DE102006000649A1 - Universally-applicable composition, e.g. for pigment paste, coating material or ink, contains pigment or filler and a film-forming dispersant comprising ketone, ketone-aldehyde or urea-aldehyde resin and ionic liquid - Google Patents

Abstract

Universally-applicable compositions (I) containing (A) 1-70 wt% pigment and/or filler, also contain (B) 30-99 wt% of a composition comprising (a) 95-5 wt% ketone-, ketone/aldehyde- or urea/aldehyde-resin(s) and/or their hydrogenated derivatives and (b) up to 95 wt% ionic liquid(s), plus (C) 0-69 wt% other binder(s) and (D) 0-69 wt% auxiliary substances. Independent claims are included for (1) a method for the production of (I) by intensively mixing the above components by stirring and/or dispersion at 20-80[deg]C (2) objects obtained by using (I).

Description

The The present invention relates to universally applicable compositions from A) colorants and / or fillers, B) compositions of ionic liquids and ketone, ketone / aldehyde and / or Urea / aldehyde resins and / or their hydrogenated derivatives with universal solubility and C) optionally further binders and / or D) optionally auxiliaries and additives and their use in aqueous, solvent-containing and solvent-free Coating materials such as paints, varnishes, adhesives, Inks or printing inks and for coloring plastics.

For dispersion of fillers and pigments in liquid Media are usually used dispersants, so the for one effective dispersion of the solids required to reduce mechanical shear forces as possible as possible high filling levels to realize and the time required for this process is, if possible to keep low. The dispersants help break up agglomerates, wet and / or occupy the surface active compounds as the surface the particles to be dispersed and stabilize them against a undesirable Reagglomeration.

Network- and dispersants facilitate in the manufacture of colors and paints the incorporation of pigments and fillers, which are considered important Formulating ingredients the visual appearance and the physicochemical Significantly determine the properties of coatings. For an optimal Need to exploit these solids are evenly distributed in paints and varnishes second, once the distribution has been reached, it must stabilize become.

The stabilizing and dispersing-facilitating effect is due in many make on the use of special binder components (pigment paste resin). Such binders are therefore also valuable components for coating materials, because they cause faster drying and increase the Hardness of resulting films contribute.

Important for a universal application of the binder is firstly a universal compatibility with other binders - such. B. with the significant Langölalkydharzen, vegetable oils, hydrocarbon resins, acrylate resins and polyamides - secondly, and a universal solubility in organic solvents such. B. in the often used for ecological and toxicological reasons pure aliphatics and white spirits. Such binders with universal compatibility and solubility in organic solvents are z. In EP 1 486 520 or DE 44 04 809 described.

In addition, it is necessary for a universal application of the binders that these binders are also miscible with water or soluble in water. In the EP 1 486 520 or DE 44 04 809 products described have no water miscibility or water solubility.

The Object of the present invention was universally applicable Compositions such as pigment pastes, coating materials and printing inks based on compositions of ionic liquids and ketone, ketone / aldehyde and / or urea / aldehyde resins and / or their hydrogenated derivatives to develop as film-forming pigment paste resins, which are characterized by a brilliant color and a high color depth distinguish. The Compositions are intended for both solventborne and solventless Applications should be suitable and characterized by a low viscosity at high Characterize pigment content.

The The object underlying the invention is surprisingly achieved according to the claims by Colorants and / or fillers in the presence of at least one ionic liquid composition and ketone, ketone / aldehyde and / or urea / aldehyde resins and / or their hydrogenated secondary products, which are described in more detail below will be rubbed.

The according to the invention, universal usable compositions have in contrast to low molecular weight Dispersants and wetting agents very good film-forming properties. The compositions are largely free of formaldehyde.

The Compositions of the invention can used, in particular for solventborne and watery Coating materials and for solvent-free Coating materials (e.g., radiation curable coating materials and / or powder coatings) such as putties, fillers, base and / or topcoats as well as printing inks, ballpoint pen pastes, pigment pastes, inks, Polishes, glazes, laminations, cosmetic articles and / or sealing and insulation materials as well as adhesives.

The Use limited This does not apply to the coating of certain substrates such as e.g. Metals, plastics, paper, cardboard, textiles, leather or wood. The compositions can for all conceivable applications both indoors and outdoors be used.

• A) 1 bis 70 Gew.-% mindestens eines Farbmittels und/oder Füllstoffes und
• B) 30 bis 99 Gew.-% mindestens einer Zusammensetzung aus a. 95 bis 5 Gew.-% mindestens eines Keton-, Keton/Aldehyd-, Harnstoff/Aldehyd-Harzes und/oder dessen hydrierten Folgeproduktes und b. 5 bis 95 Gew.-% mindestens einer Ionischen Flüssigkeit,

wobei die Summe der Gewichtsangaben der Komponenten a) und b) 100 Gew.-% beträgt
und

• C) 0 bis 69 Gew.-% mindestens eines weiteren Bindemittels und
• D) 0 bis 69 Gew.-% mindestens eines Hilfsstoffes,

wobei die Summe der Gewichtsangaben der Komponenten A) bis D) 100 Gew.-% beträgt.The present invention generally relates to universally usable compositions

• A) 1 to 70 wt .-% of at least one colorant and / or filler and
• B) 30 to 99 wt .-% of at least one composition of a. 95 to 5 wt .-% of at least one ketone, ketone / aldehyde, urea / aldehyde resin and / or its hydrogenated derivative and b. From 5 to 95% by weight of at least one ionic liquid,

wherein the sum of the weights of components a) and b) is 100 wt .-%
and

• C) 0 to 69 wt .-% of at least one further binder and
• D) 0 to 69 wt .-% of at least one excipient,

wherein the sum of the weights of components A) to D) is 100 wt .-%.

It It was found that the combination of the below described Compositions such as pigment pastes, coating materials and printing inks from components A) to D) meet all the required criteria.

Component A)

The Invention-essential component A) is used in amounts of 1 to 70 Wt .-%, preferably from 10 to 40 wt .-% used. Basically suitable are all colorants and / or fillers, which are used in the paint, paint and ink industry. Selected They are colored for coloristic aspects and requirements such. Hue, brightness, saturation, Color strength, Compatibility, Transparency, hiding power, light fastness, Bleed fastness etc.

It For example, inorganic pigments and fillers such as e.g. milori, Titanium dioxide, iron oxides, metal pigments (e.g., spinel, bismuth vanadate, Nickel titanium, chromium oxide), carbon blacks and carbonates, e.g. Chalk, limestone, calcite, dolomite, barium carbonate, sulphates, such as. Baryte, blanc fixe, calcium sulfates, silicates, e.g. Talk, Pyrophyllite, chlorite, mica, kaolin, slate meal, field column, precipitated Ca, Al, Ca / Al, Na / Al silicates, silicas, e.g. Quartz, fused silica, Cristobalite, diatomaceous earth, precipitated and / or fumed silica, glass flour and oxides, e.g. Magnesium and aluminum oxides and hydroxides and organic pigments such as e.g. Isoindoline, azo, quinacridone, Perylene, dioxazine, phthalocyanine pigments used. In addition, metallic effect pigments such as. Aluminum, copper, copper / zinc and zinc pigments, fire-colored bronzes, Iron oxide-aluminum pigments, Interference or pearlescent effect pigments such as e.g. Metal oxide-mica pigments, Bismuth oxychloride, basic lead carbonate, fish silver or micronized Titanium dioxide, platelet-shaped graphite, platy iron oxide, Multilayer effect pigments made of PVD films or by the CVD method (Chemical Vapor deposition) as well as liquid crystal (polymer) pigments be used. About that In addition, dyes are used. A list used Pigments, fillers and / or dyes is in "Römpp Lexikon, Paints and printing inks, publisher Ulrich Zorll, Georg Thieme Verlag, Stuttgart, 1998 "or" Pigment and filler tables, Editor Olaf Lückert, Vincentz Verlag, Hannover, 2002 ".

Component B)

The essential to the invention component B) is in amounts of from 30 to 99 Wt .-%, preferably from 30 to 60 wt .-% used.

• a. 95 bis 5 Gew.-% mindestens eines Keton-, Keton/Aldehyd-, Harnstoff/Aldehyd-Harzes und/oder dessen hydrierten Folgeproduktes und
• b. 5 bis 95 Gew.-% mindestens einer Ionischen Flüssigkeit,

wobei die Summe der Gewichtsangaben der Komponenten a) und b) 100 Gew.-% beträgt.Component B) contains

• a. 95 to 5 wt .-% of at least one ketone, ketone / aldehyde, urea / aldehyde resin and / or its hydrogenated secondary product and
• b. From 5 to 95% by weight of at least one ionic liquid,

wherein the sum of the weights of components a) and b) is 100 wt .-%.

When Ketones for the preparation of the ketone and ketone aldehyde resins (component B) a.) Are all ketones, in particular acetone, acetophenone, Methyl ethyl ketone, tert-butyl methyl ketone, heptanone-2, pentanone-3, Methyl isobutyl ketone, cyclopentanone, cyclododecanone, mixtures of 2,2,4- and 2,4,4-trimethylcyclopentanone, cycloheptanone and cyclooctanone, Cyclohexanone and all alkyl-substituted cyclohexanones with a or more alkyl radicals containing a total of 1 to 8 carbon atoms have, individually or in mixture. As examples alkyl-substituted Cyclohexanone can 4-tert-amylcyclohexanone, 2-sec-butylcyclohexanone, 2-tert-butylcyclohexanone, 4-tert-butylcyclohexanone, 2-methylcyclohexanone and 3,3,5-trimethylcyclohexanone.

in the Generally can but all in the literature for Ketone and ketone-aldehyde resin syntheses as suitable called ketones, usually all C-H-acidic ketones are used. Prefers are ketone-aldehyde resins based on the ketones acetophenone, cyclohexanone, 4-tert-butylcyclohexanone, 3,3,5-trimethylcyclohexanone and heptanone alone or in admixture and ketone resins based on cyclohexanone.

When Aldehyde component of the ketone-Aldehydhaxze (component B) a.) Are suitable in principle unbranched or branched aldehydes, such as. B. Formaldehyde, acetaldehyde, n-butyraldehyde and / or isobutyraldehyde, Valeric aldehyde and dodecanal. In general, everyone can in the literature for Ketonharzsynthesen be used as suitable called aldehydes. Preferably, however, formaldehyde is used alone or in mixtures.

The needed Formaldehyde is usually as about 20 to 40 wt .-% aqueous or alcoholic (eg, methanol or butanol) solution. Other uses of formaldehyde such. B. also the use of para-formaldehyde or trioxane are also possible. aromatic Aldehydes, such as. As benzaldehyde, may in mixture with formaldehyde Also included.

Especially are preferred as starting compounds for the component B) a. acetophenone, Cyclohexanone, 4-tert-butylcyclohexanone, 3,3,5-trimethylcyclohexanone and heptanone alone or in mixture and formaldehyde.

As component B) a. hydrogenated derivatives of the ketone and aldehyde resins are also used. The ketone-aldehyde resins described above are hydrogenated in the presence of a catalyst with hydrogen at pressures of up to 300 bar. The carbonyl group of the ketone-aldehyde resin is converted into a secondary hydroxy group. Depending on the reaction conditions, a part of the hydroxy groups can be split off, so that methylene groups result. To illustrate, the following scheme is used:

in der X Sauerstoff oder Schwefel, A einen Alkylenrest bedeuten und n für 0 bis 3 steht, mit 1,9 (n + 1) bis 2,2 (n + 1) mol eines Aldehyds der allgemeinen Formel (ii)

in der R₁ und R₂ für Kohlenwasserstoffreste (z. B. Alkyl-, Aryl- und/oder Alkylarylreste) mit jeweils bis zu 20 Kohlenstoffatomen stehen
und/oder Formaldehyd verwendet.As component B) a. Furthermore, urea-aldehyde resins are prepared using a urea of the general formula (i)

in which X is oxygen or sulfur, A is an alkylene radical and n is 0 to 3, with 1.9 (n + 1) to 2.2 (n + 1) mol of an aldehyde of the general formula (ii)

in which R ₁ and R _{2 are} hydrocarbon radicals (for example alkyl, aryl and / or alkylaryl radicals) each having up to 20 carbon atoms
and / or formaldehyde.

suitable Urea of the general formula (i) with n = 0 are z. B. urea and thiourea, with n = 1 methylene diurea, ethylene diurea, Tetramethylenediurea and / or hexamethylenediurea as well their mixtures. Preference is given to urea.

suitable Aldehydes of the general formula (ii) are, for example, isobutyraldehyde, 2-methylpentanal, 2-ethylhexanal and 2-phenylpropanal and theirs Mixtures. Isobutyraldehyde is preferred.

formaldehyde can in aqueous Form, some or all of alcohols such. As methanol or ethanol may be used as paraformaldehyde and / or trioxane.

in the In general, all monomers used in the literature for the preparation of aldehyde-urea resins are suitable.

Typical methods of preparation and compositions are e.g. In DE 27 57 220 , DE-OS 27 57 176 and EP 0 271 776 described.

wobei R1, R2, R3, R4, R5 und R6, gleich oder unterschiedlich sind und
Wasserstoff, Hydroxy-, Alkoxy-, Sulfanyl- (R-S-), NH₂-, NHR-, NRR'-Gruppe, wobei R und R' gleiche oder unterschiedliche, substituierte oder unsubstituierte Alkylgruppen mit 1 bis 8 Kohlenstoffatomen sein können, oder Halogen, insbesondere F, Cl, Br oder I, wobei für Kationen der Struktur 10 und 11 einer der Reste R1 bis R4, bevorzugt alle Reste R1 bis R4 vorzugsweise ungleich Wasserstoff sind; und/oder
ein gesättigter oder ungesättigter, linearer oder verzweigter aliphatischer Kohlenwasserstoffrest mit 1 bis 40, vorzugsweise 1 bis 30, bevorzugt 1 bis 20 Kohlenstoffatomen, der substituiert, beispielsweise mit einer Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppe, oder unsubstituiert sein kann; und/oder
ein cycloaliphatischer Kohlenwasserstoffrest mit 5 bis 30, vorzugsweise 5 bis 10, bevorzugt 5 bis 8 Kohlenstoffatomen, der substituiert, beispielsweise mit einer Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppe, oder unsubstituiert sein kann; und/oder
ein aromatischer Kohlenwasserstoffrest mit 6 bis 30, vorzugsweise 6 bis 12, bevorzugt 6 bis 10 Kohlenstoffatomen, der substituiert, beispielsweise mit einer Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppe, oder unsubstituiert sein kann; und/oder
ein Alkylarylrest mit 7 bis 40, vorzugsweise 7 bis 14, bevorzugt 7 bis 12 Kohlenstoffatomen, der substituiert, beispielsweise mit einer Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppe, oder unsubstituiert sein kann; und/oder
ein durch ein oder mehrere Heteroatome (Sauerstoff, NH, NCH₃) unterbrochener linearer oder verzweigter aliphatischer und/oder cycloaliphatischer und/oder aromatischer Kohlenwasserstoffrest mit 2 bis 100 Kohlenstoffatomen, bevorzugt mit 2 bis 80 Kohlenstoffatomen, besonders bevorzugt mit 2 bis 40 Kohlenstoffatomen, der substituiert, beispielsweise mit Amino-, Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppen, oder unsubstituiert sein kann; und/oder
ein durch ein oder mehrere Funktionalitäten, ausgewählt aus der Gruppe -O-C(O)-, -(O)C-O-, -NH-C(O)-, -(O)C-NH, -(CH₃)N-C(O)-, -(O)C-N(CH₃)-, -S(O)₂-O-, -O-S(O)₂-, -S(O)₂-NH-, -NH-S(O)₂-, -S(O)₂-N(CH₃)-, -N(CH₃)-S(O)₂-, unterbrochener linearer oder verzweigter aliphatischer Kohlenwasserstoffrest mit 2 bis 20 Kohlenstoffatomen, der substituiert, beispielsweise mit einer Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppe, oder unsubstituiert sein kann; und/oder
ein endständig -OH, -NH₂, -N(H)CH₃ funktionalisierter linearer oder verzweigter aliphatischer Kohlenwasserstoffrest mit 1 bis 20 Kohlenstoffatomen, der substituiert, beispielsweise mit einer Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppe, oder unsubstituiert sein kann.In the context of the present invention, ionic liquids (component B) b.) Are understood as meaning salts which have a melting point of not more than 100 ° C. For an overview of ILs, see See Welton (Chem. Rev. 99 (1999), 2071) and Wasserscheid et al. (Angew Chem 112 (2000), 3926). Preferably used as IL are those salts which have a melting temperature below 75 ° C, preferably below 50 ° C, particularly preferably below 20 ° C. Preferably, ionic liquids contain organic cations. Preference is given to ionic liquids which have one or more cations according to the following structures,

wherein R1, R2, R3, R4, R5 and R6 are the same or different and
Hydrogen, hydroxy, alkoxy, sulfanyl (RS), NH ₂ , NHR, NRR 'group, wherein R and R' may be the same or different, substituted or unsubstituted alkyl groups having 1 to 8 carbon atoms, or halogen , in particular F, Cl, Br or I, wherein for cations of the structure 10 and 11 one of the radicals R 1 to R 4, preferably all radicals R 1 to R 4 are preferably not hydrogen; and or
a saturated or unsaturated, linear or branched aliphatic hydrocarbon radical having 1 to 40, preferably 1 to 30, preferably 1 to 20 carbon atoms which is substituted, for example with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen Group, or may be unsubstituted; and or
a cycloaliphatic hydrocarbon radical having 5 to 30, preferably 5 to 10, preferably 5 to 8 carbon atoms, which may be substituted, for example with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or unsubstituted ; and or
an aromatic hydrocarbon radical having 6 to 30, preferably 6 to 12, preferably 6 to 10 carbon atoms, which may be substituted, for example with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or unsubstituted ; and or
an alkylaryl group of 7 to 40, preferably 7 to 14, preferably 7 to 12, carbon atoms which may be substituted, for example, with one hydroxy, alkyl of 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or unsubstituted; and or
a linear or branched aliphatic and / or cycloaliphatic and / or aromatic hydrocarbon radical having from 2 to 100 carbon atoms, preferably from 2 to 80 carbon atoms, particularly preferably from 2 to 40 carbon atoms, interrupted by one or more heteroatoms (oxygen, NH, NCH ₃ ) substituted, for example, with amino, hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen groups, or may be unsubstituted; and or
a by one or more functionalities selected from the group -OC (O) -, - (O) CO-, -NH-C (O) -, - (O) C-NH, - (CH ₃ ) NC (O ) -, - (O) CN (CH ₃₎ -, -S (O) ₂ -O-, -OS (O) ₂ -, -S (O) ₂ -NH-, -NH-S (O) ₂ -, -S (O) ₂ -N (CH ₃ ) -, -N (CH ₃ ) -S (O) ₂ -, interrupted linear or branched aliphatic hydrocarbon radical having 2 to 20 carbon atoms, which is substituted, for example with a hydroxy , Alkyl of 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or may be unsubstituted; and or
a terminal -OH, -NH ₂ , -N (H) CH ₃ functionalized linear or branched aliphatic hydrocarbon radical having 1 to 20 carbon atoms which is substituted, for example with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or may be unsubstituted.

Prefers become ionic liquids, which is a cation based on ammonium, pyridinium, pyrrolidinium, Pyrrolinium, oxazolium, oxazolinium, imidazolium, thiazolium or phosphonium ions.

The ionic liquids preferably have one or more anions selected from phosphate, halogen phosphates, especially hexafluorophosphate, halides, especially chloride, alkyl phosphates, aryl phosphates, nitrate, sulfate, hydrogen sulfate, alkyl sulfates, aryl sulfates, perfluorinated alkyl and aryl sulfates, sulfonate, alkyl sulfonates, aryl sulfonates, perfluorinated alkyl and aryl sulfonates, in particular trifluoromethylsulfonate, tosylate, perchlorate, tetrachloroaluminate, heptachlorodialuminate, tetrafluoroborate, alkyl borates, arylborates, amides, in particular perfluorinated amides, dicyanamide, saccharinate, thiocyanate, carboxylates, in particular acetates, preferably acetate and / or trifluoroacetate, and / or bis (perfluoroalkylsulfonyl) amide anions.

wobei R1, R2, R3 und R4 gleich oder unterschiedlich sein können und
ein gesättigter oder ungesättigter, linearer oder verzweigter aliphatischer Kohlenwasserstoffrest mit 1 bis 40, vorzugsweise 1 bis 30, bevorzugt 1 bis 20 Kohlenstoffatomen, der substituiert, beispielsweise mit einer Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppe, oder unsubstituiert sein kann; und/oder
ein durch ein oder mehrere Heteroatome (Sauerstoff, NH, NCH₃) unterbrochener linearer oder verzweigter aliphatischer und/oder cycloaliphatischer und/oder aromatischer Kohlenwasserstoffrest mit 2 bis 100 Kohlenstoffatomen, bevorzugt mit 2 bis 80 Kohlenstoffatomen, besonders bevorzugt mit 2 bis 40 Kohlenstoffatomen, der substituiert, beispielsweise mit Amino-, Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppen, oder unsubstituiert sein kann; und/oder
ein durch ein oder mehrere Funktionalitäten, ausgewählt aus der Gruppe -O-C(O)-, -(O)C-O-, -NH-C(O)-, -(O)C-NH, -(CH₃)N-C(O)-, -(O)C-N(CH₃)-, -S(O)₂-O-, -O-S(O)₂-, -S(O)₂-NH-, -NH-S(O)₂-, -S(O)₂-N(CH₃)-, -N(CH₃)-S(O)₂-, unterbrochener linearer oder verzweigter aliphatischer Kohlenwasserstoffrest mit 2 bis 20 Kohlenstoffatomen, der substituiert, beispielsweise mit einer Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppe, oder unsubstituiert sein kann; und/oder
ein endständig -OH, -NH₂, -N(H)CH₃ funktionalisierter linearer oder verzweigter aliphatischer Kohlenwasserstoffrest mit 1 bis 20 Kohlenstoffatomen, der substituiert, beispielsweise mit einer Hydroxy-, Alkyl mit 1 bis 8, vorzugsweise 1 bis 4 Kohlenstoffatomen und/oder Halogen-Gruppe, oder unsubstituiert sein kann, sowie ein Anion ausgewählt aus Tetrafluorborat, Alkylborat, insbesondere Triethylhexylborat, Arylborat, Halogenphosphat, insbesondere Hexafluorphosphat, Nitrat, Sulfonate, insbesondere perfluorierte Alkyl- und Arylsulfonate, Hydrogensulfat, Alkylsulfate, Halogenide, insbesondere Chloride, Acetate, Thiocyanate, perfluorierte Amide, Dicyanamid und/oder Bis(perfluoralkylsulfonyl)amid-, insbesondere Bis(trifluormethansulfonyl)amid ((CF₃SO₂)₂N).In a particularly preferred embodiment of the IL, at least one salt is used which contains as cation an imidazolium, a pyridinium, an ammonium or phosphonium ion of the following structures:

wherein R1, R2, R3 and R4 may be the same or different and
a saturated or unsaturated, linear or branched aliphatic hydrocarbon radical having 1 to 40, preferably 1 to 30, preferably 1 to 20 carbon atoms which is substituted, for example with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen Group, or may be unsubstituted; and or
a linear or branched aliphatic and / or cycloaliphatic and / or aromatic hydrocarbon radical having from 2 to 100 carbon atoms, preferably from 2 to 80 carbon atoms, particularly preferably from 2 to 40 carbon atoms, interrupted by one or more heteroatoms (oxygen, NH, NCH ₃ ) substituted, for example, with amino, hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen groups, or may be unsubstituted; and or
a by one or more functionalities selected from the group -OC (O) -, - (O) CO-, -NH-C (O) -, - (O) C-NH, - (CH ₃ ) NC (O ) -, - (O) CN (CH ₃₎ -, -S (O) ₂ -O-, -OS (O) ₂ -, -S (O) ₂ -NH-, -NH-S (O) ₂ -, -S (O) ₂ -N (CH ₃ ) -, -N (CH ₃ ) -S (O) ₂ -, interrupted linear or branched aliphatic hydrocarbon radical having 2 to 20 carbon atoms, which is substituted, for example with a hydroxy , Alkyl of 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or may be unsubstituted; and or
a terminal -OH, -NH ₂ , -N (H) CH ₃ functionalized linear or branched aliphatic hydrocarbon radical having 1 to 20 carbon atoms which is substituted, for example with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or may be unsubstituted, and an anion selected from tetrafluoroborate, alkyl borate, in particular triethylhexylborate, arylborate, halogenophosphate, in particular hexafluorophosphate, nitrate, sulfonates, in particular perfluorinated alkyl and aryl sulfonates, hydrogen sulfate, alkyl sulfates, halides, in particular chlorides, acetates , Thiocyanates, perfluorinated amides, dicyanamide and / or bis (perfluoroalkylsulfonyl) amide, especially bis (trifluoromethanesulfonyl) amide ((CF ₃ SO ₂ ) ₂ N).

According to the invention can as Component B) b. also a mixture of at least two different ionic species liquids be used. Here, the IL can be at least two different Have anions and / or two different cations.

The Component B) is prepared by mixing or dissolving components a) and b) at temperatures between 20 and 180 ° C, preferably between 40 and 150 ° C, especially preferably between 60 and 120 ° C in a stirred tank produced.

The Component B) may be used in bulk or optionally in the presence of a suitable solvent getting produced. Preferred solids contents are in use of a solvent 40 to 95% by mass, particularly preferably 50 to 80% by mass.

When solvent suitable are those used in the adhesive and paint industry become. Preference is given, e.g. Alcohols, acetates, ketones, ethers, Glycol ethers, aliphatic, aromatic, alone or in mixture. But it can also called reactive diluents which are commonly used in radiation-curing coating materials Find application such. Acrylate-functionalized mono-, di- or higher Alcohols.

Component C)

The Binder C) can optionally contained and are in amounts of 0 to 69 wt .-%, preferably used from 0 to 60 wt .-%. Preference is given to binders, from the group of polyurethanes, polyacrylates, polyethers, polyesters, Alkyd resins, polyamides, casein, cellulose ethers, derivatives of cellulose, Polyvinyl alcohols and derivatives, polyvinyl acetates, polyvinyl chlorides, Polyvinylpyrolidones, rubbers, natural resins, hydrocarbon resins such as. Coumarone, indene, cyclopentadiene resins, terpene resins, maleate resins, Phenolic resins, phenol / urea-aldehyde resins, aminoplasts (e.g., melamine, Benzoguanamine resins), epoxy acrylates, epoxy resins, silicic acid esters and alkali silicates (e.g., water glass) and / or silicone resins and / or fluorine-containing polymers used. The binders may be foreign and / or self-crosslinking, air-drying (physically drying) and / or oxidatively curing. The binders can in organic solvents soluble be and / or soluble in water, mixed or dispersible.

Basically suitable are all binders used in the paint, paints and printing inks industry be used.

Component D)

The Component D) may optionally be included and is used in amounts of 0 to 69 wt .-%, preferably from 0 to 60 wt .-% used. As a component D) are suitable auxiliaries and additives such as inhibitors, organic solvents, Water, surface-active Substances, oxygen and / or radical scavengers, catalysts, light stabilizers, Color lighteners, photosensitizers and initiators, additives for influencing rheological properties, e.g. thixotropic agents and / or thickening agents, leveling agents, anti-skinning agents, defoamers, Antistatic agents, lubricants, wetting and dispersing agents, crosslinkers such as. blocked or unblocked (poly) isocyanates, preservatives such as. also fungicides and / or biocides, thermoplastic additives, Plasticizers, matting agents, fire retardants, internal release agents and / or Propellant.

Preparation of the compositions from the components A) to D):

The Preparation of the compositions is carried out by intensive mixing of the components at temperatures of 20 to 80 ° C ("textbook of paint technology", Th. Brock, M. Groteklaes, P. Mischke, ed. V. Zorll, Vincentz Verlag, Hannover, 1998, page 229 ff.).

Not liquid Components may first be mixed in suitable solvents before mixing or water in solution brought, then the remaining components are added with stirring. In the case of e.g. pigments and / or fillers a dispersion takes place.

The Compositions of the invention can used, in particular for solventborne and watery Coating materials and for solvent-free Coating materials (e.g., radiation curable coating materials and / or powder coatings) such as putties, fillers, base and / or topcoats as well as printing inks, ballpoint pen pastes, pigment pastes, inks, polishes, Glazes, laminations, cosmetics and / or sealing and insulating materials as well as adhesives and / or for coloring plastics.

there can Substrates of e.g. Metals, plastics, paper, cardboard, inorganic Fabrics such as e.g. Ceramics, stone, concrete and / or glass, textiles, Fibers, fabric materials, leather and / or synthetic materials, such as artificial leather, wood, plastic and / or composite films such as. aluminum laminated films are coated. The compositions can for all conceivable applications both indoors and outdoors can be used, e.g. Building protection, automobiles, coil coating, Can-Coating, textile finishing, Wood coatings, plastics, decorative applications, etc. Also for use in adhesives, such as For example the bonding of textiles, leather, paper and similar materials are such Compositions suitable.

The Compositions of the invention are characterized by a brilliant hue and a high color depth out. The compositions have a low viscosity at high Pigment content and are storage stable.

The compositions according to the invention are distinguished by a particularly high rate of drying and drying, good blocking resistance, high gloss and good water resistance. The course is perfect and the surfaces are free of disturbances, such as craters and Wetting problems.

The dried, hardened or crosslinked films obtained from the compositions have good adhesion properties on underlying coatings; Also, the intercoat adhesion to overlying layers is positive affected.

The Compositions of the invention have a solids content of 10% to 99%, preferably from 20% to 80%. The content of volatile Organic compounds (VOC) is between 0 and 50 wt .-%, preferably between 0 and 40% by weight, more preferably between 0 and 30 Wt .-%. The formaldehyde content of the compositions is below 100 ppm, preferably below 20 ppm and more preferably below of 1 ppm.

The The following examples are intended to illustrate the invention made but further do not restrict their scope:

1.) Examples of preparation component B)

The listed Starting materials are products of Degussa AG.

The respective ionic liquid was heated to 100 ° C in the above amount with stirring. So then the respective resin was in the amount indicated above with stirring added slowly and stirred until complete homogenization.

All Products are clear and clearly soluble in ethanol, ethyl acetate, butyl acetate, methoxypropyl acetate, xylene, white spirit and n-hexane and soluble in water or dispersible.

In contrast, is Synthetic resin TC universally soluble in organic solvents, but not in water. resin SK is in water, aliphatic hydrocarbons and aromatics insoluble.

2.1.) Production of aqueous compositions

• Predispersion: 5 min Pendraulik LM 34-Labordissolver, 4000 rpm (disc ∅, 40 mm)
• BA-dispersing: 60 min Skandex-Dispers BA-S 20, 540 g chromanite Steel beads (∅ 3 mm), cooling Level 2,
• Application: The application was carried out by means of a paint dumbbell (gap height 200 μm) on glass plates. Drying conditions: flash off for 30 minutes at room temperature and for 30 min at 80 ° C in a convection oven.

The Coatings Ia to Va differed visually significantly from the comparison by a high brilliance.

2.2.) Preparation of solvent-containing and aqueous compositions a) Reibgutformulierungen

These black pigment preparations were low viscosity.

b) Preparation of solvent-containing and low-solvent, black coating materials

The Example 2.2.) a) prepared black pigment preparation were both solvent-based as well as watery let down.

It can be both solvent-containing, low-solvent as well as solvent-free Pigment preparations and Produce coating materials.

Claims (37)

Universally applicable compositions in the Containing substantially A) 1 to 70 wt .-% of at least one Colorant and / or filler and B) 30 to 99 wt .-% of at least one composition a. 95 to 5 wt .-% of at least one ketone, ketone / aldehyde, urea / aldehyde resin and / or its hydrogenated second product and b. to 95 wt .-% of at least one Ionic liquid, in which the sum of the weights of components a) and b) 100% by weight is and possibly. C) 0 to 69 wt .-% of at least one further binder and D) 0 to 69 wt .-% of at least one excipient, where the sum the weights of components A) to D) is 100 wt .-%. Universally usable compositions according to claim 1., characterized in that the compositions according to the invention a solids content of from 10% to 99%, preferably from 20% to 80%, a formaldehyde content below 100 ppm, preferably below 20 ppm and more preferably below 1 ppm. Universally applicable compositions after at least one of the claims 1st and 2nd, characterized in that as component A) colorants and / or fillers be used. Universally applicable compositions after at least one of the preceding claims, characterized in that as component A) pigments, dyes and / or fillers be used. Universally usable compositions according to at least one of the preceding claims, since characterized in that as component A) milori blue, titanium dioxide, iron oxides, metal pigments such as spinel, bismuth vanadate, nickel titanium, chromium oxide, carbon blacks and carbonates such as chalk, limestone, calcite, dolomite, barium carbonate, sulfates such as baryte, blanc fixe, calcium sulfates, Silicates such as talc, pyrophyllite, chlorite, mica, kaolin, slate flour, field fission, precipitated Ca, Al, Ca / Al, Na / Al silicates, silicas such as quartz, fused silica, cristobalite, kieselguhr, precipitated and / or fumed silica, glass powder and oxides such as magnesium and aluminum oxides and hydroxides and organic pigments such as isoindoline, azo, quinacridone, perylene, dioxazine, phthalocyanine pigments, metallic effect pigments such as aluminum, copper, copper / zinc and zinc pigments, fire-colored bronzes, iron oxide-aluminum pigments, interference or pearlescent pigments such as metal oxide mica pigments, bismuth oxychloride, basic lead carbonate, fish silver or micronized titanium dioxide particle-shaped graphite, platelet-shaped iron oxide, multilayer effect pigments of PVD films or produced by the CVD method (Chemical Vapor Deposition) and liquid crystal (polymer) pigments alone or mixed. Universally applicable compositions according to a the previous claims, thereby characterized in that as component B) a composition of a. 95 to 5 wt .-% of at least one ketone, ketone / aldehyde, urea / aldehyde resin and / or its hydrogenated second product and b. to 95 wt .-% of at least one Ionic liquid, in which the sum of the weights of components a) and b) 100% by weight is, is used. Universally applicable compositions after at least one of the preceding claims, characterized in that in the ketone-aldehyde resins of the component B) a. C-H-acidic ketones are used. Universally applicable compositions after at least one of the preceding claims, characterized in that in the ketone-aldehyde resins of the component B) a. Ketones selected from acetone, acetophenone, methyl ethyl ketone, heptanone-2, pentanone-3, Methyl isobutyl ketone, cyclopentanone, cyclododecanone, mixtures of 2,2,4- and 2,4,4-trimethylcyclopentanone, Cyclohepanone, cyclooctanone, cyclohexanone as starting bonds alone or in mixtures. Universally applicable compositions after at least one of the preceding claims, characterized in that in the ketone-aldehyde resins of the component B) a. alkyl-substituted cyclohexanones having one or more alkyl radicals, having a total of 1 to 8 hydrocarbon atoms, individually or be used in mixture. Universally applicable compositions after at least one of the preceding claims, characterized in that in the ketone-aldehyde resins of the component B) a. 4-tert-amylcyclohexanone, 2-sec-butylcyclohexanone, 2-tert-butylcyclohexanone, 4-tert-butylcyclohexanone, 2-methylcyclohexanone and 3,3,5-trimethylcyclohexanone. Universally applicable compositions after at least one of the preceding claims, characterized in that acetophenone, cyclohexanone, 4-tert-butylcyclohexanone, 3,3,5-trimethylcyclohexanone and heptanone alone or mixed in component B) a. used become. Universally applicable compositions after at least one of the preceding claims, characterized in that as aldehyde component of the ketone-aldehyde resins in component B) a. Formaldehyde, acetaldehyde, n-butyraldehyde and / or iso-butyraldehyde, valeric aldehyde, dodecanal alone or in mixtures be used. Universally applicable compositions after at least one of the preceding claims, characterized in that as aldehyde component of the ketone-aldehyde resins in component B) a. Formaldehyde and / or para-formaldehyde and / or Trioxane can be used. Universally applicable compositions after at least one of the preceding claims, characterized in that resins of acetophenone, cyclohexanone, 4-tert-butylcyclohexanone, 3,3,5-trimethylcyclohexanone, Heptanone alone or in mixture and formaldehyde (component B) a.) be used. Universally applicable compositions after at least one of the preceding claims, characterized in that as component B) a. Resins according to claims 7 to 14, which were hydrogenated after preparation, can be used. Universally applicable compositions after the previous claim, characterized in that as a component B) a. hydrogenated derivatives of resins consisting of acetophenone, Cyclohexanone, 4-tert-butylcyclohexanone, 3,3,5-trimethylcyclohexanone, Heptanone alone or in mixture and formaldehyde. Universally usable compositions according to at least one of the preceding claims, characterized in that as component B) a. Urea-aldehyde resins prepared using a urea of the general formula (i)

in which X is oxygen or sulfur, A is an alkylene radical and n is 0 to 3, with 1.9 (n + 1) to 2.2 (n + 1) mol of an aldehyde of the general formula (ii)

in which R ₁ and R _{2 are} hydrocarbon radicals each having up to 20 carbon atoms and / or formaldehyde used. Universally applicable compositions after at least one of the preceding claims, characterized in that as component B) a. Urea-aldehyde prepared using urea and thiourea, methylene diurea, Ethylene diurea, tetramethylene diurea and / or hexamethylene diurea or mixtures thereof are used. Universally applicable compositions after at least one of the preceding claims, characterized in that as component B) a. Urea-aldehyde prepared using isobutyraldehyde, formaldehyde, 2-methylpentanal, 2-ethylhexanal and 2-phenylpropanal or mixtures thereof used become. Universally applicable compositions after at least one of the preceding claims, characterized in that as component B) a. Urea-aldehyde manufactured using urea, isobutyraldehyde and Formaldehyde be used. Universally applicable compositions after at least one of the preceding claims, characterized in that as component B) b. Ionic liquids organic cations are used. Universally usable compositions according to the preceding claim, characterized in that as component B) b. Ionic liquids containing one or more cations according to the structures below are used

wherein R 1, R ₂ , R 3, R 4, R 5 and R 6 are the same or different and are hydrogen, hydroxy, alkoxy, sulfanyl (RS), NH ₂ , NHR, NRR ', where R and R' identical or different, substituted or unsubstituted alkyl groups having 1 to 8 carbon atoms, or halogen, in particular F, Cl, Br or I, wherein for cations of structure 10 and 11 one of the radicals R1 to R4, preferably all radicals R1 to R4 are preferably are not hydrogen; and / or a saturated or unsaturated, linear or branched aliphatic hydrocarbon radical having 1 to 40, preferably 1 to 30, preferably 1 to 20 carbon atoms, which is substituted, for example with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or may be unsubstituted; and or a cycloaliphatic hydrocarbon radical having 5 to 30, preferably 5 to 10, preferably 5 to 8 carbon atoms, which may be substituted, for example with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or unsubstituted ; and / or an aromatic hydrocarbon radical having 6 to 30, preferably 6 to 12, preferably 6 to 10 carbon atoms, which is substituted, for example with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or can be unsubstituted; and / or an alkylaryl radical having 7 to 40, preferably 7 to 14, preferably 7 to 12 carbon atoms, which is substituted, for example with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or unsubstituted can be; and / or a linear or branched aliphatic and / or cycloaliphatic and / or aromatic hydrocarbon radical having from 2 to 100 carbon atoms, preferably from 2 to 80 carbon atoms, particularly preferably from 2 to 40, interrupted by one or more heteroatoms (oxygen, NH, NCH ₃ ) Carbon atoms which may be substituted, for example with amino, hydroxy, alkyl of 1 to 8, preferably 1 to 4 carbon atoms and / or halogen groups, or may be unsubstituted and / or one or more functionalities selected from the group consisting of OC (O) -, - (O) CO-, -NH-C (O) -, - (O) C-NH, - (CH ₃ ) NC (O) -, - (O) CN (CH ₃ ) -, -S (O) ₂ -O-, -OS (O) ₂ -, -S (O) ₂ -NH-, -NH-S (O) ₂ -, -S (O) ₂ -N (CH ₃ ) -, -N (CH ₃ ) -S (O) ₂ -, interrupted linear or branched aliphatic hydrocarbon radical having 2 to 20 carbon atoms, substituted, for example, with a hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or unsubsti can be tuiert; and / or a terminal -OH, -NH ₂ , -N (H) CH ₃ -functionalized linear or branched aliphatic hydrocarbon radical having 1 to 20 carbon atoms which is substituted, for example with a hydroxy, alkyl with 1 to 8, preferably 1 to 4 Carbon atoms and / or halogen group, or may be unsubstituted. Universally applicable compositions after at least one of the preceding claims, characterized in that as component B) b. Ionic liquids containing a cation based on ammonium, pyridinium, Pyrrolidinium, pyrroliaium, oxazolium, oxazolinium, imidazolium, thiazolium or phosphonium ions. Universally applicable compositions after at least one of the preceding claims, characterized in that as component B) b. Ionic liquids are used, preferably one or more anions selected from Phosphate, halogen phosphates, in particular hexafluorophosphate, halides, especially chloride, alkyl phosphates, aryl phosphates, nitrate, sulfate, Hydrogen sulfate, alkyl sulfates, aryl sulfates, perfluorinated alkyl and aryl sulfates, sulfonate, alkyl sulfonates, aryl sulfonates, perfluorinated alkyl and arylsulfonates, in particular trifluoromethylsulfonate, tosylate, Perchlorate, tetrachloroaluminate, heptachlorodialuminate, tetrafluoroborate, Alkyl borates, aryl borates, amides, especially perfluorinated amides, Dicyanamide, saccharinate, thiocyanate, carboxylates, in particular acetates, preferably acetate and / or trifluoroacetate, and / or bis (perfluoroalkylsulfonyl) amide anions, exhibit. Universally usable compositions according to at least one of the preceding claims, characterized in that as component B) b. Ionic liquids are particularly preferably used which contain at least one salt which contains as cation an imidazolium, a pyridinium, an ammonium or phosphonium ion of the following structures:

wherein R 1, R 2, R 3 and R 4 may be the same or different and a saturated or unsaturated, linear or branched aliphatic hydrocarbon radical having 1 to 40, preferably 1 to 30, preferably 1 to 20 carbon atoms which is substituted, for example with a hydroxy, alkyl with 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or may be unsubstituted; and / or interrupted by one or more heteroatoms (oxygen, NH, NCH ₃₎ linear or branched aliphatic and / or cycloaliphatic and / or aromatic hydrocarbon radical with 2 to 100 carbons atoms, preferably having 2 to 80 carbon atoms, more preferably having 2 to 40 carbon atoms, which may be substituted, for example, with amino, hydroxy, alkyl having 1 to 8, preferably 1 to 4 carbon atoms and / or halogen groups, or unsubstituted ; and / or one or more functionalities selected from the group -OC (O) -, - (O) CO-, -NH-C (O) -, - (O) C-NH, - (CH ₃ ) NC (O) -, - (O) CN (CH ₃₎ -, -S (O) ₂ -O-, -OS (O) ₂ -, -S (O) ₂ -NH-, -NH-S ( O) ₂ -, -S (O) ₂ -N (CH ₃ ) -, -N (CH ₃ ) -S (O) ₂ -, interrupted linear or branched aliphatic hydrocarbon radical having 2 to 20 carbon atoms, substituted, for example with a hydroxy, alkyl of 1 to 8, preferably 1 to 4 carbon atoms and / or halogen group, or may be unsubstituted; and / or a terminal -OH, -NH ₂ , -N (H) CH ₃ -functionalized linear or branched aliphatic hydrocarbon radical having 1 to 20 carbon atoms which is substituted, for example with a hydroxy, alkyl with 1 to 8, preferably 1 to 4 Carbon atoms and / or halogen group, or unsubstituted; and an anion selected from tetrafluoroborate, alkyl borate, in particular triethylhexyl borate, aryl borate, halogenophosphate, in particular hexafluorophosphate, nitrate, sulfonates, in particular perfluorinated alkyl and aryl sulfonals, hydrogen sulfate, alkyl sulfates, halides, in particular chlorides, acetates, thiocyanates, perfluorinated amides, dicyanamide and / or bis (perfluoroalkylsulfonyl) amide, especially bis (trifluoromethanesulfonyl) amide ((CF ₃ SO ₂ ) ₂ N). Universally applicable compositions after at least one of the preceding claims, characterized in that as component B) b. also a mixture is used by at least two different ionic liquids and Here, the IL at least two different anions and / or two different Cations may have. Universally applicable compositions according to a the previous claims, characterized in that binder is used as component C) become. Universally applicable compositions according to a the previous claims, characterized in that as component C) aqueous and / or solvent-containing and / or solvent-free, foreign and / or self-crosslinking and / or air-drying (physically drying) and / or oxidatively curing Binders are used Universally applicable compositions according to a the previous claims, characterized in that as component C) binders selected from the group of polyurethanes, polyacrylates, polyethers, polyesters, Alkyd resins, polyamides, casein, cellulose ethers, derivatives of cellulose, Polyvinyl alcohols and derivatives, polyvinyl acetates, polyvinyl chlorides, Polyvinylpyrolidones, rubbers, natural resins, hydrocarbon resins such as. Coumarone, indene, cyclopentadiene resins, terpene resins, maleate resins, Phenolic resins, phenolic / urea-aldehyde resins, Aminoplasts (e.g., melamine, benzoguanamine resins), epoxy acrylates, Epoxy resins, silicic acid esters and / or alkali silicates (e.g., water glass) and / or silicone resins and / or fluorine-containing polymers used alone or in admixture become. Universally applicable compositions according to a the previous claims, characterized in that as component D) auxiliaries and additives be used. Universally applicable compositions according to a the previous claims, characterized in that as component D) auxiliaries and additives, selected from inhibitors, organic solvents, Water, surface-active Substances, oxygen and / or radical scavengers, catalysts, light stabilizers, Color brighteners, photosensitizers and initiators, additives for influencing rheological properties, e.g. thixotropic agents and / or thickening agents, leveling agents, skin-preventing agents, defoamers, Antistatic agents, lubricants, wetting and dispersing agents, cross-linking agents such as blocked and / or unblocked (poly) isocyanates, preservatives such as. also fungicides and / or biocides, thermoplastic additives, Plasticizers, matting agents, fire retardants, release agents and / or Be used blowing agents alone or in mixture. A process for the preparation of universally usable compositions, essentially comprising A) 1 to 70 wt .-% of at least one colorant and / or filler and B) 30 to 99 wt .-% of at least one composition of a. 95 to 5 wt .-% of at least one ketone, ketone / aldehyde, urea / aldehyde resin and / or its hydrogenated derivative and b. up to 95% by weight of at least one ionic liquid, wherein the sum of the weights of components a) and b) is 100 wt .-% and optionally C) 0 to 69 wt .-% of at least one further binder and D) 0 to 69 wt .-% of at least one excipient, wherein the Sum of the weights of components A) to D) is 100 wt .-%, by intensive mixing by stirring and / or dispersing the components at temperatures of +20 to + 80 ° C. Use of the universally applicable compositions according to at least one of the preceding claims for solvent-borne and / or aqueous and / or for solvent-free Coating materials. Use of the universally applicable compositions according to at least one of the preceding claims for leveling compounds, fillers, base and / or topcoats and printing inks, ballpoint pen pastes, pigment pastes, Inks, polishes, glazes, laminations, cosmetics and / or Sealing and insulating materials as well Adhesives and for coloring of plastics. Use of the universally applicable compositions according to at least one of the preceding claims for the coating and / or Printing and / or lamination and / or bonding and / or coloring of Objects. Use of the universally applicable compositions according to at least one of the preceding claims for the coating and / or Printing and / or lamination and / or bonding of objects Metals, plastics, paper, cardboard, inorganic materials such as Ceramics, stone, concrete and / or glass, textiles, fibers, fabric materials, Leather and / or synthetic materials such as artificial leather, wood, Films of plastics and / or composites such as e.g. aluminum coated Films. objects manufactured using universally applicable compositions according to at least one of the preceding claims.