassium Polyacrylate, Potato Starch Modified, PPG-14 Laureth-60 Hexyl Dicarbamate, PPG-14 Laureth-60 Isophoryl Dicarbamate, PPG-14 Palmeth-60 Hexyl Dicarbamate, Propylene Glycol Alginate, PVP / Decene Copolymer, PVP Montmorillonite, Rhizobian Gum , Ricinoleic Acid / Adipic Acid / AEEA Copolymer, Sclerotium Gum, Sodium Acrylate / Acryloyldimethyl Taurate Copolymer, Sodium Acrylates / Acrolein Copolymer, Sodium Acrylates / Acrylonitrogens Copolymer, Sodium Acrylates Copolymer, Sodium Acrylates / Vinyl Isodecanoate Crosspolymer, Sodium Acrylate / Vinyl Alcohol Copolymer, Sodium carbomer, sodium carboxymethyl chitin, sodium carboxymethyl dextran, sodium carboxymethyl beta-glucan, sodium carboxymethyl starch, sodium carrageenan, sodium cellulose sulfates, sodium cyclodextrin sulfates, Sodium Hydroxypropyl Starch Phosphate, Sodium Isooctylene / MA Copolymer, Sodium Magnesium Fluorosilicate, Sodium Polyacrylate, Sodium Polyacrylate Starch, Sodium Polyacryloyldimethyl Taurate, Sodium Polymethacrylate, Sodium Polystyrene Sulfonate, Sodium Silicoaluminate, Sodium Starch Octenylsuccinate / Sodium Styroxycellulose Acrylates Copolymer, Sodium Tauride Acrylates / Acrylic Acid / Acrylonitrogens Copolymer, Solanum Tuberosum (Potato) Starch, Starch / Acrylates / Acrylamide Copolymer, Starch Hydroxypropyltrimonium Chloride, Steareth-60 Cetyl Ether, Steareth-100 / PEG-136 / HDI Copolymer, Sterculia Urens Gum, Synthetic Fluorophlogopite, Tamarindus Indica Seed Gum, Tapioca Starch, TEA-Alginate, TEA-Carbomer, Triticum Vulgare (Wheat) Starch, Tromethamine Acrylates / Acrylonitrogens Copolymer, Tromethamine Magnesium Aluminum Silicate, Welan Gum, Xanthan Gum, Yeast Beta-Glucan, Yeast Polysaccharides, Zea Mays (Corn) Starch.

Another way to increase the viscosity of cosmetic products is to thicken the non-aqueous phase, the lipid phase of the cosmetic products. For this purpose, polymers are used which are not water-soluble but compatible with lipids. They are also used for the gel formation of cosmetic products with a high lipid content. Some of these polymers are listed below: Acrylates / C10-30 Alkyl Acrylate Crosspolymer, Adipic Acid / PPG-10 Copolymer, Alkyl Methacrylates Crosspolymer, Alumina Magnesium Metasilicate, Aluminum Starch Octenylsuccinate, Beeswax, Behenyl Methacrylate / Perfluorooctylethyl Methacrylate Copolymer, Bispolyethylene Dimethicone, Butadienes / Acrylonitrile Copolymer, Butylene / Ethylene Copolymer, Butylene / Ethylene / Styrene Copolymer, Butylene Glycol Montanate, Butyrospermum Parkii (Shea Butter), C29-70 Acid, C23-43 Acid Pentaerythritol Tetraester, C20-24 Alkyl Dimethicone, C24-28 Alkyl Dimethicone , C1-5 alkyl galactomannan, C18-38 alkyl hydroxystearoyl stearate, C20-24 alkyl methicone, C24-28 alkyl methicone, C30-45 alkyl methicone, candelilla wax hydrocarbons, C10-30 cholesterol / lanosterol esters, cellobiose octanonanoate, ceresin, cerotic Acid, Cetearyl Dimethicone / Vinyl Dimethicone Crosspolymer, Chlorinated Paraffin, Cholesterol, Cholesteryl Acetate, Cholesteryl Hydroxystearate, Chole steryl isostearate, cholesteryl macadamiate, cholesteryl stearate, C10-40 hydroxyalkyl acid cholesterol ester, C10-40 isoalkyl acid cholesterol ester, C10-40 isoalkyl acid octyldodecanol ester, C10-40 isoalkyl acid phytosterol ester, C10-40 isoalkyl acid30 triglyceride 38 Olefin / Isopropyl Maleate / MA Copolymer, Copal, Corn Starch Modified, C6-14 Perfluoroalkylethyl Acrylate / HEMA Copolymer, C6-14 Polyolefin, Decene / Butene Copolymer, Dihydrogenated Tallow Benzylmonium Hectorite, Dilinoleic Acid / Ethylenediamine Copolymer, Dilinoleic Acid / Sebacic Acid / Piperazine / Ethylenediamine Copolymer, Dimethicone Crosspolymer, Dimethicone / Phenyl Vinyl Dimethicone Crosspolymer, Dimethicone / Vinyl Dimethicone Crosspolymer, Dimethicone / Vinyltrimethylsiloxysilicate Crosspolymer, Diphenyl Dimethicone / Vinyl Diphenyl Dimethicone / Silsesquioxeth Dicidocone / Glypolymer / Divo , Ethyl cellulose, ethylene / acrylic acid copolymer, E thylene / acrylic acid / VA copolymer, ethylenediamine / dimer tallate copolymer bis-hydrogenated tallow amide, ethylenediamine / stearyl dimer dilinoleate copolymer, ethylenediamine / stearyl dimer tallate copolymer, ethylene / octene copolymer, ethylene / propylene copolymer, ethylene / propylene / styrene copolymer, Euphorbia Cerifera (Candelilla) Wax, Hydrogenated Butylene / Ethylene / Styrene Copolymer, Hydrogenated Ethylene / Propylene / Styrene Copolymer, Hydrogenated Japan Wax, Hydrogenated Polyisobutene, Hydrogenated Styrene / Butadiene Copolymer, Hydrogenated Styrene / Methyl Styrene / Indene Copolymer, Hydroxypropylcellulose, Isobutylene / Isoprene Copolymer, Lithium Oxidized Polyethylene, Methoxy PEG-17 / Dodecyl Glycol Copolymer, Methoxy PEG-22 / Dodecyl Glycol Copolymer, Methyl Methacrylate Crosspolymer, Methylstyrene / Vinyltoluene Copolymer, Microcrystalline Wax, Montan Acid Wax, Montan Wax, Myrica Cerifera (Bayberry) Fruit Wax , Nylon-611 / Dimethicone Copolymer, Octadecene / MA Copolymer, Oleic / Linoleic / Linoleni c Polyglycerides, Ouricury Wax, Oxidized Beeswax, Oxidized Microcrystalline Wax, Oxidized Polyethylene, Oxidized Polypropylene, Ozokerite, Paraffin, PEG-18 Castor Oil Dioleate, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-5 Hydrogenated Castor Oil Isostearate PEG-10 Hydrogenated Castor Oil Isostearate, PEG-20 Hydrogenated Castor Oil Isostearate, PEG-30 Hydrogenated Castor Oil Isostearate, PEG-40 Hydrogenated Castor Oil Isostearate, PEG-50 Hydrogenated Castor Oil Isostearate, PEG-58 Hydrogenated Castor Oil Isostearate, PEG- 50 Hydrogenated Castor Oil Succinate, PEG-5 Hydrogenated Castor Oil Triisostearate, PEG-10 Hydrogenated Castor Oil Triisostearate, PEG-15 Hydrogenated Castor Oil Triisostearate, PEG-20 Hydrogenated Castor Oil Triisostearate, PEG-30 Hydrogenated Castor Oil Triisostearate, PEG-40 Castor Oil Triisostearate, PEG-60 Hydrogenated Castor Oil Triisostearate, PEG-5 Lanolinamide, PEG-5 Oleamide Dioleate, Phthalic Anhydride / Butyl Benzoic Ac id / Propylene Glycol Copolymer, Phthalic Anhydride / Glycerin / Glycidyl Decanoate Copolymer, Phthalic Anhydride / Trimellitic Anhydride / Glycols Copolymer, Piperylene / Butene / Pentene Copolymer, Polybutene, Polybutylene Terephthalate, Polycyclopentadienes, Polydipentene, Polyethylenes, Polyethylene Terephthalate, Polyglycerol 3 Polymers Polyglyceryl-4 Polyricinoleate, polyglyceryl-5 Polyricinoleate, polyglyceryl-10 Polyricinoleate, polyisobutenes, polyisoprenes, polypentenes, Polyperfluoroethoxymethoxy difluoromethyl Distearamide, polypropylenes, Polysilicone-4, Polysilicone-5, Polysilicone-17, polystyrene, polyvinyl butyral, polyvinyl laurate, potassium Oxidized Microcrystalline Wax, Potassium PEG-50 Hydrogenated Castor Oil Succinate, PVM / MA Decadiene Crosspolymer, PVP / Decene Copolymer, Rhus Succedanea Fruit Wax, Rosin, Silica Dimethicone Silylate, Silica Dimethyl Silylate, Simmondsia Chinensis (Jojoba) Seed Wax, Sodium PVM / MA / Decadiene Crosspolymer, Spent Grain Wax, Steareth-10 Allyl Ether / Acrylates Copolymer, Steareth-60 Cetyl Ether, Stearoxymethicone / Dimethicone Copolymer, Stearyl Methacrylate / Perfluorooctylethyl Methacrylate Copolymer, Styrene / Methacrylamide / Acrylates Copolymer, Synthetic Beeswax, Synthetic Candelilla Wax, Synthetic Carnauba, Synthetic Japan Wax, Synthetic Wax, TDI Oxidized Micro Wax, Tricontanyl PVP, trifluoropropyl dimethicone crosspolymer, trifluoropropyl dimethicone / trifluoropropyl Divinyldimethicone crosspolymer, trifluoropropyl dimethicone / vinyl trifluoropropyl dimethicone / Silsesquioxane Crosspolymer, Trimethylpentanediol / Isophthalic Acid / Trimellitic anhydride copolymer, Trimethylsiloxysilicate / Dimethiconol Crosspolymer, vinyl Dimethicone / lauryl Dimethicone Crosspolymer, vinyl D imethicone / methicone silsesquioxane crosspolymer, VP / Eicosene copolymer, VP / hexadecene copolymer

Another essential function of polymers in cosmetic products is the function as a suspension aid. Suspension aids facilitate the distribution of solids in liquids. Here, the polymers cover the surface of the solid particles by adsorption and thereby change the surface properties of the solids. Examples of these polymers are listed below:
Acrylates Copolymer, Acrylates / Methoxy PEG-15 Methacrylate Copolymer, Acrylates / Vinyl Isodecanoate Crosspolymer, Acrylates / VP Copolymer, Acrylic Acid / Acrylamidomethyl Propane Sulfonic Acid Copolymer, Ammonium Styrene / Acrylates Copolymer, Ammonium VA / Acrylates Copolymer, Bentonite, Biotite, Calcium Lignosulfonate , Corn Starch / Acrylamide / Sodium Acrylate Copolymer, C6-14 Perfluoroalkylethyl Acrylate / HEMA Copolymer, Diallyloxyneohexyl Zirconium Tridecanoate, Dihydrogenated Tallow Benzylmonium Hectorite, Dimethicone Crosspolymer, Dimethiconol / Stearyl Methicone / Phenyl Trimethicone Copolymer, Dimethylol Sodium Phenol / Phenolate Copolymer Methylene Dinaphthalenesulfonate, Disteardimonium Hectorite, Ethylene / MA Copolymer, Ethylene / VA Copolymer, Ethylhexyl Hydroxystearoyl Hydroxystearate, Hectorite, Hydroxyethyl Acrylate / Sodium Acryloyldimethyl Taurate Copolymer, Hydroxyethyl PEI-1000, Hydroxyethyl PEI-1500, Hydroxypropyl Starch, Hydroxypropyltrinium Polym er, isobutylene / MA copolymer, isopropyl ester of PVM / MA copolymer, maltodextrin, methacryloyl ethyl betaine / acrylates copolymer, methoxy PEG-17 / dodecyl glycol copolymer, methoxy PEG-22 / dodecyl glycol copolymer, myristoyl / PCA chitin, nitrocellulose, PEG -18 Castor Oil Dioleate, PEG-150 / Decyl Alcohol / SMDI Copolymer, PEG-12 Dimethicone Crosspolymer, PEG-150 / Stearyl Alcohol / SMDI Copolymer, PEI-7, PEI-10, PEI-15, PEI-30, PEI- 35, PEI-45, PEI-250, PEI-275, PEI-700, PEI-1000, PEI-1400, PEI-1500, PEI-1750, PEI-2500, PEI-14M, Perfluorononyl Octyldodecyl Glycol Meadowfoamate, Perlite, Phosphonobutanetricarboxylic Acid, Polyacrylamidomethylpropane Sulfonic Acid, Polycaprolactone, Polyethylacrylate, Polyhydroxystearic Acid, Polyperfluoroethoxymethoxy PEG-2 Phosphate, Polyvinyl Imidazolinium Acetate, Polyvinyl Methyl Ether, PPG-3 Myristyl Ether Neoheptanoate, PVM / MA Copolymer, PVP, Quaternic Acid / PVP / Acid / Acid / PVP -18 bentonite, quaternium-18 / benzalkonium bentonite, quaternium-18 hectorite, Quaternium-90 Bentonite, Rhizobian Gum, Silica, Silica Dimethicone Silylate, Silica Dimethyl Silylate, Silica Silylate, Sodium Acrylate / Acryloyldimethyl Taurate Copolymer, Sodium Acrylates / Vinyl Isodecanoate Crosspolymer, Sodium Acrylic Acid / MA Copolymer, Sodium C4-12 Olefin / Maleic Acid Copolymer, Sodium Dextran Sulfate, Sodium Dimaltodextrin Phosphate, Sodium Glycereth-1 Polyphosphate, Sodium Isooctylene / MA Copolymer, Sodium Magnesium Fluorosilicate, Starch Hydroxypropyltrimonium Chloride, Stearalkonium Bentonite, Stearalkonium Hectorite, Stearylvinyl Ether / MA Copolymer, Styrene / Acrylates / Acrylonitrile / Acrylates / Ammonium Methacrylate Copolymer, Styrene / MA Copolymer, Sucrose Benzoate / Sucrose Acetate Isobutyrate / Butyl Benzyl Phthalate Copolymer, Tosylamide / Epoxy Resin, Tosylamide / Formaldehyde Resin, VP / Dimethylaminoethylmethacrylate Copolymer, VP / Eicosene Copolymer, VP / Hexadecene Copolymer, VP / VA copolymer.

Finally, the antistatic effect of polymers is another essential function for cosmetic products. With the help of the electrical properties of these polymers, the electrical potential of the surfaces of the substrates treated with cosmetic agents skin, nails and keratin fibers is influenced. In hair care, for example, this reduces the effect known as the "fly-away effect" and is based on the electrostatic repulsion of the hair fibers. But also on the skin surface the skin feeling is influenced in this way. Some of these polymers develop their optimal effect in a certain pH range. Examples of such polymers are:
Acrylamidopropyltrimonium Chloride / Acrylamide Copolymer, Acrylamidopropyltrimonium Chloride / Acrylates Copolymer, AMP-Isostearoyl Gelatin / Keratin Amino Acids / Lysine Hydroxypropyltrimonium Chloride, Benzyltrimonium Hydrolyzed Collagen, Caesalpinia Spinosa Hydroxypropyltrimonium Chloride, Cocamidopropyldimonium Hydroxypropyl Hydrodimonium Collagen, Hydroxypropyl Hydrodimodium Collagen, Hydroxypropyl Hydrolyzedium Collagen Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydro xypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk Amino Acids, Dimethicone Hydroxypropyl Trimonium Chloride, Dimethicone Propylethylenediamine Behenate, Dimethicone Propyl PG-Betaine, Ditallow Dimonium Cellulose Sulfate, Gelatin / Keratin Amino Acids / Lysine Hydroxypropyltrimonium Chloride, Polyimonamide / Gelatin / Gelatin -Glucan Hydroxypropyltrimonium Chloride, Guar Hydroxypropyltrimonium Chloride, Hydrogenated Starch Hydrolysate Hydroxypropyltrimonium Chloride, Hydroxypropyl Guar Hydroxypropyltrimonium Chloride, Hydroxypropyltrimonium Hydrolyzedimino Hydroxy Hydroxypropyl Hydroxy Hydroxy Hydroxy Hydroxypropyl Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Hydroxy Tri Rice Bran Protein, Hydroxypropyltrimonium Hydrolyzed Silk, Hydroxypropyltrimonium Hydrolyzed Soy Prote in, Hydroxypropyltrimonium Hydrolyzed Vegetable Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein / Siloxysilicate, Hydroxypropyltrimonium Hydrolyzed Wheat Starch, Hydroxypropyltrimonium Hydrolyzed Whey, Laurdimonium Hydroxypropyl Hydrolyzed Jojoba Protein, Laurdimonium Hydroxypropyl Hydroxyl Hydrolyzed Protein / Laurdimonium Hydroxypropyl Hydrolyzed Protein Hydrolyzed Wheat Starch, Laurdimonium Hydroxypropyl Wheat Amino Acids, Laur / Myrist / Palmitamidobutyl Guanidine Acetate, Lauryldimonium Hydroxypropyl Hydrolyzed Casein, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen, Lauryldimonium Hydroxypropyl Hydrolyzed Keratin, Lauryldimonium Hydroxypropyl Hydrolyzedolyyl Propyl, Methylamine, Laurethyl Hydroxypropyl Hydrolyzed Collagen, PEG-2 Coco-Benzonium Chloride, PEG-10 Coco-Benzonium Chloride, PEG- 2 Cocomonium Chloride, PEG-15 Cocomonium Chloride, PEG-5 Cocomonium Methosulfate, PEG-15 Cocomonium Methosulfate, PEG-15 Cocopolyamine, PEG-9 Diethylmonium Chloride, PEG-25 Diethylmonium Chloride, PEG-2 Dimeadowfoamamidoethylmonium Methosulfate, PEG-3monoleoyl , PEG-3 Distearoylamidoethylmonium Methosulfate, PEG-4 Distearylethonium Ethosulfate, PEG-2 Hydrogenated Tallow Amine, PEG-5 Hydrogenated Tallow Amine, PEG-8 Hydrogenated Tallow Amine, PEG-10 Hydrogenated Tallow Amine, PEG-15 Hydrogenated Tallow Amine, PEG- 20 Hydrogenated Tallow Amines, PEG-30 Hydrogenated Tallow Amines, PEG-40 Hydrogenated Tallow Amines, PEG-50 Hydrogenated Tallow Amines, PEG-15 Hydrogenated Tallowmonium Chloride, PEG-5 Isodecyloxypropylamine, PEG-2 Lauramine, PEG-5 Oleamine, PEG- 15 oleamines, PEG-30 oleamines, PEG-2 oleammonium chlorides, PEG-15 oleammonium chlorides, PEG-12 palmitamines, PEG-8 palmitoyl methyl diethonium methosulfates, PEG / PPG-1/25 diethylmonium chlorides, PEG-2 rapeseedamines, PEG-2 Soyamine, PEG-5 Soyamine, PEG-8 Soyamine, PEG-10 Soyamine, PEG-15 Soyamine, PEG-2 Stearamine, PEG-5 Stearamine, PEG-10 Stearamine, PEG-15 Stearamine, PEG-50 Stearamine, PEG-2 Stearmonium Chloride, PEG-15 Stearmonium Chloride, PEG-5 Stearyl Ammonium Chloride, PEG-5 Stearyl Ammonium Lactate, PEG-10 Stearyl Benzonium Chloride, PEG-6 Stearylguanidine, PEG-5 Tallow Amide, PEG-2 Tallow Amine, PEG-7 Tallow Amine, PEG-11 Tallow Amine, PEG-15 Tallow Amine, PEG-20 Tallow Amine, PEG-25 Tallow Amine, PEG-3 Tallow Aminopropylamine, PEG-10 Tallow Aminopropylamine, PEG-15 Tallow Aminopropylamine, PEG- 20 Tallow Ammonium Ethosulfate, PEG-5 Tallow Benzonium Chloride, PEG-15 Tallow Polyamine, PEG-3 Tallow Propylene Edimonium Dimethosulfate, PG-Hydroxyethylcellulose Cocodimonium Chloride, PG-Hydroxyethylcellulose Lauryldimonium Chloride, PG-Hydroxyethylcellulose Stearyldimonium Chloride, Polymethacrylamide, Polymethacrylamide, Polymethacrylate Acrylate -1, poly quaternium-2, polyquaternium-4, polyquaternium-5, polyquaternium-6, polyquaternium-7, polyquaternium-8, polyquaternium-9, polyquaternium-10, polyquaternium-11, polyquaternium-12, polyquaternium-13, polyquaternium-14, polyquaternium-14 15, Polyquaternium-16, Polyquaternium-17, Polyquaternium-18, Polyquaternium-19, Polyquaternium-20, Polyquaternium-22, Polyquaternium-24, Polyquaternium-27, Polyquaternium-28, Polyquaternium-29, Polyquaternium-30, Polyquaternium-31 Polyquaternium-32, Polyquaternium-33, Polyquaternium-34, Polyquaternium-35, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-43, Polyquaternium-44, Polyquaternium-45, Polyquaternium-46, Polyquaternium-48, 49, Polyquaternium-50, Polyquaternium-54, Polyquaternium-60, Polysilicone-1, Polyvinyl Imidazolinium Acetate, PPG-2 Cocamine, PPG-9 Diethylmonium Chloride, PPG-25 Diethylmonium Chloride, PPG-40 Diethylmonium Chloride, PPG-2 Hydrogenated Tallowamine , PPG-24-PEG-21 Tallowaminopropylamine, PPG-2 Tallowamine, PPG-3 Tallow Aminopropylamine, Propyltrimonium Hydrolyzed Collagen, Propyltrimonium Hydrolyzed Soy Protein, Propyltrimonium Hydrolyzed Wheat Protein, Quaternium-8, Quaternium-14, Quaternium-15, Quaternium-16, Quaternium-18, Quaternium-18 Methosulfate 22 , Quaternium-24, Quaternium-26, Quaternium-27, Quaternium-30, Quaternium-33, Quaternium-43, Quaternium-45, Quaternium-51, Quaternium-52, Quaternium-53, Quaternium-56, Quaternium-60, Quaternium -61, Quaternium-63, Quaternium-70, Quaternium-71, Quaternium-72, Quaternium-73, Quaternium-75, Quaternium-76 Hydrolyzed Collagen, Quaternium-77, Quaternium-78, Quaternium-79 Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Keratin, Quaternium-79 Hydrolyzed Milk Protein, Quaternium-79 Hydrolyzed Silk, Quaternium-79 Hydrolyzed Soy Protein, Quaternium-79 Hydrolyzed Wheat Protein, Quaternium-80, Quaternium-81, Quaternium-82, Quaternium-83, Quaternium-86, Quaternium-88, Quaternium-89, Quaternium-90, Silicone Quaternium-2 Panthenol Succinate, Steardimonium Hydroxypropyl Hydrolyzed Casein, Steardimonium Hydroxypropyl Hydrolyzed Collagen, Steardimonium Hydroxypropyl Hydrolyzed Jojoba Protein, Steardimonium Hydroxypropyl Hydrolyzed Keratin, Steardimonium Hydroxypropyl Hydrolydiumium Rice Protein, Steardimonium Hydroxypropyl Hydrolyzed Rice Protein, Steardimonium Hydroxyl Hydroxypropyl Hydrolyzed Vegetable Protein, Steardimonium Hydroxypropyl Hydrolyzed Wheat Protein, Steartimonium Hydroxyethyl Hydrolyzed Collagen, Triethonium Hydrolyzed Collagen Ethosulfate, Trigonella Foenum-Graecum Hydroxypropyltrimonium Chloride, Wheat Germamidopropyldimonium Hydroxypropyl Hydrolyzed Wheat Protein, Wheat Germamidulfylate Epoxydylamido Propyl Methyloxidyl Ethoxide Methyloxidyl Ethyldimidomethyl Propyl Methylamide Ethoxyl Methylamide Ethoxyl Methylamide Ethoxyl Methylamide

Under cationic polymers (G1) are to be understood as polymers which are used in the main and / or Side chain have a group, which can be "temporary" or "permanent" cationic. According to the invention, such are considered to be “permanently cationic” Polymers referred to independently have a cationic group on the pH of the agent. This are usually polymers that have a quaternary nitrogen atom, for example in the form of an ammonium group. Preferred cationic Groups are quaternary Ammonium groups. In particular those polymers in which the quaternary ammonium group has a C1-4 hydrocarbon group to one made of acrylic acid, methacrylic acid or the derivatives of which are attached to the main polymer chain, have proven to be particularly suitable.

in der R¹ = -H oder -CH₃ ist, R², R³ und R⁴ unabhängig voneinander ausgewählt sind aus C1-4-Alkyl-, -Alkenyl- oder -Hydroxyalkylgruppen, m = 1, 2, 3 oder 4, n eine natürliche Zahl und X^– ein physiologisch verträgliches organisches oder anorganisches Anion ist, sowie Copolymere, bestehend im wesentlichen aus den in Formel (G1-I aufgeführten Monomereinheiten sowie nichtionogenen Monomereinheiten, sind besonders bevorzugte kationische Polymere. Im Rahmen dieser Polymere sind diejenigen erfindungsgemäß bevorzugt, für die mindestens eine der folgenden Bedingungen gilt:
R¹ steht für eine Methylgruppe
R², R³ und R⁴ stehen für Methylgruppen
m hat den Wert 2.Homopolymers of the general formula (G1-I),

in which R ¹ = -H or -CH ₃ , R ² , R ³ and R ^{4 are} independently selected from C1-4 alkyl, alkenyl or hydroxyalkyl groups, m = 1, 2, 3 or 4, n is a natural number and X ^{- is} a physiologically compatible organic or inorganic anion, and copolymers consisting essentially of the monomer units listed in formula (G1-I and nonionic monomer units) are particularly preferred cationic polymers. Within the scope of these polymers, those are preferred according to the invention , for which at least one of the following conditions applies:
R ¹ represents a methyl group
R ² , R ³ and R ⁴ represent methyl groups
m has the value 2.

Suitable physiologically compatible counterions X ^- are, for example, halide ions, sulfate ions, phosphate ions, methosulfate ions and organic ions such as lactate, citrate, tartrate and acetate ions. Halide ions, in particular chloride, are preferred.

On a particularly suitable homopolymer is, if desired crosslinked, poly (methacryloyloxyethyltrimethylammonium chloride) with the INCI name Polyquaternium-37. Networking can if desired with the aid of polyolefinically unsaturated compounds, for example Divinylbenzene, tetraallyloxyethane, methylenebisacrylamide, diallyl ether, Polyallylpolyglyceryl ether, or allyl ethers of sugars or sugar derivatives such as erythritol, pentaerythritol, arabitol, mannitol, sorbitol, sucrose or glucose. Methylene bisacrylamide is a preferred one Crosslinking agent.

The homopolymer is preferably used in the form of a non-aqueous polymer dispersion which should not have a polymer content below 30% by weight. Such polymer dispersions are available under the names Salcare ^® SC 95 (approx. 50% polymer content, further components: mineral oil (INCI name: Mineral Oil) and tridecyl-polyoxypropylene-polyoxyethylene ether (INCI name: PPG-1-Trideceth-6) ) and Salcare ^® SC 96 (approx. 50% polymer content, further components: mixture of diesters of propylene glycol with a mixture of caprylic and capric acid (INCI name: Propylene Glycol Dicaprylate / Dicaprate) and tridecyl-polyoxypropylene-polyoxyethylene ether (INCI - Name: PPG-1-Trideceth-6)) commercially available.

Copolymers with monomer units according to formula (G1-I) contain as non-ionic monomer units ten, preferably acrylamide, methacrylamide, acrylic acid C _1-4 alkyl esters and methacrylic acid C _1-4 alkyl ester. Among these nonionic monomers, acrylamide is particularly preferred. As in the case of the homopolymers described above, these copolymers can also be crosslinked. A preferred copolymer according to the invention is the crosslinked acrylamide-methacryloyloxyethyltrimethylammonium chloride copolymer. Such copolymers in which the monomers are present in a weight ratio of about 20:80, commercially available as about 50% non-aqueous polymer dispersion under the name Salcare ^® SC 92nd

• – quaternisierte Cellulose-Derivate, wie sie unter den Bezeichnungen Celquat^® und Polymer JR^® im Handel erhältlich sind. Die Verbindungen Celquat^® H 100, Celquat^® L 200 und Polymer JR^®400 sind bevorzugte quaternierte Cellulose-Derivate,
• – kationische Alkylpolyglycoside gemäß der DE-PS 44 13 686 ,
• – kationiserter Honig, beispielsweise das Handelsprodukt Honeyquat^® 50,
• – kationische Guar-Derivate, wie insbesondere die unter den Handelsnamen Cosmedia^®Guar und Jaguar^® vertriebenen Produkte,
• – Polysiloxane mit quaternären Gruppen, wie beispielsweise die im Handel erhältlichen Produkte Q2-7224 (Hersteller: Dow Corning; ein stabilisiertes Trimethylsilylamodimethicon), Dow Corning^® 929 Emulsion (enthaltend ein hydroxyl-amino-modifiziertes Silicon, das auch als Amodimethicone bezeichnet wird), SM-2059 (Hersteller: General Electric), SLM-55067 (Hersteller: Wacker) sowie Abil^®-Quat 3270 und 3272 (Hersteller: Th. Goldschmidt), diquaternäre Polydimethylsiloxane, Quaternium-80),
• – polymere Dimethyldiallylammoniumsalze und deren Copolymere mit Estern und Amiden von Acrylsäure und Methacrylsäure. Die unter den Bezeichnungen Merquat^®100 (Poly(dimethyldiallylammoniumchlorid)) und Merquat^®550 (Dimethyldiallylammoniumchlorid-Acrylamid-Copolymer) im Handel erhältlichen Produkte sind Beispiele für solche kationischen Polymere,
• – Copolymere des Vinylpyrrolidons mit quaternierten Derivaten des Dialkylaminoalkylacrylats und -methacrylats, wie beispielsweise mit Diethylsulfat quaternierte Vinylpyrrolidon-Dimethylaminoethylmethacrylat-Copolymere. Solche Verbindungen sind unter den Bezeichnungen Gafquat^®734 und Gafquat^®755 im Handel erhältlich,
• – Vinylpyrrolidon-Vinylimidazoliummethochlorid-Copolymere, wie sie unter den Bezeichnungen Luviquat^® FC 370, FC 550, FC 905 und HM 552 angeboten werden,
• – quaternierter Polyvinylalkohol,
• – sowie die unter den Bezeichnungen Polyquaternium 2, Polyquaternium 17, Polyquaternium 18 und Polyquaternium 27 bekannten Polymeren mit quartären Stickstoffatomen in der Polymerhauptkette.

Other preferred cationic polymers are, for example

• - Quaternized cellulose derivatives, as are commercially available under the names Celquat ^® and Polymer JR ^® . The compounds Celquat ^® H 100, Celquat ^® L 200 and Polymer JR ^® 400 are preferred quaternized cellulose derivatives,
• - Cationic alkyl polyglycosides according to the DE-PS 44 13 686 .
• Cationized honey, for example the commercial product Honeyquat ^® 50,
• Cationic guar derivatives, such as, in particular, the products sold under the trade names Cosmedia ^® Guar and Jaguar ^® ,
• Polysiloxanes with quaternary groups, such as, for example, the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized trimethylsilylamodimethicone), Dow ^Corning® 929 emulsion (containing a hydroxylamino-modified silicone, which is also referred to as amodimethicone), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ^® -Quat 3270 and 3272 (manufacturer: Th. Goldschmidt), diquaternary polydimethylsiloxanes, Quaternium-80),
• - Polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid. The products commercially available under the names Merquat ^® 100 (poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers,
• - Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as, for example, vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers quaternized with diethyl sulfate. Such compounds are commercially available under the names Gafquat ^® 734 and Gafquat ^® 755,
• Vinylpyrrolidone-vinylimidazolium methochloride copolymers, as are offered under the names Luviquat ^® FC 370, FC 550, FC 905 and HM 552,
• - quaternized polyvinyl alcohol,
• - And the known under the names Polyquaternium 2, Polyquaternium 17, Polyquaternium 18 and Polyquaternium 27 polymers with quaternary nitrogen atoms in the main polymer chain.

Can be used as cationic polymers (. B. commercial product, Quatrisoft ^® LM 200) under the designations Polyquaternium-24, known polymers. Likewise usable according to the invention are the copolymers of vinyl pyrrolidone, such as those available as commercial products Copolymer 845 (manufacturer: ISP), Gaffix ^® VC 713 (manufacturer: ISP), Gafquat ^® ASCP 1011, Gafquat ^® HS 110, Luviquat ^® 8155 and Luviquat ^® MS 370 are.

Further cationic polymers according to the invention are the so-called "temporarily cationic" polymers. These polymers usually contain an amino group which is present as a quaternary ammonium group at certain pH values and is therefore cationic. Preferably, for example, are chitosan and its derivatives, such as 101 are freely available commercially, for example under the trade names Hydagen CMF, Hydagen HCMF ^®, Kytamer ^® PC and Chitolam ^® NB /.

According to the invention preferred cationic polymers are cationic cellulose derivatives and chitosan and its derivatives, in particular the commercial products Polymer ^® JR 400, Hydagen ^® HCMF and Kytamer ^® PC, cationic guar derivatives, cationic honey derivatives, in particular the commercial product Honeyquat ^® 50, cationic Alkylpolyglycodside according to the DE-PS 44 13 686 and polyquaternium-37 polymers.

Furthermore, cationized protein hydrolyzates are to be counted among the cationic polymers, the underlying protein hydrolyzate being derived from animals, for example from collagen, milk or keratin, from plants, for example from wheat, corn, rice, potatoes, soy or almonds, from marine life forms, for example from fish collagen or algae, or biotechnologically obtained protein hydrolyzates. The protein hydrolysates on which the cationic derivatives according to the invention are based can be obtained from the corresponding proteins by chemical, in particular alkaline or acidic hydrolysis, by enzymatic hydrolysis and / or a combination of both types of hydrolysis. The hydrolysis of proteins usually results in a protein hydrolyzate with a molecular weight distribution of approximately 100 daltons up to several thousand daltons. Preferred cationic protein hydrolyzates are whose underlying protein content has a molecular weight of 100 to 25,000 daltons, preferably 250 to 5000 daltons. Cationic protein hydrolyzates also include quaternized amino acids and their mixtures. The quaternization of the protein hydrolyzates or the amino acids is often carried out using quaternary ammonium salts such as, for example, N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides. Furthermore, the cationic protein hydrolyzates can also be further derivatized. As typical examples of the inventive cationic protein hydrolysates and derivatives are the ^th under the INCI names in the "International Cosmetic Ingredient Dictionary and Handbook" (seventh edition 1997, The Cosmetic, Toiletry, and Fragrance Association 1101 17 Street, NW, Suite 300 , Washington, DC 20036-4702) and commercially available products: Cocodimonium hydroxypropyl hydrolyzed collagen, Cocodimopnium hydroxypropyl hydrolyzed casein, Cocodimonium hydroxypropyl hydrolyzed collagen, Cocodimonium hydroxypropyl hydrolyzed hair keratin, Cocodimonium hydroxypropyl hydrolyzed keratin, Cocodimonium hydroxypropyl hydrolyzed hydroxypropyl hydrolyzed Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk Amino Acids, Hydroxypropyl Arginine Lauryl / Myristyl Ether HCl, Hydroxypropyltrimonium Gelatin, Hydroxypropyltrimonium Hydrolyzed Casein , Hydroxypropyltrimonium Hydrolyzed Collagen, Hydroxypropyltrimonium Hydrolyzed Conchiolin Protein, Hydroxypropyltrimonium Hydrolyzed Keratin, Hydroxypropyltrimonium Hydrolyzed Rice Bran Protein, Hydroxyproypltrimonium Hydrolyzed Silk, Hydroxypropyltrimonium Hydrolyzed Soy Protein, Hydroxypropyl Hydrolyzed Vegetable Protein, Hydroxypropyltrimonium Hydroxysiloxysiloxysiloxydehydrogenated Hydroxytyltrimonium Hydroxysiloxysilicate Protein, laurdimonium hydroxypropyl hydrolyzed wheat protein, laurdimonium hydroxypropyl hydrolyzed wheat protein / siloxysilicate, lauryldimonium hydroxypropyl hydrolyzed casein, lauryldimonium hydroxypropyl hydrolyzed collagen, lauryldimonium hydroxypropyl hydrolyzed keratin, lauryldimonium hydroxypropyl hydrolyzedoyl hydroxypropyl hydrolyzedoyl, lauryldimonium hydroxypropyl Collagen, steardimonium hydroxypropyl hydrolyzed keratin , Steardimonium Hydroxypropyl Hydrolyzed Rice Protein, Steardimonium Hydroxypropyl Hydrolyzed Silk, Steardimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Vegetable Protein, Steardimonium Hydroxypropyl Hydrolyzed Wheat Protein, Steartimonium Hydroxyethyl Hydrolyzed Collagen, Quaternium-76 Hydrolyzedagen 79, Quaternagen-76 Hydrolyzed Collagen Hydrolyzed Keratin, Quaternium-79 Hydrolyzed Milk Protein, Quaternium-79 Hydrolyzed Silk, Quaternium-79 Hydrolyzed Soy Protein, Quaternium-79 Hydrolyzed Wheat Protein.

All the cationic protein hydrolyzates and are particularly preferred -derivatives based on plants.

at The anionic polymers (G2) include anionic polymers, which carboxylate and / or sulfonate groups exhibit. examples for are anionic monomers from which such polymers can consist Acrylic acid, methacrylic acid, crotonic, maleic anhydride and 2-acrylamido-2-methylpropanesulfonic acid. The acidic groups in whole or in part as sodium, potassium, ammonium, Mono- or triethanolammonium salt are present. Preferred monomers are 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid.

As anionic polymers have proven to be particularly effective, which contain 2-acrylamido-2-methylpropanesulfonic acid as the sole or co-monomer, being the sulfonic acid group wholly or partly as sodium, potassium, ammonium, mono- or Triethanolammonium salt can be present.

More preferably, the homopolymer of 2-acrylamido-2-methyl propane sulfonic acid, which is available for example under the name Rheothik ^® 11-80 is commercially.

Within this embodiment it may be preferred to use copolymers of at least one anionic To use monomer and at least one nonionic monomer. In terms of The anionic monomers are based on the substances listed above directed. Preferred nonionic monomers are acrylamide, methacrylamide, acrylate, methacrylates, Vinyl pyrrolidone, vinyl ether and vinyl ester.

Preferred anionic copolymers are acrylic acid-acrylamide copolymers and in particular polyacrylamide copolymers with monomers containing sulfonic acid groups. A particularly preferred anionic copolymer consists of 70 to 55 mol% of acrylamide and 30 to 45 mol% of 2-acrylamido-2-methylpropanesulfonic acid, the sulfonic acid group being wholly or partly as sodium, potassium, ammonium, mono- or triethanolammonium Salt is present. This copolymer can also be crosslinked, the preferred crosslinking agents being polyolefinically unsaturated compounds such as tetraallyloxyethane, allyl sucrose, allylpentae rythritol and methylene bisacrylamide are used. Such a polymer is contained in the commercial product Sepigel ^® 305 from SEPPIC. The use of this compound, which in addition to the polymer component contains a hydrocarbon mixture (C ₁₃ -C ₁₄ isoparaffin) and a nonionic emulsifier (Laureth-7), has proven to be particularly advantageous in the context of the teaching according to the invention.

Also, as a compound with isohexadecane and sold under the name Simulgel ^® 600 Polysorbate-80 sodium acryloyldimethyltaurate copolymers have proven effective as in the present invention particularly.

Also preferred anionic homopolymers are uncrosslinked and crosslinked polyacrylic acids. Allyl ethers of pentaerythritol, sucrose and propylene can be preferred crosslinking agents. Such compounds are for example available under the trademark Carbopol ^® commercially.

Copolymers of maleic anhydride and methyl vinyl ether, especially those with crosslinks, are also color-preserving polymers. A maleic acid-methyl vinyl ether copolymer crosslinked with 1,9-decadiene is commercially available under the name Stabileze ^® QM.

• – Vinylacetat/Crotonsäure-Copolymere, wie sie beispielsweise unter den Bezeichnungen Resyn^® (NATIONAL STARCH), Luviset^® (BASF) und Gafset^® (GAF) im Handel sind.
• – Vinylpyrrolidon/Vinylacrylat-Copolymere, erhältlich beispielsweise unter dem Warenzeichen Luviflex^® (BASF). Ein bevorzugtes Polymer ist das unter der Bezeichnung Luviflex^® VBM-35 (BASF) erhältliche Vinylpyrrolidon/Acrylat-Terpolymere.
• – Acrylsäure/Ethylacrylat/N-tert.Butylacrylamid-Terpolymere, die beispielsweise unter der Bezeichnung Ultrahold^® strong (BASF) vertrieben werden.

Anionic polymers which are also suitable according to the invention include:

• - vinyl acetate / crotonic acid copolymers, such as are commercially available for example under the names Resyn ^® (National Starch), Luviset ^® (BASF) and Gafset ^® (GAF).
• - vinylpyrrolidone / vinyl acrylate copolymers, obtainable for example under the trade name Luviflex ^® (BASF). A preferred polymer is that available under the name Luviflex VBM-35 ^® (BASF) vinylpyrrolidone / acrylate terpolymers.
• - Acrylic acid / ethyl acrylate / N-tert-butyl acrylamide terpolymers, which are sold, for example, under the name Ultrahold ^® strong (BASF).

Amphoteric polymers (G3) can also be used as polymers. The term amphoteric polymers includes both those polymers which contain both free amino groups and free -COOH or SO ₃ H groups in the molecule and are capable of forming internal salts, and also zwitterionic polymers which contain quaternary ammonium groups and -COO in the molecule ^- - or -SO ₃ ^- contain groups, and summarized those polymers which contain -COOH or SO ₃ H groups and quaternary ammonium groups.

An example of the present invention amphopolymer suitable is that available under the name Amphomer ^® acrylic resin which is a copolymer of tert-butylaminoethyl methacrylate, N- (1,1,3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group of acrylic acid, Methacrylic acid and its simple esters.

Further amphoteric polymers which can be used according to the invention are the compounds mentioned in British Patent Application 2 104 091, European Patent Application 47 714, European Patent Application 217 274, European Patent Application 283 817 and German Patent Application 28 17 369. Further suitable zwitterionic polymers are methacroylethylbetaine / methacrylate copolymers, which are available under the name Amersette® ^® (AMERCHOL).

• (a) Monomeren mit quartären Ammoniumgruppen der allgemeinen Formel (G3-I), R¹-CH=CR²-CO-Z-(C_nH_2n)-N⁽⁺⁾R³R⁴R⁵ A^(–) (G3-I)in der R¹ und R² unabhängig voneinander stehen für Wasserstoff oder eine Methylgruppe und R³, R⁴ und R⁵ unabhängig voneinander für Alkylgruppen mit 1 bis 4 Kohlenstoffatomen, Z eine NH-Gruppe oder ein Sauerstoffatom, n eine ganze Zahl von 2 bis 5 und A^(–) das Anion einer organischen oder anorganischen Säure ist, und
• (b) monomeren Carbonsäuren der allgemeinen Formel (G3-II), R⁶-CH=CR⁷-COOH (G3-II)in denen R⁶ und R⁷ unabhängig voneinander Wasserstoff oder Methylgruppen sind.

Amphoteric polymers which are preferably used are those polymers which essentially consist of one another

• (a) monomers with quaternary ammonium groups of the general formula (G3-I), R ¹ -CH = CR ² -CO-Z- (C _n H _2n ) -N ⁽⁺⁾ R ³ R ⁴ R ⁵ A ^(-) (G3-I) in which R ¹ and R ² independently of one another represent hydrogen or a methyl group and R ³ , R ⁴ and R ⁵ independently of one another are alkyl groups having 1 to 4 carbon atoms, Z is an NH group or an oxygen atom, n is an integer from 2 to 5 and A ^{(-) is} the anion of an organic or inorganic acid, and
• (b) monomeric carboxylic acids of the general formula (G3-II), R ⁶ -CH = CR ⁷ -COOH (G3-II) in which R ⁶ and R ^{7 are} independently hydrogen or methyl groups.

According to the invention, these compounds can be used both directly and in salt form, which is obtained by neutralizing the polymers, for example with an alkali metal hydroxide. With regard to the details of the preparation of these polymers, reference is expressly made to the content of German laid-open specification 39 29 973. Those polymers in which monomers of type (a) are used, in which R ³ , R ⁴ and R ^{5 are} methyl groups, Z is an NH group and A ^{(-) is} a halide, methoxysulfate or ethoxysulfate, Ion is; Acrylamidopropyl-trimethyl-ammonium chloride is a particularly preferred monomer (a). Acrylic acid is preferably used as monomer (b) for the polymers mentioned.

The agents according to the invention can in a further embodiment contain non-ionic polymers (G4).

• – Vinylpyrrolidon/Vinylester-Copolymere, wie sie beispielsweise unter dem Warenzeichen Luviskol^® (BASF) vertrieben werden. Luviskol^® VA 64 und Luviskol^® VA 73, jeweils Vinylpyrrolidon/Vinylacetat-Copolymere, sind ebenfalls bevorzugte nichtionische Polymere.
• – Celluloseether, wie Hydroxypropylcellulose, Hydroxyethylcellulose und Methylhydroxypropylcellulose, wie sie beispielsweise unter den Warenzeichen Culminal^® und Benecel^® (AQUALON) vertrieben werden.
• – Schellack
• – Polyvinylpyrrolidone, wie sie beispielsweise unter der Bezeichnung Luviskol^® (BASF) vertrieben werden.
• – Siloxane. Diese Siloxane können sowohl wasserlöslich als auch wasserunlöslich sein. Geeignet sind sowohl flüchtige als auch nichtflüchtige Siloxane, wobei als nichtflüchtige Siloxane solche Verbindungen verstanden werden, deren Siedepunkt bei Normaldruck oberhalb von 200°C liegt. Bevorzugte Siloxane sind Polydialkylsiloxane, wie beispielsweise Polydimethylsiloxan, Polyalkylarylsiloxane, wie beispielsweise Polyphenylmethylsiloxan, ethoxylierte Polydialkylsiloxane sowie Polydialkylsiloxane, die Amin- und/oder Hydroxy-Gruppen enthalten.
• – Glycosidisch substituierte Silicone gemäß der EP 0612759 B1 .

Suitable nonionic polymers are for example:

• - vinylpyrrolidone / Vinylester copolymers, as are marketed, for example under the trademark Luviskol ^® (BASF). Luviskol ^® VA 64 and Luviskol ^® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are also preferred nonionic polymers.
• - cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methylhydroxypropyl cellulose, such as are for example sold under the trademark Culminal® ^® and Benecel ^® (AQUALON).
• - Shellac
• - polyvinylpyrrolidones, as, for example, sold under the name Luviskol ^® (BASF).
• - siloxanes. These siloxanes can be both water-soluble and water-insoluble. Both volatile and non-volatile siloxanes are suitable, non-volatile siloxanes being understood to mean those compounds whose boiling point is above 200 ° C. at normal pressure. Preferred siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, such as, for example, polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups.
• - Glycosidically substituted silicones according to the EP 0612759 B1 ,

It it is also possible according to the invention that the preparations used several, in particular two different ones Polymers of the same charge and / or one ionic and one Contain amphoteric and / or non-ionic polymer.

Other preferred polymers are all polymers in the "International Cosmetic Ingredient Dictionary and Handbook" (seventh edition 1997, The Cosmetic, Toiletry, and Fragrance Association 1101 17 ^th Street, NW, Suite 300, Washington, DC 20036-4702) as polymers in one of the chapters on polymers such as "film formers" or "hair fixatives" and are commercially available. Reference is expressly made to this document and the sections cited from it.

The Polymers (G) are preferred in the agents used according to the invention in amounts of 0.01 to 30% by weight, based on the total agent, contain. Amounts from 0.01 to 25, in particular from 0.01 to 15 % By weight are particularly preferred.

The third component of the combination according to the invention is a cosmetic Active ingredient. The selection of the active ingredient concerned is based after the desired one Effect achieved with the molded body shall be. For Moldings, which keratin fibers are supposed to strengthen, the fibers hold, fullness and shine and should be easy to style, are preferred according to the invention selected the active ingredient groups described below.

As The first group of active ingredients are fatty substances (D). Among fatty substances are to be understood fatty acids, Fatty alcohols, natural and synthetic waxes, which are both in solid form and liquid in aqueous dispersion can be present and natural and synthetic cosmetic oil components to understand.

Linear and / or branched, saturated and / or unsaturated fatty acids with 6-30 carbon atoms can be used as fatty acids (D1). Fatty acids with 10-22 carbon atoms are preferred. Among these were, for example, to name the isostearic as the commercial products Emersol ^® 871 and Emersol ^® 875, and isopalmitic acids such as the commercial product Edenor ^® IP 95, and all other products sold under the trade names Edenor ^® (Cognis) fatty acids. Further typical examples of such fatty acids are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, aradeinic acid, elaeachene acid and elaeachene acid Eruca Acid and its technical mixtures, which occur, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxosynthesis or in the dimerization of unsaturated fatty acids. The fatty acid cuts which are obtainable from coconut oil or palm oil are usually particularly preferred; the use of stearic acid is generally particularly preferred.

The Amount used thereby 0.1–15 % By weight, based on the total average. The amount is preferably 0.5-10 % By weight, with quantities of 1-5% by weight being particularly advantageous. could be.

Saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C ₆ -C ₃₀ , preferably C ₁₀ -C ₂₂ and very particularly preferably C ₁₂ -C ₂₂ carbon atoms can be used as fatty alcohols (D2). For example, decanol, octanol, octenol, dodecenol, decenol, octadienol, dodecadienol, decadienol, oleyl alcohol, eruca alcohol, ricinol alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, capryl alcohol, arachidyl alcohol, arachidyl alcohol, arachidyl alcohol, arachidyl alcohol, arachidyl alcohol, arachidyl alcohol , as well as their Guerbet alcohols, this list is intended to be exemplary and not limiting. The fatty alcohols, however, derive from preferably natural fatty acids, and it can usually be assumed that they are obtained from the esters of the fatty acids by reduction. Also suitable according to the invention are those fatty alcohol cuts which are produced by reducing naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols, and thus represent a mixture of different fatty alcohols. Such substances are, for example, under the names Stenol ^® , for example Stenol ^® 1618 or Lanette ^® , for example Lanette ^® O or Lorol ^® , for example Lorol ^® C8, Lorol ^® C14, Lorol ^® C18, Lorol ^® C8-18, HD-Ocenol ^® , Crodacol ^® , e.g. Crodacol ^® CS, Novol ^® , Eutanol ^® G, Guerbitol ^® 16, Guerbitol ^® 18, Guerbitol ^® 20, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb ^® 12, Isocarb ^® 16 or to buy Isocarb ^® 24. Of course, according to the invention, wool wax alcohols, such as those commercially available under the names Corona ^® , White Swan ^® , Coronet ^® or Fluilan ^® , can also be used. The fatty alcohols are used in amounts of 0.1-30% by weight, based on the entire preparation, preferably in amounts of 0.1-20% by weight.

As natural or synthetic waxes (D3) used according to the invention solid paraffins or isoparaffins, carnauba waxes, beeswaxes, Candelilla waxes, ozokerite, ceresin, walrus, sunflower wax, Fruit waxes such as apple wax or citrus wax, microwaxes made of PE or PP. Such waxes are available, for example, from Kahl & Co., Trittau.

The Amount used 0.1-50 % By weight based on the total agent, preferably 0.1-20% by weight and particularly preferably 0.1-15 % By weight based on the total average.

• – pflanzliche Öle. Beispiele für solche Öle sind Sonnenblumenöl, Olivenöl, Sojaöl, Rapsöl, Mandelöl, Jojobaöl, Orangenöl, Weizenkeimöl, Pfirsichkernöl und die flüssigen Anteile des Kokosöls. Geeignet sind aber auch andere Triglyceridöle wie die flüssigen Anteile des Rindertalgs sowie synthetische Triglyceridöle.
• – flüssige Paraffinöle, Isoparaffinöle und synthetische Kohlenwasserstoffe sowie Di-n-alkylether mit insgesamt zwischen 12 bis 36 C-Atomen, insbesondere 12 bis 24 C-Atomen, wie beispielsweise Di-n-octylether, Di-n-decylether, Di-n-nonylether, Di-n-undecylether, Di-n-dodecylether, n-Hexyl-n-octylether, n-Octyl-n-decylether, n-Decyl-n-undecylether, n-Undecyl-n-dodecylether und n-Hexyl-n-Undecylether sowie Di-tert-butylether, Di-iso-pentylether, Di-3-ethyldecylether, tert.-Butyl-n-octylether, iso-Pentyl-n-octylether und 2-Methyl-pentyl-n-octylether. Die als Handelsprodukte erhältlichen Verbindungen 1,3-Di-(2-ethyl-hexyl)-cyclohexan (Cetiol^® S) und Di-n-octylether (Cetiol^® OE) können bevorzugt sein.
• – Esteröle. Unter Esterölen sind zu verstehen die Ester von C₆-C₃₀-Fettsäuren mit C₂-C₃₀-Fettalkoholen. Bevorzugt sind die Monoester der Fettsäuren mit Alkoholen mit 2 bis 24 C-Atomen. Beispiele für eingesetzte Fettsäurenanteile in den Estern sind Capronsäure, Caprylsäure, 2-Ethylhexansäure, Caprinsäure, Laurinsäure, Isotridecansäure, Myristinsäure, Palmitinsäure, Palmitoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearinsäure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Mischungen, die z.B. bei der Druckspaltung von natürlichen Fetten und Ölen, bei der Oxidation von Aldehyden aus der Roelen'schen Oxosynthese oder der Dimerisierung von ungesättigten Fettsäuren anfallen. Beispiele für die Fettalkoholanteile in den Esterölen sind Isopropylalkohol, Capronalkohol, Caprylalkohol, 2-Ethylhexylalkohol, Caprinalkohol, Laurylalkohol, Isotridecylalkohol, Myristylalkohol, Cetylalkohol, Palmoleylalkohol, Stearylalkohol, Isostearylalkohol, Oleylalkohol, Elaidylalkohol, Petroselinylalkohol, Linolylalkohol, Linolenylalkohol, Elaeostearylalkohol, Arachylalkohol, Gadoleylalkohol, Behenylalkohol, Erucylalkohol und Brassidylalkohol sowie deren technische Mischungen, die z.B. bei der Hochdruckhydrierung von technischen Methylestern auf Basis von Fetten und Ölen oder Aldehyden aus der Roelen'schen Oxosynthese sowie als Monomerfraktion bei der Dimerisierung von ungesättigten Fettalkoholen anfallen. Erfindungsgemäß besonders bevorzugt sind Isopropylmyristat (Rilanit^® IPM), Isononansäure-C16-18-alkylester (Cetiol^® SN), 2-Ethylhexylpalmitat (Cegesoft^® 24), Stearinsäure-2-ethylhexylester (Cetiol^® 868), Cetyloleat, Glycerintricaprylat, Kokosfettalkohol-caprinat/-caprylat (Cetiol^® LC), n-Butylstearat, Oleylerucat (Cetiol^® J 600), Isopropylpalmitat (Rilanit^® IPP), Oleyl Oleate (Cetiol, Laurinsäurehexylester (Cetiol^® A), Di-n-butyladipat (Cetiol^® B), Myristylmyristat (Cetiol^® MM), Cetearyl Isononanoate (Cetiol^® SN), Ölsäuredecylester (Cetiol^® V).
• – Dicarbonsäureester wie Di-n-butyladipat, Di-(2-ethylhexyl)-adipat, Di-(2-ethylhexyl)-succinat und Di-isotridecylacelaat sowie Diolester wie Ethylenglykol-dioleat, Ethylenglykol-di-isotridecanoat, Propylenglykol-di(2-ethylhexanoat), Propylenglykol-di-isostearat, Propylenglykol-di-pelargonat, Butandiol-di-isostearat, Neopentylglykoldicaprylat,
• – symmetrische, unsymmetrische oder cyclische Ester der Kohlensäure mit Fettalkoholen, beispielsweise beschrieben in der DE-OS 197 56 454 , Glycerincarbonat oder Dicaprylylcarbonat (Cetiol^® CC),
• – Trifettsäureester von gesättigten und/oder ungesättigten linearen und/oder verzweigten Fettsäuren mit Glycerin,
• – Fettsäurepartialglyceride, das sind Monoglyceride, Diglyceride und deren technische Gemische. Bei der Verwendung technischer Produkte können herstellungsbedingt noch geringe Mengen Triglyceride enthalten sein. Die Partialglyceride folgen vorzugsweise der Formel (D4-I),
  
  in der R¹, R² und R³ unabhängig voneinander für Wasserstoff oder für einen linearen oder verzweigten, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22, vorzugsweise 12 bis 18, Kohlenstoffatomen stehen mit der Maßgabe, dass mindestens eine dieser Gruppen für einen Acylrest und mindestens eine dieser Gruppen für Wasserstoff steht. Die Summe (m+n+q) steht für 0 oder Zahlen von 1 bis 100, vorzugsweise für 0 oder 5 bis 25. Bevorzugt steht R¹ für einen Acylrest und R² und R³ für Wasserstoff und die Summe (m+n+q) ist 0. Typische Beispiele sind Mono- und/oder Diglyceride auf Basis von Capronsäure, Caprylsäure, 2-Ethylhexansäure, Caprinsäure, Laurinsäure, Isotridecansäure, Myristinsäure, Palmitinsäure, Palmoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearinsäure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Mischungen. Vorzugsweise werden Ölsäuremonoglyceride eingesetzt.

The natural and synthetic cosmetic oil bodies (D4) which can increase the effect of the active ingredient according to the invention include, for example:

• - vegetable oils. Examples of such oils are sunflower oil, olive oil, soybean oil, rapeseed oil, almond oil, jojoba oil, orange oil, wheat germ oil, peach seed oil and the liquid components of coconut oil. Other triglyceride oils such as the liquid portions of beef tallow and synthetic triglyceride oils are also suitable.
• Liquid paraffin oils, isoparaffin oils and synthetic hydrocarbons and di-n-alkyl ethers with a total of between 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n- nonyl ether, di-n-undecyl ether, di-n-dodecyl ether, n-hexyl-n-octyl ether, n-octyl-n-decyl ether, n-decyl-n-undecyl ether, n-undecyl-n-dodecyl ether and n-hexyl n-undecyl ether and di-tert-butyl ether, di-isopentyl ether, di-3-ethyldecyl ether, tert-butyl-n-octyl ether, isopentyl-n-octyl ether and 2-methyl-pentyl-n-octyl ether. The compounds are available as commercial products 1,3-di- (2-ethyl-hexyl) -cyclohexane (Cetiol ^® S), and di-n-octyl ether (Cetiol ^® OE) may be preferred.
• - ester oils. Ester oils are understood to be the esters of C ₆ -C ₃₀ fatty acids with C ₂ -C ₃₀ fatty alcohols. The monoesters of fatty acids with alcohols having 2 to 24 carbon atoms are preferred. Examples of fatty acid constituents used in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linoleic acid, arenachic acid, araoleic acid, araoleic acid, araoleic acid, araelostic acid, elaostelic acid, elaoleic acid, elaostic acid, elaostic acid Erucic acid and its technical mixtures, which occur, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxosynthesis or in the dimerization of unsaturated fatty acids. Examples of the fatty alcohol fractions in the ester oils are isopropyl alcohol, capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaolol alcohol, elaolyl alcohol, elaolyl alcohol chyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, which are obtained, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from Roelen's oxosynthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols. According to the invention particularly preferably isopropyl myristate (IPM Rilanit ^®), isononanoic acid C16-18 alkyl ester (Cetiol ^® SN), 2-ethylhexyl palmitate (Cegesoft ^® 24), stearic acid-2-ethylhexyl ester (Cetiol ^® 868), cetyl oleate, glycerol tricaprylate, Kokosfettalkohol- caprinate / caprylate (Cetiol ^® LC), n-butyl stearate, olerlerucate (Cetiol ^® J 600), isopropyl palmitate (Rilanit ^® IPP), oleyl oleates (cetiol, lauric acid hexyl ester (Cetiol ^® A), di-n-butyl adipate (Cetiol ^® B ), Myristyl myristate (Cetiol ^® MM), cetearyl isononanoate (Cetiol ^® SN), oleic acid decyl ester (Cetiol ^® V).
• - Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecylacelate as well as diol esters such as ethylene glycol dioleate, ethylene glycol di-isotridecanoate, propylene glycol di (2 -ethylhexanoate), propylene glycol di-isostearate, propylene glycol di-pelargonate, butanediol di-isostearate, neopentyl glycol dicaprylate,
• - Symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, for example described in the DE-OS 197 56 454 , Glycerol carbonate or dicaprylyl carbonate (Cetiol ^® CC),
• Trifatty acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol,
• - Fatty acid partial glycerides are monoglycerides, diglycerides and their technical mixtures. When using technical products, small quantities of triglycerides may still be present due to the manufacturing process. The partial glycerides preferably follow the formula (D4-I),
  
  in which R ¹ , R ² and R ³ independently of one another represent hydrogen or a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22, preferably 12 to 18, carbon atoms, with the proviso that at least one of these groups represents a Acyl radical and at least one of these groups represents hydrogen. The sum (m + n + q) represents 0 or numbers from 1 to 100, preferably 0 or 5 to 25. R ¹ preferably represents an acyl radical and R ² and R ^{3 represents} hydrogen and the sum (m + n + q) is 0. Typical examples are mono- and / or diglycerides based on caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linoleic acid , Elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures. Oleic acid monoglycerides are preferably used.

The Amount of natural and synthetic cosmetic oil body in the used according to the invention Average is usually 0.1-30 % By weight, based on the total agent, preferably 0.1-20% by weight, and in particular 0.1-15 Wt .-%.

The Total amount of oil and fat components in the agents according to the invention is usually 0.5-75 % By weight, based on the total average. Amounts of 0.5–35% by weight are preferred according to the invention.

The combination of the combination according to the invention with surfactants (E) has also proven to be advantageous. In a further preferred embodiment, the agents used according to the invention contain surfactants. The term surfactants is understood to mean surface-active substances which form adsorption layers on surfaces and interfaces or which can aggregate in volume phases to form micelle colloids or lyotropic mesophases. A distinction is made between anionic surfactants consisting of a hydrophobic residue and a negatively charged hydrophilic head group, amphoteric surfactants, which carry both a negative and a compensating positive charge, cationic surfactants, which in addition to a hydrophobic residue have a positively charged hydrophilic group, and nonionic surfactants, which have no charges but strong dipole moments and are highly hydrated in aqueous solution. Further definitions and properties of surfactants can be found in "H.-D. Dörfler, interfacial and colloid chemistry, VCH Verlagsgesellschaft mbH. Weinheim, 1994". The definition given above can be found from p. 190 in this publication.

• – lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen (Seifen),
• – Ethercarbonsäuren der Formel R-O-(CH₂-CH₂O)_x-CH₂-COOH, in der R eine lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 16 ist,
• – Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acyltauride mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acylisethionate mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Sulfobernsteinsäuremono- und -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen,
• – lineare Alkansulfonate mit 8 bis 24 C-Atomen,
• – lineare Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen,
• – Alpha-Sulfofettsäuremethylester von Fettsäuren mit 8 bis 30 C-Atomen,
• – Alkylsulfate und Alkylpolyglykolethersulfate der Formel R-O(CH₂-CH₂O)_x-OSO₃H, in der R eine bevorzugt lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 12 ist,
• – Gemische oberflächenaktiver Hydroxysulfonate gemäß DE-A-37 25 030 ,
• – sulfatierte Hydroxyalkylpolyethylen- und/oder Hydroxyalkylenpropylenglykolether gemäß DE-A-37 23 354 ,
• – Sulfonate ungesättigter Fettsäuren mit 8 bis 24 C-Atomen und 1 bis 6 Doppelbindungen gemäß DE-A-39 26 344 ,
• – Ester der Weinsäure und Zitronensäure mit Alkoholen, die Anlagerungsprodukte von etwa 2–15 Molekülen Ethylenoxid und/oder Propylenoxid an Fettalkohole mit 8 bis 22 C-Atomen darstellen,
• – Alkyl- und/oder Alkenyletherphosphate der Formel (E1-I),
  
  in der R¹ bevorzugt für einen aliphatischen Kohlenwasserstoffrest mit 8 bis 30 Kohlenstoffatomen, R² für Wasserstoff, einen Rest (CH₂CH₂O)_nR¹ oder X, n für Zahlen von 1 bis 10 und X für Wasserstoff, ein Alkali- oder Erdalkalimetall oder NR³R⁴R⁵R⁶, mit R³ bis R⁶ unabhängig voneinander stehend für Wasserstoff oder einen C1 bis C4 – Kohlenwasserstoffrest, steht,
• – sulfatierte Fettsäurealkylenglykolester der Formel (E1-II) R⁷CO(AlkO)_nSO₃M (E1-II)in der R⁷CO- für einen linearen oder verzweigten, aliphatischen, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 C-Atomen, Alk für CH₂CH₂, CHCH₃CH₂ und/oder CH₂CHCH₃, n für Zahlen von 0,5 bis 5 und M für ein Kation steht, wie sie in der DE-OS 197 36 906.5 beschrieben sind,
• – Monoglyceridsulfate und Monoglyceridethersulfate der Formel (E1-III)
  
  in der R⁸CO für einen linearen oder verzweigten Acylrest mit 6 bis 22 Kohlenstoffatomen, x, y und z in Summe für 0 oder für Zahlen von 1 bis 30, vorzugsweise 2 bis 10, und X für ein Alkali- oder Erdalkalimetall steht. Typische Beispiele für im Sinne der Erfindung geeignete Monoglycerid(ether)sulfate sind die Umsetzungsprodukte von Laurinsäuremonoglycerid, Kokosfettsäuremonoglycerid, Palmitinsäuremonoglycerid, Stearinsäuremonoglycerid, Ölsäuremonoglycerid und Talgfettsäuremonoglycerid sowie deren Ethylenoxidaddukte mit Schwefeltrioxid oder Chlorsulfonsäure in Form ihrer Natriumsalze. Vorzugsweise werden Monoglyceridsulfate der Formel (E1-III) eingesetzt, in der R⁸CO für einen linearen Acylrest mit 8 bis 18 Kohlenstoffatomen steht, wie sie beispielsweise in der EP-B1 0 561 825 , der EP-B1 0 561 999 , der DE-A1 42 04 700 oder von A.K.Biswas et al. in J.Am.Oil.Chem.Soc. 37, 171 (1960) und F.U.Ahmed in J.Am.Oil.Chem.Soc. 67, 8 (1990) beschrieben worden sind,
• – Amidethercarbonsäuren wie sie in der EP 0 690 044 beschrieben sind,
• – Kondensationsprodukte aus C₈-C₃₀-Fettalkoholen mit Proteinhydrolysaten und/oder Aminosäuren und deren Derivaten,welche dem Fachmann als Eiweissfettsäurekondensate bekannt sind, wie beispielsweise die Lamepon^®-Typen, Gluadin^®-Typen, Hostapon^® KCG oder die Amisoft^®-Typen.

Suitable anionic surfactants (E1) in preparations according to the invention are all anionic surface-active substances suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. B. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups can be contained in the molecule. Examples of suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts with 2 to 4 carbon atoms in the alkanol group,

• - linear and branched fatty acids with 8 to 30 carbon atoms (soaps),
• Ether carboxylic acids of the formula RO- (CH ₂ -CH ₂ O) _x -CH ₂ -COOH, in which R is a linear alkyl group with 8 to 30 C atoms and x = 0 or 1 to 16,
• Acyl sarcosides with 8 to 24 carbon atoms in the acyl group,
• Acyl taurides with 8 to 24 carbon atoms in the acyl group,
• Acyl isethionates with 8 to 24 carbon atoms in the acyl group,
• Monosulfonic acid and dialkyl sulfosuccinates with 8 to 24 carbon atoms in the alkyl group and mono-alkyl polyoxyethyl sulfosuccinates with 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups,
• Linear alkanesulfonates with 8 to 24 carbon atoms,
• - linear alpha olefin sulfonates with 8 to 24 carbon atoms,
• - Alpha-sulfofatty acid methyl esters of fatty acids with 8 to 30 carbon atoms,
• Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH ₂ -CH ₂ O) _x -OSO ₃ H, in which R is a preferably linear alkyl group with 8 to 30 C atoms and x = 0 or 1 to 12,
• - Mixtures of surface-active hydroxysulfonates according to DE-A-37 25 030 .
• - Sulphated hydroxyalkyl polyethylene and / or hydroxyalkylene propylene glycol ether according to DE-A-37 23 354 .
• - Sulfonates of unsaturated fatty acids with 8 to 24 carbon atoms and 1 to 6 double bonds according to DE-A-39 26 344 .
• Esters of tartaric acid and citric acid with alcohols, which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols with 8 to 22 carbon atoms,
• Alkyl and / or alkenyl ether phosphates of the formula (E1-I),
  
  in which R ^{1 is} preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R ^{2 is} hydrogen, a radical (CH ₂ CH ₂ O) _n R ¹ or X, n is a number from 1 to 10 and X is hydrogen, an alkali or alkaline earth metal or NR ³ R ⁴ R ⁵ R ⁶ , with R ³ to R ⁶ independently of one another being hydrogen or a C1 to C4 hydrocarbon radical,
• Sulfated fatty acid alkylene glycol esters of the formula (E1-II) R ⁷ CO (AlkO) _n SO ₃ M (E1-II) in the R ⁷ CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, Alk for CH ₂ CH ₂ , CHCH ₃ CH ₂ and / or CH ₂ CHCH ₃ , n for numbers from 0.5 to 5 and M stands for a cation, as in the DE-OS 197 36 906.5 are described
• - Monoglyceride sulfates and monoglyceride ether sulfates of the formula (E1-III)
  
  in which R ⁸ CO stands for a linear or branched acyl radical with 6 to 22 carbon atoms, x, y and z in total for 0 or for numbers from 1 to 30, preferably 2 to 10, and X stands for an alkali or alkaline earth metal. Typical examples of monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts. Monoglyceride sulfates of the formula (E1-III) are preferably used, in which R ⁸ CO represents a linear acyl radical having 8 to 18 carbon atoms, as described, for example, in EP-B1 0 561 825 , the EP-B1 0 561 999 , the DE-A1 42 04 700 or by AKBiswas et al. in J.Am.Oil.Chem.Soc. 37, 171 (1960) and FUAhmed in J.Am.Oil.Chem.Soc. 67, 8 (1990),
• - Amidether carboxylic acids as in the EP 0 690 044 are described
• - Condensation products from C ₈ -C ₃₀ fatty alcohols with protein hydrolyzates and / or amino acids and their derivatives, which are known to those skilled in the art as protein fatty acid condensates, such as the Lamepon ^® types, Gluadin ^® types, Hostapon ^® KCG or the Amisoft ^® types ,

preferred Anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids with 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule, sulfosuccinic and dialkyl esters with 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid mono-alkyl polyoxyethyl ester with 8 to 18 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, monoglycer disulfates, Alkyl and alkenyl ether phosphates and protein fatty acid condensates.

Zwitterionic surfactants (E2) are those surface-active compounds which carry at least one quaternary ammonium group and at least one -COO ^(-) - or -SO ₃ ^(-) group in the molecule. Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example coconut alkyl dimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example coconut acylaminopropyldimethylammonium glycinate, and 2-alkyl-3 -carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate. A preferred zwitterionic surfactant is the fatty acid amide derivative known under the INCI name Cocamidopropyl Betaine.

Ampholytic surfactants (E3) are understood to mean those surface-active compounds which, in addition to a C ₈ -C ₂₄ -alkyl or -acyl group, contain at least one free amino group and at least one -COOH or -SO ₃ H group in the molecule and for the formation of internal ones Salts are capable. Examples of suitable ampholytic surfactants are N-alkylglycine, N-alkylpropionic acid, N-alkylaminobutyric acid, N-alkyliminodipropionic acid, N-hydroxyethyl-N-alkylamidopropylglycine, N-alkyltaurine, N-alkylsarcosine, 2-alkylaminopropionic acid and alkylaminoacetic acid each with about 8 to 24 C. Atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C ₁₂ -C ₁₈ acyl sarcosine.

• – Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – mit einem Methyl- oder C₂-C₆-Alkylrest endgruppenverschlossene Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe, wie beispielsweise die unter den Verkaufsbezeichnungen Dehydol^® LS, Dehydol^® LT (Cognis) erhältlichen Typen,
• – C₁₂-C₃₀-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Glycerin,
• – Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl,
• – Polyolfettsäureester, wie beispielsweise das Handelsprodukt Hydagen^® HSP (Cognis) oder Sovermol – Typen (Cognis),
• – alkoxilierte Triglyceride,
• – alkoxilierte Fettsäurealkylester der Formel (E4-I) R¹CO-(OCH₂CHR²)_wOR³ (E4-I)in der R¹CO für einen linearen oder verzweigten, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 Kohlenstoffatomen, R² für Wasserstoff oder Methyl, R³ für lineare oder verzweigte Alkylreste mit 1 bis 4 Kohlenstoffatomen und w für Zahlen von 1 bis 20 steht,
• – Aminoxide,
• – Hydroxymischether, wie sie beipielsweise in der DE-OS 19738866 beschrieben sind,
• – Sorbitanfettsäureester und Anlagerungeprodukte von Ethylenoxid an Sorbitanfettsäureester wie beispielsweise die Polysorbate,
• – Zuckerfettsäureester und Anlagerungsprodukte von Ethylenoxid an Zuckerfettsäureester,
• – Anlagerungsprodukte von Ethylenoxid an Fettsäurealkanolamide und Fettamine,
• – Zuckertenside vom Typ der Alkyl- und Alkenyloligoglykoside gemäß Formel (E4-II), R⁴O-[G]_p (E4-II)in der R⁴ für einen Alkyl- oder Alkenylrest mit 4 bis 22 Kohlenstoffatomen, G für einen Zuckerrest mit 5 oder 6 Kohlenstoffatomen und p für Zahlen von 1 bis 10 steht. Sie können nach den einschlägigen Verfahren der präparativen organischen Chemie erhalten werden. Stellvertretend für das umfangreiche Schrifttum sei hier auf die Über sichtsarbeit von Biermann et al. in Starch/Stärke 45, 281 (1993), B. Salka in Cosm.Toil. 108, 89 (1993) sowie J. Kahre et al. in SÖFW-Journal Heft 8, 598 (1995) verwiesen. Die Alkyl- und Alkenyloligoglykoside können sich von Aldosen bzw. Ketosen mit 5 oder 6 Kohlenstoffatomen, vorzugsweise von Glucose, ableiten. Die bevorzugten Alkyl- und/oder Alkenyloligoglykoside sind somit Alkyl- und/oder Alkenyloligoglucoside. Die Indexzahl p in der allgemeinen Formel (E4-II) gibt den Oligomerisierungsgrad (DP), d. h. die Verteilung von Mono- und Oligoglykosiden an und steht für eine Zahl zwischen 1 und 10. Während p im einzelnen Molekül stets ganzzahlig sein muss und hier vor allem die Werte p = 1 bis 6 annehmen kann, ist der Wert p für ein bestimmtes Alkyloligoglykosid eine analytisch ermittelte rechnerische Größe, die meistens eine gebrochene Zahl darstellt. Vorzugsweise werden Alkyl- und/oder Alkenyloligoglykoside mit einem mittleren Oligomerisierungsgrad p von 1,1 bis 3,0 eingesetzt. Aus anwendungstechnischer Sicht sind solche Alkyl- und/oder Alkenyloligoglykoside bevorzugt, deren Oligomerisierungsgrad kleiner als 1,7 ist und insbesondere zwischen 1,2 und 1,4 liegt. Der Alkyl- bzw. Alkenylrest R⁴ kann sich von primären Alkoholen mit 4 bis 11, vorzugsweise 8 bis 10 Kohlenstoffatomen ableiten. Typische Beispiele sind Butanol, Capronalkohol, Caprylalkohol, Caprinalkohol und Undecylalkohol sowie deren technische Mischungen, wie sie beispielsweise bei der Hydrierung von technischen Fettsäuremethylestern oder im Verlauf der Hydrierung von Aldehyden aus der Roelen'schen Oxosynthese erhalten werden. Bevorzugt sind Alkyloligoglucoside der Kettenlänge C₈-C₁₀ (DP = 1 bis 3), die als Vorlauf bei der destillativen Auftrennung von technischem C₈-C₁₈-Kokosfettalkohol anfallen und mit einem Anteil von weniger als 6 Gew.-% C₁₂-Alkohol verunreinigt sein können sowie Alkyloligoglucoside auf Basis technischer C_9/11-Oxoalkohole (DP = 1 bis 3). Der Alkyl- bzw. Alkenylrest R¹⁵ kann sich ferner auch von primären Alkoholen mit 12 bis 22, vorzugsweise 12 bis 14 Kohlenstoffatomen ableiten. Typische Beispiele sind Laurylalkohol, Myristylalkohol, Cetylalkohol, Palmoleylalkohol, Stearylalkohol, Isostearylalkohol, Oleylalkohol, Elaidylalkohol, Petroselinylalkohol, Arachylalkohol, Gadoleylalkohol, Behenylalkohol, Erucylalkohol, Brassidylalkohol sowie deren technische Gemische, die wie oben beschrieben erhalten werden können. Bevorzugt sind Alkyloligoglucoside auf Basis von gehärtetem C_12/14-Kokosalkohol mit einem DP von 1 bis 3.
• – Zuckertenside vom Typ der Fettsäure-N-alkylpolyhydroxyalkylamide, ein nichtionisches Tensid der Formel (E4-III), R⁵CO-NR⁶-[Z] (E4-III)in der R⁵CO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen, R⁶ für Wasserstoff, einen Alkyl- oder Hydroxyalkylrest mit 1 bis 4 Kohlenstoffatomen und [Z] für einen linearen oder verzweigten Polyhydroxyalkylrest mit 3 bis 12 Kohlenstoffatomen und 3 bis 10 Hydroxylgruppen steht. Bei den Fettsäure-N-alkylpolyhydroxyalkylamiden handelt es sich um bekannte Stoffe, die üblicherweise durch reduktive Aminierung eines reduzierenden Zuckers mit Ammoniak, einem Alkylamin oder einem Alkanolamin und nachfolgende Acylierung mit einer Fettsäure, einem Fettsäurealkylester oder einem Fettsäurechlorid erhalten werden können. Hinsichtlich der Verfahren zu ihrer Herstellung sei auf die US-Patentschriften US 1,985,424 , US 2,016,962 und US 2,703,798 sowie die Internationale Patentanmeldung WO 92/06984 verwiesen. Eine Übersicht zu diesem Thema von H.Kelkenberg findet sich in Tens. Surf. Det. 25, 8 (1988). Vorzugsweise leiten sich die Fettsäure-N-alkylpolyhydroxyalkylamide von reduzierenden Zuckern mit 5 oder 6 Kohlenstoffatomen, insbesondere von der Glucose ab. Die bevorzugten Fettsäure-N-alkylpolyhydroxyalkylamide stellen daher Fettsäure-N-alkylglucamide dar, wie sie durch die Formel (E4-IV) wiedergegeben werden: R⁷CO-NR⁸-CH₂-(CH-OH)₄-CH₂OH (E4-IV) Vorzugsweise werden als Fettsäure-N-alkylpolyhydroxyalkylamide Glucamide der Formel (E4-IV) eingesetzt, in der R⁸ für Wasserstoff oder eine Alkylgruppe steht und R⁷CO für den Acylrest der Capronsäure, Caprylsäure, Caprinsäure, Laurinsäure, Myristinsäure, Palmitinsäure, Palmoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Arachinsäure, Gadoleinsäure, Behensäure oder Erucasäure bzw. derer technischer Mischungen steht. Besonders bevorzugt sind Fettsäure-N-alkylglucamide der Formel (E4-IV), die durch reduktive Aminierung von Glucose mit Methylamin und anschließende Acylierung mit Laurinsäure oder C12/14-Kokosfettsäure bzw. einem entsprechenden Derivat erhalten werden. Weiterhin können sich die Polyhydroxyalkylamide auch von Maltose und Palatinose ableiten.

Nonionic surfactants (E4) contain, for example, a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups as the hydrophilic group. Such connections are, for example

• - Adducts of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with linear and branched fatty alcohols with 8 to 30 C atoms, with fatty acids with 8 to 30 C atoms and with alkylphenols with 8 to 15 C atoms in the alkyl group,
• Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide end-capped with a methyl or C ₂ -C ₆ -alkyl radical to linear and branched fatty alcohols having 8 to 30 C atoms, to fatty acids having 8 to 30 C atoms atoms and onto alkylphenols having 8 to 15 carbon atoms in the alkyl group, such as the type available under the commercial names Dehydol ^® LS, Dehydol ^® LT (Cognis),
• C ₁₂ -C ₃₀ fatty acid monoesters and diesters of adducts of 1 to 30 moles of ethylene oxide with glycerol,
• - adducts of 5 to 60 moles of ethylene oxide with castor oil and hardened castor oil,
• - polyol, such as the commercially available product ^® Hydagen HSP (Cognis) or Sovermol - types (Cognis),
• - alkoxylated triglycerides,
• Alkoxylated fatty acid alkyl esters of the formula (E4-I) R ¹ CO- (OCH ₂ CHR ² ) _w OR ³ (E4-I) in which R ¹ CO is a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, R ^{2 is} hydrogen or methyl, R ^{3 is a} linear or branched alkyl radical having 1 to 4 carbon atoms and w is a number from 1 to 20 stands,
• Amine oxides,
• - Hydroxy mixed ethers, such as those in the DE-OS 19738866 are described
• - Sorbitan fatty acid esters and addition products of ethylene oxide with sorbitan fatty acid esters as in for example the polysorbates,
• - sugar fatty acid esters and adducts of ethylene oxide with sugar fatty acid esters,
• - adducts of ethylene oxide with fatty acid alkanolamides and fatty amines,
• Sugar surfactants of the alkyl and alkenyl oligoglycoside type according to formula (E4-II), R ⁴ O- [G] _p (E4-II) in which R ^{4 represents} an alkyl or alkenyl radical having 4 to 22 carbon atoms, G represents a sugar radical having 5 or 6 carbon atoms and p represents numbers from 1 to 10. They can be obtained according to the relevant procedures in preparative organic chemistry. Representative of the extensive literature here is the review by Biermann et al. in Starch /force 45, 281 (1993), B. Salka in Cosm.Toil. 108, 89 (1993) and J. Kahre et al. in SÖFW-Journal issue 8, 598 (1995). The alkyl and alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably from glucose. The preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides. The index number p in the general formula (E4-II) indicates the degree of oligomerization (DP), ie the distribution of mono- and oligoglycosides, and stands for a number between 1 and 10. While p in the individual molecule must always be an integer and here can assume all the values p = 1 to 6, the value p for a certain alkyl oligoglycoside is an analytically determined arithmetic parameter, which usually represents a fractional number. Alkyl and / or alkenyl oligoglycosides with an average degree of oligomerization p of 1.1 to 3.0 are preferably used. From an application point of view, preference is given to those alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and is in particular between 1.2 and 1.4. The alkyl or alkenyl radical R ⁴ can be derived from primary alcohols having 4 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, capronic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as are obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's oxosynthesis. Alkyl oligoglucosides of chain length C ₈ -C ₁₀ (DP = 1 to 3) are preferred, which are obtained as a preliminary step in the separation of technical C ₈ -C ₁₈ coconut fatty alcohol by distillation and with a proportion of less than 6% by weight of C ₁₂ - Alcohol can be contaminated and alkyl oligoglucosides based on technical C _9/11 oxo alcohols (DP = 1 to 3). The alkyl or alkenyl radical R ¹⁵ can also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms. Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and their technical mixtures, which can be obtained as described above. Alkyl oligoglucosides based on hardened C _12/14 coconut alcohol with a DP of 1 to 3 are preferred.
• Sugar surfactants of the fatty acid N-alkyl polyhydroxyalkyl amide type, a nonionic surfactant of the formula (E4-III), R ⁵ CO-NR ⁶ - [Z] (E4-III) in which R ⁵ CO for an aliphatic acyl radical having 6 to 22 carbon atoms, R ⁶ for hydrogen, an alkyl or hydroxyalkyl radical with 1 to 4 carbon atoms and [Z] for a linear or branched polyhydroxyalkyl radical with 3 to 12 carbon atoms and 3 to 10 hydroxyl groups stands. The fatty acid N-alkyl polyhydroxyalkylamides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride. With regard to the processes for their production, reference is made to the US patents US 1,985,424 . US 2,016,962 and US 2,703,798 and international patent application WO 92/06984. An overview of this topic by H. Kelkenberg can be found in Tens. Surf. Det. 25, 8 (1988). The fatty acid N-alkylpolyhydroxyalkylamides are preferably derived from reducing sugars having 5 or 6 carbon atoms, in particular from glucose. The preferred fatty acid N-alkylpolyhydroxyalkylamides are therefore fatty acid N-alkylglucamides, as represented by the formula (E4-IV): R ⁷ CO-NR ⁸ -CH ₂ - (CH-OH) ₄ -CH ₂ OH (E4-IV) The preferred fatty acid N-alkylpolyhydroxyalkylamides used are glucamides of the formula (E4-IV) in which R ^{8 is} hydrogen or an alkyl group and R ⁷ CO is the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, Stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, arachic acid, gadolein acid, behenic acid or erucic acid or their technical mixtures. Fatty acid N-alkylglucamides of the formula (E4-IV) which are obtained by reductive amination of glucose with methylamine and subsequent acylation with lauric acid or C12 / 14 coconut fatty acid or a corresponding derivative are particularly preferred. Furthermore, the polyhydroxyalkylamides can also be derived from maltose and palatinose.

As preferred nonionic surfactants have been the alkylene oxide addition products to saturated linear Fatty alcohols and fatty acids with 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Preparations with excellent properties are also used obtained when used as nonionic surfactants fatty acid esters of ethoxylated glycerin.

This Connections are identified by the following parameters. The alkyl radical R contains 6 to 22 carbon atoms and can be both linear and branched his. Primary are preferred linear and 2-methyl branched aliphatic radicals. Such Examples of alkyl radicals are 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. 1-Octyl, 1-decyl, 1-lauryl, 1-myristyl. When using so-called "oxo alcohols" predominate as starting materials Compounds with an odd number of carbon atoms in the alkyl chain.

Farther the most preferred nonionic surfactants are sugar surfactants. these can in those used according to the invention Agents preferably in amounts of 0.1-20 wt .-%, based on the entire means. Amounts of 0.5-15% by weight are preferred, and amounts of 0.5-7.5% by weight are very particularly preferred.

at the compounds with alkyl groups used as surfactant can are each a uniform substance. However, it is in usually preferred in the manufacture of these substances from native vegetable or animal raw materials, so that one Mixtures of substances with different raw materials dependent alkyl chain lengths receives.

at the surfactants, the adducts of ethylene and / or propylene oxide of fatty alcohols or derivatives of these addition products, can both products with a "normal" homolog distribution as well as those with a narrow homolog distribution become. Under "normal" homolog distribution are understood as mixtures of homologues that are used in the Reaction of fatty alcohol and alkylene oxide using alkali metals, Alkali metal hydroxides or alkali metal alcoholates as catalysts receives. On the other hand, narrow homolog distributions are obtained if, for example Hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates can be used as catalysts. The use of products with a narrow homolog distribution can be preferred.

The Surfactants (E) are used in amounts of 0.1-45% by weight, preferably 0.5-30% by weight. and very particularly preferably from 0.5 to 25% by weight, based on the entire used according to the invention Means used.

Can be used according to the invention are also cationic surfactants (E5). Typical examples of cationic Surfactants are, in particular, tetraalkylammonium compounds amidoamines or ester quats. Preferred quaternary ammonium compounds are Ammonium halides, in particular chlorides and bromides, such as alkyltrimethylammonium chlorides, Dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, Distearyldimethylammonium chloride, lauryldimethylammonium chloride, Lauryldimethylbenzylammonium chloride, tricetylmethylammonium chloride, Hydroxyethyl Hydroxycetyl Dimmonium Chloride as well as those among the INCI names Quaternium-27 and Quaternium-83 known imidazolium compounds. The long alkyl chains of the above surfactants are preferred 10 to 18 carbon atoms.

at Esterquats are known substances that are both at least an ester function as well as at least one quaternary ammonium group included as a structural element.

in der R¹⁴CO für einen Acylrest mit 6 bis 22 Kohlenstoffatomen, R¹⁵ und R¹⁶ unabhängig voneinander für Wasserstoff oder R¹⁴CO, R¹⁵ für einen Alkykest mit 1 bis 4 Kohlenstoffatomen oder eine (CH₂CH₂O)_m4H-Gruppe, ml, m2 und m3 in Summe für 0 oder Zahlen von 1 bis 12, m4 für Zahlen von 1 bis 12 und Y für Halogenid, Alkylsulfat oder Alkylphosphat steht. Typische Beispiele für Esterquats, die im Sinne der Erfindung Verwendung finden können, sind Produkte auf Basis von Capronsäure, Caprylsäure, Caprinsäure, Laurinsäure, Myristinsäure, Palmitinsäure, Isostearinsäure, Stearinsäure, Ölsäure, Elaidinsäure, Arachinsäure, Behensäure und Erucasäure sowie deren technische Mischungen, wie sie beispielsweise bei der Druckspaltung natürlicher Fette und Öle anfallen. Vorzugsweise werden technische C_12/18-Kokosfettsäuren und insbesondere teilgehärtete C_16/18-Talg- bzw. Palmfettsäuren sowie elaidinsäurereiche C_16/18-Fettsäureschnitte eingesetzt. Zur Herstellung der quaternierten Ester können die Fettsäuren und das Triethanolamin im molaren Verhältnis von 1,1 : 1 bis 3 : 1 eingesetzt werden. Im Hinblick auf die anwendungstechnischen Eigenschaften der Esterquats hat sich ein Einsatzverhältnis von 1,2 : 1 bis 2,2 : 1, vorzugsweise 1,5 : 1 bis 1,9 : 1 als besonders vorteilhaft erwiesen. Die bevorzugten Esterquats stellen technische Mischungen von Mono-, Di- und Triestern mit einem durchschnittlichen Veresterungsgrad von 1,5 bis 1,9 dar und leiten sich von technischer C_16/18- Talg- bzw. Palmfettsäure (Iodzahl 0 bis 40) ab. Aus anwendungstechnischer Sicht haben sich quaternierte Fettsäuretriethanolaminestersalze der Formel (E5-I) als besonders vorteilhaft erwiesen, in der R¹⁴CO für einen Acylrest mit 16 bis 18 Kohlenstoffatomen, R¹⁵ für R¹⁵CO, R¹⁶ für Wasserstoff, R¹⁷ für eine Methylgruppe, ml, m2 und m3 für 0 und Y für Methylsulfat steht.These are, for example, quaternized fatty acid triethanolamine ester salts of the formula (E5-I),

in which R ¹⁴ CO represents an acyl radical with 6 to 22 carbon atoms, R ¹⁵ and R ¹⁶ independently of one another for hydrogen or R ¹⁴ CO, R ^{15 represents} an alkyl radical with 1 to 4 carbon atoms or a (CH ₂ CH ₂ O) _m4 H- Group, ml, m2 and m3 in total for 0 or numbers from 1 to 12, m4 for numbers from 1 to 12 and Y for halide, alkyl sulfate or alkyl phosphate. Typical examples of ester quats that can be used in the context of the invention are products based on caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, isostearic acid, stearic acid, oleic acid, elaidic acid, arachic acid, behenic acid and erucic acid and their technical mixtures, such as they occur, for example, in the pressure splitting of natural fats and oils. Technical C _12/18 coconut _fatty acids and in particular partially hardened C _16/18 tallow or palm fatty acids as well as C _16/18 fatty acid _cuts rich in elaidic acid are preferably used. The fatty acids and the triethanolamine can be used in a molar ratio of 1.1: 1 to 3: 1 to produce the quaternized esters. With regard to the application properties of the ester quats, an application ratio of 1.2: 1 to 2.2: 1, preferably 1.5: 1 to 1.9: 1, has proven to be particularly advantageous. The preferred esterquats are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 to 1.9 and are derived from technical C _16/18 - tallow or palm fatty acid (iodine number 0 to 40). From an application point of view, quaternized fatty acid triethanolamine ester salts of the formula (E5-I) have proven to be particularly advantageous in which R ¹⁴ CO for an acyl radical having 16 to 18 carbon atoms, R ¹⁵ for R ¹⁵ CO, R ¹⁶ for hydrogen, R ¹⁷ for a methyl group , ml, m2 and m3 for 0 and Y for methyl sulfate.

in der R¹⁸CO für einen Acylrest mit 6 bis 22 Kohlenstoffatomen, R¹⁹ für Wasserstoff oder R¹⁸CO, R²⁰ und R²¹ unabhängig voneinander für Alkylreste mit 1 bis 4 Kohlenstoffatomen, m5 und m6 in Summe für 0 oder Zahlen von 1 bis 12 und Y wieder für Halogenid, Alkylsulfat oder Alkylphosphat steht.In addition to the quaternized fatty acid triethanolamine ester salts, quaternized ester salts of fatty acids with diethanolalkylamines of the formula (E5-II) are also suitable as esterquats.

in which R ¹⁸ CO for an acyl radical with 6 to 22 carbon atoms, R ¹⁹ for hydrogen or R ¹⁸ CO, R ²⁰ and R ²¹ independently of one another for alkyl radicals with 1 to 4 carbon atoms, m5 and m6 in total for 0 or numbers from 1 to 12 and Y again represents halide, alkyl sulfate or alkyl phosphate.

in der R²²CO für einen Acylrest mit 6 bis 22 Kohlenstoffatomen, R²³ für Wasserstoff oder R²²CO, R²⁴, R²⁵ und R²⁶ unabhängig voneinander für Alkylreste mit 1 bis 4 Kohlenstoffatomen, m7 und m8 in Summe für 0 oder Zahlen von 1 bis 12 und X wieder für Halogenid, Alkylsulfat oder Alkylphosphat steht.Finally, the quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines of the formula (E5-III) should be mentioned as a further group of suitable ester quats.

in which R ²² CO for an acyl radical with 6 to 22 carbon atoms, R ²³ for hydrogen or R ²² CO, R ²⁴ , R ²⁵ and R ²⁶ independently of one another for alkyl radicals with 1 to 4 carbon atoms, m7 and m8 in total for 0 or numbers from 1 to 12 and X again represents halide, alkyl sulfate or alkyl phosphate.

in der R²⁷CO für einen Acylrest mit 6 bis 22 Kohlenstoffatomen, R²⁸ für Wasserstoff oder R²⁷CO, R²⁹ und R³⁰ unabhängig voneinander für Alkylreste mit 1 bis 4 Kohlenstoffatomen und Y wieder für Halogenid, Alkylsulfat oder Alkylphosphat steht. Derartige Amidesterquats sind beispielsweise unter der Marke Incroquat^® (Croda) im Markt erhältlich.Finally, as ester quats there are also substances in which the ester is bound by an amide bond is replaced and which preferably follow the formula (E5-IV) based on diethylenetriamine,

in which R ²⁷ CO represents an acyl radical with 6 to 22 carbon atoms, R ²⁸ for hydrogen or R ²⁷ CO, R ²⁹ and R ³⁰ independently of one another for alkyl radicals with 1 to 4 carbon atoms and Y again for halide, alkyl sulfate or alkyl phosphate. Such amide ester are for example available under the brand Incroquat ^® (Croda) market.

Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines. Such products are sold, for example, under the trademarks Stepantex ^® , Dehyquart ^® and Armocare ^® . The products Armocare ^® VGH-70, an N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, as well as Dehyquart ^® F-75, Dehyquart ^® C-4046, Dehyquart ^® L80 and Dehyquart ^® AU-35 are examples of such esterquats.

The alkylamidoamines are usually produced by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines. An inventively particularly suitable compound from this group is that available under the name Tegoamid ^® S18 commercially stearamidopropyl dimethylamine.

The Cationic surfactants (E5) are used in the invention Agents preferably in amounts of 0.05 to 10 wt .-%, based on all the means included. Amounts of 0.1 to 5 wt .-% are particularly preferred.

anionic, nonionic, zwitterionic and / or amphoteric surfactants and their mixtures can preferred according to the invention his.

• – Anlagerungsprodukte von 4 bis 30 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare Fettalkohole mit 8 bis 22 C-Atomen, an Fettsäuren mit 12 bis 22 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – C₁₂-C₂₂-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Polyole mit 3 bis 6 Kohlenstoffatomen, insbesondere an Glycerin,
• – Ethylenoxid- und Polyglycerin-Anlagerungsprodukte an Methylglucosid-Fettsäureester, Fettsäurealkanolamide und Fettsäureglucamide,
• – C₈-C₂₂-Alkylmono- und -oligoglycoside und deren ethoxylierte Analoga, wobei Oligomerisierungsgrade von 1,1 bis 5, insbesondere 1,2 bis 2,0, und Glucose als Zuckerkomponente bevorzugt sind,
• – Gemische aus Alkyl-(oligo)-glucosiden und Fettalkoholen zum Beispiel das im Handel erhältliche Produkt Montanov^®68,
• – Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl,
• – Partialester von Polyolen mit 3–6 Kohlenstoffatomen mit gesättigten Fettsäuren mit 8 bis 22 C-Atomen,
• – Sterine. Als Sterine wird eine Gruppe von Steroiden verstanden, die am C-Atom 3 des Steroid-Gerüstes eine Hydroxylgruppe tragen und sowohl aus tierischem Gewebe (Zoosterine) wie auch aus pflanzlichen Fetten (Phytosterine) isoliert werden. Beispiele für Zoosterine sind das Cholesterin und das Lanosterin. Beispiele geeigneter Phytosterine sind Ergosterin, Stigmasterin und Sitosterin. Auch aus Pilzen und Hefen werden Sterine, die sogenannten Mykosterine, isoliert.
• – Phospholipide. Hierunter werden vor allem die Glucose-Phospolipide, die z.B. als Lecithine bzw. Phospahtidylcholine aus z.B. Eidotter oder Pflanzensammen (z.B. Sojabohnen) gewonnen werden, verstanden.
• – Fettsäureester von Zuckern und Zuckeralkoholen, wie Sorbit,
• – Polyglycerine und Polyglycerinderivate wie beispielsweise Polyglycerinpoly-12-hydroxystearat (Handelsprodukt Dehymuls^® PGPH),
• – Lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen und deren Na-, K-, Ammonium-, Ca-, Mg- und Zn – Salze.

In a further preferred embodiment, the effect of the combination according to the invention can be increased by emulsifiers (F). Emulsifiers cause water or oil-stable adsorption layers to form at the phase interface, which protect the dispersed droplets against coalescence and thus stabilize the emulsion. Like surfactants, emulsifiers are therefore made up of a hydrophobic and a hydrophilic part of the molecule. Hydrophilic emulsifiers preferably form O / W emulsions and hydrophobic emulsifiers preferably form W / O emulsions. An emulsion is to be understood as a droplet-like distribution (dispersion) of a liquid in another liquid with the use of energy to create stabilizing phase interfaces by means of surfactants. The selection of these emulsifying surfactants or emulsifiers is based on the substances to be dispersed and the particular external phase as well as the fine particle size of the emulsion. Further definitions and properties of emulsifiers can be found in "H.-D. Dörfler, interfacial and colloid chemistry, VCH Verlagsgesellschaft mbH. Weinheim, 1994". Emulsifiers which can be used according to the invention are, for example

• Addition products of 4 to 30 mol of ethylene oxide and / or 0 to 5 mol of propylene oxide with linear fatty alcohols with 8 to 22 C atoms, with fatty acids with 12 to 22 C atoms and with alkylphenols with 8 to 15 C atoms in the alkyl group,
• C ₁₂ -C ₂₂ fatty acid monoesters and diesters of adducts of 1 to 30 mol of ethylene oxide with polyols having 3 to 6 carbon atoms, in particular with glycerol,
• - Ethylene oxide and polyglycerol adducts with methyl glucoside fatty acid esters, fatty acid alkanolamides and fatty acid glucamides,
• C ₈ -C ₂₂ alkyl mono- and oligoglycosides and their ethoxylated analogs, degrees of oligomerization from 1.1 to 5, in particular 1.2 to 2.0, and glucose as the sugar component being preferred,
• Mixtures of alkyl (oligo) glucosides and fatty alcohols, for example the commercially available product Montanov ^® 68,
• - adducts of 5 to 60 moles of ethylene oxide with castor oil and hardened castor oil,
• Partial esters of polyols with 3 to 6 carbon atoms with saturated fatty acids with 8 to 22 C atoms,
• - sterols. Sterols are understood to be a group of steroids that are attached to the C atom 3 of the steroid structure carry a hydroxyl group and are isolated from both animal tissue (zoosterols) and vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Sterols, the so-called mycosterols, are also isolated from mushrooms and yeasts.
• - phospholipids. These are understood above all to mean the glucose phospholipids which are obtained, for example, as lecithins or phosphididylcholines from, for example, egg yolk or plant seeds (for example soybeans).
• Fatty acid esters of sugars and sugar alcohols, such as sorbitol,
• - polyglycerols and polyglycerol derivatives such as polyglycerol poly-12-hydroxystearate (commercial product Dehymuls ^® PGPH),
• - Linear and branched fatty acids with 8 to 30 carbon atoms and their Na, K, ammonium, Ca, Mg and Zn salts.

The agents according to the invention contain the emulsifiers preferably in amounts of 0.1-25% by weight, in particular 0.5-15 % By weight, based on the total average.

Prefers can the compositions according to the invention at least one nonionic emulsifier with an HLB value of 8 to 18, according to the in Römpp-Lexikon Chemistry (Hrg. J. Falbe, M.Regitz), 10th edition, Georg Thieme Verlag Stuttgart, New York, (1997), page 1764. Nonionic emulsifiers with an HLB value of 10-15 can be particularly useful according to the invention be preferred.

Farther can in those used according to the invention Preparations protein hydrolyzates and / or amino acids and their derivatives (H) be included. Protein hydrolyzates are product mixtures that are created by acidic, basic or enzymatically catalyzed breakdown of proteins (Proteins) be preserved. According to the invention, the term protein hydrolyzates also includes total hydrolyzates as well as individual amino acids and their derivatives and mixtures of different amino acids understood. Furthermore, according to the invention, amino acids and amino acid derivatives constructed polymers understood by the term protein hydrolyzates. The latter include, for example, polyalanine, polyasparagine, polyserine etc. to count. More examples of usable according to the invention Compounds are L-alanyl-L-proline, polyglycine, glycyl-L-glutamine or D / L-methionine-S-Methylsulfoniumchlorid. Of course can according to the invention also β-amino acids and their derivatives such as β-alanine, anthranilic or hippuric acid be used. The molecular weight of those which can be used according to the invention Protein hydrolyzate is between 75, the molecular weight for glycine, and 200,000, is preferred the molecular weight 75 to 50,000 and very particularly preferably 75 to 20000 daltons.

According to the invention, protein hydrolyzates both plant and animal or marine or synthetic Origin are used.

Animal protein hydrolyzates are, for example, elastin, collagen, keratin, silk and milk protein protein hydrolyzates, which can also be in the form of salts. Such products are, for example, under the trademarks Dehylan ^® (Cognis), Promois ^® (Interorgana), Collapuron ^® (Cognis), Nutrilan ^® (Cognis), Gelita-Sol ^® (Deutsche Gelatine Fabriken Stoess & Co), Lexein ^® (Inolex) and Kerasol ^® (Croda) sold.

According to the invention, the use of protein hydrolysates of plant origin, e.g. B. soy, almond, pea, potato and wheat protein hydrolyzates. Such products are, for example, under the trademarks Gluadin ^® (Cognis), DiaMin ^® (Diamalt), Lexein ^® (Inolex), Hydrosoy ^® (Croda), Hydrolupin ^® (Croda), Hydrosesame ^® (Croda), Hydrotritium ^® (Croda) and Crotein ^® (Croda) available.

Although the use of the protein hydrolyzates as such is preferred, amino acid mixtures obtained in some other way can optionally be used in their place. It is also possible to use derivatives of the protein hydrolyzates, for example in the form of their fatty acid condensation products. Such products are sold for example under the names Lamepon® ^® (Cognis), Lexein ^® (Inolex), Crolastin ^® (Croda) or crotein ^® (Croda).

The Protein hydrolyzates or their derivatives are used in the invention Agents preferably in amounts of 0.1 to 10 wt .-%, based on the total funds included. Amounts of 0.1 to 5% by weight are special prefers.

Furthermore, in a preferred embodiment of the invention, the action of the active ingredients (A) can be increased by UV filter (I). The structure and physical properties of the UV filters to be used according to the invention are not subject to any general restrictions. Rather, all UV filters that can be used in the cosmetics sector are suitable, the absorption maximum of which lies in the UVA (315-400 nm), in the UVB (280-315 nm) - or in the UVC (<280 nm) range. UV filters with an absorption maximum in the UVB range, in particular in the range from approximately 280 to approximately 300 nm, are particularly preferred.

The used according to the invention UV filters can selected for example are made from substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylates, cinnamic, salicylates, Benzimidazoles and o-aminobenzoic acid esters.

Examples of UV filters which can be used according to the invention are 4-amino-benzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline methyl sulfate, 3,3,5-trimethyl cyclohexyl salicylate (homosalates), 2-Hydroxy-4-methoxy-benzophenone (Benzophenone-3; Uvinul ^® M 40, Uvasorb ^® MET, Neo Heliopan ^® BB, Eusolex ^® 4360), 2-phenylbenzimidazole-5-sulfonic acid and their potassium, sodium and triethanolamine salts ( Phenylbenzimidazole sulfonic acid; Parsol ^® HS; Neo Heliopan ^® Hydro), 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxo-bicyclo- [2.2.1] hept-1- yl-methane-sulfonic acid) and its salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propane-1,3-dione (butyl methoxydibenzoylmethane; Parsol ^® 1789, Eusolex ^® 9020), α - (2-Oxoborn-3-ylidene) toluene-4-sulfonic acid and its salts, ethoxylated ethyl 4-aminobenzoate (PEG-25 PABA; Uvinul ^® P 25), 4-dimethylaminobenzoic acid 2-ethylhexyl ester (octyl dimethyl PABA; Uvasorb ^® DMO, Escalol ^® 507, Eusolex ^® 6007), salicylic acid-2-ethylhexy ester (octyl salicylate; Escalol ^® 587, Neo Heliopan ^® OS, Uvinul ^® O18), 4-methoxycinnamic acid isopentyl ester (isoamyl p-methoxycinnamate; Neo Heliopan ^® E 1000), 4-methoxycinnamic acid 2-ethylhexyl ester (octyl methoxycinnamate; Parsol ^® MCX, Escalol ^® 557, Neo Heliopan ^® AV), 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt (Benzophenone-4; Uvinul ^® MS 40; Uvasorb ^® S 5), 3- (4'-methylbenzylidene) -D, L-camphor (4-methylbenzylidene camphor; Parsol ^® 5000, Eusolex ^® 6300), 3-benzylidene camphor (3-benzylidene camphor), 4-isopropylbenzylsalicylate, 2,4,6-trianilino- (p-carbo-2'- ethylhexyl-1'-oxi) -1,3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of N - {(2 and 4) - [2-oxoborn-3-ylidenemethyl] benzyl } -acrylamids, 2,4-dihydroxybenzophenone (Benzophenone-1; Uvasorb ^® 20 H, Uvinul ^® 400), 1,1'-Diphenylacrylonitrilsäure-2-ethylhexyl ester (octocrylene; Eusolex ^® OCR, Neo Heliopan ^® Type 303, Uvinul ^® N 539 SG), o-aminobenzoic acid menthyl ester (menthyl anthranilate; Neo H eliopan ^® MA), 2,2 ', 4,4'-tetrahydroxy benzophenone (benzophenone-2; Uvinul ^® D-50), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone (Benzophenone-6), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone-5-sodium sulfonate and 2-cyano-3, 3-diphenylacrylate 2'-ethylhexyl acrylate. 4-Aminobenzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline-methyl sulfate, 3,3,5-trimethyl-cyclohexylsalicylate, 2-hydroxy-4-methoxy-benzophenone, 2 are preferred -Phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts, 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxo-bicyclo- [2.2.1] hept- 1-yl-methanesulfonic acid) and its salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propane-1,3-dione, α- (2-oxoborn-3-ylidene) -toluene-4-sulfonic acid and its salts, ethoxylated ethyl 4-aminobenzoate, 2-ethylhexyl 4-dimethylaminobenzoate, 2-ethylhexyl salicylate, isopentyl 4-methoxycinnamate, 2-ethylhexyl 4-methoxycinnamate, 2-hydroxy -4-methoxybenzophenone-5-sulfonic acid and its sodium salt, 3- (4'-methylbenzylidene) -D, L-camphor, 3-benzylidene-camphor, 4-isopropylbenzylsalicylate, 2,4,6-trianilino- (p-carbo- 2'-ethylhexyl-1'-oxi) -1,3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of N - {(2 and 4) - [2-ox Oborn-3-ylidenemethyl] benzyl} acrylamide. According to the invention, 2-hydroxy-4-methoxy-benzophenone, 2-phenylbenzimidazole-5-sulfonic acid and their potassium, sodium and triethanolamine salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) are very particularly preferred -propane-1,3-dione, 2-ethylhexyl 4-methoxycinnamate and 3- (4'-methylbenzylidene) -D, L-camphor.

Prefers are such UV filters, whose molar extinction coefficient is at the absorption maximum is above 15,000, in particular above 20,000.

Farther was found to be structurally similar in many UV filters make the water-insoluble Connection in the context of the teaching of the invention the higher effect across from such water-soluble Has connections that differ from it through one or more additionally distinguish ionic groups. As water-insoluble in the context of the invention to understand those UV filters which do not exceed 1% by weight at 20 ° C, in particular not more than 0.1% by weight, dissolve in water. Farther these connections should be in usual cosmetic oil components at room temperature at least 0.1, in particular at least 1% by weight soluble his). The use of water-insoluble UV filters can therefore be preferred according to the invention.

According to one another embodiment The invention preferred UV filters are those that have a cationic Group, especially a quaternary Have ammonium group.

This UV filters have the general structure U - Q.

The Structural part U stands for a group that absorbs UV rays. This group can in principle of the known, used in the cosmetics sector, mentioned above Derive UV filters in which a group, usually a hydrogen atom, of the UV filter by a cationic group Q, especially with a quaternary Amino function, is replaced.

• – substituierte Benzophenone,
• – p-Aminobenzoesäureester,
• – Diphenylacrylsäureester,
• – Zimtsäureester,
• – Salicylsäureester,
• – Benzimidazole und
• – o-Aminobenzoesäureester.

Connections from which the structural part U can be derived are, for example

• - substituted benzophenones,
• P-aminobenzoic acid ester,
• - diphenylacrylic acid ester,
• - cinnamic acid esters,
• - salicylic acid esters,
• - benzimidazoles and
• O-aminobenzoic acid esters.

structural parts U, which is derived from cinnamic acid amide or derived from N, N-dimethylamino-benzoic acid amide are preferred according to the invention.

The Structural parts U can chosen in principle that the absorption maximum of the UV filter in both UVA (315–400 nm) -, as well as in the UVB (280-315 nm) - or in the UVC (<280 nm) range. UV filter with an absorption maximum in the UVB range, in particular in the range from about 280 to about 300 nm, are special prefers.

Farther structure part U, also depending on structure part Q, preferably chosen that the molar extinction coefficient of the UV filter at the absorption maximum is above 15,000, in particular above 20,000.

The Structure part Q contains a quaternary ammonium group is preferred as the cationic group. This quaternary ammonium group can in principle be connected directly to the structural part U, so that the structural part U is one of the four substituents of the positive represents charged nitrogen atom. However, one of the is preferred four substituents on the positively charged nitrogen atom form a group, in particular an alkylene group having 2 to 6 carbon atoms, the as a connection between the structural part U and the positively charged Nitrogen atom acts.

The group Q advantageously has the general structure - (CH ₂ ) _X -N ⁺ R ¹ R ² R ³ X ^- , in which x represents an integer from 1 to 4, R ¹ and R ² independently of one another represent C _{1 -4} -alkyl groups, R ³ stands for a C _1-22 -alkyl group or a benzyl group and X ^- for a physiologically compatible anion. Within the framework of this general structure, x preferably represents the number 3, R ¹ and R ² each for a methyl group and R ³ either for a methyl group or a saturated or unsaturated, linear or branched hydrocarbon chain with 8 to 22, in particular 10 to 18, carbon atoms.

physiological compatible Anions are, for example, inorganic anions such as halides, especially chloride, bromide and fluoride, sulfate ions and phosphate ions and organic anions such as lactate, citrate, acetate, tartrate, methosulfate and tosylate.

Two preferred UV filters with cationic groups are the commercially available compounds cinnamic acid trimethyl ammonium chloride (Incroquat ^® UV 283) and dodecyl tosylate (Escalol ^® HP 610).

Of course, the teaching of the invention includes also the use of a combination of several UV filters. in the Framework of this embodiment is the combination of at least one water-insoluble UV filter with at least a UV filter with a cationic group is preferred.

The UV filters (I) are common in the agents used according to the invention in amounts 0.1-5% by weight, based on the total mean. Quantities of 0.4-2.5% by weight are preferred.

The effect of the combination according to the invention can be further increased by a 2-pyrrolidinone-5-carboxylic acid and its derivatives (J). Another object of the invention is therefore the use of the active ingredient in combination with derivatives of 2-pyrrolidinone-5-carboxylic acid. The Nat rium, potassium, calcium, magnesium or ammonium salts, in which the ammonium ion carries one to three C ₁ - to C ₄ -alkyl groups in addition to hydrogen. The sodium salt is very particularly preferred. The amounts used in the agents according to the invention are 0.05 to 10% by weight, based on the total agent, particularly preferably 0.1 to 5 and in particular 0.1 to 3% by weight.

Likewise the combination of active ingredient (A) has been found to be advantageous Vitamins, provitamins and vitamin precursors and their derivatives (K) proved.

there are such according to the invention Vitamins, pro-vitamins and vitamin precursors are preferred, which are common be assigned to groups A, B, C, E, F and H.

The group of substances called vitamin A includes retinol (vitamin A ₁ ) and 3,4-didehydroretinol (vitamin A ₂ ). The β-carotene is the provitamin of retinol. According to the invention, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as palmitate and acetate come into consideration as vitamin A components. The preparations used according to the invention preferably contain the vitamin A component in amounts of 0.05-1% by weight, based on the entire preparation.

• – Vitamin B₁ (Thiamin)
• – Vitamin B₂ (Riboflavin)
• – Vitamin B₃. Unter dieser Bezeichnung werden häufig die Verbindungen Nicotinsäure und Nicotinsäureamid (Niacinamid) geführt. Erfindungsgemäß bevorzugt ist das Nicotinsäureamid, das in den erfindungsgemäß verwendetenen Mitteln bevorzugt in Mengen von 0,05 bis 1 Gew.-%, bezogen auf das gesamte Mittel, enthalten ist.
• – Vitamin B₅ (Pantothensäure, Panthenol und Pantolacton). Im Rahmen dieser Gruppe wird bevorzugt das Panthenol und/oder Pantolacton eingesetzt. Erfindungsgemäß einsetzbare Derivate des Panthenols sind insbesondere die Ester und Ether des Panthenols sowie kationisch derivatisierte Panthenole. Einzelne Vertreter sind beispielsweise das Panthenoltriacetat, der Panthenolmonoethylether und dessen Monoacetat sowie die in der WO 92/13829 offenbarten kationischen Panthenolderivate. Die genannten Verbindungen des Vitamin B₅-Typs sind in den erfindungsgemäß verwendeten Mitteln bevorzugt in Mengen von 0,05–10 Gew.-%, bezogen auf das gesamte Mittel, enthalten. Mengen von 0,1–5 Gew.-% sind besonders bevorzugt.
• - Vitamin B₆ (Pyridoxin sowie Pyridoxamin und Pyridoxal).

The vitamin B group or the vitamin B complex include

• - Vitamin B ₁ (thiamine)
• - Vitamin B ₂ (riboflavin)
• - Vitamin B ₃ . The compounds nicotinic acid and nicotinamide (niacinamide) are often listed under this name. According to the invention, preference is given to nicotinic acid amide, which is preferably present in the agents used according to the invention in amounts of 0.05 to 1% by weight, based on the total agent.
• - Vitamin B ₅ (pantothenic acid, panthenol and pantolactone). Within this group, panthenol and / or pantolactone is preferably used. Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, panthenol monoethyl ether and its monoacetate and the cationic panthenol derivatives disclosed in WO 92/13829. The compounds of the vitamin B ₅ type mentioned are preferably contained in the agents used according to the invention in amounts of 0.05-10% by weight, based on the total agent. Amounts of 0.1-5% by weight are particularly preferred.
• - Vitamin B ₆ (pyridoxine, pyridoxamine and pyridoxal).

vitamin C (ascorbic acid). Vitamin C is preferred in the agents used according to the invention in amounts of 0.1 to 3 wt .-%, based on the total agent. Use in the form of the palmitic acid ester, glucoside or Phosphates can be preferred. Use in combination with Tocopherols can also be preferred.

vitamin E (tocopherols, especially α-tocopherol). Tocopherol and its derivatives, including esters such as the acetate, the nicotinate, the phosphate and the succinate fall, are used in the invention Agents preferably in amounts of 0.05-1 wt .-%, based on the total funds included.

vitamin F. Under the term "Vitamin F "are common essential fatty acids, especially linoleic acid, linolenic and arachidonic acid, Roger that.

vitamin H. Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] imidazole-4-valeric acid, for the However, the trivial name biotin has now become established. biotin is used in the invention Agents preferably in amounts of 0.0001 to 1.0% by weight, in particular in Contain amounts from 0.001 to 0.01 wt .-%.

Prefers contain the used according to the invention Medium vitamins, provitamins and vitamin precursors from the groups A, B, E and H.

panthenol, Pantolactone, pyridoxine and its derivatives and nicotinamide and biotin are particularly preferred.

Finally, the effect also through the combined use with plant extracts Increase (L).

Usually these extracts are made by extracting the whole plant. But in some cases it can also be preferred, the extracts exclusively from flowers and / or Scroll of the plant.

Regarding the usable according to the invention Plant extracts are particularly referred to the extracts, in the on page 44 of the 3rd edition of the guide to the ingredient declaration cosmetic products, published by the industrial association Detergent e.V. (IKW), Frankfurt, starting from the table.

According to the invention especially the extracts from green Tea, oak bark, nettle, witch hazel, hops, henna, chamomile, Burdock root, horsetail, hawthorn, linden flowers, almond, Aloe vera, spruce needles, horse chestnut, Sandalwood, juniper, coconut, Mango, apricot, lime, wheat, kiwi, melon, orange, grapefruit, Sage, rosemary, birch, mallow, cuckoo flower, quendel, yarrow, Thyme, lemon balm, hake, coltsfoot, marshmallow, meristem, ginseng and ginger root preferred.

Especially the extracts from green tea, oak bark, nettle, Witch hazel, hops, chamomile, burdock root, horsetail, linden flowers, almond, Aloe vera, coconut, Mango, apricot, lime, wheat, kiwi, melon, orange, grapefruit, Sage, rosemary, birch, cuckoo flower, quendel, yarrow, Common hake, meristem, ginseng and ginger root.

All especially for the use according to the invention the extracts from green tea, almond, aloe vera, Coconut, Mango, apricot, lime, wheat, kiwi and melon.

As Extracting agent for the production of the plant extracts mentioned can Water, alcohols and mixtures thereof can be used. Under the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as the sole extractant and as a mixture with Water, preferred. Plant extracts based on water / propylene glycol in relation to 1:10 to 10: 1 have proven to be particularly suitable.

The Plant extracts can according to the invention both in pure as well as in diluted Form are used. If they are used in diluted form, usually contain them about 2-80 % By weight of active substance and as a solvent the extractant or mixture of extractants used in their extraction.

Farther it may be preferred to use mixtures of the agents according to the invention several, in particular from two, different plant extracts use.

In addition can it has proven to be advantageous if, in addition to the combination according to the invention Penetration aids and / or swelling agents (M) are included. These auxiliaries provide better penetration of active ingredients into the keratin fiber or help swell the keratin fiber. This includes, for example to count urea and urea derivatives, guanidine and its derivatives, arginine and its derivatives, water glass, imidazole and its derivatives, histidine and its derivatives, benzyl alcohol, glycerin, glycol and glycol ether, Propylene glycol and propylene glycol ether, for example propylene glycol monoethyl ether, Carbonates, hydrogen carbonates, diols and triols, and in particular 1,2-diols and 1,3-diols such as 1,2-propanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-dodecanediol, 1,3-propanediol, 1,6-hexanediol, 1,5-pentanediol, 1,4-butanediol.

Advantageous in the sense of the invention additionally short chain carboxylic acids (N) supportive with the combination according to the invention interact. Among short chain carboxylic acids and their derivatives in For the purposes of the invention, carboxylic acids are understood which are saturated or unsaturated and / or straight-chain or branched or cyclic and / or aromatic and / or can be heterocyclic and have a molecular weight less than 750. Preferred in the sense of the invention saturated or unsaturated straight chain or branched carboxylic acids with a chain length be from 1 to 16 carbon atoms in the chain, very particularly preferred are those with a chain length from 1 to 12 carbon atoms in the chain.

The short-chain carboxylic acids in the context of the invention can have one, two, three or more carboxy groups. For the purposes of the invention, preference is given to carboxylic acids having several carboxy groups, in particular di- and tricarboxylic acids. The carboxy groups can be present in whole or in part as an ester, acid anhydride, lactone, amide, imidic acid, lactam, lactim, dicarboximide, carbohydrazide, hydrazone, hydroxam, hydroxime, amidine, amidoxime, nitrile, phosphonic or phosphate ester. The carboxylic acids according to the invention can of course, be substituted along the carbon chain or the ring structure. The substituents of the carboxylic acids according to the invention include, for example, C1-C8-alkyl, C2-C8-alkenyl, aryl, aralkyl and aralkenyl, hydroxymethyl, C2-C8-hydroxyalkyl-C2-C8-hydroxyalkenyl, aminomethyl -, C2-C8-aminoalkyl, cyano, formyl, oxo, thioxo, hydroxy, mercapto, amino, carboxy or imino groups. Preferred substituents are C1-C8-alkyl, hydroxymethyl, hydroxy, amino and carboxy groups. Substituents in the α position are particularly preferred. Very particularly preferred substituents are hydroxyl, alkoxy and amino groups, where the amino function can optionally be further substituted by alkyl, aryl, aralkyl and / or alkenyl radicals. Furthermore, preferred carboxylic acid derivatives are the phosphonic and phosphate esters.

in der Z steht für eine lineare oder verzweigte Alkyl- oder Alkenylgruppe mit 4 bis 12 Kohlenstoffatomen, n für eine Zahl von 4 bis 12 sowie eine der beiden Gruppen X und Y für eine COOH-Gruppe und die andere für Wasserstoff oder einen Methyl- oder Ethylrest, Dicarbonsäuren der allgemeinen Formel (N-I), die zusätzlich noch 1 bis 3 Methyl- oder Ethylsubstituenten am Cyclohexenring tragen sowie Dicarbonsäuren, die aus den Dicarbonsäuren gemäß Formel (N-I) formal durch Anlagerung eines Moleküls Wasser an die Doppelbindung im Cyclohexenring entstehen.Examples of carboxylic acids according to the invention are formic acid, acetic acid, propionic acid, butyric acid, isobutyric acid, valeric acid, isovaleric acid, pivalic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, glyceric acid, glyoxylic acid, adipic acid, pimelic acid, suberic acid, azocanoic acid, sebrotonic acid, sebacic acid , Elaidic acid, maleic acid, fumaric acid, muconic acid, citraconic acid, mesaconic acid, camphoric acid, benzoic acid, o, m, p-phthalic acid, naphthoic acid, toluoylic acid, hydratropic acid, atropic acid, cinnamic acid, isonicotinic acid, nicotinic acid, bicarbamicanoic acid, 4,4'-dicarboxylic acid, 4,4'-diacid 6'-binicotinic acid, 8-carbamoyloctanoic acid, 1,2,4-pentane tricarboxylic acid, 2-pyrrolecarboxylic acid, 1,2,4,6,7-naphthalene pentaacetic acid, malonaldehyde acid, 4-hydroxy-phthalamic acid, 1-pyrazole carboxylic acid, gallic acid or propane tricarboxylic acid, a Dicarboxylic acid selected from the group formed by compounds d he general formula (NI),

in the Z stands for a linear or branched alkyl or alkenyl group with 4 to 12 carbon atoms, n for a number from 4 to 12 and one of the two groups X and Y for a COOH group and the other for hydrogen or a methyl or Ethyl radical, dicarboxylic acids of the general formula (NI) which additionally carry 1 to 3 methyl or ethyl substituents on the cyclohexene ring and dicarboxylic acids which formally form from the dicarboxylic acids of the formula (NI) by addition of a molecule of water to the double bond in the cyclohexene ring.

Dicarboxylic acids Formula (N-I) are known in the literature.

On Manufacturing method is, for example, US Pat. No. 3,753,968 refer to. German patent 22 50 055 discloses the Use of these dicarboxylic acids in liquid Soap masses. From German Offenlegungsschrift 28 33 291 are Deodorants known, the zinc or magnesium salts of these dicarboxylic acids contain. Finally are means from the German Offenlegungsschrift 35 03 618 Wash and rinse the hair known in which by adding these dicarboxylic acids a noticeably improved hair cosmetic effect of the contained in the agent water-soluble ionic polymers is obtained. After all, are from the German Laid-open publication 197 54 053 means for treating hair known which have nourishing effects.

The dicarboxylic acids of the formula (N-I) for example by reacting polyunsaturated dicarboxylic acids with unsaturated Monocarboxylic acids be produced in the form of a Diess-Alder cyclization. Usually is considered a polyunsaturated fatty acid dicarboxylic acid out. Preference is given to that obtained from natural fats and oils Linoleic acid. As a monocarboxylic acid component are especially acrylic acid, but also e.g. methacrylic acid and crotonic acid prefers. Usually arise in reactions according to Diels-Alder isomer mixtures, at which a component is in excess. These mixtures of isomers can according to the invention as well how the pure connections are used.

Can be used according to the invention in addition to the preferred dicarboxylic acids according to formula (N-I) are also such dicarboxylic acids, which differ from the compounds of formula (N-I) by 1 to 3 Distinguish methyl or ethyl substituents on the cyclohexyl ring or from these compounds formally by the addition of a molecule of water to form the double formation of the cyclohexene ring.

The dicarboxylic acid (mixture) which results from the reaction of linoleic acid with acrylic acid has proven to be particularly effective according to the invention. It is a mixture of 5- and 6-car boxy-4-hexyl-2-cyclohexene-1-octanoic acid. Such compounds are commercially available under the names Westvaco Diacid ^® 1550 and Westvaco Diacid ^® 1595 (manufacturer: Westvaco).

Next those listed above as examples short chain according to the invention carboxylic acids yourself can also their physiologically tolerable Salts used according to the invention become. examples for such salts are the alkali, alkaline earth, zinc and ammonium salts, including the mono-, di- and to understand trimethyl, ethyl and hydroxyethyl ammonium salts are. Can very particularly preferably in the context of the invention, however, with alkaline amino acids, such as for example, arginine, lysine, ornithine and histidine acids be used. It may also be preferred for formulation reasons be the carboxylic acid from the water-soluble Representatives, especially the water-soluble salts.

Furthermore, it is preferred according to the invention to use hydroxycarboxylic acids and in this case in particular the dihydroxy, trihydroxy and polyhydroxycarboxylic acids as well as the dihydroxy, trihydroxy and polyhydroxydi, tri and polycarboxylic acids together with the active ingredient (A). It has been shown here that, in addition to the hydroxycarboxylic acids, the hydroxycarboxylic acid esters and the mixtures of hydroxycarboxylic acids and their esters as well as polymeric hydroxycarboxylic acids and their esters can be very particularly preferred. Preferred hydroxycarboxylic acid esters are, for example, full esters of glycolic acid, lactic acid, malic acid, tartaric acid or citric acid. Other basically suitable hydroxycarboxylic acid esters are esters of β-hydroxypropionic acid, tartronic acid, D-gluconic acid, sugar acid, mucic acid or glucuronic acid. Suitable alcohol components of these esters are primary, linear or branched aliphatic alcohols with 8-22 carbon atoms, for example fatty alcohols or synthetic fatty alcohols. The esters of C12-C15 fatty alcohols are particularly preferred. Esters of this type are commercially available, eg under the trademark Cosmacol® ^® EniChem, Augusta Industriale. Particularly preferred polyhydroxy polycarboxylic acids are polylactic acid and poly-tartaric acid and their esters.

A very particularly diverse and interesting cosmetic active ingredient group are polyhydroxy compounds. The use according to the invention of polyhydroxy compounds as an active ingredient with the other components according to the invention can therefore be particularly preferred. Taking polyhydroxy compounds In the sense of the invention, all substances are understood which the definition in Römpp's Lexikon der Chemie, Version 2.0 of the CD-ROM edition from 1999, published by Georg Thieme. Therefore are organic compounds with at least to understand two hydroxy groups. In particular, in the sense of to understand the present invention hereunder:

• - polyols with at least two hydroxyl groups, and with a carbon chain from 2 to 30 carbon atoms such as trimethylolpropane,
• - ethoxylates and / or propoxylates with 1 to 50 moles of ethylene oxide and or propylene oxide the aforementioned polyols,
• - Carbohydrates, Sugar alcohols and sugar and their salts,
• - in particular Monosaccharides, disaccharides, trisaccharides and oligosaccharides, these also in the form of aldoses, ketoses and / or lactoses, as well as protected through usual and -OH and -NH protecting groups known in the literature, such as the triflate group, the trimethylsilyl group or acyl groups and continue to exist in the form of the methyl ether and as a phosphate ester can,
• - aminodeoxy sugar, Deoxy sugar, thio sugar, these also in the form of aldoses, Ketoses and / or lactoses, as well as protected by usual and in the literature known -OH- and -NH- protecting groups, such as the triflate group, the trimethylsilyl group or acyl groups and also in the form the methyl ether and as a phosphate ester may be present, Prefers include monosaccharides with 3 to 8 carbon atoms, such as Triosen, Tetrosen, Pentosen, Hexosen, Heptosen and Octosen, whereby these also in the form of aldoses, ketoses and / or lactoses as well protected through usual and -OH and -NH protecting groups known in the literature, such as the triflate group, the trimethylsilyl group or acyl groups and continue to exist in the form of the methyl ether and as a phosphate ester can, Farther are preferred oligosaccharides with up to 50 monomer units, wherein these also in the form of aldoses, ketoses and / or lactoses as well protected through usual and -OH and -NH protecting groups known in the literature, such as the triflate group, the trimethylsilyl group or acyl groups and further in the form of the methyl ether and as a phosphate ester.

Very particularly preferred polyols of the present invention are polyols having 2 to 12 carbon atoms in the molecular structure. These polyols can be straight-chain, branched, cyclic and / or unsaturated. The hydroxyl groups are very particularly preferably terminally adjacent or terminally by the rest of the Chain separated. Examples of these polyols are: glycol, polyethylene glycol up to a molecular weight of up to 1000 daltons, neopentyl glycol, partial glycerol ether with a molecular weight of up to 1000 daltons, 1,2-propanediol, 1,3-propanediol, glycerol, 1,2-butanediol , 1,3-butanediol, 1,4-butanediol, 1,2,3-butanetriol, 1,2,4-butanetriol, pentanediols, for example 1,2-pentanediol, 1,5-pentanediol, hexanediols, 1,2- Hexanediol, 1,6-hexanediol, 1,2,6-hexanediol, 1,4-cyclo-hexanediol, 1,2-cyclo-hexanediol, heptanediols, 1,2-heptanediol, 1,7-heptanediol, octanediols, 1, 2-octanediol, 1,8-octanediol, 2-ethyl-1,3-hexanediol, octadienols, decadienols, dodecanediols, 1,2-dodecanediol, 1,12-dodecanediol, 1,12-dodecanediol with 10 mol EO, dodecadienols.

Farther exemplary of the polyols according to the invention be mentioned Sorbitol, inositol, mannitol, tetrite, pentite, hexite, threitol, erythritol, Adonit, Arabit, Xylit, Dulcit, Erythrose, Threose, Arabinose, Ribose, Xylose, lyxose, glucose, galactose, mannose, allose, old rose, gulose, Idose, Talose, Fructose, Sorbose, Psicose, Tegatose, Deoxyribose, Glucosamine, galactosamine, rhamnose, digitoxose, thioglucose, sucrose, Lactose, trehalose, maltose, cellobiose, melibiose, gestiobiose, Rutinose, raffinose and cellotriose. Furthermore, be on the relevant specialist literature such as Beyer-Walter, textbook of organic chemistry, S. Hirzel Verlag Stuttgart, 19th edition, section III, pages 393 and referred to the following.

Of course, the teaching of the invention includes all isomeric forms, such as cis-trans isomers, diastereomers, Epimers, anomers and chiral isomers.

It is according to the invention also possible, to use a mixture of several polyols (B).

The polyols according to the invention (B) are in the compositions in concentrations of 0.01% by weight up to 20% by weight, preferably from 0.05% by weight to 15% by weight and very particularly preferably contained in amounts of 0.1% by weight up to 10% by weight.

• – nichtionische Polymere wie beispielsweise Vinylpyrrolidon/Vinylacrylat-Copolymere, Polyvinylpyrrolidon und Vinylpyrrolidon/Vinylacetat-Copolymere und Polysiloxane,
• – Verdickungsmittel wie Agar-Agar, Guar-Gum, Alginate, Xanthan-Gum, Gummi arabicum, Karaya-Gummi, Johannisbrotkernmehl, Leinsamengummen, Dextrane, Cellulose-Derivate, z. B. Methylcellulose, Hydroxyalkylcellulose und Carboxymethylcellulose, Stärke-Fraktionen und Derivate wie Amylose, Amylopektin und Dextrine, Tone wie z. B. Bentonit oder vollsynthetische Hydrokolloide wie z. B. Polyvinylalkohol,
• – haarkonditionierende Verbindungen wie Phospholipide, beispielsweise Sojalecithin, Ei-Lecitin und Kephaline, sowie Silikonöle,
• – Parfümöle, Dimethylisosorbid und Cyclodextrine,
• – Lösungsmittel und -vermittler wie Ethanol, Isopropanol, Ethylenglykol, Propylenglykol, Glycerin und Diethylenglykol,
• – symmetrische und unsymmetrische, lineare und verzweigte Dialkylether mit insgesamt zwischen 12 bis 36 C-Atomen, insbesondere 12 bis 24 C-Atomen, wie beispielsweise Di-n-octylether, Di-n-decylether, Di-n-nonylether, Di-n-undecylether und Di-n-dodecylether, n-Hexyl-n-octylether, n-Octyl-n-decylether, n-Decyl-n-undecylether, n-Undecyl-n-dodecylether und n-Hexyl-n-Undecylether sowie Di-tert-butylether, Di-iso-pentylether, Di-3-ethyldecylether, tert.-Butyl-n-octylether, iso-Pentyl-n-octylether und 2-Methyl-Pentyl-n-octylether,
• – Fettalkohole, insbesondere lineare und/oder gesättigte Fettalkohole mit 8 bis 30 C-Atomen,
• – Monoester von C8 bis C30 – Fettsäuren mit Alkoholen mit 6 bis 24 C-Atomen,
• – faserstrukturverbessernde Wirkstoffe, insbesondere Mono-, Di- und Oligosaccharide, wie beispielsweise Glucose, Galactose, Fructose, Fruchtzucker und Lactose,
• – konditionierende Wirkstoffe wie Paraffinöle, pflanzliche Öle, z. B. Sonnenblumenöl, Orangenöl, Mandelöl, Weizenkeimöl und Pfirsichkernöl sowie
• – Phospholipide, beispielsweise Sojalecithin, Ei-Lecithin und Kephaline,
• – quaternierte Amine wie Methyl-1-alkylamidoethyl-2-alkylimidazolinium-methosulfat,
• – Entschäumer wie Silikone,
• – Farbstoffe zum Anfärben des Mittels,
• – Antischuppenwirkstoffe wie Piroctone Olamine, Zink Omadine und Climbazol,
• – Wirkstoffe wie Allantoin und Bisabolol,
• – Cholesterin,
• – Konsistenzgeber wie Zuckerester, Polyolester oder Polyolalkylether,
• – Fette und Wachse wie Walrat, Bienenwachs, Montanwachs und Paraffine,
• – Fettsäurealkanolamide,
• – Komplexbildner wie EDTA, NTA, β-Alanindiessigsäure und Phosphonsäuren,
• – Quell- und Penetrationsstoffe wie primäre, sekundäre und tertiäre Phosphate,
• – Trübungsmittel wie Latex, Styrol/PVP- und Styrol/Acrylamid-Copolymere
• – Perlglanzmittel wie Ethylenglykolmono- und -distearat sowie PEG-3-distearat,
• – Pigmente,
• – Reduktionsmittel wie z. B. Thioglykolsäure und deren Derivate, Thiomilchsäure, Cysteamin, Thioäpfelsäure und α-Mercaptoethansulfonsäure,
• – Treibmittel wie Propan-Butan-Gemische, N₂O, Dimethylether, CO₂ und Luft,
• – Antioxidantien.

Other active ingredients, auxiliaries and additives are, for example

• Non-ionic polymers such as, for example, vinyl pyrrolidone / vinyl acrylate copolymers, polyvinyl pyrrolidone and vinyl pyrrolidone / vinyl acetate copolymers and polysiloxanes,
• Thickeners such as agar agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. B. methyl cellulose, hydroxyalkyl cellulose and carboxymethyl cellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays such. B. bentonite or fully synthetic hydrocolloids such. B. polyvinyl alcohol,
• Hair-conditioning compounds such as phospholipids, for example soy lecithin, egg lecithin and cephalins, and silicone oils,
• - perfume oils, dimethyl isosorbide and cyclodextrins,
• Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol,
• - Symmetrical and asymmetrical, linear and branched dialkyl ethers with a total of between 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n -undecyl ether and di-n-dodecyl ether, n-hexyl-n-octyl ether, n-octyl-n-decyl ether, n-decyl-n-undecyl ether, n-undecyl-n-dodecyl ether and n-hexyl-n-undecyl ether and Di tert-butyl ether, di-iso-pentyl ether, di-3-ethyl decyl ether, tert-butyl-n-octyl ether, iso-pentyl-n-octyl ether and 2-methyl-pentyl-n-octyl ether,
• Fatty alcohols, in particular linear and / or saturated fatty alcohols with 8 to 30 carbon atoms,
• - monoesters from C8 to C30 - fatty acids with alcohols with 6 to 24 C atoms,
• Active ingredients that improve fiber structure, in particular mono-, di- and oligosaccharides, such as, for example, glucose, galactose, fructose, fructose and lactose,
• - conditioning agents such as paraffin oils, vegetable oils, e.g. B. sunflower oil, orange oil, almond oil, wheat germ oil and peach seed oil as well
• Phospholipids, for example soy lecithin, egg lecithin and cephalins,
• Quaternized amines such as methyl 1-alkylamidoethyl-2-alkylimidazolinium methosulfate,
• - defoamers like silicones,
• Dyes for coloring the agent,
• - anti-dandruff agents such as piroctone olamine, zinc omadine and climbazol,
• - active ingredients such as allantoin and bisabolol,
• - cholesterol,
• - consistency enhancers such as sugar esters, polyol esters or polyol alkyl ethers,
• - fats and waxes such as walrus, beeswax, montan wax and paraffins,
• - fatty acid alkanolamides,
• Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,
• Swelling and penetration substances such as primary, secondary and tertiary phosphates,
• - opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers
• Pearlescent agents such as ethylene glycol mono- and distearate and PEG-3 distearate,
• - pigments,
• - Reducing agents such. B. thioglycolic acid and its derivatives, thiolactic acid, cysteamine, thio malic acid and α-mercaptoethanesulfonic acid,
• Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,
• - antioxidants.

Regarding others optional components and the amounts of these components used expressly to the relevant manuals known to those skilled in the art, e.g. B. the above Monograph referenced by K. H. Schrader.

In a second special embodiment According to the invention, the cosmetic compositions are in the form of solid or powdered shaped bodies. In this embodiment contains the molded body according to the invention also at least one resolution accelerator. The term resolution accelerator comprises thereby gas-developing components, pre-formed and enclosed Gases, explosives and their mixtures.

Under the term resolution accelerator, Moldings explosives, Explosives or disintegrants are substances that are to be understood Tablets are added to disintegrate them when contacted with water or other solvents to accelerate.

overviews there are e.g. in J.Pharm.Sci. 61 (1972), Römpp Chemilexikon, 9th edition, volume 6, p. 4440 and Voigt "Textbook of pharmaceutical technology" (6th edition, 1987, Pp. 182-184). These substances enlarge Access of the solvent, for example water, its volume, on the one hand its own volume enlarged (swelling), on the other hand also about the release of gases can generate a pressure that the Tablet breaks into smaller particles. Be in pharmacy for this purpose cellulose derivatives or polymers used.

In a special embodiment of the present invention as a shaped body, gas-evolving components are used as dissolution accelerators. Upon contact with water, these components react with one another to form gases in-situ, which generate a pressure in the tablet which causes the tablet to disintegrate into smaller particles. An example of such a system are special combinations of suitable acids with bases. Mono-, di- or trivalent acids with a pK _a value of 1.0 to 6.9 are preferred. Preferred acids are citric acid, malic acid, maleic acid, malonic acid, itaconic acid, tartaric acid, oxalic acid, glutaric acid, glutamic acid, lactic acid, fumaric acid, glycolic acid and mixtures thereof. Citric acid is particularly preferred. It can be very particularly preferred to use the citric acid in particle form, the particles having a diameter below 1000 μm, in particular less than 700 μm, very particularly preferably less than 400 μm. Further alternative suitable acids are the homopolymers or copolymers of acrylic acid, maleic acid, methacrylic acid or itaconic acid with a molecular weight of 2,000 to 200,000. Homopolymers of acrylic acid and copolymers of acrylic acid and maleic acid are particularly preferred. Preferred bases according to the invention are alkali metal silicates, carbonates, hydrogen carbonates and mixtures thereof. Metasilicates, bicarbonates and carbonates are particularly preferred, bicarbonates are very particularly preferred. Particulate hydrogen carbonates with a particle diameter of less than 1000 μm, in particular less than 700 μm, very particularly preferably less than 400 μm are particularly preferred. Sodium or potassium salts of the above bases are particularly preferred. These gas-generating components are preferably present in the colored shaped bodies according to the invention in an amount of at least 10% by weight, in particular at least 20% by weight.

In a further embodiment of the present invention as a shaped body, the gas is pre-formed or enclosed, so that when the shaped body begins to dissolve, gas development begins and the further dissolution accelerates. Examples of suitable gases are air, carbon dioxide, N ₂ O, oxygen and / or other non-toxic, non-combustible gases.

In a third, particularly preferred embodiment of the present Invention as a molded article as a resolution accelerator Disintegration aids, so-called shaped body disintegrants, incorporated into the shaped body, to shorten the decay times.

These substances, which are also referred to as "explosives" due to their effect, enlarge Water access their volume (swelling). Swelling disintegration aids are, for example, synthetic polymers such as polyvinylpyrrolidone (PVP) or natural polymers or modified natural products such as cellulose and starch and their derivatives, alginates or casein derivatives.

Disintegrants based on cellulose are used as preferred disintegrants in the context of the present invention, so that preferred moldings such a disintegrant based on cellulose in amounts of 0.5 to 50% by weight, preferably 3 to 30% by weight, based on the entire molded body contain. Pure cellulose has the formal gross composition (C ₆ H ₁₀ O ₅ ) _n and, viewed formally, is a β-1,4-polyacetal of cellobiose, which in turn is made up of two molecules of glucose. Suitable celluloses consist of approximately 500 to 5000 glucose units and consequently have average molecular weights of 50,000 to 500,000. Cellulose-based disintegrants which can be used in the context of the present invention are also cellulose derivatives which can be obtained from cellulose by polymer-analogous reactions. Such chemically modified celluloses include, for example, products from esterifications or etherifications in which hydroxy hydrogen atoms have been substituted. However, celluloses in which the hydroxyl groups have been replaced by functional groups which are not bound via an oxygen atom can also be used as cellulose derivatives. The group of cellulose derivatives includes, for example, alkali celluloses, carboxymethyl cellulose (CMC), cellulose esters and ethers and aminocelluloses. The cellulose derivatives mentioned are preferably not used as the only cellulose-based disintegrant, but are used in a mixture with cellulose. The content of cellulose derivatives in these mixtures is preferably below 50% by weight, particularly preferably below 20% by weight, based on the cellulose-based disintegrant. Pure cellulose which is free of cellulose derivatives is particularly preferably used as the cellulose-based disintegrant.

The cellulose used as disintegration aid cannot be used in finely divided form, but can be converted into a coarser form, for example granulated or compacted, before being added to the premixes to be pressed. The particle sizes of such disintegrants are usually above 200 μm, preferably at least 90% by weight between 300 and 1600 μm and in particular at least 90% by weight between 400 and 1200 μm. The disintegration auxiliaries according to the invention are available commercially for example under the name of Arbocel ^® from Rettenmaier. A preferred disintegration aid is, for example, Arbocel ^® TF-30-HG.

Microcrystalline cellulose is preferably used as a cellulose-based disintegrant or as a component of this component. This microcrystalline cellulose is obtained by partial hydrolysis of celluloses under conditions which only attack and completely dissolve the amorphous areas (approx. 30% of the total cellulose mass) of the celluloses, but leave the crystalline areas (approx. 70%) undamaged. Subsequent disaggregation of the microfine celluloses produced by the hydrolysis provides the microcrystalline celluloses, which have primary particle sizes of approximately 5 μm and can be compacted, for example, into granules with an average particle size of 200 μm. Suitable microcrystalline cellulose is available commercially for example under the trade name Avicel ^®.

Further disintegrants which may be present in the context of the invention, such as, for example, collidone, alginic acid and its alkali metal salts, amorphous or also partially crystalline sheet silicates (bentonites), polyacrylates, polyethylene glycols are, for example, the publications WO 98/40462 (Rettenmaier), WO 98/55583 and WO 98/55590 (Unilever) and WO 98/40463, DE 19709991 and DE 19710254 (Henkel). Reference is expressly made to the teaching of these writings. The disintegrants obtainable by the process according to the invention can be present homogeneously distributed in the shaped body from a macroscopic point of view, but from a microscopic point of view they form zones of increased concentration due to production.

The accelerated resolution the molded body can also according to the invention Pregranulation of the other constituents of the molded body achieved become.

In a preferred embodiment contain the shaped body according to the invention these in addition to Ausflösungsbeschleuniger a mixture of starch and at least one saccharide. The use of disaccharides according to this embodiment is preferred. Said mixture is preferably in a weight ratio of Strength and the saccharides used from 10: 1 to 1:10, particularly preferably from 1: 1 to 1 10, very particularly preferably from 1: 4 to 1: 7 in the molded body in front.

The disaccharides used are preferably selected from lactose, maltose, sucrose, Trehalose, turanose, gentiobiose, melibiose and cellobiose. Especially lactose, maltose and sucrose are preferred and very particularly preferably lactose used in the moldings according to the invention.

The Strength-disaccharide mixture is in the molded body in an amount of 5 to 60% by weight, preferably 20 to 40% by weight based on the mass of the entire molded body.

Builders can be another essential constituent of the moldings according to the invention. Typical examples of builders which are suitable as an optional component are zeolites, water glasses, phyllosilicates, phosphates and polycarboxylates. The fine crystalline, synthetic and bound water-containing zeolite which is frequently used as a detergent builder is preferably zeolite A and / or P. As zeolite P, for example, zeolite MAP ^(R) (commercial product from Crosfield) is particularly preferred. However, zeolite X and mixtures of A, X and / or P and Y are also suitable. Of particular interest is also a cocrystallized sodium / potassium aluminum silicate made of zeolite A and zeolite X, which as VEGOBOND AX ^® (commercial product from Condea Augusta SpA) is commercially available. The zeolite can be used as a spray-dried powder or as an undried stabilized suspension that is still moist from its production. In the event that the zeolite is used as a suspension, it can contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3% by weight, based on zeolite, of ethoxylated C ₁₂ -C ₁₈ fatty alcohols with 2 to 5 ethylene oxide groups , C ₁₂ -C ₁₄ fatty alcohols with 4 to 5 ethylene oxide groups or ethoxylated isotridecanols. Suitable zeolites have an average particle size of less than 10 μm (volume distribution; measurement method: Coulter Counter) and preferably contain 18 to 22% by weight, in particular 20 to 22% by weight, of bound water.

Suitable substitutes or partial substitutes for phosphates and zeolites are crystalline, layered sodium silicates of the general formula NaMSi _x O _{2x + 1} .yH ₂ O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4. Such crystalline layered silicates are described, for example, in the European patent application EP 0164514 A1 described. Preferred crystalline layered silicates of the formula given are those in which M represents sodium and x assumes the values 2 or 3. In particular, both β- and δ-sodium disilicate Na ₂ Si ₂ O ₅ .yH ₂ O are preferred, wherein β-sodium disilicate can be obtained, for example, by the method described in international patent application WO 91/08171. Further suitable layer silicates are, for example, from the patent applications DE 2334899 A1 . EP 0026529 A1 and DE 3526405 A1 known. Their usability is not limited to a special composition or structural formula. However, smectites, in particular bentonites, are preferred here. Suitable layered silicates, which belong to the group of water-swellable smectites, are, for example, those of the general formulas (OH) ₄ Si _8-y Al _y (Mg _x Al _4-x ) O ₂₀ montmorrilonite (OH) ₄ Si _8-y Al _y (Mg _6-z Li _z ) O ₂₀ hectorite (OH) ₄ Si _8-y Al _y (Mg ₆ - _z Al _z ) O ₂₀ saponite with x = 0 to 4, y = 0 to 2, z = 0 to 6. In addition, small amounts of iron can be incorporated into the crystal lattice of the layered silicates according to the above formulas. Furthermore, due to their ion-exchanging properties, the layered silicates can contain hydrogen, alkali, alkaline earth ions, in particular Na ⁺ and Ca ²⁺ . The amount of water of hydration is usually in the range from 8 to 20% by weight and is dependent on the swelling condition or on the processing. Useful layer silicates are, for example, from US 3,966,629 . US 4,062,647 . EP 0026529 A1 and EP 0028432 A1 known. Layered silicates are preferably used which are largely free of calcium ions and strongly coloring iron ions due to an alkali treatment.

The preferred builder substances also include amorphous sodium silicates with a modulus Na ₂ O: SiO ₂ from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2, 6, which are delayed release. The delay in dissolution compared to conventional amorphous sodium silicates can be caused in various ways, for example by surface treatment, compounding, compacting / compression or by overdrying. In the context of this invention, the term “amorphous” is also understood to mean “X-ray amorphous”. This means that the silicates in X-ray diffraction experiments do not provide sharp X-ray reflections, as are typical for crystalline substances, but at most one or more maxima of the scattered X-rays, which have a width of several degree units of the diffraction angle. However, it can very well lead to particularly good builder properties if the silicate particles provide washed-out or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline areas of size 10 to a few hundred nm, values up to max. 50 nm and in particular up to max. 20 nm are preferred. Such so-called X-ray amorphous silicates, which also have a delay in dissolution compared to conventional water glasses, are described, for example, in the German patent application dung DE 4400024 A1 described. Compacted / compacted amorphous silicates, compounded amorphous silicates and over-dried X-ray amorphous silicates are particularly preferred.

It goes without saying it is also possible to use the generally known phosphates as builder substances, provided that such use is not avoided for ecological reasons should be. The sodium salts of the orthophosphates are particularly suitable, the pyrophosphates and especially the tripolyphosphates. Your salary is generally not more than 25% by weight, preferably not more than 20 wt .-%, each based on the finished agent. In some make it has been shown that tripolyphosphates in particular are already in small amounts up to a maximum of 10% by weight, based on the finished agent, in combination with other builder substances to a synergistic Improve secondary washing ability.

useful organic builders, those that come into question as co-builders are, for example, those in the form their sodium salts usable polycarboxylic acids, such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), unless such use for ecological reasons objectionable, and mixtures of these. Preferred salts are the salts of polycarboxylic acids like citric acid, adipic acid, Succinic acid, Glutaric acid, tartaric acid, sugar acids and Mixtures of these. The acids themselves can also be used become. The acids In addition to their builder effect, they typically also have the property an acidifying component and thus also serve to set a lower and milder one pH value of detergents or cleaning agents. In particular, here are citric acid, Succinic acid, glutaric, adipic acid, gluconic and to name any mixtures of these.

Other suitable organic builder substances are dextrins, for example oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches. The hydrolysis can be carried out by customary, for example acid or enzyme-catalyzed, processes. They are preferably hydrolysis products with average molecular weights in the range from 400 to 500,000. A polysaccharide with a dextrose equivalent (DE) in the range from 0.5 to 40, in particular from 2 to 30, is preferred, DE being a customary measure for the reducing effect of a polysaccharide compared to dextrose, which has a DE of 100. Both maltodextrins with a DE between 3 and 20 and dry glucose syrups with a DE between 20 and 37 as well as so-called yellow dextrins and white dextrins with higher molar masses in the range from 2,000 to 30,000 can be used. A preferred dextrin is in the British patent application GB 9419091 A1 described. The oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function. Such oxidized dextrins and processes for their production are, for example, from the European patent applications EP 0232202 A1 . EP 0427349 A1 . EP 0472042 A1 and EP 0542496 A1 as well as the international patent applications WO 92/18542, WO 93/08251, WO 93/16110, WO 94/28030, WO 95/07303, WO 95/12619 and WO 95/20608. An oxidized oligosaccharide according to the German patent application is also suitable DE 19600018 A1 , A product oxidized at C _{6 of} the saccharide ring can be particularly advantageous.

Other suitable cobuilders are oxydisuccinates and other derivatives of disuccinates, preferably ethylenediamine disuccinate. In this context, glycerol disuccinates and glycerol trisuccinates, such as those described, for example, in the US patents, are particularly preferred US 4,524,009 . US 4,639,325 , in the European patent application EP 0150930 A1 and Japanese patent application JP 93/339896. Suitable amounts used in formulations containing zeolite and / or silicate are 3 to 15% by weight. Other useful organic cobuilders are, for example, acetylated hydroxycarboxylic acids or their salts, which may also be in lactone form and which contain at least 4 carbon atoms and at least one hydroxyl group and a maximum of two acid groups. Such cobuilders are described, for example, in international patent application WO 95/20029.

Suitable polymeric polycarboxylates are, for example, the sodium salts of polyacrylic acid or polymethacrylic acid, for example those with a relative molecular weight of 800 to 150,000 (based on acid and measured in each case against polystyrene sulfonic acid). Suitable copolymeric polycarboxylates are, in particular, those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid. Copolymers of acrylic acid with maleic acid which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid have proven to be particularly suitable. Their relative molecular weight, based on free acids, is generally 5,000 to 200,000, preferably 10,000 to 120,000 and in particular 50,000 to 100,000 (measured in each case against polystyrene sulfonic acid). The (co) polymeric polycarboxylates can be used either as a powder or as an aqueous solution, 20 to 55% by weight aqueous solution solutions are preferred. Granular polymers are usually subsequently mixed into one or more basic granules. Also particularly preferred are biodegradable polymers made up of more than two different monomer units, for example those which according to the DE 4300772 A1 as monomeric salts of acrylic acid and maleic acid as well as vinyl alcohol or vinyl alcohol derivatives or according to the DE 4221381 C2 contain as monomers salts of acrylic acid and 2-alkylallylsulfonic acid and sugar derivatives. Other preferred copolymers are those described in the German patent applications DE 4303320 A1 and DE 4417734 A1 are described and preferably have acrolein and acrylic acid / acrylic acid salts or acrolein and vinyl acetate as monomers. Also to be mentioned as further preferred builder substances are polymeric aminodicarboxylic acids, their salts or their precursor substances. Polyaspartic acids or their salts and derivatives are particularly preferred.

Other suitable builder substances are polyacetals, which are obtained by reacting dialdehydes with polyolcarboxylic acids which have 5 to 7 carbon atoms and at least 3 hydroxyl groups, for example as in the European patent application EP 0280223 A1 described, can be obtained. Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from polyol carboxylic acids such as gluconic acid and / or glucoheptonic acid.

If required can the final preparations of the moldings still inorganic salts as filling or Containing agents, such as sodium sulfate, which preferably in amounts of 0 to 10, in particular 1 to 5% by weight on medium - included is.

The Consumers may be particularly impressed with the perception of the moldings through a spherical Shape of the molded body, optionally in conjunction with aromatic fragrance notes, the colorant according to the invention with a luxury food such as. Confectionery get in touch. This association can, in particular in children, oral intake or swallowing Molded body in principle cannot be excluded. In a preferred embodiment The moldings according to the invention therefore contain a bitter substance to prevent swallowing or accidental ingestion. Bitter substances according to the invention preferred in water at 20 ° C at least 5 g / l soluble are.

Regarding an unwanted Interaction with any fragrance components contained in the shaped body, especially a change of the fragrance perceived by the consumer, have the ionogenic Bitter substances have proven to be superior to the non-ionic ones. ionogenic Bitter substances, preferably consisting of organic cations) and organic anion (s), are therefore for the preparations according to the invention prefers.

Quaternary ammonium compounds which contain an aromatic group both in the cation and in the anion are particularly suitable as bitter substances. One such compound is commercially available for example under the trademark Bitrex ^® and Indigestin ^® available benzyldiethyl ((2,6-Xylylcarbamoyl) methyl) ammonium benzoate. This compound is also known as Denatonium Benzoate.

The Bitter substance is in the moldings according to the invention in amounts of 0.0005 up to 0.1 wt .-%, based on the molded body. Especially amounts of 0.001 to 0.05% by weight are preferred.

Next the above-mentioned preferred components can do this In principle, all other preparations, the expert for such cosmetics known components contain.

• – nichtionische Polymere wie beispielsweise Vinylpyrrolidon/Vinylacrylat-Copolymere, Polyvinylpyrrolidon und Vinylpyrrolidon/Vinylacetat-Copolymere und Polysiloxane,
• – Verdickungsmittel wie Agar-Agar, Guar-Gum, Alginate, Xanthan-Gum, Gummi arabicum, Karaya-Gummi, Johannisbrotkernmehl, Leinsamengummen, Dextrane, Cellulose-Derivate, z. B. Methylcellulose, Hydroxyalkylcellulose und Carboxymethylcellulose, Stärke-Fraktionen und Derivate wie Amylose, Amylopektin und Dextrine, Tone wie z. B. Bentonit oder vollsynthetische Hydrokolloide wie z. B. Polyvinylalkohol,
• – haarkonditionierende Verbindungen wie Phospholipide, beispielsweise Sojalecithin, Ei-Lecitin und Kephaline, sowie Silikonöle,
• – Parfümöle, Dimethylisosorbid und Cyclodextrine,
• – Lösungsmittel und -vermittler wie Ethanol, Isopropanol, Ethylenglykol, Propylenglykol, Glycerin und Diethylenglykol,
• – symmetrische und unsymmetrische, lineare und verzweigte Dialkylether mit insgesamt zwischen 12 bis 36 C-Atomen, insbesondere 12 bis 24 C-Atomen, wie beispielsweise Di-n-octylether, Di-n-decylether, Di-n-nonylether, Di-n-undecylether und Di-n-dodecylether, n-Hexyl-n-octylether, n-Octyl-n-decylether, n-Decyl-n-undecylether, n-Undecyl-n-dodecylether und n-Hexyl-n-Undecylether sowie Di-tert-butylether, Di-iso-pentylether, Di-3-ethyldecylether, tert.-Butyl-n-octylether, iso-Pentyl-n-octylether und 2-Methyl-pentyl-n-octylether,
• – Fettalkohole, insbesondere lineare und/oder gesättigte Fettalkohole mit 8 bis 30 C-Atomen,
• – Monoester von C8 bis C30-Fettsäuren mit Alkoholen mit 6 bis 24 C-Atomen,
• – faserstrukturverbessernde Wirkstoffe, insbesondere Mono-, Di- und Oligosaccharide, wie beispielsweise Glucose, Galactose, Fructose, Fruchtzucker und Lactose,
• – konditionierende Wirkstoffe wie Paraffinöle, pflanzliche Öle, z. B. Sonnenblumenöl, Orangenöl, Mandelöl, Weizenkeimöl und Pfirsichkernöl sowie
• – Phospholipide, beispielsweise Sojalecithin, Ei-Lecithin und Kephaline,
• – quaternierte Amine wie Methyl-1-alkylamidoethyl-2-alkylimidazolinium-methosulfat,
• – Entschäumer wie Silikone,
• – Farbstoffe zum Anfärben des Mittels,
• – Antischuppenwirkstoffe wie Piroctone Ölamine, Zink Omadine und Climbazol,
• – Wirkstoffe wie Allantoin und Bisabolol,
• – Cholesterin,
• – Konsistenzgeber wie Zuckerester, Polyolester oder Polyolalkylether,
• – Fette und Wachse wie Walrat, Bienenwachs, Montanwachs und Paraffine,
• – Fettsäurealkanolamide,
• – Komplexbildner wie EDTA, NTA, β-Alanindiessigsäure und Phosphonsäuren,
• – Quell- und Penetrationsstoffe wie primäre, sekundäre und tertiäre Phosphate,
• – Trübungsmittel wie Latex, Styrol/PVP- und Styrol/Acrylamid-Copolymere
• – Perlglanzmittel wie Ethylenglykolmono- und -distearat sowie PEG-3-distearat,
• – Pigmente,
• – Reduktionsmittel wie z. B. Thioglykolsäure und deren Derivate, Thiomilchsäure, Cysteamin, Thioäpfelsäure und α-Mercaptoethansulfonsäure,
• – Treibmittel wie Propan-Butan-Gemische, N₂O, Dimethylether, CO₂ und Luft,
• – Antioxidantien.

Other active ingredients, auxiliaries and additives are, for example

• Non-ionic polymers such as, for example, vinyl pyrrolidone / vinyl acrylate copolymers, polyvinyl pyrrolidone and vinyl pyrrolidone / vinyl acetate copolymers and polysiloxanes,
• Thickeners such as agar agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. B. methyl cellulose, hydroxyalkyl cellulose and carboxymethyl cellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays such. B. bentonite or fully synthetic hydrocolloids such. B. polyvinyl alcohol,
• Hair-conditioning compounds such as phospholipids, for example soy lecithin, egg lecithin and cephalins, and silicone oils,
• - perfume oils, dimethyl isosorbide and cyclodextrins,
• Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol,
• - Symmetrical and asymmetrical, linear and branched dialkyl ethers with a total of between 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n -undecyl ether and di-n-dodecyl ether, n-hexyl-n-octyl ether, n-octyl-n-decyl ether, n-decyl-n-undecyl ether, n-undecyl-n-dodecyl ether and n-hexyl-n-undecyl ether and Di tert-butyl ether, di-iso-pentyl ether, di-3-ethyl decyl ether, tert-butyl-n-octyl ether, iso-pentyl-n-octyl ether and 2-methyl-pentyl-n-octyl ether,
• Fatty alcohols, in particular linear and / or saturated fatty alcohols with 8 to 30 carbon atoms,
• - Monoesters of C8 to C30 fatty acids with alcohols with 6 to 24 carbon atoms,
• Active ingredients that improve fiber structure, in particular mono-, di- and oligosaccharides, such as, for example, glucose, galactose, fructose, fructose and lactose,
• - conditioning agents such as paraffin oils, vegetable oils, e.g. B. sunflower oil, orange oil, almond oil, wheat germ oil and peach seed oil as well
• Phospholipids, for example soy lecithin, egg lecithin and cephalins,
• Quaternized amines such as methyl 1-alkylamidoethyl-2-alkylimidazolinium methosulfate,
• - defoamers like silicones,
• Dyes for coloring the agent,
• - anti-dandruff agents such as piroctone oil amines, zinc omadine and climbazol,
• - active ingredients such as allantoin and bisabolol,
• - cholesterol,
• - consistency enhancers such as sugar esters, polyol esters or polyol alkyl ethers,
• - fats and waxes such as walrus, beeswax, montan wax and paraffins,
• - fatty acid alkanolamides,
• Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,
• Swelling and penetration substances such as primary, secondary and tertiary phosphates,
• - opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers
• Pearlescent agents such as ethylene glycol mono- and distearate and PEG-3 distearate,
• - pigments,
• - Reducing agents such. B. thioglycolic acid and its derivatives, thiolactic acid, cysteamine, thio malic acid and α-mercaptoethanesulfonic acid,
• Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,
• - antioxidants.

Regarding others optional components and the amounts of these components used expressly to the relevant manuals known to those skilled in the art, e.g. B. the above Monograph referenced by K. H. Schrader.

The Shaped bodies according to the invention can be any take on a geometric shape, such as concave, convex, biconcave, biconvex, cubic, tetragonal, orthorhombic, cylindrical, spherical, cylindrical segment-like, disc-shaped, tetrahedral, dodecahedral, octahedral, conical, pyramidal, ellipsoid, five, seven- and octagonal-prismatic as well as rhombohedral shapes. Completely irregular areas like Arrow or animal shapes, trees, Clouds etc. will be realized. The training as a board, the rod or bar shape, Cube, Cuboid and corresponding room elements with flat side surfaces as well especially cylindrical Circular designs or oval cross-section and shaped body with spherical Geometry is preferred according to the invention. Shaped bodies are particularly preferred in the shape of spherical Geometry.

The cylindrical Design captured the presentation form from the tablet to compact cylinder pieces a relationship of height to diameter larger than 1. Knows the base molding corners and edges, they are preferably rounded. As an additional optical differentiation is an embodiment with rounded Corners and beveled ("chamfered") edges preferred.

In a preferred embodiment can the portioned compacts each formed as separate individual elements be the predetermined dosage of the cosmetic active ingredients equivalent. But it is also possible compacts to form a plurality of such mass units in one compact connect, in particular by predetermined predetermined breaking points the easy separability of portioned smaller units is provided is. The formation of the portioned compacts as tablets in cylindrical or cuboid shape can be useful with a diameter / height ratio in Range of about 0.5: 2 to 2: 0.5 is preferred. Commercial hydraulic presses, Eccentric presses or rotary presses are suitable devices in particular for the production of such Compacts.

The preferred spatial shape of the shaped bodies according to the invention has a rectangular shape Footprint on, being the height the molded body is smaller than the smaller rectangle side of the base area. Rounded edges are preferred for this type of offer.

On further preferred shaped body, that can be manufactured has a plate-like or panel-like structure with alternately thick long and thin short segments so that individual segments of this "bolt" at the predetermined breaking points, the short thin ones Display segments, broken off and used in such portions can come. This principle of the "bar-shaped" shaped body can also in other geometric shapes, for example vertical ones Triangles that are connected to each other only on one of their sides are to be realized.

Contain the moldings according to the invention at least two cosmetic active ingredients, it can be in a further embodiment be advantageous not only to the various components a single tablet. When tableting are in this embodiment moldings get multiple layers, i.e. at least two layers, exhibit. It is also possible that these different layers have different dissolving speeds exhibit. From this you can advantageous application properties of the molded articles result. If, for example, components are contained in the moldings, the affect each other negatively, so it is possible to use one component in the faster soluble Integrate layer and the other component in a slower soluble Incorporate layer so that the components are not already during the release operation react with each other.

The Layer structure of the moldings can be done both in stacks, with a solution of the inner layers) on the edges of the molded body, if the outer layers not yet complete solved are. With the stacked The stacking axis can be arranged as desired in relation to the tablet axis his. The stacking axis can thus, for example, in the case of a cylindrical tablet parallel or perpendicular to the height of the cylinder.

It can also according to one another embodiment be preferred if a complete wrapping of the inner layers) by the respective outer layers) is achieved, which prevents the premature release of components of the inner layers). Shaped bodies are preferred, in which the layers with the different active ingredients envelop each other. For example be a layer (A) complete of layer (B) and this in turn completely encased by layer (C). As well can moldings be preferred in which e.g. the layer (C) completely of the layer (B) and this in turn is completely enveloped by the layer (A).

Similar Effects can also be achieved by coating individual components of the parts to be pressed Reach composition or the entire molded body. For this, the body to be coated for example with aqueous solutions or emulsions become, or about the process of melt coating received a coating.

The produced according to the invention (Troughs) shaped bodies can fully or partially provided with a coating. Method, in which a post-treatment in applying a coating layer the molded surface (s), in which the filled (n) Trough (s), or in the application of a coating layer on the entire molded body there are preferred according to the invention.

After pressing, the shaped bodies have a high degree of stability. The breaking strength of cylindrical shaped bodies can be determined via the measured variable of the diametrical breaking load. This can be determined according to

Here in σ stands for the diametric Diametric fracture stress (DFS) in Pa, P is the force in N, which leads to the pressure exerted on the molded body, the the breakage of the molded body caused, D is the shaped body diameter is the height in meters and t the molded body.

The moldings of the present invention preferably have a density of 0.3 g / cm ³ to 2.0 g / cm ³ , in particular 0.5 g / cm ³ to 1.1 g / cm ³ .

Furthermore, the moldings according to the invention can be made from a base molding with the term “base molding by "described, which is produced per se by known tabletting processes and has a depression. Preferably, the basic molded body is first produced and the further compressed part is applied to or introduced into this basic molded body in a further working step. The resulting product is described below designated with the generic term "trough shaped body" or "trough tablet".

The Basic tablet can in principle according to the invention accept all feasible forms of space. Are particularly preferred the spatial shapes already mentioned above. The shape of the trough can be free to get voted, molded articles preferred according to the invention are in which at least one trough is a concave, convex, cubic, tetragonal, orthorhombic, cylindrical, spherical, segment-like, disc-shaped, tetrahedral, dodecahedral, octahedral, conical, pyramidal, ellipsoid, five, seven- and octagonal-prismatic as well as rhombohedral shape. Completely irregular trough shapes like arrow or animal shapes, trees, Clouds etc. will be realized. As with the basic shaped bodies, the troughs are rounded Corners and edges or with rounded corners and touched edges prefers.

The Size of the trough compared to the entire molded body depends on the desired Intended use of the molded body. Depending on whether in the second pressed part a smaller or larger amount the size of the trough can be contained in active substance vary. Independently molded articles are of use preferred, in which the weight ratio of the base molding to depression filling in the range from 1: 1 to 100: 1, preferably from 2: 1 to 80 : 1, particularly preferably from 3: 1 to 50: 1 and in particular from 4: 1 to 30: 1.

Similar Statements can be made about the surface proportions that the Basic tablet or the trough filling on the total surface of the shaped body turn off. Here are moldings preferred where the surface the pressed-in cavity filling 1 to 25%, preferably 2 to 20%, particularly preferably 3 to 15% and in particular accounts for 4 to 10% of the total surface area of the filled base molding.

If, for example, the overall shaped body has dimensions of 20 × 20 × 40 mm and thus a total surface area of 40 cm ² , trough fillings are preferred which have a surface area of 0.4 to 10 cm ² , preferably 0.8 to 8 cm ² , particularly preferably of Have 1.2 to 6 cm ² and in particular from 1.6 to 4 cm ² .

The depression filling and the base molding are preferably colored visually distinguishable. In addition to the optical differentiation have tablets on the one hand application technology advantages through different solubilities of the different areas on the other hand, but also by the separate Storage of the active ingredients in the different shaped body areas on.

Molded body, at which the pressed-in trough filling loosens more slowly than the Base moldings are preferred according to the invention. By incorporating certain components, on the one hand, the Solubility of depression filling specifically varied, on the other hand, the release of certain Ingredients from the trough filling lead to advantages in the application process.

It can be preferred according to the invention be, individual active ingredients separately before their incorporation into the molded body to encapsulate; for example, it is conceivable, especially reactive To use components or the fragrances in encapsulated form.

The The molded articles according to the invention are produced first by dry mixing the ingredients, all or part can be pre-granulated and then Inform, in particular compression to tablets, with known ones Procedure can be. The premix is prepared in a so-called die between two stamps into a fixed one Compressed compressed. This process, briefly referred to below as Tabletting is divided into four sections: Dosage, compression (elastic deformation), plastic deformation and expelling.

First of all, the premix is introduced into the die, the filling quantity and thus the weight and the shape of the molding being formed being determined by the position of the lower punch and the shape of the pressing tool. The constant metering, even at high molding throughputs, is preferably achieved by volumetric metering of the premix. As the tableting continues, the upper punch touches the premix and lowers further towards the lower punch. During this compression, the particles of the premix are pressed closer together, the hollow volume within the filling between the stamps decreases continuously. From a certain position of the upper punch (and thus from a certain pressure on the premix), the plastic deformation begins, in which the particles flow together and the molded body is formed. Depending on the physical properties of the premix, some of the premix particles are also crushed and sintering of the premix occurs at even higher pressures. With increasing press speed, that is to say high throughput quantities, the phase of elastic deformation is shortened further and further, so that the resulting shaped bodies can have more or less large cavities. In the last step of tableting, the finished molded body is pressed out of the die by the lower punch and transported away by subsequent transport devices. At this point in time, only the weight of the molded body is finally determined, since the compacts can still change their shape and size due to physical processes (stretching, crystallographic effects, cooling, etc.).

The Tableting takes place in commercially available Tablet presses, which are basically equipped with single or double stamps can. In the latter case, it is not only the upper stamp that builds up pressure used, the lower punch also moves during the pressing process towards the upper stamp during the Upper stamp presses down. For little ones Production quantities are preferably eccentric tablet presses, where the stamp or stamps are attached to an eccentric disc are, in turn, on an axis with a certain rotational speed is mounted. The movement of these stamps is with the way of working of a usual Four-stroke engine comparable. The pressing can be done with an upper and lower stamps can be made but also several stamps can be attached to an eccentric disc, the number of die holes is expanded accordingly. The throughputs of eccentric presses vary from a few hundred to depending on the type maximum 3000 tablets per hour.

For larger throughputs you choose Rotary tablet presses on a so-called die table A larger number of matrices circular is arranged. The number of matrices varies depending on the model 6 and 55, including larger matrices available in the stores are. Each die on the die table is an upper and lower stamp assigned, whereby the pressing pressure is active only by the upper or lower stamp, but also be built up by both stamps can. The die table and the stamp move around a common one vertical axis, the stamp using rail-like Curve tracks during of circulation in the positions for filling, Compression, plastic deformation and discharge are brought. In the places where a particularly serious increase or decrease in Stamp is required (filling, Compression, ejection), these curved tracks are created by additional low-pressure pieces, pull-down rails and lift tracks supported. The filling the die is made over a rigidly arranged feed device, the so-called filling shoe, the one with a storage container for the Premix is connected. The pressure on the premix is above the Press paths for Upper and lower stamp individually adjustable, the pressure build-up by rolling the stamp shaft heads past adjustable pressure rollers happens.

Rotary presses can to increase throughput also with two filling shoes be provided, with only one to produce a tablet Semicircle must be run through. For the production of two and more layers moldings become several filling shoes arranged one behind the other without the lightly pressed first Shift before further filling pushed out becomes. Through suitable process control it is also possible to produce coated and dot tablets in this way, which have an onion skin-like structure, whereby in the case of Dot tablets do not cover the top of the core or core layers and remains visible. Rotary tablet presses are also available Can be equipped with single or multiple tools, for example an outer circle with 50 and an inner circle with 35 holes simultaneously for pressing to be used. The throughputs modern rotary tablet presses are over one million tablets per Hour.

• – Verwendung von Kunststoffeinlagen mit geringen Dickentoleranzen
• – Geringe Umdrehungszahl des Rotors
• – Große Füllschuhe
• – Abstimmung des Füllschuhflügeldrehzahl auf die Drehzahl des Rotors
• – Füllschuh mit konstanter Pulverhöhe
• - Entkopplung von Füllschuh und Pulvervorlage

When tableting with rotary presses, it has proven to be advantageous to carry out the tabletting with the smallest possible fluctuations in the weight of the tablet. The fluctuations in hardness of the tablet can also be reduced in this way. Small fluctuations in weight can be achieved in the following ways:

• - Use of plastic inserts with small thickness tolerances
• - Low number of revolutions of the rotor
• - Big filling shoes
• - Matching the filler paddle speed to the speed of the rotor
• - Filling shoe with constant powder height
• - Decoupling of filling shoe and powder feed

to All of them offer a reduction in stamp caking non-stick coatings known from the art. Particularly advantageous are plastic coatings, plastic inserts or plastic stamps. Rotating punches have also proven to be advantageous, whereby if possible The upper and lower stamps should be rotatable. With rotating Stamping can usually be done without a plastic insert become. The stamp surfaces should be electropolished here.

It it was also shown that long press times are advantageous. these can with pressure rails, several pressure rollers or low rotor speeds can be set. Because the fluctuations in hardness the tablet should be caused by the fluctuations in the pressing forces Systems are used that limit the pressing force. Here elastic Stamps, pneumatic compensators or spring elements in the force path be used. The pressure roller can also be designed to be resilient.

in the Suitable tableting machines within the scope of the present invention are available from the companies Apparatebau Holzwarth GbR, Asperg, Wilhelm Fette GmbH, Schwarzenbek, Fann Instruments Company, Houston, Texas (USA), Hofer GmbH, Weil, Horn & Noack Pharmatechnik GmbH, Worms, IMA Verpackungssysteme GmbH Viersen, KILIAN, Cologne, KOMAGE, Kell am See, KORSCH Pressen AG, Berlin, and Romaco GmbH, Worms. Other providers include Dr. Herbert Pete, Vienna (AT), Mapag Maschinenbau AG, Bern (CH), BWI Manesty, Liverpool (GB), I. Holand Ltd., Nottingham (GB), Courtoy N.V., Halle (BE / LU) and Mediopharm Kamnik (SI). For example, the Hydraulic double printing press HPF 630 from LAEIS, D. tableting tools are, for example, from Adams Tablettierwerkzeuge, Dresden, Wilhelm Fett GmbH, Schwarzenbek, Klaus Hammer, Solingen, Herber & Söhne GmbH, Hamburg, Hofer GmbH, Weil, Horn & Noack, Pharmatechnik GmbH, Worms, Ritter Pharamatechnik GmbH, Hamburg, Romaco, GmbH, Worms and Notter Werkzeugbau, Tamm available. Other providers are e.g. Senss AG, Reinach (CH) and Medicopharm, Kamnik (SI).

The However, the method for producing the shaped bodies is not based on this limited, that just a particulate Premix to a shaped body is pressed. Rather leaves the process can also be expanded to include in itself known manner produces multilayered molded articles by two or prepares several premixes that are pressed together. Here the first one is filled Premixed slightly pre-compressed to create a smooth and parallel to the Floor moldings to get the running top, and after filling the second premix to the finished molded body finally pressed. In the case of three-layer or multi-layer moldings after each premix addition a further pre-compression before adding the last premix the molded body is finally pressed.

The Compression of the particulate Composition in the trough can be analogous to the manufacture of the base moldings Tablet presses take place. A procedure is preferred for which is only the basic shaped body made with trough, then filled and subsequently be pressed again. This can be done by ejecting the base molding a first tablet press, filling and transport in one second tablet press in which the final compression takes place. Alternatively, the final compression can also be carried out by pressure rollers that run over the Roll molded articles on a conveyor belt. It is but also possible a rotary tablet press with different stamp sets to be provided so that a first set of stamps presses depressions into the moldings and the second set of stamps after filling by repressing for a flat molded body surface ensures.

The Shaped articles according to the invention can the production are packed, the use of certain Packaging systems especially proven has because the packaging systems on the one hand the storage stability of the ingredients increase, on the other hand, however, the long-term liability of the trough filling may also be significant improve. The term "packaging system" denotes always the primary packaging in the context of the present invention the molded body, i.e. the packaging, which directly contacts the inside of the molded body is. An optional secondary packaging there are no requirements, so all the usual ones Materials and systems can be used.

berechnen, wobei A die Fläche des zu testenden Materials in cm², x die Gewichtszunahme des Calciumchlorids in g und y die Expositionszeit in h bedeutet.Packaging systems which have only a low moisture permeability are preferred according to the invention. In this way, the shaped body according to the invention can be obtained over a longer period of time, even if, for example, hygroscopic components are used in the shaped bodies. Packaging systems which have a moisture vapor permeability rate of 0.1 g / m ² / day to less than 20 g / m ² / day are particularly preferred if the packaging system is stored at 23 ° C. and a relative equilibrium moisture content of 85%. The specified temperature and humidity conditions are the test conditions that are mentioned in DIN standard 53122, whereby according to DIN 53122 minimal deviations are permitted (23 ± 1 ° C, 85 ± 2% relative humidity). The moisture vapor transmission rate of a The given packaging system or material can be determined using other standard methods and is also, for example, in the ASTM standard E-96-53T ("Test for measuring Water Vapor transmission of Materials in Sheet form") and in the TAPPI standard T464 m-45 ("Water Vapor Permeability of Sheet Materials at high temperature at Humidity "). The measuring principle of current methods is based on the water absorption of anhydrous calcium chloride, which is stored in a container in the appropriate atmosphere, the container being closed at the top with the material to be tested. The moisture vapor permeability rate can be determined from the surface of the container which is closed with the material to be tested (permeation surface), the weight gain of the calcium chloride and the exposure time

calculate, where A is the area of the material to be tested in cm ² , x is the weight gain of calcium chloride in g and y is the exposure time in h.

The relative equilibrium humidity, often referred to as "relative humidity", is 85% at 23 ° C. when measuring the moisture vapor transmission rate in the context of the present invention. The absorption capacity of air for water vapor increases with the temperature up to a respective maximum content, the so-called saturation content, and is given in g / m ³ . For example, 1 m ^{3 of} air at 17 ° is saturated with 14.4 g of water vapor; at a temperature of 11 ° there is saturation with just 10 g of water vapor. The relative humidity is the ratio of the actual water vapor content to the saturation content corresponding to the prevailing temperature. For example, if air contains 17 ° 12 g / m ³ water vapor, then the relative humidity = (12 / 14.4) · 100 = 83%. If this air is cooled, then the saturation (100% r.L.) is reached at the so-called dew point (in the example: 14 °), ie, if it cools further, a precipitate is formed in the form of fog (dew). Hygrometers and psychrometers are used for the quantitative determination of moisture.

The relative equilibrium humidity of 85% at 23 ° C can be for example in laboratory chambers with moisture control depending on device type to +/- 2% RH adjust exactly. Also about saturated Solutions of certain Salts form in closed systems at a given temperature constant and well-defined relative air humidity on the phase equilibrium between partial pressure of water, more saturated solution and soil body based.

The Combinations of molded articles and packaging system can Of course in turn in secondary packaging, for example, cardboard boxes or trays, are packed, whereby the secondary packaging no further requirements have to be made. The secondary packaging is therefore possible but not necessary.

The Packaging system depending on the embodiment the invention one or more moldings. It is preferred according to the invention either a molded body to design such that it is an application unit of the colorant includes, and this molded body to be packed individually, or the number of moldings in one packaging unit pack, which in total comprises an application unit. This Principle leaves self-evident expand, so that combinations according to the invention also three, four, five or more molded articles can be contained in one packaging unit. Of course, two can or more molded articles have different compositions in one package. On this way it is possible certain components spatially to separate from each other, for example, stability problems to avoid.

The Packaging system of the combination according to the invention can from the different materials exist and any external forms accept. For economic reasons establish and for the sake of However, packaging systems are preferred for easier processability, where the packaging material is light, light to process and inexpensive as well as ecological compatible is.

In a first preferred according to the invention The packaging system consists of a sack or combinations Bags made of single-layer or laminated paper and / or plastic film. You can the moldings unsorted, i.e. as a loose fill, be filled into a bag made of the materials mentioned. It but is from aesthetic establish and preferred for sorting the combinations in secondary packaging moldings to be filled individually or in groups in sacks or bags. This Packaging systems can then - again preferably sorted - optional be packed in outer packaging, what the compact offer form of the shaped body underlines.

The sacks or bags made of single-layer or laminated paper or plastic film, which are preferably used as a packaging system, can be designed in a wide variety of ways, for example as a blown-up bag without a central seam or as a bag with a central seam, which is sealed by heat (hot fusion), adhesives or adhesive tapes become. Single-layer bag or sack materials are the known papers, which may or may not be impregnated, and plastic films, which may or may not be co-extruded. Plastic films which can be used as a packaging system in the context of the present invention are specified, for example, in Hans Domininghaus "The plastics and their properties", 3rd edition, VDI Verlag, Düsseldorf, 1988, page 193. The one shown there 111 at the same time gives information on the water vapor permeability of the materials mentioned.

Even though it possible is, in addition to the films or papers mentioned, also wax-coated To use paper in the form of cardboard boxes as a packaging system for the shaped articles, it is preferred in the context of the present invention if the Packaging system does not include boxes made of wax-coated paper.

On the optional secondary packaging there are no requirements, so all the usual ones Materials and systems can be used.

Likewise Preferred embodiments are where the packaging system is designed to be resealable. It has, for example proven to be practical, a reclosable tube as a packaging system Use glass, plastic or metal. In this way is it possible that To optimize the dosability of the cosmetic products so that the For example, consumers can be guided per defined Use for example in the case of a hair treatment depending on the present Hair length unit one shaped body each to use. For example, the Hair length unit than 10 cm hair length per molded body To be defined. The consumer is then able to Dosage according to his individual hair length targeted over the Number of moldings used to control. Even packaging systems that have a microperforation, can be preferred according to the invention realize.

• (I) ein oder mehrere erfindungsgemäße Einmalportionen (A) aus der Verpackung entnommen werden und gegebenenfalls in einem Medium (M) unter Bildung der Zubereitung (AM) gelöst werden,
• (II) die erfindungsgemäße Einmalportion (A) oder gegebenenfalls die Zubereitung (AM) auf die Haut, die Nägel oder die keratinischen Fasern aufgetragen wird und
• (III) gegebenenfalls nach einer Einwirkzeit wieder abgespült wird.

A second object of the invention is a method for the cosmetic treatment of skin, nails or fibers containing keratin, in which

• (I) one or more disposable portions (A) according to the invention are removed from the packaging and, if appropriate, dissolved in a medium (M) to form the preparation (AM),
• (II) the single portion (A) according to the invention or optionally the preparation (AM) is applied to the skin, the nails or the keratin fibers and
• (III) optionally rinsed off after an exposure time.

If mixing with a medium (M) takes place Medium (M) preferably a cosmetic gel or a cosmetic O / W emulsion or a cosmetic W / O emulsion. The medium (M) has a viscosity from 500-50000 mPa.s, particularly preferably from 500-25000 mPa.s, very particularly preferably from 500-15000 mPa · s (Brookfield RVT viscometer / 20 ° C / spindle 4/20 rpm).

Under a rinse if necessary after a contact time it must be understood that the preparation (A) or (AM) on the skin, the nails or the keratin fibers are applied, there its intended effect, Cleaning, care etc. unfolded and after a contact time again rinsed becomes. The exposure time is usually in the range of a few seconds up to 1 hour and depends on the type of cosmetic Agent. However, this is known to the person skilled in the art. For example a rinse-off hair care product after a soak in the area 1 minute (hair rinse) up to 45 minutes (intensive hair treatment) on the keratin fibers or hair remain. If necessary, the exposure time can be changed the temperature, for example by using a drying hood or a hair dryer varies become. Here you can Temperatures between 20 ° C and 45 ° C measured on the skin, nails or the keratin fibers occur.

Examples

Unless otherwise noted, all quantities are parts by weight. Examples 1 and 2 are each packed piece by piece in single-use packaging, the remaining examples in quantities of 5.0 g to 30.0 g. The disposable packaging can consist of only a single container, or can be connected to one another on a card made of cardboard, plastic, etc. to form several, preferably up to 30, disposable single-use packs. 1. Styling tablet

The tablet is dissolved in 50 ml water in a cup or small bowl. A viscous gel forms, which can be applied to the keratin fibers as usual. 2. Foaming styling tablet

4. Deodorant

5. After Shave

6. Feuchtigkeitscreme mit Vitamin E

7. Reichhaltige Nachtpflege

8. Allzweckcreme

9. Reichhaltige W/O Creme

10. Natürlich tönende Tagescreme

12. Haarkur, leave-on

13. Leave-on Haarkur

14. Leave-on Haarkur

16. Haarkur

17. Haarmaske

18. Intensivhaarkur

19. Haarspitzenfliud

20. Leave-on Haarmilch

22. Haarfestiger

23. Styling-Wachs

24. 2-in-1 Shampoo

25. Konditioniershampoo

26. Babyshampoo

27. Perlglänzendes Pflegeshampoo

28. Schaumbad

29. Reinigungsmilch

30. Haarspülung Eumulgin^® B2 0,3 Cetyl/Stearylalkohol 3,3 Isopropylmyristat 0,5 Paraffinöl perliquidum 15 cSt. DAB 9 0,3 Dehyquart^®A-CA 2,0 Salcare^®SC 96 1,0 Citronensäure 0,4 Gluadin^® WQ 2,0 Phenonip^® 0,8 Wasser ad 100 31. Haarspülung Eumulgin^® B2 0,3 Cetyl/Stearylalkohol 3,3 Isopropylmyristat 0,5 Paraffinöl perliquidum 15 cSt. DAB 9 0,3 Dehyquart^®L 80 0,4 Cosmedia Guar^® C 261 1,5 Promois^® Milk-CAQ 3,0 Panthenol 0,5 Citronensäure 0,4 Phenonip^® 0,8 Wasser ad 100 32. Haarkur Dehyquart^® F75 4,0 Cetyl/Stearylalkohol 4,0 Paraffinöl perliquidum 15 cSt DAB 9 1,5 Dehyquart^®A-CA 4,0 Salcare^®SC 96 1,5 Amisafe-LMA-60^® 1,0 Gluadin^®W 20 3,0 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Citronensäure 0,15 Phenonip^® 0,8 Wasser ad 100 33. Haarkur Dehyquart^® L80 2,0 Cetyl/Stearylalkohol 6,0 Paraffinöl perliquidum 15 cSt DAB 9 2,0 Rewoquat^®W 75 2,0 Panthenol 0,5 Cosmedia Guar^® C261 0,5 Sepigel^®305 3,5 Honeyquat^® 50 1,0 Gluadin^® WQ 2,5 Gluadin^®W 20 3,0 Citronensäure 0,15 Phenonip^® 0,8 Wasser ad 100 34. Haarkur Dehyquart^® F75 0,3 Salcare^®SC 96 5,0 Gluadin^® WQ 1,5 Dow Corning^®200 Fluid, 5 cSt. 1,5 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Gafquat^®755N 1,5 Biodocarb^® 0,02 Parfümöl 0,25 Wasser ad 100 35. Haarkur Sepigel^®305 5,0 Dow Corning^®Q2-5220 1,5 Promois^® Milk Q 3,0 Polymer P1 entsprechend DE 3929173 0,6 Panthenol 0,5 Genamin^®DSAC 0,3 Phenonip^® 0,8 Parfümöl 0,25 Wasser ad 100 36. Shampoo Texapon^® NSO 40,0 Dehyton^® G 6,0 Polymer JR 400^® 0,5 Cetiol^® HE 0,5 Ajidew^® NL 50 1,0 Gluadin^® WQT 2,5 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Gluadin^® W 20 0,5 Panthenol (50%) 0,3 Vitamin E 0,1 Vitamin H 0,1 Citronensäure 0,5 Natriumbenzoat 0,5 Parfüm 0,4 NaCl 0,5 Wasser ad 100 37. Shampoo Texapon^® NSO 43,0 Dehyton^® K 10,0 Plantacare^® 1200 UP 4,0 Euperlan^®PK 3000²⁹ 1,6 Arquad^®316 0,8 Polymer JR^® 400 0,3 Gluadin^® WQ 4,0 Glucamate^®DOE 120 0,5 Panthenol 0,5 Natriumchlorid 0,2 Wasser ad 100 38. Shampoo Texapon^®N 70 21,0 Plantacare^® 1200 UP 8,0 Gluadin^® WQ 1,5 Cutina^® EGMS 0,6 Honeyquat^® 50 2,0 Ajidew^® NL 50 2,8 Antil^® 141 1,3 Panthenol 0,5 Natriumchlorid 0,2 Magnesiumhydroxid ad pH 4,5 Wasser ad 100 39. Shampoo Texapon^® K 14 S 50,0 Dehyton^® K 10,0 Plantacare^® 818 LTP 4,5 Polymer P1, entsprechend DE 39 29 973 0,6 Cutina^® AGS 2,0 D-Panthenol 0,5 Glucose 1,0 Panthenol 0,5 Salicylsäure 0,4 Natriumchlorid 0,5 Gluadin^® WQ 2,0 Wasser ad 100 40. Haarkur Celquat^® L 200 0,6 Luviskol^® K30 0,2 D-Panthenol 0,5 Polymer P1, entsprechend DE 39 29 973 0,6 Dehyquart^® A-CA 1,0 Gluadin^® W 40 1,0 Natrosol^® 250 HR 1,1 Dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanon 0,5 Gluadin^® WQ 2,0 Wasser ad 100 41. Gesichtswässer

42. Hydrogele

43. Hautemulsionen (O/W)

44. Stylinggel Acrysol^® ICS-1 1,5 g Plantacare^® 2000 UP 0,3 g Gaffix^® VC-713 3,0 g Dehyquart^® A-CA 1,0 g Luviskol VA 64 2,0 g Amino-2-methyl-2-propanol-1 ad pH 6,0 Wasser ad 100 g
Viskosität bei 25°C 2500 mPas, gemessen mit Brookfield RVT, Spindel 3 45. Stylinggel Aquaflex^® SF 40 1,5 g Dow Corning Surfactant 193 1,5 g Acrisint^® 400 0,8 g Amino-2-methyl-2-propanol-1 ad pH 5,5 Ethanol 30,0 g Wasser ad 100 46. Stylinggel Aquaflex^® SF 40 1,0 g Propylenglykol 5,0 g Carbopol^® ETD 2020 0,5 g Amino-2-methyl-2-propanol-1 ad pH 7 Eumulgin^® B1 0,4 g Panthenol 0,3 Glucose 3,0 Wasser ad 100 The tablet can be foamed into a foam by hand with the addition of water and then applied to the keratin fibers as usual. 3. Deodorant

4. Deodorant

5. After Shave

6. Moisturizer with vitamin E.

7. Rich night care

8. All-purpose cream

9. Rich W / O cream

10. Naturally toning day cream

12. Hair treatment, leave-on

13. Leave-on hair treatment

14. Leave-on hair treatment

16.Hair treatment

17. Hair mask

18. Intensive hair treatment

19. Hair tip fluid

20. Leave-on hair milk

22. Hair fixer

23. Styling wax

24. 2-in-1 shampoo

25. Conditioning shampoo

26. Baby shampoo

27. Pearlescent care shampoo

28. Bubble bath

29. Cleansing milk

30. Hair conditioner Eumulgin ^® B2 0.3 Cetyl / stearyl 3.3 isopropyl 0.5 Paraffin oil perliquidum 15 cSt. DAB 9 0.3 Dehyquart ^® A-CA 2.0 Salcare ^® SC 96 1.0 citric acid 0.4 Gluadin ^® WQ 2.0 Phenonip ^® 0.8 water ad 100 31. Hair conditioner Eumulgin ^® B2 0.3 Cetyl / stearyl 3.3 isopropyl 0.5 Paraffin oil perliquidum 15 cSt. DAB 9 0.3 Dehyquart ^® L 80 0.4 Cosmedia® guar ^® C 261 1.5 Promois® ^® Milk-CAQ 3.0 panthenol 0.5 citric acid 0.4 Phenonip ^® 0.8 water ad 100 32. Hair treatment Dehyquart ^® F75 4.0 Cetyl / stearyl 4.0 Paraffin oil perliquidum 15 cSt DAB 9 1.5 Dehyquart ^® A-CA 4.0 Salcare ^® SC 96 1.5 Amisafe-LMA-60 ^® 1.0 Gluadin ^® W 20 3.0 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 citric acid 0.15 Phenonip ^® 0.8 water ad 100 33. Hair treatment Dehyquart ^® L80 2.0 Cetyl / stearyl 6.0 Paraffin oil perliquidum 15 cSt DAB 9 2.0 Rewoquat ^® W 75 2.0 panthenol 0.5 Cosmedia® guar ^® C261 0.5 Sepigel ^® 305 3.5 Honeyquat ^® 50 1.0 Gluadin ^® WQ 2.5 Gluadin ^® W 20 3.0 citric acid 0.15 Phenonip ^® 0.8 water ad 100 34. Hair treatment Dehyquart ^® F75 0.3 Salcare ^® SC 96 5.0 Gluadin ^® WQ 1.5 Dow ^Corning® 200 Fluid, 5 cSt. 1.5 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 Gafquat ^® 755N 1.5 Biodocarb ^® 0.02 perfume oil 0.25 water ad 100 35. Hair treatment Sepigel ^® 305 5.0 Dow Corning ^® Q2-5220 1.5 Promois ^® Milk Q 3.0 Polymer P1 accordingly DE 3929173 0.6 panthenol 0.5 Genamin ^® DSAC 0.3 Phenonip ^® 0.8 perfume oil 0.25 water ad 100 36. Shampoo Texapon ^® NSO 40.0 Dehyton ^® G 6.0 Polymer JR 400 ^® 0.5 Cetiol ^® HE 0.5 Ajidew ^® NL 50 1.0 Gluadin ^® WQT 2.5 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 Gluadin ^® W 20 0.5 Panthenol (50%) 0.3 Vitamin E. 0.1 Vitamin H 0.1 citric acid 0.5 sodium benzoate 0.5 Perfume 0.4 NaCl 0.5 water ad 100 37. Shampoo Texapon ^® NSO 43.0 Dehyton ^® K 10.0 Plantacare ^® 1200 UP 4.0 Euperlan ^® PK 3000 ²⁹ 1.6 Arquad ^® 316 0.8 Polymer JR ^® 400 0.3 Gluadin ^® WQ 4.0 Glucamate ^® DOE 120 0.5 panthenol 0.5 sodium chloride 0.2 water ad 100 38. Shampoo Texapon ^® N 70 21.0 Plantacare ^® 1200 UP 8.0 Gluadin ^® WQ 1.5 Cutina ^® EGMS 0.6 Honeyquat ^® 50 2.0 Ajidew ^® NL 50 2.8 Antil ^® 141 1.3 panthenol 0.5 sodium chloride 0.2 magnesium hydroxide ad pH 4.5 water ad 100 39. Shampoo Texapon ^® K 14 S 50.0 Dehyton ^® K 10.0 Plantacare ^® 818 LTP 4.5 Polymer P1, accordingly DE 39 29 973 0.6 Cutina ^® AGS 2.0 D-panthenol 0.5 glucose 1.0 panthenol 0.5 salicylic acid 0.4 sodium chloride 0.5 Gluadin ^® WQ 2.0 water ad 100 40. Hair treatment Celquat ^® L 200 0.6 Luviskol ^® K30 0.2 D-panthenol 0.5 Polymer P1, accordingly DE 39 29 973 0.6 Dehyquart ^® A-CA 1.0 Gluadin ^® W 40 1.0 Natrosol ^® 250 HR 1.1 Dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone 0.5 Gluadin ^® WQ 2.0 water ad 100 41. Facial Toner

42. Hydrogels

43. Skin Emulsions (O / W)

44. styling gel Acrysol ^® ICS-1 1.5 g Plantacare ^® 2000 UP 0.3 g Gaffix ^® VC-713 3.0 g Dehyquart ^® A-CA 1.0 g Luviskol VA 64 2.0 g Amino-2-methyl-2-propanol-1 ad pH 6.0 Water ad 100 g
Viscosity at 25 ° C 2500 mPas, measured with Brookfield RVT, spindle 3 45. styling gel Aquaflex ^® SF 40 1.5 g Dow Corning Surfactant 193 1.5 g Acrisint ^® 400 0.8 g Amino-2-methyl-2-propanol-1 ad pH 5.5 ethanol 30.0 g water ad 100 46. styling gel Aquaflex ^® SF 40 1.0 g propylene glycol 5.0 g Carbopol ^® ETD 2020 0.5 g Amino-2-methyl-2-propanol-1 ad pH 7 Eumulgin ^® B1 0.4 g panthenol 0.3 glucose 3.0 water ad 100

Claims (30)

Cosmetic composition (K), which is present as a flowable, pasty, liquid or gel-like preparation, or as a powder, as granules or as a shaped body, characterized in that the cosmetic composition (K) is in a single-serving pack ( 1 ) is introduced, the single-serving pack ( 1 ) a container part ( 2 ), which has a cup-like shape ( 4 ) with an opening ( 5 ) and a sealing flange ( 6 ) which has the opening ( 5 ) surrounds at least as a radially outwardly projecting collar, and the single-serving pack ( 1 ) also a cover ( 3 ), which with the sealing flange ( 6 ) of the container part ( 2 ) is connected and the opening ( 5 ) of the container part ( 2 ) closes and which is formed by a peelable or peelable and / or push-through closure film. Cosmetic composition (K) according to claim 1, characterized in that they are at least one natural or contains synthetic polymer, the polymer or polymers preferably in an amount from 0.01 to 30% by weight of the total cosmetic composition is included. Cosmetic composition (K) according to Claim 1 or 2, characterized in that it is in liquid form, it having a viscosity in the range from 100 mPas to 10 ⁵ mPas. Cosmetic composition (K) according to claim 1 or 2, characterized in that they are powdered or granular or solid molded body is present, it contains at least one resolution accelerator. One-time portion pack ( 1 ), in particular for a cosmetic composition (K) according to one of Claims 1 to 4, consisting of a cup-like container part (formed from a film) ( 2 ) with a closure flange which projects essentially radially outwards ( 6 ) enclosed opening ( 5 ), and one with the sealing flange ( 6 ) of the container part ( 2 ) connected, the opening ( 5 ) sealing, peelable and / or push-through sealing film ( 3 ), characterized in that the container part ( 2 ) contains a cosmetic composition (K) which is present as a flowable, pasty, liquid or gel-like preparation, or as a powder, granulate or shaped body. One-time portion pack ( 1 ) with cosmetic composition (K) according to any one of claims 1 to 5, characterized in that the opening ( 5 ) is round, preferably circular, and that at least the side walls of the cup-like shape ( 4 ) of the container part ( 2 ) are only round, preferably rotationally symmetrical. One-time portion pack ( 1 ) with cosmetic composition (K) according to any one of claims 1 to 6, characterized in that the cup-like shape ( 4 ) of the container part ( 2 ) at least partially (8) is at least approximately in the form of a segment of a hollow sphere or as a segment of a hollow ellipsoid of revolution. One-time portion pack ( 1 ) with a cosmetic composition (K) according to any one of claims 1 to 7, characterized in that the wall of the cup-like shape ( 4 ) of the container part comprises an area which is at least approximately in the form of a hollow cylinder or a hollow truncated cone. One-time portion pack ( 1 ) with a cosmetic composition (K) according to one of claims 1 to 8, characterized in that the closure flange ( 6 ) with straight side edges ( 11 ) and especially with rounded corners ( 7 ) is trained. One-time portion pack ( 1 ) with cosmetic composition (K) according to one of claims 1 to 9, characterized in that the outer contour of the sealing film ( 3 ) with the outer contour of the sealing flange ( 6 ) matches. One-time portion pack ( 1 ) with cosmetic composition (K) according to one of claims 1 to 10, characterized in that the opening ( 5 ) has an area of 1 to 20 cm ² , preferably 6 to 12 cm ² . One-time portion pack ( 1 ) with cosmetic composition (K) according to any one of claims 1 to 11, characterized in that the cosmetic composition (K) in an amount with a weight between 0.1 and 40 g, preferably between 3 and 12 g and / or with a Volume between 0.1 and 40 ml, preferably between 3 and 12 ml is introduced. One-time portion pack ( 1 ) with a cosmetic composition (K) according to any one of claims 1 to 12, characterized in that the sealing film ( 3 ) has a thickness of 0.05 to 0.5 mm and in particular comprises a metal foil, preferably an aluminum foil, optionally in a multilayer composite foil. One-time portion pack ( 1 ) with cosmetic composition (K) according to any one of claims 1 to 13, characterized in that the wall of the cup-like shape ( 4 ) of the container part ( 2 ) has a thickness of 0.2 to 1.5 mm, preferably 0.5 to 1 mm, and in particular comprises a plastic film, optionally in a multilayer composite film. One-time portion pack ( 1 ) with a cosmetic composition (K) according to one of claims 1 to 14, characterized in that the cup-like shape ( 4 ) of the container part ( 2 ) is made of a transparent or translucent material. One-time portion pack ( 1 ) with a cosmetic composition (K) according to any one of claims 1 to 15, characterized in that the sealing film ( 3 ) over the entire circumference of the opening ( 5 ) by means of an adhesion promoter and / or by means of a sealed connection and / or welded connection with the sealing flange ( 6 ) is connected, preferably the closure flange ( 6 ) has at least one edge area in which it does not match the tear-open tab ( 13 ) formed area of the overlying sealing film ( 3 ) connected is. One-time portion pack ( 1 ) with cosmetic composition (K) according to any one of claims 1 to 16, characterized in that the sealing film is roughened and / or coated, in particular rubberized, on one or both sides at least in an area designed as a tear-open flap. One-time portion pack ( 1 ) with a cosmetic composition (K) according to any one of claims 1 to 17, characterized in that the sealing film ( 3 ) is printed directly or indirectly. One-time portion pack ( 1 ) with cosmetic composition (K) according to one of claims 1 to 18, characterized in that the single-serving pack ( 1 ) is a blister pack, in particular a printed blister pack. One-time portion pack ( 1 ) with cosmetic composition (K) according to claim 19, characterized in that the single-serving pack ( 1 ) is a peelable blister pack. Packaging Unit ( 10 ) with several single-serving packs ( 1 ) with cosmetic composition tongue (K) according to one of claims 1 to 20, characterized in that two or more single-serving packs ( 1 ) arranged side by side in at least one row and over their sealing flanges ( 6 ) are connected to each other, each single-serving pack ( 1 ) each contains a cosmetic composition (K). Packaging Unit ( 10 ) according to claim 21, characterized in that the single-serving packs ( 1 ) by means of predetermined breaking points ( 12 ) are releasably connected to each other. Packaging Unit ( 10 ) according to claim 21 or 22, characterized in that at least two different cosmetic compositions (K) are provided, each in at least one of the interconnected single-use packs ( 1 ) are included. Packaging Unit ( 10 ) according to claim 23, characterized in that in the interconnected single-serving packs ( 1 ) contains on the one hand hair shampoo and on the other hand hair conditioning agents or on the one hand UV skin protection agents and on the other hand apres-sun care products or on the one hand facial cleansing agents and on the other hand facial care products. Packaging Unit ( 10 ) according to claim 23 or 24, characterized in that the different cosmetic compositions (K) have different colors. Packaging Unit ( 10 ) according to one of claims 23 to 25, characterized in that the closure films ( 3 ) are colored differently for the different cosmetic compositions (K). Kit containing at least one single-serving pack ( 1 ) with cosmetic composition (K) according to one of claims 1 to 20 and / or at least one packaging unit ( 10 ) according to one of claims 21 to 26, characterized in that an outer packaging preferably made of plastic, cardboard or cardboard ( 16 ) is provided in which the single-serving pack (s) ( 1 ) and / or packaging units) ( 10 ) is held or is fully included and preferably also contains instructions for use. Kit according to claim 27, characterized in that the outer packaging ( 16 ) by a flat envelope with two opposite side walls ( 17a . 17b ) is formed, between which the sealing flanges ( 6 ) several single-serving packs ( 1 ), especially from a j packaging unit ( 10 ) are included, with a side wall ( 17a ) multiple openings ( 18 ), through which a cup-like shape ( 4 ) of the container part ( 2 ) a single-serving pack ( 1 ) protrudes. Method for the cosmetic treatment of skin, nails or fibers containing keratin, characterized in that a) one or more single portions (A) of a cosmetic composition (K) from a single portion package ( 1 ) are removed according to one of the preceding claims and, if appropriate, are dissolved in a medium (M) to form the preparation (AM), b) the single portion (A) according to the invention or, if appropriate, the preparation (AM) onto the skin, the nails or the keratin Fibers is applied and c) optionally rinsed off after an exposure time. Process for the production of a single-serving pack ( 1 ) according to one of claims 1 to 20 or for producing a packaging unit ( 10 ) according to one of claims 21 to 26, characterized in that the following process steps are carried out: a) deforming a thermoforming film, b) filling the container part thus formed ( 2 ) with a cosmetic composition (K), which is in the form of a flowable, pasty, liquid or gel-like composition (K), or as a powder, as granules or as a shaped body, c) sealing, preferably sealing, the container part ( 2 ) with a sealing film ( 3 ), and d) stamping.