Hadean zircon
Hadean zircon is the oldest-surviving crustal material from the Earth's earliest geological time period, the Hadean eon, about 4 billion years ago. Zircon is a mineral that is commonly used for radiometric dating because it is highly resistant to chemical changes and appears in the form of small crystals or grains in most igneous and metamorphic host rocks.[1]
![](http://upload.wikimedia.org/wikipedia/commons/thumb/d/d7/Jack_Hills%2C_Western_Australia_%28Landsat_5_TM%2C_2009-07-14%2C_detail%29.jpg/330px-Jack_Hills%2C_Western_Australia_%28Landsat_5_TM%2C_2009-07-14%2C_detail%29.jpg)
Hadean zircon has very low abundance around the globe because of recycling of material by plate tectonics. When the rock at the surface is buried deep in the Earth it is heated and can recrystallise or melt.[1] In the Jack Hills, Australia, scientists obtained a relatively comprehensive record of Hadean zircon crystals in contrast to other locations. The Jack Hills zircons are found in metamorphosed sediments that were initially deposited around 3 billion years ago,[1] or during the Archean Eon. However, the zircon crystals there are older than the rocks that contain them. Many investigations have been carried out to find the absolute age and properties of zircon, for example the isotope ratios, mineral inclusions, and geochemistry of zircon. The characteristics of Hadean zircons show early Earth history and the mechanism of Earth's processes in the past.[1] Based on the properties of these zircon crystals, many different geological models were proposed.
Background
[edit]Importance
[edit]Deeper understanding of Earth history
[edit]The geological history of the Hadean eon of early earth is poorly known due to the lack of rock record older than 4.02 Ga (giga-annum or billion years).[2][3][4] Most scientists accept that the plate recycling mechanism has melted almost all pieces of Earth's crust.[2] However, some tiny parts of the crust have not been melted, as some rare Hadean zircon grains included in much younger host rock were discovered.[2] The examination of Hadean detrital or inherited grains of zircon can give evidence of geophysical conditions of the early earth.[4]
Scientific contribution
[edit]Since there is no strong evidence depicting the early Earth's true environment, many models are generated to explain early Earth history.[1] The high value of Hadean heat production and impact flux proved that continental crust did not exist, which is very different from the modern process. In the absence of large amount of undistributed data and within the constraints of analytical methods, calculation on geophysics and planetary science has been rapidly developed to explore this new area of knowledge.[1]
Abundance
[edit]Less than 1% of zircons detected around the world are over four billion years old.[1] The probability of discovering so much as a single zircon over four billion years in age is very low.[1] The abundance of over four billion-year-old zircon in the Jack Hills is anomalously high for most Archean quartzites and thus abundances probabilities of other spots are extremely low (0.2–0.02%).[5][failed verification]
By adopting uranium-lead dating (U-Pb) together with other analytical methods, more geochemical information can be obtained. Only 3% out of over 200,000 detrital zircon grains dated by U-Pb analysis are over four billion years old.[6][7]
![](http://upload.wikimedia.org/wikipedia/commons/thumb/6/64/Zircon_type.png/390px-Zircon_type.png)
Types
[edit]Due to different content of uranium and trace element concentration, four clusters of zircons are identified as below [1]
- Lunar and meteorite zircon
- Detrital grains zircon
- Kimberlite zircon
- Ocean crust zircon
Low crystallisation temperatures and trace element characteristics are the two major characteristics that differentiate mantle derived zircon or oceanic crust-derived zircon.[8][9][10] Lunar and meteoritic zircons are unique because of their REE signature for example, lack of a cerium anomaly.[11] The crystallization temperature ranges from 900 to 1100 °C. In contrast, terrestrial Hadean zircons are restricted to 600 to 780 °C.[12] Hadean Jack Hills zircon has a wide range of oxygen fraction comparing to meteoritic zircons.[12] No extraterrestrial zircons were found in any terrestrial locality. The textural characteristics like the growth zoning and inclusion mineralogy shows that Hadean zircon from the Jack Hills all come from igneous sources.[13][14]
Properties
[edit]![](http://upload.wikimedia.org/wikipedia/commons/thumb/a/a2/Zircon_Age_distribution_U-Pb.png/280px-Zircon_Age_distribution_U-Pb.png)
The unspecified samples used for analyses below were Jack Hills zircon in Australia because of the high abundances and data available.
Age distribution
[edit]U-Pb dating in the U-Pb zircon system has long been viewed as the crustal geochronometer because zircon is chemically resistant and enriched in U and Th compared to the daughter product Pb.[16] Trace element and isotopic composition of zircon is important to determine the crystallisation environment.[16]
Results from detrital zircons from the Erawondoo Hill discovery site conglomerate[17][18] generally show the zircons to have a bimodal age distribution with major peaks at c. 3.4 and 4.1 Ga.
However, zircon is sensitive to radiation damage and can degrade into amorphous material.[19] The Hadean zircon with original uranium concentrations greater than 600 ppm is challenged by the effect of post-crystallization alteration.
Isotope geochemistry
[edit]Stable isotope data, indicating that the original host rocks to the zircon related to a significant amount of material formed on or near the Earth's surface and subsequently transferred to a middle- to lower-crustal level where they melted to generate the host magmas from which zircon crystallised.[6][13]
Data type | Observation | Interpretation | Limitation |
---|---|---|---|
Oxygen isotope ratios | Granitoids with lower ઠ18O values | There were hydrothermal interactions with meteoric water instead of weathering.[20][21] | There is a lack of comprehensive record of the analysed areas within the grains, which leads to difficulty in relating ages of specifically dated parts of the zircon grains to their oxygen and hafnium isotope systematics and trace element concentrations.[22] |
Ratios of oxygen isotopes have been measured in Hadean zircons. High value of 18ઠSMOW observed in Hadean Jack Hills zircons led to two different ideas about the source of Hadean zircon.[22][6] 18O-enriched clay minerals were found in the host rock of zircon grains. | Water was present on the Earth's surface around 4.3 Ga.[6] | ||
Hadean Jack Hills zircons contain more 18O-enrichments than the mantle zircon about 5.3%.[23] I-type granitoids protoliths give relatively low ઠ18O values while those derived by S type metasedimentary rocks have higher ઠ18O values. | The presence in the protolith of recycled crustal material that had interacted with liquid water under surface, or near surface, condition.[23] | ||
Lutetium-hafnium | The ratio of isotopes of hafnium 176Hf/177Hf data in crustal rocks being consistent with the formation of crust since 4.5 Ga.[24][25] | Lu-Hf systematics potentially indicating existence of an early formed reservoir, similar to continental crust in its degree of Lu depletion relative to Hf.[24][25] | Most of the data matches the formation of crust at 4.5 Ga while some zircon data is unreasonable requiring the removal of protolith from chrondritic uniform reservoir (CHUR). Since these extra findings, studies cannot conform the positive value of EHf(T) due to the complication of Hf isotope analysis and lack of U-Pb date being simultaneously available.[24] |
Cluster of results along a line corresponding to a Lu/Hf ~0.01, low reservoir at ~4Ga[26] | The data is consistent with either early extraction of very felsic crust or by remelting of a primordial basaltic reservoir, but in either case extrapolation of this trend yields a present-day εHf(T) of approximately −100[25][26] | A recycling event c. 3.9–3.7 Ga which resembles the Hf isotope evolution of modern subduction-related orogens and so may have additional tectonic significance.[26] | |
Plutonium-xenon | Some Hadean zircon grains originally contained plutonium, an element that has since disappeared from the natural environment. In the meteorite record, the abundance ratio of initial plutonium to uranium (Pu/U) was about 0.007 and 244Pu was present in the early Solar System.[27] | The result of the ratio can be interpreted as xenon loss during later metamorphism. Uranium became oxidised to soluble uranyl ion (UO22+) while the solubility of plutonium compounds is low, variations in Pu/U are regarded as an effective indicator of aqueous alteration in Jack Hills protoliths.[28] | Only Nd/U has correlations expected from aqueous processes excluding analysis of Xe isotopic ratios, U-Pb age, trace element contents, and δ18O[27][28] |
The initial Pu/U ratios of Jack Hills zircon ranges from c. 0.007 to zero.[28] | Due to Xe loss during later metamorphism. Variation in Pu/U has been suggested as a potential indicator of aqueous alteration in the Jack Hills zircon protoliths[28] | ||
High-Nd/U zircons display only low Pu/U, while Nd/U zircons show more heterogeneous Pu/U[28] | High-Nd/U group appears less magmatically evolved than other Hadean zircons, has REE patterns suggestive of some degree of alteration, either by hydrothermal fluid interaction or phosphate replacement, and consists of solely low-Pu/U zircons with a range of Hadean to Proterozoic U-Xe ages[27][28] | ||
Lithium | Lithium isotopes significantly vary in Hadean zircon. The 7Li isotope result of Hadean Jack Hills zircons gave highly negative values.[29] | The environment of forming zircon as highly weathered.[29] | A high lithium diffusion rate in zircon at low temperature[30] and exchange with hydrogen during metamorphism are two examples of subsequent variations to lithium that may limit the usefulness of the measurements[30] |
Li is homogeneously distributed within single growth zones of the zircons. Jack Hills zircons are zoned in both 7Li and Li concentration.[31] | These values correlate with igneous growth zoning.[32][31] |
Mineral inclusions
[edit]![](http://upload.wikimedia.org/wikipedia/commons/thumb/6/6b/Biotite_and_muscovite.jpg/170px-Biotite_and_muscovite.jpg)
The development of textural criteria for identifying primary inclusions[33] opens up possibilities for recognising zircons' changing provenance with time and investigating their post-depositional alteration history. There are two common inclusion assemblages that are consistent with their forming in "I-type" (hornblende, quartz, biotite, plagioclase, apatite, ilmenite) and "S-type" (quartz, K-feldspar, muscovite, monazite) granitoids.[33] Dominated by quartz with less abundant K-feldspar, plagioclase, muscovite, biotite, and phosphates, that are interpreted to have formed under relatively low geothermal gradient similar to that pertaining to modern subduction zones.[14][33]
Data type | Observation | Interpretation |
---|---|---|
Muscovite | Quartz and muscovite are the principal inclusion phases, potentially pointing to an aluminous granitic source.[14][34] Hopkins (2010) used a thermodynamic solution model for celadonite substitution in muscovite[35] to estimate pressures for muscovite inclusions in magmatic zircons. The result revealed that the pressure conditions for over 1700 inclusion samples is greater than 5 kbar, coupled with a relatively low host zircons crystallization temperature.[35] | Muscovite inclusion coupled with a thermodynamic model implied that the Earth surface had a remarkably low heat flow. This result led scientists to suggest formation in an underthrust or subduction-like environment as found on the modern Earth[14][34] |
Iron oxides | Cerium anomaly of a zircon (Ce/Ce*) is a quantitative investigation for host magma fO2.[36] Hadean Jack Hills zircons show a range in fO2 with an average near the fayalite-magnetite-quartz (FMQ) buffer.[37] | The Hadean geological setting is similar to the modern upper mantle[36][37] |
Biotite | Composition of biotite differ among granitoids. FeO, MgO and Al2O3 content isolate calc-alkaline, peraluminous and alkaline granitoids.[38][full citation needed] | The nature of Hadean melt compositions can be known.[38] |
Sulfide and carbonaceous phases have been revealed in Hadean zircon though the number of cases is small.[38] | The rare phases have deleted the volatile contents in Hadean magmas and source materials.[38] | |
Graphite | By knowing the occurrence of carbon, existence of life can be revealed in the aspect of timing, conditions and mechanisms.[39][40] | Isotopic result identified the zircon was 3.8 to 3.5 billion years age and metabolism has occurred within the host microbiota.[39][40] |
Zircon geochemistry
[edit]By analysing the content of zircon, some zircon show the presence of titanium, rare earth minerals, lithium, aluminium and carbon. Certain ratio and normal distribution give evidence of zircon's origin and the source of magma.
Data type | Observation | Interpretation | Limitation |
---|---|---|---|
Titanium | The content of Ti-in-zircon serves as a crystallization thermometer given knowledge of the melt aSiO2 and aTiO2.[41][42] The Ti measurements were applied to grains ranging from 3.91 to 4.35 Ga and the majority of the data plots a normal distribution graph.[41] | Crystallisation of Ti-in-zircon grains are from evolved melts[41] | It yielded an extremely high temperature 680±25 °C. Since the crystallisation of rutile is unknown, researchers can only estimate the temperature by calculation.[43] |
Rare-earth mineral | Cerium anomaly of a zircon (Ce/Ce*) is a quantitative investigation for host magma fO2.[42] The result showed low value of Ce/Ce* ratio. | Diversity of source materials[42] | REE signatures in some zircon grains that have been interpreted to indicate crystallisation of these grains from evolved melts.[41][42][43] |
In EDS analysis, magnetite was dominant in the inclusion instead of ilmenite in granitoids.[44] | Hydrothermal alternation of zircon is often determined by high, flat light rare-earth mineral (LREE) pattern.[44] | ||
Lithium | Li zoning in zircon serve as a peak temperature indicator while examining retention of primary remanent magnetic signals.[32] Jack Hills zircon containing c. 5up-wide Li concentration band which required below 500 °C peak heating temperature of zircon. | The grains can be applied to study primary magnetism because it did not exceed the Curie temperature which is 585 °C for magnetite.[32] | The metaconglomerates at Erawondoo Hill did not experience temperature greater than 500 °C.[31] The result showed that there is variation of data and thermal history in different occurrences.[31] |
Aluminium | Peraluminous granitoids contain around 10 ppm aluminium in Jack Hills zircon[32] while the I-type and A-type zircon obtained average 1.3 ppm. The molar value of Al2O3/(CaO+Na2O+K2O) greater than 1.[45] | The origin is from recycled pelitic material.[45] | Small amount of sample zircon contains high Al contents suggests that metaluminous crustal rocks is more common than peraluminous rocks in the Hadean. However, the c. 20% overlap of low Al (i.e., < 5 ppm) in S-type zircons somewhat obscures this inference.[46] |
Some of the grains show high aluminium content[45] | Metaluminous crustal rocks may be more common than peraluminous rocks in the Hadean.[45] | ||
Carbon | Scientists measured concentration of carbon in the form of graphite in zircon by using secondary ion mass spectrometer (SIMS). Detecting Hadean crustal carbon could ensure that there was a transfer of carbon from mantle reservoirs[47] | Allow the selection among models of the early earth.[48] | Quite a few early earth models contain this property which cannot confirm which model is correct[47][48] |
Analytic method
[edit]![](http://upload.wikimedia.org/wikipedia/commons/thumb/a/a1/Principe_FIB-en.svg/220px-Principe_FIB-en.svg.png)
Ion microprobe analysis
[edit]Ion microprobe (or secondary ion mass spectrometry, SIMS) and uranium-thorium-lead geochronology are two common methods to measure isotope in specific time interval.[49][50]
Highly precise in situ SIMS measurements of oxygen isotopes[51] and OH/O ratios, laser-ablation inductively-coupled mass spectrometry (LA-ICP-MS) determination of hafnium isotopes,[52][53] and atom-probe tomography.[54] LA-ICP-MS is the most common method to date using isotopes but it lacks capacity to measure 204Pb. Therefore, there is a possibility that the occurrences of single zircons over 4 billion years old could be due to inclusion of non-radiogenic Pb.
![](http://upload.wikimedia.org/wikipedia/commons/thumb/3/33/EPMA.jpg/170px-EPMA.jpg)
U-Pb dating, delta 18O and Ti measurements can be tested by CAMECA ims 1270 ion microprobe.[51] Epoxy are applied on the sample. A flat surface of sample is needed to conduct an analysis.[55] U-Pb dating and T measurement uses a primary O− beam with low intensity (10-15 nA). U-Pb age standard AS3 was used for dating studies. The concentration of Ti can be determined based on analysis of Jack Hills zircon[55] and NIST610 glass.
Electron microprobe analysis
[edit]For inclusions investigation, JEOL 8600 electron microprobe analyzer (EPMA) were used to chemically analyze zircon.[1] It is used to analyze the chemical composition of material. Electron beams are emitted to the mineral's surface and blow off ions and estimate the abundance of the elements within a very small sized sample. Many isotopes can be measured at once in this analysis for example Ti and Li.[32]
Occurrence
[edit]![](http://upload.wikimedia.org/wikipedia/commons/thumb/3/3a/Zircon_world_map.pdf/page1-390px-Zircon_world_map.pdf.jpg)
Occurrences | Analytic method and result | Interpretation |
---|---|---|
Australia[edit] | ||
Mt. Narryer[56][57] | Ion microprobe dating of 80 detrital zircons from quartzites have disclosed that 2% to 12% grains >4.0Ga, with younger zircons ranging to ca.3 Ga. In the LA-ICP-MS study, Mt. Narryer zircons has higher U contents and lowest Ce/Ce* in contrast to Jack Hills zircons | Diversity of source rock. Magmatic origins. |
Churla Wells[58] | The grains are 4.14 to 4.18Ga by using 207Pb/206Pb dating. Core region has a much lower Hf, REE, Uand Th than other outer region. While U content in core is around 666ppm, Th/U is 0.6. | Granitic magma origin |
Maynard Hills[59] | Dating of greenstone belt revealed that the 207Pb/206Pb age is 4.35Ga. | / |
Mt Alfred[60] | The concordant zircon has the age 4.17Ga. No geochemistry data has been collected | / |
North America[edit] | ||
Northwest Territory, Canada[61][62][63] | The protolith crystallisation age is 3.96Ga analysed by U-Pb dating. Applying LA-ICP-MS, 4.20+0.06Ga zircon was being dated. The unaltered zircon under the above method obtained LREE pattern. | Magmatic origin. Derivation from a felsic melt by a process other than differentiation of a mafic magma |
Greenland[64][65] | The crystallisation age is determined as 3.83±0.01Ga by ion microprobe dating. 4.08±0.02Ga was identified in U-Pb survey | / |
Asia[edit] | ||
Tibet[66] | In ion microprobe method, detrital grain's Th/U ratios is greater than 0.7 | Magmatic origin |
North Qinling[67] | The LA-ICP-MS age of xenocrystic zircon in North Qinling Orogenic Belt is 4.08Ga. Hf isotope also support the age data of LA-ICP-MS test | / |
North China Craton[68] | The zircon is 4.17±0.05Ga determined by LA-ICP-MS U-Pb dating method. Th/U ratio is 0.46 | Magmatic origin |
South China[69] | Conducting ion microprobe U-Pb dating, 207Pb/206Pb age is 4.13±0.01 Ga with 5.9±0.1% 18O isotope data. Positive Ce anomaly | early earth is a highly oxidizing environment and a high Ti-in-zircons crystallization temperature of 910'C. |
South America[edit] | ||
Southern Guyana[70] | 4.22Ga by LA-ICP-MS U-Pb dating method. No other geochemical analysis has been conducted | / |
Eastern Brazil[71] | The age of the rock is 4.22Ga and Th/U ratios of 0.8 and high U contents (up to 1400ppm) | Felsic magmatic origin |
Proposed mechanisms for forming Hadean Jack Hills zircons
[edit]![](http://upload.wikimedia.org/wikipedia/commons/thumb/e/ea/Cross-section_of_a_subduction_zone_and_back-arc_basin.jpg/390px-Cross-section_of_a_subduction_zone_and_back-arc_basin.jpg)
Plate tectonic theory is widely accepted for the generation of crust. With the Hadean rock record, most of the scientists concluded that the hypothesis of a hellish early Earth devoid of ocean is incorrect.[1] Scientists have constructed different models to explain the thermal history in the early earth, such as the continental growth model,[72] Icelandic rhyolites,[73] intermediate igneous rocks, mafic igneous rocks, sagduction,[74] impact melt,[75] heat pipe tectonics,[76] terrestrial KREEP[77] and multi-stage scenarios.
The most famous one is continental growth model which is similar to the modern tectonic dynamics.[1]
Relatively low crystallisation temperature and some are enriched in heavy oxygen, contain inclusion similar to modern crustal processes and show evidence of silicate differentiation at ~4.5 Ga.[1] Early terrestrial hydrosphere, early felsic crust in which granitoids were produced and later weathered under high water activity conditions and even the possible existence of plate boundary interactions.[1] [78]
References
[edit]- ^ a b c d e f g h i j k l m n Harrison, T. (2009). The Hadean Crust: Evidence from >4 Ga Zircons. Annual Review of Earth and Planetary Sciences, 37, 479-505.
- ^ a b c Bowring;Williams, Samuel A;Ian S. (1999). "Priscoan (4.00±4.03 Ga) orthogneisses from northwestern Canada". Contrib Mineral Petrol. 134 (1): 3–16. Bibcode:1999CoMP..134....3B. doi:10.1007/s004100050465. S2CID 128376754.
{{cite journal}}
: CS1 maint: multiple names: authors list (link) - ^ Willbold, Mojzsis, Chen, & Elliott. (2015). Tungsten isotope composition of the Acasta Gneiss Complex. Earth and Planetary Science Letters, 419, 168-177.
- ^ a b Roth, Bourdon, Mojzsis, Touboul, Sprung, Guitreau, & Blichert-Toft. (2013). Inherited 142Nd anomalies in Eoarchean protoliths. Earth and Planetary Science Letters, 361, 50-57.
- ^ Harrison, T., Blichert-Toft, J., Mueller, W., Albarede, F., Holden, P., & Mojzsis, S. (2005). "Heterogeneous Hadean hafnium; evidence of continental crust at 4.4 to 4.5 Ga". Science, 310(5756), 1947–1950.
- ^ a b c d Peck, Valley, Wilde, & Graham. (2001). "Oxygen isotope ratios and rare earth elements in 3.3 to 4.4 Ga zircons: Ion microprobe evidence for high δ18O continental crust and oceans in the Early Archean". Geochimica Et Cosmochimica Acta, 65(22), 4215-4229.
- ^ Hiess, Nutman, Bennett, & Holden. (2006). "Ti zircon thermometry applied to metamorphic and igneous systems". Geochimica Et Cosmochimica Acta, 70(18), A250.
- ^ Grimes, C., John, B., Kelemen, P., Mazdab, F., Wooden, J., Cheadle, M., . . . Schwartz, J. (2007). Trace element chemistry of zircons from oceanic crust; a method for distinguishing detrital zircon provenance. Geology (Boulder), 35(7), 643-646.
- ^ Lassiter, Byerly, Snow, & Hellebrand. (2014). Constraints from Os-isotope variations on the origin of Lena Trough abyssal peridotites and implications for the composition and evolution of the depleted upper mantle. Earth and Planetary Science Letters, 403, 178-187.
- ^ Coogan, L., & Hinton, R. (2006). Do the trace element compositions of detrital zircons require Hadean continental crust? Geology (Boulder),34(8), 633-636.
- ^ Martin, Duchêne, Deloule, & Vanderhaeghe. (2006). Oxygen isotopes, REE and U–Pb behaviour during metamorphic zircon formation. Geochimica Et Cosmochimica Acta, 70(18), A394.
- ^ a b Watson, E., & Harrison, T. (2005). Zircon thermometer reveals minimum melting conditions on earliest Earth. Science, 308(5723), 841-844.
- ^ a b Cavosie AJ, Wilde SA, Liu D, Weiblen PW, Valley JW (2004) Internal zoning and U–Th–Pb chemistry of Jack Hills detrital zircons: a mineral record of early Archean to Mesoproterozoic (4348–1576 Ma) magmatism. Precambrian Res 135:251–279
- ^ a b c d Hopkins M, Harrison TM, Manning CE (2008) Low heat flow inferred from > 4 Gyr zircons suggests Hadean plate boundary interactions. Nature 456:493–496
- ^ Holden P, Lanc P, Ireland TR, Harrison TM, Foster JJ, Bruce ZP (2009). "Mass-spectrometric mining of Hadean zircons by automated SHRIMP multi-collector and single-collector U/Pb zircon age dating: The first 100 000 grains". International Journal of Mass Spectrometry 286:53–63
- ^ a b Meinhold, G., Morton, A., Fanning, C., & Whitham, A. (2011). "U–Pb SHRIMP ages of detrital granulite-facies rutiles: Further constraints on provenance of Jurassic sandstones on the Norwegian margin". Geological Magazine, 148(3), 473–480.
- ^ Crowley, Bowring, Shen, Wang, Cao, & Jin. (2006). "U–Pb zircon geochronology of the end-Permian mass extinction". Geochimica Et Cosmochimica Acta, 70(18), A119.
- ^ Iizuka, Tsuyoshi; Yamaguchi, Akira; Haba, Makiko K.; Amelin, Yuri; Holden, Peter; Zink, Sonja; Huyskens, Magdalena H.; Ireland, Trevor R. (January 2015). "Timing of global crustal metamorphism on Vesta as revealed by high-precision U–Pb dating and trace element chemistry of eucrite zircon". Earth and Planetary Science Letters. 409: 182–192. Bibcode:2015E&PSL.409..182I. doi:10.1016/j.epsl.2014.10.055. hdl:1885/22438. S2CID 140575706.
- ^ Bengtson, Ewing, & Becker. (2012). "Corrigendum to 'He diffusion and closure temperatures in apatite and zircon: A density functional theory investigation' [Geochim. Cosmochim. Acta 86 (2012) 228–238]". Geochimica Et Cosmochimica Acta, 98, 202.
- ^ Valley JW, Chiarenzelli JR, McLelland JM (1994). "Oxygen isotope geochemistry of zircon". Earth and Planetary Science Letters 126:187–206
- ^ Trail D, Bindeman IN, Watson EB, Schmitt AK (2009). "Experimental calibration of oxygen isotope fractionation between quartz and zircon". Geochimica ey Cosmochimica Acta 73:7110–7126
- ^ a b Abbott, S., Harrison, T., Schmitt, A., & Mojzsis, S. (2012). "A search for thermal excursions from ancient extraterrestrial impacts using Hadean zircon Ti-U-Th-Pb depth profiles". Proceedings of the National Academy of Sciences of the United States of America, 109(34), 13486–13492.
- ^ a b Valley JW, Kinny PD, Schulze DJ, Spicuzza MJ (1998). "Zircon megacrysts from kimberlite: oxygen isotope variability among mantle melts". Contributions to Mineralogy and Petrology 133:1–11
- ^ a b c Kinny PD, Compston W, Williams IS (1991). "A reconnaissance ion-probe study of hafnium isotopes in zircons". Geochimica et Cosmochimica Acta 55:849–859
- ^ a b c Amelin YV, Lee DC, Halliday, A. N., Pidgeon RT (1999). "Nature of the Earth’s earliest crust from hafnium isotopes in single detrital zircons". Nature 399:252–255
- ^ a b c Blichert-Toft J, Albarède F (2008). "Hafnium isotopes in Jack Hills zircons and the formation of the Hadean crust". Earth and Planetary Science Letters 265:686702
- ^ a b c Turner, W., Heaman, L., & Creaser, R. (2003). "Sm-Nd fluorite dating of Proterozoic low-sulfidation epithermal Au-Ag deposits and U-Pb zircon dating of host rocks at Mallery Lake, Nunavut, Canada". Canadian Journal Of Earth Sciences 40(12), 1789–1804.
- ^ a b c d e f Turner G, Harrison TM, Holland G, Mojzsis SJ, Gilmour J (2004). "Xenon from extinct 244Pu in ancient terrestrial zircons". Science 306:89–91
- ^ a b Tang, Rudnick, Mcdonough, Bose, & Goreva. (2017). "Multi-mode Li diffusion in natural zircons: Evidence for diffusion in the presence of step-function concentration boundaries". Earth and Planetary Science Letters 474, 110–119.
- ^ a b Trail, D., Cherniak, D., Watson, J., Harrison, E., Weiss, B., & Szumila, T. (2016). "Li zoning in zircon as a potential geospeedometer and peak temperature indicator". Contributions to Mineralogy and Petrology 171(3), 1–15.
- ^ a b c d Cimino, R., Rasmussen, & Neimark. (2013). "Communication: Thermodynamic analysis of critical conditions of polymer adsorption". The Journal of Chemical Physics, 139(20), The Journal of Chemical Physics, 28 November 2013, Vol.139(20).
- ^ a b c d e Trail D, Cherniak DJ, Watson EB, Harrison TM, Weiss BP, Szumila I (2016). "Li zoning in zircon as a potential geospeedometer and peak temperature indicator". Contributions to Mineralogy and Petrology 171:1–15
- ^ a b c Bell, Boehnke, & Harrison. (2017). "Corrigendum to 'Applications of biotite inclusion composition to zircon provenance determination' [Earth Planet. Sci. Lett. 473 (2017) 237–246]". Earth and Planetary Science Letters 475, 267.
- ^ a b Hopkins M, Harrison TM, Manning CE (2010). "Constraints on Hadean geodynamics from mineral inclusions in > 4 Ga zircons". Earth and Planetary Science Letters 298:367–376
- ^ a b White RW, Powell RW, Holland TJB (2001). "Calculation of partial melting equilibria in the system Na2O–CaO– K2O–FeO–MgO–Al2O3–SiO2–H2O (NCKFMASH)". Journal of Metamorphic Geology 19:139–153
- ^ a b Rasmussen B, Fletcher IR, Muhling JR, Gregory CJ, Wilde SA (2011). "Metamorphic replacement of mineral inclusions in detrital zircon from Jack Hills Australia: Implications for the Hadean Earth". Geology 39:1143–1146
- ^ a b Trail D, Thomas JB, Watson EB (2011b). "The incorporation of hydroxyl into zircon". American Mineralogist 96:60–67
- ^ a b c d Abdel-Rahman, A. (1996). "Discussion on the Comment on Nature of Biotites in Alkaline, Calc-alkaline and Peraluminous Magmas". 37(5), 1031–1035.
- ^ a b Nutman, A., Mojzsis, S., & Friend, C. (1997). "Recognition of >=3850 Ma water-lain sediments in West Greenland and their significance for the early Archaean Earth". Geochimica Et Cosmochimica Acta, 61(12), 2475-2484.
- ^ a b Rosing, M. (1999). "C-13-depleted carbon microparticles in > 3700-Ma sea-floor sedimentary rocks from west Greenland". Science, 283(5402), 674–676.
- ^ a b c d Cherniak, D. J.; Watson, E. B. (August 2007). "Ti diffusion in zircon". Chemical Geology. 242 (3–4): 470–483. Bibcode:2007ChGeo.242..470C. doi:10.1016/j.chemgeo.2007.05.005.
- ^ a b c d Tailby, N. D.; Walker, A. M.; Berry, A. J.; Hermann, J.; Evans, K. A.; Mavrogenes, J. A.; O'Neill, H. St.C.; Rodina, I. S.; Soldatov, A. V.; Rubatto, D.; Sutton, S. R. (February 2011). "Ti site occupancy in zircon". Geochimica et Cosmochimica Acta. 75 (3): 905–921. Bibcode:2011GeCoA..75..905T. doi:10.1016/j.gca.2010.11.004.
- ^ a b Ferry, J. M.; Watson, E. B. (1 October 2007). "New thermodynamic models and revised calibrations for the Ti-in-zircon and Zr-in-rutile thermometers". Contributions to Mineralogy and Petrology. 154 (4): 429–437. Bibcode:2007CoMP..154..429F. doi:10.1007/s00410-007-0201-0. ISSN 0010-7999. S2CID 129429412.
- ^ a b Hopkins, M., Harrison, T., & Manning, C. (2012). "Metamorphic replacement of mineral inclusions in detrital zircon from Jack Hills, Australia; implications for the Hadean Earth; discussion". Geology (Boulder), 40(12), E281-e281.
- ^ a b c d Alahakoon, Burrows, Howes, Karunaratne, Smith, & Dobedoe. (2010). "Fully densified zircon co-doped with iron and aluminium prepared by sol–gel processing". Journal of the European Ceramic Society, 30(12), 2515–2523.
- ^ Trail D, Tailby, N, Wang Y, Harrison TM, Boehnke P (2016). "Al in zircon as evidence for peraluminous melts and recycling of pelites from the Hadean to modern times". Geochemistry, Geophysics, Geosystems
- ^ a b Marty B, Alexander CMD, Raymond SN (2013) l. "Primordial origins of Earth's carbon". Reviews in Mineralogy and Geochemistry 75:149–181
- ^ a b Dasgupta R (2013). "Ingassing storage and outgassing of terrestrial carbon through geologic time". Reviews in Mineralogy and Geochemistry 75:183–229
- ^ Clement, C.F; Harrison, R.G (July 1992). "The charging of radioactive aerosols". Journal of Aerosol Science. 23 (5): 481–504. Bibcode:1992JAerS..23..481C. doi:10.1016/0021-8502(92)90019-R.
- ^ Gebauer, Dieter; Williams, Ian S.; Compston, William; Grünenfelder, Marc (January 1989). "The development of the Central European continental crust since the Early Archaean based on conventional and ion-microprobe dating of up to 3.84 b.y. old detrital zircons". Tectonophysics. 157 (1–3): 81–96. Bibcode:1989Tectp.157...81G. doi:10.1016/0040-1951(89)90342-9.
- ^ a b Schulze, Daniel J.; Harte, Ben; Valley, John W.; Brenan, James M.; Channer, Dominic M. De R. (1 May 2003). "Extreme crustal oxygen isotope signatures preserved in coesite in diamond". Nature. 423 (6935): 68–70. Bibcode:2003Natur.423...68S. doi:10.1038/nature01615. PMID 12721625. S2CID 4413573.
- ^ Hawkesworth, Chris; Kemp, Tony (August 2006). "A zircon perspective on the evolution of the continental crust: Insights from combined Hf and O isotopes". Geochimica et Cosmochimica Acta. 70 (18): A236. Bibcode:2006GeCAS..70Q.236H. doi:10.1016/j.gca.2006.06.476.
- ^ Taylor, D. J.; McKeegan, K. D.; Harrison, T. M.; Young, E. D. (1 June 2009). "Early differentiation of the lunar magma ocean . New Lu-Hf isotope results from Apollo 17". Geochimica et Cosmochimica Acta Supplement. 73: A1317. Bibcode:2009GeCAS..73R1317T. ISSN 0046-564X.
- ^ Valley, John W.; Cavosie, Aaron J.; Ushikubo, Takayuki; Reinhard, David A.; Lawrence, Daniel F.; Larson, David J.; Clifton, Peter H.; Kelly, Thomas F.; Wilde, Simon A.; Moser, Desmond E.; Spicuzza, Michael J. (23 February 2014). "Hadean age for a post-magma-ocean zircon confirmed by atom-probe tomography". Nature Geoscience. 7 (3): 219–223. Bibcode:2014NatGe...7..219V. doi:10.1038/ngeo2075.
- ^ a b Valery K Brel; Namig S. Pirkuliev; Nikolai S. Zefirov (2001). "Chemistry of xenon derivatives. Synthesis and chemical properties". Russian Chemical Reviews. 70 (3): 231–264. Bibcode:2001RuCRv..70..231B. doi:10.1070/RC2001v070n03ABEH000626. ISSN 0036-021X. S2CID 250883131.
- ^ Maas, Kinny, Williams, Froude, & Compston. (1992). The Earth's oldest known crust: A geochronological and geochemical study of 3900–4200 Ma old detrital zircons from Mt. Narryer and Jack Hills, Western Australia. Geochimica Et Cosmochimica Acta, 56(3), 1281-1300.
- ^ Pidgeon, & Nemchin. (2006). Comparative age distributions and internal structures of Archaean zircons from quartzites from Mt Narryer and the Jack Hills, Western Australia. Geochimica Et Cosmochimica Acta, 70(18), A493.
- ^ Nelson, Robinson, & Myers. (2000). Complex geological histories extending for ≥4.0 Ga deciphered from xenocryst zircon microstructures. Earth and Planetary Science Letters, 181(1), 89-102.
- ^ Wyche S (2007) Evidence of Pre-3100 Ma Crust in the Youanmi and South West Terranes, and Eastern Goldfields Superterrane, of the Yilgarn Craton. Dev Precambrian Geol 15:113–123
- ^ Thern, & Nelson. (2012). Detrital zircon age structure within ca. 3Ga metasedimentary rocks, Yilgarn Craton: Elucidation of Hadean source terranes by principal component analysis. Precambrian Research,214-215, 28-43.
- ^ Bowring SA, Williams IS (1999) Priscoan (4.00–4.03 Ga) orthogneisses from northwestern Canada. Contrib Mineral Petrol 134:3–16
- ^ Stern RA, Bleeker W (1998) Age of the world’s oldest rocks refined using Canada’s SHRIMP the Acasta gneiss complex Northwest Territories Canada. Geosci Canada 25:27–31
- ^ Mojzsis SJ, Cates NL, Caro G, Trail D, Abramov O, Guitreau M, Blichert-Toft J, Hopkins MD, Bleeker W (2014) Component geochronology in the polyphase ca. 3920 Ma Acasta Gneiss. Geochim Cosmochim Acta 133:68–96
- ^ Mojzsis, S., & Harrison, T. (2002). Origin and significance of Archean quartzose rocks at Akilia, Greenland. Science, 298(5595), 917.
- ^ Wilke, Schmidt, Dubrail, Appel, Borchert, Kvashnina, & Manning. (2012). Zircon solubility and zirconium complexation in H2O Na2O SiO2±Al2O3 fluids at high pressure and temperature. Earth and Planetary Science Letters, 349-350, 15-25.
- ^ Fei, Guangchun, Zhou, Xiong, Duo, Ji, Zhou, Yu, Wen, Chun-Qi, Wen, Quan, . . . Liu, Hongfei. (2015). Zircon U-Pb age and geochemical characteristics of ore-bearing granodiorite porphyry in the Duobuza porphyry copper deposit, Tibet. Journal of the Geological Society of India, 86(2), 223-232.
- ^ Diwu Chunrong, Sun Yong, Wang Hongliang, & Dong Zhengchan. (2010). A mineral record of 4.0 Ga metamorphism; evidence of metamorphic zircon xenocryst from western north Qinling orogenic belt. Geochimica Et Cosmochimica Acta, 74(12), A237-A237.
- ^ Cui, Pei-Long, Sun, Jing-Gui, Sha, De-Ming, Wang, Xi-Jing, Zhang, Peng, Gu, A-Lei, & Wang, Zhong-Yu. (2013). Oldest zircon xenocryst (4.17 Ga) from the North China Craton. International Geology Review,55(15), 1902-1908.
- ^ Harrison TM, Schmitt AK (2007) High sensitivity mapping of Ti distributions in Hadean zircons. Earth Planet Sci Lett 261:9–19
- ^ Nadeau S, Chen W, Reece J, Lachhman D, Ault R, Faraco MTL, Fraga LM, Reis NJ, Betiollo LM (2013) Guyana: the Lost Hadean crust of South America? Braz J Geol 43:601–606
- ^ Paquette JL, Barbosa JSF, Rohais S, Cruz SC, Goncalves P, Peucat JJ, Leal ABM, Santos-Pinto M, Martin H (2015) The geological roots of South America: 4.1 Ga and 3.7 Ga zircon crystals discovered in NE Brazil and NW Argentina. Precambrian Res 271:49–55
- ^ Sohma, T. (1999). Study of the Indian Shield: A Tectonic Model of Continental Growth. Gondwana Research, 2(2), 311-312.
- ^ Haraldur Sigurdsson. (1977). Generation of Icelandic rhyolites by melting of plagiogranites in the oceanic layer. Nature, 269(5623), 25-28.
- ^ François, Philippot, Rey, & Rubatto. (2014). Burial and exhumation during Archean sagduction in the East Pilbara Granite-Greenstone Terrane. Earth and Planetary Science Letters, 396, 235-251.
- ^ Plescia, J., & Cintala, M. (2012). Impact melt in small lunar highland craters. Journal of Geophysical Research: Planets, 117(E12), N/a.
- ^ Moore, W., & Webb, A. (2013). Heat-pipe Earth. Nature, 501(7468), 501-5.
- ^ Longhi, & Auwera. (1993). The monzonorite-anorthosite connection: The petrogenesis of terrestrial KREEP. Lunar and Planetary Inst., Twenty-Fourth Lunar and Planetary Science Conference. Part 2: G-M, 897-898.
- ^ These last two sentences make no sense. Please edit accordingly.