Talk:Methylcyclopentadienyl manganese tricarbonyl
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Article has bias
[edit]It's missing the history of the Canadian ban and the corporate lawsuit trying to force it to be un-banned. It makes it sound as if MMT was actually found to be safe by scientific research, rather than found to be "safe" as the result of a legal threat. — Preceding unsigned comment added by 24.59.149.223 (talk) 19:25, 15 December 2013 (UTC)
Article DEFINITELY has bias
[edit]The statement on vehicle manufacturers says "some" vehicle manufacturers do NOT recommend using MMT on their vehicles". That is COMPLETELY FALSE: it should truthfully say: MOST vehicle manufacturers recommend AGAINST the use of MMT on their vehicles". At least Chrysler, VW and BMW caution the owner AGAINST using MMT additivated gasoline. Anyone can find that MMT leaves deposits inside the catalytic converter, as well as on spark plugs, where it is clearly visible. The deposits are red colored, like a red brick. 192.100.180.10 (talk) 19:07, 23 July 2015 (UTC)Amclaussen, Mexican Petroleum Institute. — Preceding unsigned comment added by 192.100.180.21 (talk) 20:26, 20 June 2014 (UTC)
- Please provide a decent source and we'll take care of this bias. Editors here have little contact with the petrochemical industry, so your advice is needed. --Smokefoot (talk) 22:52, 20 June 2014 (UTC)
- I'm no petrochemical scientist, but I can confirm that Ford specifically states, "Do not use... fuels containing the octane booster, methylcyclopentadienyl manganese tricarbonyl (MMT)." Just finished reading that bullet point in my owners manual for the 2014 Focus I just purchased. It's found on page 155. Mine is the third printing, so it may vary when compared to other printings. --atirox (talk) 04:50, 22 September 2014 (UTC)
Not only does the article not have a bias, it is blatently protecting the interests of Afton Chemicals. — Preceding unsigned comment added by 2602:306:CD66:2BA0:D97E:A876:BE0B:E958 (talk) 18:21, 17 October 2014 (UTC)
Error in image
[edit]Et2Al6 in the methodology diagram must be Al2Et6 Fivemack 13:49, 12 January 2007 (UTC)
References
[edit]- Lynam, DR; Roos, JW; Pfeifer, GD; Fort, BF; Pullin, TG (1999 Apr-Jun"). "Environmental effects and exposures to manganese from use of methylcyclopentadienyl manganese tricarbonyl (MMT) in gasoline". Neurotoxicology" datatype="xsd:string. 20 (2–3): 145–50. PMID 10385878.
{{cite journal}}: Check date values in:|date=(help) - Crump, Kenny S (2000). "Manganese exposures in Toronto during use of the gasoline additive, methylcyclopentadienyl manganese tricarbonyl". Journal of Exposure Analysis and Environmental Epidemiology. 10 (3): 227–39. doi:10.1038/sj.jea.7500085. PMID 10910116.
- Zayed, Joseph; Vyskocil, Adolf; Kennedy, Greg (1999). "Environmental contamination and human exposure to manganese - contribution of methylcyclopentadienyl manganese tricarbonyl in unleaded gasoline". International Archives of Occupational and Environmental Health. 72 (1): 7–13. doi:10.1007/s004200050327. PMID 10029224.
- Gulson, B; Mizon, K; Taylor, A; Korsch, M; Stauber, J; Davis, J; Louie, H; Wu, M; Swan, H (2006). "Changes in manganese and lead in the environment and young children associated with the introduction of methylcyclopentadienyl manganese tricarbonyl in gasoline—preliminary results". Environmental Research. 100 (1): 100–14. doi:10.1016/j.envres.2005.03.013. PMID 16337847.
- Ter Haar, G. L.; Grifffing, M. E.; Brandt, M.; Oberding, D. G.; Kapron, M. (1975). "Methylcyclopentadienyl Manganese Tricarbonyl as an Antiknock: Composition and Fate of Manganese Exhaust Products". Journal of the Air Pollution Control Association. 25 (8): 858. doi:10.1080/00022470.1975.10470152.
- Aue, Walter A.; Millier, Brian.; Sun, Xun Yun. (1990). "Determination of (methylcyclopentadienyl)manganese tricarbonyl in gasolines by gas chromatography with flame photometric detection". Analytical Chemistry. 62 (22): 2453. doi:10.1021/ac00221a008.
- Normandin, L; Kennedy, G; Zayed, J (1999). "Potential of dandelion (Taraxacum officinale) as a bioindicator of manganese arising from the use of methylcyclopentadienyl manganese tricarbonyl in unleaded gasoline". The Science of the total environment. 239 (1–3): 165–71. doi:10.1016/S0048-9697(99)00292-2. PMID 10570841.
- Du, Bin; Wei, Qin; Xu, Guiying (1999). "Rapid Determination of Methylcyclopentadienyl Manganese Tricarbonyl in Gasoline by FAAS". Analytical Letters. 32 (5): 1011. doi:10.1080/00032719908542873.
- Davis, JM (1998). "Methylcyclopentadienyl manganese tricarbonyl: Health risk uncertainties and research directions". Environmental Health Perspectives. 106 (Suppl 1): 191–201. PMC 1533284 Methylcyclopentadienyl manganese tricarbonyl: health risk uncertainties and research directions. PMID 9539013.
{{cite journal}}: Check|pmc=value (help) - Frumkin, Howard; Solomon, Gina (1997). "Manganese in the U.S. Gasoline supply". American Journal of Industrial Medicine. 31 (1): 107–15. doi:10.1002/(SICI)1097-0274(199701)31:1<107::AID-AJIM16>3.0.CO;2-6. PMID 8986262.
- Pellizzari, E (1999). "Particulate matter and manganese exposures in Toronto, Canada". Atmospheric Environment. 33 (5): 721. doi:10.1016/S1352-2310(98)00229-5.
- Sierra, Patricia; Loranger, Sylvain; Kennedy, Greg; Zayed, Joseph (1995). "Occupational and Environmental Exposure of Automobile Mechanics and Nonautomotive Workers to Airborne Manganese Arising from the Combustion of Methylcyclopentadienyl Manganese Tricarbonyl (MMT)". American Industrial Hygiene Association Journal. 56 (7): 713–6. doi:10.1080/15428119591016746. PMID 7618609.
- Pfeifer, G.D.; Roper, J.M.; Dorman, D.; Lynam, D.R. (2004). "Health and environmental testing of manganese exhaust products from use of methylcyclopentadienyl manganese tricarbonyl in gasoline". Science of the Total Environment. 334–335: 397–408. doi:10.1016/j.scitotenv.2004.04.043. PMID 15504525.
- Loranger, Sylvain; Zayed, Joseph (1994). "Manganese and lead concentrations in ambient air and emission rates from unleaded and leaded gasoline between 1981 and 1992 in Canada: A comparative study". Atmospheric Environment. 28 (9): 1645. doi:10.1016/1352-2310(94)90310-7.
- Garrison, Arthur W.; Lee Wolfe, N.; Swank, Robert R.; Cipollone, Mark G. (1995). "Environmental fate of methylcyclopentadienyl manganese tricarbonyl". Environmental Toxicology and Chemistry. 14 (11): 1859. doi:10.1002/etc.5620141107.
- Davis, J. Michael; Jarabek, Annie M.; Mage, David T.; Graham, Judith A. (1998). "The EPA Health Risk Assessment of Methylcyclopentadienyl Manganese Tricarbonyl (MMT)". Risk Analysis. 18 (1): 57–70. doi:10.1111/j.1539-6924.1998.tb00916.x. PMID 9523444.
- Hinderer, Robert K. (1979). "Toxicity studies of methylcyclopentadienyl manganese tricarbonyl (MMT)". American Industrial Hygiene Association Journal. 40 (2): 164–7. doi:10.1080/15298667991429462. PMID 495448.
- Zayed, J.; Gérin, M.; Loranger, S.; Sierra, P.; Bégin, D.; Kennedy, G. (1994). "Occupational and Environmental Exposure of Garage Workers and Taxi Drivers to Airborne Manganese Arising from the Use of Methylcyclopentadienyl Manganese Tricarbonyl in Unleaded Gasoline". American Industrial Hygiene Association Journal. 55 (1): 53–8. doi:10.1080/15428119491019267. PMID 8116528.
- Caprino, L; Togna, GI (1998). "Potential health effects of gasoline and its constituents: A review of current literature (1990-1997) on toxicological data". Environmental Health Perspectives. 106 (3): 115–125. doi:10.1289/ehp.98106115. PMC 1533055. PMID 9452413.
- Cooper, W. Clark (1984). "The health implications of increased manganese in the environment resulting from the combustion of fuel additives: A review of the literature". Journal of Toxicology and Environmental Health. 14 (1): 23–46. doi:10.1080/15287398409530561. PMID 6389893.
- Abbott, Peter J. (1987). "Methylcyclopentadienyl manganese tricarbonyl (MMT) in petrol: The toxicological issues". Science of the Total Environment. 67 (2–3): 247–55. doi:10.1016/0048-9697(87)90215-4. PMID 3438743.
- http://publications.gc.ca/collections/Collection/H46-1-34-1994E-1.pdf.
{{cite journal}}: Cite journal requires|journal=(help); Missing or empty|title=(help) - Vellareddy Anantharam; Kitazawa, M; Wagner, J; Kaul, S; Kanthasamy, AG (2002-03-01). "Caspase-3-Dependent Proteolytic Cleavage of Protein Kinase Cδ Is Essential for Oxidative Stress-Mediated Dopaminergic Cell Death after Exposure to Methylcyclopentadienyl Manganese Tricarbonyl". The Journal of Neuroscience. 22 (5): 1738–51. PMID 11880503.
--Stone (talk) 12:41, 28 December 2012 (UTC)
- Interesting collection. The primary literature on commercial chemicals is usually large. I bolded an attractive secondary source, per WP:MEDRS. I dont think we use MMT in the US, but they do in Canada. The key question would be the benefits of replacing tetraethyl lead (and other additives) with MMT. --Smokefoot (talk) 17:45, 28 December 2012 (UTC)
How to make it
[edit]What is the synesis of this compond? 76.124.224.179 (talk) 15:11, 27 January 2013 (UTC)
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