D3 Manual - Sep 09, 2019
D3 Manual - Sep 09, 2019
D3 Manual - Sep 09, 2019
DESIGN MANUAL - D3
WATER QUALITY AND TREATMENT
PREPARED BY:
NATIONAL WATER SUPPLY & DRAINAGE BOARD
Galle Road, Ratmalana
July 2018
Table of Contents
Volume I – Water Quality & Treatment (Water quality, Unit treatment processes, Planning of
plant design and layout and Operation and maintenance documentation)
Volume I
Preface 1-17
Abbreviations 1-21
1. INTRODUCTION 1-24
1.1. Objective and Scope .......................................................................................................... 1-24
1.2. Water Safety Plan (WSP) .................................................................................................. 1-24
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3.1.4. Biological Analysis ................................................................................................ 3-3
3.1.5. Bacteriological Analysis......................................................................................... 3-3
3.1.6. Reservoirs and source water monitoring ................................................................ 3-4
3.1.7. Filter Media Performance Determination ............................................................... 3-4
3.1.8. Water Treatment Chemicals ................................................................................... 3-4
3.2. Sampling Procedures for Chemical And Physical Analysis ............................................... 3-4
3.2.1. Grab Sampling........................................................................................................ 3-4
3.2.2. Composite Sampling .............................................................................................. 3-5
3.2.3. Stream, River or Lake Water Sampling ................................................................. 3-5
3.2.4. Dug Well, Tube Well and Well With Hand Pump and Other Devices .................. 3-6
3.2.5. Type of Container, Method of Preservation and Maximum Holding Time ........... 3-6
3.2.6. Sampling Procedure for Bacteriological Analysis.................................................. 3-8
3.3. Testing Methods of Water Quality Parameters ................................................................... 3-8
3.3.1. Testing of Petroleum Product / Petrochemical ..................................................... 3-11
3.3.2. Testing of Pesticide Water.................................................................................... 3-11
3.4. Interpretation of Test Results ............................................................................................ 3-11
3.4.1. Interpretation of Physical results .......................................................................... 3-11
3.4.2. Chemical Analysis ................................................................................................ 3-12
3.5. Interpretation of Microbial Water Quality ........................................................................ 3-17
3.5.1. New Techniques for Bacteriological Test ............................................................ 3-17
3.5.2. Membrane Filtration Test ..................................................................................... 3-17
3.5.3. Presence- absence coliform test............................................................................ 3-18
3.5.4. Most Probable Number (MPN) ............................................................................ 3-18
3.5.5. Automated microbiology Detection system ......................................................... 3-19
3.5.6. Examination of Correctness of Analyses.............................................................. 3-19
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4.5.3. Source Protection ................................................................................................. 4-25
4.5.4. Intake Protection for Direct River Abstraction Works ......................................... 4-25
4.5.5. Reservoir Management ......................................................................................... 4-26
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5.7.8. Dissolved Air Flotation (DAF) Clarifiers............................................................. 5-80
5.7.9. Quantity of Sludge Produced................................................................................ 5-85
5.8. Filtration ............................................................................................................................ 5-86
5.8.1. Introduction to Filtration ...................................................................................... 5-86
5.8.2. Types of Filters ..................................................................................................... 5-86
5.8.3. Removal of Microorganisms by Granular Bed Filtration ..................................... 5-87
5.8.4. Filtration mechanisms .......................................................................................... 5-88
5.8.5. Filterability Test ................................................................................................... 5-90
5.9. Rapid Sand Filters ............................................................................................................. 5-91
5.9.1. Conventional Design ............................................................................................ 5-92
5.9.2. Filter Arrangements .............................................................................................. 5-94
5.9.3. Underdrain and Support Gravel............................................................................ 5-96
5.9.4. Backwash Water Trough .................................................................................... 5-101
5.9.5. Multiple and Coarse Media Filters ..................................................................... 5-102
5.9.6. Rate Control Systems for Gravity Filters ........................................................... 5-104
5.9.7. Constant Rate Filtration...................................................................................... 5-104
5.9.8. Declining Rates Filters ....................................................................................... 5-106
5.9.9. Common Elements of Filter Control Systems .................................................... 5-108
5.9.10. Up Flow Filtration .............................................................................................. 5-109
5.9.11. Direct Filtration .................................................................................................. 5-110
5.9.12. Filter Cleaning or Backwashing of Rapid Filters ............................................... 5-111
5.9.13. Filter Operation and Maintenance ...................................................................... 5-123
5.9.14. Backwash Water Recovery................................................................................. 5-126
5.9.15. Upgrading Existing Filters ................................................................................. 5-127
5.9.16. Dolomite Filter Systems ..................................................................................... 5-129
5.10. Pressure Filters ................................................................................................................ 5-129
5.10.1. Description of Pressure Filters ........................................................................... 5-129
5.10.2. Comparison of Pressure and Gravity Filtration .................................................. 5-130
5.10.3. Operation of Pressure Filters .............................................................................. 5-131
5.10.4. Rate Control for Pressure Filters ........................................................................ 5-132
5.10.5. Applications of Pressure Filters.......................................................................... 5-132
5.11. Precoat / Diatomaceous Earth Filtration ......................................................................... 5-132
5.11.1. Applications and Performance ........................................................................... 5-134
5.11.2. Diatomaceous Earth Filter Operation ................................................................. 5-135
5.11.3. Diatomaceous Earth Filter Design...................................................................... 5-135
5.11.4. Filter Media ........................................................................................................ 5-136
5.11.5. Filter Operation .................................................................................................. 5-136
5.12. Slow Sand Filtration ........................................................................................................ 5-137
5.12.1. Introduction to Slow Sand Filter ........................................................................ 5-137
5.12.2. Filtration Mechanism ......................................................................................... 5-138
5.12.3. Source Water Quality Consideration .................................................................. 5-139
5.12.4. Features of Slow Sand Filter .............................................................................. 5-140
5.12.5. Design of Slow Sand Filter................................................................................. 5-141
5.12.6. Pre-treatment Methods ....................................................................................... 5-145
5.12.7. Construction of the Clear-Water Tank ............................................................... 5-146
5.12.8. Operation & Maintenance of Slow Sand Filter .................................................. 5-146
5.12.9. Control of Slow Sand Filter................................................................................ 5-152
5.12.10. Monitoring & Evaluation of Slow Sand Filter ............................................... 5-153
5.13. Roughing Filtration ......................................................................................................... 5-153
5.13.1. Introduction to Roughing Filter .......................................................................... 5-153
5.13.2. Mechanism of Roughing Filters ......................................................................... 5-154
5.13.3. Features of Roughing Filter ................................................................................ 5-155
5.13.4. Vertical-flow Roughing Filters........................................................................... 5-155
5.13.5. Horizontal-flow Roughing Filters ...................................................................... 5-157
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5.13.6. Design of Roughing Filter .................................................................................. 5-159
5.13.7. Operation & Maintenance of Roughing Filter .................................................... 5-162
5.13.8. Factors Affecting Roughing Filter Performance ................................................ 5-165
5.13.9. Monitoring / Evaluation of Roughing Filter ....................................................... 5-165
5.14. Sludge Treatment ............................................................................................................ 5-166
5.14.1. Introduction ........................................................................................................ 5-166
5.14.2. Unit operations and Processes ............................................................................ 5-168
5.14.3. Sources and Characteristics of Residuals ........................................................... 5-170
5.14.4. Design Considerations and Criteria .................................................................... 5-179
5.14.5. Sludge Thickening .............................................................................................. 5-180
5.14.6. Sludge Dewatering ............................................................................................. 5-184
5.14.7. Sludge Lagoons .................................................................................................. 5-184
5.14.8. Sludge Drying Beds............................................................................................ 5-187
5.14.9. Belt Filter Press (BFP) ....................................................................................... 5-190
5.14.10. Plate and Frame Filter Press ........................................................................... 5-191
5.14.11. Mechanical Sludge Dewatering...................................................................... 5-192
5.14.12. Recirculation of Backwash Water .................................................................. 5-193
5.14.13. Ultimate Disposal and Utilization of Solids ................................................... 5-194
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6.4.7. Disinfection of Pipelines and Structures .............................................................. 6-37
6.5. Gas Chlorination ............................................................................................................... 6-38
6.5.1. Chlorine Gas Supply ............................................................................................ 6-39
6.5.2. Chlorine Storage and Handling ............................................................................ 6-39
6.5.3. Safety Consideration ............................................................................................ 6-39
6.5.4. Absorption of Chlorine Gas Streams .................................................................... 6-40
6.5.5. Gas Feed and Applications ................................................................................... 6-41
6.5.6. Diffusion, Mixing and Contact ............................................................................. 6-44
6.5.7. Control system ...................................................................................................... 6-45
6.5.8. Design Consideration ........................................................................................... 6-45
6.6. Chloramines ...................................................................................................................... 6-48
6.6.1. Monochloramine .................................................................................................. 6-48
6.6.2. Chloramination Equipment .................................................................................. 6-49
6.7. Chlorine Dioxide ............................................................................................................... 6-49
6.7.1. Mode of Action .................................................................................................... 6-49
6.7.2. Disinfection Performance of Chlorine Dioxide .................................................... 6-49
6.8. Ozone Disinfection............................................................................................................ 6-50
6.8.1. Primary Uses and Points of Application of Ozone ............................................... 6-50
6.8.2. Ozone Disinfection Equipment ............................................................................ 6-51
6.9. Ultra-Violet Disinfection (UV) ......................................................................................... 6-52
6.9.1. UV Disinfection Requirements ............................................................................ 6-53
6.9.2. Ultraviolet Disinfection Equipment ..................................................................... 6-53
6.10. Disinfectants and Disinfectant By-Products...................................................................... 6-54
6.10.1. Chlorine and its by-products ................................................................................ 6-54
6.10.2. Chloramine and its by-products............................................................................ 6-57
6.10.3. Chlorine Dioxide and Its By-Products ................................................................. 6-57
6.10.4. Ozone and Its By-Products ................................................................................... 6-57
6.10.5. Measures to Reduce Disinfection By-products in Drinking Water ...................... 6-58
6.10.6. Balancing Chemical and Microbial Risks ............................................................ 6-58
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7.6.7. Membrane Module Configurations ...................................................................... 7-23
7.6.8. Membrane Properties ........................................................................................... 7-24
7.6.9. Particle Capture in Membrane Filtration .............................................................. 7-25
7.6.10. Membrane Integrity Testing ................................................................................. 7-26
7.6.11. Pretreatment Facilities in MF and UF Systems .................................................... 7-26
7.6.12. Comparison Between Membrane Filtration and Rapid Sand Filters .................... 7-27
7.6.13. Process Design Considerations............................................................................. 7-27
7.6.14. Sample Calculations ............................................................................................. 7-27
7.7. High Pressure Membrane Technology .............................................................................. 7-29
7.7.1. Introduction to Reverse Osmosis Technology...................................................... 7-29
7.7.2. Osmotic Pressure .................................................................................................. 7-29
7.7.3. Applications of RO ............................................................................................... 7-29
7.7.4. Mechanisms of Solute Rejections ........................................................................ 7-30
7.7.5. Governing Equations in RO ................................................................................. 7-30
7.7.6. Membrane Materials, Structure and Elements ..................................................... 7-33
7.7.7. Concentration Polarization ................................................................................... 7-34
7.7.8. RO Process Description........................................................................................ 7-36
7.7.9. Membrane Fouling ............................................................................................... 7-36
7.7.10. Tests for Particulate Fouling ................................................................................ 7-37
7.7.11. Pretreatment and Post Treatment.......................................................................... 7-40
7.7.12. Energy Recovery of RO Plants............................................................................. 7-41
7.7.13. Site Selection of Seawater Open Intake ............................................................... 7-41
7.7.14. Computer Aided RO System Design .................................................................... 7-42
7.7.15. Disposal of Brine or Concentrate ......................................................................... 7-42
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9.3.2. Linear Layout ......................................................................................................... 9-9
9.3.3. Campus Layout....................................................................................................... 9-9
9.3.4. Compact Layout ................................................................................................... 9-10
9.4. Factors Affecting Plant Layout ......................................................................................... 9-12
9.4.1. Redundancy .......................................................................................................... 9-13
9.4.2. Flexibility of Operations....................................................................................... 9-13
9.4.3. Convenience of Routine Operations ..................................................................... 9-13
9.4.4. Access for Equipment Maintenance ..................................................................... 9-13
9.4.5. Noise Control ....................................................................................................... 9-14
9.4.6. Internal Roads and Parking .................................................................................. 9-14
9.4.7. Chemical Delivery ................................................................................................ 9-14
9.4.8. Plant Visitors ........................................................................................................ 9-14
9.4.9. Site Security ......................................................................................................... 9-14
9.5. Technical Issues to Consider in Plant Arrangement.......................................................... 9-15
9.5.1. Hydraulic Profile .................................................................................................. 9-15
9.5.2. Conveyance of Water between Process Units ...................................................... 9-16
9.5.3. Application Points for Chemicals ......................................................................... 9-16
9.5.4. Separation of Filtered Water and Unfiltered Water.............................................. 9-16
9.5.5. Finished Water Storage ........................................................................................ 9-16
9.5.6. Source Water Storage ........................................................................................... 9-17
9.5.7. Lagoons ................................................................................................................ 9-17
9.5.8. Locating Hazardous Chemicals ............................................................................ 9-17
9.6. Provision for Future Changes in Plant Design .................................................................. 9-17
9.6.1. Capacity Expansion .............................................................................................. 9-17
9.6.2. Future Process Additions...................................................................................... 9-18
9.7. Support Facilities to be Considered in Plant Design ......................................................... 9-18
9.7.1. Maintenance Facilities .......................................................................................... 9-19
9.7.2. Laboratory Facilities............................................................................................. 9-19
9.8. Instrumentation and Control.............................................................................................. 9-22
9.8.1. Measuring Instruments ......................................................................................... 9-22
9.8.2. Control Arrangement ............................................................................................ 9-22
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Annex-D.1: Design Example – Hydraulic Flocculator
Annex-G: Practical Guide for Dosage of Bleaching Power in Disinfection of Public Drinking
Water Supplies
Glossary 95
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List of Figures
Figure 2-1: Transparency measurement using Secchi Disk ......................................................... 2-27
Figure 2-2: Mortality Ratios for variety of pathogens .................................................................. 2-33
Figure 2-3: Median dose of organisms required in drinking wter to cause infection ................ 2-34
Figure 2-4: The Coliform Members ............................................................................................... 2-35
Figure 2-5:Invertabrate animal life ................................................................................................ 2-36
Figure 3-1: Sample Collection ........................................................................................................... 3-6
Figure 3-2: Balis graph .................................................................................................................... 3-12
Figure 3-3: Coliform & E-coil ......................................................................................................... 3-18
Figure 3-4: Presence – absence coliform test ................................................................................. 3-18
Figure 3-5:Most Probable Number ................................................................................................ 3-19
Figure 4-1: Flow Diagram Showing Possible Treatment Stages .................................................. 4-11
Figure 4-2: Approximate Operational Ranges for Treatment Processes .................................... 4-13
Figure 4-3: Treatment of Groundwater Sources for Various Water Qualities .......................... 4-14
Figure 4-4: Treatment of Surface Water Sources for Various Water Qualities ........................ 4-15
Figure 4-5: Treatment train of brackish or sea water for various water qualities .................... 4-16
Figure 4-6: Velocity cap and T Screen ........................................................................................... 4-26
Figure 5-1: Some designs for floating booms ................................................................................... 5-3
Figure 5-2: Floating booms at Ambathale intake for debris and oil control ................................ 5-3
Figure 5-3: Low and High tide level in Colombo during a week ................................................... 5-4
Figure 5-4: Different scenarios of tide formation ............................................................................ 5-4
Figure 5-5: Salinity barrier using Sand bag at Ambathale ............................................................ 5-5
Figure 5-6: Control of algae by ultra sound waves ......................................................................... 5-6
Figure 5-7: The “LG Sonic e-line” for control algae up to 200 meter ........................................... 5-7
Figure 5-8: “MPC Buoy” Solar powered algae control with online water quality monitoring
(Range 500m) ................................................................................................................ 5-7
Figure 5-9: Intake structure with screens and weir ........................................................................ 5-8
Figure 5-10: Scour protection in the intake structure .................................................................... 5-8
Figure 5-11: Front view of Coarse and Fine Screens .................................................................... 5-11
Figure 5-12: Schematic of a Travelling Band Screen and Drum screen ..................................... 5-11
Figure 5-13: Cross sectional view of Microstrainer ...................................................................... 5-12
Figure 5-14: Multiple Cascade weir/step aerator .......................................................................... 5-22
Figure 5-15: Multiple Cascade Platform Aerator ......................................................................... 5-22
Figure 5-16: Multiple Trays Aerator .............................................................................................. 5-23
Figure 5-17: Typical cone tray aerator ......................................................................................... 5-23
Figure 5-18: Packed Tower Aerator - Source: Letterman (1999) ................................................ 5-24
Figure 5-19: Spray aerator .............................................................................................................. 5-25
Figure 5-20: Plate Aerator (Inka System) ...................................................................................... 5-26
Figure 5-21: Flow-through low profile aeration system ............................................................... 5-27
Figure 5-22: Venturi Aerator .......................................................................................................... 5-27
Figure 5-23: Pressure Aerator ........................................................................................................ 5-28
Figure 5-24 Design alternatives for a deep-well aerator ............................................................... 5-29
Figure 5-25: Mechanical Aerators .................................................................................................. 5-29
Figure 5-26: Efficiency of Aeration ................................................................................................ 5-30
Figure 5-27: Efficiency Coefficient Vs. Height of Weir ................................................................ 5-31
Figure 5-28: Iso‐Electric Point (IEP) of colloidal particle ............................................................ 5-34
Figure 5-29: Formation of Double Layer ....................................................................................... 5-35
Figure 5-30: Stability of colloidal particles .................................................................................... 5-35
Figure 5-31: Effect Of Ionic Strength On The Interaction Energy ............................................. 5-36
Figure 5-32: Weir for Rapid mix .................................................................................................... 5-47
Figure 5-33: Parshall flume rapid mixer........................................................................................ 5-47
Figure 5-34: Baffle System .............................................................................................................. 5-48
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Figure 5-35: Turbine Mixer ............................................................................................................ 5-49
Figure 5-36: Types of Impellers ...................................................................................................... 5-50
Figure 5-37: Section of Static Mixer ............................................................................................... 5-51
Figure 5-38: Inline Mechanical Mixer ............................................................................................ 5-51
Figure 5-39: Nozzle inside the Pipe (Section through Pump Mixer) ........................................... 5-52
Figure 5-40: Section through over-and-under baffled flocculation chamber ............................. 5-54
Figure 5-41: Plan of round - the end baffled flocculation basin .................................................. 5-54
Figure 5-42: Vertical Shaft Impeller Flocculator .......................................................................... 5-56
Figure 5-43: Section of Flocculator with Horizontal Shaft Paddles ............................................ 5-57
Figure 5-44: Vertical Shaft Paddle Flocculator ............................................................................. 5-58
Figure 5-45: Paths traced by discrete particles in a horizontal flow settling basin .................... 5-60
Figure 5-46: Settling column and iso-percentage settling curves for flocculent particles ......... 5-61
Figure 5-47: Horizontal Flow Rectangular Sedimentation Basin ................................................ 5-62
Figure 5-48: Mechanical sludge removal systems used in rectangular basins............................ 5-65
Figure 5-49: Radial-flow basin with rotating half-bridge scraper............................................... 5-66
Figure 5-50: Circular Mechanically Scraped Sedimentation Basin ............................................ 5-66
Figure 5-51: Flocculation-Clarifiers (Degrement)......................................................................... 5-67
Figure 5-52: Pyramid-type Sludge Blanket Clarifier .................................................................... 5-68
Figure 5-53: Sludge Recirculation Type (solid contact clarifier system) .................................... 5-70
Figure 5-54: Pulsator Clarifier (Degrement) ................................................................................. 5-71
Figure 5-55: Typical Forms of Plate Settlers ................................................................................. 5-74
Figure 5-56: Various forms of tube modules ................................................................................. 5-74
Figure 5-57: Typical Forms of Plate Settlers Arrangements........................................................ 5-74
Figure 5-58: Tube settlers in horizontal flow sedimentation basin .............................................. 5-76
Figure 5-59: Tube Settlers in Vertical Flow Clarifier ................................................................... 5-77
Figure 5-60: Conventional Water Treatment Plant at Thanthirimaley (R&D, RSC-NW) ....... 5-78
Figure 5-61: The SETA plant at Ambathale .................................................................................. 5-79
Figure 5-62: The lamella settler consists of specially fabricated lamella modules inside the
settling area (SUPER PULSATOR).......................................................................... 5-79
Figure 5-63: Sludge collectors inside the Lamella settler tank (SUPER PULSATOR) ............. 5-79
Figure 5-64: Process Schematic Diagram for a DAF .................................................................... 5-81
Figure 5-65: Generic DAF Process Flow Diagram ........................................................................ 5-81
Figure 5-66: Schematic diagram illustrating straining, flocculation, and sedimentation
actions in granular media filters ............................................................................... 5-86
Figure 5-67: Typical Filter Pore and Giardia cysts....................................................................... 5-89
Figure 5-68: Transport of impurities towards the grain .............................................................. 5-89
Figure 5-69: Particle Removal Efficiency in a granular filter ...................................................... 5-90
Figure 5-70: Filterability Test ......................................................................................................... 5-91
Figure 5-71: Typical filter configurations ...................................................................................... 5-94
Figure 5-72: Details of Manifold and Laterals .................................................................................. 5-97
Figure 5-73: Pipe lateral underdrain with nozzles ........................................................................ 5-97
Figure 5-74: Fabricated Block Underdrains with IMS cap .......................................................... 5-98
Figure 5-75: Forms of False-Bottom Underdrains ........................................................................ 5-99
Figure 5-76: Type of Filter Nozzles and their Installations ........................................................ 5-100
Figure 5-77: A central backwash water trough ........................................................................... 5-102
Figure 5-78: Schematic plant diagrams for the most common control systems for gravity
filters, showing typical control elements................................................................. 5-105
Figure 5-79: Declining Rates Filters ............................................................................................. 5-107
Figure 5-80: Details of up-flow filter ............................................................................................ 5-110
Figure 5-81: Low Pressure / Self-Backwashing filter.................................................................. 5-115
Figure 5-82: Typical surface agitator and arrangements ........................................................... 5-118
Figure 5-83: Head loss versus superficial velocity ....................................................................... 5-121
Figure 5-84: Characteristics of initial effluent quality ................................................................ 5-124
Figure 5-85: Sample Head loss Gauge .......................................................................................... 5-129
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Figure 5-86: Vertical-type pressure sand filters .......................................................................... 5-130
Figure 5-87: Horizontal-type pressure sand filter ....................................................................... 5-131
Figure 5-88: Precoat filtration ...................................................................................................... 5-133
Figure 5-89: Construction details of a flat-leaf element ............................................................. 5-136
Figure 5-90: Typical slow sand filter biota at different depths .................................................. 5-139
Figure 5-91: Features of a Slow Sand Filter ................................................................................ 5-141
Figure 5-92: Inlet and Outlet structures of Slow Sand Filter..................................................... 5-144
Figure 5-93: Alternative underdrain and filter support arrangements .................................... 5-145
Figure 5-94: Continuous Sand Washing ...................................................................................... 5-148
Figure 5-95: Washing Platfom for Manual Cleaning of Sand.................................................... 5-148
Figure 5-96: Mechanized In-Situ Sand Washing ............................................................................. 5-149
Figure 5-97: Recommended Resanding Procedure (AWWA, 1991).......................................... 5-151
Figure 5-98: Types flow control of slow sand filter ..................................................................... 5-152
Figure 5-99: Mechanism of roughening filter .............................................................................. 5-155
Figure 5-100: Diagram of up flow and down flow roughing filters. .......................................... 5-156
Figure 5-101: Diagram of Horizontal Flow Roughing Filter...................................................... 5-158
Figure 5-102: Arrangement of Horizontal Flow Roughening Filter.......................................... 5-160
Figure 5-103: Components of Roughing Filters .......................................................................... 5-161
Figure 5-104: Effect of Operation on Size of Filters ................................................................... 5-163
Figure 5-105: Typical Gravel and Sieving Installation ............................................................... 5-164
Figure 5-106: Water Sampling Point in Roughing Filtration .................................................... 5-166
Figure 5-107: Backwash Water Recovery Tank.......................................................................... 5-178
Figure 5-108: View of Back wash recovery Tanks and Backwash recirculation Tank and
Inside view (Biyagama WTP) .................................................................................. 5-178
Figure 5-109: Interface heights ..................................................................................................... 5-181
Figure 5-110: Illustration of interfaces during settling test ........................................................ 5-181
Figure 5-111: Graph to select the required area according to Talmage and Fitch procedure 5-182
Figure 5-112: Sludge Thickener .................................................................................................... 5-183
Figure 5-113: Sludge drying processes ......................................................................................... 5-186
Figure 5-114: Sand Drying Bed..................................................................................................... 5-188
Figure 5-115: Belt Filter Press (BFP) ........................................................................................... 5-190
Figure 5-116: Plate and Frame Filter Press ................................................................................. 5-191
Figure 5-117: Centrifuging ............................................................................................................ 5-193
Figure 5-118: Process flow diagram for sludge management in water treatment plant.......... 5-198
Figure 6-1: Alum dosing Arrangements........................................................................................... 6-5
Figure 6-2: Schematic diagram of a system for preparing lime slurry from quick lime ............. 6-7
Figure 6-3: Schematic diagram of Lime turbine saturator ............................................................ 6-9
Figure 6-4: Image of Lime turbine saturator in Ambathale WTP .............................................. 6-10
Figure 6-5: Dry feed system with dissolving tank ......................................................................... 6-13
Figure 6-6: Dry feed system for PAC (Source: Konduwatuwana) .............................................. 6-15
Figure 6-7: Poor baffling arrangements in contact tank .............................................................. 6-23
Figure 6-8: Average baffling arrangements in contact tank ........................................................ 6-24
Figure 6-9: Superior baffling arrangements in contact tank ....................................................... 6-24
Figure 6-10: pH and temperature dependency of HOCl ↔ OCl– equilibrium........................... 6-30
Figure 6-11: Reactions of Chlorine in Water ................................................................................. 6-33
Figure 6-12: Typical Hypochlorite Feed Systems .......................................................................... 6-35
Figure 6-13: Typical Bleaching Powder Solution Dosing System ................................................ 6-36
Figure 6-14: Typical Installation of Gas Chlorination (Gravity & Pumping) ............................ 6-41
Figure 6-15: Typical Chlorine Diffusors ........................................................................................ 6-44
Figure 6-16: Different Types of Mixing Arrangements for Chlorine dispersion ....................... 6-45
Figure 6-17: Sophisticated Gas Chlorine Feed Systems ............................................................... 6-47
Figure 6-18: Simplified Ozone Feed System Schematic................................................................ 6-52
Figure 6-19: Stainless Steel UV Disinfection Chambers ............................................................... 6-53
Figure 6-20: Risks and benefits of water chlorination (Morris, 1978) ........................................ 6-59
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Figure 7-1: Filtration Media.............................................................................................................. 7-6
Figure 7-2: Field of activity of Fe and Mn oxidizing bacteria in a pH-Eh diagram
(Mouchet,1992) ............................................................................................................. 7-7
Figure 7-3: Schematic diagram of separation process through a semipermeable membrane .. 7-16
Figure 7-4: Particle rejection (approximate) in different membrane process (Crittenden J.C.
et. al., 2012) ................................................................................................................. 7-17
Figure 7-5: Transmembrane pressure development during membrane filtration (Crittenden
J.C. et. al., 2012).......................................................................................................... 7-22
Figure 7-6: Schematic diagram of cross flow filtration ................................................................ 7-23
Figure 7-7: Schematic diagram of dead end filtration .................................................................. 7-23
Figure 7-8: Pressure vessel configuration (Crittenden J.C. et. al., 2012) .................................... 7-24
Figure 7-9: Submerged configuration (Crittenden J.C. et. al., 2012) .......................................... 7-24
Figure 7-10: Osmosis verses reverse osmosis ................................................................................. 7-29
Figure 7-11: Sketch of a Composite Membrane ............................................................................ 7-33
Figure 7-12: Typical hollow fiber membrane module (US AID, 1980) ....................................... 7-33
Figure 7-13: Sketch of a spiral wound RO membrane element (Source: U.S. AID, 1980) ........ 7-34
Figure 7-14: Schematic of concentration polarization .................................................................. 7-34
Figure 7-15: Schematic diagram of vessel and stage arrangement .............................................. 7-36
Figure 7-16: Calculation of tgα from the t/V versus V curve (Alhadidi et al., 2011) .................. 7-38
Figure 7-17: Fouling Index Curve (Alhadidi et al., 2011) ............................................................. 7-38
Figure 7-18: Scheme of filtration setup for MFI measurements at constant flux (Salinas
Rodriguez, 2011) ......................................................................................................... 7-39
Figure 8-1: Caldwell-Lawrence Diagram: 25°C, 40 mg/L TDS ..................................................... 8-5
Figure 8-2: Corrosion of pipe wall .................................................................................................... 8-8
Figure 9-1: Types of typical Basic Plant Layout ........................................................................... 9-12
Figure A. 0-1: Section- Aerator............................................................................................................... 6
Figure A. 0-2: Section - Step Aerator ................................................................................................... 15
Figure A. 0-3: Parshall flume rapid mixer ............................................................................................ 16
Figure A. 0-4: Calibration curve of the 0.3m throat Parshall flume rapid mixer .................................. 18
Figure A. 0-5: Turbine Mixer ................................................................................................................ 19
Figure A. 0-6: Hydraulic Flocculator (Conceptual Design) .................................................................. 25
Figure A. 0-7: The variation of Hydraulic Gradient and water depth ................................................... 26
Figure A. 0-8: Plan view of Flocculator unit with paddles .......................Error! Bookmark not defined.
Figure A. 0-9: Flocculator Paddle Details .................................................Error! Bookmark not defined.
Figure A. 0-10: Sizing of Sedimentation basin ..................................................................................... 33
Figure A. 0-11: Inlet port of Sedimentation basin ............................................................................ 34
Figure A. 0-12: Detail of Collecting Channel .................................................................................... 35
Figure A.0-13: Sizing of Hopper Bottom Sludge Blanket Clarifier ................................................ 40
Figure A. 0-14: Stocked Sand Analysis ................................................................................................ 79
Figure A. 0-15: Filter Paper Test- Ambalanthota Water Supply........................................................... 82
Figure A. 0-16: Filter Paper Test- Matara Water Supply ...................................................................... 83
Figure A. 0-17: Detail of Floating bowl chlorinator ......................................................................... 87
Figure A. 0-18: Chlorine Solution Feeding Arrangement ............................................................... 88
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List of Tables
Table 2-1: Type of Taste and Odour and the Material Cause ..................................................... 2-26
Table 2-2: Types of microorganisms and their sizes ..................................................................... 2-32
Table 2-3: Classification of Trophic state ...................................................................................... 2-37
Table 2-4: Specification for Potable water SLS: 614:2013 ........................................................... 2-38
Table 2-5: Proposed guideline values of cyanotoxins in drinking water in Sri Lanka .............. 2-40
Table 2-6: Tolerance limits for inland surface waters used as raw water for public water
supply: SLS 722: 1985 ................................................................................................ 2-40
Table 2-7: Definitions related to water quality and pollution control ......................................... 2-41
Table 2-8: Potential Waterborne Disease-Causing Organisms .................................................... 2-41
Table 2-9: Aesthetic Quality related diseases and WHO guideline values.................................. 2-42
Table 2-10: Chemical related diseases and WHO guideline values ............................................. 2-43
Table 2-11: Metals related diseases and WHO guideline values.................................................. 2-44
Table 2-12: Diseases caused by Pesticides and WHO guideline values ....................................... 2-46
Table 2-13: ComparisonofSLS, EU and, USEPA,WHOguidelines .............................................. 2-47
Table 3-1: Sample Label .................................................................................................................... 3-6
Table 3-2 Handling of Samples ......................................................................................................... 3-7
Table 3-3: The equipment and the method of testing of Water Quality Parameters. .................. 3-9
Table 3-4: Health hazards and Treatment options for metals ..................................................... 3-14
Table 3-5: Conductivity Factors of Ions Commonly Found In Water ........................................ 3-19
Table 4-1: Water Quality Concerns ................................................................................................. 4-5
Table 4-2: Applications of desalination/ membrane technologies .................................................. 4-8
Table 4-3: Summary of Treatment Process Applications ............................................................... 4-8
Table 4-4: Effectiveness of Water Treatment Process in removing various impurities ............ 4-10
Table 4-5: Recommended Water Treatment Processes ................................................................ 4-12
Table 4-6: Advanced Treatment Processes and its removal ......................................................... 4-16
Table 5-1: Classification of Screens ................................................................................................ 5-10
Table 5-2: Standard Treated Water Quantity and Microstrainer Size....................................... 5-13
Table 5-3: Microstrainer Filter Mesh Specifications .................................................................... 5-13
Table 5-4: Advantages and Disadvantages of Different PAC Application Points ...................... 5-15
Table 5-5: Magnitude of partial pressure of water vapour and saturation value of oxygen in
water ............................................................................................................................ 5-30
Table 5-6: 10 Minutes Mean Speed ................................................................................................ 5-31
Table 5-7: Type of Mixing and Efficiency Equation ..................................................................... 5-32
Table 5-8: Type of mixing and efficiency ....................................................................................... 5-32
Table 5-9: Particle sizes found in Water Treatment ..................................................................... 5-33
Table 5-10: Common inorganic coagulants ................................................................................... 5-39
Table 5-11: Dosing Concentration of Chemicals ........................................................................... 5-44
Table 5-12: Comparison of Mechanical and Hydraulic Mixers ................................................... 5-46
Table 5-13 : Power number of various Rapid mix impellers........................................................ 5-50
Table 5-14: Components in Design of Jet mixing System ............................................................. 5-52
Table 5-15: Guidelines for the Design and Construction of Baffled Channel Flocculators ...... 5-55
Table 5-16: Typical criterias for mechanical flocculators ............................................................ 5-56
Table 5-17: Classification of Clarification System ........................................................................ 5-58
Table 5-18: Basic Types of Settling ................................................................................................. 5-59
Table 5-19: Typical Settling Velocities of Particles ....................................................................... 5-61
Table 5-20: Recommended surface overflow rates ....................................................................... 5-63
Table 5-21: Advantages and Disadvantages of Flocculation-Clarifiers ...................................... 5-67
Table 5-22: Advantages and Disadvantages of Sludge Recirculation Type ................................ 5-70
Table 5-23: Advantages and disadvantages of pulsation sludge blanket contact clarifier ........ 5-72
Table 5-24: Type of Pulsators ......................................................................................................... 5-72
Table 5-25: Classification of Filtration Systems ............................................................................ 5-86
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Table 5-26: Characteristics of sand filters ..................................................................................... 5-87
Table 5-27: Media Used in Multilayer Filtration ........................................................................ 5-103
Table 5-28: Backwash Water Source Data .................................................................................. 5-113
Table 5-29: Comparison of Two Backwash Alternatives for Granular Bed Filters ................ 5-116
Table 5-30: Contrasts between Backwash Alternatives .............................................................. 5-117
Table 5-31: Typical Water and Air-Scour Flow Rates for Backwash Systems ........................ 5-122
Table 5-32: Calculation of production per m2 ............................................................................. 5-128
Table 5-33: Backwash Velocity of pressure filters (Temperature 15-25 C) ............................ 5-131
Table 5-34: Suggested source water quality limitation of conventional slow sand filter ......... 5-140
Table 5-35: Recommended Number of Filter Basins .................................................................. 5-142
Table 5-36: Comparisons of the Operation of Slow Sand and GAC Sandwich Filters............ 5-150
Table 5-37: Schedule of Activities for Slow Sand Filter Operation ........................................... 5-151
Table 5-38: Performance of roughing filters ............................................................................... 5-154
Table 5-39: Different Sizes of Roughing Filter Media ................................................................ 5-159
Table 5-40: Tentative Design Guidelines for HRF ...................................................................... 5-159
Table 5-41: Tolerance limits for the Discharges of Industrial waste in to Inland surface
waters......................................................................................................................... 5-167
Table 5-42: Unit operations and processes used for residual management .............................. 5-168
Table 5-43: Typical Constants for Estimating Sludge Production ............................................ 5-171
Table 5-44: physical and chemical characteristics of Alum and Iron Coagulated Sludge ...... 5-172
Table 5-45: Physical and Chemical Quality of Filter backwash ................................................ 5-177
Table 5-46: Normal ranges of solid content by various residual treatment processes ............. 5-179
Table 5-47: Sludge Dewatering Systems Treatment ................................................................... 5-184
Table 5-48: EU Council Directive 86/278/EEC for land application of Sludge ........................ 5-196
Table 6-1: Lime – Jumbo bags + Dry lime feeder versus Manual addition to batching tanks +
Dosing pumps .............................................................................................................. 6-16
Table 6-2: Suggested values for t10/ in respect of different baffling arrangements .................. 6-23
Table 6-3: Recommended CTTab values for 99% (2-log) inactivation ......................................... 6-25
Table 6-4: CTTab Values for achieving inactivation Giardia lamblia cysts by free chlorine
residual ........................................................................................................................ 6-26
Table 6-5: CTTab Values for achieving inactivation viruses by free chlorine residual ............... 6-26
Table 6-6: CTTab Values for achieving inactivation Giardia lamblia cysts and viruses by
chlorine dioxide, Ozone, chloramines, and UV ........................................................ 6-26
Table 6-7: Recommended disinfection credits for entire treatment process to meet SWTR
requirements ............................................................................................................... 6-27
Table 6-8: Chlorine used for various treatment processes other than Disinfection ................... 6-31
Table 6-9: Bleaching powder requirements for disinfection of mains and storage basins ........ 6-38
Table 6-10: Comparison of Chlorinators ....................................................................................... 6-42
Table 6-11: Chlorine Cylinder Inventory ...................................................................................... 6-48
Table 6-12: Chemical and Water requirements for Chlorine Absorption in Alkaline Solution6-48
Table 6-13: Ct in mg min/l for 2 log inactivation of Cryptosporidium, Giardia and viruses
using chlorine dioxide................................................................................................. 6-49
Table 6-14: Required Ct values (in mg min/l) for inactivation of microorganisms by ClO2
compared with Cl2 and O3 at 10°C and pH 6-9........................................................ 6-50
Table 6-15: UV Dose Requirements – millijoules percentimeter squared (mJ/cm2) .................. 6-53
Table 6-16: Recommended Number of TTHM Monitoring Locations V Population ................ 6-57
Table 7-1: Oxidation of Iron and Manganese with Oxygen, Chlorine, Chlorine Dioxide and
Potassium Permanganate ............................................................................................. 7-2
Table 7-2: Mean maximum temperature and corresponding recommended fluoride
concentration for drinking purposes .......................................................................... 7-9
Table 7-3: Fluoride removal methods (based on Heidweiller, 1990; Pickard and Bari, 2004
and BGS, 2003; cited in Feenstra, et al., 2007) ........................................................ 7-11
Table 7-4: Water clarification based total hardness ..................................................................... 7-14
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Table 7-5: Comparison of membrane filtration and reverse osmosis (Water Treatment
Principles and Design) ................................................................................................ 7-17
Table 7-6: Comparison between outside in and inside out modes of hollow fibre membrane
configurations ............................................................................................................. 7-22
Table 7-7: Operating characteristics of MF and UF membrane and rapid sand filters ............ 7-27
Table 8-1: Electrochemical series for Common Metals and Alloys in Sea Water ........................ 8-3
Table 8-2: Corrosivity State of Water for Different CCPP Values ............................................... 8-4
Table 8-3: Stability Indices with Typical Values for Stable Water ............................................... 8-5
Table 8-4: Determination of Langelier Saturation Index ............................................................... 8-6
Table 9-1: Typical Design Criteria for a full treatment works ...................................................... 9-2
Table 9-2: Factors that Influence Required Site Area .................................................................... 9-5
Table 9-3: List Laboratory Equipment .......................................................................................... 9-19
Table A. 0-1: Details of Cascade Trays. ............................................................................................... 10
Table A. 0-2: Dimensions and Capacities of the Parshall Flume for Various Throat Widths (D.A.
Okun, pp 91-104)............................................................................................................. 16
Table A. 0-3: Maximum Submergence ratio ......................................................................................... 17
Table A. 0-4: Summary of Head loss G Values .................................................................................... 24
Table A. 0-5: Recommended surface overflow rates ............................................................................ 33
Table A. 0-6: Bleaching Powder and Water Requirements to Make 1% Chlorine Solutions...... 86
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Preface
Procedure Manuals and Design Manuals for NWSDB have been prepared in year 1989 under
the USAID SRI LANKA PROJECT 383-0088. Due to the rapid changes in Procedures and
Technology during the past 30 years, these manuals need to be updated to suit the present-day
situation incorporating the present technology and changes in environmental and social
aspects.
In 2014 NWS&DB had taken steps for updating the D3 Manual, the third in the series of
Design Manuals for ―Water Quality and Treatment‖ by appointing a steering committee in
year 2014. The steering committee appointed a sub committee to review the present manual
and to prepare necessary updating by incorporating new chapters in consultation with the
steering committee.
This Manual is specifically targeted for water quality and treatment processes and it covers
water quality and treatment processes, planning of plant design and layout, basic design
aspects, water safety aspect and Algae (Cyanobacteria) treatment.
Users are advised to thoroughly use this manual together with D2 Manual in Planning and
Designs of Water Supply Schemes. The users are also advised to refer text books which are
listed under References for further details.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 1-17
List of NWSDB Manuals
Procedure Manuals
P1 - Project Planning Feasibility
P2 - Procedures for Procurement Management and Bid evaluation
P3 - Guidelines for Commissioning and Handing Over/taking Over of a Water Supply Project
P4 - Guidelines for Technical Co-ordination
P5 - Project Design Procedures for HO/RSCC
P6 - Guidelines on Project Appraisal Committee Submissions and Approvals
P7 - Project Management and Contract Administration
P 8 - Health and Safety Manual (New)
P 9 - Laboratory Procedure Manual (New)
P10 - Pipeline Repairs (New)
P11 - NRW Leak Detection (New)
Design Manuals
D1 - Rural water Supply
D2 - Urban Water Supply & Sanitation
D3 - Water Quality & Treatment
D4 - Ground Water
D5 - Mechanical Electrical & Instrumentation Aspect of Water Supply Design
D6 - Guidelines for Latrine Selection & Constructions.
D7 - Waste water Treatment
D8 - Water service Connections
D9 - Plumbing Code
D10-Pre Stressed Concrete Manual for Circular Tanks (New)
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 1-18
Planing and Design Manual Review Committee (PDMRC)
This manual was reviewed and approved by PDMRC. Members of that committee at the time
of commencement were as follows (Appointed on 16.01.2014).
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 1-19
D3 Manual Updating Team (Appointed Date – 21.03.2014)
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 1-20
Abbreviations
AAS Atomic Absorption Spectrophotometry
AOC Assimilable Organic Carbon
ASTM American Society for Testing and Materials
AWWA American Water Works Association
BAC Biological Activate Carbon
BBB Build Black Better
BFP Belt Filter Press
CCPP Calcium Carbonate Precipitation Potential
CCTV Closed-Circuit Television
CEA Central Environmental Authority
CEB Ceylone Electricity Board
CFD Computational Flourd Dynamics
CFU Colony Forming Unit
CKDu Chronic Kidney Disease of unknown etiology
CM Corrective Maintenance
COC Conformity of Construction
CT Contact Time
DAF Dissolved Air Floatation
DADMAC Di- Allyl Di- Methyl Ammonium Chlorite
DBP Disinfection By-Product
DI Ductile Iron
DNA Deoxyribonucleic Acid
DO Dissolved Oxygen
DOC Dissolved Organic Carbon
DOM Dissolved Organic Material
DWQG Drinking Water Quality Guideline
EDCs Endocrine Disruptor Chemicals
EIA Environmental Impact Assessment
ELISA Enzyme-Linked Immunosorbent Assay
EPA Environmental Procurement Agent
EPL Environmental Protection License
EPS Extracellular Polymeric Substance
ERP Emergency Response Plan
ES Effective Size
FAO Food and Agriculture Organization
FC Flow Controller
FEEM Fluorescence Excitation-Emission Matrix
FTT Flavour Threshold Test
GIS Geographical Information System
GAC Granular Activated Carbon
GACF Granular Activated Carbon Filtration
GC / MS Gas Chromatography / Mass Spectrometry
GoSL Government of Sri Lanka
GV Guideline Value
HAAs Haloacetic Acids
HACCP Hazard Assesment Critical Controle Point
HDPE High Density Polyethylene
HPLC High Performing Liquid Chromatography
HRF Horizontal-Flow Roughing Filters
HRT Hydraulic Retention Time
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HVODR Hipolimnetic Volumetric Oxygen Depletion Rate
ICP Inductively Coupled Plasma
IEE Initial Environmental Examination
IEP Iso Electric Point
IMS Integrated Media Support
IOB Iron Oxidizing Bacteria
IRW Internal Renewable Water
kDa Kilo-Dalton
LC-OCD Liquid Chromatography Organic Carbon Detection
LOAEL Lowest-Observed-Adverse-Effect Level
Lpcd Littre per Capita per Day
LRV Log Removal Value
LSI Langlier Saturation Index
MEC Mediated Electro-Catalytic
MF Micro-Filtration
MFI-UF Modified Fouling Index –Ultrafiltration
MnOB Manganese Oxidizing Bacteria
MnZ Manganese Zeolite
MPN Most Probable Number
MSDS Material Safety Data Sheet
MTBE Methyl Tertiary-Butyl Ether
MWCO Molecular Weight Cut Off
NaZ Greensand Zeolite
NDP Net Driving Pressure
NF Nano-Filtration
NGO Non Governmantal Organization
NOAEL No-Observed-Adverse-Effect Level
NOAA National Oceanic and Atmospheric Administratio
NOM Natural Organic Matter
NRW Non-Revenue Water
NTU Nephelometre Turbidity Unit
NWSDB National Water Supply & Drainage Board
ORP Oxidation Reduction Potential
O&M Operation & Maintenance
PAC Powder Activated Carbon
PACl Poly Aluminum Chloride
PAH Poly Aromatic Hydrocarbon
PCB Polychlorinated Biphenyl
PDNA Post Disaster Needs Assessment
P&D Planning and Designs
P&ID Process and Instrumentation Diagram
P&ID Process & Instrumentation Diagram
PE Poly Ethylene
PES Polyether Sulfone
PFR Plug Flow Reactor
PMP Preventive Maintenance Program
POC Particulate Organic Carbon
POM Particulate Organic Material
PPE Persional Protective Equipments
PVC Poly Vinile Cloride
R Recovery
RCl Residual Chlorine
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RSF Rapid Sand Filtration
RTD Residence Time Distribution
RO Reverse Osmosis
RWS Rural Water Supply
SDI Silt Density Index
SDB Sustainable Development Banks
SGD Sustainable Development Goal
SIA Social Impact Assessment
SLLR&DC Sri Lanka Land Reclamation & Development Corporation
SLR Surface Loading Rates
SLS Sri Lankan Standards
SOC Synthetic Organic Chemicals
SOPS Standard Operations Procedures
SSF Slow-Sand Filters
SUVA Specific Ultra Violet Absorbance
SWRO Seawater Reverse Osmosis
SWTR Surface Water Treatment Rule
TCU True Colour Unit
TDH Total Dynamic Head
TDS Total Dissolved Solids
TEP Transparent Exopolymer Particles
THM Trihalomethane
TMP Trans Membrane Pressure
TOC Total Organic Carbon
TON Threshold Odour Number
TOT Threshold Odour Test
TPH Total Petroleum Hydrocarbons
TSS Total Suspended Solids
TTHM Total Trihalomethane
UC Uniformity Coefficient
UF Ultra Filtration
UFW Unaccounted for Water
uPVC UV Stabilized Polyvinylchloride
USA United States of America
USEPA United State Environmental Plant Agency
UV Ultra Violet
UV254 Amount of UV light absorbed by sample
VOC Volatile Organic Compounds
WHO World Health Organization
WSP Water Safety Plan
WSS Water Supply Scheme
WTP Water Treatment Plant
ZSF Zone Setling Velocity
Deposition factor
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CHAPTER 1
INTRODUCTION
This Design manual is intended to be used by the NWSDB Engineers in assessing water
quality, and identifying the need for water treatment in planning and design of water treatment
plants. This objective is based on the health risk management strategy under the principles of
―Water Safety Planning‖.
The designer should have the basic background information on the need for design. The water
treatment design is needed to achieve provision of safe water for drinking and other domestic
and industrial uses. The designer should comply with global needs such as
adaptation/resilience to climate change, green concepts and achieving Sustainable
Development Goals (SDGs). Also he/she should comply with local needs such as energy
saving, zero discharge principles with 3R practice; Reduce, Reuse and Recycle.
It is important to achieve durability aspects along with paying attention to operational and
maintenance aspects of the designs.
Water Treatment step is a part of the ―Water Safety Plan‖ (WSP) described in section 1.2
below. Simply water treatment step is a barrier or ―A Control Measure‖ to avoid
contamination of water, which is the basis of water safety plan. The designers should be
aware that catchment protection, effectiveness of a treatment plant and adequate disinfection
play important role in achieving the safety of drinking water. Although Water Safety Plan is
intended to be an operational tool with an inherent terminology, knowledge on the water
safety concept during the design stage with possible inputs would be an advantage for better
management of water supply systems upon commissioning.
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CHAPTER 2
Water quality assessment is a key process, which determines the unit treatment process before
establishing any water supply scheme. The treatment method must be carefully designed to
achieve the acceptable standard limits.
Pollutant inputs have been increased in recent decades, and the result has been the degradation
of water quality in many rivers and lakes. Chemical discharges to rivers or lakes originated
either from point sources or nonpoint sources. Point sources include effluent pipes from
municipal sewerage treatment plants and factories, relatively simple to monitor and regulate.
Non point inputs are the major source of water pollution in today includes runoff from
agriculture, unprotected sewage, urban runoff, abandoned mines and atmospheric
precipitations. And acid rain also causes damage to the aquatic environment. Furthermore, sea
water intrusion also affects the water sources which are close to the marine environment.
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2.2.2.1. Temperature
Temperature is an important factor to be considered when assessing water quality. In addition
to its own effects, temperature influences several other parameters and can alter the physical
and chemical properties of water. In this regard, water temperature should be accounted for
when determining:
Dissolved oxygen and other dissolved gas concentrations
Conductivity and salinity
Oxidation reduction potential (ORP)
pH
Water Density
Toxicity level ( E.g. Metals)
Microbiology
Table 2-1: Type of Taste and Odour and the Material Cause
Type Cause of Problem
Salty – brackish High sodium
Alkali taste High hardness, total dissolved solids, high alkalinity
Taste
Low pH, high metal, corrosive water.
problem
Metallic taste Metallic taste can be caused by inorganic chemicals such
as iron, manganese, zinc and bacteria (Iron Bacteria).
Rotten egg, musty, earthy,
Hydrogen sulfide, sulphate bacteria,
Odour / grassy odour smell
smell Oily smell Gasoline or oil contamination or nuisance bacteria.
problem Methane gas Organic decomposition (decomposed sewerage)
Phenolic smell Industrial or gasoline contamination
2.2.2.3. Colour
Colour in drinking water may be due to the presence of organic matter such as humic
substances, metals such as iron and manganese, or highly coloured industrial wastes.
The colour measured in water that contains suspended matter is defined as "apparent colour";
the "True colour‖ is measured in water samples from which particulate matter (colour caused
by colloidal, such as vegetable or organic extracts) has been removed by centrifugation. In
general, the true colour of a given water sample is substantially less than its apparent colour
and measured in Hazen units, or Pt. Co. Units (Platinum Cobalt unit). True colour is
measured for the conformation of drinking water quality according to SLS limits.
2.2.2.4. Turbidity
Turbidity is a measure of the relative clarity or cloudiness of water. Turbidity in water may be
caused by a wide variety of suspended matter, such as clay, silt, finely divided organic and
inorganic matter, soluble colored organic compounds, and other micro-organisms.Turbidity in
some groundwater sources is a consequence of inert clay or chalk particles or the precipitation
of non-soluble reduced iron (Fe2+) and other oxide. Natural phenomenon such as landslides
can produce extreme turbidity which is difficult to accommodate treatment facility. Turbidity
levels are an important consideration for the effective design and operation of treatment
processes and an indicator of water quality changes in drinking water systems. Turbidity
measurements are reported in Nephelometric Turbidity Units (NTU). Turbidity in excess of
4NTU may be noticeable and consequently objectionable to consumers
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 2-26
2.2.2.5. Secchi Disk Transparency
Transparency referred as water clarity is a qualitative indicator. It is a measure of how far
light can travel in water. Transparency is directly affected by the level of suspended particles
and dissolved materials in the water. The main types of suspended particles that affect
transparency are algae and sediment. Transparency is a useful routine indicator of water
quality changes and patterns, especially in lakes and reservoirs measured routinely.
Transparency is measured in meters as shown in Figure 2-1.
2.2.2.6. Solids
Total solids in water are the weight of all mineral and organic matter in the water in either
solution or suspension. Total Dissolved Solids (TDS): Comprise inorganic salts mainly
calcium, magnesium, potassium, sodium, bicarbonates, chlorides and sulphates and small
amounts of organic matter that are dissolved in water. Concentrations of TDS in water vary
considerably in different geological regions owing to differences in the solubility of minerals.
High solids content indicates that water is highly contaminated or contains excessing amounts
of mineral matter.
Filtering a sample will remove all the suspended solids. TDS meter does not measure
dissolved solids. It measures conductivity and TDS is calculated by multiplying the
conductivity by a conversion factor. Two assumptions are all dissolved solids produce
conductivity and solutions having the same TDS have equal conductivity.
Total Suspended Solids (TSS) refers to any particles that are suspended in the water column.
These particles can include silt, algae, sediment, and other solids floating in the water (both
organic and inorganic).
Turbidity and TSS are similar in the sense; they both measure the clarity of liquid. But they
aren‘t actually measuring the same property. Turbidity looks at how well a light passes
through liquid and TSS is a quantitative expression of suspended particles. Even though
turbidity and TSS complement each other, their effects are different. For example, TSS can
calculate sediment quality, while turbidity can‘t. And there is no linear relationship between
NTU and TSS in mg/L which makes it very difficult to convert.
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2.2.3. Chemical Characteristics
The chemical characteristics of natural water are a reflection of the minerals contained in the
soils and rocks with which the water has been in contact. In addition, agricultural and urban
runoff and municipal and industrial treated wastewater influence the water quality. Microbial
and chemical transformations also affect the chemical characteristics of water.
2.2.3.2. Chlorides
Chloride, in the form of the Cl-, is one of the major inorganic anions, in saltwater and
freshwater. Chlorides widely distributed in nature include sodium (NaCl), potassium (KCl)
and calcium (CaCl2) salts. The source of chlorides may be due to sewage, manufacturing
wastes, mineral deposits‘, oil fuel wastes or salt water. Chlorides in excess of the normal
content may be considered an indication of contamination by sewage, since chloride is the
constituent of urine or intrusion of salt water if the supply is located near the coast.
2.2.3.3. pH
The pH of a solution is the negative common logarithm of the hydrogen ion activity:
pH = -log [H+]
In dilute solutions, the hydrogen ion activity is approximately equal to the hydrogen ion
concentration. The pH is one of the most important operational water quality parameter.
Careful attention to pH control is necessary at all stages of water treatment to ensure
satisfactory water clarification and disinfection. The pH of the water entering the distribution
system must be controlled to minimize the corrosion of water mains and pipes (Refer Chapter
8).
2.2.3.4. Alkalinity
The alkalinity of water is defined as its capacity to neutralize acid. Alkali substances in water
include hydroxides, carbonates and bicarbonates.
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Hydroxide or caustic alkalinity: is derived from hydroxides of sodium, potassium, calcium
and magnesium.
The amount of hardness and alkalinity are same when calcium and magnesium carbonates are
present alone.
2.2.3.5. Hardness
Hardness in water is caused by a variety of dissolved polyvalent metallic ions, predominantly
calcium and magnesium cations, although other cations (e.g. aluminium, barium, iron,
manganese, strontium and zinc) also contribute. Calcium-based hardness usually
predominates in natural Ground water. The degree of hardness of drinking-water is important
for palatability and for economic and operational considerations.
Depending on the interaction of other factors, such as pH and alkalinity, water with hardness
above approximately 200 mg/L may cause scale deposition in the treatment works,
distribution system, pipe work and tanks. It will also result in high soap consumption and
subsequent ―scum‖ formation. On heating, hard waters form deposits of calcium carbonate
scale. Soft water, (with a hardness of less than 100 mg/L) may, in contrast, have a low
buffering capacity and so be more aggressive for water pipe lines.
2.2.3.7. Nitrogen
Nitrogen is essential for all living things as it is a component of protein. Nitrogen exists in the
environment in many forms and changes as it moves through the nitrogen cycle. Nitrite
(NO2−) is usually present in reducing environment and the nitrate is the more stable oxidation
state. The presence of nitrates in water is usually the result of farming activities like
fertilizing, or seepage from septic systems. Nitrite can also be formed chemically in
distribution pipes by Nitrosomonas bacteria during stagnation of nitrate-containing and
oxygen-poor drinking-water or if Chloramination is used to provide a residual disinfectant.
Nitrogen is a part of many fertilizers and is important for plant nutrition. Nevertheless, if
fertilizers are overused, irrigation water or rain can carry excess nitrogen away from the
landscape, and potentially into nearby water bodies. Too much nitrogen in lakes and streams
can cause an overgrowth of algae (algal bloom) and other plants. Over time, the plants will
deplete the oxygen levels in the water, which can trigger fish kills commonly known as
eutrophication. Excess nitrates can also leach through the soil, and may ultimately end up in
our ground water. Nitrogen in water exists in 4 main forms:
1) Organic nitrogen (in the form of proteins, amino acids and urea also called albuminoid
ammonia).
2) Ammonia nitrogen (as ammonium salts or free ammonia).
3) Nitrite nitrogen and intermediate oxidation stage.
4) Nitrate nitrogen final oxidation product.
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Organic matter (albuminoid nitrogen, albuminoid ammonia) decomposes to ammonia
nitrogen (free ammonia) then decomposes to unstable nitrites (characteristics of fresh sewage)
then oxidizes to nitrates – a relatively stable form.
( ) ( ) ( )
2.2.3.8. Phosphorous
Phosphorous is essential to the growth of organisms. Phosphates occur as ortho-phosphates,
condensed phosphates (pyro-, meta- and other polyphosphates) and organically bound
phosphates. The major source of orthophosphates arise from laundering or cleaning as major
constituent of many commercial cleaning preparations, sewage discharges and fertilizers
mixing through runoff. Discharge of raw or treated wastewater, agricultural drainage, or
certain industrial wastes to the reservoirs increase the nutrient level such as nitrogen and
phosphorous, which enhance the growth of algae and lead to eutrophication. Organic
phosphates are formed primarily by biological processes.
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trichloroethylene, and trichloroethane), and a family of compounds formerly in wide use, the
polychlorinated biphenyls.
The term ―synthetic organic chemicals‖ has become a regulatory rather than a chemical
description. It has evolved to distinguish a group of mostly Volatile Organic Chemicals
(VOCs), regulated first under the 1986 amendments of the federal Safe Drinking Water Act,
from ―SOCs‖ regulated under Phase 2 and later regulations. However, some of the SOCs are
also VOCs (e.g., ethylbenzene, styrene, toluene, and xylenes, and the fumigant pesticides).
The bulk of SOCs are pesticides, but also include the polycyclic aromatic hydrocarbons, the
polychlorinated biphenyls, and two water treatment polymers.
2.2.4.4. Dyes
Water pollution due to effluents from textile dyeing industry is a cause of serious concern.
The techniques for detection of dyes are cost intensive and pointless because the dyes undergo
chemical changes under environmental conditions and the transformation products may be
more toxic and carcinogenic than the parent molecule.
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2.2.4.5. Synthetic Hormones
Endocrine Disruptor Chemicals (EDCs) are a type of chemical that directly influences sex
hormones. By inhibiting the function of these hormones, fertility decreases, and an imbalance
of such hormones has been shown to cause feminizing effects in males. This is a human issue
and becomes increasingly noticeable in fish populations worldwide. It is believe that these
chemicals present in the water supply leads to increasing feminizing effects in male fish.
Estrogens accumulate in body fat and tissue, and because of the cycle of the food chain, the
artificial estrogens /EDC‘s bio-accumulate as they rise up the different levels of the food
chain.
Many bacteria, viruses and parasites (Protozoa and helminthes) are causative organisms for
some of the more virulent diseases transmitted to humans directly through water and
indirectly through contaminated food. The presence of other disease causing microbes in
water is unhealthy and even life threatening. The type of microorganisms and their size are
listed in the Table 2-2.
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Figure 2-2: Mortality Ratios for variety of pathogens
The number of organisms that a human must be exposed to before infection varies a great deal
from one pathogen to the next and also from one human to the next. The public health
community uses the median infectious dose, N50, as a measure of the ‗‗typical‘‘ dose
required for infection in human beings. The methods for conducting such dose–response
assessments are beyond the scope of this discussion but may be found in Haas et al. (1999).
The wide variation in median dose from one pathogen to the next to bring about a response is
illustrated on Figure 2-3.
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Figure 2-3: Median dose of organisms required in drinking wter to cause infection
Source: MWH’s Water Treatment: Principles and Design, Third Edition
2.2.5.2. Viruses
Viruses are a major class of microorganisms but lack many of the attributes of cells. Some
viruses, which cause infectious hepatitis, poliomyelitis, meningitis, and gastroenteritis, can be
waterborne. Viruses range in size from 0.01 to 0.1 μm. Waterborne viruses can be found in
the faeces of infected people and animals. Ground water and surface water supplies that are
exposed to wastewater seepages or discharges can become contaminated by viruses. They
need a host to live. Eg: hepatitis A (destroys liver).
2.2.5.3. Bacteria
Bacteria such as Escherichia coli, Salmonella, Shigella, and Vibrio lives in the intestinal
tracts of humans and other warm blooded animals, can contaminate water if feces enter the
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water. Gastrointestinal disorders are common symptoms of diseases transmitted by
waterborne pathogenic bacteria
The coliform members as shown in Figure 2-4 include Citrobacter, Enterobacter, Escherichia,
and Klebsiella. Many of these bacteria are found naturally in the intestines of humans and
animals, and some are even found naturally in soil and water. E. coli represents the majority
and is found exclusively in the intestines of humans and animals. The family
Enterobacteriaceae encompasses E. coli and all members of the coliform group and includes
foodborne pathogens Salmonella, Shigella, and Yersinia. The Enterobacteriaceae may be
superior to coliforms as have collectively greater resistance to the environment.
Shigella
Enterobactericeae
Yersinia Salmonella
Total Coliform
Fecal Coliform
E. Coli
Pathogenic
E.Coli
Fecal Coliform: These organisms are a subset of the total coliform group. They are
considered a better indicator of fecal contamination than the coliform group.
Escherichia coli: E. coli is present in all mammalian feces at high concentrations; it does not
multiply appreciably, but can survive in water for weeks, and so it is useful as an indicator of
fecal pollution of drinking water systems.
Salmonella typhosa: Typhoid fever, gastrointestinal disorders, high fever, ulceration of the
intestines, and possible nerve damage
Iron bacteria: In water containing Ferrous and Manganous salts, oxidation by iron bacteria
may cause rust-coloured deposits on the walls of tanks, pipes and channels and carry-over of
deposits into the water.
Cyanobacteria and algae: Blooms of cyanobacteria and other algae in reservoirs and in river
waters may impede coagulation and filtration, causing coloration and turbidity of water after
filtration. Some cyanobacterial products such as cyanotoxins cause health problems. However
the production by cyanobactera chemical effects on taste does not seem to be linked to the
production of cyanotoxins.
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2.2.5.4. Protozoa
The two protozoa of the most concern are Giardia and Cryptosporidium. Giardia and
Cryptosporidium form dormant and hardy forms called cysts during their life cycles. The cyst
forms are resistant to chlorine, and can pass through the filters used in many water treatment
plants. If ingested in drinking water they can cause weakening and prolonged diarrhoea in
humans, and can be life threatening to those people with impaired immune systems.
Eutrophication is the enrichment of a water body with nutrients, usually with an excess
amount of nutrients. This process induces growth of plants and algae and due to the biomass
load, which creates "bloom" or great increase of phytoplankton in a water body as a response
to increased levels of nutrients. Since algae are aquatic plants, they require the same
conditions (sunlight and nutrients) as land plants. Algae analysis has shown that as much as
ten percent of the weight of algae is nitrogen and that they contain significant amounts of
phosphorus. Nitrogen and phosphorus are important components of fertilizers.
Eutrophication (growths of Algae) is usually induced by three factors that are light,
temperature, the nutrients (phosphorous and nitrogen). Other factors, such as area, shape, and
depth of water surface also influence the growth of different types of algae. Acidity or
alkalinity, and retention time of the water also affect algal growth. A number of properties and
reactions in the environment also influence growth of algae. Nutrients are the discharge of
phosphate-containing detergents, run-off from fertilizer, and animal, domestic, and industrial
waste.
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When algae die, they decompose and the nutrients contained in that organic matter are
converted into inorganic form by microorganisms. This decomposition process consumes
oxygen, which reduces the concentration of dissolved oxygen. The depleted oxygen levels in
turn may lead to fish kills.
There are six commonly measured variables, which are widely acceptable as good indicators
of the tropic state or level of the lake or tank: chlorophyll a (Chl-a), Secchi depth (SD), total
phosphorus (T-P), Total nitrogen (T-N), Hypolimnetic Volumetric Oxygen Depletion Rate
(HVODR), and phytoplankton species and biomass. In order to evaluate the tropic state of the
tank, following classification is used as given in Table 2-3. For classification and treatment
refer options refer special manual on Algal treatment in the Volume II of D3 manual.
2.2.6.1. Cyanobacteria
Cyanobacteria, also called blue-green algae, is a common and naturally occurring component
of most aquatic ecosystem and contaminate natural and man-made bodies of water. They also
occur on rocks and soil, and in symbiosis with plant and fungi.
Elements heavier than lead, such as radon, radium, thorium, and uranium isotopes, decay by
the release of alpha, alpha and gamma, or beta and gamma emissions. Radionuclides lighter
than lead generally decay by beta and gamma emissions.
Natural radiation is found in elements in the Earth's crust [potassium- 40 (40K)]. Another
source of natural radiation results from cosmic ray bombardment in the atmosphere [tritium
(3H) and carbon-14 (14C)]. Other high-atomic-weight, naturally occurring isotopes found in
natural water include uranium-238, thorium-232, uranium-235 and breakdown products as
radium-226 and radium-228. The units of radiation measurements are curies (CI) or rems [CI
= 3.7 X 1010 nuclear transformations per second; picocurie (pCI) = 10-12 CI]. A rem is the
radiation dose producing the same biological effect (rem = absorbed dose X quality factors).
Each type of radiation has different health effects. For example, alpha particles travel at
velocities up 107 m/sec. When ingested the relatively massive alpha particles can very
damaging to body tissue. Beta particles travel at about the speed of light, penetrate to greater
depth because of their smaller mass and create less damage. Gamma radiation penetrates
deeply, but has limited effects at low levels. The damage to the body from drinking water
compared to natural background radiation is low; however, the potential harm exists from any
level of radiation.
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2.3. Water Quality Guidelines and Standards
The primary aim of the WHO Guidelines is the protection of public health. These Guidelines
are published primarily as a basis for the development of national drinking water standards,
which, if properly implemented, will ensure the safety of drinking water supplies by
eliminating known hazards. The WHO Guidelines provide the recommendations for
managing the risk from hazards that may compromise the safety of drinking water. These
Guidelines values are not mandatory limits.
The Guidelines are utilized primarily by water and health regulators, policymakers and their
advisors, to assist in the development of national standards, in the context of local or national
environmental, social, economic, and cultural conditions.
Sri Lankan Standard Institution updates the SLS standards and if the water quality parameter
is not specified in SLS standard the guideline value of WHO or international standards is
applicable with justification. Table 2-4 provides the specification for potable water in Sri
Lanka.
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Limit Method of test
SI
Characteristic (mg/L) Referee Method Alternative method
No.
Maximum
XXI Total dissolved solids mg/L 500 APHA 2540 - C
XXII Total hardness (as CaCO3 ) mg/L 250 APHA 2340 - C
XXIII Total phosphates (as PO43-) mg/L 2.0 APHA 4500-PC
XIV Zinc (as Zn) mg/L 3.0 APHA 3111 B
Limits for toxic substances
I Arsenic (a As) 0.01 APHA 3111 C
Ii Cadmium (as Cd) 0.03 APHA 3111 B ICP-MS(APHA3125,
EPA 200.8
Iii Chromium (as Cr-) 0.05 APHA 3111 C
Iv Cyanide (as CN) 0.05 APHA (4500 –CN APHA 4500 CN G
C; EPA 335.4 APHA 4500 CN H
V Lead (as Pb) 0.01 APHA 3111 B
ICP-MS(APHA3125,
VI Mercury (as Hg) 0.001 APHA 3111 B
EPA 200.8
VII Selenium (as Se) 0.01 APHA 3114 C
The faecally derived pathogens are the principal concerns in setting health-based targets for
microbial safety. The two indicator organisms proposed in the standard are coliform bacteria
and E.coli bacteria (provides the evidence of recent faecal contamination of water). Total
coliforms and E.coli should be absent immediately after disinfection until it reach to
consumer point. However SLS: 614 allowed three coliform bacteria at the user point but no
E.coli shall be present. In addition, it mentions that no microscopic organisms such as algae,
zooplankton, flagellate and parasites should be present in water.
The physical parameters such as, colour, taste, odour and turbidity provides aesthetically
acceptance by consumers. Taste and odour in drinking water indicate some form of pollution
or of a malfunction during water treatment or distribution due to the presence of potentially
harmful substances. Although WHO guideline has not set any targets for these category
parameters, SLS has defined the value for Colour as 5 Pt Co unit and Turbidity as 2 NTU,
which guide to maintain the treatment plant operation. In the meantime, WHO has defined the
turbidity level should be less than 0.5 NTU for effective disinfection. Although SLS:
614:2013 specify Turbidity as 2 NTU, NWSDB should achieve 0.2 NTU in designing of
water treatment plants for filtered water and for further explanation refer section 6.2.4.
The pH is an important operational water quality parameter and no health concern levels
found in drinking water but SLS set value is 6.5 – 8.5 for pipe born water supply for the
protection due to corrosion. No health-based WHO guideline value is proposed for chloride
and Hardness in drinking water. However, chloride concentrations give a detectable taste in
excess about 250 mg/L, and this has been proposed in the SLS. Similarly no health
concerning values are proposed for Iron, Manganese, Potassium, Sodium, sulphate and total
dissolved solids in WHO guideline values but excess concentrations will affect acceptability
of drinking water. These values have been set as the SLS standard values.
The nutrients levels, Nitrate 50 mg/l as Nitrate ions and Nitrite 3 mg/l (as nitrite ion) is
established in both standards to protect against methaemoglobinaemia (Blue baby syndrome)
in bottle-fed infants.
Further, the SLS has reduced in the amendment for the parameters concerning toxic
substances (Arsenic, Lead, Selenium, Mercury, Cadmium and Cyanide) due to the growing
health issues in the island like CKDu. In addition, new parameters have been introduced in the
new edition for algal toxins for Cylindrospermopsin and Microcystins for the protection of
public health as given in Table 2-5.
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Table 2-5: Proposed guideline values of cyanotoxins in drinking water in Sri Lanka
Parameter Desirable Level Permissible Level
Microcystin-LR (MC-LR), μg/l 1 3
Cylindrospermopsin, μg/l 2 5
2.3.2. Standard for the inland surface waters used as raw water
The Table 2-6 provides the tolerance limits for inland surface waters used as raw water for
public water supply in Sri Lanka.
Table 2-6: Tolerance limits for inland surface waters used as raw water for public water supply:
SLS 722: 1985
No Determinant Unit Tolerance limit
1 Coliform organisms – MPN /100 Not more than 5000 with less than 5% of the
(Monthly average) mL samples with value 20,000 and less than 20% of the
samples with the value 5000
2 pH 6.0 – 9.0
3 Chloride mg/L 1,200 max
4 Nitrate (as N) mg/L 10 max
5 Fluoride (as F) mg/L 1.5 max
6 Phenolic compounds (as mg/L 0.005 max
phenolic OH)
7 Oils and grease mg/L 0.1 max
8 Pesticide residue mg/L WHO Requirement
9 Arsenic (as As) mg/L 0.05 max
10 Cyanide (as CN) mg/L 0.05 max
11 Lead (as Pb) mg/L 0.1 max
12 Mercury (as Hg) mg/L 0.001 max
13 Selenium (as Se) mg/L 0.05 max
14 Chromium (as Cr) mg/L 0.05 max
15 Dissolved oxygen (as DO) mg/L 4 min
16 Biochemical Oxygen Demand mg/L 5 max
17 Radioactive material
Alpha emitters µc/mL 10-9
Beta emitters µc/mL 10-8
Central Environmental Authority has the following tolerance limit for effluents discharge for
different purposes as listed below.
1. Tolerance Limits for the Discharge of Industrial Waste in to Inland Surface Waters
2. Tolerance Limits for Industrial Waste Discharged on Land for Irrigation Purpose
3. Tolerance Limits for Industrial and Domestic Waste Discharged in to Marine Coastal
Areas
4. Tolerance Limits for Waste from Rubber Factories being Discharged into Inland Surface
Waters
5. Tolerance Limits for Waste from Textile Industry being Discharged into Inland Surface
Waters
6. Tolerance Limits for Waste from Being Discharged from Tanning Industries
7. Tolerance Limits for Discharge of Effluents into Public Sewers with Central Treatment
Plants
Table 2-7 summarizes the definitions related to water quality and pollution control in order to
understand various terms.
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Table 2-7: Definitions related to water quality and pollution control
Term Definition
Water quality criterion Numerical concentration or narrative statement recommended to
(synonym: water quality guideline) support and maintain a designated water use
Water quality objective A numerical concentration or narrative statement which has been
(synonyms: water quality goal or established to support and to protect the designated uses of water at
target) a specific site, river basin or part(s) thereof
Water quality standard An objective that is recognized in enforceable environmental control
laws or regulations of a level of Government
Precautionary principle The principle, by virtue of which action to avoid the potential
adverse impact of the release of hazardous substances shall not be
postponed on the ground that scientific research has not fully proved
a causal link between those substances, on the one hand, and the
potential adverse impact, on the other
Table 2-9: Aesthetic Quality related diseases and WHO guideline values
WHO guideline
Parameters Diseases
values
01 pH Extreme pH greater than 11 causes irritation to the eyes, skin, hair No health-based
fibres to swell and mucous membranes. guideline value is
Lower pH below pH 4, causes redness and irritation of the eyes. proposed.
Also, can affect the degree of corrosion of metals as well as
disinfection efficiency, leads to an indirect effect on health.
Below pH 2.5, damage to the epithelium is irreversible and extensive
02 Colour Colour is not injurious to health but is objectionable. No health –based
Typical finished waters have colour values ranging from 3 to 15. guideline value is
proposed.
03 Turbidity Health effect may cause due to suspended particles or colloidal Below 0.2 NTU
caused by inorganic, organic or microorganisms (bacteria, viruses is recommended
and protozoa) are typically attached. for effective
disinfection
04 TDS water becomes significantly unpalatable at levels greater than about 1500 mg/L
1000 mg/l
05 Alkalinity Acceptable limit is 500 mg/L. Acceptable limit
Excessive alkalinity may cause stomach trouble and encrustation of is 500 mg/L.
utensils, pipes and heaters. If the alkalinity is too low, pH changes
from acidic to basic rapidly. Water with low alkalinity can also be
corrosive and can irritate the eyes. Water with high alkalinity has a
soda-like taste and can dry out the skin.
06 Hardness High hardness may affect acceptability of drinking water and form No health based
deposits of calcium carbonate scale on pipes and plumbing, guideline value is
precipitation in boilers and heat exchangers adversely affects heat proposed.
transfer
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2.4.2.1. Mineralization
Waters with high levels of salts, measured as TDS, may be less palatable to consumers and
depending upon the specific salts present, may have a laxative effect on the transient
consumer. High levels of sulphates are implicated in this latter aspect. Sulphate may also
impart taste, at levels above 300 to 400 mg/L. Concentrations of chloride above 250 mg/L
may give water a salty taste.
High salts can also adversely affect industrial cooling operations, boiler feed, and specific
processes requiring softened or demineralized waters, such as food and beverage industries
and electronics firms. Typically, high salts will force these industries to pretreat their water.
High levels of chloride and sulphate can accelerate corrosion of metals in both industrial and
consumer systems. Removal of salts requires expensive treatment, such as demineralization
by ion exchange, electrodialysis, or reverse osmosis, and is not usually done for drinking
water. For excessively high-salt water, blending with lower-salt supplies may reduce the
problem.
2.4.2.2. Staining
Staining of laundry and household fixtures can occur in waters with iron, manganese, or
copper in solution. In oxygenated surface waters of neutral or near neutral pH (5 to 8), typical
concentrations of total iron (mostly the ferric form) are around 0.05 to 0.2 mg/L. In
groundwater, the occurrence of iron at concentrations of 1.0 to 10 mg/L is common. Higher
concentrations (up to 50 mg/L of mostly the ferrous form) are possible in low-bicarbonated,
low-oxygen waters.
If water has iron, red-brown ferric hydroxide precipitates on fixtures and laundry as soon as
oxygen begins to dissolve in the water. The ferrous ion is oxidized to the ferric form by the
oxygen. Manganese is often present with iron and may cause similar staining problems,
yielding a red precipitate or, with the use of bleach, a dark brown to black staining precipitate.
Excess copper in water may create blue stains.
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Parameters Diseases WHO guideline
values
03 Calcium & Affect the acceptability of drinking water, Not available
Magnesium
04 Sulphate High concentration cause noticeable taste. 400 mg/L
High sulphate intake cause gastrointestinal effects resulting
from ingestion.
05 Fluoride High fluoride intake can give rise to dental fluorosis, an 1.5 mg/L
unsightly brown mottling of teeth and skeletal fluorosis, a
condition arising from increasing bone density and which can
eventually lead to fractures and crippling skeletal deformity.
06 Nitrate & Nitrite In bottle-fed infants methaemoglobinaemia (Blue-baby 50 mg/L
syndrome). Lack of oxygen transportation to the blood 3 mg/L
vessels.
06 Phosphate Important substances in human body.
07 Free Ammonia Cause taste and odor problem in drinking water. Not available
08 Dissolved Depletion of dissolved oxygen can encourage the microbial No health-based
Oxygen reduction of nitrate to nitrite and sulphate to sulphide. Also, guideline value is
cause an increase in the concentration of ferrous iron in recommended.
solution, with subsequent discoloration at the tap when the
water is aerated.
Very high levels of dissolved oxygen may exacerbate
corrosion of metal pipes.
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Nos Parameters Disease Guideline values
09 Lead Is a cumulative poison, that it remains in the body 0.01 mg/L
following exposure.
Lead is hazardous to health and affects the central
nervous system. Children and pregnant women are
most at risk.
Minor symptoms include abdominal pains,
decreased appetite, constipation, fatigue, and
decreased physical fitness.
Long-term exposure may cause kidney damage,
anemia, nerve and brain damage, and death.
10 Magnesium Quickly expelled from the bodies of healthy 150 mg/L
humans. People with kidney disease, however, may
suffer from hypertension, confusion, muscle
weakness, and coma
11 Manganese Large doses causes headaches, laziness, irritability, 0.1 mg/L
restlessness, and weakness of the legs.
Long-term heavy exposure may result in a nervous
system disorder.
12 Mercury Large dose of mercury intake results in weakness, 0.006 mg/L
loss of appetite, insomnia, indigestion, diarrhea,
gum inflammation, loosening of the teeth,
irritability, memory loss, muscle tremors, and brain
damage.
Methyl mercury causes Minamata disease.
13 Nickel Carcinogenic 0.07 mg/L
14 Potassium Affect only people have Kidney dysfunction, Hearth Below the health
diseases, coronary arteru diseases, coronary artery concern value
diseases, hypertension, diabetes etc.
15 Radon Carcinogen cause lung cancer
16 Selenium Large dose intake causes, growth inhibition, skin 0.01 mg/L
discoloration, bad teeth, and some psychological and
gastrointestinal problems.
A small amount of selenium has been shown to
protect against poisoning by such metals as mercury,
cadmium, and silver.
17 Silver Poisoning causes a blue-gray discoloration of the
skin, mucous membranes, and eyes,
High doses is fatal to humans.
18 Sodium Normal intake levels is beneficial to adults. 200 mg/L
However, people with heart disease or hypertension
should reduce sodium intake to lower the blood
pressure.
19 Uranium It is a kidney toxin and associated with an increase 0.30 mg/L
in fractional calcium excretion and increased
microglobulinurea.
20 Zinc Essential trace element. High concentration may 3.0 mg/L
appear pale colour and develop a greasy film on
boiling.
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Table 2-12: Diseases caused by Pesticides and WHO guideline values
Nos Parameters Disease Guideline values
01 Aldrin and Persistent Organic Pollutants. Highly toxic to 0.00003 mg/L
dieldrin human. Effect central nervous system and the liver.
02 Carbofuran Highly toxic after acute oral administration. The 0.007 mg/L
main systemic effect of carbofuran poisoning in
short-term and long-term toxicity studies appears to
be cholinesterase (enzyme in the brain) inhibition.
No evidence of teratogenicity ( disturb the
development of embryo) has been found in
reproductive toxicity studies. On the basis of
available studies, carbofuran does not appear to be
carcinogenic or genotoxic
03 Chlorpyrifos Long term exposure inhibit the cholinesterase 0.03 mg/L
(enzyme hydrolyses esters).
04 Endosulfan Effect the kidney. 0.02 mg/L
05 Endrin Effect the central nervous system and carcinogenic 0.0006 mg/L
06 Glyphosate Low toxic. 0.9 mg/L
07 Petrochemicals Benzene and other petrochemicals can cause cancer
even at low exposure levels.
08 Algal toxins Microcystin-LR hepatotoxic, genotoxic, and 0.001 mg/L
carcinogenic
Chlorination can kill many pathogenic (disease causing) microorganisms such as E.coli, but
others, like Cryptosporidium and Giardia, are very resistant to chlorine and require other
measures to properly remove them. Although chlorination has been the most common method
of disinfection, chlorine in water can react with other innocent organic materials in drinking
water and form chemicals called Trihalomethanes (THMs), such as chloroform. THMs have
been shown to be potentially carcinogenic (cancer causing). There is a need to maintain
enough residual chlorine in the storage and distribution system to ensure proper disinfection.
Hence, water quality standards introduces new limits for total trihalomethanes (chloroform,
bromodichloromethane, dibromochloromethane, and bromoform), the sum concentration for
five haloacetic acids (mono-, di-, and trichloroacetic acids and mono- and dibromoacetic
acids), bromate, chlorite, chlorine, chlorine dioxide, chloral hydrate, and chloramines.
Systems using settling and filtration will also be required to achieve percent reductions of
total organic carbon, depending upon source water quality, and prior to disinfection.
Radionuclides
Radioactivity can cause developmental and teratogenic effect (disturb the development of
embryo), heritable genetic effects, and somatic effects including carcinogenesis. The
carcinogenic effects of nuclear radiations (alpha, beta, and gamma) on the cell are thought to
be ionization of cellular constituents leading to changes in the cellular DNA and followed by
DNA-mediated cellular abnormalities. All radionuclides are considered human carcinogens,
though their primary target organs and relative efficiencies differ.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 2-46
Exposure to large amounts of radioactivity can cause nausea, vomiting, hair loss, diarrhea and
hemorrhage, destruction of the intestinal lining, central nervous system damage, and death. It
also causes DNA damage and raises the risk of cancer, particularly in young children.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 2-47
Chemical
No's Parameter Unit WHO USEPA EU SLS
Group
1,2-Dichlorobenzene (0-
43 µg/L 1,000 600 - Organic
dichlorobenzene)
1,4-Dichlorobenzene (p-
44 µg/L 300 75 - Organic
dichlorobenzene)
45 1,2-Dichloroethane µg/L 30 5.0 3.0 Organic
46 1,2-Dichloroethene µg/L 50 - - Organic
47 1,1-Dichloroethylene µg/L - 7.0 - Organic
48 cis-1,2-Dichloroethylene µg/L - 70 - Organic
49 trans-1,2-Dichloroethylene µg/L - 100 - Organic
50 Dichloromethane µg/L 20 5.0 - Organic
51 1,2-Dichloropropane µg/L 40 5.0 - Organic
52 1,3-Dichloropropene µg/L 20 - - Organic
53 Dichlorprop µg/L 100 - - Organic
54 Di(2-ethythexyl) adipate µg/L - 400 - Organic
55 Di(2-ethythexyl) phthalate µg/L 8.0 6.0 - Organic
56 Dimethoate µg/L 6.0 - - Organic
57 Dinoseb µg/L - 7.0 - Organic
58 1,4-Dioxane µg/L 50 - - Organic
59 Dioxin (2,3,7,8-TCDD) µg/L - 0.0 - Organic
60 Diquat µg/L - 20 - Organic
61 Edetic acid µg/L 600 - - Organic
62 Endothall µg/L - 100 - Organic
63 Endrin µg/L 0.6 2.0 - Organic
64 Epichlorohydrin µg/L 0.4 - 0.1 Organic
65 Ethylbenzene µg/L 300 700 - Organic
66 Ethylene dibromide µg/L - 0.1 - Organic
67 Fenoprop/Silvex/2,4'5-TP µg/L 9.0 50 - Organic
68 Fluoride µg/L 1,500 4,000 1,500 1,000 Organic
69 Glyphosate µg/L - 700 - Organic
70 Haloacetic acids (HAAs) µg/L - 60 - DBP
71 Heptachlor µg/L - 0.4 - Organic
72 Heptachlor epoxide µg/L - 0.2 - Organic
73 Heptachlorobenzene µg/L - 1.0 - Organic
74 Hexachlorobutadiene µg/L 0.6 - - Organic
75 Hexachlorocyclopentadiene µg/L - 50 - Organic
76 Hydroxyatrazine µg/L 200 - - Organic
77 Isoproturon µg/L 9.0 - - Organic
78 Lead µg/L 10 15 10 10 Inorganic
79 Lindane µg/L 2.0 0.2 - Organic
80 Mecoprop µg/L 10 - - Organic
81 Mercury µg/L 6.0 2.0 1.0 1.0 Inorganic
4-(2-Methyl-4-
82 µg/L 2.0 - - Organic
chlorophenoxy)acetic acid (MCPA)
83 Methoxychlor µg/L 20 40 - Organic
84 Metolachlor µg/L 10 - - Organic
85 Microcystin-LR µg/L 1.0 - - Algal toxic
86 Molinate µg/L 6.0 - - Organic
87 Monochloramine µg/L 3,000 - - Disinfectant
88 Monochloroacetate µg/L 20 - - DBP
89 Nickel µg/L 70 - 20 20 Organic
90 Nitrate (as NO3 ) µg/L 50,000 45,000 50,000 50,000 Organic
91 Nitrilotriacetic acid µg/L 200 - - Organic
92 Nitrite (as NO2 ) µg/L 3,000 4,500 500 3,000 Inorganic
93 N-Nitrosodimethylamine µg/L 0.1 - - DBP
94 Oxamyl (Vydate) µg/L - 200 - Organic
95 Pendimethalin µg/L 20 - - Organic
96 Pentachlorophenol µg/L 9.0 1.0 - Organic
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 2-48
Chemical
No's Parameter Unit WHO USEPA EU SLS
Group
97 Pesticides µg/L - - 0.1 Organic
98 Pesticides (total) µg/L - - 0.5 Organic
99 Picloram µg/L 500 - Organic
100 Polychlorinated Biphenyls (PCBs) µg/L 0.5 - Organic
101 Polycyclic aromatic hydrocarbons µg/L - 0.1 Organic
102 Selenium µg/L 40 50 10 10 Inorganic
103 Simazine µg/L 2.0 4.0 - Organic
104 Styrene µg/L 20 100 - Organic
105 Terbuthylazine µg/L 7.0 - - Organic
Tetrachloroethene
106 µg/L 40 5.0 - Organic
(Tetrachloroethylene)
107 Tetrachloroethene + trichloroethene µg/L - - 10 Organic
108 Thallium µg/L - 2.0 - Inorganic
109 Toluene µg/L 700 1,000 - Organic
110 Toxaphene µg/L - 3.0 - Organic
111 Trichloroacetate µg/L 200 - - DBP
112 1,2,4-Trichlorobenzene µg/L - 70 - Organic
113 1,1,1-Trichloroethane µg/L - 200 - Organic
114 1,1,2-Trichloroethane µg/L - 5.0 - Organic
115 Trichloroethene µg/L 20 5.0 - Organic
116 2,4,6-Trichlorophenol µg/L 200 - - Organic
2,4,5-T (2,4,5-trichlorophenoxy
117 µg/L 9.0 - - Organic
acetic acid)
118 Trifluralin µg/L 20 - - Organic
119 Trihalomethanes(total) µg/L - 80 100 DBP
120 Vinyl chloride µg/L 0.3 2.0 0.5 Organic
121 Xylenes µg/L 500 10,000 - Organic
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CHAPTER 3
In assessment programs, this initial sampling shall be done to cover at least a year to complete
the full seasonal cycle. Overall process shall included the collection of data to
determinephysical, chemical and biological nature of the water. The process of survey should
start with an in-depth investigation of all factors and activities which exert an influence,
directly or indirectly, on water quality. Inventories have to be prepared on:
The geographical features of the area, including: topography, lithology, climate, land-
use, hydrogeology, hydrologyetc. within the catchment area
Water uses, including: dams, canals, water withdrawal for cities and industries,
agricultural activities, navigation, recreation, fisheries, etc.
Pollution sources (present and expected), including: domestic, industrial and
agricultural, as well as their pollution control measures and waste treatment facilities
within the catchment
study catchment characteristics immediate upstream
7 Pesticide residues Aldrin and dieldrin, Carbofuran, Chlordane, Chlorpyrifos, Endrin, etc.,
8 Filter media evaluation Particle size distribution, Uniformity coefficient, Effective size, Acid
solubility, Accumulated solid contents (g/L), Specific gravity, Ignition
loss, silica content, wearing loss.
9 Water Treatment Aluminium sulphate, Hydrated Lime, Polyaluminium chloride,
chemicals Polymers, Bleaching powder, Chlorine gas, Powdered activated carbon,
Polyacrylamide, Potassium permanganate
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 3-2
(Ca). Data on water quality parameters in existing water supply schemes should be obtained
from NWS&DB laboratories where relevant.
3.1.2. Minor And Trace Inorganic Analysis (Metals And Heavy Metals)
Thesource water analysis for this category to be conductedon a monthly routine basis. Metals,
minor and trace inorganic constituents include : Aluminium (Al), Arsenic (As), Barium (Ba),
Beryllium (Be), Cadmium (Cd), Chromium (Cr), Cobalt (Co), Copper (Cu), Iron (Fe),
Lithium (Li), Lead (Pb), Manganese (Mn), Mercury (Hg), Molybdenum (Mo), Nickel (Ni),
Selenium (Se), Silver (Ag), Strontium (Sr) and Zinc (Zn).
Escherichia coli (E. coli) is a subgroup of the coliform family. Most E. coli bacteria are
harmless and live in the intestines of human and warm-blooded animals. The presence of E.
coli in a drinking water sample usually indicates recent fecal contamination. That indicates
there is a greater risk that pathogens are present.
However, water quality can vary rapidly, and all systems are at risk of occasional failure. For
example, rainfall can greatly increase the levels of microbial contamination in source waters,
and waterborne outbreaks often occur following rainfall. Results of analytical testing must be
interpreted taking this into account. The presence of indicator organism does require an
analysis of all water system facilities and their operation to determine how these organisms
entere into the water system. In such situation it is necessary to collect water samples
immediately and analyse the entire system. Collecting additional samples helps to determine
whether an actual problem exists or not.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 3-3
also considered indicator organisms are fecal streptococci (Streptococcus faecalis) and
clostridia (Clostridium perfringens).
Note: For operational purposes above parameters shall be monitored on routine basis (daily,
monthly or quarterly) depend on the requirement.
The results in g/L are compared to those of a new media placed or specially washed used
media. A filter bed should be investigated at least twice per year to determine the condition of
the media in order to advise on maintenance or to evaluate filtration effectiveness. Need for
this type of determination shall be identified by the monitoring of filter effluent turbidities.
There are two main techniques used to collect samples namely ; grab sampling and composite
sampling.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 3-4
immediate sample thus preferred for some tests. Specifically, pH, dissolved oxygen, and total
residual chlorine that change very rapidly in the water.
Field or in-situ measurements are required for water quality parameters such as pH,
temperature, turbidity, dissolved oxygen and conductivity. For these parameters Grab sample
provide accurate results. Testing of Some ions, such as fluoride and sulphide can also be
determined using ion selective electrodes in the field, although their determination can be
subject to matrix interferences.
Whatever the method of sampling used, following points have to be considered before
collecting the sample:
Sample drawn from a stream or river should not be collected too close to the bank or
too deep under the surface.
Sample should not be drawn from stagnated area.
In piped water systems, samples should be collected at all points representing the
distribution network.
Sample should be drawn from tap connected directly to the water main and not from
storage tanks.
Field measurements such as, temperature, pH, Dissolved Oxygen (DO), Conductivity
and Turbidity are conducted at the site of sample.
Avoid touching the inside or lip of the sample bottles or caps, wear gloves if necessary
(during collection of samples for trace metals).
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 3-5
Sample collection from surface Collection of sample from Well
water
Figure 3-1: Sample Collection
3.2.4. Dug Well, Tube Well and Well With Hand Pump and Other Devices
If the sample is to be taken from a well fitted with a hand pump, pump water to waste for
about 5 minutes before collecting sample. If the well is equipped with a mechanical pump,
collect sample from a tap on the discharge, after allowing to waste. If there is no pumping,
collect a sample directly from the well by means of a bottle fitted with a weight at the base
and that will take care to avoid contamination of samples by any surface scum.
Sample Containers and Labels: Sample must be collected in the correct volume sufficient
for the specific tests, with the right device and in the right container. Containers are usually
glass, polyethylene or polypropylene, and are selected based on their lack of interaction with
analytical parameters. Each water sample bottle must be labelled with a site code, a site
location description, sample collection time and date, analysis required, the initials of the
person collecting the water sample and accompanied by analysis request form showing the
required parameters. In addition, samples should be adequately preserved if required and
transported to the laboratory as quickly as possible. Label the bottle with the appropriate acid
sticker if preservative is added. Use clear tape to affix the label.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 3-6
Table 3-2 Handling of Samples
Maximum
Determination Container Preservation
holding time
1. BACTERIAL TESTS
Coliform, Colilert P, G & sterile Cool, 4°C, 0.008% Na2S2O3 6-24 hours
Coliform, Fecal and Total P,G& sterile Cool, 4°C, 0.008% Na2S2O3 6-24 hours
Fecal Streptococci P,G& sterile Cool, 4°C, 0.008% Na2S2O3 6-24 hours
2. INORGANIC TESTS
Acidity P,G Cool, 4°C 24 hours
Alkalinity P,G Cool, 4°C 24 hours
Ammonia P,G Filter and store 4°C 24 hours
Calcium P,G HNO3 to pH<2 6 months
Chloride P,G None Required 28 days
Chlorine, Total Residual P,G None Required 5 minutes
Chlorophyll G Amber Filter and freeze filter pater in dark 28 days
Color P,G Cool, 4°C 48 hours
Conductivity P,G Cool, 4°C 28 days
Ferrous Iron Acid washed P Acidify with HCl acid to pH <2 24 hours
Iron total or G 28 days
Fluoride P,G None Required 28 days
Hardness P,G HNO3 to pH<2 6 months
pH P,G None Required Immediately
Kjeldahl and Organic N2 P,G Freeze sample 28 days
Magnesium P Acidify with Nitric to pH<2 and cool 28 days
to 4°C
Nitrate P,G Filter and freeze the sample 28 days
Nitrite P,G Freeze immediately 48 hours
Odour P,G Cool, 4°C, 6 hours
Oxygen, Dissolved (Winkler) GBOD bottle Fix on Site & Store in Dark 8 hours
Phenolic compounds G amber with Cool, 4°C, H2SO4 to pH<2 21 days
PTFE cap
Phosphorus, Total P,G Cool, 4°C, H2SO4 to pH<2 28 days
Residue, Total P,G Cool, 4°C 24 hours
Total Dissolved Solids (TDS) P,G Cool, 4°C 24 hours
Total Suspended Solids P,G Cool, 4°C 24 hours
(TSS)
Silica P Only Filter and Cool, 4°C 28 days
Specific Conductance P,G Cool, 4°C 28 days
Sulfate P,G Cool, 4°C 7 days
Sulphide total P None Required immediately
Surfactants G rinsed with Cool, 4°C, H2SO4 to pH<2 48 hours
methanol
Temperature P,G None Required Immediately
Turbidity P,G Cool, 4°C 24 hours
3. METALS
Metals Acid washed P,G HNO3 to pH<2 cool to4°C 6 months
Chromium VI P,G Cool, 4°C 24 hours
Mercury Acid washed G HNO3 to pH<2 and potassium 28 days
dichromate.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 3-7
Maximum
Determination Container Preservation
holding time
4. ORGANIC TESTS
Organic Carbon, Total (TOC) Amber glass Cool, 4°C, H2SO4 to pH<2 07 days
OR with PTFE cap
UV 254 liner
Biochemical Oxygen P,G Cool, 4°C 24 hours
Demand (BOD)
Chemical Oxygen Demand P,G Cool, 4°C, H2SO4 to pH<2 07 days
(COD)
Oil and Grease Cool, 4°C, H2SO4 to pH<2 28 days
Phenols G, Teflon-Lined Cool, 4°C 7 days until
Pesticides Cap Cool, 4°C extraction; 40
days after
Chlorinated Herbicides Cool, 4°C extraction
Trihalomethanes G Airtight 14 days
Algae
Algal toxins Amber glass or Cool, stored in thedark Month (frozen)
Teflon
P= Polyethylene, G – Borosilicate Glass, PTFE : Polytetrafluoroethylene
1. When the sample is collected, leave ample air space in the bottle (at least 2.5cm) to
facilitate mixing by shaking, before examination.
2. Collect samples that are representative of the water being tested, flush or disinfect
sample ports and use disinfectant technique (UV or autoclave) to avoid sample
contamination.
3. Keep sampling bottle closed until it is to be filled.
4. Remove stopper or cap as a unit (a paper or foil hood over the stopper). Do not
contaminate inner surface of stopper or cap and neck of bottle.
5. Fill container without rinsing.
6. Place the removed stopper or cap immediately, secure hood around neck of bottle. A
paper or foil hood over the stopper and bottleneck is necessary.
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Table 3-3: The equipment and the method of testing of Water Quality Parameters.
Nos Parameters Methods Required Equipment
Physical
01 Odour / Taste Organoleptic Sensory evaluation
Standard Colour Disks
03 Colour Visual comparison / Colorimetric
Spectrophotometer 400 – 700nm
04 Turbidity Light scattering pattern Turbidity meter
pH meter with glass electrode
1.Electrometric/ Potentiometric
05 pH Bromothymol Blue (BTB / Thymol
2.pH indicators
Blue (TB), Litmus papers
Oxidation-reduction indicator
06 ORP pH / ORP meter
Electrode
Conductivity meter with Platinum
07 Conductivity Specific conductance
electrodes
Total Dissolved Conductivity / TDS meter, Analytical
08 1.Conductivity 2.Gravimetry
Solids Balance
Chemical
01 Hardness EDTA titration method Titration
02 Calcium AAS, ICP, AAS , ICP
EDTA titration method Titration
03 Magnesium AAS, ICP, AAS, ICP,
Gravimetric method Electronic Balance
04 Chloride Argentometric (Silver Nitrate titration) Titration
05 Chlorine Iodometric method Titration
DPT colorimetry Spectrophotometer
06 Salinity Electrical conductivity method Conductivity meter
07 Sulphate Turbidimetric Colorimeter 420nm/
Spectrophotometer
08 Fluoride SPADNS method Colorimeter, Spectrophotometer
Iron selective Electrode Ion meter & Fluoride selective
Electrode
09 Alkalinity Titrimetric Titration
10 Nitrate UV spectrophotometric absorption UV Spectrophotometer
220nm
Electrode Method Nitrate Ion electrode
Cadmium Reduction
Phenoldisulphonic acid, Hydrazine Spectrophotometer / colorimeter
reduction method
11 Nitrite Colorimetric method Spectrophotometer / colorimeter
12 Phosphate Vanodomolybdo phosphoric Acid Colorimeter
method Spectrophotometer
Stannous chloride method
13 Free Ammonia Nesslerization Method Spectrophotometer
Ammonia selective electrode Selective Electrode
Titrimetric method Acid titration
14 Dissolved Oxygen Winkler Method with axide Iodometric Titration
modification Oxygen sensitive membrane
Membrane electrode method electrode
Metals
01 Aluminum AAS (Flame), ICP, AAS , ICP
Eriochrome cyanine method Spectrophotometer
02 Arsenic AAS (Vapour), ICP, AAS , ICP
Silver diethyldithiocarbamate Spectrophotometer
03 Cadmium AAS (Flame), ICP, AAS , ICP
Dithizone Spectrophotometer
04 Calcium AAS, ICP, AAS , ICP
EDTA titration method Titration
05 Chromium AAS (Flame), ICP, AAS , ICP
colorimetry Spectrophotometer
06 Chromium hexavalent Colorimetric, ICP/MS AAS , ICP
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 3-9
Nos Parameters Methods Required Equipment
07 Copper AAS (Flame), ICP, AAS , ICP
Neocuproine method Spectrophotometer
08 Cyanide AAS, ICP AAS , ICP
Colorimetric (Spectrophotometer) Spectrophotometer
09 Iron AAS (Flame), ICP, AAS , ICP
Phenanthroline method Spectrophotometer
10 Lead AAS (Flame), ICP, Dithizone method AAS , ICP
(Spectrophotometry) Spectrophotometer
11 Magnesium AAS (Flame), ICP AAS , ICP
Gravimetric method Analytical balance
12 Manganese AAS (Flame), ICP, Persulphate method AAS , ICP
(Spectrophotometry) Spectrophotometer
13 Mercury AAS (Vapour)) AAS , ICP
14 Nickel AAS (Flame), ICP, AAS , ICP
15 Potassium Flame Photometric, AAS (Flame AAS , ICP
emission), ICP, Ion selective Electrode, Spectrophotometer
Spectrophotometry
16 Selenium AAS (Flame), ICP, Spectrophotometry AAS , ICPSpectrophotometer
17 Sodium Flame photometer, AAS (Flame AAS , ICP
emission), ICP,
18 Zinc AAS (Flame), ICP, Zincon method AAS , ICP
(Spectrophotometry) Spectrophotometer
Organic
01 BOD Titrimetric (Winkler method) Incubators
Respirometric method Respirometers
02 COD Open/ Close Reflux titrimetric method COD digesters 105°C, 2Hrs
03 TOC / DOC Combustion-infrared method TOC analyzer
Persulphate oxidation method
04 THM Liquid-Liquid Extraction Gas GC/MS
Chromatography (Purge and Trap )
05 Oil & Grease Solvent extraction gravimetry Electronic balance,
Soxhlet extration Soxhlet extraction apparatus
Partition- Infrared method
06 Phenols Chloroform extraction method Spectrophotometer
Direct photometric method
07 Polychlorinated Liquid-Liquid Extraction GC
Biphenyls (PCBs) GC or GC/MS GC/MS
08 Surfactants Colorimetry Sublation apparatus and
Spectrophotometer
09 Pesticides GC/MS, HPLC GC/MS, HPLC
Bacteriological
Analysis
01 Total Coliform Membrane Filtration, Incubators
02 Faecal Coliform Most Probable Number (MPN),
03 Salmonella sp Hydrogen sulphide strip method
04 Total bacteria Pourplate
Cyanotoxins
Microcystin-LR ELISA or HPLC, Limit of Detection ELISA or HPLC,
(LOD) <0.1μg/l
Cylindrospermopsin ELISA or HPLC, Limit of Detection ELISA or HPLC,
(LOD) <0.1μg/l
Note: GC / MS = Gas Chromatography / Mass Spectrometry, ICP = Inductively Coupled Plasma, AAS =
Atomic Absorption Spectrophotometry, HPLC = High Performing Liquid Chromatography Note that for testing
of Testing of Algae refer Annex reference on algal treatment.
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3.3.1. Testing of Petroleum Product / Petrochemical
Detailed physical and chemical properties are available for only about 250 petroleum
hydrocarbons. It is not practical to analyse for all possible petroleum hydrocarbons in water,
since it would be prohibitively costly to quantify each individual compound using current
analytical technology. The suitable approach to make the problem more manageable was to
divide Total Petroleum Hydrocarbons (TPH) into a series of fractions based on the number of
carbon atoms in conjunction with general structure in Aromatic and Aliphatic fractions. The
approach taken within the petroleum industry is to refer to aliphatic and aromatic fractions on
the basis of their boiling point normalized to the boiling point of the n-alkanes or retention
time on a boiling point gas chromatographic column. This is characterized by the equivalent
carbon (EC) number. For example, the boiling point of hexane, which consists of six carbon
atoms, is 69 °C, and its EC number is 6. Benzene also consists of six carbon atoms, but its
boiling point is 80 °C, and its EC number is 6.5.
The methods for petroleum hydrocarbons are largely based on gas chromatography and liquid
chromatography. The use of infrared spectrometry for total hydrocarbons may be of value in
conjunction with analytical data on specific substances such as benzene and the low-
molecular-weight aromatic hydrocarbons. Taste and odour testing would also be a valuable
supplement parameter to chemical analysis.
3.2.1.2. Turbidity
Turbidity in excess of 4 NTU may be noticeable and consequently objectionable to
consumers. Water is practically muddy at turbidity 500 NTU. Turbidity can seriously interfere
with the efficiency of disinfection by providing protection for organisms, and therefore the
water treatment is designed to remove particulate matter before disinfection. For effective
disinfection, turbidity should be less than 0.5 NTU.
3.2.1.3. pH
The pH is mostly a result of natural geological conditions at the site, the type of minerals
found in the local rock and can be affected by acid rain. No health-based guideline value is
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 3-11
proposed for pH. Although pH usually has no direct impact on consumers, it is one of the
most important operational water quality parameters. Exposure to pH greater than 11 or low
pH less than 4 results in similar effects in irritation to the eyes, skin, and mucous membranes.
In addition, pH can affect the degree of disinfection efficiency. For effective disinfection with
chlorine, the pH should preferably be in the range of 6.5 – 8.0. The water with a pH < 6.5
could be acidic, soft, and corrosive. Acidic water could contain metal ions such as iron,
manganese, copper, lead, and zinc metals some of which are toxic. While pH levels above 8.5
may create scaling problems and a bitter taste. Low pH water entering the distribution system
must be controlled to minimize the corrosion of water mains and pipes in household water
systems.
3.4.2.1.Alkalinity
The level of alkalinity is important in coagulation and flocculation process. Water with low
alkalinity is more difficult to form flocs and the alkalinity has to be increased by adding lime.
Removal of hardness by precipitation is aided by lime (Ca(OH)2) and soda ash
(Na2CO3).Alkalinity is important to control corrosion in piping systems.
The taste threshold for the calcium ion is in the range 100–300 mg/L. Hardness levels above
500 mg/L are generally considered to be aesthetically unacceptable, although this level is
tolerated in some communities.
Depending on the interaction of other factors, such as pH and alkalinity, water with hardness
above approximately 200 mg/L may cause scale deposition in the distribution system as well
as sanitary installation and increased soap consumption. In contrast, soft water, with hardness
less than about 100 mg/L, has a greater tendency to cause corrosion of pipes, resulting in the
presence of certain heavy metals, such as cadmium, copper, lead, and zinc, in drinking-water.
The degree to which this corrosion and solubilization of metals occurs also depends on the
pH, alkalinity, and dissolved oxygen concentration.
The taste threshold for the calcium ion is in the range 100–300 mg/L. Hardness levels above
500 mg/L are generally considered aesthetically unacceptable, although this level is tolerated
in some communities.
Depending on the interaction of other factors, such as pH and alkalinity, water with hardness
above approximately 200 mg/L may cause scale deposition in the distribution system, water
meter as well as sanitary installation and increased soap consumption. In contrast, soft water,
with hardness less than about 100 mg/L, has a greater tendency to cause corrosion of pipes,
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 3-13
resulting in the presence of certain heavy metals, such as cadmium, copper, lead, and zinc, in
drinking water. The degree to which this corrosion and solubilisation of metals occurs also
depends on the pH, alkalinity, and dissolved oxygen concentration.
3.4.2.5. Chloride
Chloride will impart a salty or brackish taste to water, which will be noticeable around 250
mg/L. At 500 – 1000 mg/L content water will be unpalatable. Water containing more than
4,000 mg/L is unsafe. Salinity is a measure of the total salt concentration, comprised mostly
of Na+ and Cl- ions. This is most importantly measured when seawater mixes with
freshwater. Excessive chloride concentration increases the rate of corrosion of metals,
depending on the alkalinity of the water. This can lead to increased concentrations of metals
in the water supply.
3.4.2.6. Fluoride
Fluoride an essential element for human beings with regard to the prevention of dental caries
(tooth decay). Higher concentrations are often associated with groundwater. However
consumption of fluoride rich drinkingwater 3- 6 mg/L results in dental fluorosis and over 10
mg/L develops to crippling skeletal fluorosis, both effects being irreversible. WHO has
recommended a fluoride concentration of between 1.0 to 1.5mg/L in drinking water as the
optimum level that promotes dental as well as skeletal.
Another serious health problem with growing concern in the recent past is the Chronic Kidney
Disease of unknown aetiology (CKDu) among many people in the dry zone in some districts
of Sri Lanka. Statistically, it has been highlighted that this problem too, is common in the
areas of groundwater bearing high fluoride.
3.4.2.7. Sulphate
Levels of sulphate in rainwater and surface water correlate with emissions of sulfur dioxide
from anthropogenic sources. Seawater contains about 2700 mg/L. Recommended maximum
concentration is 250 mg/L for driking water. Excess sulphate in drinking-water cause
noticeable taste. High sulphate may contribute to the corrosion of distribution systems. No
health concern at levels found in drinking-water.
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Occurrence in the drinking WHO GV
Metal Health hazards Treatment option
water mg/L
Released to the environment in
wastewater, fertilizers and Carcinogenic by the Coagulation or
Cadmium impurities in galvanized pipes inhalation route, Kidney is precipitation 0.03
and solders and some metal the target organ. softening
fittings
Exist in valences of +2 to +6 Chromium (VI) human
0.015 mg/l should be
widely distributed in Earth‘s carcinogen and chromium
Chromium achievable using 0.05
crust. Chromium (III) is an (III) not carcinogenic to
coagulation
essential nutrient. humans.
Enters by dissolution from
Zinc galvanized pipes. But essential Cause metallic taste. 3
element.
3.4.2.9. Sodium
No health-based guideline value is proposed for sodium as the contribution from drinking-
water to daily intake is small. However, sodium may affect the taste of drinking-water at
levels above about 200 mg/L. And water softening devices usually increase sodium
concentration, while reverse osmosis and distillation units will reduce it.
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3.4.2.10. Potassium
Potassium occurs in drinking-water well below concentrations than of health concern.
However the recommended daily requirement is greater than 3000 mg. Potassium affect only
individuals in high-risk groups i.e. individuals with kidney dysfunction or other diseases, such
as heart disease, coronary artery disease, hypertension, diabetes, adrenal insufficiency, pre-
existing hyperkalaemia; people taking medications that interfere with normal potassium-
dependent functions in the body; and older individuals or infants.
3.4.2.11. Iron
The iron exists in the form of Fe2+ and Fe3+ readily combine with oxygen- and sulfur-
containing compounds to form oxides, hydroxides, carbonates, and sulfides. Iron
concentrations below 0.3 mg/L areunnoticeable.
In drinking-water supplies, iron(II) salts are unstable and are precipitated as insoluble iron(III)
hydroxide, which settles out as a rust-coloured silt. Groundwater may contain iron(II) without
discoloration or turbidity but may develop turbidity and colour in piped systems at iron levels
above 0.05–0.1 mg/L.Iron in drinking water is not a health hazard unless at extreme levels.
But, Iron result in staining (reddish brown) of laundry, plumbing fixtures, at concentrations
above 0.3 mg/L. Iron also promotes undesirable bacterial growth ("iron bacteria") within a
waterworks and distribution system, resulting in the deposition of a slimy coating on the
piping. It may impart an inky or metallic taste to water and exceeding 0.05mg/L may develop
some odour, stain fixtures or form precipitates.
3.4.2.12. Manganese
Manganese may become noticeable in tap water at concentrations greater than 0.05 mg/L by
showing a color(dark brownish-red), odor, or taste to the water. However, health effects from
manganese are not a concern until concentrations are approximately 10 times higher.
3.4.2.15. Trihalomethane
THMs are formed in drinking water primarily as a result of chlorination of organic matters
present in raw water supplies is carcinogenic. The rate and degree of THM formation increase
as a function of the chlorine and humic and fulvic acid concentration, temperature, pH and
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bromide ion concentration. Chloroform is the most common THM and the principal
disinfection by-product in chlorinated drinking water. In the presence of bromides,
brominated THMs are formed preferentially, and chloroform concentrations decrease
proportionally. The WHO guideline values Chloroform: 0.3 mg/L, Bromoform: 0.1 mg/L,
Dibromochloromethane 0.1 mg/L, and Bromodichloromethane 0.06 mg/L.
Escherichia coli (E. coli) is a subgroup of the coliform family. Most E. coli bacteria are
harmless and exist in the intestines of human and warm-blooded animals. The presence of E.
coli in a drinking water sample usually indicates recent fecal contamination. That indicates
there is a greater risk that pathogens are present.
However, water quality can vary rapidly, and all systems are at risk of occasional failure. For
example, rainfall can greatly increase the levels of microbial contamination in source waters,
and waterborne outbreaks often occur following rainfall. Results of analytical testing must be
interpreted taking this into account. The presence of indicator organism does require an
analysis of all water system facilities and their operation to determine how these organisms
entered into the water system. It is required to collect additional water samples immediately
and inspect the entire system. Collecting additional samples helps to determine whether an
actual problem exists or not.
E. coli - Provides conclusive evidence of recent faecal pollution and should not be present in
drinking water, it is an indication that human sewage or animal faeces has contaminated the
water supply. E.coli is a useful indicator, but it has limitations. Enteric viruses and protozoa
are more resistant to disinfection; consequently, the absence of E.coli will not necessarily
indicate freedom from these organisms. Under certain circumstances, it may be desirable to
include more resistant microorganisms, such as bacteriophages and or bacterial spores.
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Coliform E.coil
Figure 3-3: Coliform & E-coil
Interferences:
The presence of residual chlorine or other halogen can prevent the continuation of
bacterial action. To prevent this occurrence, sodium thiosulfate should be added.
Water samples high in copper, zinc, or other heavy metals can be toxic to bacteria.
Chelating agents such as ethylenediaminetetraacetic acid (EDTA) should only be
added when heavy metals are suspected of being present.
Samples containing large amounts of suspended solids/ high turbidity will interfere
with colony growth and with the subsequent counting of colonies on the filter
membrane.
Water to be tested is diluted serially and inoculated in lactose broth. Coliforms if present in
water, utilize the lactose present in the medium to produce acid and gas.The presence of acid
is indicated by color change of the medium and the presence of gas is detected as gas bubbles
collected in the inverted durham tube.The number of total coliforms is determined by
counting the number of tubes giving positive reaction (i.e both color change and gas
production) and comparing the pattern of positive results (the number of tubes showing
growth at each dilution) with standard statistical tables. Which give the result as MPN.
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Figure 3-5:Most Probable Number
3.5.5. Automated microbiology Detection system
Complete automated microbiology testing sysemt capable of providing results on-site
unprecedented time-to-result performance. This give rapid alet with no fixed incubation delay.
No sample preparation or visual interpretation of results required. Dirext testing of turbid
samples are possible.
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3.4.5.1. Anion-Cation Balance
The anion and cation sums, when expressed as milliequivalents per liter, must balancebecause
all potable waters are electrically neutral. The test is based on the percentage
differencedefined as follows:
∑ ∑
∑ ∑
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CHAPTER 4
Thus, the overall objective of the treatment train is to make the disinfection process more
efficient. In addition, multiple barriers to the pathogens are put in place because pathogens are
removed in each of the processes that precede disinfection.
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The objectives of this chapter are to provide an approach to process selection to form
treatment trains and to summarize the essential factors to be considered in selecting water
treatment processes.
It is necessary to select a water source with acceptable water quality to allow satisfactory
treatment by conventional treatment, however depending on the trend of raw water quality, an
advanced treatment may be introduced. When serious situation occurs or expected to occur
which can hardly coped by conventional treatment, it is necessary to newly install or
strengthen to existing treatment process a new an advanced treatment facility, or to secure the
land for future construction and an allowance in hydraulic head.
SLS 722: 1985 prescribe the tolerance limits for inland surface waters used as raw water for
public water supply as given in section 2.3.2.
Commonly present inorganic ions are Na+, Cl-, SO4-, Ca2+, Mg2+ etc. In addition compounds
originating from groundwater might be present e.g. Iron, manganese, arsenic, fluoride. Clay
particles originating from soil erosion. Algae use to grow in stagnated water with sufficient
nutrients such as Nitrogen and phosphate especially during drought.
In addition, iron and manganese are dissolved from bottom sediments due to decrease in
dissolved oxygen in the bottom part of the reservoir and lake.
In Sri Lanka the lake / reservoir water are constructed by damming a river or with a system of
cascading reservoirs. Hence, in many cases the water quality can be expected with mixed
contaminants in river and lake / reservoir. For example, turbidity can be expected in rivers
while algae may be expected in lake/reservoir. In the cascade system of reservoirs, water flow
through paddy fields several times thus collecting residuals of fertilizers and pesticides and
also solid and liquid water from domestic settlements including pharmaceuticals.
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4.2.3. Groundwater
Groundwater is classified into shallow Groundwater and deep Groundwater. Generally,
shallow Groundwater tends to be affected by surface water and deep Groundwater has
features derived from the geology around the aquifer.
Contamination of groundwater by human activity is a major issue. Principal sources of
groundwater contaminations are:
• Industrial wastes including leakage from power generation plants
• Municipal landfills
• Agrochemicals e.g. pesticides
• Septic systems and cesspool effluents
• Leaks from petroleum pipelines and storage tanks
• Animal wastes
• Acid drainage
• Saltwater intrusion
• Irrigation return flow/agriculture run off
Commonly present constituents are inorganic ions such as. Na+, Cl-, SO42-, Ca2+ etc. In some
areas toxic compounds like arsenic and fluoride may also be present. Iron and Manganese are
commonly in most ground waters. In addition, organic nitrogen is decomposed into ammonia
nitrogen and further oxidised into nitrite and nitrate. The carbon in the organic substances is
decomposed into carbon dioxide, and it is partially dissolved to form hydrogen carbonate or
free carbon dioxide. Methane and hydrogen sulphide might also be present in certain areas.
When surface water can infiltrate into groundwater supply there is a high possibility for the
groundwater to be contaminated with microorganism (especially protozoa such as
Guardia,bacteria viruses), turbidity and organic materials in surface water. it is no more
groundwater and is referred to as groundwater under the direct influence of surface water
requiring surface water treatment processes. Hence, water quality tests of ground water must
carefully be conducted.
It is also necessary to investigate the geological condition of a ground water source for
assessing the pollution possibilities.
However, the rainfall population and water usage and are not evenly divided. In addtion, the
climate change scenario is creating prolonged period of droughts and flash floods increasing
the threats to water security. Therfore, there can be areas where use of brackish water or
seawater might be an economical solution in few areas in Sri Lanka especially in the Northern
Province due to increased cost of water transportation over longer distances and sectoral
demands for water. The total disolved solids in brackish water and seawater is 1,000 mg/L
and 35,000 mg/L respectively in addition to the colur, tubidity and presence of algae in
tropical climates.
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4.2.5. Advantages and Disadvantage of Groundwater
The topic of groundwater source quality is complex with numerous influences, both natural
and human in origin. Apart from being frequently more accessible (drilling a well near a
facility is often more convenient than piping in surface water from a remote location),
groundwater is typically chosen because its natural level of quality requires less treatment to
ensure safe, potable consumption for humans. Although many groundwater benefit from
aesthetic treatment, and sometimes from treatment to remove constituents such as metals and
arsenic that pose long-term health risks, in general groundwater sources compare favourably
against surface water due to the reduced treatment needed. In the threatening areas of the
modern world, groundwater sources are far less vulnerable to terrorist attack than surface
water reservoirs, just as they were recognized as being less vulnerable to nuclear fallout
during the political atmosphere of the 1950s and 1960s.
Arguably, surface water and groundwater form a water resource field in any hydrologic
setting, and from a groundwater-biased view, surface water bodies are often simply points
where the water table rises above the surface. Thus impacts on one part of this continuum can
affect the other over time. However, the hydraulic connections between these two resources
can be obscure (at least superficially).
There are both Advantages and Disadvantage of Groundwater in comparision with surface
water source. They include the followings:
Advantages:
1. Groundwater is not easily contaminated as surface water
2. The quality of Groundwater, while not always as good as would be prefered, is stable
throughout the year.
3. Groundwater sources are generally lower in bateriological count than surface water.
4. Groundwater is available in most locations
Disadvantages:
1. Once Groundwater is contaminated, it is difficult to recover and there is not simple to
remove the contaminants.
2. Groundwater usually have more minerals than surface water including the increased
level of hardness.
3. Extraction of Groundwater normally requires a pump, thus increasing operational cost.
4. Groundwater is more suceptible to long term contamination from fuel spills.
5. Groundwater supplies often have iron and mangaese thus increasing treatment cost and/
or causing stains on plumings and clothings.
6. Wells in the coastal area are subjected to salt water intrusion . This phenomenon is
difficult to predict and costly to treat.
7. Source of contaminents can be hidden from sight.
Water suppliers need to recognize that a significant change in any of these parameters from
watershed activities can result in a range of problems, from aesthetic to human health
concerns. A summary of the water quality parameters, their possible source, and the potential
effect on water supply can be found in Table 4-1.
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Table 4-1: Water Quality Concerns
Parameter Sources Effects on water supplier
Solids, Domestic sewage, urban and agricultural Hinder water treatment process. Reduce
Turbidity runoff, construction activity, mining, soil treatment effectiveness. Shield
erosion microorganism against disinfectants.
Reduce reservoir capacity
Nutrients Septic system leachate, wastewater plant Nitrates that may be toxic to infants and
discharge, lawn and road runoff, animal unborn fetuses. Accelerates eutrophication:
feedlots, agricultural lands, eroded High levels of algae Dissolved oxygen
landscapes, landfill leachate, rainfall deficiencies Increase algae activity High
(especially nitrogen) colour and turbidity Disinfection by-
product formation Taste and odour
problems
Natural organic Naturally occurring; wetlands in the Influence nutrient availability Mobilize
matter (NOM) watershed tend to increase concentrations hydrophobic organics Disinfection by-
product formation
Synthetic Domestic and industrial activities, spills and Adverse impacts on human health and
organic carbon leaks, wastewater discharges, agricultural aquatic life
and urban runoff, leachate, wastewater
treatment and transmission
Coliform Domestic sewage from wastewater Fecal coliform are indicators of warm-
bacteria discharges, sewers, septic systems, urban blooded animal fecal contamination that
runoff, animal farms and grazing, waterfowl pose a threat to human health with
droppings, land application of animal wastes microbial pathogens like giardia,
cryptosporidium, and viruses
Metals Industrial activities and wastewater, runoff Adverse effect to aquatic life and public
health
Oil and grease Runoff containing kerosene, lubricating and Interfere with biological waste treatment
road oils from gas stations, industries, causing maintenance problems Interfere
domestic, commercial and institutional with aquatic life Aesthetic impacts Human
sewage, food waste and cooking oil health associated with selected
hydrocarbons
Sodium Road de-icing and salt storage High blood pressure and heart disease
Toxic Agriculture, lawn care, industrial sites, roads Toxic to humans and aquatic life
compounds and parking lots, wastewater
Aesthetic Taste and Odour: industrial chemicals, algae Aesthetic problems
elements metabolites, NOM, urea Colour: metals, Reduce public confidence in water supply
NOM, algae, AOC, Turbidity: solids and safety
algae, Staining: Metals
Algae Wastewater plant discharges, septic systems, Taste and odour Filter clogging Some
landfill leachate, urban and agricultural algae species toxic to aquatic life
runoff, precipitation
Dissolved Organic matter, wastewater discharges, Water treatment problems Release of iron
oxygen runoff, consumption by aerobic aquatic life and manganese Taste and odour problems
and chemical substances Ammonia
The principal requirements of drinking water are to protect the consumer health (free of
pathogens and toxic chemicals) and to make it acceptable to the consumer (aesthetic: sight,
taste, odour, and colour). In addition, water is treated for economic reasons such as preventing
scaling and corrosion in pipelines and staining clothes during laundering. In some cases it is
needed to make up deficiency in some quality in water such as adding oxygen by aeration.
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The choice of water treatment process depends on quality of the raw water in the source, its
variation, design period, required quality of treated water (end use) and economic resources
available for O&M. This is achieved by arranging a train of unit processes. The ultimate unit
process is disinfection and one of the purposes of prior stages of treatment is to ―prepare‖
water for disinfection.
Chlorine is the most commonly used disinfectant and unless turbidity and colour are removed
from the water, the efficiency of the disinfection may be impaired. High levels of turbidity
can also protect microorganism from the effect of chlorination and can simulate the re-growth
of bacteria in treatment works and the distribution systems.
Treatment must be both economical and reliable, requiring the optimum capital investment
and operation and maintenance. The relative merits of sources requiring much treatment
against the cost of long pipelines from a distant source demanding less treatment should be
weighed carefully in view of the constant attention required for the operation and maintenance
of a treatment plant.
It is important, therefore to select the source which requires the least treatment and the most
economical treatment processes. For small community water supplies, managed by
community, complicated treatment schemes are not suited. In such cases an alternative less
polluted source of water, even at a greater distance may be preferred. Design details of
various unit processes are explained in Chapter 5.
Factors that should be considered in decision making on water treatment processes include
• Level of contaminant removal/ specifications for treated water quality
• Raw water quality and its variations
• Relative costs of different treatment processes
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• Process applicability, flexibility and reliability
• Prevailing site conditions (land availability, accessibility, geographical conditions)
• Utility capabilities such as, degree of automation, extension of M&E Equipment
utilization and instrumentation, preference of mechanical solutions to hydraulic ones
• Appropriateness of the process for location based on availability of technical
resources, support services, and qualified personnel
• Affordability of capital investment costs and operation and maintenance expenses
• Possibility of future contamination and salinity intrusion
• Environmental compatibility and social acceptance
• Influence of national sanitation and pollution policies
The selection of water treatment methods that conform to the above-mentioned criteria does
not require the creation of new technologies, but rather the innovative application of proven
technologies.
Refer Figure 4-2 for filtration spectrum and approximate operational range of treatment
process. The applications of desalination technologies are given in Table 4-2 and refer section
7.6 for further details on membrane filtrations such as Reverse osmosis; Nanofiltration;
Ultrafiltration; and Microfiltration.
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Table 4-2: Applications of desalination/ membrane technologies
Source Technology
Seawater Distillation / Sea Water Reverse Osmosis
Brackish/Fresh Reverse Osmosis / Electrodialysis
Low salinity water (polishing) Ion exchange
Hard water Nanofiltration / ion exchange
Turbidity is caused by the presence of suspended matter such as clay, decaying vegetation,
algae etc in surface water. Removal of turbidity may be achieved by coagulation, flocculation,
sedimentation and rapid filtration or by biologically mediated slow sand filtration process.
Colour in raw waters is due mainly to organic matter originating from the decay of vegetation
into surface water. True colour and apparent colour are significant parameters in selecting the
treatment process. True colour is measured after filtration of water through a fine filter paper
and is, therefore, soluble or of a fine colloidal nature. Chemical coagulation is used to remove
the colour but the mechanisms and conditions are different from those for turbidity removal
relying more on precipitation and/or adsorption of colour compounds onto the surface of
flocs. Because colour is relatively non-biodegradable and of a soluble or fine-colloidal nature,
very little true colour is removed by slow sand filtration. Therefore, in the case of higher true
colour in the raw water, coagulation, flocculation, sedimentation and filtration is required.
Iron and manganese are leached out from soils, particularly by acidic waters, and are present
in solution or as complexes with organic material in the water. Iron can be precipitated and
removed under the same conditions required for colour removed by chemical coagulations.
Manganese remains soluble under these conditions. Effective precipitation can be brought
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about by a combination of increased pH and addition of oxidising agent (usually chlorine).
The precipitate is then removed in filters. Therefore, at least two stage of treatment, and in
many cases three stages, each at different pH, may be required: the first stage with chemical
coagulation (and sedimentation or floatation) for removal of colour, turbidity, and iron; the
second stage for removal of residual coagulant by rapid filtration; and the third stage, at a high
pH and with an oxidant, for manganese removal by high rate filtration.
Aeration may be used on surface waters to help remove tastes and odours due to dissolved
gases, or on groundwater supplies to reduce or remove objectionable amount of carbon
dioxide, hydrogen sulphide or methane and to introduce oxygen to assist in iron and
manganese removal. In surface waters with a high organic content aeration may also assist in
colour removal.
Microstrainer and Dissolved Air Floatation (DAF) are preferred in places where algae are
present in raw water. Powder Activated Carbon (PAC) is preferred for short occurrence of
taste and odour in water over Granular Activated Carbon (GAC) which requires pressurized
system (additional heads) at higher cost. Further, a provision of installing microstrainer and
GAC filtration for future implementation at least shall be economical in places where it is
susceptible for the occurrence of taste and odour.
When coagulant, pre-chlorine and PAC are planned to be used as chemicals, separate
requirements for contact time and adding sequence must be strictly defined and adhered to.
Recycling of waste water during water treatment may be preferred by depending on the
requirements and the situation. This can save water, pumping energy and chemicals especially
for low turbidity water. However, care must be taken to ensure that there are no harmful
materials such as mono-polymers in the recycled water especially when polymers are used as
coagulant aid and in the presence of algae in raw water.
The possible treatment stages including unit processes, chemical dosing points, wash water
recovery and sludge disposal are summarised in flow diagram showing possible treatment
stages in a conventional rapid filtration plant as shown in. The effectiveness of treatment
processes in removal of various impurities is shown in Table 4-4.
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Table 4-5 presents treatment options in a slightly different format with recommended process
for various levels of undesirable characteristics. Both Table 4-4 and Table 4-5 should be used
with caution since treatment effectiveness usually depends on a combination of unit process.
Figure 4-2 shows the approximate operational ranges of treatment processes with respect to
removal of particles of different sizes, and Figure 4-3,
Figure 4-4 and Figure 4-5 shows various unit processes required for groundwater, surface
water and brackish or sea water qualities.
coagulation and
Sedimentation
Chlorination
Flocculation
Rapid Sand
Slow Sand
Filtration
Filtration
Chemical
Aeration
Water Quality Characteristics
Engineers and water utilities today have many process options when water treatment plant
expansions or new water treatment plants are being planned. Although the increased number
of choices for water treatment processes will be beneficial for water utilities and for their
customers, the availability of more options complicates the decision making process and
forces everyone involved to think more carefully before selecting a water treatment process.
This situation will benefit water utilities and their customers in the long run, if choices are
made wisely.
Reverse osmosis has highest material rejection capacity (0.0001-0.001 m range) and mostly
used for desalination of seawater in drinking water supply. Nanofiltration (NF), ultrafiltration
(UF) and microfiltration (MF) are used for removal of particles, colour, NOMs and inorganic
and organic contaminants.
NF process (0.001-0.01 m range) is used for softening, and for removal of TDS and TOC.
UF is designated to remove colloidal sized particle (0.005-0.1 m range). Most turbidity
causing particle, viruses, and most organic substances (such as large molecular NOMs and
protein) are within the removal range of UF, MF (0.05-1 m range) is mostly used in pre-
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treatment prior to reverse osmosis process for rejecting suspended solids, large molecules, or
irons (refer Table 4-6).
To Supply
GAC Filtration
Settling
Wash water
Filters
Backwashing
Sludge
Settling / DAF
Supernatant water
Water Treatment Plant
Flocculation
PAC/ Polymer
Sludge
Mixing chamber
Coagulant dosing
Pre- settling tanks/ Sludge
Roughening Filters
Pre- chlorination
Aeration
Wash water
Micro strainers
Desilting
Decanter
Wash water Sludge
Fine screens Thickener
Source
Adapted from G. Smethurst, 1979 ―Basic Water Treatment For Application Worldwide‖.
Thomas Telford Limited, Mar 31, 1990.
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Table 4-5: Recommended Water Treatment Processes
Micros trainers
(Coarse/ Fine)
Ion Exchange
Chlorination/
Micro, Nano,
Chlorination
Chlorination
Chlorination
Storage/ De-
Desalination
Flocculation
Lime (Soda)
(PAC/GAC)
Roughening
Preliminary
Green Sand
coagulation
Raw Water
Settlement/
Membrane
Slow Sand
Oxidation
Flotation(
Screening
Filtration
Filtration
Filtration
Filtration
Activated
Filtration
Softening
Aeration
Carbon
Settling
and de-
Water Quality
(DAF)
Rapid
silting
Super
Ultra
Post-
(RO)
Pre-
and
Characteristics to be
reduced
Floating Debris E O
Algae # O O O O O E E
Turbidity
0 – 2 NTU O E O O E
2 – 30 NTU O O E E O E
30 – 100 NTU O O E E E O E
100 – 750 NTU E E E E E E
750 – 1000 NTU* E O E E E E E
> 1000 NTU* E O E E E E E
Colour
< 30 Hazen O O O O E
> 30 Hazen O E E E E
Taste and odour O O O O O
Hardness > 200 mg/L E O O
Iron and Manganese
Fe < 0.30 mg/L E O O E O E
Fe - 0.30 – 1.0 mg/L E O E E O O O E O O
Fe > 1.0 mg/L O E E E O E E O O
Chlorides
0 - 250 mg/L
> 250 mg/L E
Coliform bacteria
0 – 20 O O E
20 – 100 E O O E O E
100 – 5000 O E O O E O E
> 5000 E O E O O E E
Toxic Chemicals O E E E
TOC/ UV254 E O O O O O E
Legend: E = Essential, and O = Optional, Note: # = sonicator at intake is optional and * = Coagulant aids or polymers is optional
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Figure 4-2: Approximate Operational Ranges for Treatment Processes
Source: OSMONIC Inc., USA
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Shallow Groundwater (Aerobic Condition)
Aerobic, not Post-
corrosive water Chlorination
Bypass Options
Bypass Options
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Surface Water – Streams/River
Protected hill country Post-
streams turbidity < 2 NTU Chlorination
Bypass Options
Streams slightly turbid Roughening Slow Sand Post-
occasionally >2 NTU Filter (>10 NTU) Filtration Chlorination
or
Streams slightly polluted Infiltration Post-
turbidity occasionally > 2 NTU Gallery Chlorination
Bypass Options
Streams slightly polluted, Coagulation and Rapid
Sedimentation Post-
frequent high turbidity Flocculation Filtration Chlorination
and colour
Tanks or Lakes, canals slightly Micro- Oxidation Coagulation and Dissolved Rapid Post-
polluted, low turbidity and algae Filtration Flocculation Air Filtration Chlorination
Flotation
Figure 4-4: Treatment of Surface Water Sources for Various Water Qualities
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Table 4-6: Advanced Treatment Processes and its removal
Process Size/m What is removed
Reverse Osmosis (RO) 0.0001-0.001 Desalination of sea water
Nano filtration (NF) 0.001-0.01 Softening, removal of TDS and TOC
Ultra filtration (UF) 0.005-0.1 Colloidal sized particles, Most turbidity causing particle,
viruses, and most organic substances (such as large molecular
NOMs and protein)
Micro filtration (MF) 0.05-1 Mostly used in pre-treatment prior to reverse osmosis process
for rejecting suspended solids, molecules, or irons.
Although Seawater Reverse Osmosis (SWRO) technology has gained higher ground on water
desalination in recent years, operational cost is still high and not affordable for many
countries due to several factors. One important factor is membrane fouling which results in
both an increase in operational pressure and a short lifetime of the membrane elements and in
an increased number of chemical cleanings to restore membranes permeability. Membrane
fouling in SWRO can be caused by organic matter (lipids, proteins, and polysaccharides),
microorganisms (algae, plankton, and unicellular organisms), colloids and suspended solids,
salts and metal cations.
Gravity DMF
Flocculation Gravity
DMF
Coagulant
pH adjustment Post
Flocculation treatment
Pressure filter Pressure filter
MF/UF submerged
MF/UF Pressurised
Pre-coating
MF/UF Pressurised
Inline coagulation
MF/UF Pressurised
Figure 4-5: Treatment train of brackish or sea water for various water qualities
Seawater pretreatment is a key component to protect the membranes from fouling. The main
purpose of the pretreatment system is to remove particulate, colloidal, organic, mineral and
microbiological contaminants contained in the source seawater and to prevent their
accumulation on the downstream SWRO membranes. Mainly two types of pretreatment
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systems are typically used to protect seawater reverse osmosis membranes from fouling as
shown in
Figure 4-4 conventional granular media filtration and membrane filtration. While granular
media filtration is still a dominating seawater pretreatment technology, the use of Ultra-
Filtration (UF) pretreatment has undergone rapid growth during the past decade and will
continue to grow and may offer cost and performance benefits for the site specific conditions
and challenges of a given seawater desalination project. The choice of the approach is mainly
based on the parameters to be removed from seawater.
Each unit treatment process has a limited scale-down factor. If this limit is exceeded, the pilot
unit process will no longer simulate the full-scale process. Most scale-down limits have been
established empirically from previous pilot studies. For example, gravity filter operations can
be simulated using filter columns as small as 10 cm in diameter. However, backwashing
studies using the same size filter do not provide quality data. This is so primarily because the
excessive ratio of sidewall area to surface area creates friction between the media and
sidewall, short-circuiting wash-water.
Pilot plant design and operations should be kept as simple as possible. Pilot plants should be
operated manually to maintain control of the processes, to determine idiosyncrasies associated
with unit processes and individual equipment pieces, and to rectify small problems as they
occur. Problems not manually corrected could jeopardize the relevance of significant amounts
of data. For example, flow can be controlled using rate controllers and variable-speed drives
on pumps. With small flows, in-line flow meter accuracy can be off by as much as 25% or
more. Without a manual check of flow rate, all data collected would have a significant factor
of error that, if left unchecked, could result in a critical final design flow. Automatic data
collection is effective for establishing trends and monitoring operational and water quality
data during the absence of operators.
Pilot plant design and operations must also be flexible because these plants are used to
investigate the unknown and to stress the limits of a treatment process. During a study it is
common to change process variables and even to change processes themselves. Flexibility in
design allows the operator to quickly connect and disconnect unit processes or by-pass
processes. Modular design allows for complete processes to be quickly removed or inserted
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into the treatment train, reducing downtime. For example, if the pilot plant is not operational
for significant periods of time, specific water quality events important to the study might be
missed.
Although the pilot plant comprises the tools used in performing a study, it is the design of the
study that dictates many of the design characteristics of the pilot plant.
Engineers generally turn to pilot plant studies to compare alternative treatment processes
before design, construction, or plant modification. One significant advantage of using pilot
plant studies in new facility design is that pilot plants allow the engineers to use site-specific
design criteria rather than generic or rule-of-thumb conservative design criteria. This
advantage can result in significant cost savings without sacrificing treatment quality.
New treatment processes are usually investigated at the pilot scale to establish a success rate
before their recommendation. For example, the concern for controlling the formation of
disinfection by-products has led to using ozone as a pre-oxidant and disinfectant in place of
chlorine and chlorine dioxide. Pilot plants and pilot studies have allowed ozone to be
compared as an alternative oxidant and disinfectant. Ozone concentrations, contact times, and
dissolution techniques are investigated at the pilot scale and proved practical before full-scale
plant design is started. In many instances, pilot plant studies produce results that provide for
funding agencies the confidence to approve the use of new technologies and for client
confidence to accept them.
Pilot studies are often used to demonstrate treatment processes over extended periods and
under varying water quality conditions. Seasonal fluctuations due to lake turnover and algae
blooms in reservoirs, daily water quality changes in rivers due to biological respiration, runoff
events, and industrial discharges are some of the occurrences that can disrupt treatment
processes. If water sources are likely to experience any of these events, it may be necessary to
study their effects on various treatment processes for extended periods. Funding agencies may
require operating a pilot plant for a year or more before granting permission to use new
treatment technologies.
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isotherm may pass through the water at the intake level for short periods, causing wide swings
in pH, which may severely affect the coagulation process.
Another common use of pilot plant studies is to determine how best to correct full-scale unit
process problems without shutting down the full-scale process. Once the comparability
between the pilot plant process and the full-scale process has been established, individual
process parameters can be isolated and tested for comparison with the full-scale process. For
example, if floc carryover through a clarification tank is a problem, a pilot plant can be used
to test how the problem can best be alleviated by testing various combinations of coagulant
type and dosage, mixing times and energies, and flocculation time. Testing these variables on
a full plant basis can be dangerous in that some changes could result in complete failure of the
process or production of water of unsatisfactory quality.
Purpose of Bench-Scale Tests: In the absence of existing treatability data or treatment plant
operational data, bench-scale tests can be run to help the selection of the pilot-scale treatment
processes. Bench-scale tests are typically batch tests; the results are not capable of showing
dynamics found in the continuous flow process stream. Bench-scale tests can, however,
provide immediate and short-term results of significant value. Results from bench-scale tests
can also be incorporated into design criteria for the processes.
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Bench-scale tests are generally conducted concurrently with the pilot plant study to help
determine proper pilot plant protocols. Preliminary selection of treatment chemicals, mixing
times and energies, settling rates, flotation rates, and media selection can be estimated using
bench-scale tests.
Other types of bench-scale equipment are available to test for settling, carbon adsorption,
dissolved air flotation, and solids dewatering characteristics.
Bench-scale tests are generally conducted by adding various treatment chemicals directly to
the jars while mixing. Treatment chemicals can be prepared in advance and added by syringe
or pipette to the jar at the appropriate time. Rapid mixing is usually simulated for 0.5 to 1.0
min at full rpm. Flocculation can be simulated by varying the rpm from 80 to 20 over an
extended period typically from 5 to 20 min. The floc is then allowed to settle for 30 to 60 min
without mixing.
Samples are periodically collected from the sample tap on the jar to determine the settleability
of the floc. Floc suitable for conventional settling will readily settle in less than 5 min, or
sometimes even during the slow flocculation step. Floc suitable for flotation will remain
suspended for over 30 min. Pin-size floc suitable for direct filtration will be barely visible and
will remain suspended.
Samples collected from the jar after settling can be filtered through filter paper and analysed
for particulate removal and colour reduction. True colour can be used as a surrogate
measurement for natural organic matter reduction. If samples are to be analysed for total or
dissolved organic carbon reduction, glass fibre filters should be used so as not to contaminate
the samples with organic paper fibres.
Hydraulic Requirements: Several hydraulic concerns should be addressed before pilot plant
construction or installation. The first is where the source water should come from and how it
is to be supplied to the pilot plant. It is important that the source water supplied to the pilot
plant be representative of the water that will be used in the treatment plant being designed. In
many cases, providing a continuous supply of source water requires modifications to existing
structures or running a long length of pipe from the source to the pilot plant.
The method of disposal of both treated and untreated water from the pilot plant must also be
determined. It is often difficult to locate gravity drain lines from the pilot plant, and it may be
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necessary to arrange for a sump or collection tank with pumps to remove the wastewater to a
sewer or drain.
If possible, the pilot plant should be designed so that pumping will not be required between
the unit processes. In most cases, water being processed contains solids, and running the water
through a pump could change the characteristics of the solids. This could have a significant
adverse impact on pilot plant results. In addition, every pump introduces another potential
source of failure. Staged platforms are usually used to support tanks and other hydraulic
structures so that flow is by gravity and the number of pumps is kept to a minimum.
Space Requirements: The pilot plant study often is required to be done adjacent to the water
supply source. Operating full-scale water treatment plants are often the location for pilot plant
studies. These facilities may or may not have the space to accommodate a pilot plant. If the
pilot plant size excludes its location from within the existing buildings, temporary housing
may be required. Tractor-trailer-mounted units may become attractive in the absence of
existing housing.
Water tanks associated with larger flows and storage requirements may present a structural
issue associated with floor loading capacities. Clearance associated with taller components
such as filters, contactors, and sedimentation processes may restrict their location or use.
Underestimating the space requirements for a pilot study can cause delay and extra costs.
Careful planning and coordination with the end user are required for a successful study.
Electric Power Requirements: The electrical loads required by the pilot plant must be
determined in advance to avoid on-site problems and delays. The total electrical draw
(amperes) and voltage requirements must be compared with available on-site electrical
facilities. If special electrical work is required to supply power to the pilot plant, it may be
necessary to obtain a local permit and hire a licensed electrician. One way of minimizing
outside labour charges for electrical work is to provide a power panel with the pilot plant
prewired to all electrical equipment. In this way, it is necessary to provide only a single
source of power to the panel at the site.
Pilot plants designed for overseas installation will probably require special consideration of
the electrical design. The voltage and hertz of power available differ from country to country,
and it may be necessary to provide a transformer as part of the pilot plant equipment package.
The approach to permanent pilot plant construction differs significantly from temporary plant
construction. Permanent pilot plants have to meet local building, plumbing, electrical, and fire
codes. In addition, bidding laws may require extensive engineering services to provide design
drawings and specifications before bids can be taken and the plant constructed.
In locating a permanent pilot plant, it is extremely important to identify the area and height
requirements, source water and drainage availability, and electrical requirements. For
instance, laying pipes along the floor surface is not usually acceptable for permanent
applications. Any changes to the main treatment plant facility to accommodate the pilot plant
should be determined to be part of the pilot plant cost.
Temporary pilot plants offer the owner the same opportunities to test treatment options, but
usually at a fraction of the cost of building a permanent installation. Temporary pilot plants
can be constructed in many ways. Modular pilot plants are gaining in popularity and make it
easy for vendors to move their equipment from one site to another. Start-up time is reduced
because the intricate connections move with the plant. The only on-site work is limited to
source water piping, electrical supply modifications, drainage piping, and process-to-process
piping.
The customer or user can lease or rent the equipment for the time necessary to perform the
evaluations, and when the tests are completed, the equipment can be removed and the area
where it was located can be returned to its previous condition. Also, the use of modular plants
more readily allows for process changes during the study compared with permanent
installations.
The use of modular equipment reduces the installation and start-up effort but does not
eliminate it entirely. Site-specific constraints and minor process modifications can have major
impacts. The use of equipment from different vendors, equipment built in different countries,
and different construction materials, flow requirements, system pressures, and electrical
demands are some of the problems that can cause installation nightmares.
Start-up time should include time for troubleshooting and repairs. The shipping of equipment
often produces some form of damage as well. Long periods of non-use can have an adverse
impact on equipment. Whenever possible, the people who are designated to operate the pilot
plant should help with the installation and start-up. The manufacturer or the contractors who
install the plant often know the strengths and weaknesses of the equipment and materials that
are provided, and this information can be valuable to the operator.
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Operations and maintenance manuals for each piece of equipment and unit process should be
available to the user for proper start-up, and these should be studied by the operators during
the installation and start-up. Once the study has begun, time is usually limited and operators
may not take the time to learn how to properly maintain the equipment.
Each unit process should be independently tested for proper hydraulic, electrical, and
mechanical function before testing the entire process train. Once all connections have been
made, the entire system can be hydraulically tested by passing source water through it. Each
chemical feed system should be calibrated under the flow and pressure conditions likely to be
experienced before start-up, and preliminary jar tests can be conducted before start-up to
identify likely chemical selections and dosages.
Consideration must also be given to the experience level of the installers and operator because
this will affect the time of installation and start-up. When one is hiring engineers or
contractors for the design, construction, and installation of a pilot plant, their experience with
similar projects should be investigated before awarding the contract. Selection of the lowest
bid with least experience can spell disaster in the long run.
Hazards and hazardous events from the catchment to consumer needs to be defined ; identify
all hazardous events that could contaminate, compromise or interrupt supply; identify all
potential hazards in supply chain; Evaluate the risks associated with each hazard/ hazardous
event. These are based on site visits or inspection, and desk studies using historical data (e.g.
flood events), and predictive information. The risks are assessed both by qualitative approach
and Semi-quantitative approach (likelihood and consequence in risk).
WSP describes the existing and potential control measures, assess the effectiveness of control
measures (validation); recalculate the risks accounting for existing control measures and
prioritize risks in the catchment. An improvement/upgrade plan is given in WSP by
prioritized action for each uncontrolled or ineffectively controlled risk. It includes
implementation of short-, medium- and long-term activities. It maximizes effectiveness of
resources.
Water suppliers may benefit from reduced costs through reducing or eliminating any
unnecessary monitoring and testing, reducing the need for treatment or improving
maintenance. Other benefits include improved communication/ stakeholder relationships,
improved management and operation of the water supply system and more effective
coordination of the procedures. Therefore, pollution prevention is emphasised before the
treatment.
Although water safety plan is an operational process, a WTP designer can proactively develop
a WSP with the potential operational staff to improve the functioning and operational
monitoring of the WTP. Basically the WTP designer shall realise that a WTP itself is a control
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measure considering multiple barriers to pollution risk control in WSP terminology. Further,
the designer shall concentrate on disaster risks and climate change related risks in order to
comply climate resilience under WSP.
It reviews a raw water source‘s features for the purposes of preventing potential
contamination or water quality degradation. Sanitary surveys will identify deficiencies in
water systems and it will require treatment technology based on evaluation of sanitary survey.
Depending on susceptibility of individual sources, up to 4-log treatment inactivation of
viruses may be required. The designer may use a sanitary survey to understand the existing
source wataer conditions.
Direct river abstraction does not allow much scope independently for the WTP designer for
source management, although there are measures that can be taken to protect intakes from the
effects of short term pollution.
The majority of surface water supplies are derived from reservoirs, and efficient management
of the catchment and the reservoir itself can ensure maintenance of the quality.
The most significant risk to reservoirs comes from farming activities and, particularly in
upland areas, from forestry. Close liaison between authorities concerned with water supply,
pollution control, agriculture and forestry is vital for protection of water sources. Forestry can
lead to increased acidity, aluminium and solids concentrations in upland rivers and reservoirs.
Use of pesticides and fertilizers can have detrimental effects on water quality, particularly in
low land areas where use of fertilisers can cause problem of excessive algal growth in
reservoirs, resulting in treatment problems.
The water and forestry industries have to prepare guideline for forestry working practice to
minimise impact on water supplies. These include the following:
Avoid deforestation of areas adjacent to streams and rivers for a suitable distance on
either side. This area should be left to natural vegetation and wildlife
Designing drainage channels and access roads to avoid excessive erosion and high
runoff rates, thus minimising discharge of sediments and other postulants
Consultation with water undertakings over forest planning, and the use of fertilizers
and pesticides
Provision of emergency telephone numbers to allow forestry managers to contact
water undertakings
River sources are particularly susceptible to risk of pollution by spillage from industries.
Liaison with police and fire services can minimise the risk.
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Catchment control measures in relation to agricultural practices can play a major role in
management of cryptosporidium risk the storage, disposal and use of animal manures to
prevent contamination of intakes and boreholes are of particular importance.
The WSP will provide a catchment improvements and management plans as output control
measures and this has to be implemented with the active participation of all relevant
stakeholders. The district Water Quality Surveillance Committee is a proven mechanism in
implementing WSP.
Improvements to the catchment area could apply the multi-stage barriers approach that
usually includes:
• Selection of the best available source
• Protection of that source with management control barrier
• Flocculation and sedimentation barrier
• Filtration barrier and disinfection barrier
The multi-stage barrier options following source selection and protection can vary with the
availability of financial and technical resources. Inexpensive mitigation measures might
incorporate physical barriers, such as fences, that limit the people and livestock that have
direct access to the surface water, and reeds or foliage that act as a natural barrier and filter to
particulate matter that is carried into the surface source through runoff. Natural plant barriers
such as thorn bushes can be formed around basins to conceal and break wind effect and limit
uncontrolled access to the surface water. In addition, the intake location and design can help
to reduce the turbidity.
a) Provision of backside storage; even one or two day‘s storage can be adequate to allow
short-term pollution to pass the intake. Dividing walls of baffles should be installed to
minimise short-circuiting, a common problems in small storage reservoirs.
b) Floating booms to prevent ingress of oil and floating debris.
c) A monitoring and sampling programme at a sufficient distance upstream of the intake to
give ample time for action. It is ideal of an upstream intake in the same stream / river that
could be used as sampling and warning. A wide range of automatic continuous monitors
are now available, including fish monitors for detection of general pollution. Good
communication with the emergency services is also important.
d) Relocation of the existing intake upstream of high-risk areas (e.g. location prone to
landslides, settlements etc.)
e) Diverting any pollution canal, stream etc., to downstream of the water intake.
f) Provision for accessibility for cleaning purpose and protections against crocodile, elephant
etc.,
g) Verbaties, Zebra mussel impacts may need to be addressed in some regions.
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h) Fish protection is an especially important design consideration
i) Design challenges applicable to most regions include flotation, geotechnical, mechanical
and chemical treatment considerations.
Design of intake systems may affect aquatic organisms present in the river, lake, or reservoir.
Fish protection is a significant design element in some areas. Three basic types of devices
used to prevent juvenile fish from entering flow diversions are (1) physical barrier screens, (2)
behavioural guidance systems, and (3) capture and release systems. The most widely accepted
and successful method of protecting juvenile salmonid passage is to use physical barriers.
When one is designing a juvenile fish screen, the swimming ability of the species and the life
stage targeted for protection should be considered.
An effective approach for fish protection, which also minimizes the introduction of other
contaminants, is to use low entrance velocities. The flow should approach the screen in a
laminar mode. A screen can be placed on the end of the pump intake in a pressurized system.
Cleaning of pump intake screens can be accomplished using fixed spray bar with rotating
screen, fixed screen with rotating bar, or internal airburst systems.
A positive method to reduce fish entry into submerged intake facilities is the velocity cap.
Figure 4-6 illustrates a horizontal cap on the top of the intake structure, which forces all water
to enter horizontally. Fish tend to swim against horizontal currents and avoid the intake which
is not possible in a vertical entry.
The installation of stainless steel T screens on each of the intake caissons (Figure 4-6) can
protect fish in direct intake. The intake T screens are over 3.0 m long and sized to meet 12.2
cm/s approach velocity requirements for salmonid fish protection, each Screen openings are
0.069 in. (1.75 mm). 10.2-atm airburst cleaning system can be actuated by head loss across
the screens, timed cycle, or manual operation.
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Dilution of occasional pollutants
Reduction in concentrations of pathogenic organism
These benefits rely on good reservoir construction and operation. For example, short-
circuiting can be overcome by careful sitting of inlet and outlet, by the installation of walls or
baffles, or by mixing using aerators.
However, it must be noted that before deciding the control technique applied, the designers
have to collect related information of the water source and to understand hydrology, water
quality and pollution reasons before developing control measures.
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CHAPTER 5
This chapter covers only the conventional unit processes from aeration to filtration including
screening. For chemical feeding and disinfection, refer CHAPTER 6 and for other unit
processes including advanced treatment processes refer CHAPTER 7.
Traditional treatment engineering has focused on the treatment plant as the sole vehicle for
controlling drinking water quality. The engineer's role was to characterize the quality of the
source water entering the plant and devise treatment facilities to produce water meeting
drinking water standards. The point of measurement for drinking water standards was the
finished treated water exiting the plant. Today's engineer must view the water treatment plant
as only a major component in a multistep treatment process. This process includes
consideration of the path that the water travels upstream of the plant in the watershed and the
elements of the water transmission and distribution system downstream of the plant. Changing
water quality must be managed in each of these steps, and new regulations require that
drinking water standards be met at the customer's tap.
5.1. Intake
Raw water intake structures are used to control extraction of raw water from surface water
sources. Their main objective is to extract the best quality water so that fish, floating debris,
coarse sediment and other harmful suspended matter can not enter in to the plant. These
structures may be simple submerged intake pipes or elaborate tower like structures that house
intake gates, screens, control valves, pumps, chemical feeders, flow meters, etc. These may be
an integral part of a dam or a separate structure located elsewhere. There are several types of
intakes such as floating intakes, submerged intakes, tower intakes, shore intakes, pier intake,
etc. Engineers must carefully study various factors in selection of a location for a raw water
intake. These factors includes water quality, water depth, stream or current velocities,
foundation stability, easy access, availability of power, distance to the water treatment plant,
obstruction to navigation and environmental impacts, etc.
The design of a water intake is generally a site specific and a standard design cannot be
adopted for a given site without further modifications. (Refer D2 Manual for more details).
The following are to be considered in order to improve the quality of water entering in to the
water treatment plant.
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5.1.1.1. Floating Oil Boom
The following main methods of combating an oil spill can adapted:
mechanical recovery;
dispersant use;
in-situ burning;
Mechanical containment and recovery of oil is the most desirable option (eg.using absorbing
pads). Booms are used for containment, and skimmers are used to recover oil from the water
surface. Natural or induced agitation of water causes dispersion of oil into the water column.
Dispersants are mixtures of surfactants in one or more solvents, specifically formulated to
enhance the rate of this natural process. In-situ burning has the advantage that it rapidly
removes large volumes. However, it poses fire hazards, and has limitations when the
thickness of the oil slick is less than 2 mm. Emulsions burn poorly, if at all. Floating oil boom
is a successful method of preventing floating oil entering in to water intake in river or lake.
Boom barriers are used to contain and control floating debris such as floating timber, logs,
rubbish, garbage, hyacinth, duckweed, and sargassum. Floating debris barriers can be used for
demarcation, floating trash containment, seaweed control, or for aquatic plant control such as
for a deep debris boom that could be placed in front of a river intake structure.
Floating booms could be made out of bamboo or polyethylene material. The design of a
floating could be solid of inflatable. The NWSDB practice so far is solid type floating booms.
The Figure 5-1 shows some designs for floating booms. However, in practice NWSDB has
been using very simple means of floating booms in the form of floating pipes. NWSDB is
getting assistance from SLRDC and Sri Lanka Navy for the construction of floating booms at
major river intakes.
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a) A solid flotation curtain bloom with external ballast b) An external flotation fence bloom with external
flotation and ballast. Anchoring points are located at
intervals along its lower length.
c) An inflammable curtain bloom with a combined d) Intertidal shore bloom. Upper air inflation pocket
ballast and tension chain fitted in an integral pocket to allow flotation, lower water filled pocket to provide
attached to the bottom of the skirt. ballast when floating and to ensure a good seal with
substrate at low tide.
Figure 5-1: Some designs for floating booms
Figure 5-2: Floating booms at Ambathale intake for debris and oil control
The sea level fluctuation with the tidal effect is a well-known phenomenon. Salinity intrusion
due to tidal effects at the intake of the water treatment plant in Ambathale is being handled by
means of a practical approach. The river flow conditions are predicted using international
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tidal charts and managed by release of water from upstream Castlereigh and Maussakele
reservoirs built for power generation. A temporary sand bag barrier is also built across the
river in management of this event during February to March each year. The Low and High
tide level in Colombo during a week is shown in Figure 5-3.
Figure 5-3: Low and High tide level in Colombo during a week
Reference: https://www.tide-forecast.com/locations/Colombo-Sri-Lanka/tides/latest
Tides are formed due to gravitational forces between the earth and the moon while moon
moving around the earth. Different scenarios of tide formation are detailed in Figure 5-4.
Spring tides are especially strong tides (nothing to do with the season ―Spring‖). They occur
when the Earth, the Sun and the Moon are in line. The gravitational forces of the Moon and
the Sun both contribute to the tides. Spring tides occur during the full moon and the new
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moon. The Proxigean Spring Tide is a rare, unusually high tide. This very high tide occurs
when the moon is both unusually close to the Earth (at its closest perigee, called the proxigee)
and in the New Moon phase (when the Moon is between the Sun and the Earth). The
proxigean spring tide occurs at most once every 1.5 years.
The Neap tides are especially weak tides. They occur when the gravitational forces of the
Moon and the Sun are perpendicular to one another (with respect to the Earth). Neap tides
occur during quarter moons. The tidal variations control the sea water level on a monthly
cyclic manner. The climate change effects add on to the long-term sea level rise. The
prediction of sea level rise for Sri Lanka is 0.5m for 2100. Annual tidal predictions are
published by National Oceanic and Atmospheric Administration (NOAA).
The tidal effect on raw water quality is very high during drought time. For example, the tidal
effect is critical for Kelani River from February to March during past few years. The tidal
effect is predicted from the chart published for each year. The temporary salinity barrier at the
Ambathale intake is built and maintained based on this tidal level observation during the
period from February to March each year in the recent past. Although the width of the river at
Kelani River is suitable for building a temporary sand bag barrier, the Kethhena intake at
Kaluganga is suffering from the salinity intrusion due to incapability of having such salinity
barrier across the river due to practical difficulties. Accordingly, the consumers of Kaluthara
water supply scheme receive salty water during February to April each year. Each year the
salinity barrier using sand bag at Ambathale is built under a contract (refer Figure 5-5). It is
topped up after each flood event and removed with the help of Sri Lanka Navy during major
floods.
The Wee oya storage tank in the Kelani Catchment is proposed to store fresh water for use
during the drought period. However, proposal to use Wee Oya water for flushing the salinity
wedge during February to April period by the Department of Irrigation remains questionable
due to water balance problems and climate predictions on sea level rise for the next 100 years.
A gate structure is available to maintain the river flow towards the downstream along with
flushing of the salinity through the gate.
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walls and prevents the algae from floating up to the surface, reducing biomass along with the
presence of toxins and geosmins in water.
The ultrasonic algae control devices emit specific ultrasonic waves in order to control algae
and biofouling in lakes, reservoirs, and industrial applications.
It uses scientifically proven ultrasonic frequencies to control many types of algae. A very
common differentiation is between green algae and toxic cyanobacteria, which are also known
as blue-green algae. Blue-green algae and some green algae are capable of travelling through
the water vertically due to their possession of gas vesicles. The ultrasonic sound waves create
an ultrasonic pressure in the top layer of the water. This ultrasonic sound barrier prevents the
algae from rising to the surface and absorbing light for photosynthesis. Therefore, algae are
no longer capable of growing further. The algae will die while the cell wall remains intact,
preventing the release of toxins from the algae into the water. The algae will sink to the
bottom of the water reservoir and are degraded by the bacteria present.
The control of algae by ultra sound waves reduces the undesirable taste and odour causing
compounds in the treated water delivered to the customers as shown in Figure 5-6.
The effects of these ultrasonic algae control products have been tested by various universities
and are proven to be safe for fish, plants, zooplankton, and insects. The University of
Portsmouth, UK; UNICET Catania, Italy; and BOKU, Austria found that LG Sonic units are
safe for fish. The devices have been tested on their effect on zooplankton, and no negative
effect was found. The products are not based on cavitation, which is a phenomenon where
high-power ultrasound causes the formation of micro-bubbles that implode, causing intense
heat pressure. These processes can destroy cells and might harm fish and plants.
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“E-line” for range up to 200 m
The ―LG Sonic e-line‖ has 12 ultrasonic programs to effectively control different types of
algae. Each program contains different types of ultrasonic parameters, such as frequency,
amplitude, waveform and signal duration. The ―LG Sonic e-line‖ can efficiently control algae
up to 200 meter per device with a power consumption of just 5-40 Watt.
Figure 5-7: The “LG Sonic e-line” for control algae up to 200 meter
Figure 5-8: “MPC Buoy” Solar powered algae control with online water quality
monitoring (Range 500m)
This solution is to anchor one or multiple MPC-Buoy systems that transmit specific ultrasonic
parameters depending on the type of algae. Each device can control algae in areas up to 500m
in diameter.
The ―MPC-Buoy‖ provides a complete overview of the water quality by collecting the
following parameters every 10 minutes: Chlorophyll α (green algae), Phycocyanin (blue-
green algae), pH, Turbidity, Dissolved Oxygen, and Temperature. The collected data is
delivered in real time via radio, GPRS, or 3G to a web-based software. Based on the
developed algorithm the manufacturer can modify the ultrasonic program to the specific water
conditions and predict an algal blooms a few days ahead. Based on the received information,
the ultrasonic program can be activated according to the water conditions and type of algae
present. This way, it is possible to eliminate existing algae and prevent the growth of new
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 5-7
algae. The system is capable to change for 12 ultrasonic programs to suit for algae type and
water quality available in the field.
―LG Sonic‖ has integrated the satellite remote sensing technology to accurately map the
spatial and temporal distribution of the water quality parameters to generate a complete
overview of the algae distribution in large water bodies.
A main cause of the problem due to accumulation of sediments is the highly variable flow
pattern of the rivers varying between very low (low flow) and very high (flash floods) during
a season. Figure 5-10 shows patterns of sediment deposition and scouring at intake
structures.
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The problem of sedimentation at water intakes on rivers can largely be eliminated or
minimized by appropriate design of the civil structures around the intakes. This needs to be
done with due consideration of the local morphological and hydraulic conditions. Even the
application of sound engineering design practice cannot always overcome all sedimentation
problems of such smaller intakes for all flow patterns.
In spite of available sound engineering practices and because of the fact that each intake
normally has unique, complex flow characteristics, it is generally advisable to verify each
design of an intake in a laboratory by means of a hydraulic model, provided the size of the
intake warrant the cost of a model study.
There are two locations of sediment deposition at an intake. One is at the main intake point at
river and the other is at the wet well. De-silting at the main river can be done by dredging or
pumping. Most significant location is the bottom of the wet well. Sediment at the wet well can
be removed by using silt pumps. However, while controlling the sediment at the main intake
point at the river, it will control the sedimentation at the wet well.
The principle of sediment rejection which is the upper layers of the flow are allowed to enter
the intake, the lower layers are kept from entering the intake and conveyed towards
downstream with the remaining river flow can be used to control the sedimentation at the
river intake point. For this method, various kinds of submerged sills and bars are used to keep
the sediment away from entering the intake.
In all cases of sediment removal including discharging back into rivers, all relevant legislation
must be taken into consideration. Environmental Impact Assessment (EIA) procedure would
be to approach for a permit to allow the planned operations. Based on the degree of
environmental sensitivity of each case, would be able to indicate if an environmental impact
assessment is required before a permit can be issued.
There are many types of screens that can be used in water treatment processes and this can be
classified as shown in Table 5-1. Furthermore, the following configurations are also
available:
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1. Bar or rack screens: Bar screens comprised of parallel bars, usually vertical or inclined;
2. Mesh screens: Mesh screens comprised of a fabric with mesh size depending on floating
and suspended matter.
3. Band screens: Consists of a perforated belt passing over an upper and lower rollers;
4. Perforated plate screen: Consists of a fixed band of perforated screens;
5. Grating screens: Consists of two sets of parallel bars;
Bar screens are very simple arrangements and used in many water supply schemes in Sri
Lanka. There are mainly two types depending upon its movement. One is removable type and
other is fixed type. The removable type bar screens are operated by means of guides installed
on the sidewalls of the concrete structure. A lifting beam is used to raise or lower the bar
screen. The segments are manually cleaned after raising it to the operating floor. The fixed
type bar screens are installed on the concrete structure by bolting or grouting. They are
cleaned by bar screen cleaning equipment.
5.1.5.2.Fine Screen
Fine bar screens are similar to coarse screen with closer bar spacing (5 to 20mm) and often
placed just after a coarse screen (see Figure 5-11). The approach flow rate to the screen
should not exceed 1.4 m/s to avoid drawing in fish and small objects. Duplicate screens are
provided to allow the removal of one screen for cleaning manually.
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Angle of Inclination 10-30° to the vertical
Head loss through a screen may be estimated by the following formula:
( )
Where h = head loss (m)
V = velocity through the screen (m/s)
U = velocity before the screen (m/s)
Under the normal circumstances, the crossing velocity through the screen should be sufficient
for matter to attach itself to the screen without producing a loss of head or a complete
clogging of the screen or allowing matter not to be carried by the flow.
Coarse bar screen Lifting hook Fine mesh/grading screen
Perforated plate
Side wall
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5.1.5.3.Micro-strainer
Microstrainer is a special category of fine screen used for removal of finer solids from raw
water by passage through a fabric of either fine steel mesh or plastic cloth fixed over a
cylindrical support frame as shown in Figure 5-13. The removal mechanism is based upon the
size of the opening in the fabric. Depending on the size of the aperture in the fabric, it behaves
either as a filter to remove the coarse turbidity, zooplankton, algae, etc. or as a fine screen to
remove larger particles.
Water jet
Overflow weirs (Continuous)
Combined main
(shaft & wash pipe
Rotation (linear
velocity 0.25 m/s
The head loss, which is proportionate to the quantity of suspended substance in raw water,
indicate the removal effect and the appropriateness of operational factors of the system
(filtration speed, drum‘s peripheral speed, filter net characters and washing effect) and used as
a general index for running the system. Where substances caught by the filter net form film,
substances that are smaller than the filter net are also caught and thereby the removal ratio is
increased. The removal ratio is generally increased as the head loss reaches a certain point and
is reduced afterwards.
The drop in removal ratio occurs because part of deposited substances that stand, increase in
water pressure through the mesh. Therefore when selecting and designing microstrainers, the
mesh size is selected and the effective filtration bed area is estimated by measuring the size,
condition and quality of organisms in raw water, and decision is made by pilot plant study
(See Table 5-2).
Since the material and mesh size govern the removal effect, the filter nets are selected
according to raw water and target substances are to be removed. The synthetic fibres nets (e.g.
nylon) and have high chemical resistance, relatively low price. On the other hand, they require
reinforcement by pilot nets due to relatively lower mechanical strength.
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Table 5-2: Standard Treated Water Quantity and Microstrainer Size
Rotary drum 1,500 2,000 2,000
35x 500x 700x 900x 1,200x 2,800x 2,800x
(diameter x x x x
300 700 900 1,200 1,500 3,600 4,000
length) 2,000 2,400 3,000
Filtration rate Treated amount (m3/d)
0.5 m/min 150 500 850 1,460 2,440 4,060 6,520 8,120 13,690 12,200
13,04 16,24
1.0 m/min 300 1,000 1,750 2,290 4,880 8,130 27,380 30,410
0 0
12,20 19,56 24,36
1.5 m/min 450 1,500 2,561 4,390 7,320 41,080 45,610
0 0 0
24,41 39,13 48,72
3.0 m/min 900 3,000 5,130 8,780 14,640 82,160 91,230
0 0 0
Rotary drum 1,500 2,000 2,000
35x 500x 700x 900x 1,200x 2,800x 2,800x
(diameter x x x x
300 700 900 1,200 1,500 3,600 4,000
length) 2,000 2,400 3,000
Filtration Bed
0.21 0.70 1.98 3.39 5.65 9.42 15.1 18.8 31.7 35.2
area (m2)
Circuit Speed
3.5- 5.5- 5.2- 5.3- 5.3- 5.3- 8.2- 8.2- 7.6- 7.6-
(m/min) -50
14.2 22.0 20.9 21.0 21.0 21.2 32.0 32.6 30.5 30.5
HZ
Washing
water volume 0.036 0.06 0.07 0.11 0.12 0.18 0.26 0.33 0.39 0.43
(m3/min)
Washing
Pressure 0.196 0.196 0.196 0.196 0.196 0.196 0.196 0.196 0.196 0.196
(MPa)
Motor Output
0.4 0.4 0.75 0.75 0.75 1.5 2.2 2.2 3.7 3.7
(kW)
The effectiveness of a microstrainer in removal of solids depends upon the mesh size and on
the material that forms the filter mesh. In addition, the performance is also based on the
operating factors such as hydraulic loading rate, requirement for cleaning, and maintenance
factors. For the determination of the appropriate material, size of the strainer, and hydraulic
loading rate, pilot testing is recommended. Cleaning and maintenance requirement must be
evaluated after careful review of the operation and performance of full scale installations.
The washing water pressure for filter is around 0.20 MPa in standard, but the washing effect
differs by the type of suspended substances. However, a minimum washing water pressure is
maintained unless the head loss is increased due to imperfect washing. Since the washing
water volume differs by microstrainer size, filtration speed and revolution, the necessary
water volume is secured by referring to Table 5-2. The specification for the micro-strainer
filter mesh is given in Table 5-3.
In many cases, microstrainers are intermittently employed according to the seasonal growth of
organism and ventilation for drying of filter mesh to be allowed in indoor installations. Scour
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line to empty the basin for maintenance and repairs and provision of cranes is desirable to
facilitate maintenance.
5.1.6. Disposal of Screenings
Screenings is the waste materials collected from screens. Screenings should be properly
disposed. Various methods of screening disposals are used such as:
Burning
burying
digestion
dumping into large bodies of water
Shredding and returning it to wastewater collection or treatment system
Screenings inside the plants are handled by either manually in small facilities, or
mechanically through conveyer belt. Because of transportation and environmental constrains,
drying or compacting treatment have been given increased consideration. Inland burying is
efficient in small treatment plants, while burning is best for medium and large treatment
plants. Other methods cause problems and may need subsequent treatment. Digestion is used
for large systems and in combination with the treatment of the organic portion of municipal
solid waste.
5.2. Pre-Treatment
5.2.1. Pre-oxidation
Preoxidation is commonly used for biological growth control through treatment plant source
water piping and structures, Oxidation-reduction (redox) reactions form the basis for many
water treatment processes addressing a wide range of water quality objectives. These may
include removal of iron, manganese, sulphur, colour, tastes, odour, and synthetic organics
(herbicides and pesticides). A redox reaction consists of two half-reactions: the oxidation
reaction, in which a substance loses, or donates, electrons; and the reduction reaction, in
which a substance gains, or accepts, electrons. An oxidation reaction and a reduction reaction
must always be coupled because free electrons cannot exist in solution and electrons must be
conserved. Iron and Manganese removal and taste and odour control are discussed in chapter
7.
5.2.2. Pre-sedimentation
Presedimentation is used primarily by those plants treating high-turbidity surface waters,
especially rivers. Some of these plants use metal salt or polymer coagulants to enhance
suspended-solids removal. Presedimentation provides a more uniform water quality at the
treatment plant, removes a major portion of the suspended solids with little chemical cost, and
offers potential cost savings in residuals treatment and disposal. Presedimentation also
provides an opportunity for pretreatment and removal of tastes and odours and other organic
compounds with powdered activated carbon and oxidizing agents before the elevated pH
associated with the softening process. In some cases, this provides more efficient and
effective treatment.
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The AWWA standard for PAC specifies a minimum iodine number of 500. Higher iodine
numbers indicate greater absorbency
Higher molasses numbers indicate greater absorbency
Moisture content should be minimized and should not exceed 8%
AWWA standard specifies a minimum apparent density of 0.25 g/cm3
Ash content, which is an impurity that reduces adsorptive capacity, should be minimized
Smaller PAC particles adsorb organic compounds more rapidly than larger particles, so
PAC is manufactured as a very fine powder. Typically, 65% to 95% of commercially
available PAC passes through a 325-mesh (44-m) sieve.
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PAC is increasingly being used in conjunction with microfiltration or ultrafiltration membrane
systems. Not all membrane filtration products are compatible with PAC so the types of PAC
that can be used may be limited. Therefore, it is vital that the use of PAC be discussed with
the membrane filtration supplier when considering this application. PAC dosage depends on
the type and concentration of organic compounds present. Common dosages range from 2 to
20 mg/L for nominal taste and odour control, but doses can exceed 100 mg/L to handle severe
taste and odour episodes or spills of organic chemicals.
5.2.4. Control of pH
Control of pH and alkalinity is an essential aspect of coagulation. The optimum pH for
coagulation varies but is generally within the following ranges for turbidity removal:
• Alum: pH 5.5 to 7.5; typical pH 7.0
• Ferric salts: pH 5.0 to 8.5; typical pH 7.5
It can be necessary to adjust the pH of some source waters to achieve optimum coagulation.
The pH is often lowered by adding carbon dioxide or an acid. Alum and ferric chloride
consume alkalinity and can lower pH; however, reducing pH by adding more chemical than is
required for coagulation should be avoided as it increases overall chemical costs and sludge
production/costs. In some source waters with low pH or low alkalinity, it may be necessary to
add caustic soda or lime to raise pH and to offset the acidity of metal-ion coagulants, even in
an enhanced coagulation mode of operation.
For waters that require enhanced coagulation to remove organic matter, the pH of coagulation
should be lowered as compared to coagulation for turbidity removal only. Typically, the
optimum pH for organics removal with alum is between 6.0 and 6.5, and between 5.5 and 6.0
for ferric coagulants. Often, polyaluminum chloride can provide organics removal without as
significant a decrease in pH.
There are a number of secondary impacts of utilizing the higher coagulant dosages and lower
pH values for enhanced coagulation. A few of these impacts include the following:
Increased solids. The higher coagulant dosages directly result in increased sludge volumes.
Increased concrete-metal corrosion. The lower pH of the coagulated water for TOC removal
will be significantly more aggressive on concrete and metals as compared to the more neutral
pH of water that has been coagulated for turbidity removal.
For plants where only a small increase in pH is required, liquid caustic soda is most
commonly used because of its ease of handling. When a large increase in pH is required, lime
is normally the most economical choice. Lime, however, may add turbidity to finished water;
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therefore, if lime is used for post-filtration pH adjustment, it is generally best to use a lime
saturator to minimize the potential of turbidity addition. Also, in some waters, the utilization
of soda ash for pre-coagulation alkalinity adjustment often helps the overall coagulation
process.
Gas stripping as a water treatment practice is used for the following applications:
Removal of taste and odour causing volatile substances.
Removal of CO2 to reach carbonate (CO32‐) equilibrium (de-carbonation) to reduce the
lime dosage needed for corrosion control or lime softening or before metal oxidation.
Removal of volatile and semivolatile organic chemicals such as trichloroethylene (TCE)
tetrachloroethylene (PCE), considered to be a risk to public health.
Removal of naturally occurring dissolved gases such as radon, hydrogen sulphide (H2S)
for taste and odour control and preservation of distribution systems from sulphate attack
and methane (CH4) to prevent fire / explosions.
Removal of volatile disinfection by-products from water.
Removal of ammonia (NH3) from water to reduce eutrophic conditions in water reuse
applications.
Removal of entrained air or to relieve gas super saturation, e.g. to prevent ―air binding‖ of
filters, removal of taste and odour producing substances such as H2S, NH3, detergents and
geosmin.
Aeration may be used on surface waters to help remove tastes and odours due to dissolved
gases, or on groundwater supplies to reduce or remove objectionable amount of carbon
dioxide, hydrogen sulphide or methane and to introduce oxygen to assist in iron and
manganese removal. In surface waters with a high organic content (such as in Kalatuwawa)
aeration may also assist in colour removal.
Some water supply schemes have been constructed in Sri Lanka without aerators where
dissolved oxygen in the raw water level is sufficient. However aeration could be justified on
long term pollution condition in future. Implementation of water safety plan is important to
control such pollution on long-term along with climate resilience. Therefore, careful
consideration has to be given based on the raw water DO level before deciding the treatment
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process. When aeration is not required for the above purposes, it increases the cost of
pumping (usually 1 to 3 m head) hence the cost of treatment and increases the oxygen content
making the water more corrosive. Therefore, aerators should not be operated unless it is
required for addition or removal of gases or volatile components.
Natural surface waters often contain dissolved organic and inorganic substances, which may
volatilize on aeration while some dissolved organic matter are oxidised. This exchange has an
effect on reducing obnoxious tastes and odours and hence reductions of ultimate chlorine
demand. However, aeration may not remove all tastes and odours caused by less volatile
substances.
Dissolved ferrous and manganous compounds are oxidized by aeration, and precipitated as
insoluble ferric and manganic oxide, which may then be removed, by sedimentation and or
filtration. This process is likely to be less effective in the presence of organic matter, which
may combine with the iron and manganese to form complex compounds, which do not
precipitate well. In such cases, moderate rather than vigorous aeration may work better.
Groundwater will release a part of any dissolved gases and aerate with atmospheric oxygen
thus acquiring a more desirable taste. The release of carbon dioxide increases the pH and
reduces the corrosivity of the water. Reducing the carbon dioxide content, however, may shift
the carbonate bicarbonate equilibrium in the water so that deposits of calcium carbonates are
formed which may cause problems. Refer CHAPTER 8 for details on corrosivity of the water.
The rate of aeration is governed by the area of interface between the air and liquid, the
thickness of the inter layers and the time of contact. Therefore, careful consideration is to be
given to these factors in deciding aeration process.
Aerators are often used for both aeration and gas stripping purposes simultaneously. They can
be classified into five general types as follows;
1. Water fall / Gravity aerators (cascade, tray aerators, spray aerators, packing tower,)
2. Diffusion / bubble aerators
3. Mechanical aerators
4. Pressure aerators
5. Membrane aerators (A fine bubble aeration system)
Providing a maximum interface between air and water at a minimum expenditure of energy
for all types of aerators is a major design consideration.
Two general methods may be used for the aeration of water. The most common in industrial
use is the water-fall aerator. Using spray nozzles, the water is broken up into small droplets or
a thin film to enhance counter-current air contact. Turbulence increases the aeration of
flowing streams. The contact time and the ratio of air to water must be sufficient for effective
removal of the unwanted gas.
In the air diffusion method of aeration, air is diffused into a receiving vessel containing
counter-current flowing water, creating very small air bubbles. This ensures good air-water
contact for "scrubbing" of undesirable gases from the water.
Many variations of the waterfall principle are used for aeration. The simplest configuration
employs a vertical riser that discharges water by free fall into a basin. The riser usually
operates on the available head of water. The efficiency of aeration is improved as the fall
distance is increased. In addition, steps or shelves may be added to break up the fall and
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spread the water into thin sheets or films, which increases contact time and aeration
efficiency. The types of fall aerators commonly used are multiple trays aerator, and Cascade
aerator.
5.3.1. Application of Aeration
Addition of Oxygen: - Aeration adds oxygen (O2) to water to oxidize dissolved iron and/or
manganese (to facilitate their removal).
Taste and odour control: - Aeration has limited value in taste and odour removal. Most
Taste- and odour- causing compounds have a high solubility in water. Therefore, aeration is
generally less efficient in removal of taste and odour than other methods, such as chemical
oxidation and adsorption.
Iron and Manganese Removal: - Iron and Manganese are typically accomplished by
oxidising the iron and manganese ions into soluble oxides. The application of aeration is to
provide a sufficient amount of oxygen for this reaction to occur. This process is used in
ground water applications, where dissolved oxygen of the water is low. Therefore, aeration in
this application will result in oxidation of Iron and Manganese, causing their precipitation and
an increase in the dissolved oxygen concentration. Manganese often cannot be readily
oxidised at normal pH levels. Increasing the pH to 8.5 will enhance manganese oxidation,
particularly if a pack tower aerator with coke bed packing is used.
Volatile Organic Compound (VOC) Removal: - Most of the VOC can readily be removed
by aeration. Consideration must be given in the design of aeration units to remove VOCs in
the exhausted air; some of these compounds are also subjected to maximum ambient air-
concentration limitations.
Carbon Dioxide Removal: - Carbon dioxide can readily be removed by aeration. Carbon
dioxide has low solubility in water; aeration is very efficient in its removal. This process is
usually applied prior to softening of ground water, because high concentrations of carbon
dioxide are generally encountered in ground water. Since higher concentration of carbon
dioxide increases the chemical requirements for softening, there are benefits to carbon dioxide
removal prior to softening.
Hydrogen Sulphide Removal: - Hydrogen sulphide is a major taste- and odour- causing
compound that can be treated effectively by aeration. The mechanism of treatment in this case
is primarily oxidation of Hydrogen sulphide, resulting in water and free sulphur. In some
cases, free sulphur can interfere with other treatment processes. Hydrogen Sulphide can be
more effectively removed by initially aerating the water in an environment with high
concentration of carbon dioxide in the environment.
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5.3.2.1. Equilibrium Conditions
The term equilibrium applied to gases dissolved in water signifies a steady-state concentration
of dissolved substances. Aeration promotes the establishment of equilibrium between
dissolved, volatile constituents in the water and the constituents in the air to which the water
is exposed. For example, when water is exposed to air, oxygen and nitrogen dissolve in the
water until a state of equilibrium is reached. The function of aeration is to speed up this
natural process. True equilibrium may not be attained by aeration unless the air-water
exposure period is relatively long. From a practical standpoint, however, it is generally not
necessary to achieve absolute equilibrium.
Saturation value has considerable practical and theoretical significance. It is the difference
between the saturation value of a gas and its actual concentration in the water that provides
the driving force for the interchange of gas between air and water. Water deficient in oxygen
will absorb it when brought into contact with air, and the air-water equilibrium will be
reached from the direction of oxygen deficiency. Prolonged aeration produces oxygen
saturation. On the other hand, if water contains more oxygen or, as is more commonly
encountered, more carbon dioxide than the saturation amount, air stripping brings about
release of the gas. In this instance, equilibrium is approached from the direction of
supersaturation. The final result of prolonged air stripping, however, is the same--saturation.
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Ci* = liquid-phase concentration in equilibrium with gas-phase concentration, (kg/m3)
Di = bulkhead liquid-phase concentration, (kg/m3)
The driving force for mass transfer is the difference between actual conditions in the air
stripping unit and conditions associated with equilibrium between the gas and liquid phases.
Equilibrium concentration of a solute in air is directly proportional to the concentration of the
solute in water at a given temperature.
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a. Step Aerator
The step aerator can be designed to any shape such as symmetrical arrangement of above
cross section or place over the peripheral of a rectangle to have aesthetical appearance base on
the site suitability. Examples of cascade tray and step aerator designs are given in Annex B.1
and B.2 respectively.
IN
H
T
OUT W = width
SECTION PLAN
Figure 5-14: Multiple Cascade weir/step aerator
IN D1
H1 Note:
D - Diameter of platform
H2 H - Height of Drop
D2
H3
H4
D3
D4 OUT
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Trays can be of any suitable non – corrosive material, and for better dispersion may be filled
with course gravel. Coke may also be used, which acts as a catalyst, to promote the
precipitation of iron and manganese from the water. Slat and coke trays are similar to the
cascade and cone aerators. They usually consist of three-to-five stacked trays, which have
spaced wooden slats in them. The trays are then filled with fist sized pieces of coke, rock,
ceramic balls, limestone, or other materials. The primary purpose of the materials is providing
additional surface contact area between the air and water.
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5.3.3.5. Packed Tower Aerator
Packed Tower aerators (refer Figure 5-18) are used for many industrial water conditioning
purposes. Horizontal wood or plastic slated trays, or towers filled with packing of various
shapes and materials, are designed to maximize disruption of the falling water into small
streams for greater air-water contact. Air is forced through the unit by a blower, which
produces uniform air distribution across the entire cross section, cross current or counter-
current to the fall of the water. Owing to these features, forced draft aerators are more
efficient for gas removal and require less space for a given capacity. This is mostly used in
small or industrial water treatment plants. The disadvantage of tower aerator is that the system
is sensitive to clogging.
The airflow required for a packed tower depends on the Hendry‘s law coefficient for the
compound to be removed from the water or when multiple VOCs has to be removed, the
VOCs is the most difficult to remove. For a given airflow and tower diameter, an increase in
packing height result in greater VOC removal but increased capital and operating cost.
The volumetric air to water ratio used in a tower is a function of water temperature and
desired level of contaminant removal. The contaminant removal increase in water
temperature, but heating the influent water to reduce airflow requirements or increase removal
is generally not cost effective.
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5.3.3.6. Draft- Aerators
Draft aerators are similar to other water-into-air aerators, except that the air is induced by a
blower. There are two basic type of draft aerators. One has external blowers mounted at the
bottom of the tower to induce air from the bottom of the tower. Water is pumped to the top
and allowed to cascade down through the rising air. The other, an induced-draft aerator, has a
top-mounted blower forcing air from bottom vents up through the unit to the top. Both types
are effective in oxidizing iron and manganese before filtration.
Spray aerators are usually efficient with respect to gas transfer such as carbon dioxide
removal or oxygen addition. However, they require a large installation area, are difficult to
house, and pose operating problems during freezing weather and blocking of nozzles. To be
most effective, spray aerators need a supplemental air exchange to minimize the build-up of
contaminants in the air phase. The water is sprayed into the air, at about 5 - 7m/sec (Figure
5-19). The nozzles design is important in achieving optimum dispersion.
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The combination of horizontal water flow and vertical airflow (i.e. the flows are
perpendicular), is cross flow aeration. The height of the bubble bed is determined by adjusting
the height of the weir at the end of the plate.
Water
Air
Due to the reduced construction height and head loss, this technique offer good possibilities
for incorporating it in existing treatment plants. Sometime it is possible to place the plate
aerators in the filter building directly above the filters.
In diffused aeration, submerged pipes or nozzles release air or oxygen into the water. As
bubbles rise through the water, oxygen is transferred from a gaseous state to a liquid state thus
adding Dissolved Oxygen (DO) to the water.
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Figure 5-21: Flow-through low profile aeration system
This system also removes carbon dioxide, VOCs, gasoline compounds, hydrogen sulphide,
methane and radon from ground water and is particularly applicable to small water supplies.
The advantage of Venturi Aerator is that it requires little space and the system is not
expensive. The disadvantage is that only limited flow variation can be allowed for an
optimum effect. The Energy consumption is approximately 20 - 30 Wh/m3.
Consistent removal of 99 % of VOCs (PCE) through two units in series and radon >92 % is
achieved in a pilot test studies with an optimum air/water ratio of 10:1 for ground water. This
technology has advantage over a conventional technology (e.g., packed towers), used for gas
stripping because, the water remains under pressure and there is no need to break head and re-
pump.
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Figure 5-24 Design alternatives for a deep-well aerator
Mechanical surface aerators are used extensively in wastewater applications for supplying
oxygen to water. To a lesser extent, they are used to control taste and odour problems in water
treatment and are commonly installed at a reservoir rather than at the treatment plant. They
generally consist of an electric motor suspended on a float, with a driveshaft operating a
propeller located a short distance below the water surface. The water is drawn up by the blade
and thrown into the air in tiny droplets so that the water can pick up oxygen. A variation in
design is the surface aerator equipped with a draft tube extending below the propeller. With
this design, water is drawn up from near the bottom of deeper basins.
Submerged aerators operate in the reverse of surface aerators. The submerged blade draws
water downward and, in the process, draws in air, which is diffused into the water. This type
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of aerator results in relatively calm water at the surface compared with surface aerators.
Submerged aerators are best used for increasing dissolved oxygen levels.
Magnitude of partial pressure of water vapour and saturation value of oxygen in water
depends on temperature and are as follows:
Table 5-5: Magnitude of partial pressure of water vapour and saturation value of
oxygen in water
Temperature, T [C] 0 5 10 15 20 25 30
Water Vapor pressure, pw [kPa] 0.611 0.872 1.23 1.71 2.33 3.17 4.24
Oxygen saturation [mg/L] 14.6 12.75 11.27 10.07 9.07 8.24 7.54
Assuming constant time for each aeration step, under steady state conditions (constant flow),
The Oxygenation efficiency is defined as follows:
hence
( )
Where
Cs = Saturation concentration
Co = Initial concentration
Ce = Concentration at exit
Ct = Concentration at time t
K = Overall gas transfer coefficient
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For flows between 20 and 100 m3/h of m straight weir length, efficiency coefficient K can be
calculated as: K= 0.452 (1+0.46 T) h for unpolluted water. Where h=height of weir step [m]
and T= temperature (C).
At least 4 jets per meter weir length, the relationship between K and h is shown in Figure
5-27. Note that more efficiency is obtained when h 0.7 m where K*Cs = 7h. and h= height
of weir step [m].
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a = cross section area of nozzle opening
t = time of travel or exposure
= angle of inclination of spray to horizontal
Coefficient of velocity, contraction and discharge vary with the shape and other
characteristics of the nozzle or orifice and can be obtained from the manufacturer or
determined experimentally.
An advantage of spray aerators is the ease of incorporation into existing installations. The
spray aerators can be placed directly above the filters. Disadvantage of spray aerators are the
high sensitivity to clogging, high maintenance and drift. Also it require large footprint,
freezing problem in colder climate, short explosive time between water and air, and high
energy requirements.
The type of aeration system is also selected based on the efficiencies for gas transfer. The
efficiencies for various gas transfers are compared in Table 5-7 for the type of aeration
systems in practice and can be used as a guideline for design purpose.
A certain amount of dissolved oxygen is present in raw and treated waters. However,
dissolved oxygen may cause corrosion. Corrosion can occur whenever water and oxygen
come into contact with metallic surfaces. Generally the higher the dissolved oxygen
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concentration, the more rapid the corrosion. The solution to this problem is to not over-aerate.
This may be difficult because no definite rule exists as to what constitutes over-aeration. The
amount of aeration needed will vary from plant to plant and will also vary with the season.
Filters in water containing a high amount of dissolved oxygen will have a tendency to release
the oxygen in the filter as it passes through. The process can continue until the spaces between
the filter media particles begin to fill with bubbles. Called air binding, this causes the filter to
behave as though it is plugged and in need of backwashing.
Solids suspended in water include sand, soil, organic material, bacteria, virus and other
particulate material. Some of these materials pose a nuisance in water treatment. Typical size
variations of particulates found in surface water are listed in Table 5-9. Particles greater than
1 m (micron) will usually settle in quiescent water but smaller particle will not settle readily.
A suspension of particles that will not settle is known as stable suspension. The particles that
will make up these suspensions are known as colloids.
Insoluble matter may form (stable) colloidal solutions or dispersions. According to their
structure and properties, we distinguish two types: Hydrophobic (―water hating‖) colloids and
Hydrophilic (―water loving‖) colloids.
A hydrophobic colloidal particle is a solid particle and is mostly of inorganic origin, e.g. clay
particles and non-hydrated metal oxides. The material of the colloidal particle is often
insoluble in water. They are unstable; once the particles aggregate by destabilizing with an
electrolyte, they do not easily re-form as colloids whereas hydrophilic colloid (which means
that water is strongly absorbed) forms colloids easily. The water content of such a colloidal
particle is up to 90 – 99 %. Consequently, their density will only be a little higher than water,
which results in a low settling rate. Organic compounds (e.g. starch and proteins) will form
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hydrophilic colloids. When these materials are mixed with water, they form colloidal solution,
which cannot be easily destabilised.
The reason for colloids to stay as such small particles is that the particles have predominantly
similar negative electrical charge, meaning the repulsive forces keep the individual particles
separate. This charge is found at the surface of the particles, which may occur because of an
imperfection of the crystal lattice (e.g. clay), ionization of a surface group, or the adsorption
of a specific iron on the particle surface. The significance of the surface charge is associated
with the very large specific surface area of the particle.
Colloidal particles show a random movement (Brownian movement) in water. This is because
they are very small and collide with water molecules. At higher temperatures, the number of
collisions will increase much. This phenomenon of "Tyndall Effect" is the similar
phenomenon as flickering dust particles in air lighting up in a sunbeam.
Electrostatic force is the principal force contributing to the stability of the colloidal
suspensions. All colloids are electrically charged. The nature of the charge varies somewhat,
depending on the nature of the colloid. Metallic oxides are generally positively charged; non-
metallic oxides and metallic sulphides are generally negatively charged. As a result of this
electrical charge, the colloids of similar charge will repel each other. Surface charges may
occur because of an imperfection of the crystal lattice at the edge of the colloidal particle in
ground‐ and surface waters. Typically, negatively charged colloids predominate in natural
water.
For some colloids, the sign (+ or -) and magnitude of the surface charge depends on:
Nature of the colloid,
Ionic strength (salt concentration) and other compounds in water.
pH,
At higher pH, more attached H+ ions leave the surface and the particle becomes more
negatively charged. At Iso‐Electric Point (IEP), the colloidal particle has no charge anymore
(Figure 5-28).
H+
H+
In solution
H+
Charge
IEP
Electric
(+)
pH
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double layer. A model of a colloidal particle and its double layer is shown in Figure 5-29. In
this diffused layer, the molecules of water are sufficiently bound to create a shear surface.
The water molecules inside the shear surface will behave as if attached to the colloid; water
molecules outside the shear surface will behave as if independent of the colloid;
As shown in the model, the electrical potential at the shear surface is known as zeta potential.
The zeta potential is often measured in water treatment to give operators and indication of the
stability of the colloidal system or of the effectiveness of the coagulation process.
The stability of hydrophobic colloids depends on two opposite forces as shown in Figure
5-30. When two equally charged colloidal particles approach each other, the repulsive
electrical force will increase. On the other hand, an attractive force (the mysterious ―Van de
Waals‐force‖ (which is independent of the charges) will increase when the distance between
the particles decreases.
The action of both forces will keep the particles separated from each other and prevent
sedimentation or agglomeration of the colloidal particles. The suspension is now called
―stable‖. (Only after a very long time sedimentation may take place). The required interaction
energy needed to approach two particles to each other, based upon the two opposite forces in
charge, can also be qualitatively depicted in the next plot.
Van de Waals‐force decrease the distance between the colloidal particles. The electrostatic
force ―descends‖ slower, which means that the resulting net force causes such an energy
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barrier [see Figure 5-31(a)] in such a way, that collision of the particles is impossible. To
cope the barrier and to achieve proceeded agglomeration (sticking together), energy should be
added to the system.
There are generally accepted to be four main methods of destabilization of colloids systems.
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referred to as coagulant aids. Excessive agitation of flocs formed using a polymer coagulant,
can lead to the flocs breaking up.
The extent to which any one of the above mechanism occur depends on the pH, the raw water
quality and the type of coagulant used. True colour is thought to be removed largely by
adsorption on to the floc surface and by co-precipitation. Under suitable conditions, residual
concentration of coagulant in the treated water will be low and most of any natural iron or
aluminium in the raw water will be removed with the colour and turbidity.
5.4.3.1.Coagulation of Colour
Frequently, the objective of clarification is the reduction of colour, turbidity and suspended
solids. Swamps and wetlands introduce colour into surface waters, particularly after heavy
rainfalls. Colour-causing materials can cause various problems, such as objectionable taste,
increased microbiological content, fouling of anion exchange resins, and interference with
coagulation and stabilization of silt, soluble iron, and manganese.
Most organic colour in surface waters is colloidal and negatively charged. Chemically,
colour-producing compounds are classified as humic and fulvic acids. Humic acids are
stronger acids, soluble in stronger base but insoluble in strong acid. Humic acids have
molecular weight from several hundreds to few thousands. They can aggregate naturally into
particle with much apparent molecular weights. They are composed partially of aromatic
compounds with carboxyl, phenolic and quinoid groups. Humic substances have high cation
exchange capacities, can concentrate or bind metal ions, and accumulate hydrophobic organic
compounds, including several pesticides. Fulvic acids are similar in structure to humic acid
but have lower molecular weights and soluble in both acid and base.
Colour can be removed well by coagulation with aluminium or iron salts or synthetic cationic
polymers. A fraction of the humic substances is not readily removed and fulvic acids can be
difficult to coagulate. Alum is most effective at pH value about 5; ferric sulphate is most
effective at pH value about 4. However, jar test is an essential tool for selecting the types,
dose of chemicals to be added and the optimum pH value.
Chlorine oxidizes colour compounds, while the inorganic coagulants can physically remove
many types of organic colour by neutralization of surface charges and subsequent flocculation
and clarification. The use of chlorine to oxidize organic colour bodies may be limited due to
the production of chlorinated organic by-products, such as trihalomethanes. Additional colour
removal is achieved by chemical interaction with aluminium or iron hydrolysed products.
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Highly charged cationic organic polyelectrolytes can also be used to coagulate some types of
colour causing particles.
Coagulation for colour reduction is normally carried out at pH 4.5 to 5.5. Optimum pH for
turbidity removal is usually much higher than that for colour reduction. The presence of
sulphate ions can interfere with coagulation in colour reduction, whereas calcium and
magnesium ions can improve the process and broaden the pH range in which colour may be
reduced effectively.
Variation in pH affects particle surface charge and floc precipitation during coagulation. Iron
and aluminium hydroxide flocs are best precipitated at pH levels that minimize the coagulant
solubility. However, the best clarification performance may not always coincide with the
optimum pH for hydroxide floc formation. In addition, the iron and aluminium hydroxide
flocs increase volume requirements for the disposal of settled sludge.
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With aluminium sulphate, optimum coagulation efficiency and minimum floc solubility
normally occur at pH 6.0 to 7.0. Iron coagulants can be used successfully over the much
broader pH range of 5.0 to 11.0. If ferrous compounds are used, oxidation to ferric iron is
needed for complete precipitation. This may require either chlorine addition or pH
adjustment.
The chemical reactions between the water and aluminium or iron result in the formation of the
hydroxide coagulant as in the following:
Oxidation in situ after addition of Fe2+ to the water to be treated, the water should contain
oxygen and the pH should be > 8.5. Oxidation of an Fe2+ solution with oxygen (from air), at
low pH (<3) and with powdered activated carbon (PAC) as catalyst:
4 Fe2+ + O2 + 4 H+ + PAC → 4 Fe3+ + 2 H2O
Polymeric primary coagulants are cationic materials with relatively low molecular weights
(under 500,000). The cationic charge density (available positively charged sites) is very high.
Polymeric flocculants or coagulant aids may be anionic, cationic, or nonionic. Their
molecular weights may be as high as 50,000,000.
For any given particle, there is an ideal molecular weight and an ideal charge density for
optimum coagulation. There is also an optimum charge density and molecular weight for the
most efficient flocculent.
As suspensions are normally non-uniform, specific testing is necessary to find the coagulants
and flocculants with the broadest range of performance.
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polymers may also bridge, to some extent, from one particle to another but are not particularly
effective flocculants. The use of polyelectrolytes permits water clarification without the
precipitation of additional hydroxide solids formed by inorganic coagulants. The pH of the
treated water is unaffected.
The efficiency of primary coagulant polyelectrolytes depends greatly on the nature of the
turbidity particles to be coagulated, the amount of turbidity present, and the mixing or
reaction energies available during coagulation. With lower influent turbidity, more turbulence
or mixing is required to achieve maximum charge neutralization.
The use of organic polymers offers several advantages over the use of inorganic coagulants:
The amount of sludge produced during clarification can be reduced by 50-90%. The
approximate dry weight of solids removed per pound of dry alum and ferric sulphate
are approximately 0.12 and 0.25 kg, respectively.
The resulting sludge contains less chemically bound water and can be more easily
dewatered.
Polymeric coagulants do not affect pH. Therefore, the need for supplemental alkalinity,
such as lime, caustic, or soda ash is reduced or eliminated.
Polymeric coagulants do not add to the total dissolved solids concentration. For
example, 1 ppm of alum adds 0.45 ppm of sulphate ion (expressed as CaCO3). The
reduction in sulphate can significantly extend the capacity of anion exchange systems.
Soluble iron or aluminium carryover in the clarifier effluent may result from inorganic
coagulant use. Therefore, elimination of the inorganic coagulant can minimize the
deposition of these metals in filters, ion exchange units, and cooling systems.
Drawbacks:
a) Release of undesired materials (organics and nutrients) into the water
b) Many of the natural coagulants are not thoroughly investigated
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To increase floc strength, size and density for better separation
To improve coagulation/flocculation at low temperature (<12-15°C)
Coagulant aids have proven quite successful in precipitation softening and clarification to
achieve improved settling rates of precipitates and finished water clarity. In many cases,
coagulant aids are not required during the normal operation of the treatment plant, but are
used during emergency/ shock loading treatment of water, which has not been adequately
treated in the flocculation and sedimentation basin. At low temperature the viscosity of water
is higher and the shear forces. To avoid floc fraction, a coagulant aid is added in countries
with moderate /cold climate.
Most of the coagulation aids are polyelectrolytes, from natural or synthetic origin. Generally,
very high molecular weight, anionic polyacrylamides are the most effective coagulant aids.
Nonionic or cationic types have proven successful in some clarifier systems. Essentially, the
polymer bridges the small floc particles and causes them to agglomerate rapidly into larger,
more cohesive flocs that settle quickly. The higher-molecular-weight polymers bridge
suspended solids most effectively.
Several products are applied e.g.: Modified starch products (Trade name: ―Wisprofloc‖);
Natural product which gets moulded quickly; Alginates (products as proteins, obtained from
algae); Synthetic compounds (e.g. poly acryl amide). The monomer acrylamide is toxic and
any traces of the monomer should not be present in the coagulant aid solution when using this
polymer.
Generally, waters containing 10 to 60 NTU are most effectively treated with an inorganic
coagulant and cationic polymer. In most cases, a significant portion of the inorganic coagulant
demand can be met with the cationic polyelectrolyte. With turbidity greater than 60 NTU, a
polymeric primary coagulant alone is normally sufficient.
Iron (II) sulphate is a waste product of steel industry. It is formed by pickling steel with
sulphuric acid. That is why in some countries this product is relatively cheap. As this has free
HCl, the solution is highly corrosive. Ferric chloride can quickly form flocs and require about
half the dose of alum as per a study carried by NWSDB (Reference no. 22). Moreover, Alum
is imported to Sri Lanka. Further, it was reported that higher turbidity was observed in
coagulated and settled water using Ferric chloride compared to alum.
Flocculation starts when neutralized or entrapped particles begin to collide and fuse to form
larger particles. This process can occur naturally or can be enhanced by the addition of
polymeric flocculent aids.
After destabilisation of the colloidal particles and the formation of micro‐flocs, agglomeration
of micro‐flocs to larger macro‐flocs may start. Therefore, the micro‐flocs should collide to
each other in order to form conglomerates. To improve the number of collisions in this so-
called ―Flocculation process‖, the micro‐flocs should move quickly: The natural Brownian
movement takes care of the ―perikinetic flocculation‖, but this movement is not sufficient for
a reasonable flocculation rate. An artificial increase of the velocity of the micro‐flocs is
needed. In the ―orthokinetic flocculation‖, flocculation is accomplished by agitation or
creating turbulence in the suspension, which increases the chance of collision, and the
velocity (the kinetic energy of the micro flocs), managing the ―energy barrier‖ for an
effective collision.
Sedimentation refers to the physical removal of solids from suspension, by settling under
gravity that occurs once the particles have been coagulated and flocculated. Sedimentation or
subsidence alone, without prior coagulation, results in the removal of only relatively coarser
suspended solids.
The coagulation/flocculation and sedimentation process requires three distinct unit processes
as follows:
high shear, rapid mix for coagulation
low shear, high retention time, moderate mixing for flocculation
liquid and solids separation
Dry feeder draw finely ground chemical from agitated storage hoppers and usually delivered
to a solution pot for injection into main supply as a solution or slurry. Whereas in solution
feeders the chemical is dissolved in large storage tanks (Holding solution to feed for 12-24
hours) with stirrers to a standard concentration (Refer Table 5-11) which is then added via
constant head orifice or similar measuring device.
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Duplicate feeding arrangements must be provided in case of break down and storage capacity
adjacent to the feeder should be provided for at least one-month‘s requirements. Since most of
the chemicals solutions are highly corrosive, the tank should be plastic material or lined with
plastic coating and the feeding lines should be of non-corrosive (e.g. Plastic, Alkethene, PE or
rubber). For detail on dosing arrangements, refer CHAPTER 6.
The pH corrections shall be done prior to addition of coagulant. As an example, lime can be
added at the entrance of aerator and in contrast, acid can be added after the aeration. Higher
pH facilitates oxidation of iron and manganese causing them to deposit.
Iron salt coagulants are manufactured by dissolving various iron sources (iron ores and scrap
iron) in sulphuric or hydrochloric acid or by reprocessing materials such as acidic iron salt
solutions from iron mills and foundries. Ferric chloride is made from reprocessed titanium
dioxide liquors. Like alum, the iron salt coagulants typically contain metal contaminants,
usually Mn, Cu, V, Zn, Pb, and Cd. The amount varies with the source of the product thus
testing metal concentration is a prudent procedure.
In most cases, the low amounts of heavy metal contaminants in coagulants will not have a
significant effect on metal concentrations in the treated water. The metals may already be in
an insoluble form or they are likely to precipitate or adsorb on the floc when the coagulant is
added to the water. The metals may, increase the heavy metal content of treatment residue.
The AWWA standards for coagulants shall include only a general statement about limits on
impurity levels in the products. The statement says that the contaminants should not be
present in quantities that will cause ―deleterious or injurious effects‖ on human health when
the product is used properly.
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5.5. Rapid Mix / Flash Mix
Immediately after coagulant addition, coagulants must be dispersed rapidly to ensure instant
contact between the coagulant and suspended particles, resulting in quick adsorption and
avoiding of formation of useless polymers (Al4+ compound). The hydrolysis complex ions are
formed in 0.01‐1 sec. The success of coagulation process depends on rapid and thorough
dispersion of coagulant and is known as rapid or flash mix.
Micro-flocs form because of collisions between the primary particles. The reaction rate of
destabilization is controlled by the flow condition in addition to the characteristics of
chemical parameters. Normally, a moderate and uniform distribution of turbulent flow is
crucial and achieved by rapid mixing. The geometry of rapid mixers is the most important
aspect of the design and the primary concern is to provide uniform mixing, to minimise dead
areas and short-circuiting.
Some design requirements to have effective use of coagulant are:
Detention time in mixer should be less than 1 min
Mixing intensity should be high
G‐value should be in the range of 500‐1,000 s‐1. In certain conditions raw water,
G value of 3500 s-1 may be the optimum G value for proper coagulation
In case the residence time increases, the G‐value should decrease, to avoid disintegration of
the formed micro‐flocs. The term Gt is often used to match the proper velocity gradient with
detention time. In certain conditions of raw water, the G‐value may be as high as 3,500 s‐1 for
proper coagulation. Typical Gt values range between 30,000 and 60,000. The optimum Gt
values vary a great deal with the chemicals and dosage rates. Optimum design values are best
determined experimentally. These are incorporated in the design of rapid mixers.
The mixing theory involves fluid transport, which has three forms: (1) advection, (2) turbulent
diffusion, and (3) molecular diffusion. The first two may be modelled by the classical Navier-
Stokes equation expressed in finite difference form and molecular diffusion is modelled by
Fick's law. Mathematical models and physical models help to understating the mixing but
neither is sufficient for design. The substitute is empirical guideline and experiences.
The intensity of mechanical agitation in rapid mixing and flocculation is expressed in terms of
the measured mean velocity gradient (G) defined as follows:
This applies either to a mechanical mixer (rapid or slow) or a hydraulic flocculator. However,
it is also common to dose chemicals into the flow over weirs and to flocculate in baffled or
sinuous channels. In this case, the power input to the water is determined by the head loss (h)
over the weirs, in the channels. The power needed to transfer a flow of Q (m3/s) is given by
P=ghQ where is the density of water (kg/m3), g is acceleration due to gravity (ms-2) and h
is the head loss (m). Thus for baffled or sinuous channels:
√
Where T is the detention time in the chamber or channel where mixing take place.
For turbulent condition, the power requirements can be estimated as expressed by Rushton:
When the flow is in laminar regime (the laminar regime corresponds to (Re < 10 for many
impellers, laminar flow persists until Re = 100 or greater):
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Lime Alum Half open pipe to Slotted pipe to dose
dose Lime Alum
IN
W
H
OUT
D
L
L PLAN
SECTION
Figure 5-32: Weir for Rapid mix
The floor of the converging section is horizontal, the floor of the throat inclines downward,
and the floor of the diverging section slopes upward as show in Figure 5-33. The Parshall
flume can be constructed in a wide range of sizes to handle virtually any flow range. The
design calculation for hydraulic rapid mixing is provided in Annex C.1.
STILLING WELL
THROAT
Ha Hb
S=2/3A H
A 1
6
D W C
5
1
Coagulant diffuser
PLAN
B F G STILLING WELL DETAIL
Coagulant diffuser
FLOW K=75mm
T Ha E
Hb
Hd
1 N M
1
4
2.67
SECTIONAL ELEVATION
Figure 5-33: Parshall flume rapid mixer
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Over-And-Under Baffle System
An over-and-under baffle system is shown in Figure 5-34. The water entering the first
compartment rises to a level sufficient to overflow the first weir plate. The coagulant is added
to the overflow, and distributed over the width by means of several orifices from a manifold
parallel to the weir crest. The water falls in to the pool below.
Floor
Turbine Mixer is an improvement of a paddle mixer creating the maximum G for a particular
power input. Coagulants are injected at the turbine installed in a chamber as shown in Figure
5-35.
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Coagulant dose
Plate
Impeller
Baffle
Basin
The mixing devices shall be able to adjust the intensity of mixing with changes in water
quality or flow rate. This can be achieved by providing a variable speed drive. The shape and
the geometry of the tank and impeller system must be specified as the flow pattern is unique
to that particular system.
If the baffles do not reach the bottom of the tank, then solid accumulation in the tank bottom
may be reduced. Another approach is to set the shaft of the impeller away from the centre or
by tilting the axix of the pump at some angle to the vertical.
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Straight Blade or Flat Blade Flat Blade Disk Impeller Pitched Blade Axial-Flow
Radial-Flow Turbine Impeller Impeller
The impellers that force water outward at right angle to the axis of rotation in a manner
similar to that of a radial flow pump are called radial-flow impellers or turbine impellers. The
motion induced by radial-flow impeller is characterised by "higher shear" and "low flow".
The radial-flow impeller has three main components:
1. A radial flow of high velocity, which creates high shear zone just at the tip of the
impeller.
2. The flat blade of the impeller causes a separation effect, i.e. stir turbulence on the
trailing side
3. The radial flow rails set up advection currents that move up and down the wall of the
tank, re-circulating the centre. These currents also experience shear and that eddies
peel off. Eventually, all of the energy is dissipated as turbulence.
The design calculation for mechanical flash mixer is provided in Annex C.2.
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i.e. there is no operator involvement. The installation of static mixers in pipes is a common
practice in chemical engineering and becoming popular in water industry.
Static mixers are placed directly in the treatment line upstream of the flocculation phase. This
is the short length (typically 2-4 times diameter) of pipe containing fixed blades that create
vigilant agitation of flow passing over the blades. They were developed initially by the
chemical process industry for intimate mixing of different chemicals. Static mixers used in
water treatment typically have a head drop of about 0.5 meter (Figure 5-37). They have to be
installed in a pressure pipeline.
The greater advantage is that they are compact and highly effective in rapidly dispersing the
coagulant, reduced resident time requirements and improved performance of the injected
chemicals. They are less suited to large flow variations as they are optimized to treat a
particular flow.
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5.5.8. Diffusion Mixing by Pressurised Nozzles
A submerged "Jet" discharge chemicals at high velocity into water as illustrated in Figure
5-39. Application of jet mixing includes coagulation, disinfection, air dispersion etc., in water
treatment. The advantage of jet mixing includes simplicity such as no moving parts (except
for pumps), low capital cost, reliability and effectiveness. Also either source water without
added chemicals or partially destabilized source water can be used in the chemical injection
system. A valve installed in the pump discharge line can control pumping rate and vary
energy input for various plant flows and types of coagulating chemicals. A disadvantage is the
possible clogging of nozzles.
Figure 5-39: Nozzle inside the Pipe (Section through Pump Mixer)
There are many kinds of configurations, e.g., radial flow of several jets towards the centre of a
pipe, radial flow from a centre ring, a single jet pointed upstream in the pipe. As a rule of
thumb in coagulation mixing, the total jet flow is about 10% of the water flow. The
components of Jet mixing System are given in Table 5-14.
Table 5-14: Components in Design of Jet mixing System
Design Component
Water Inlet pipeline Jet pipeline Nozzle Coagulant Feed
Diameter Metering pump Number Point of feed
Flow Flow and head Flow and head Orientation of flow
Flow variation Total flow Velocity of each core Feed velocity
Velocity of water Diameter Orientation Flow
Pressure at jet Appurtenances Upstream/ downstream Pump selection
Valves-actuated Radial from peripheral
Valves-control Radial from center
Flow meter Spray angle
Pressure gauge Diffusion plate or not
5.6. Flocculators
Flocculation is carried out in tanks known as flocculators. A flocculator is characterized by its
velocity gradient, its contact time, and the extreme local velocities of the moving element and
liquid, which shear the floc (limited to 0.4 m/sec).
The size of floc particles and their speed of formation can be improved by creating velocity
gradient in the water. Such conditions can be provided by rectangular horizontal flow tanks
with slowly rotating paddles or with baffles or by vertical flow tanks with mechanical stirring
or baffles. Mechanical type is common in large plants and hydraulic or gravity type is used in
smaller plants.
The Flocculators are categorised as follows:
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A. Mechanical Mixing Flocculators
Vertical shaft with impeller (turbine or propeller type blades)
Paddle type with either horizontal or vertical shafts
B. Hydraulic Mixing Baffled Channels Flocculators
Horizontal baffled channels (round the end)
Vertically baffled channel (over and under)
The speed of the mechanically-operated paddles can be adjusted to suit variations in flow,
temperature or raw water quality. Furthermore, mechanical flocculators are readily available
from proprietors in a variety of designs to suit any mode of operation. The principal elements
of mechanical flocculator systems are agitator impellers, drive motors, speed controllers and
reducers, transmission systems, shafts and bearings. The cost and added complexity of
mechanical flocculator systems introduce additional complications, particularly in regards to
operation and maintenance.
The major shortcomings of hydraulic flocculators reported widely in the technical literature
are:
No flexibility to respond to changes in raw water quantity,
The hydraulic and consequent flocculation parameters, are a function of flow and cannot
be adjusted independently
The head loss is comparably high
Cleaning may be difficult
Durability of baffles used may be lesser
These shortcomings are the reasons for hydraulic flocculators not to be continued extensively.
However, it is possible to mitigate these shortcomings with properly designed systems that
will function under a reasonably wide range of operating conditions.
The velocity gradient G for Hydraulic Flocculators can be controlled by changing the spacing
of the baffles. G should be greater than 10 in order to promote flocculation but less than 75 if
disintegration of the floc by shear forces is to be avoided. The value of G can be adjusted
according to required floc size with the initial value as high as 100 and the final values
dropped to as low as 10 (typical value would be in the range of 15-90).
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The minimum detention time in the basin should be at least 20 minutes. Care must be taken in
introducing flocculated water into the sedimentation tank to minimise disintegration of flocs.
The recommended velocity in the canal or pipe to the sedimentation basin should be between
0.1-0.3 m/s and emphasis must be placed on laminar flow.
Two methods of providing tapered G values are by either varying the baffle spacing in a basin
having a fixed cross section or by evenly spacing the baffle along varying channel depth.
Typical sketch of horizontal and vertical flow baffled channel flocculators are shown in
Figure 5-40 and Figure 5-41 respectively.
INLET OUTLET
INLET
OUTLET
The water velocity in horizontal-flow and vertical-flow units generally varies from 0.1 to 0.3
m/sec. Detention time is 20 to 30 minutes. In general, velocity gradients for both types of
baffled channel flocculators should vary between 100 - 10 per sec. In addition to the
foregoing design criteria, the practical guidelines enumerated in Table 5-15 should be
considered in the design and construction of baffled channel flocculators, although they are
somewhat general and should not be interpreted as necessarily binding in all cases.
Tapered energy flocculation in baffled channels generally is achieved by varying the spacing
of the baffles, i.e. close spacing of baffles for high velocity gradients, and wider spacing for
low velocity gradients. The configuration of baffles that will induce a specific tapered
velocity gradient is best determined under actual plant operating conditions, by either re-
spacing or changing the number of baffles in the flocculation basin to attain the desired head
loss. it is recommends a tapered velocity gradient from about 75 sec-1 at the inlet to 10 to 15
sec-1 at the outlet of the flocculators.
Table 5-15: Guidelines for the Design and Construction of Baffled Channel Flocculators
Around the-End (Horizontal flow)
Distance between baffles should not be less than 45 cm to permit cleaning.
Clear distance between the end of each baffle and the wall is about 1-1.5 times the
distance between baffles, should not be less than 60 cm.
Depth of water should not be less than 1.0 m.
Decay-resistant timber should be used for baffles; stainless steel, PVC, PPE baffles
can also be used.
Avoid using asbestos-cement baffles as they corrode at the pH of alum coagulation.
Over and Under (Vertical flow)
Distance between baffles should not be less than 45 cm.
Depth should be 2 to 3 times the distance between baffles.
Clear space between the upper edge of a baffle and the water surface, or the lower
edge of a baffle and the basin bottom, should be about 1-1.5 times the distance
between baffles.
Material for baffles is the same as in around-the-end units.
Weep holes should be provided for drainage to avoid accumulation of sludge.
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Table 5-16: Typical criterias for mechanical flocculators
Vertical shaft with
Parameters Horizontal shaft with paddle
turbine
Velocity gradient, G (s-1) 50-10 70-10
Detention time, t (min) 30-40 20- 40
Flocculation stage 3-6 2-4
Maximum flow velocity (m/s) 1.0 2-3
Paddle area (%) 5 – 20 0.1-0.2
Blade diameter/ Tank with, D/L 0.5-0.75 0.2-0.4
Speed of shaft, (rpm) 1-5 8-25
Plate
Impeller
Baffle
Basin
The rotating unit consist of vertical shaft propeller with three or four blades and is driven by a
reduction gear system and most often with a variable speed drive (Figure 5-42).
The efficiency of vertical shaft mixers can be improved by installation of starter baffles. The
purpose of the starter baffle is to increase the effective turbulence as well as to prevent
rotational fluid motion within the tank. A proper starter baffle design specifies the installation
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of 2 or four pairs of baffles on opposite side of the compartments. The width of each
individual starter baffle should be 1/8 to 1/12 of the distance across the individual mixer
compartments.
Design Criteria
Parameter Value
Diameter of wheel 3-4m
Paddle board section 100 - 150 mm
Paddle board length 2 - 3.5 m
paddle board area / tank section area < 20%
Paddle tip speed Strong floc, 4 m/sec and
Weak floc, 2 m/sec
Spacing between paddle wheels on same shaft 1m
Clearance from basin walls 0.7 m
Minimum basin depth 1 m or diameter of paddle wheel
Minimum clearance between stages 1m
Diffuser Walls are used to divide flocculation basins into separate compartments and
hydraulic division between flocculation basin and sedimentation basin. Separate
compartments are provided when on even velocity profile is required and back-mixing is
undesirable.
Figure 5-43 and Figure 5-44 show typical arrangements of horizontal- and vertical-axis
paddle flocculators. The axes should rotate in alternative directions along the tank; e.g. the
first and third paddle rotate clockwise, but the second rotates counter clockwise.
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Drive Unit
Drive platform
Water Surface
Side view
To produce better-quality floc, two flocculators can be used in series for a given flocculation
time. This configuration allows:
Adjustment of the velocity gradient as a function of time
Delay of partial reagent feed
Depth limitation in tanks handling large flows
Some existing plants in Sri Lanka use a combination of flocculation and settling within a
single structure in up flow sludge blanket clarifiers (see Figure 5-51and Figure 5-52). These
units operate best under high turbidity conditions as a dense sludge blanket can be formed.
However, maintaining sludge blanket is a challenge during overloading and high temperature
areas. The sludge rises and overflows at the slightest provocation. An example hydraulic
design calculation for mechanical flocculator is given in Annex D.2.
5.7. Clarification
Clarification is the removal of suspended matter from water by a process of settling or
floating. In the process, particle heavier than water will settle to the bottom of an especially
designed tank. To constantly secure the settling function, sedimentation basin must be
equipped with suitable de-sludging equipment to match the structure. This mechanism must
be free of failures and capable of thoroughly discharging of the deposited sludge to avoid
suspension of operation. Clarification system is classified as given in Table 5-17.
Horizontal flow basin Multi stage type (2 or 3 story but not common in Sri Lanka)
Horizontal flow
Plate/ tube settle type
Upward flow
Center- feed type
Radial flow or Circular basin
Peripheral-feed type
Flocculation Clarifiers Clari-Flocculator
Sludge Circulation type
Suspended solids contact clarifier
Sludge blanket type
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Pulsation (Combined) type
Floating basin Dissolved Air Flotation (DAF) basin
Note: Plate/ tube settlers are attached to suspended solid contact clarifiers
Rectangular sedimentation basins are commonly found in water treatment plants. Rectangular
basins are popular as they tend to have:
Predictable performance
Lower maintenance
Minimal short circuiting
Solids contact clarifiers are generally circular in shape and built to provide the most
economical solution to precipitation and clarification requirements. The basic design provides
for flash mix, coagulation, flocculation, solids recirculation, clarification, and positive sludge
removal in a single basin - eliminating the need for multiple basins and associated piping and
pumping. Suspended solid contact clarifiers are classified into sludge circulation type, sludge
clarification type and combined type. By principal or mechanism and each type have many
models and different ranges of applicable raw water and working conditions. Hence, it is
necessary to select a proper model by carefully studying the situations.
When DAF is compared with sedimentation basin, DAF basins are smaller due to relatively
high surface loading and lower detention time, so a considerable saving in capital cost can be
realised. DAF is much more efficient for separating low density particle such as algae,
Giardia cysts, and aluminium humate precipitates produced from coagulation. In fact, these
type of particles cause notorious problems in conventional plants that have floc carry over to
the filters especially in cold water conditions causing short filter runs. Water from reservoirs
have problem with certain algae that cause taste and odours and clog filters. DAF perform
better in treating low density particle to produce longer filter runs.
Fundamentals of Settling
Several cases of settling behaviour may be distinguished on the basis of the nature of the
particles to be removed and their concentration. Thus, individual particles may be discrete
(sand grains) or flocculent (most organic materials and biological solids). Particle
concentrations may vary from very low through too high in which case adjacent particles are
actually in contact. Common classifications of settling behaviour are described in Table 5-18.
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Sedimentation refers to the settlement of particles from water by force of gravity. Stroke‘s law
describes the terminal settling velocity of discrete spherical particle in a laminar flow regime
as follows:
( )
Where:
= settling velocity
= gravitational force constant
= dynamic viscosity
= water density
= Particle density
= Particle diameter
The general conclusion that Vs depends on a particular diameter, particle density and, under
some conditions, also on fluid viscosity and hence on temperature, is important in
understanding sedimentation behaviour. Furthermore, in practical sedimentation tanks, the
terminal settling velocity is quickly reached, so, for non-flocculent particles and uniform fluid
flow the settling velocity is constant throughout the settling time. This fact can be usefully
applied to a study of settling in an ideal sedimentation tank to provide an important design
principle for sedimentation processes.
Although Stroke‘s law helps to understand how particle settle, empirical observations are
needed to deal with the behaviour of real suspension. In ideal upflow settling tank, all particle
that have a settling velocity greater than water upflow velocity will be captured: This is
explained as follows:
Consider a particle with settling velocity (Vo) which is just removed. I.e. traverses the full
depth (H) of the basin in the detention time (T). Refer Figure 5-45 for details.
(m/hr) where (h)
A = surface area of the basin (m2)
Q = flow rate through the basin (m3/h)
Then = m/h which is the surface-loading or overflow rate of the ideal tank.
u
Supernatant
Supernatant
u V0 Supernatant u
V0 V0
H0
Carryover
L L
1) Vs=V0, r = 100% 2) Vs<V0, r = Vs/V0 % 3) Vs>V0, r = 100%
r = the removal rate
Figure 5-45: Paths traced by discrete particles in a horizontal flow settling basin
Note that the basin depth, H is immaterial. Particle with the settling velocity (Vs) of Vo equal
or greater should be removed, but when Vs is lower than Vo.
Provided, H < Vs T, they are removed but if
H > Vs T, they are partially removed
Therefore, proportion of removed particles is . The same result applies to circular tanks.
Thus to increase the removal ratio, the following three ways can be considered:
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1. To increase the sedimentation area of the basin (insert a partition plate between the
surface and the bottom of the basin, the structure & maintenance are complicated the
same technique is used in plate or tube settlers)
2. To increase the settling velocity of flocs (larger & heavier flocs by suitable coagulant /
coagulant aids or use of suspended solid clarifier)
3. To decrease the flow rate Q (use of uni-flow sedimentation basin by branching
supernatant in the middle. The inclined bottom type will reduce construction cost too)
Some typical settling velocities of particles are given in Table 5-19. To predict the fraction of
suspension that may be removed by an ideal basin is in terms of its fall velocity can be
obtained from the settling column test. The typical arrangements of settling analysis of
suspension of discrete particles is given in Figure 5-46. Designers are encouraged to use the
settling column test when the quality of raw water is not stable.
Portion for
concentration
Test
50 cm
60 cm
50 cm
Cock
40 cm
50 cm
Sample of
Suspension
Figure 5-46: Settling column and ISO-percentage settling curves for flocculent particles
In practice, to design a full-scale settling tank to achieve comparable removal, the settling rate
from the column test should be multiplied by a factor of 0.65 to 0.85, and the detention time
should be multiplied by a factor of 1.25 to 1.5.
Coagulation and flocculation can be optimised through jar testing to create particles that more
readily settle. Polymers are especially effective for increasing the density of floc particle‘s
density and cohesiveness, which improve settling characteristics. However, polymers are
recommended to reduce the peak loads rather than applying for the whole periods.
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5.7.1. Horizontal Flow Sedimentation Basin
Sedimentation or settling basin is a solid-liquid separation process utilizing gravitational
settling to remove suspended solids from the water. This is one of the cheapest and easiest
ways of removing suspended solids. Sedimentation basins are also known as settling basins,
or clarifiers. The horizontal flow basin can be either rectangular or circular.
In plain sedimentation, impurities are separated from water by the action of gravity alone. In
contrast, in coagulant aided sedimentation the particles are too small to be removed by gravity
and aided with coagulants to increase size and agglomeration.
Sedimentation basins are designed to reduce the velocity of water entering the basin so that it
is retained long enough to permit particle to settle. A sedimentation basin has four sections:
the inlet zone, the settling zone, the outlet zone and the sludge deposit zone (see Figure 5-47).
L1 L2 L3 L4
Baffle
Outlet zone
Inlet Zone
wall h4 Settling Zone h5
h1 h2 h3
Sludge Zone
Sectional Elevation
Settling zone
Sludge zone
Outlet zone
Inlet zone
Plan
Figure 5-47: Horizontal Flow Rectangular Sedimentation Basin
The Inlet Zone: The inlet flow arrangement must provide a flow distribution that
maximizes the opportunity for particles to settle. The inlet should evenly distribute the
flow across the sedimentation basin and dissipate incoming velocity. If these two
functions are achieved, the hydraulic flow characteristics of the basin will more
closely simulate those of an ideal basin and make possible more efficient performance.
Inlet zones are designed differently for rectangular and circular basins.
The settling Zone: is where the water is held long enough to permit suspended
particles to settle. The efficiency of the settling process will be improved if there is no
turbulence or cross circulation in the basin.
The Outlet Zone: is where the clarified water is collected from the top layer of the
basin. This area is separated from the settling zone by a weir which controls water
flow out of the basin and into the outlet zone. Like the inlet zone, outlet zone has a
great deal of influence on the flow pattern and settling behaviour of floc in a
sedimentation basin. Either V-notch or submerged orifice weir plates are commonly
used. Of these two submerged orifice plates are preferred, because their use tends to
result in less floc break-up between sedimentation and filtration units and also because
they reduce floating materials like ice in colder climate.
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The Sludge Zone: collects the material settled from the water. The floor in the sludge
zone should have a minimum of 5% slope towards the drain.
Sedimentation basin design is based on the assumption of ideal conditions in the settling zone,
such as:
A uniform flow distribution vertically and horizontally at the inlet and outlet to the
settling zone
A uniform solid concentration at the inlet to the settling zone vertically and
horizontally
For pre-sedimentation (without chemical pre-treatment) lower surface loading rates should be
used compared with chemical coagulation as given in Table 5-20.
Sedimentation after efficient chemical coagulation should remove almost all of the colloidal
and suspension impurities in water. Large flocs have setting velocities in the range 0.5 – 3.5
m/hr and for alum floc 1.0 m/hr is commonly used for design purpose.
These typical surface loading rates result in relatively large basin area requirements that
increase the cost, the land area requirement. Consequently, there is a growing trend to use
high-rate clarification devises such as plate or tube settlers in an effort to reduce space and
cost requirements.
For efficient design, most (if not all) of the following factors should be considered.
Number of basins (at least two)
Dimensions
Velocity of the flow (surface loading rate)
Detention time
Sludge storage and removal
Inlet and outlet arrangements
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Particle size and solid to be removed
Water temperature
It is very difficult to consider all the above factors due to the influences by external factors
such as wind and require experience and judgements. The inlet-outlet condition, baffling, can
be optimized to reduce hydraulic short-circuiting and to improve sedimentation performance.
In order to reach closed to the ideal conditions, the inlet is provided with baffles or submerged
ports for equal distribution of water and at uniform velocities. The outlet should be designed
to maintain suitable settling velocities and to minimize short-circuiting. Adjustable plates with
―V‖ notches (50 mm deep at 75-150 mm spacing) are preferred to avoid issues arising from
constructional inaccuracies over plates or submerged orifices.
Basins can be designed with hoppers in the first half of the tank, where most of the sludge is
likely to settle, and equipped with mud valves that can be frequently opened to waste the bulk
of the sludge. This design reduces the frequency of removing the basin from service for
complete cleaning. However, withdrawal of sludge from these hoppers should be frequent and
controlled. Otherwise, if the solids become too thick, flow may "pipe" through to the drain,
leaving the bulk of solids on the sides of the hoppers. Frequent removal of solids through
these hoppers may also disrupt density currents and improve performance.
A mechanical device for sludge scraping is used whenever; the area of setting zone exceeds
30 to 40 m2. This permit a reduction in steep slopes required for natural sludge drainage
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(down 2% for light sludge), thereby making construction of large units with limited depth
economically feasible. The sludge hoppers are located directly below the raw water inlet. The
scraper is either mounted on a cross bridge (Figure 5-48) that travels back and forth along the
basin or consist of a flight and chain system (Figure 5-48) that scrape the bottom from
downstream to upstream of the basin and the surface is scraped in the opposite direction.
The advantage of flight and chain system is to allow slow displacement (not exceeding 1
cm/s) of many individual scrapers. On the other hand, the entire scraper system is submerged,
and the maximum 6m width of the scrapers increases the number of system required.
Traveling Bridge Bridge Travel Scum Trough
Water Level
Outlet zone
Inlet Zone
Sludge hoppers
Sludge collector
In Bridge system, the scraper device controls the scraper movements and bridge direction
changes are fully automatic. The speed of the bridge movement varies from 3 to 4.5 cm/s
depending on the length of the basin. Bridge system can be designed to straddle and scrape
several settling basins at the same time or bridge that span several basins with one scraping
device shifting periodically from one basin to the next. The end carriage has either elastomer-
tyred wheel for rolling directly on concrete with lateral guide rollers, or steel rollers for rail-
mounted units.
Sludge draw off line must be designed to eliminate clogging. Sufficient line velocity should
be provided to prevent deposits. Pipe diameter should be sufficient and pipe runs should be as
straight as possible. Minimum size of pipes to be used for de-sludging is 300 mm diameter for
non-mechanised units and 200-300 mm diameter for mechanical units. Multi suction points
with radial tees are to be provided for effective removal of sludge and separate lines for each
basin. An example hydraulic design calculation for horizontal flow sedimentation basin is
given in Annex E.1.
Circular basin may be either the centre- feed or the peripheral-feed type. In centre- feed, the
water enters through a central inlet and flows radially outwards a continuous peripheral outlet
weir as shown in Figure 5-49. The tracer studies have demonstrated that peripheral-feed
sedimentation basin experience less short-circuiting than centre-feed basins, yet centre- feed
basins are much more common.
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Figure 5-49: Radial-flow basin with rotating half-bridge scraper
The sludge scraper system may be radial or diametral. In radial scraper system, the bottom
scraper is mounted on rods and suspended from supporting bridge that rotates about the axis
of the basin. An on-board drive at one end of the bridge powers a wheel that moves along the
periphery of the unit thereby rotating the bridge. In diametral scraper system, the length of
the scraper unit is doubled. It may be suspended from a diametral bridge with a dual reduction
gear drive at both ends or with the central drive. The central drive is often preferred to
peripheral one. It is nowadays common to incorporate flocculation and clarification enhanced
by up flow solids contact basin.
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Effluent
Sludge
Influent
Coagulated water enters a flocculation chamber located in the centre of the basin.
Flocculation can be provided by variable speed mechanical mixers inside the flocculation
chamber. Flocculated water then enters into annular clarification zone and flocs are settled
and are raked to a centre sludge collection sump for removal. Clarified water is collected from
radial or peripheral weirs.
The lessons learned, advantages and disadvantages of this water treatment applications are
given in Table 5-21. The many disadvantages have limited the application of this design and
have led the way for improved designs.
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Detention period = 2 hours (not usually used as a criterion)
Weir loading = < 9 m3/hr/m of weir length
The flashed mixed coagulated water enters the basin in the hopper-bottomed via pipeline,
flow upwards and passes through a zone of fluidised settled floc (Sludge Blanket). The
passage through blanket act to flocculate and entrap the small particle as shown in Figure
5-52. Above the sludge blanket, there is a layer of clear water in the upper square portion of
the basin. Supernatant runs off from a trough arranged on the surface, and excess sludge is
discharged from the sludge outlet which is provided at the bottom of the sludge hopper.
In theory, any particle with a settling velocity greater than the upward velocity will settle in
the middle of the hopper bottom tank and be removed. But in practice, such basins are more
efficient than expected due to inter-particle collision. Thus, it became usual to operate such
basin to maintain a blanket of fluidised solids in the basin to improve efficiency. The principal
of inter-particle collision in sludge blanket led to more sophisticated up flow basins referred
to as Solid contact clarifier (as their key feature of flocculation).
Settled water channel Decanting trough Inlet
Sludge
blanket
Sludge
concentrator
Bottom sludge
extractor pipe
These clarifiers require competent operation to maintain an optimum sludge blanket layer
with suitable controls for sludge withdrawal. The blanket is sensitive to the coagulant dosage
and to a number of other factors including the prevailing difference between ambient
temperature and the influent temperature. In hot environment in certain circumstances, they
have a tendency to 'roll over' in the afternoon. Shading the basins will assist in some
instances.
The other drawback of this basin is that the size has to be limited due to typically 60 hoppers
and the hopper bottom penetrates deep into the ground and imposes the economic dimension
of the square top (a limit that arrives more quickly in rocky or waterlogged ground. Further, it
is observed that the provision for dewatering the clarifier is to be done by separate pumping
arrangements for cleaning purpose, hence suitable arrangements has to be selected based on
the topography. The basins are normally considered unsuitable for treating waters with the
high silt loads so often in tropical rivers; because tanks are, small and removal of large
quantities of heavy sludge have practical difficulties. Experience with this type of clarifier in
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Sri Lanka has been mixed due to high turbidity variations and not recommended for small
water treatment plants with river water source. Note that the provision has to be given to
extract water / sludge by careful hydraulic provision or by proper pumping arrangement.
Figure 5-53 illustrates a typical commercial re-circulated solid contact clarifier system. This
combine a large diameter, slow speed concentric turbine, generating high volume internal
recirculation to promote mixing, flocculation and solids-contact. The recirculation system is
designed to promote particle growth and improve the removal of suspended solids. Influent
water immediately contacts a large volume of dense floc from previously precipitated sludge
in the recirculation drum and is pumped upward by the turbine. Depending on the application,
a volume of 8 to 20 times the maximum influent rate is re-circulated by the turbine to mix
with new incoming feed, while the final effluent passes under the reaction cone to the
clarification zone. Heaviest particles settle to the floor where they are raked to the centre for
recirculation or discharge.
The circular settling basins with peripheral drive may be designed to include a central area for
flocculation, with associated slow mixers also being mounted on the supporting bridge. The
construction and size of the mixing area differ by model. With regard to the mixing and
circulation there are systems using rotary vanes, water flow and air. Also, there are models
equipped with rotary sludge scrapers to cope with large sludge volume. Table 5-22 presents
some advantage and disadvantage of re-circulated solid contact clarifier system.
When adapting suspended solid contact clarifier, the following considerations shall be taken
into account:
1. The turbidity of water shall be 10 – 1,000 and the fluctuation in turbidity, temperature
and flow rate shall be small
2. The surface loading rate shall be 24-36 m3 /m2 /hr
3. The weir loading rate shall be 8-15 m3 /m2 /hr
4. Detention time shall be 1.5 – 2.5 hours
5. No of tanks shall be more than one
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Figure 5-53: Sludge Recirculation Type (solid contact clarifier system)
Vacuum generated flow pulsations create a homogeneous sludge blanket that results in
excellent effluent quality at minimal operating costs. The typical components of a Pulsator
Clarifier developed by Degrement are shown in Figure 5-54. It is integrated with
flocculation/clarification in one unit, completely automated and requires minimal operator
attention. There are no submerged moving parts, and all underwater components are
fabricated with corrosion-resistant materials.
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1. Raw water
2. Clarified water
outlet
3. Sludge removal
pipe
4. Stilling buffles
5. Upper level
sludge blanket
6. Vaccum
chamber
7. Vaccum pump
8. Air release valve
9. Raw water
distribution
system
10. Sludge
concentrators
11. Reagent feed
Figure 5-54: Pulsator Clarifier (Degrement)
The coagulated water enters vacuum chamber. The air is sucked by means of vacuum pump at
a rate of a half of water flow rate and the water rises in the chamber. When it rises 0.6 m to
1.0 m above the clarifier water level, an electric relay actuates a valve to connect the chamber
to atmospheric pressure. The available hydraulic head creates a surge of water flow through
perforated pipe over the entire floor of clarifier. The units are usually calibrated so that the
vacuum chamber drains into the clarifier in 5 to 20 seconds whereas it takes 20 to 40 seconds
to fill.
The hydraulic surge created in the vacuum chamber is harnessed into gentle turbulence by
baffles to promote flocculation of de-stabilized water. This passes through a sludge blanket,
where previously formed floc particle accelerate flocculation kinetics and filter flocs from
water. Clarified water exist at the top of the sludge blanket and is collected near the water
surface of the basin by a submerged orifice launder system.
The blanket pulses up and down and tends to expand due to the added coagulant and the
impurities in the water, and its level rises regularly. The excess sludge flows into hoppers and
become concentrated there. Sludge is drawn off periodically through the pipes. Overstressing
of the sludge blanket must be avoided to prevent solid carryover. Polymer as flocculation aids
are added to develop a heavier floc less susceptible to carryover. The upwards rise velocity is
also limited to 2.4 m/hr to prevent over expansion of sludge blanket. Detention times in the
units are generally 2 hrs.
The unit has no mechanical sludge mixing system that would break up the floc particles
already formed. Due to the high concentration of the sludge blanket and its role as a buffer, a
poor adjustment of the treatment rate or a variation in the pH have no immediate negative
effect; a slower variation in the turbidity of the settled water is observed, however this does
not produce any massive loss of the sludge in the clarifier.
The pulsation sludge blanket contact clarifier is particularly suited for treating surface water
with low turbidity and high colour content. This is attractive by giving its ability to retain
Powdered Activated Carbon (PAC) and provide large surface area for organic adsorption
from water contacting the blanket. This organic removal feature may make sludge blanket
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contact clarifier more attractive in removal for eliminating pesticides and dissolved organic
carbon more effectively for compliance with increasingly stringent disinfection by product
regulations. Table 5-23 presents some advantage and disadvantage of pulsation sludge
blanket contact clarifier.
Table 5-23: Advantages and disadvantages of pulsation sludge blanket contact clarifier
Advantages Disadvantages
Allow for space reduction and decreased structural- Heavier suspended solids such as silt and
mechanical cost. sand accumulate in the system and require
There is a constant sludge blanket depth regardless of periodic removal.
flow and solid content. Rapid change in raw water quality and
There are no submerged mechanical components temperature more quickly influence this low-
Mechanical systems are limited to vacuum apparatus detention time process.
and sludge blow down equipment. Performance is sensitive to sludge blanket
Sludge blanket can retain PAC for enhanced organic homogeneity and density
removal
Sludge blanket flocculation efficiency.
This can be optimised with laminar modules on the upper part and/or plates in the sludge bed
in the Pulsatube and Ultra-pulsator versions Table 5-24 and clarifier can double its operating
speeds and adapt itself to water at extremely cold temperatures. This is termed as "Super
Pulsator" which utilizes the lamella settling effect to combine the respective advantage of
sludge contact settling, sludge blanket pulsing, and sludge densification. The improved
system is designed for 1 hour detention time with 6 to 7.3 m/hr overflow rates.
A recent development in high rate sedimentation is the plate settler. Plate settlers may be
made of metal, plastic, or waterproof plywood. Flow through the plate settlers may be
classified with respect to the direction of water flow relative to the direction of particle
settlement as.
1) Counter-current; flow upwards
2) Co-current; flow and sediment both downwards
3) Cross-flow; flow horizontal with vertical settlement
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Settling efficiency is dependent upon the perpendicular spacing between the plates, lengths of
plates and angle of inclination. The basin overflow rates for plate settlers are 5-8 times those
of conventional rectangular basins.
Tubes may be circular or square in section, of about 5 cm size and inclined at 60° to the
horizontal. Water is passed up through the tubes, and sediment settles out and trickles down,
keeping the tubes clean. Tubes are usually prefabricated in packs and made of PVC; they are
light and cheap; pipes may also be used. Loading is normally 9 m3/hr per m2 (m/hr). The
range of parameters is given below:
Banks of plates or small tubes, inclined at 45 to 60 angles from the horizontal, are provided
for modification of conventional sedimentation basin.
With the use of tilted plates or inclined tubes, the removal efficiency can be
considerably improved and the required surface area can be considerably lower.
Tilted plates and tubes enhance solid removal because:
• Settling distance that a particle falls to enter the sludge zone is reduced
(surface loading rate is reduced)
• Laminar flow is achieved through the plates or tubes (thus conditions are more
close to ideal settling)
• Density currents, temperature currents and wave actions do not hinder
sedimentation process as in the case of conventional sedimentation basins
Tilted plates or inclined tubes can be used for both rectangular as well as circular tanks.
Sometimes these devices are placed only near the outlet of the basin and positioned so
that water must pass through the plates or tubes.
In order to avoid clogging of the tilted plate or tube settlers, the surface along which
the settling material moves down should be made as smooth as possible.
The spacing of the plates or opening (w) should not be less than 4 cm and for up-flow,
the slope should be larger than 50.
Tube settlers
Basins to operate at two to four times standard application rates.
Cut coagulant dosages by up to half.
Minimize turbidity load on filters.
Increase settling area without increasing basin footprint—new basins can be smaller
and existing basins can handle more flow.
Integrated structural ribs and wave sheet provide substantial loading strength.
Unidirectional tube design prevents floc re-suspension and reduces plugging potential.
Nesting design prevents flow bypass by eliminating gaps between modules.
Available in food grade PVC or PPE.
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Figure 5-55: Typical Forms of Plate Settlers
Co-current Settlers:
Suspension is fed above the settling modules
Settled solids move down the surface in the same direction as the liquid
The over flow rate in tilted plate separator with different flow directions (refer Figure 5-58) is
as follows:
For up-flow (counter current)
Where
S' = overflow rate in tilted plate separator (m/s)
w = distance between the plates (m)
= inclination of the plate with horizontal ()
Q = flow (m3/s)
So = overflow rate for the tank of given size without plates and
Lo, Bo, Ho = length, width and height of the tank (m)
t = thickness of the plate (m)
Theoretically shallow basin should be effective in terms of settling efficiency (short settling
distance)
Shallow, parallel tubes increase surface area and reduce settling distance
Tubes are placed at 50 - 60 efficient settling, self-cleaning of surfaces occur
Typical separation distance between inclined surfaces = 50 mm, with an inclined
length of 1-2m
When used for upgrading existing sedimentation basins, improved surface loading rates of 4-5
times may be obtained and it is also important to upgrade the sludge removal facilities to deal
with the extra volume of sludge. A typical layout of a plate/tube settlers installed in
sedimentation basins is shown in Figure 5-58.
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From flocculator Outlet zone
Support Structure for cleaning purpose
Tube / Plates
Support Structure
Sludge
Zone
In Horizontal flow basin, the space between the system and tank base and inlet wall shall be
1.5 m or more. The average velocity of the flow at the inlet shall be 0.7 mm/min or less.
The installation area of upward flow through plate/tube settling system shall be 90% of the
sedimentation basin and may be 80% due to structural limitations but care should be taken to
avoid short-circuit flows like baffle walls. The space between the system and tank walls and
baffle walls shall be 100 mm or less.
Tube Settlers are designed based on the total projected surface area of tubes. Surface loading
rate of 1.2 m/h for aluminum, iron based coagulants (range from 1-2 m/h). Turbulence causes
uneven flow distribution to the tubes and sludge falling from the tubes must be able to settle
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to the tank bottom (high velocities cause high shear). To avoid turbulence stilling zone of
25% of the total basin area should be left (stilling zone: distance between the inlet and the
settlers. A minimum depth of 3 m should be left below the tubes and a clear space of 2-3 m
above the tubes must be provided. Solids can be removed with same type of equipment as
used in the conventional sedimentation unit.
Typical Loading rates for Plate (Lamella) Settlers range from 0.7-1.7 m/h, which corresponds
to 5-15 m/h for overall basin loading when co-current flow is applied. Launders should be
placed on the order of 1.8 m and submerged orifices should be designed to create head loss–
to enable good flow distribution. Orifice velocity of 46-76 cm/s is adequate. Chain and flight
or bottom tract units are generally used for sludge collection.
A typical layout of an inclined plate or tube settlers installed when a vertical flow clarifier of a
compact design of flocculator is shown in Figure 5-59.
The advantage of these treatment plants is that the products are of lightweight and could be
modified at any time in contrast to concrete structures. However, these plants have limitations
on the capacity say up to 10,000 cum/day under the scale of economy and in movability.
NWSDB has developed its own plants with type drawings available in the Planning and
Design office for 500, 1000 and 1500 cum per day capacity plants. NWSDB has gone up to
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2000 cum/day capacity under this design concept. Higher capacities such as ―SETA plant at
Ambathale‖ are available up to 50,000 cum/day capacity. The ―SETA‖ plant is non-movable
in contrast to the smaller capacity plants.
The main unit operation modules are aerator, flash mixer, flocculator, tube settler and sand
filters. Chemical dosing arrangement need to be incorporated. The function of aerator is
dissolved gas exchange and oxidation. There is a tendency of pH increase in the aeration unit
due to oxidation taking place. This helps to reduce taste and odour, ammonia if any and to
oxidize Fe2+ and Manganese up to certain extent. In designing a tray aerator one concern shall
be the wind effect which will throw the water often out of the trays. The flash mixer shall be
designed to cater for G value, which should be in the range of 1000. In 500 cum/day plant the
flocculator for slow mixing shall be mechanical type as calculations do not allow for a
hydraulic flocculator under practical considerations. The attractive feature of a package plant
is the tube settler, which was developed using the skills of the central workshop of the
NWSDB.
In theory the plate settlers and tube settlers behave in a same manner. In plate settler‘s the
distance between parallel plates shall be 50 mm for optimum removal efficiency under
practical considerations. The best angle of inclination to the horizontal shall be 60 deg. under
the same criteria. In practice, it is difficult to mount the plates. Therefore, PVC tubes of 50
mm were considered for the construction. The recommended length of tubes is 1m. The
central workshop developed the technique of making 1m x 1m x 1m PVC tube modules for
package treatment plants. The hydraulics of the tube settler tank plays an important role on its
performance. Therefore, the tube settler is given a special shape to allow for inlet and up flow
hydraulics, avoiding short-circuiting and sludge collection and management. The advantage
of a tube settler is the area requirement is only about 1/5th of the same for a plain
sedimentation tank. The criteria for settling in a tube settler is the overflow rate in the range of
6 m/h and not the retention time. The rapid sand filters and Chlorine contact tanks could also
be developed under package plant module concepts. It is adequate to provide 100 to 150 mm
hydraulic profile vertical drop between the unit operation modules. All these modules add on
to a complete package water treatment system as shown in Figure 5-60.
Figure 5-62: The lamella settler consists of specially fabricated lamella modules inside
the settling area (SUPER PULSATOR)
Figure 5-63: Sludge collectors inside the Lamella settler tank (SUPER PULSATOR)
The ―SETA‖ plant uses tube settler for settling. The super pulsator is based on incorporation
of tube settlers at the upper zone of the Pulsator. The tube settler technology is based on the
principle ―Particle interception by plate or tube cutting short the particle settling trajectory‖ in
the sedimentation tank. This technology has made it feasible to cut down the settling time to
around 45 minutes. In addition, it is noted that the tube settlers are capable of managing shock
loading of turbidity due to its low retention time requirement. For example, sudden turbidity
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variation from 150 NTU to 300 NTU in a short period during rainy season is well managed by
SETA plant and Super Pulsator at Ambathale.
5.7.8. Dissolved Air Flotation (DAF) Clarifiers
Flotation can be described as a gravity separation process in which gas bubbles attach to solid
particles to cause the apparent density of the bubble-solid agglomerates to be less than that of
the water, thereby allowing the agglomerate to float to the surface. Different methods of
producing gas bubbles give a rise to different types of flotation processes. These are
electrolytic flotation, dispersed-air flotation, and dissolved-air flotation. In dissolved-air
flotation, bubbles are produced by the reduction in pressure of a water stream saturated with
air and preferred for the production of potable water.
Dissolved-air flotation as a primary clarification is particularly effective for the treatment of
algae-laden waters and low-turbidity, highly coloured waters or lightly loaded water giving
light and fragile flocs. Flotation has several process advantages over sedimentation, it can
produce better water quality; it can be operated at high surface loadings, resulting in relatively
small and shallow plants; and it can be started up quickly, with a steady water quality being
achieved within 45 min. In addition, the solids concentration of the sludge produced is
significantly higher (about 3 %) than that of the sludge produced by sedimentation.
Dissolved air flotation is an alternative clarification process ideal for treating raw water with
light particles, such as algae or colour-causing organics, and at low temperatures when
sedimentation is not as effective. Widely used for drinking water clarification in Europe since
the late 1960s . It was not until the early 2000s that DAF became more widely used in the U.S
and other regions. Since that time, DAF has become a mainstream clarification process for
drinking water treatment plants, especially where algae is prevalent, as well as a popular pre-
treatment process for seawater desalination systems to combat red tide or algae bloom
occurrences throughout the world.
DAF is particularly effective in removing low density particles either initially in the water
supply or those produced through precipitation and removal process for protozoa pathogens. It
is demonstrated that DAF achieves 2-3 log removals of Cryptosporidium compared to 2 log
removal by sedimentation.
Figure 5-64 is a process schematic diagram for a DAF drinking water plant. Coagulation and
flocculation are required pretreatment processes. The chemistry of coagulation for
sedimentation and DAF plants is similar, so that coagulant dosages and pH conditions are
identical to forming flocs. An exception is that for some water types, especially those of low
to moderate turbidities, sedimentation plants may require higher coagulant dosages so as to
increase flocculation kinetics and produce flocs large enough to settle rapidly.
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Figure 5-64: Process Schematic Diagram for a DAF
The sizes of flocs in the influent to the DAF tank affects greatly the collisions among flocs
and bubbles in the DAF tank contact zone and subsequently, the rise velocities of flocs with
attached bubbles in the DAF tank separation zone. The flocs with attached bubbles are called
floc-bubble aggregates. Flocculation is used in both sedimentation and DAF plants, but their
objectives differ. When settling follows flocculation, the goal is to produce large flocs capable
of settling at a fairly rapid rate. Flocs with sizes of 100 μm and greater are required to produce
reasonable settling rates. Proper floc sizes for DAF differs, especially in treating reservoir
supplies with low density particles and little mineral turbidity. For treating these type
supplies, the optimum floc size for the DAF contact zone is 10s of µm determined from
modelling, laboratory, and pilot plant data.
Air drum
Air
Coagulant mixing
compressor
Recycle pump
Feed
Water
Floatation
Basin
Clear water
Filtration
Sri Lankan experience demonstrate that the DAF followed by granular media filtration is far
better for the treatment of algae compared to the DAF is placed above the filters where algal
cells may escape during filtration process.
Effective gravity settling of particles requires that they be destabilized, coagulated, and
flocculated by using metal salts, polymers, or both. The same is true for DAF. In gravity
settling, the flocculation process must be designed to create large, heavy floc that settles to the
bottom of the basin. In DAF, flocculation is designed to create a large number of smaller floc
particles that can be floated to the surface.
For efficient flotation, flocculated particles must be in contact with a large number of air
bubbles. Three mechanisms are at work in this air/floc attachment process:
Adhesion of air bubbles on the floc surface
Entrapment of bubbles under the floc
Absorption of bubbles into the floc structure
The size of air bubbles is important. If bubbles are too large, the resulting rapid rise rate will
exceed the laminar flow requirements, causing poor performance. If bubbles are too small, a
low-rise rate will result and tank size may need to be increased. In a typical DAF tank,
flocculated water is introduced uniformly across the end of the tank, near the bottom, into the
recycle dispersion zone. Recycle is continuously introduced through a distribution system of
proprietary nozzles, valves, or orifices. When the recycle flow pressure is suddenly decreased
from its operating pressure to atmospheric pressure, saturated air within the recycle stream is
released in the form of micro-bubbles with a size range of 10 to 100 µm, and averaging
around 40 to 50 µm. These micro-bubbles attach to flocculated material by the mechanisms
described previously, causing flocculated material to float to the surface.
At the surface, the bubble-floc forms a stable and continuously thickening layer of float, or
sludge. If left at the surface, the float can thicken to as much as 3% to 6% dry solids. This can
be an advantage if solids are to be mechanically dewatered, because solids may be suitable for
dewatering without further thickening, or the thickening process can be reduced. Sludge
thickness depends on the time it is allowed to remain on the surface and the type of removal
system employed.
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filtrations are combined into one basin, whereas separate processes are recommended for
better treatment.
Air is supplied from an air compressor controlled by the saturation tank water level. Operating
efficiency of this type system is in the 80% to 85% range and may be improved by using
packed bed saturation tanks to increase the air-water interface. Packed bed saturators are more
expensive, but their greater efficiency may make them more economical in large plants.
Saturated water flows from the saturation tank through a system of headers to the proprietary
recycle dispersion system, where the pressure is dropped to atmospheric and micro-bubbles
are created.
Some of the main advantages of DAF include better performance for removing light particles
such as algae, which are difficult to settle. DAF can also usually achieve lower effluent
turbidity than settling, typically less than 0.5 NTU. It is not as sensitive to temperature,
especially cold temperatures as is common in settling, and the start-up time is very short,
approximately 30 minutes. Further, DAF does not need to generate heavy floc for settling, so
lower coagulant dosage and shorter flocculation time can be used. The process can also
operate at much higher Surface Loading Rates (SLR) than sedimentation, especially in the
high-rate DAF processes, which can be up to 50 m3/m2/hr.
With mechanical sludge removal, the DAF sludge can be quite thick (2 to 5 percent solids),
which eliminates the need for thickening before dewatering. Because of air attachment,
polymer is not required for stable performance, as opposed to high rate settling processes that
must use polymer to attach particles to ballast. Using polymer is a major concern if the
clarification process is used for membrane filtration pre-treatment. However, DAF is not
suited for raw water with high-density solids or turbidity higher than 100 NTU, as the pumped
recycle percentage required is higher, making the process more energy intensive and less
economical than competing technologies. In general, DAF uses more energy than
sedimentation because of the recycle water pumping and air compressing requirements, and it
usually needs protection from freezing and raining to prevent the floated solids from settling.
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Traditionally, the surface loading rates of DAF had been in the 10-15 m3/m2/hr range. With
the advent of high-rate DAF technologies, which can operate at surface loading rates of 30-50
m3/m2/hr, DAF becomes highly competitive in capital cost and reduces site space
requirements, especially at larger treatment plants.
In practice, DAF tanks are often designed to be preceded by flocculation with detention time
of 20 to 30 minutes. Smaller flocculation times are feasible. From theoretical basis, large flocs
are not needed because they would tend to settle rather than float. A floc size of 10 to 30 m
with flocculation time less than 10 minutes provide for effective floatation.
Three common types of mechanical skimming equipment are the chain-and-flight skimmer,
oscillating skimmer, and rotating skimmer. A typical mechanical skimming device is the
chain-and flight type, similar to those used to scrape settled solids in gravity sedimentation
basins. In this case, however, flights are equipped with rubber squeegees or nylon brushes that
drag the float along the water surface and up onto a dewatering beach. As solids are dragged
up the beach, water is squeezed out and drains away, further thickening the float. The float
then drops off the beach into a hopper from which it flows by gravity or is pumped to waste or
thickening.
Solids content of the float is controlled by how often it is removed and by how much excess
water is dragged along with the solids. Adjusting the flight depth into the water is critical to
the amount of excess water and to treatment efficiency. If the moving flights are set too deep,
they can create flow patterns in the basin that will cause poor particle removal and floc carry-
through to the effluent. If the flight is set too shallow, it can disrupt the adhesive forces in the
float blanket. This disruption causes solids to settle back into the tank, resulting in floc carry-
through. The skimmer is usually operated on a timer, with the frequency of operation based
on solids production and the desired level of thickening. All mechanical components are
above water, making maintenance easier than that for gravity sedimentation basins.
The skimmer unit is constructed of stainless steel and plastic. High-hardness plastics provide
low operating friction, allowing the mechanism to operate efficiently. The profile-duplicating
blade is typically a nylon brush that aids in sludge dewatering. The brush allows the sludge to
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thicken to a slightly higher solids percentage while the blade pauses inherently during
operation on the sludge beach. Maintenance is minimal, consisting of checking the plastic
wear blocks and regular servicing of the gear motor.
Rotating Skimmer consists of a rotating shaft with curved or straight blades attached. The
shaft is mounted at the effluent end of the basin above a sludge beach. As the blades rotate,
they pull a portion of the float blanket onto the beach and into a hopper. The general flow of
water toward the effluent causes the blanket to flow up to the beach, where the rotating blades
continually remove a portion.
Hydraulic Removal of float is where float can be hydraulically removed from the surface of a
DAF unit by flooding. This is accomplished by partially closing the basin effluent gate or in
some cases raising a mechanical effluent weir, which causes increased head loss and a small
rise in the water surface level. This increase in level brings the surface up above a weir that
discharges to a sludge drain. Part of the flow through the basin is now diverted over this weir,
dragging the float blanket along with it.
Adhesion of the sludge particles helps keep the blanket intact as it moves across the surface to
the weir. Water is trickled down the basin walls to break adhesion to the wall so that the
blanket can move freely. Float removal is relatively frequent to prevent the blanket from
becoming too thick because a heavy blanket does not flow well. A solids content of about
0.5% is best.
When most of the blanket is removed, usually in about 10 min or less, the effluent gate
reopens and operations return to normal. This mode of float removal eliminates all
mechanical equipment in the basins. The disadvantage is that the removed solids are diluted
and may require more extensive thickening for subsequent mechanical dewatering.
The sludge from coagulation process also contains the metal hydroxide produced. Aluminium
sulphate produces a hydroxide that has bound water. Iron coagulants are ferric sulphate,
ferrous sulphate, and ferric chloride. In all three cases, the iron precipitate formed is ferric
hydroxide. The insoluble ferric hydroxide is a bulky and gelatinous floc. Theoretical
quantities of sludge produced by various coagulant chemicals are listed Table 5-43.
Because of bound water, the actual reported quantities of sludge from alum, ferric sulphate,
and ferric chloride are 0.33, 0.59 and 0.48 respectively. Therefore, it is advisable to increase
the theoretical quantities of sludge when designing sludge handling equipment and processes.
In general, the solid content of coagulation sludge is 0.5 to 2%.
Generally, 80 to 90 percent of the total solids are removed in the sedimentation process. The
mass of the solids must be removed from the sedimentation basin before accumulation
becomes excessive. Although some plants drain basin and remove sludge manually, others
use mechanical sludge collection equipment to move the sludge to a hopper for removal.
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5.8. Filtration
5.8.1. Introduction to Filtration
Filtration is used to separate non-settable solids from water by passing it through a porous
medium. The most common system is filtration through a layered bed of granular media,
typically sand (although many other materials are used). Filtration is used in addition to
regular coagulation, flocculation and sedimentation for removal of colloidal particles from
surface water in order to meet the drinking water standards.
Filtration is one of the oldest forms of water treatment and in fact is nature‘s own water
treatment mechanism in ground water. Filtration, usually considered a simple mechanical
process, actually involves the mechanisms of adsorption (physical and chemical), straining,
sedimentation, interception, diffusion, and inertial impaction as shown in Figure 5-66.
In most of water clarification processes where coagulation and precipitation occur, at least a
portion of the clarified water is filtered. Clarifier effluents of 2-5 NTU may be improved to
0.1-1.0 NTU by conventional sand filtration. Filtration ensures acceptable suspended solids
concentrations in the finished water even when shortcomings occur in the clarification
processes.
Many particles in water are too small to be removed by sedimentation alone. Filtration
removes microorganism and suspended solids passes from sedimentation basins or it
eliminates precipitated particles and flocs remaining after sedimentation.
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Direction of flow during filtration Down-flow / up-flow
Cleaning process Backwash (water or air + water) / manual
Method of flow rate control Constant-rate / variable declining-rate
Rapid filtration is recommended for medium or large schemes where skilled operators will be
available. A comparison of characteristics of the main types of filters is shown in Table 5-24.
Rapid sand filters must be provided with efficient pre-treatment for water with turbidity in
excess of 5 NTU.
The size and shape of the filter media affect the efficiency of the solids removal. Sharp,
angular media form large voids and remove less fine material than rounded media of
equivalent size. The media must be coarse enough to allow solids to penetrate the bed for 50 -
100 mm. Although most suspended solids are trapped at the surface or in the first 25 to 50
mm depth of bed, some penetration is essential to prevent a rapid increase in pressure drop.
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deposits also can get re-suspended in the distribution system when velocity changes or
interruption occurs.
However, turbidity of drinking water has other troublesome implications as well. Sand
filtration removes some cyst-forming microorganisms, such as Giardia, which cannot be
killed by traditional chlorination. Cysts have resistant covers, which protect the
microorganism while it goes into an inactive state. The outbreaks of waterborne
cryptosporidiosis over the last decades are well documented and main concern in water supply
in UK and USA.
Regulations require that at least 99.9% of Giardia cysts and 99.99% of viruses be removed
from drinking water. Since it is difficult to test directly for these microorganisms, turbidity in
water can be used as an indicator for their presence. By requiring a low turbidity in the
finished water, treatment plants are ensuring that few or no Giardia is present in finished
drinking water.
Considerable evidence exist to demonstrate that conventional water treatment process can
give good removal of oocysts (99% or more), but there are number of operational factors
which influence this removal and need to be addressed to minimize the risk of oocysts
breakthrough into the treated water. Of particular importance is the maintenance of good
chemical conditions for coagulation and minimization of particle break through the filters.
When water flows through the filter bed, suspended and colloidal particles are retained by the
filter media. Particles that are larger than the pores in the filter bed will remain on the bed
(Figure 5-67). With rapid filtration, this does not occur often, because the larger particles
(iron or aluminium flocs) are already removed in the preceding floc removal process
(sedimentation or flotation).
The filtration comprised of three principal mechanisms: (a) Transport, (b) attachment, and (c)
detachment. Transport mechanism move a particle into and through a filter pore so that it
comes very close to the surface of the filter media or existing deposit where attachment
mechanism serve to retain the suspended particle in contact with the media surface or
previously deposited solids. Detachment mechanisms result from the hydrodynamic forces of
the flow acting in such a way that certain part of the previously adhered particle, less strongly
linked to the others, is detached from the filter media or previous deposits and carried further
into or through the filter.
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Al or Fe Floc,
10m
Bacillus, 1-2m
Grain Diameter=
400m Diatoms, 10m
Pore Diameter, 52m
Silica Particle,
Clay20m
Particle,
30m
When the trajectory curves, a heavy particle can be transported to the filter medium due to
inertia. If the trajectory approaches the filter grains, then particles can also be intercepted.
Heavy particles are especially subject to sedimentation and lighter particles to diffusion. Due
to these mechanisms, the particle can switch to other trajectories that flow nearer to a grain or
can collide directly with a grain, and it remains at the surface or on the grain.
The suspended solid removal efficiency and the type of dominating transport mechanism
depend on the size of the particle and their size distribution in the filtering water. From
researches it was found that there exists a size of suspended solids for which the removal
efficiency is minimum as shown in Figure 5-69. This critical suspended solid size is about 1
m. For suspended solid larger than 1 m, removal is enhanced by sedimentation and/or
interception, i.e. gravity forces. For suspended solid smaller than 1 m, removal increase with
decreasing particle size.
This is happening due to shift in the removal process combined effects. It concludes that:
Efficiency dependent on particle size;
Greater grain surface area increases efficiency (smaller grains) – angular grains better than
spherical;
Larger grains hold more deposits
higher flow - lower efficiency
Better at higher temperatures – viscosity higher at low temperatures
Down flow more efficient – if gravity particle transport is important
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100
80
60
Removal (%) 40
Diffusion effect Gravity effect
20
0
0.01 0.10 1.00 10.00
Particle size (m)
Figure 5-69: Particle Removal Efficiency in a granular filter
It is observed that attachment can be improved by using optimum polymer dose determined in
the coagulation jar test. The polymers probably enhance attachment in filtration by
adsorption, producing charge neutralization and/or bridging.
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Figure 5-70: Filterability Test
The filter number includes the major parameters of deep bed filtration; inlet and filtrate
concentrations, i.e. clarification capacity; head loss per unit time, i.e. clogging characteristics;
flow rate, which greatly affect the filter economy. Which may depend on its pre-treatment, it
is related to the filter material, because filterability is an interactive property. Any relevant
measure of water quality can be used e.g. turbidity, colour, or coagulant concentration.
No significant numerical value is defined for filterability number, but relative values indicate
relative filterabilities. A minimum value from a number of tests would indicate an optimum
filterability. The apparatus is not a design tool but will enable for preliminary screening of
variable (pre-treatment, media and flow rates) before establishing proper, more complex, and
pilot testing (e.g. 1 m deep column) for design purpose. So there could be considerable
reduction in time and efforts by preliminary use of filterability test.
During operation, solids are removed from the water and accumulate within the voids and on
the top surface of the filter medium. This clogging results in a gradual increase in head loss, if
the flow rate is to be sustained. The total head loss may approach the maximum head loss
provided in the plant, sometimes called the available head loss. After a period of operation,
the rapid filter is cleaned by backwashing with an upward flow of water, usually assisted by
some auxiliary scouring system. The operating time between backwashes is referred to as a
filter cycle or a filter run. The head loss at the end of the filter run is called the terminal head
loss.
One of the following three criteria indicates the need for backwash, whichever occurs first:
The head loss across the filter increases to the available limit or to a lower established
limit (usually 2.4 to 3.0 m) of water.
The filtrate begins to deteriorate in quality or reaches some pre-set upper limit.
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Some maximum time limit (usually 3 or 4 days) has been reached.
Typical filter cycles range from about 12 hours to 96 hours, although some plants operate
with longer cycles. Setting an upper time limit for the cycle is desirable because of concern on
bacterial growth in the filter, and because of concern that compaction of the solids
accumulated in the filter will make backwashing difficult.
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horizontal spacing of 2m. Top of troughs should be
level and dimensions such that maximum flow can
be carried with 50 mm free board.
An example hydraulic design calculation for rapid sand filter and preparation of sand for filter
is given in Annex F.1 and F.2 respectively.
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5.9.2. Filter Arrangements
Filters can be configured in a number of ways in the overall plant layout. It is important to
develop a layout that is the least costly and is operationally optimized. A minimum-cost filter
design is obtained by differentiating the cost function in terms of length-to-width ratio as a
variable.
In larger plants, placing filters in rows on opposite sides of a pipe gallery is common practice.
In smaller plants, a single row of filters results in simpler construction. Typical filter
configurations are shown in Figure 5-71.
Location of the filtered water clearwell under the pipe gallery, and common walls between
filtered and unfiltered water, should be avoided to prevent the possibility that leakage through
the walls may contaminate filtered water. A false floor should be provided in the washwater
gullet to prevent a common wall from existing between unfiltered water in the gullet and
filtered water in the underdrain system. Drainage should be provided for spaces beneath false
floors of this type.
In warm climates, filters may be placed outdoors with precautions for controlling algae
formation in the filter box. One method is provision of shock chlorination of filter influent or
washwater. In colder climates, filters are normally housed to prevent ice formation.
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changes in the filtration rate can have adverse effect on filter performance due to particle
detachment resulting in increase of effluent turbidity.
It should be noted that in the case of a plant with four filters, if one is removed for back
washing, the filtration rate in the three remaining filters is increased by 33%. In Contrast,
capital cost of filters can generally be minimized by designing for the minimum number of
filters consistent with size limitations. Plant expansions are usually accomplished by adding
filters of the same size as existing units, because installing larger filters may require extensive
changes in the filter wash system.
Kawamura (1999) recommends the following formula as a guide to determining the required
number of filters:
√
Where N is the number of filters and Q is the plant design flow rate in million gallons (US
gallons) per day (1 Million gallons per day = 3,785 m3/day). It is recommended to provide at
least two units for small plants processing with 2 Mgd and minimum number of four filters
for medium and large plants those processing over 15 Mgd. However, in the design stage due
consideration should be given to cater the maximum designed flow when one filter is out of
service for maintenance and another filter is closed down for back washing.
Where declining rate filtration is selected, the variable nature of filtration rates, and the
number of filters must be considered in determining the design capacity of the filters. If a
filter of self-backwash type is selected, the minimum number of four filters must be provided
regardless of plant size, and preferably six in order to produce sufficient water to wash a filter
effectively.
The maximum dimensions of single filter are generally determined by the economic sizing of
filter backwash facility and possible difficulties in providing uniform distribution of backwash
water over the entire filter bed. The practical maximum size of typical gravity filter is about
100 m2. This size has been provided for plants of capacity over 10 mgd and about 50 m 2 for
plants of capacity less than 10 mgd.
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Pressure filters are usually limited by shipping constraints. The largest standard units typically
available are 3.7-m tanks. This limits vertical filters to about 10 m2 of filter medium.
Horizontal filters are normally not longer than 12 m. Larger units of both types can specially
be fabricated on site.
Available head may be restricted by site conditions and plant layout, by the designed
maximum length of filter run, by optimizing head loss, or by terminating turbidity
breakthrough. Ideally, allowable head loss is determined from pilot plant studies. Fixed head
losses through piping, venturi meters, and throttling valves can be calculated from
manufacturers' literature and by hydraulic analyses. Head losses through filter media are
determined by pilot plant studies or are calculated from Kozeny equation.
Once these factors are known, water depth and weir elevation can be established to achieve a
cost-effective design. Objectives in designing a filter box should be to minimize the cost of
construction and to avoid the possibility that the filter will develop negative pressures.
Wide varieties of underdrain systems are in use, however, they can be grouped into four basic
types. There are as follows:
Manifold-lateral system
Block underdrain system
False-floor underdrain
Porous bottom underdrain
A pipe lateral system uses a control manifold with several perforated laterals on each side.
This type is the oldest type of filtered water collecting system. Piping materials include
ductile iron, and PVC. The perforations are usually placed on the underside of the laterals to
prevent them from plugging with sand. This also allows backwash to be directed against the
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floor, which helps to keep gravel and sand beds from being directly disturbed by the high
velocity water jets.
The perforated pipe laterals are located at frequent intervals along a manifold (Figure 5-72).
Perforations in the laterals are 6 to 13 mm in diameter, located on 8- to 30-cm spacing.
Orifices are normally spaced at 8 to 30 cm and laterals at roughly the same spacing as the
orifices. Approximately 45 cm of support gravel is required to cover a lateral network. Three
to five graded layers are usually involved, with sizes varying from 38 to 3 mm.
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compensating lateral (upper), shown in Figure 5-74. Small control orifices open from the
feeder lateral directly into the compensating lateral. Washwater and air are admitted to and
flow through the feeder lateral and rise to discharge from the control orifices into the
compensating lateral. The triangular shape of the primary lateral distributes incoming
washwater and air uniformly along its length. Support gravel is typically used with this type
of underdrain, graded in an hourglass configuration. As a replacement for support gravel, an
integral media support (IMS) cap made of plastic beads sintered together may be installed on
top of the plastic block underdrain, as shown in Figure 5-74. Top openings on these types of
underdrains are about 6 mm in diameter. Water quality should be reviewed closely prior to
use of an IMS cap.
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Figure 5-75: Forms of False-Bottom Underdrains
A false-floor slab (or a steel plate in pressure filters) is located 0.3 to 0.6 m above the bottom
of the filter, thus providing an underdrain plenum below the false floor. Nozzles to collect the
filtrate and distribute the backwash water are located about 9 to 150 cm centres. Nozzles may
have coarse openings of about 6 mm, or they may have very fine openings that are sufficiently
small to retain the filter medium. The nozzles may be equipped with a stem protruding about
15 to 23 cm into the underdrain plenum. One or two small holes or slots in the stem serve to
distribute air, either alone or in combination with water.
Water that passes the filter bed is drained through nozzles to the filtrate reservoir. Nozzles are
synthetic tubes that are incorporated into the construction of the filter bottom. To avoid loss of
filter sand, perforated heads are placed onto the tubes (Figure 5-76). Frequently, a number of
support layers of coarse filter material are placed between the filter bottom and the filter bed
to enable larger slot sizes in the nozzle, to avoid clogging the nozzles. In addition to draining
the filtered water, nozzles also have a function in the supply of backwash water and air. The
most important aspect is a uniform distribution of water and air over the filter bed, which can
be achieved by introducing a considerable filter bottom resistance (0.5-2 m).
Installing nozzles with the correct size air holes (and/or slots) in the stem for air scouring is
critical for achieving the right amount of airflow and backpressure. The location, dimensions
and number of air holes and slots are other important factors in the design of the filter nozzle.
For the nozzle to work effectively it is essential that the air holes and slots are specifically
designed to suit the capacity of the backwash air supply.
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Figure 5-76: Type of Filter Nozzles and their Installations
Nozzles that have a short stem without backwash holes/slots are not suitable for air scouring
as they will use too much air and so they are not able to guarantee the equal air distribution in
the total number of nozzles installed in the filter drain floor. They are only for use with water
backwashing. Designing, constructing and installing the correct nozzles to suit system
demands is fundamental to the effectiveness of filtration process.
Nozzles differ in type and size. The main parts are the nozzle and the stem. The width of the
slots in the nozzle is chosen based on the filter media and must be smaller than the smallest
particle of the filter material. In order to create an even distribution of air over the entire filter
bottom during backwashing, resistance is necessary over the filter bottom. This resistance is
created by the pipe that is attached to the nozzle. This pipe causes an air cushion, which in
turn causes resistance, underneath the filter bed. This cushion can be varied in thickness by
changing the position of the slot in the stem. The diameter of the hole can be accurately
calculated to fit the volume of necessary backwash air. As this is a difficult calculation and
sometimes different volume of air is used during backwashes, a second hole can be made in
the stem. When a larger volume of air is used, it can also escape through this second hole. The
distribution of air over the filter will remain even.
A stem with a groove can be used as an alternative. For this, however, it is necessary that the
filter bottom is horizontal, in order to get an even distribution of air over the filter. This
alternative is therefore not preferred.
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contribute to clogging during filter washing. Some failures resulting from plugging and
breakage have been experienced with this type of underdrain.
Additional problems that may occur include breakage because of the brittle nature of the
porous material and failure of sealed joints between plates. Porous bottoms have been used
successfully in a few locations, but they are less widely accepted than the block or false-
bottom underdrain systems discussed previously.
Each gravel layer should be as uniform as possible, preferably with the 10 and 90
percent passing diameters not more than a factor of 1.414 apart. In the United States, a
sieve size ratio of 2 for the passing and retaining sieves is commonly accepted.
Bottom layer lower grain size limit should be 2 to 3 times the orifice diameter of the
underdrain system.
Top layer lower grain size limit should be 4 to 4.5 times the ES of the media to be
retained.
From layer to layer, the upper grain size limit of the coarser layer should be 4 times
the lower grain size limit of the adjacent finer layer.
Each layer should be at least 7 cm thick, or 3 times the upper grain size limit of the
layer, whichever is greater.
Note that the under drain system must be checked by back washing the system after installing
the filter nozzle supports with caps before placing the support layer or filter media in order to
correct any fault at earlier stage. Then at least be re-checked after installing the nozzle to
measure the even distribution of air or water. Further, the bottom slab of false bottom has to
be designed for both side loading (both filter media and back wash thrust) and resistant
against shear.
The volume of wash water required to wash a filter will depend on the depth of the filter
medium and the vertical distance from the fixed-bed surface to the overflow level. The greater
the depth of medium, the greater the water volume needed to flush the dirt out of the medium
and into space above the medium. The greater the vertical distance from the surface of the
medium to the wash-water overflow level, the greater the volume needed to wash the dirt out
of the filter box. Typically, it will take about four displacement volumes for the void volume
in the bed plus the water volume above the bed to reach the overflow level.
If backwash troughs are used, they must be of adequate size and of appropriate spacing to take
away the dirty backwash water without surcharging. Spacing is dictated by maximum
horizontal travel of the water. At maximum backwash rate, there should be a free fall of the
water into the troughs, even at the upstream end. The top edges of the troughs should all be at
the same elevation, and all should be level so that the flow is withdrawn evenly over the
whole bed.
In filters with backwash troughs and washed with full-bed fluidization, the expanded media
surface should be lower than the bottom of the troughs. If the expanded media rises up
between the troughs, the effective vertical flow velocity is increased and the danger of
carrying the filter medium into the troughs is increased.
The wash-water volume required per wash to clean the filter could be reduced by decreasing
the vertical distance from the fixed bed surface up to the top edge of the troughs. The
temptation to do this must be resisted, however, because the danger of loss of filter medium
would be increased. Loss of filter medium is greater when anthracite is used. In this case, to
minimize the loss of anthracite, the vertical distance to the edge of the troughs should be
increased above the traditional 0.75 to 0.9 m, to 1.1 to 1.2 m. This, in turn, will require a
greater volume of wash water to complete the backwash.
In the past, wash water was drained to wastewater ponds, so that the solids would settle and
the supernatant water was drained to the surface water. Because of stricter regulations,
concerning discharge to surface waters, soil protection and groundwater protection measures,
backwash water has to be treated before discharging. After UV-disinfection, the treated water
can be recycled into the main treatment process only if no polymers are used. An alternative
backwash water treatment plant consists of micro-/ultra-filtration.
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fine, denser particles are at the bottom. Down-flow filtration allows deep, uniform penetration
by particulate matter and permits high filtration rates and long service runs. Because small
particles at the bottom are also more dense (less space between particles), they remain at the
bottom. Even after high-rate backwashing, the layers remain in their proper location in the
mixed media filter bed.
From researches, it is found that the particle removal efficiency decreases with diameter up to
2 mm (from 70% to 40%) and rapidly increases with diameter up to 1 mm. This is happening
due to shift in the removal process combined effects. It concludes that:
Efficiency dependent on particle size;
Greater grain surface area increases efficiency (smaller grains) – angular grains better than
spherical;
Larger grains hold more deposits
higher flow - lower efficiency
Better at higher temperatures – viscosity higher at low temperatures
Down flow more efficient – if gravity particle transport is important
Table 5-27 lists four media that are used in multilayer filtration. Several other mixed media
combinations have also been tested and used effectively. The use of too many different media
layers can cause severe backwashing difficulties. High wash water requirements would also
result.
Anthracite/sand dual media filter beds normally provide all the advantages of single-media
filtration but require less backwash water than sand or anthracite alone. Similar claims have
been made for anthracite/sand/garnet mixed units. The major advantages of dual-media
filtration are higher rates and longer runs.
The conventional rapid filter generally uses sand with an effective size of 0.6 mm and a
uniformity coefficient of 1.5-2.0. This results in stratification of the media after backwashing,
in which the fine medium remains at the top and the coarse medium at the bottom of the filter
bed. This sand arrangement will restrict the effective use of the entire filter bed. To overcome
this problem of gradation, two alternative media have been proposed, notably (i) dual-media
and multi-media filters, and (ii) coarse size, narrowly grade media filters.
The size of the media must be carefully selected so that the water used for fluidizing and re-
stratifying the bed does not cause severe intermixing. Optimum conditions for minimizing the
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intermixing exist, depending on the media type, specific gravity and size involved. As an
alternative to anthracite, polystyrene beads, coconuts shell charcoal, or natural coke may be
used. Heavier materials such as garnet sand, limonite or magnetite may be used as the lower
medium.
For small-size rapid filters, it is common to use only two materials in combination; 0.3 – 0.5
m of sand with an effective size of 0.4-0.7mm as the under-layer, topped by 0.5 – 0.7 m of
anthracite with an effective size of 1.0 – 1.6 mm. Pilot testing in Sri Lanka using a layer of
50-60cm coconut charcoal (specific gravity of 1.42) of 0.83 – 1.4 mm size over a 25 cm layer
of sand (0.5-1.44mm size) has shown good results.
In coarse media filtration, narrowly graded coarse sand with an effective size of 2mm, placed
to a greater depth can be used instead of sand with smaller effective size (0.45 – 0.55) and a
large uniformity coefficient (about 1.5). The filter can be operated at a higher rate, and the
deeper penetration and higher storage capacities in the narrowly graded coarse medium leads
to longer filter runs. However, due to greater particle deposition throughout the filter,
backwashing requirements are higher. Generally, air-water backwashing is necessary in
coarse medium filters and these requirements are higher than for conventional filters, and the
under drain system may also require modification.
When dual media filters are installed in plants it will be important to provide a high pressure
hose line to jet in to the expanded charcoal during backwash. Mud balls form quickly in the
light charcoal media. They must be broken up and washed out otherwise problems will
quickly develop. A high-pressure jet stream directed into the expanded bed throughout the
wash will do the job.
Filter control systems currently in use can be divided into two categories: mechanical control
systems, and non-mechanical control systems (that achieve control by the inherent hydraulics
of the operating filters). Control systems can also be classified as equal rate systems or
declining rate systems, as was done by Browning (1987). Five control systems are shown in
Figure 5-78, using Browning‘s classification system and nomenclature:
No instrumentation is required for flow rate or head loss measurement on the individual
filters. This is the simplest system for operators because the head loss is clearly evident
merely from observing the water level in the filter box, and there is no control equipment or
instrumentation to maintain.
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5.9.7.2. Proportional-Level Influent Flow Splitting
This is an equal-rate mechanical system in which flow control occurs by inlet flow splitting
as in the prior system (Variable-Level Influent Flow Splitting). A flow splitting weir or orifice
at the inlet of each filter is located above the operating water level of the filter. However, each
filter requires a level transmitter, a level controller, a modulating valve, and a head-loss
instrument. The modulating valve acts to control the water level in the associated filter, not as
a flow-rate controller. The degree of opening of the effluent modulating valves is proportional
to the water level in the associated filter, being closed when the level is at the bottom of a
preselected water level band, and open when the water level is at the top of the band. Head
loss is monitored for backwash initiation. No flow-measurement instrumentation is required
for the individual filters.
When everything is working properly, flow rate through each filter will be equal. However,
equipment malfunction often results in unequal flow that often goes undetected. Head loss is
monitored for backwash initiation.
As solids accumulate in the filter media, the water level rises in all connected filters to
provide the head required to drive the flow through the filter media. Water level is monitored
at a single location for backwash initiation. In some plants, backwash is initiated when the
filtration rate of the dirtiest filter drops to a preselected level, or on a time-interval basis. The
filtration rate of each filter declines in a stepwise fashion after each backwash. As a clean
(backwashed) filter is returned to service, it assumes the highest rate of filtration.
A fixed-flow restrictor (orifice plate or fixed-position valve) is provided for each filter to limit
the starting rate on a clean filter. No instrumentation for flow rate or head loss measurement is
required on individual filters. However, operating personnel prefer to have some flow-rate
indication to help them understand the system and for diagnostic purposes. Less total filter
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system head loss must be provided because head consumed in turbulent head losses early in
the filter run is reallocated to clogging head loss as the filtration rate declines.
In this method, incoming flow is supplied to all operating filters on a free-flow basis to meet
their individual operating rates. There are no effluent controllers. The only control is the
effluent overflow arrangement for declining rate operation. Figure 5-79 shows the general
arrangement for declining rate operation.
All of the filters in the bank of filters served by the common influent header get dirty; thus,
the flow through the dirtiest bed tends to decrease the most rapidly. This causes the flow to
redistribute itself automatically so the cleaner filters pick up the capacity lost by the dirtier
filters. The water level rises slightly in the redistribution of flow to provide the additional
head needed by the cleaner filters to pick up the decreased flow of the dirtier filters. The
cleanest filter accepts the greatest flow increase in this offset and the decreased flow through
dirtier filters; as a result, the flow rate does not decrease as much or as rapidly as expected.
This method of operation causes a gradually declining rate towards the end of a filter run. The
rate increases, which do occur always, in the the cleaner filters of the filter bank, where they
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will have the least effect on filter effluent quality. These rate changes, both upward and
downward occur gradually and smoothly without any automatic control equipment.
There are many advantages to this scheme in terms of better filtration and simpler operation
and maintenance. However, another very important advantage is that many existing plants can
easily be adapted to these processes. The needed modification can often be done with local
resources (see also section Error! Reference source not found., upgrading Existing Filters).
All of the filters in the bank of filters served by the common influent header get dirty; thus,
the flow through the dirtiest bed tends to decrease the most rapidly. This causes the flow to
redistribute itself automatically so the cleaner filters pick up the capacity lost by the dirtier
filters. The water level rises slightly in the redistribution of flow to provide the additional
head needed by the cleaner filters to pick up the decreased flow of the dirtier filters. The
cleanest filter accepts the greatest flow increase in this offsets and the decreased flow through
dirtier filters; as a result, the flow rate does not decrease as much or as rapidly as expected.
If the downstream control point is located above the top surface of the medium, no possibility
of having pressures below atmospheric pressure (i.e., negative head) exists anywhere within
the filter medium or underdrain system because the static water level is above the surface of
the medium. Also, no possibility of accidentally allowing the filter water level to drop below
the top surface of the medium (i.e., partially dewatering the filter medium) exists. These
advantages are not obtained without cost, however, because all of the needed head to operate
the filter must be placed above the downstream control level, and this means a deeper filter
box.
The three constant rate systems have the common characteristic that the entire filter system
operating head provided, which is essentially constant, is consumed throughout the filter run.
The head that is not utilized by the dirty filter medium is wasted either in the modulating
control valve of the mechanical systems, or in free fall into the filter box for the influent flow-
splitting system. The declining-rate systems have a lower total filter system head requirement
in the plant hydraulic profile because the total head is reallocated as the filter cycle proceeds
as described earlier.
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The two non-mechanical systems (i.e., without proportional level control) have the inherent
advantage that sudden changes in filtration rate cannot be imposed on the filter. If the total
plant flow is increased or a filter is removed from service, the filters can only pick up the load
by changing water level to generate the head needed to accommodate the increased flow. This
changing of water level takes time, so that the change in filtration occurs slowly and smoothly
without mechanical devices.
Slow, smooth changes in filtration rate are also possible in properly designed proportional-
level mechanical control systems. The rate-of-change of the modulating control valve position
should be proportional to the divergence of the measured variable (flow rate or level) from the
desired value. The proportional level control band should be substantial. The drive for the
control valve should be an electric motor rather than a pneumatic or hydraulic valve drive,
because the latter two drive types are prone to sticking, overshooting, and hunting problems
as they age. No industry standards for filter control systems are available, so that some
systems do not have all of the attributes listed above.
In all of the control systems, there is legitimate concern about the passage of protozoan cysts
during the ripening phase at the beginning of the filter cycle. As discussed elsewhere,
provision for a filter-to-waste mode is the best available solution.
Up flow filters have been used successfully in Singapore and Western Europe for some years.
They may in some cases be useful as a pre-treatment for rapid or slow sand filtration but are
suitable only for water with low or medium turbidity (< 80 units) or they will be subjected to
short filter runs and restricted flow rates, due to high head losses.
Up-flow units contain single filter medium–usually graded sand. The finest sand is at the top
of the bed with the coarsest sand below. Gravel is retained by grids in a fixed position at the
bottom of the unit. The function of the gravel is to ensure proper water distribution during the
service cycle. Another grid above the graded sand prevents fluidization of the media. Air
injection during cleaning (not considered as backwash because the direction of flow is the
same as when in-service) assists in the removal of solids and the reclassification of the filter
media. During operation, the larger, coarse solids are removed at the bottom of the bed, while
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smaller solids particles are allowed to penetrate further into the media. Typical service flow
rates are 290-590 m3/m²/day.
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5.9.11.1. Appropriate Source Waters for Direct Filtration
Direct Filtration has been recommended for raw water turbidity up to 20 NTU and colour up
to 30. However, coagulant dosing is required when turbidity exceed 5 NTU. A very light dose
of either alum or ferric chloride coagulant is required to destabilize the low turbidity content
so that it can be readily trapped on or in the filter media. This would require less use of
coagulant, and increased filter loading rates, with an increase in filter washing during times of
high turbidity.
The suitability of raw water for direct filtration may be investigated using jar tests and
filtration through standard laboratory filter paper as a screening technique to select
appropriate waters for direct filtration, refer Annex F.3 for the filter paper test. An AWWA
report on direct filtration defined a water meeting the following criteria as a ―perfect
candidate‖ for direct filtration:
Colour < 40 colour units
Turbidity < 5 NTU
Algae < 2000 asu/mL
Iron < 0.3 mg/L
Manganese < 0.05 mg/L
*asu/ml = areal standard units/ml; 1asu is 20 × 20 𝝁m and for a medium-sized algae 1 asu/ml
can approximated to 0.1 𝝁g/l of chlorophyll ‗a‘.
The selection of the coagulant dosage for direct filtration is best determined by full-length
filter cycles using pilot or full-scale filters. Jar tests are often misleading because the goal in
direct filtration is to form small pinpoint floc that are barely visible but that will filter
effectively. Thus, the usual criteria used to judge jar test observations, such as formation of a
large floc or clear supernatant liquor, after settling, are not appropriate for direct filtration.
The jar test and filter paper filtration technique is somewhat better, but it provides no
information on terminal breakthrough behaviour or rate of generation of head loss.
Failure to clean filter media adequately can lead to a multitude of problems. Initially,
mudballs form and accumulate in the bed, causing clogging. Then the clogged areas contract
as head loss increases. This shrinkage opens cracks in the filter media surface and sometimes
at the filter walls. Cracks can cause short-circuiting of the bed during filtration, with
subsequent decline in filtered water quality. Clogged areas also contribute to channelling of
washwater, which can lead to be offended.
During filtration, the filter media becomes coated with floc, which plugs the voids between
the filter grains, making the filter difficult to clean. The media must be expanded to clean the
filter during the backwash. This expansion causes the filter grains to violently rub against
each other, dislodging the floc from the media. The filter backwash rate has to be adequate to
expand and agitate the filter media and suspend the flocs in the water for removal. However,
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if the filter backwash rate is too high, media will be washed from the filter into the troughs
and out of the filter.
The vertical velocity of the water during the backwash must be greater than the settling
velocity of the floc, but less than the settling velocity of the media in order to remove
deposited floc without removing the media. The velocity of the floc has been found to range
between 2.5 and 25 cm/min. and a minimum peak wash rinse rate should be 30 cm/min. The
settling velocity of the media can be calculated by Newton‘s equation. For water at 20C, for
sand with the specific gravity of 2.61 and anthracite with the specific gravity of 1.5 are Vs
(sand) and Vs (anthracite).
In most cases, the filter backwash rate will not break up the mass on the top of the filter. The
design engineer will recommend the installation of a surface wash of some type, the most
common being a set of rotary arms that are suspended above the media during filtration.
During filter backwash, the media expands upwards and around the washing arms. A newer
method of surface wash involves using air scour before the water wash. This is a very
efficient method but requires the installation of a large air blower to produce the air. The
normal design for the air wash will be 0.6-1.5 cubic meter of air per square meter of filter
area.
The filter should be backwashed when the following conditions have been met:
The head loss is so high that the filter no longer produces water at the desired rate; and/or
Floc starts to break through the filter and turbidity in the filter effluent increases; and/or
A filter run reaches a given hour of operation.
If a filter is taken out of service for some reason, it must always be backwashed prior to
being put back on-line.
The decision to backwash the filter should not be based on only one of the above conditions.
If a filter is not backwashed until the head loss exceeds a certain meters, the turbidity may
break through and cause the filter to exceed the standard of 0.2 NTU of turbidity to satisfy
WHO guideline. Similarly, depending on filter effluent- turbidity alone can cause high head
loss and decreased filter flow rate, which can cause the pressure in the filter to drop below
atmospheric pressure and cause the filter to air bind and stop filtering.
If the water applied to a filter is of very good quality, the filter runs can be very long. Some
filters can operate longer than one week before needing to be backwashed. However, this is
not recommended as long filter runs can cause the filter media to pack down so that it is
difficult to expand the bed during the backwash.
The normal method for backwashing a filter involves draining the water above the filter to a
level of 150 mm above the filter media. The surface wash is then turned on and allowed to
operate for several minutes to break up the crust on the filter. After that, the backwash valve is
opened, allowing backwash water to start flowing into the filter and start carrying suspended
material away from the filter.
The time elapsed from when the filter wash is started until full flow is applied to the filter
should be greater than one minute. After a few minutes, the filter backwash valve should be
fully opened to allow full expansion of the filter media. Generally, this expansion will be 20-
40 percent over the normal filter bed volume. The expansion needed will depend on how
much agitation is needed to suspend the filter media to remove the suspended material trapped
in the filter.
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With a multi-media filter, the rate must be high enough to scrub the interface between the coal
and the sand, where the highest amount of suspended solids will be removed from the media.
The filter will be washed 10-15 minutes, depending on the amount of solids that must be
removed. The best way to determine how long the filter should be washed is to measure the
turbidity of the backwash water leaving the filter. In some cases, a filter is washed too long.
This could be costly. Too much backwash water is used, and it must be treated after use.
Backwash valves must be opened slowly, and butterfly valve is preferred over gate valves and
to seal water. Opening the valves too rapidly can cause serious damage to the filter
underdrain, filter gravel, and filter media.
The selection of a washing technique is closely tied to filter media and underdrain selection.
In current practice, washing normally includes up-flow water flushing. The rate and duration
of water flushing are variable, however, and may be supplemented with air scour or surface
water wash. Operational sequencing of combined washing systems and the source of the
washwater introduce additional variations.
Bleeding flow from a high-service discharge main result in energy loss because of pressure
reduction required before washing to avoid media loss. For direct washing, a pressure-
reducing valve or orifice is placed in the washwater supply line. For bleeding flow to fill a
washwater tank, an altitude valve or other level control device is used to control the water
level in the tank. In either case, the washwater supply line is often sized to restrict the
maximum amount of water that can be delivered. Both options avoid provision of separate
washwater pumps. Direct washing also avoids construction of a washwater tank but presents
greater difficulty in controlling washwater flow. Because of the large pressure drop often
involved in supplying washwater by high-service bleeding, the potential for cavitation in or
following head-dissipating devices in the supply line is significant.
If elevated finished-water storage is not available to provide head for filter washing,
washwater may be pumped to a separate washwater storage tank or directly to the filters. Use
of a washwater tank permits pumping at a lower rate. Tank storage volume must be sufficient
to permit filter washing at the maximum wash rate while the pump operates at the minimum
run times. A number of proprietary filters are available that obtain washwater by means other
than those previously listed.
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Arrangement Unchlorinated backwash typically Filtered water tank acts as both storage for
requires a separate filtered water tank and backwash water and chlorine contact tank
chlorine contact tank (or baffled zone in (prior to pH correction / lime dosing). No
same tank), and affects the upstream requirement for separate filtered water tank
hydraulic profile and potentially capital or zone for chlorinated and unchlorinated
costs. volumes.
Chlorine contact before lime addition
should be considered.
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higher than that of the filter washwater troughs or side weir. This difference in level must be
sufficient to provide the head needed to deliver adequate water for backwashing.
To obtain a high enough backwash rate, the number of filter should be 4 to 6, while to
overcome the resistance against back washing, the depth of supernatant water must be large, 3
to 4m, increasing the cost of construction.
The practical application normally dictates the method selected. Filter bed expansion during
up-flow water washing results in media stratification. Air washing results in filter media
mixing. If stratification is desired, air scour must be avoided or must precede fluidization and
expansion with water. There are a number of conflicting opinions on the best method of
backwash.
The backwashing system is the most frequent source of filter failure. Therefore, selecting the
type of backwashing system and ensuring the proper design, construction, and operation of
that system are key elements in the success of a water treatment plant. Two prominent
systems of backwashing currently in use are compared in Table 5-29.
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Table 5-29: Comparison of Two Backwash Alternatives for Granular Bed Filters
Backwash method
With fluidization Without fluidization
Applications 1. Fine sand Coarse mono-medium
2. Dual media Sand or
3. Triple media Anthracite
Routines used 1.Water wash + surface wash Air scour + water wash
2.Water wash + air scour simultaneously during overflow
Air first Finish with water wash only
Water second
No air during overflow
Fluidization Yes, during water wash No
Bed expansion 15 to 30 percent Nil
Wash troughs Usually used Usually not used
Horizontal water travel to Up to 0.9 m Up to 4 m
overflow
Vertical height to 0.75 to 0.90 m 0.5m
overflow
Maximum shear on the grains theoretically occurs (for typical filter sand) at a bed expansion
of 80% to 100%. The increase in shear with increasing bed porosity is relatively slight beyond
the point at which expansion begins. Optimal expansion may be less than 20%. Normally,
when water wash is applied exclusively, an expansion of 20% to 50% is used. Water wash at a
sufficient rate to substantially expand (10% or greater) a granular bed is generally referred to
as high-rate water wash. Water wash incapable of fully fluidizing a bed (i.e., less than 10%
expansion) is generally referred to as a low-rate water wash.
High-rate water wash tends to stratify granular media. In multimedia beds, this action is
essential and beneficial, but it is not required for uniformly graded single-medium beds. In
single-medium beds, high-rate water wash results in movement of the fine grains to the top of
the bed, which has a negative effect on head loss and filter-run length.
The traditional backwash system uses an upflow water wash with full bed fluidization.
Backwash water is introduced into the bottom of the bed through the underdrain system. It
should be turned on gradually over at least a 30-s time interval to avoid disturbing the gravel
layers or subjecting the underdrain to sudden momentary pressure increases. The filter
medium gradually assumes a fluidized state as the backwash flow rate is increased and the
bed expands. The backwash flow is continued with full fluidization until the waste wash water
is reasonably clear: a turbidity level of about 10 NTU is sufficiently clear. Then the supply
valve is shut off. Shutoff is not as crucial as the opening phase because no danger to the
underdrain or gravel exists. However, a slow shutoff will result in a greater degree of
restratification.
According to Baylis, backwash by water fluidization alone is a weak washing method. The
reason for that weakness is attributed to a lack of any abrasion between the grains in a
fluidized bed. For that reason, backwashing is usually assisted by an auxiliary scouring
system, such as surface wash or air scour. The contrasts between the auxiliary scouring
systems are presented in Table 5-30.
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Table 5-30: Contrasts between Backwash Alternatives
Backwash method
With fluidization Without fluidization
Without With Surface With air scour Simultaneous air
Auxiliary wash auxiliary auxiliary + water
scour backwash
Wash effectiveness Weak Fair Fair Good
Solids transport to overflow Fair Fair Fair Good
Compatible with fine media Yes Yes Yes No
Compatible with dual and triple Yes Yes Yes No
media
Compatible with graded support Yes Yes Yes No
gravel
Potential for media loss to overflow Nil Yes, mainly Yes, unless Major, unless
for coal used properly used properly
Experience in the United States with high-rate water wash used alone is extensive. It is
generally successful for applications that filter iron precipitates from groundwater or remove
colour from otherwise high-quality surface water. The relatively weak cleaning action of
water wash without auxiliary scour of some type, however, generally renders it unsuitable for
filters removing large quantities of suspended solids or for applications where polymers are
used. Optimum expansion rate is influenced by the media size and porosity.
Rotary systems are more often utilized, and they generally provide better cleaning action,
lower water requirements, and less obstruction for filter access. Possible problems with
rotating surface wash units include failure to rotate, nozzle clogging, failure to clean in
corners, abrasion of concrete walls near the point of closest passage of the arm, and locally
high velocities caused when passing under washwater collection troughs. Either type of
system may fail to provide auxiliary scour where it is most needed. This can be especially true
in multimedia beds if substantial removals are occurring at media interfaces.
Surface wash systems are typically suspended about 5 cm above the surface of the
unexpanded filter bed and employed prior to introducing washwater during low-rate
backwash. Use of surface wash during high-rate backwash may cause media loss over the
waste troughs. Systems have also been placed in the unexpanded bed of dual- and mixed-
media filters where there is an accumulation of filtered materials deep within the filter bed.
Dual-arm rotary systems that have one arm above and one arm below the unexpanded surface
are also available. Nozzle plugging with media has been a problem with the submerged units.
Orifice sizes are typically 2 to 3 mm in diameter and are directed downward 15° to 45° below
the horizontal. Operating pressures are typically 350 to 520 kPa. Fixed-nozzle systems deliver
4.9 to 9.8 m/h and rotary systems deliver 1.2 to 2.4 m/h. Standard units are available up to
approximately 4 m in diameter for rotary systems. Some models induct air into the washwater
jets. A typical surface agitator and arrangements is shown in Figure 5-82.
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Figure 5-82: Typical surface agitator and arrangements
Surface wash jets are operated for 1 to 2 min before the upflow wash and usually are
continued during most of the upflow wash, during which time they become immersed in the
fluidized filter medium. Surface wash is terminated 2 or 3 min before the end of the upflow
wash.
Surface wash has a number of advantages and disadvantages. The advantages include the
following:
It is relatively simple, requiring only a source of high-pressure water in conjunction
with a system of distribution nozzles
It is accessible for maintenance and repair, because it is located above the surface of
the fixed bed
Some disadvantages of surface wash systems are:
Rotary-type washers sometimes stick temporarily and fail to rotate as intended
If mudballs do form in the bed and reach sufficient size and density, they can sink into
the fluidized bed and no longer come under the action of the surface wash jets
Fixed-nozzle surface-wash systems obstruct convenient access to the filter surface for
maintenance and repair
Because surface wash systems constitute a possible connection between filtered and
unfiltered water, backflow prevention devices must be provided in supply lines
Air scour provides effective cleaning action, especially if used simultaneously with water
wash. Cleaning is attributable to high interstitial water velocities and abrasion between grains.
On the other hand, air wash has substantial potential for media loss and gravel disruption if
not properly controlled. Use of air scour can significantly reduce the quantity of water
required for backwashing filters.
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If more than one filtering medium is used and stratification of the bed is desired, high-rate
water wash must follow air scour. In a single-medium bed, if a low-rate wash can adequately
remove scoured solids, high-rate wash can be avoided.
If air scour occurs simultaneously with water wash, airflow must usually be stopped before
washwater overflow into the washwater collection troughs to prevent media loss. For this
reason, the permissible duration of air washing is short unless the concurrent water wash rate
is low or the filter box is very deep.
Experience indicates that air scour essentially eliminates mudball formation. Difficulties have
arisen, however, from failure to remove scoured solids from filter surfaces. Contributing
factors probably include low water-washing rates, long horizontal-travel distances to
backwash troughs, and a necessary lag between termination of air scour and initiation of
higher-rate water wash.
Air scour complicates and increases the cost of wash systems as air blowers, air piping, and
air and water backwash controls are required. Air backwash can also cause disturbances to
underdrain systems because of the potential to compress air in the underdrains. Pressure relief
systems should be considered with air scour.
Air scour is used to improve the effectiveness of the backwashing operation. If air scour is
used during overflow, there is substantial danger of losing some of the medium. Therefore,
the system must be properly designed and operated to avoid such loss. The air scour operating
routines are different for finer filter media and for coarse sand media as shown in Table 5-31.
Operating sequences are listed below.
Simultaneous air scour and water backwash during rising level but before overflow.
This system can be used for fine sand, dual media, triple media, and coarse mono-medium
anthracite:
Lower the water level to just above the surface of the filter medium
Turn on air scour for 1 to 2 minutes
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Add low-rate water wash at below half the minimum fluidization velocity as water
level rises
Shut off air scour about 15 cm below overflow level while water wash continues. Most
air will be expelled before overflow
After overflow occurs, increase the water wash rate to fluidize and re-stratify the bed,
and wash until clean. Some additional air will be expelled
For the simultaneous wash routine just outlined, the wash is very effective even though the
bed is never fluidized. A slow transport of the grains occur, caused by the simultaneous air
and water flow that causes abrasion between the grains. This abrasion, plus high interstitial
water velocities, results in an effective backwash.
Several precautions must be taken to prevent the loss of sand or anthracite when using
simultaneous air and water wash during overflow. The water and airflow rates are varied
appropriately for the size of the filter medium. For coarse sand, backwash troughs are not
generally used, and the dirty washwater exits over a horizontal concrete wall or central gullet,
with the vertical distance from the surface of the sand to the washwater overflow being at
least 0.5 m. The top edge of the overflow wall(s) is sloped downward 45° toward the filter
bed, so that any sand grains that fall on the sloping wall during backwashing will reenter the
filter bed. Alternatively, if backwash troughs are used, specially shaped baffles can be located
around each trough to prevent the loss of filter medium. Such baffled troughs are especially
important when using anthracite medium.
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maintaining a constant pressure drop (equal to the buoyant weight of the media). Two typical
curves for real filter media fluidized by water are shown in Figure 5-83.
For a filter medium that has a very wide range of grain sizes, the use of Vmf for the d90 size
during backwashing could possibly expand the finest grains so much that they could be lost to
overflow. This is never a problem with the uniformity coefficients commonly specified for
filter media (UC less than 1.7, often less than 1.5).
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isolated, and a small backwash pump draws clean water from the filter effluent and reverses
the flow through that particular cell. Water is removed by a second washwater pump located
in the traveling hood and discharged to waste.
The wash cycle time is controlled by pre-set adjustable timers to permit optimization of the
automatic operation feature. Media depth varies with each application but is typically 0.8 to
0.9 m. In addition to automatic washing features, these filters have the capability of producing
relatively constant washwater flow. In a properly sized system, this constant flow can
eliminate the need to provide washwater equalization facilities and can permit direct recycle
to the plant head works.
5.9.12.1. Backwash Water and Air-Scour Flow Rates
Typical flow rates used in backwash practice are summarized in Table 5-31. Hewitt and
Amirtharajah (1984) did an experimental study of the particular combinations of air and sub-
fluidization water flow that caused the formation and collapse of air pockets within the bed, a
condition they called ―collapse-pulsing.‖ This condition was presumed to create the best
abrasion between the grains and the optimum condition for air plus sub-fluidization water
backwashing. An empirical equation relating airflow rate, fluidization velocity, and backwash
water flow rate was presented. In a companion paper, Amirtharajah (1984) developed a
theoretical equation for collapse-pulsing using concepts from soil mechanics and porous
media hydraulics. The resulting equation was:
( )
In which Qa is the airflow rate in standard cubic feet per minute per square foot and V/Vmf is
the ratio of superficial water velocity divided by the minimum fluidization velocity based on
the d60 grain size of the medium.
Table 5-31: Typical Water and Air-Scour Flow Rates for Backwash Systems
Filter Medium Backwash Sequence Air Rate Water Rate* (m/h)
(m/h)
Fine sand 0.5mm ES Air first 37–55
Water second 37
Fine dual and triple anthracite Air first 55–73
media 1.0 mm ES Water second 37–49
Coarse dual media1.5 mm ES Air first 73–91
anthracite Air + water on rising level 73–91 24
Water third 61
Coarse sand 1.0 mm ES Air + water 1st simultaneously 55–73 15–17
Water second Same or double rate
Coarse sand 2 mm ES Air + water 1st simultaneously 110–146 24–29
Water second Same or double rate
Coarse anthracite 1.5 mm ES Air + water 1st simultaneously 55–91 20–24
Water second Same or double rate
* Water rates for dual and triple media vary with water temperature and should fluidize the
bed to achieve re-stratification of the media.
The empirical and the theoretical equations give almost the same results over the range of
airflow rates from 37 through 110 m/h. For a given airflow rate, both of the equations predict
somewhat higher water flow rates than the typical values presented in Table 5-31 The
tabulated values should be used until future research reconciles these differences. Some of the
advantages of auxiliary air-scour in contrast with surface-wash systems, are the following:
It covers the full area of rectangular filters and is adaptable to any filter dimensions.
It agitates the entire filter depth. Therefore, it can agitate the interfaces in dual and
multimedia beds, and can reach mudballs that have sunk deep into the filter.
Some disadvantages of the air-scour auxiliary are:
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The need for a separate air blower and piping system.
The potential for loss of media, especially if air and water are used simultaneously
during overflow.
A greater possibility of moving the supporting gravel exists if air is delivered through
the gravel concurrently with water. Special gravel designs are required as described
earlier.
Typical wash water volumes used per unit area per wash range from 4 to 8 m3 /m2 /wash.
Methods successfully used to minimize the problem of filter ripening include a short period of
wasting the first portion of filtered water (i.e., filter-to-waste), a slow increasing of the filtered
water flow rate after a backwash, resting a filter, and adding a polymer filter aid to the
washwater supply.
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Figure 5-84: Characteristics of initial effluent quality
As an example, a filter operating at 10 m/h for 48 h and requiring 12,200 L/m 2 for an
adequate backwash would have an effective filtration rate of 9.5 m/h and an efficiency of
97%.
In a direct filtration plant, pretreated water turbidity typically exceeds source water turbidity.
The flocculation process should be operated to minimize floc size and allow penetration of the
floc deep within the filter media, effectively using its entire depth. Jar tests or on-line pilot
filters, zeta potential, or streaming current instrumentation can greatly assist the operator in
optimizing the coagulation process and ensuring adequate pretreatment for effective filtration.
Air scour and surface wash systems can prevent the formation of cracks and mudballs, but
previously formed mudballs may have to be removed manually or by soaking filter media
with acidified water. Some plants include waste washwater turbidity meters as an operational
tool to monitor the waste washwater quality and to minimize the volume of washwater usage.
When head loss exceeds the available head at some elevation within the filter media, pressure
falls below atmospheric and air escapes from solution. Air binding occurs when the
accumulation of air bubbles blocks the water's path. An excessive effective filtration rate and
significantly increased head loss result. Air binding most often occurs a few inches into a
single-medium filter or just below the anthracite-sand or GAC-sand interface in a dual-media
filter. Air escapes from the media upon closure of the filtered water rate control valve, and the
resulting agitation can cause loss of media. By design, air binding does not occur in pressure,
declining-rate, or self-backwashing filters.
A minimum water depth of 1 m above filter media in gravity plants is recommended. Modem
plants that operate at relatively high filtration rates typically require a water depth of 1.5 m or
more to prevent air binding within the media. The designer should consider the rate of head
loss development along with the desired filter run length to develop design criteria for the
filter media, filter box depth, and freeboard.
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5.9.13.10. Restart after Shutdown
Water treatment plants sometimes operate with individual filters removed from service during
low-demand periods. Additionally, some plants shut down at night or cycle the filters on and
off based on distribution storage tank levels. Some plants place individual filters or entire
plants on standby for periods of time and even drain the filters when they have sufficient
redundancy or more than one plant. Preferably, all filters should be operated continuously at a
reduced filtration rate. Continuous operation prevents formation of undesirable biological
activity caused by water standing in the filter box and avoids loss of ripened filter media in a
drained filter. In any case, inactive filters require special measures for restart.
Filters that are shut down with standing water require a brief washing or filter-to-waste period
to ensure adequate filter performance before filtered water flows to the clearwell. The restart
wash or filter-to-waste period should be programmed into the centralized control system for
the plant.
Drained filters require manual restart with close supervision, including gradual refilling with
washwater to prevent gravel upset or media separation, a complete backwash, and a longer
than normal period of filter-to-waste to ensure adequate performance before opening the
filtered water control valve. Filters should always be filled from the bottom to prevent air
entrainment.
Lost media should be replaced with appropriately specified material following the guidelines
presented earlier to ensure that the entire bed of media approximates original specifications.
Replacement media for dual- and mixed-media filters require special attention. If a layer of
fines has accumulated on the surface of the filter, it may be wise to scrape off a thin layer of
top media before adding new media. After replacing the new media on top of the filter, the
operator should initiate two complete filter wash cycles to fluidize the media, wash off fines,
and ensure re-stratification.
The concern about possible recycling of Giardia cysts and Cryptosporidium oocysts led to a
plant-scale study of the impact of waste stream recycling on filtered water quality. The proper
management of the waste streams can render them acceptable for recycling in many
situations. Backwash water and sedimentation basin sludge should be subjected to further
sedimentation at a low overflow rate or by adding a polymer to remove cysts before recycling
the supernatant. Recycled streams should be equalized and blended over the full 24-hour
operating period, or the plants operating period if it is less than 24 hours. Recycle streams
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should be regularly monitored for cysts or by particle counting to judge the effectiveness of
removing cysts from the waste stream prior to recycle.
Water from the filter backwash is discharged into a backwash tank and allowed to settle. The
supernatant, or cleared liquid, is then pumped back to the head of the treatment plant at a rate
not exceeding ten percent of the raw water flow entering the plant. The settled material is
pumped to the solids-handling process of the plant. This conserves most of the backwash
water and reduces the waste discharge.
Since backwash is a very high flow operation, the surges that are created from the backwash
coming from the filter must not be allowed to enter the head of the plant. Therefore, the spent
backwash water must be stored in storage tanks and returned slowly to the treatment process.
The increase in filter loading will be limited by the hydraulic constrains more than the
capacity of the filter and filter media. In all existing plants, however, the inlet channels appear
to have ample capacity. The filtered water outlet is probably more critical but it is short in
length so that twice the present filter rate may be possible.
The actual filter rates should be determined for all the filters in the plant. This work can be
done at the same time the raw water pumping tests are made. The procedure is quite simple:
1. Fill the filter box to the normal water level with the filter outlet valve closed.
2. Close filter inlet valve.
3. Open filtered water outlet valve.
4. Measure the drop in water level in the filter box by timing a drop of 15 to 20 cm. The
timing should be started only when the outlet valve is completely open.
5. Knowing the area of the filter box the volume is easily calculated and the filter rate
can be determined.
This information is important as an indicator of the maximum filter rate possible with the
existing bed and existing losses in the outlet valves and piping. If the rate is higher than
design rate an orifice plate can be installed in the outlet system to introduce a head loss which
will reduce the filter rate to anything the designer desires.
Filter backwash rates should also be determined. This will be just the opposite procedure to
the above.
1. Close inlet valve.
2. Filter the water down to a point about 10 cm above the bed.
3. Close filter outlet valve
4. Start backwashing
5. When wash is on full force measure the rise in the water level before it reaches the
bottom of the overflow drains. This distance is sometimes very short making the
measurement difficult.
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An effective backwash rate is 30 to 36 m3/hr per m2. The backwash rates in all existing plants
are probably less than 30 m3/hr per m2.
Most operators are reluctant to wash filters often. This is understandable because (a) it
requires work to open and close several valves; (b) it uses a large amount of water, and (c) it
takes a part of the filter capacity out of service. It is necessary to understand the importance of
operating filters at a high loading; it is far more economical to increase the filter rate even
though the washing frequency goes up. Below is a calculation of production per m2 of filter
bed at 100 m3/m2/day and 234 m3/m2/day.
min/wash (m3/m2)
Filter wash Rate
Filter Run (Hrs)
(m3/m2/min)
Wash water
(m3/m2)
100 72 0.5 1.67 0.7 2.37 2.37 97.63
234 8 0.5 15.00 14.6 29.60 12.65 204.40
Even though one filter is washed 9 times as often, the higher rate pays big dividends in
product per m2. However, filtered water quality for higher rate and water availability or
recycling of filtered water has to be considered.
For conversion of filters to direct filtration, testing is required with a low coagulant does
determined in the laboratory with filter paper (see Annex F.3). The filter performance should
be monitored for turbidity and head loss. If performance is good at the plant rate, cut out one
unit and increase the load on the others, continuing until the runs are deduced to less than 12
hours, or the effluent turbidity rises above 4.5 NTU. This will indicate the increase in filter
loading possible without any modifications. A simple filter head loss gauge is shown in
Figure 5-85.
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Figure 5-85: Sample Head loss Gauge
It is used to increase the pH value of the purified water after reverse osmosis system and to
provide minerals that are good for human health. Dolomite filters are manually controlled.
While the water is strained from top to bottom in the filter, dolomite mineral dissolves and
provides natural minerals to water such as calcium, magnesium and carbonate. By
replenishing the mineral which is reduced in time mineralization process is continued.
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constant from top to bottom, usually being wider at the top. This leaves dead areas along the
walls that do not receive adequate fluidization during backwashing and therefore, may not be
washed effectively.
In some horizontal-axis cylindrical tanks, the filter is divided into multiple (four or five) cells
by vertical bulkheads. Cost advantages are gained by this configuration because only a single
pressure vessel is needed. One filter cell can be backwashed by the production of the other
cells that remain in service. This requires a filtration rate sufficiently high so that the total
production of the operating cells is sufficient to fluidize the medium of the single cell being
backwashed.
The use of higher filtration rates and high terminal head loss in a pressure filter is tempting
because the influent is under pressure and more potential head loss is available. This
temptation should be resisted, however, unless no detriment to the quality of the filtrate can be
demonstrated on a case-by-case basis.
One advantage gained by pressure filtration is that water leaves the filter under a positive
gauge pressure, and therefore no negative pressure can ever exist in the filter medium. The
potential problems associated with negative pressure discussed earlier are therefore avoided.
Vertical pressure filters range in diameter from 0.3 -3 m with capacities as great as 19 l/s at
filtration rates of 175 m3/m²/day. Horizontal pressure filters, usually 2.4 m in diameter, are
10-7.5 m long with capacities from 12.5 to 38 l/s. These filters are separated into
compartments to allow individual backwashing. Backwash water may be returned to the
clarifier for recovery.
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Figure 5-87: Horizontal-type pressure sand filter
The operation of a pressure filter is similar in most respects to the operation of a gravity filter.
Proper backwashing of a pressure filter is more difficult, however, because the filter medium
is not conveniently visible to the operator during the backwash operation. The various
analyses that can be conveniently made by visual observation for gravity filters are difficult or
impossible to perform with pressure filters. These include:
1) Presence of filter cracks before the backwash, or mudballs after the backwash
2) Uniformity of backwash water distribution
3) Uniformity of rate of clean-up of the wash water over the full filter areas
4) Proper functioning of the auxiliary scour device such as surface wash or air scour
5) Elevation and appearance of the top surface of the filter medium after the backwash
6) Whether the medium is fully fluidized during the backwash (if that is the intended
washing method),and the extent of expansion of the filter medium
7) Extent of loss of the filter medium
Because of these difficulties, pressure filters have been implicated in waterborne disease
outbreaks that can be partially attributed to poor condition of the filter medium. Prior
concerns about the reliability of pressure filters and other concerns have caused some state
regulatory agencies to exclude the use of pressure filters in the treatment of surface waters or
other polluted source waters and lime softened waters.
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The control of washing velocity is essential and can easily be provided by equipping waste
wash water sump with the calibration threshold. At the same time, the change in quality of the
discharged water can be monitored as a way of regulating washing time. This time varies
between 5 and 8 minutes, depending on sand depth and kinds of matter retained.
5.10.4. Rate Control for Pressure Filters
Rate control for pressure filters is equally as important as it is for gravity filters because the
same filtration mechanisms are functioning in both cases. Fewer options are available for
pressure filters, however, because the pressure filter operates full of water under pressure. As
a result, options involving changing water levels are not available, and influent gravity flow
splitting is not available. Therefore, the benefits of slow rate changes by allowing water levels
to change are not available to pressure filters.
The usual arrangement for a bank of pressure filters is based on the assumption that flow
through the system will self-equalize. The total filter area of the filter bank is sized
appropriately to meet local regulatory requirements based on feed pump capacity. Individual
filter flow controllers and flow meters are not provided. The system is designed
symmetrically so that flow is distributed equally to each filter in the bank. Thus, after
backwashing all of the filters in short succession, if one filter is passing more flow than it
should, it is assumed that that filter will clog more quickly than the other filters, and that the
flow will be reduced because of the clogging resistance. Thus, the system is considered self-
equalizing during operation. However, if the multiple filters are backwashed at random
intervals during a filter cycle, the cleanest filter will provide the highest flow and the dirtiest
filter the lowest flow. The extent of these differences will not be known if individual flow
meters are not provided.
In spite of the common practice just described, it is desirable to have a flow meter on each
pressure filter in a bank of several filters. Flow metering is useful to the plant operators for
diagnostic purposes to observe if something is wrong with one filter, causing the flows not to
be equally split. This could happen if one filter is not cleaning up properly during
backwashing, perhaps due to a clogged underdrain. Or, one filter may flow at an excessive
rate due to the loss of some or its entire filtering medium.
5.10.5. Applications of Pressure Filters
Pressure filters tend to be used in small water systems. Many pressure filters are used in
industrial water and wastewater filtration applications. They also are used widely in
swimming pool filtration.
Advantages of pressure filters over gravity filters include the following:
The filtrate, which is under pressure, can be delivered to the point of use without re-
pumping. In some treatment plants, source water can be pumped from the source
through the treatment plant and directly to the point of use by the source water pumps.
A treatment plant equipped with pressure filters is somewhat easier to automate.
Some ground waters containing iron can be treated by pressure aeration and/or
chemical oxidation and then filtered directly on pressure filters. This approach has
received considerable application for small communities. For high iron and manganese
applications, pressure filters can be provided with manganese green sand and
potassium permanganate feed systems.
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diatomaceous earth as a filter medium. In precoat filtration, the water to be filtered is passed
through a uniform layer of the filter medium that has been deposited (precoated) on a septum,
a permeable material that supports the filter medium. The septum is supported by a rigid
structure termed a filter element. The pre-coat layer is powder-like Diatomaceous Earth (DE)
with particle mean size of 23.5 m with 80% of the particle ranging from 5 to 64 m. DE is
mined from fossilized remaining of microscopic algae called ―Diatoms‖ deposited in the bed
of ancient oceans. A powdered medium is manufactured from the diatomaceous deposits,
which are almost pure silica. The medium when deposited on the filter spectrum has an
average pore size of about 7 m.
As the water passes through the filter medium and septum, suspended particles about 2 µm
and larger are captured and removed. The majority of particles removed by the filter are
strained (trapped) at the surface of the layer of filter medium, with some being trapped within
the layer. As the filter cycle proceeds additional filter medium, called body feed, is regularly
metered into the influent water flow in proportion to the solids being removed. Without the
regular addition of body feed, the head loss across the precoat layer would increase rapidly.
Instead, the dirt particles intermingle with the body feed particles so that permeability of the
cake is maintained as the thickness of the cake gradually increases. By maintaining
permeability of the cake in this way, the length of the filter cycle is extended.
Ultimately, a gradually increasing pressure drop through the filter system reaches a point
where continued filtration is impractical. The forward filtration process is stopped; the filter
medium and collected dirt are washed off the septum; a new precoat of filter medium is
applied; and filtration continues. A typical schematic diagram is shown in Figure 5-88.
Precoat filters accomplish particle removal by physically straining or entrapping the solids out
of the water. The thickness of the initial layer of precoat filter medium is normally about 3
mm, and the water passageways through this layer are so small and numerous that even very
fine particles are retained.
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Precoat filters are widely used in industrial filtration applications and in swimming pool
filtration. They have also been used in municipal potable water treatment, primarily in the
direct, in-line filtration of high-quality surface waters (turbidity 10 NTU with inorganic or
non-compressible particle, turbidity 5 NTU with organic or algal matter and acceptable
colour), and in the filtration of iron and manganese from ground waters after appropriate pre-
treatment to precipitate these contaminants.
Because of small pore size of the precoat filters, high degree of Giardia cysts and
Cryptosporidium Oocysts has been observed whereas virus removal is rarely exceeding 1 log
reduction. It has been shown to be very effective in the removal of Giardia cysts (up to 6 log
removal) over a broad range of operating conditions typical of potable water filtration. The
need for proper operation and maintenance is emphasized, however, and a precoat rate of 1
kg/m2 is recommended. The removal of small particulates such as bacteria and viruses
depends on the grade of filter aid used and other operating conditions. Capture of smaller
particles such as bacteria, viruses, and asbestos fibres can be enhanced by using aluminium or
iron coagulants or cationic polymers to coat the filter medium. The use of strong oxidant such
as ozone has been demonstrated to be effective in conditioning particulate colour for removal
(and in oxidizing colour associated with DOC or reduced forms of iron and manganese).
Where the source water and other conditions are suitable, precoat filtration can offer a number
of benefits to the user, including the following:
1. Capital cost savings may be possible because of smaller land and plant building
requirements.
2. Treatment costs may be slightly less than conventional coagulation/sedimentation/
granular media filtration when filterable solids are low, although sedimentation would
not usually be needed for such high-quality source waters.
3. The process is entirely a physical/mechanical operation and can attain high log
removals of Giardia cysts and Cryptosporidium oocysts without operator expertise in
water chemistry relating to coagulation.
4. The waste residuals are easily dewatered and in some cases may be reclaimed for
other uses, including soil conditioning and land reclamation. Research is under way to
determine the feasibility of reusing filter medium as body feed.
5. Acceptable finished water clarity is achieved as soon as precoating is complete and
filtration starts. A filter-to-waste period is generally not necessary to bring turbidity of
the finished water within acceptable limits.
6. Terminal turbidity breakthrough is not generally observed because precoat filtration is
dominantly a surface filtration process.
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only larger plankton such as diatoms can sometimes be treated economically by
microstraining prior to the precoat filtration.
3. Proper design, construction and operation are absolutely essential to prevent the filter
cake from dropping off of the septa or cracking during operation, which could result in
the system failing to remove the target particulates.
Precoat filtration has been shown to be very effective in the removal of Giardia cysts over a
broad range of operating conditions typical of potable water filtration. The need for proper
operation and maintenance is emphasized, however, and a precoat rate of (1 kg/m 2) is
recommended. The capability of precoat filtration to remove cysts and the fact that chemical
coagulation is not required makes this option attractive to very small communities facing
filtration because of concern about cysts in source waters. Operators skilled in coagulation are
less likely to be available in small installations, but operators possessing mechanical skills are
required.
The removal of small particulates such as bacteria and viruses depends on the grade of filter
aid used and other operating conditions. Capture of smaller particles such as bacteria, viruses,
and asbestos fibres can be enhanced by using aluminium or iron coagulants or cationic
polymers to coat the filter medium.
Filter element: The inlet water is distributed through the containment wall, fitted with an
internal baffling device to prevent the disturbance of the filter cake. Many arrangements of
filter elements are available depending on the types of filters.
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Finished water quality (i.e. turbidity, DOC, inorganic, etc.)
Operator familiarity with the process
Because particles of the medium are much smaller than the clear openings in the septum, their
retention and the formation of a stable precoat take place as a result of bridging. As the
particles crowd together when passing through the openings, they jam and interlock, forming
bridges over the openings. As bridges form, additional particles are caught and the filter
septum is coated.
Body-feeding: The amount of body feed to be added to the source water is determined by the
nature and amount of the solids to be removed. Pilot testing during representative source
water quality periods will generally indicate the type and range of solids that will be
encountered and the amount and type of body feed needed to provide an incompressible and
permeable cake.
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Typical body feed ratios of 1 to 10 mg/L of diatomite for each 1 mg/L of suspended solids are
required, depending on the type of solids being filtered. Details of selecting the appropriate
ratio will be presented later. Compressible solids such as alum or iron coagulation solids
require the highest ratios. Proper control of the body feed dosage is the most important factor
contributing to economical operation of a precoat filtration plant. Body feed equipment can be
classified as dry or wet systems. The wet, or slurry, feeders are the most common type.
Spent Cake Removal: At the end of each filter cycle, the spent filter cake is removed from
the filter in preparation for the precoat that will begin the next cycle. If spent solids are not
fully removed from the filter vessel, the material could be re-suspended and deposited on the
filter septa. The re-suspended dirty material could foul the septa, although the effect would
usually develop gradually so that the operator would become aware of it only after a number
of cycles.
The most reliable means of determining the cleanliness of the septa involves visual
observation of the bare septa, followed by observation of the uniformity and completeness of
precoat. When the septa cannot be fully inspected, a higher than normal differential pressure
immediately after precoating (at the start of the filtration cycle) would suggest that the septa
are becoming fouled.
Techniques for removing the spent cake vary with the different kinds of filter vessels and
filter elements. Spent cake removed from a precoat filter is a mixture of filter medium and the
materials removed from the source water. This waste matter is usually removed from the filter
in slurry form. Although some systems may be able to dispose of the slurry into a sanitary
sewer system, most plants must dewater the waste material and make separate provisions for
the solids and liquid wastes.
The slow sand filter was developed in England in the early nineteenth century and continues
to be used successfully, notably on River Thames water, which serves London. In the United
States, this treatment process has been used to treat high quality upland surface waters in New
York and New England since the early 1900s. Renewed interest in the slow sand filter
occurred because numerous outbreaks of giardiasis occurred in the latter 1970s and early
1980s in communities using unfiltered or poorly filtered water. The slow sand filter is a
simple technology requiring no knowledge of coagulation chemistry and is quite attractive for
small installations treating high-quality surface waters.
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Pre-treatment is necessary with raw water having a maximum turbidity of 20 NTU or more.
But should be considered for less turbidity (10-20 NTU) to improve final water and reduce
frequent cleaning.
During the first few days, water is purified mainly by mechanical and physical processes. The
resulting accumulation of sediment and organic growth forms a thin layer on the sand surface,
which remains permeable and retains particles even smaller than the spaces between the sand
grains. As this layer (often referred to as the biological skin or "Schmutzdecke") develops, it
becomes the "living quarters" of vast numbers of microorganisms which break down organic
material retained from the water, converting it into water, carbon dioxide and other oxides
(PO4, NO3). Nitrogenous organic material will initially be converted into ammonia, which is
then oxidized by specific autotrophic bacteria to nitrite and ultimately to nitrate.
Most impurities, including bacteria and viruses, are removed from the raw water as it passes
through the filter skin and the layer of filter bed sand just below. The removal of bacteria
from the water is probably due primarily to the action of predators, such as protozoa. Those
impurities carried deeper into the filter bed will come into contact with, and become attached
to, sand grains so that the sand particles gradually become covered with a thin layer composed
mainly of organic material and microorganisms. These in turn adsorb the impurities by
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various attachment mechanisms. The purification mechanisms extend from the filter skin to
approximately 0.3-0.4 m below the surface of the filter bed, gradually decreasing in activity at
lower levels as the water becomes purified and contains less organic material and nutrients.
More products of the biological processes are removed at even greater depths by physical
processes (adsorption) and biochemical action (oxidation).
When the microorganisms become well established, the filter will work efficiently and
produce high quality effluent which is virtually free of disease carrying organisms and
biodegradable organic matter. The time taken for the filter to ripen depends on the quality of
the raw water, but water temperature and oxygen levels are also important factors. Ripening
of a new filter may generally take about three weeks, whereas a filter which has been cleaned
in a single-day operation may take only one to two days. The absence of ammonia in the
filtrate is an indication that the ripening process is completed.
The ecosystem in a slow sand filter typically includes bacteria; protozoa such as rhizopods
and ciliates; rotifers; copepods; and aquatic worms. In general, smaller organisms are found at
or near the top of the filter and are preyed upon by larger organisms that range deeper into the
filter bed, algae also may be found at or near the surface of the filter in open filters as shown
in the Figure 5-90.
The principal use of slow sand filtration is in the removal of organic matter and pathogenic
organisms from raw waters of relatively low turbidity. The biological treatment that takes
place in the "schmutzdecke" of the filter is capable of reducing the total bacteria count by a
factor of 103 to 104 and the e-coli count by a factor of 102 to 103. Accordingly, considerable
savings can be realized in the quantities of chlorine required for disinfection. Such an
advantage is particularly important in rural areas of developing countries where chlorination
practices have proven to be very unreliable, and where slow sand filtration can provide a more
reliable safety barrier than, for example, rapid filters that require uninterrupted chlorination to
assure safety. Slow-sand filters are most practical in the treatment of water with turbidity
below 50 NTU, although much higher turbidity can be tolerated for a few days.
In most cases, long-term pilot testing of the source water is essential to determine the
applicability of slow sand treatment options especially where there are seasonal variations in
temperature, DOC, or dissolved oxygen. Pilot testing up to 1 year is not unusual if there are
significant seasonal water quality and/ or operating variations. Multiple column are often used
in pilot testing so that various parameters and filter sand can be evaluated without changing
the treatment process in the middle of the filter run. The pilot testing results should be
carefully evaluated in light of available source water quality data before being incorporated
into the basis of design.
Table 5-34: Suggested source water quality limitation of conventional slow sand filter
Parameter Recommended limit
Turbidly 5 to 10 NTU *
Algae 200,000 /L
True colour 15 to 25 platinum colour unit
Dissolved organic carbon 2.5 – 3.0 mg/L
UV254 absorbance 0.080 /cm
Dissolved Oxygen 6 mg/L
Phosphorous as (PO4) 30 g/L
Ammonia as (NH3) 3 mg/L
Iron < 1 mg/L
Manganese < 1 mg/L
*- presence of clay particle must be determined
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Figure 5-91: Features of a Slow Sand Filter
Source: Huisman and Wood, 1974, p. 18
1) Rate of filtration - The traditional rate of filtration used for normal operation is 0.1 m/hour,
although it is possible to produce safe water at rates as high as 0.4 m/hour (Huisman and
Wood, 1974). At higher filtration rates, the intervals between filter cleanings are shortened,
but the quality of the treated water does not deteriorate. Higher rates of filtration are used
during those periods when some filters are out of service for cleaning, rather than providing
extra filter units at increased costs to maintain a higher rate.
2) Supernatant water - The depth of water should provide a head sufficient to overcome the
resistance of the filter bed and prevent air binding. In practice a head of between 1.0 to 1.5
meters is usually selected.
3) Filter bed: The sand bed thickness varies between 1.0 to 1.4 meters. This thickness should
be reduced to not less than 0.5 to 0.8 meters after removing the upper sand layers during filter
cleaning. Filter sand should have an effective size between 0.15 to 0.35 mm and a uniformity
coefficient between 1.5 and 3, although a coefficient of less than 2 is desirable. The careful
selection and grading of sand is not as critical as in rapid filters. Use of builder grade or
locally available sand can reduce costs.
4) Filter gravel: The filter gravel should be so graded that the sand does not penetrate the
underdrain system, yet provides free flow of water when a limited number of underdrains are
provided. For example, when using a filter bottom composed of stacked bricks with open
joints (10 mm wide), four layers of metal are normally used with the following size ranges:
0.4 to 0.6 mm 1.5 to 2 mm; 5 to 8 mm; and 15 to 25 mm; each layer about 10 cm thick.
6) Depth of Filter Box: - The minimum depth of the filter box is determined from the
following elements:
Freeboard above supernatant level 0.20 m
Supernatant water 1.00 m
Filter medium (initially) 1.00 m
Four-layer gravel support 0.30 m
Brick filter bottom 0.20 m
Total 2.70 m
It is general practice to use a filter box 3 to 4 meters deep, but a depth of 2.70 meters will
reduce construction cost without sacrificing filter efficiency.
7) No. of Filter Beds: - At least two filter units always should be built and reserve units
should be provided for large treatment plants since slow sand filtration requires that a filter be
off line for up to two weeks for scraping. A first estimate of a number of units may be from
the formula n = 15Q in which Q is expressed in m3/s. Table 5-35 summarizes the
recommendations of the World Health Organization for determining the number of filter
basins based upon given design demand.
8) Inlet Structure: - The inlet structure is intended to allow water to flow into the filter
without damaging the filter skin on top of the sand bed. Usually, the inlet structure is a box
which can also be used to drain the supernatant water quickly. The main functions of the inlet
structure are as follows:
It should reduce the energy of the incoming water to prevent the filter skin being
damaged. This means that the inlet must be located immediately above the sand bed
and the entrance velocity should be low, for example, about 0.1 m/s. As a rule of
thumb, the length of the planks in the inlet structure should be as wide in metres with a
minimum of 0.4 m and a maximum of 1 m (Figure 5-92). In this way, the height of
the overflowing water will only be a few centimetres when the filter has just been
started up, and thus a gentle flow is obtained.
It should provide a means of adjusting the supernatant water level. This can be done
by a float-controlled butterfly valve, a manually operated gate valve, or an adjustable
overflow weir in the inlet channel or pipe. The diameter of the inlet pipe should be
such, that the velocity of the water in the pipe is 0.3-0.5 m/s when the filters are
operated at the designed rate of filtration.
It should provide a means of shutting down the flow of raw water, generally by means
of a hand-operated gate valve.
In an inlet controlled filter, it should also provide the means to measure and control
the flow through the filter bed.
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9) Outlet Structure: - The main functions of the outlet structure are as follows:
It should prevent the development of below-atmospheric pressure in the filter bed.
Therefore, a simple overflow weir is often provided, with its crest slightly above the
top of the sand bed.
It should provide a means of draining the filter. A separate drain pipe is often included
in the outlet structure to pass the water to waste.
It should provide a means of refilling the filter with clean water after it has been
scrapped. This may be done through the system of underdrains.
In an outlet controlled filter, it should be possible to measure the flow through the
filter bed. The overflow weir, mentioned above, may also be used for this purpose by
means of a calibrated flow indicator, combined with a V-notch weir.
In outlet controlled filters, it should provide a means of adjusting the filtration rate by
shutting down the filter. The simplest method is manual adjustment of a valve or tap.
10) Filter Control: - Slow-sand filters are operated conventionally at a constant rate. The rate
is controlled by maintaining a constant head loss across the filter. A hand operated valve
preceded by a venturi meter can be used to regulate the filtration rate and depth of water over
the filter. The normal range of head loss from clean to clogged conditions in the sand bed and
filter appurtenances is 0.6 to 1.2 meters. An effluent weir is a valuable device to prevent
negative head loss and air binding. On the other hand, the weir and control valve can be
replaced by a simple unit consisting of a pair of telescopic tubes, the inner of which can be
raised and lowered to adjust the rate of filtration.
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Figure 5-92: Inlet and Outlet structures of Slow Sand Filter
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Figure 5-93: Alternative underdrain and filter support arrangements
The objective of the pre-treatment is to reduce the turbidity of the raw water to an average
value of 5 NTU or less and/ or to remove high algae population. This will reduce the solids
loading to slow sand filters, improving turbidity removal and extending filter run times.
When the clear-water tank is covered with a reinforced concrete slab, the structural design
differs from that of slow sand filters because side pressures are also transmitted to the cover.
If the joints between cover and walls are strengthened with extended reinforcement bars, the
strength of the structure increases, and it may therefore be possible to reduce the thickness of
the walls. When calculating the dimensions of the floor and wall of the tank, the combination
of an empty tank and a high groundwater-table are critical. Careful consideration should be
given to whether the total weight of the construction should be increased, to prevent it being
forced up and float by the water pressure.
The clear-water tank must be provided with ventilation pipes, a drain-pipe, an overflow, and a
manhole for inspection. If the tank also serves as a chlorine contact chamber, then the clear-
water outlet pipe should be located at such a height above floor level, that the minimum
detention time is 30 minutes.
Initial charging of the filter bed (and also subsequent refilling) must be done from the bottom
to top preferably with the clean water to drive out air bubbles. When the water level is far
enough above the sand bed, the raw water may be allowed to enter through the inlet to avoid
scouring. When the design water level is reached the drain valve is opened and water is run to
waste, regulated to about 25% of normal filtration rate for a period of a week to two to allow
formation of the ―Schmutzdecke‖. During this period water quality testing is to be done
periodically. And the flow rate gradually increased to design rate until such time as the testing
confirm that the filter is operating satisfactorily. The drain valve is then closed, and water
passed to the clear water basin.
After a period of operation, as the filter resistance increases it is necessary to gradually open
the regulating valve to maintain the flow rate, as measured by the discharge V-notch weir or
flow meter. When the valve is fully opened and the required flow rate cannot be maintained
cleaning of the bed is necessary and the filter must be taken out of service, temporarily. The
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raw water valve is closed, and the water level drained down to about 20 cm below the sand
surface, to permit raking in the sand.
The flow rates for slow-sand filters are about 20 to 50 times slower than for rapid filters.
Because the filter is cleaned manually, removing the dirty top sand rather than backwashing,
the sand is not stratified and its hydraulic characteristics are governed by the finer portions of
the sand.
The dirty sand can be cleaned by washing soon after removal or discarded. The SSF can be
cleaned in the following manner;
• Manual sand removal - bucket and shovel
• mechanized removal - wide tractor buckets
• mechanized in-situ sand washing
• removable top layer glass fiber mat, suitable for small installations
The process creates wastewater as the bed is being cleaned. The volume generated depends on
source water quality, filter area, and cross-flow velocity and depth and is generally in the
range of 163 to 244 L/m2 of filter area. The experience shows that using the harrowing
process reduces cleaning time to one-quarter of the time required for conventional cleaning.
The harrowing process requires the following facilities that may not be provided for a
conventionally cleaned slow sand filter
The filter box must be designed with enough headroom to permit tractor operation, and
support columns should be minimized to improve manoeuvrability. Influent and waste
headers can consist of either perforated piping or channels with adjustable weirs.
Wastewater lagoons should be designed to carry one to two harrowing with the ability to
allow time for settling and to discharge the decanted water in stages. Because wastewater has
generally not received previous chemical pretreatment, discharge requirements are usually
less rigorous. The process is now currently used at several operating plants in the United
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States to improve plant performance and reduce cleaning times. Designers of larger-capacity
plants should consider using this cleaning process.
The scraped-off material is filed in ridges or heaps and carted away. In areas where sand is
expensive or difficult to obtain, the surface scrapings from a slow sand filter may be washed,
stored, and reused at a later date. However, the scrapings must be washed immediately;
otherwise the material may go anaerobic, yielding taste and odor-producing substances that
are nearly impossible to remove during any later washing processes.
The hydraulically-operated device, shown in Figure 5-93, can be used to wash sand removed
from a filter. It functions essentially as an upward-flow clarifier; hence from a theoretical
standpoint, the rate of overflow of the wash water should not exceed the settling velocity of
the smallest particle to be retained. However, in practice, turbulence and sand concentration
reduce the desired rate of overflow appreciably so that the rate of flow of the incoming sand-
water solution is generally sufficient to effect separation without supplementary water. The
sand or grit that settles to the bottom is ejected hydraulically or can be removed by means of a
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shear gate. Pipes carrying sand-water solutions should be sized for velocities of 1.5 m/sec or
higher. About 8 m3 of sand per hour can be washed per square meter of washer surface area.
Water
Movable Hood
Water Lance
Flexible Rubber
Seal
Sand
When the bed reaches a minimum thickness of 0.5 to 0.8 m, the bed should be re-sanded. The
clean sand should be placed on top of the gravel, and the older sand should be placed on top
to provide seeding with microorganisms to form the 'Schmutzdecke' more rapidly and to
assure that all the sand will be cleaned from time to time.
Issues to resolve before filter fabric is used involve the mechanism for removal and cleaning
of the fabric, especially for large installations. Further pilot studies may be warranted to
determine the applicability of this modification with source waters of varying quality.
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the source waters and strict regulations for pesticide removals, the utility determined that
adding a GAC treatment step could allow water quality goals to be met.
To avoid the relatively high cost of constructing GAC adsorbers, installing GAC within the
filter bed is recommended. The "sandwich" bed used a 75- to 200-mm layer of GAC installed
100 to 150 mm below the sand surface. The performance of the system was compared with
that of conventional slow sand filtration with respect to head loss, color removal, TOC
removal, and THMFP. The results are presented in Table 5-36. Chlorine demand was also
reduced with the use of GAC, and pesticide levels were reduced to below standards.
Table 5-36: Comparisons of the Operation of Slow Sand and GAC Sandwich Filters
Parameter Conventional slow sand GAC sandwich filter
Cleaning frequency 30 days No change
Color removal 20% 50%
Total organic carbon reduction 20% 35% to 40%
Total trihalomethane formation potential 130 µg/L 60 g/L
reduction (24-h contact time)
Based on test results, Thames Water installed the GAC sandwich in several of its treatment
facilities. Biologically Activated Carbon (BAC) with use of both preoxidation with ozone or
other oxidants and biological activation of the sandwich layer will enhance reduction of both
TOC and disinfection by-products even further. When used primarily for the purpose of
organic reduction, the life of the GAC sandwich layer may be extended to 5 years or more.
5.12.8.6. Re-Sanding
Re-sanding becomes necessary when successive scrapings have reduced the thickness of the
sand bed to 50-60 cm. Fortunately; this rather lengthy operation only has to be done every two
or three years. For example, if the initial thickness of the filter medium is 80 cm and six
scrapings are done per year on average (6x 2 = 12 cm scrapings a year), then re-sanding
would be necessary after 2.5 years of operation. The decision to re-sand should be made well
in advance and the work is planned, if possible, in a period of low water demand. Re-sanding
may therefore need to be done before the minimum thickness of the sand bed has been
reached.
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Figure 5-97: Recommended Resanding Procedure (AWWA, 1991)
Although the tasks involved in operation and maintenance of slow sand filters will generally
not differ greatly, their frequency strongly depends on the local situation. The work schedule
has to be prepared for each plant and an example is given in Table 5-37
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5.12.9. Control of Slow Sand Filter
The following control systems are adapted in SSF as given in Figure 5-98 A,B,C and D.
1. Upstream water level control, downstream rate control
A. Constant inlet water level, variable filtered water level
B. Variable inlet water level, constant filtered water level
2. Upstream rate control, downstream water level control
C. Constant inlet water level, variable filtered water level
D. Variable inlet water level, constant filtered water level
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5.12.10. Monitoring & Evaluation of Slow Sand Filter
Provision should be made for flow measurements at each filter. Regular water quality testing,
physical, chemical and bacteriological quality of raw water and filtered water must be carried
out in each filter separately to ensure that the filter is operating satisfactorily. Complete
records of flow rates and cleaning / re-sanding operations should be kept on each filter unit, so
the long term evaluation can be carried out.
Constraints such as lack of adequate laboratory facilities and trained staff, long distances
involving unacceptable delays between sample collection and testing, and the high cost of
testing, make daily testing of most water quality parameters impossible in rural water supply
schemes. However, with training, caretakers can carry out simple tests for turbidity and
residual chlorine content. Whenever possible, the caretaker should perform at least the
following tests, although regular supervision is necessary to ensure reliability of the results:
Turbidity of raw water at the intake to check whether the intake of water should be
stopped or passes through pre-treatment process;
Turbidity of the inflow and outflow of the filter to determine whether the filter plant is
functioning properly.
Where chlorination is applied, the caretaker should also measure residual chlorine in the
clear-water tank to check whether the water is being disinfected sufficiently. Complete
physico-chemical and bacteriological tests on raw and treated water should be periodically
carried out by regional chemist. When a turbidity meter cannot be provided, visual
comparison of the turbidity of the raw water, water inflow, and the water outflow will provide
useful information. This can be done by comparing water samples in uniform glasses, placed
side by side.
Note: Covering SSF will give potential benefits such as increased run length, less problems
with airborne contamination, birds, etc., prevention of regrowth of algae, less temperature
variation, avoid freezing of water and security.
According to practical experience, intake filters are capable of reducing the solid matter
content by 50-70 %, and roughing filters are able to separate particulate matter by 90 % or
more. Roughing filters also improve the bacteriological water quality to a 1-2 log reduction of
faecal Coliform is often recorded. The filters also contribute to reducing the colour of
dissolved organics and other substances in surface water. However, since stable suspensions
rich in colloidal matter are difficult to treat by roughing filters, the addition of coagulants is
usually required. Experiences of performance of roughing filters from researchers are shown
in Table 5-38.
If the bacteriological quality of the raw water is satisfactory, it is feasible for RF to be used on
its own, without SSF. Among pre-treatment methods used before SSF, RF has been found to
be the most effective and appropriate for application in developing countries.
Removal of suspended solids in RF requires laminar flow. Hydrodynamic forces that move
the water through the pore system create patterns of flow retardation and acceleration that
have pockets of stagnant water near the media surface allowing particles to settle. A sticky
organic film on the surface of the media in the pores retains the suspended solids by mass-
particle attractions through the Vander Waals‘ forces and electrostatic forces between charged
particles (Wegelin, 1996).
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Figure 5-99: Mechanism of roughening filter
The main process is sedimentation, with horizontal flow and gravitational downward drift,
causing particles of silt to collect on the upper surface of the media. As the heaps of particles
accumulate, they slip down and drift towards the filter bottom, and over a period of times
filter fills from the bottom to top with separated solids.
The fine solid particles flowing through the filter are touching the gravel surface after a few
millimeters of settling distance, compared to fine solids with low settling velocities in
sedimentation basin. Thus, roughing filtration is a more effective process for solids removal
than plain sedimentation since the settling distance is drastically reduced by the filter material.
The raw water enters via an inlet channel across the filter width and falls over a weir into an
inlet chamber, which allows for settlement of coarse solids and separation of floating material.
Water passes into the first and subsequent filter compartments through openings in the
separation walls. Treated water is collected in an outlet chamber and discharged over a weir
(for flow measurement) to an outlet channel and then to the SSF.
The length of the filter box depends on raw water quality, hydraulic loading and size of
media. Height should be limited to about 1.5 m to allow for easy removal of media for manual
cleaning. The width depends on the required filter capacity. A minimum number of units
depend on the required filter capacity. A minimum of 2 HRF units should be provided, to
allow for one being out of service for cleaning, and an adjacent area for gravel cleaning
should be provided. A layout of typical horizontal, up flow and down flow roughing filters is
shown in Figure 5-99.
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roughing filters incorporates a simple self-cleaning mechanism and occupies minimal floor
space when compared to horizontal flow roughing filters.
The filter material of vertical-flow roughing filters is completely submerged. A water volume
of about 10 cm depth usually covers the gravel and other local available materials like
coconut fibre and broken burnt bricks. The top should be covered by a layer of coarse stones
to shade the water and thus prevent algal growth often experienced in pretreated water
exposed to the sun. Drainage facilities, consisting in perforated pipes or a false filter bottom
system, are installed on the floor of the filter boxes. Finally, pipes or special inlet and outlet
compartments are required to convey the water through the subsequent 3 filter units and they
are shown in Figure 5-100.
Vertical-flow roughing filters are usually operated at 0.3 to 1.0 m/h filtration rates. Vertical-
flow roughing filters may be sensitive to hydraulic fluctuations, especially if loaded with large
amounts of solids. Settled matter might be resuspended at increased filtration rates, causing
solids to break through the filter. Filter operation at constant flow rates is, therefore,
recommended. Raw water containing colloidal matter and a high suspension stability should
be treated at low filtration rates and preferably with fine filter material. Filter resistance is
usually less than 20 cm per filter unit and, hence, not a decisive operational criteria for
properly designed and operated roughing filters.
Due to structural constraints, vertical-flow roughing filters have a relatively small filter depth
of about 1 m. Total filter depth of the three filter units used in series is thus 3 m. This total
available filter depth limits vertical-flow roughing filter application. It can generally and
efficiently handle moderate raw water turbidity of 50 to 150 NTU. Raw water pre-treatment
by intake filters, reduction of filtration rate or provision of additional filter boxes would be
required to treat raw water of higher turbidity.
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In vertical roughing filters in layers, where all three gravel fractions are installed in one filter
box with a total filter distance of about 1 m, low turbidity raw water can be pretreated.
However, due to cleaning aspects this filter design can only be used for upflow operated
roughing filters. In such filters, the coarse filter material is placed at the bottom and the finest
material at the top of the filter. The separated solids, which accumulate mainly in the coarse
filter fraction next to the filter bottom, can be easily flushed out with the water stored in the
filter. Therefore, the use of upflow roughing filters in layers is recommended. Down flow
roughing filters in layers face considerable problems with hydraulic filter cleaning. The bulk
of solids accumulated in the coarse filter material on top of such filters would have to be
flushed through the finer rather clean filter material and would thus soil the entire filter bed.
Adequate and efficient washwater collection is important for reliable roughing filter
operation. Perforated pipes or a false filter bottom can be installed in vertical-flow roughing
filters. Perforated pipes, which should be laid in a coarse gravel pack to support an even
washwater abstraction, would require the installation of additional filter material in vertical-
flow roughing filters. Preference is given to false filter bottoms as they allow an even
washwater abstraction and do not require additional gravel layers. Although special perforated
concrete slabs will be necessary, they may be readily produced locally.
The accumulation pattern of retained solids is another difference between downflow and
upflow filters. The bulk of the solids is deposited at the inlet of the filter; i.e., for downflow
filters in the upper part of the filter, and for upflow filters in the filter medium located next to
the filter bottom. This, however, has a tremendous impact on hydraulic filter cleaning. In
downflow roughing filters, the bulk of accumulated solids have to be flushed with a relatively
small washwater volume from the soiled filter top through the lower and cleaner filter part to
the filter bottom. The opposite is true for upflow roughing filters. The bulk of retained solids
is accumulated next to the drainage system and a relatively large washwater volume,
accommodated in the upper filter part, is available to flush the solids out of the filter. Owing
to the important filter cleaning aspect, use of upflow roughing filters rather than downflow
filters is recommended.
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kept below the surface of the filter material by a weir or an effluent pipe placed at the filter
outlet to prevent algal growth in the filter.
Filtration rate in horizontal-flow roughing filters ranges between 0.3 and 1.5 m/h. It has been
defined here as hydraulic load (m³/h) per unit of vertical cross section area (m²) of the filter.
Filter length is dependent on raw water turbidity and usually lies within 5 to 7 m. Due to the
comparatively long filter length, horizontal-flow roughing filters can handle short turbidity
peaks of 500 to 1,000 NTU.
Drainage facilities, such as perforated pipes, troughs or culverts, allow hydraulic filter bed
cleaning. These drainage systems are placed at the filter bottom perpendicular to the direction
of flow. Drainage facilities in flow direction must be avoided as they could create short-
circuits during normal filter operation. Hence, false filter bottom systems cannot be installed
in horizontal-flow roughing filters. Since most of the solids accumulate at the inlet of each
filter medium, drainage facilities should be placed at the inlet of each filter compartment to
enhance hydraulic cleaning efficiency. Installation of troughs complicates construction of the
filter box floor. Furthermore, since the horizontal distance Ld between the troughs is usually
large, an even abstraction of the sludge is correspondingly difficult. Therefore, use of
perforated pipes is the best drainage system for horizontal-flow roughing filters, as it allows
easy installation of a dispersed system. Although prefabricated culverts may allow a more
even solids removal, connection to the washwater effluent pipes is more complicated.
Horizontal-flow roughing filters have a large silt storage capacity. Solids settle on top of the
filter medium surface and grow to small heaps of loose aggregates with progressive filtration
time. Part of the small heaps will drift towards the filter bottom as soon as they become
unstable. This drift regenerates filter efficiency at the top, and slowly silts the filter from
bottom to top. Horizontal-flow roughing filters also react less sensitively to filtration rate
changes, as clusters of re-suspended solids will drift towards the filter bottom or be retained
by the subsequent filter layers. Horizontal-flow roughing filters are thus less susceptible than
vertical-flow filters to solid breakthroughs caused by flow rate changes. However, they may
react more sensitively to short circuits induced by a variable raw wafer temperature.
Periodic cleaning is also essential for horizontal-flow roughing filters. Hydraulic cleaning is
carried out by fast drainage of the water stored in the filter. During filter drainage, the small
unstable heaps of accumulated solids collapse and are flushed towards the filter bottom. The
solid matter stored in the filter material is washed out of the filter box through the drainage
system. Drainage velocities of 60 to 90 m/h are necessary to achieve a good hydraulic
cleaning efficiency. Drainage pipes of adequate size are required to achieve the recommended
velocity, which drains the filter within 1 to 2 minutes. Depending on the solids concentration
in the raw water, regular hydraulic filter cleaning, at intervals of every few weeks, is required
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to avoid deterioration of filter efficiency and development of excessive filter resistance.
However, filter resistance will not exceed 20 cm if normal filter operation and regular
cleaning are observed. Frequent and efficient filter drainages will also defer the need for
manual filter cleaning, which nonetheless becomes unavoidable after some years of filter
operation.
5.13.6. Design of Roughing Filter
Input requirements
characteristics of the raw water quality in the dry and rainy seasons ;
turbidity;
suspended solids or filterability ;
E – Coli;
daily water demand (present & future) ;
raw water intake site location, elevation, high /low flows and water levels ;
treatment plant site, elevation, foundation conditions;
hours of operation of intake, HRF, SSF and distribution ;
availability of raw materials – gravel, sand, rock ;
Requirements for pre-sedimentation with or without combined raw balancing basin.
Design criteria:
Filtration rate (m/h) based on cross sectional area of filter);
Filter box: - length 9-12 m
- height 1-1.5 m
- width 2-5 m per unit
Length of compartments (see Table 5-40)
Media size: - Coarsest 35-40 mm
- finest 4 mm
Required effluent quality for SSF: -Turbidity 10 NTU
-Suspended Solids 2-5 mg/L
Openings in compartment walls: : 10-20% of cross sectional area, evenly distributed.
A layout of typical HRF is shown in Figure 5-102.
Table 5-39: Different Sizes of Roughing Filter Media
Roughing filter First compartment Second compartment (mm) Third compartment
Description (mm) (mm)
Coarse 24-16 18-12 12-8
Normal 18-12 12-8 8-4
Fine 12-8 8-4 4-2
Other criteria, such as expected efficiency of SS removal, length of filter runs, required
maximum head loss, etc. may be estimated by means of a monogram (Reference 33) if
necessary.
Table 5-40: Tentative Design Guidelines for HRF
Maximum suspended solids concentration in pre-settled 300 300- 100 100
water (mg/L) High medium Low
Filtration rate m/h 0.5 0.75 – 1 1-1.5
Filter length (m) for medium size (mm)
20mm 3-5 3* 3*
15mm 2-5 2-4 2-3
10mm 2-4 2-3 2
5mm 1-2 1-2 1
Maximum suspended solids concentration in HRF effluent
5 2-3 2
(mg/L)
*This gravel size can possibly be omitted.
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To allow for head loss across the filter, which builds up as the length of filter run increases
and the filter loads up with silt ; the outlet weir level should be 30-40 cm below the top level
of filter material (see Figure 5-102).
Filter media may be an inert material such as:
Gravel
Broken stones / rocks, metal (coarse aggregate);
Broken burnt bricks ;
Burnt charcoal ; (prior testing at pilot plant level is necessary)
Processed coconut fibre
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(a) Inlet & Outlet Structures of HRF
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Typical inlet / outlet and drainage arrangements are shown in Figure 5-102 (a) and (b)
respectively. Adequate provision of drainage is necessary for filter regeneration (by rapid
drawdown at 60-90m/h) and for emptying for cleaning purposes. Discharge should be to an
open drain and arrangements for safe disposal should be provided to avoid erosion and scour.
Typical mechanical devices to ensure a constant overflow rate are shown in Figure 5-103 (c).
Floating effluent weir or orifice is fixed to ensure a constant outflow rate.
Owning to the fact that a HRF requires continuous operation, the HRF should also be
operated in continuous mode, although the physical nature of the process does not require it.
When a SSF is operated, say, for 8 hours overnight in declining rate mode (due, for example,
to raw water pumping for 16 h/day in 2 shifts) then the HRF is required to work
intermittently. Consideration should be given to providing raw water balancing storage to
allow 24-hour plant operation, and therefore smaller HRF and SSF units (Figure 5-103).
Occasional lowering of the water table by drainage will increase efficiency and prolong filter
runs. During drainage, particle accumulations on the top of the filter media grains tend to
collapse and get flushed to the filter bottom. Rapid drainage, if possible, should also flush
some accumulated matter from the filter.
Drainage should start at the drain nearest the inlet side, to prevent the bulk of deposited
material being drawn into the finer media, thereby clogging it. When the wash water is still
turbid after drainage, the same drain should be operated again, after slow filling, until the
wash water is relatively clear. Then the next drain from the inlet should be operated, and so
on. It is important that refilling, after drainage, is slow so as to avoid stirring up settled
material.
An HRF should not be kept dry, unless the media is thoroughly cleaned. Filter runs may last 6
months or more, depending on the operating conditions and design, and when the efficiency
can no longer be restored by drainage, cleaning must be done. The media must be excavated,
washed, and returned to the filter box. This may be done by hand, using locally hired labour,
and a media cleaning area should be provided adjacent to the filter. A typical gravel cleaning
unit is shown in Figure 5-104. Equipment used in the construction stage, such as wheel-
barrows, shovels, etc., should be retained at the plant for media washing purposes during
operation.
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Figure 5-104: Effect of Operation on Size of Filters
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(a) Washing of Media
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5.13.8. Factors Affecting Roughing Filter Performance
The disadvantage of RF is low hydraulic load. The only way to provide sufficient treated
water to meet a high drinking water demand would be to build a larger RF unit (Boller, 1993).
The filtration rate (m/h) depends largely on the type of filter, the water characteristics, desired
turbidity reduction, variations in the filter media (porosity), each filter medium‘s proportion.
The number of filter fractions and height and width of filter bed area (m2) dictate filtration
and optimize the removal of suspended matter. The filter media size (mm) and type (gravel
and broken clay) is also an important consideration. The most influential factor for turbidity
removal efficiency in the raw water is particle sizes and distribution.
Filter efficiency depends on the concentration of suspended solids. The 1/3 and 2/3 Filter
theory explains how each layer removes about 1/3 of the particles letting the other 2/3 flow to
the next layer. This continues at each layer, because there is a greater concentration of
particles at the first layer, more particles are removed than in latter layers. Intermittent flow
operation can greatly decrease the particle removal efficiency because it is possible that the
biofilm around the coarse media might have dried and lost its sticky properties.
High sludge storage space can be advantageous in lengthening filter runs but becomes
problematic when the filter finally needs to be cleaned. Its buffering capacity to manage
fluctuating solid concentrations exists because the large pore spaces allow considerable
amounts of solids to be stored at very low head loss. Periodic drainage through perforated or
corrugated pipe may be able to improve the filter run time between cleanings and needs to be
further developed. Scraping of the top layer of biofilm on a weekly basis could also improve
the filter run time. Fully unpacking the media and cleaning is one of the biggest drawbacks of
the RF even when the media is readily accessible as in HRF.
5.13.8.1. Advantages of roughing filters over conventional methods
Conventional system is quite demanding in chemical use, energy input and mechanical parts
as well as skilled manpower that are often unavailable, especially in rural areas of developing
countries like Tanzania, Kenya and Sri Lanka. But roughing filters does not require chemical
use, energy input and mechanical parts. Conventional methods demand high operating costs.
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Arrangements should be made to enable this sampling/ monitoring to be done by the plant
operator, OIC with assistance of Chemist. The installation of sampling point is shown in
Figure 5-106.
Instead of disposal, the first approach to end use is now beneficial utilization and solids
treatment. Systems are often geared to preparing a material that can be used. Minimization of
the liquid volumes of waste produced is also increasingly important. Water quality issues
associated with storing residuals in the process train or associated with recycling the water
back to the treatment plant have become important in planning a waste management system.
Process flow diagram for sludge management in water treatment plant is shown in Figure
5-118.
The National Environmental Act Number 47 of 1980 and amended Act Number 56 of 1988
and the latest amendment on 1st February 2008 specifies the requirements in compliance with
―Tolerance Limits for the Discharge of Industrial Waste Into Inland Surface Waters‖ for 31
parameters given in Table 5-41. The compliance for effluent from water treatment plant is of
no exception. The new standards dictate discharge criteria need to be achieved in order to
obtain or renewal of the Environmental Protection License for Emission or Disposal of
Wastewater, which will become mandatory for all water treatment plants in the near future.
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Table 5-41: Tolerance limits for the Discharges of Industrial waste in to Inland surface
waters
No Parameter Unit type of limits Tolerance limit values
01 Total suspended solids mg/L,max 50
02 Particle size of the total suspended µm, less than 850
solids
03 pH at ambient temperature - 6.0-8.5
04 Biochemical oxygen demand mg/L, max 30
(BOD in five days at 200c or BOD in
three days at 270c)
0
05 Temperature of discharge c, max Shall no exceed 400cin any
section of the stream within
15m downstream from the
effluent outlet
06 Oils and greases mg/L 10
07 Phenolic compounds (as C6H5OH) mg/L 1
08 Chemical oxygen demand (COD) mg/L 250
09 Colour Wave length range Maximum spectral
absorption coefficient
436nm(Yellow range) 7m -1
525nm(Red range) 5m -1
620nm(Blue range) 3m -1
10 Dissolved phosphate (as P) mg/L 5
11 Total Kjeldahl nitrogen (as N) mg/L 150
12 Ammoniac Cal nitrogen (as N) mg/L 50
13 Cyanide (as CN) mg/L 0.2
14 Total residual chlorine mg/L 1.0
15 Flourides (as F) mg/L 2.0
16 Sulphide (as S) mg/L 2.0
17 Arsenic (as As) mg/L 0.2
18 Cadmium (as Cd) mg/L 0.1
19 Chromium , total (as Cr) mg/L 0.5
20 Chromium, hexavalent (as Cr 6+) mg/L 0.1
21 Copper (as Cu) mg/L 3.0
22 Iron (as Fe) mg/L 3.0
23 Lead (as Pb) mg/L 0.1
24 Mercury (as Hg) mg/L 0.0005
25 Nickle (as Ni) mg/L 3.0
26 Selenium (as Se) mg/L 0.05
27 Zinc (as Zn) mg/L 2.0
28 Pesticides mg/L 0.005
29 Detergents/surfactants mg/L 5
30 Fecal Coliform MPN/100 ml, max 40
31 Radio Active Material:
Alpha emitters Micro curie/ml, max 10-8
Beta emitters Micro curie/ml, max 10-7
Note1: All efforts should be made to remove unpleasant odour as far as possible
Note 2: These values are based on dilution of effluents by at least 8 volumes of clean receiving water. If the
dilution is below 8 times, the permissible limits are multiplied by the 1/8 of the actual dilution
Note 3: The above mentioned general standards shall cease to apply with regard to a particular industry when
industry specifies standards are notified for the industry
Note 4: Pesticide as per world health organization (WHO) and food and Agriculture Organization (FAO)
requirements.
Accordingly, NWSDB Project Appraisal Committee (PAC) approved the sludge treatment Policy and
has granted a board approval on 21st June 2012 for ―Sludge management policy for water treatment
plants and Circular was issued by General Manager, NWSDB on 19th December 2012 for
implementation.
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5.14.2. Unit operations and Processes
In general the residuals management processes includes sedimentation, thickening,
conditioning dewatering, drying and disposal. Often residuals from water treatment plants are
allowed to discharge into the sanitary sewers. Selection of any of these processes depends
greatly on such factors as space available at the site, type and quantity of sludge, local
weather condition, cost of raw chemicals and type of ultimate disposal available. A summary
of different residual management components commonly used in residual treatment train is
provided in Table 5-42.
Table 5-42: Unit operations and processes used for residual management
Unit Unit operation (UO)
Description and principal application
No and Unit Process(UP)
A Sedimentation and The objective is to remove excess water and to concentrate solids. the
Thickening (UO) liquid is usually recovered unless it contains taste and odours , algae and
other microorganisms
A1 Sludge lagoon (UO) Large open earthen or concrete basins 3 to 4 m depth of Thickening up to
solids 5 to 10 % solids can be achieved in one to three months with
continuous decanting
A2 Gravity (UO) Circular tanks designed and operated similar to solids – contact clarifier or
sedimentation basin. Chemical conditioning may increase the % of solid
content.
B Conditioning Sludge conditioning is done to aid in thickening and mechanical
dewatering. The objectives are to improve the physical properties of the
sludge, so that water will be released easily from solids. Conditioning is
generally used from alum- coagulated sludge
B1 Chemical (UP) Polymers are the most commonly used chemical for sludge conditioning.
Lime and inert granular materials like fly ash have also been used.
B2 Freezing (UO) Freezing destroys the gelatinous structures and thus improve thickening
and dewatering. This process is usually applied only where natural
freezing is possible.
B3 Heat Treatment (UO) Heating improves settling and dewatering. Because of energy cost, it is an
undesirable method of sludge conditioning.
C Dewatering(UO) The process produces relatively dry sludge for future treatment of
residuals.
C1 Drying bed(UO) This is a gravity dewatering system where conditioned sludge may be
applied without thickening. Sludge is applied on a filling and drying cycle
over filter beds or lagoons that have an under drain system. Water is
removed by filtration and decanting.
C2 Centrifuge(UO) Conditioned sludge is dewatered in a solid – bowl or basket centrifuge.
Both capital and operating costs are high
C3 Vacuum Filter (UO) Rotary drum vacuum filter with travelling media or precoat media filter
are used for dewatering. Sludge conditioning is generally needed.
C4 Filter Press(UO) Also known as plate and frame or leaf filter. It is an effective method of
sludge dewatering. It is a batch process and uses chemically conditioned
sludge.
C5 Belt Filter press(UO) Operates continuous. The sludge is squeezed between two belts as it
passes between various rollers. Sludge conditioning is necessary.
D Recovery Recovery of water, coagulants and magnesium bicarbonate is possible
from the sludge.
D1 Coagulants(UP) Recovery Aluminum and Iron can be accomplished by adding acid
(Sulfuric acid) to solubilize the metal ions from the sludge. Accumulation
of heavy metals, manganese, and other organic compounds is possible.
D2 Lime(recalcination) (UP) Recovery of lime from calcium carbonate sludge is achieved by
recalcination. The dewatered sludge is dried and heated to about 1000
degrees C. CO2 is driven off, which may be used for recarbonation.
D3 Magnesium Magnesium recovery is possible from a sludge containing calcium
carbonate and magnesium hydroxide. Bubbling CO2 produces soluble
magnesium bicarbonate, while calcium carbonate remain insoluble.
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Unit Unit operation(UO)
Description and principal application
No and Unit Process(UP)
E Disposal Disposal of residuals may be disposed on land, in sanitary sewer, in
surface waters and by deep-well injection.
E1 Land Disposal Dewatered , semi liquid, and liquid residuals are disposed of by land
filling or land spreading governed by the Resource Conservation and
Recovery Act of 1976 [18] . Cost of transportation may be significant.
E2 Sanitary Sewer Directing discharge into sewer system is an attractive option if residuals
do not adversely affect the operation of the wastewater treatment plant.
Unit Unit operation(UO) and Description and principal application
No Unit Process(UP)
E3 Surface water Central Environmental Authority (CEA) permit is required for disposal of
residuals into surface water in the form of Environmental Protection
Licence (EPL ). The permit requirement varies with the types of residuals
and with the type of surface water.
E4 Deep-well injection Brines from iron exchange and membrane processes may be injected into
deep wells. Such injection disposals are controlled by local environmental
regulations subject to geology and ground hydrology.
When the treatment capacity exceeded >4,500 m3/day (even for capacities less than 4,500
m3/day where there is scarcity of source water or extensive use of high energy for raw water
pumping), it is advantageous to reuse the backwash water in order to conserve energy and
source water. However, recycling of backwash water is not allowed in places where polymer
is used. Polymer addition is not encouraged to minimise the health effects to presence of
possible toxic monomers. In addition, backwash recycling will not be applied where raw
water contains blue green algae, protozoa such as cryptosporidium and Giardia Lamblia. The
additional energy consumed for pumping in backwash water recovery would be
comparatively less than the equivalent for that pumping of raw water. Therefore, backwash
water recovery may be economical in large water treatment plants.
Identify the residual generating processes, normally these include sludge from
coagulation- flocculation and precipitation/ sedimentation processes and filter
backwashing in conventional water treatment plant.
Conduct material mass balance analysis to establish quality and concentrations of
solids reaching the residuals stream such information is necessary under critical flow
and water quality condition.
Evaluate various applicable methods for filter backwash recovery and sludge
thickening, dewatering and disposal. Select systems that provide the most cost
effective result and are satisfactory to the concerned utility and regulatory agencies.
1. Land requirement
2. Operation under adverse climatic condition
3. Ability to handle flow variations
4. Process reliability
5. Ease of operation and maintenance
6. Prior requirements
7. Quality of supernatant and sludge
Pilot plant is becoming a valuable tool for treatable studies to develop design parameters, to
test new chemicals, to optimize dosage and to evaluate processes to improve plant
performance and reduce costs. There are a number of other cases where pilot studies may be
needed. For example, a state- approved agency might, as a matter of policy requires a pilot
study for innovative treatment processes. Another example would be a situation wherein a
process cannot be modelled sufficient to lead to design criteria, such as taste and odour
episode. In general, pilot plant studies in water works engineering are carried out for the
following purposes.
It is believed that pilot studies at municipal water treatment plants are valuable in developing
designs and process train that can improve performance of new and existing plants and reduce
operating costs.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 5-170
and powdered activated carbon, disposal of diatomaceous earth filter wash water, and disposal
of spent brines. On the whole these wastes are stable or non-putrescible, and are, therefore,
collected or discharged intermittently rather than continuously.
The characteristic of the residual streams generated in various treatment processes are
primarily a function of treatment process, added chemicals and quality of raw water. An
understanding of the quantity of sludge, solid content and the nature of solids is essential to
select and design the processing equipment properly. Typical constant for estimating sludge
production is shown in Table 5-43.
Table 5-43: Typical Constants for Estimating Sludge Production
Source Sludge Quantity Constant
Turbidity Removal 0.5 to 2 mg TSS/L , per NTU removed
Coagulation
Aluminum Sulphate (Alum) Al2(SO4)3.14 H2O 0.26 kg per kg of Coagulant b
Ferric Sulphate Fe2(SO4)3 0.54 kg per kg of Coagulant c
Ferrous Sulphate FeSO4.7 H2O 0.39 kg per kg of Coagulant d
Ferric Chloride, FeCl3 0.66 kg per kg of Coagulant e
Polymer 1 kg per kg of Coagulant
Powder activated carbon 1 kg per kg of Coagulant
Softening
Calcium 2.5 kg per kg of Calcium (as Ca) removed
Magnesium 2.4 kg per kg of Magnesium (as Mg) removed
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High turbid waters usually results in sludge that are more concentrated and less
difficult to dewater; low – turbidity water present a more difficult sludge for
processing.
Coagulation sludge from water containing high algae concentration will result in
sludge of light weight and low solids concentration.
Sludge with high proportions of metal hydroxides is not easily dewatered as sludge
that has high proportions of other materials. This is because metal hydroxide has water
molecules in their structures that separate the floc and other particles. Thus, direct
contact of particles is more difficult, unless large amount of lime and optimum
polymer dosage are used to improve the bond between the particles.
In general, settled iron sludge has a higher solids concentration than alum sludge.
The addition of polymer, lime, or PAC increases the solids concentration of both alum
and iron sludge.
Alum sludge is a voluminous gelatinous sludge with poor compressibility. It will
generally concentrate 0.5 to 2 % solids in the sedimentation basin. It can achieve 10 %
concentration in 2 days in sand beds.
Solid concentration in a sedimentation basin depends on the design and operation of
the facility. Typical underflow concentration may vary from 0.1 to 1 % solids. If
however, the sludge is allowed to accumulate for a month or longer, the sludge may
thicken up to 4 to 6% solids.
The Density of sludge depends upon moisture content. Sludge with 1 % solids has
almost the same density as water. The density of dry sludge is 1200 to 1520 kg/m 3.
The specific gravity of sludge solid is 1.5 to 2.5
Sludge viscosity and shear strength increases as solids concentration increases. Below
solids concentration of about 2 %, the specific resistance of sludge increases as solids
concentration decreases. Above 2 % solids concentration, the specific resistance
remains almost constant.
The volatile fraction of the suspended solids does not reflect the organic fraction,
because much of the loss on ignition is probably due to bound water in hydrated
oxides.
Ferric oxides are insoluble over a wider PH range than are aluminium oxides, so the
PH of the water in contact with hydrated iron oxide may be found to vary over a wide
range.
Table 5-44: physical and chemical characteristics of Alum and Iron Coagulated Sludge
Characteristics Alum Sludge Iron Sludge
Physical
Quantity, kg/1000m3 8-210 , Typical 48 80
lb/million gal 67-1750, Typical 400 668
Specific resistance s2/g 1.05-5.4 x 1010 1X 108
Viscosity g/cm/sec 0.03 (non – Newtonian) 0.03
Initial Settling velocity cm/sec 0.06-0.15 -
Dry Density kg/m3 1200-1520 1200-1800
Dewater ability 10% concentration in 2days on sand beds) -
Chemical
BOD mg/L 30-300 30-300
COD mg/L 30-5000 30-5000
pH 6.0-8.0 7.4-8.5
Total Solids. % 0.1-4 0.25-3.5
Solids Characteristics
Al2O3.5H2O% 15-40 -
Fe % - 4.6-20.6
Silicate and inert material, % 35-70 -
Organics % 15-25 -
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Volatiles % - 5.1-14.1
5.14.3.3. Quantity
The quantity of solids produced in coagulation is dependent upon total suspended solids in the
water on type and dose of coagulant, and on the settling efficiency of the sedimentation basin.
Generally 60-90 % of total solids are removed in the sedimentation basin. The remaining
solids are removed in the filters. There is no absolute correlation between the turbidity units
(TU) and total suspended solids (TSS). A ratio of TSS to TU normally varies from 05 to 2.0.
It has been reported that total solids from an alum coagulation facility may vary from 8 to
210kg/per 1000m3 of raw water treated.
As per the typical value in practice for sludge production, 1 Kg of Aluminium sulphate
produces 0.26 kg sludge. (Refer Table 5-44)
Ferric Sulphate is also a principal coagulant used in water treatment. However, It is not
commonly used in Sri Lanka. Ferric sulphate reacts with natural alkalinity, but the response is
much slower than that between alum and natural alkalinity. Ferrous ions are precipitated as
ferric hydroxide.
The dosing operations with two chemicals (ferrous sulphate and lime) are more difficult. If
excess lime is used the water may require further treatment for stabilization.
As per the typical value in practice for sludge production, 1 Kg of Ferric sulphate produces
0.54 kg sludge (Refer Table 5-44). Ferric is highly corrosive and strains the flow during
spillages. Therefore, special floor protections should be provided.
( )( )
-6
=1.684 X10 moles/L
Noting that 1 mole/L of alum yields 2 moles/L of the aluminium precipitate and that the gram
molecular weight of the precipitate is 132.05 g/mole, then the mass of dry solids is
2(1.684X10-6 moles/L)(132.05 g/mole)=4.446X10-4 g/L or 0.44 mg/L
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 5-173
Thus, on a theoretical basis, each mg/L of alum yields 0.44 mg/L of sludge on a dry weight
basis. Suspended solids present in the water will produce an amount of sludge equal to the
weight mg/L of suspended solids. The amount of sludge produced per turbidity unit is not as
obvious; however, in many waters a correlation does exist. Carbon, polymers, and clay will
produce about 1 kg of sludge per kg of chemical addition. The sludge production for alum
coagulation may then be approximated by (Davis and Cornwell, 2008):
Ms =86.4 Q(0.44A+SS+M)
Where
M s - Mass of dry sludge produced, kg/d
Q - Plant flow, m3/s
A - Alum dose, mg/L
SS - Suspended solids in raw water, mg/L
M - Miscellaneous chemical additions such as clay, polymer, and carbon, mg/L
The effect of polyaluminum chloride (PACl) doses on solids production is not as straight
forward as alum and iron calculations because there is no uniform strength measurement. A
typical liquid PACl contains about 30 to 35% PACl and about 10 percent Al2O3 .A very rough
estimate of the dry solids production is about 0.8 mg for each mg of PACl added expressed as
PACl.
Solids concentrations from horizontal flow settling basins using continuous collection
equipment for alum and iron sludge resulting from coagulation of low- to moderate-turbidity
raw water will be in the range of 0.5 to 2 percent . It is often less than 1 percent . Coagulant
sludge from highly turbid water may be in the 2 to 4 percent range (Cornwell, 1999). Twenty
to 40 percent of the solids are organic constituents; the remainders are inorganic constituents
or silts. The specific gravity of alum-coagulated solids is typically in the range of 1.2 to 1.5.
The range of specific gravity for iron coagulated sludge solids is 1.2 to 1.8 (MWH, 2005).
The sludge flow rate is often in the range of 0.3 to 1 percent of the treatment plant flow.
1. The suspended solids and other constitutes such as Fe, Mn in raw water
2. The amount of metal hydroxide
3. The calcium carbonate produced
4. The amount of polymer added
5. The powder activated carbon added
The sludge quantity is calculated from the optimum chemical dosage and constituents
removed under both the maximum day and average day design flow condition.
a) Summary of chemical dosages and raw water constituents producing sludge solids.
The following design parameters are adapted to calculate the residuals quantity from
sedimentation process.
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Optimum Coagulant (Alum) 25 mg/L
Optimum Coagulant aid (Cationic polymer) 0.05 mg/L
Hydrated lime for pH adjustment 15 mg/L
Seasonal Potassium permanganate (KMnO4) dosage 4 mg/L
Seasonal Powder Activated Carbon (PAC) dosage 5 mg/L
Table 5-45: Chemical symbol, Atomic Number, Atomic weight, and valance
Element Symbol Atomic number Atomic weight Valance
Aluminum Al 13 26.9815 3
Calcium Ca 20 40.08 2
Carbon C 6 12.01115 4
Chlorine Cl 17 35.453 1,3,5,7
Hydrogen H 1 1.00797 1
Iron Fe 26 55.847 2,3
Magnesium Mg 12 24.312 2
Manganese Mn 25 54.938 2,3,4,6,7
Nitrogen N 7 14.0067 3,5
Oxygen O 8 15.9994 2
Phosphorous P 15 30.9738 3,5
Potassium K 19 39.102 1
Sulphur S 16 32.064 2,4,6
( )
= 6.69 kg/d
iii Calculate the solid precipitation due to Mn content
= 3.2 kg/d
iv Calculate the solid due to precipitation of Aluminium sulphate
Al2(SO4)3.14H2O +3Ca(HCO3) 2 Al(OH)3 +3CaSO4+ 6 CO2 + 14 H2O
Accordingly Aluminium sulphate - 0.26 kg/kg alum added – table 5.41
Q coagulant, Max = 0.26 kg Al(OH)3/kg Alum *25 g/m3 Alum*10-3 kg/g*5000 m3/d
= 32.5 kg/d
v Calculate the solid due to polymer
Q Polymer, Max = 0.05 mg-polymer/L * 10-6 kg/mg * 103 L/m3 * 5000 m3/d
= 0.25 kg/d
vi Calculate the lime solid during pH Adjustment
(Assume 20% of Ca(OH)2 precipitates as CaCO3)
( )
( )
= 20 kg/d
vii Calculate the solid due to permanganate
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 5-175
= 11.2 kg/d
viii Calculate the solid due to PAC
Q PAC, Max = 5 mg-PAC/L X 10-6 kg/mg X 103 L/m3 X 5000 m3/d
= 25 kg/d
Ix Total solid produced
= (85 + 6.69 + 3.2 + 32.5 + 0.25 + 20 + 11.2 + 25) kg/d
= 183.84 kg/d
Because of many uncertainties associated with raw water quality, chemical dosage,
and the amount of bound water, it is common practice to increase this value by 20-60
percent. By increasing this quantity by 40%, the total sludge solids and production is
adjusted to 257.0kg/d
The solid content of coagulant residual is within the ranges of 0.1 - 4.0 percent by
weight (w/w). An average under flow solid concentration of 2 percent in sludge
withdrawal is expected from the sedimentation basin. Assume the specific gravity of
dry solids and water is 2.4 and 1.0 respectively. For one kg of wet sludge mass with 2
percent solid, the following results is expected for the above equation.
1 kg/ Sg,ws = 0.02 kg/2.4 + 0.98 kg/1.0
Solving the above Sg,ws = 1.012
e) Volume of sludge withdrawn under maximum day flow condition.
For the sludge with 2% solid and a specific gravity of 10.012 at the production rate of
231.3 kg/d, calculating the volume of wet residual per day-to-day
= 11.43 m3/d
The quantity of sludge produced per 1000m3 of raw water treated =
⁄
= 46.26 kg/1000 m3
It has been reported in the literature that total solid from an alum coagulation facility
may be 8-200 kg per 1000 m3 of raw water treated
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5.14.3.7. Spent Filter Backwash Water
All water treatment plants that practice filtration produce a large volume of wash water
containing a low suspended solid concentration. The volume of backwash water is usually 2
to 3 percent of the treatment plant capacity. Spent filter backwash water (SFBW) will
typically contain 10 to 20 percent of the total solids production. It will have a suspended
solids concentration in the range of 30 to 400 mg/L depending on the applied turbidity and the
ratio of backwash water to production water volume (Cornwell, 1999; Peck and Russell,
2005). From limited data, solids production can range from less than 3 kg/1,000 m3 to more
than 16kg/1000 m3 of production water (Cornwell, 2006). The solids in backwash water
resemble those found in sedimentation units. Because filters can support biological growth,
the spent filter backwash water may contain a larger fraction of organic solids than the solids
from the sedimentation basins. SFBW will contain substantial concentrations of
microorganisms. SFBW has been identified as a source of microorganisms that increases the
concentration of Cryptosporidium and Giardia lamblia in the recycle water. This may result in
an undesirable breakthrough of these organisms into the water supply.
Recovered washed water is contaminated with the sludge. Water collected from each filter
backwash cycle water is stored in one of the two compartments allowed to be settled for about
for 1 to 2 hr. After settled, clear water is directed to Backwash recirculation tank through a
suitable arrangement such as pontoon as shown here.
Sludge pumps have to be operated to transfer remaining sludge to sludge regulation tank once
clear water is transferred to sludge recirculation tank.
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Floating Boom
Floating Boom
Backwash
water Inlet
Figure 5-108: View of Back wash recovery Tanks and Backwash recirculation Tank and
Inside view (Biyagama WTP)
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5.14.4. Design Considerations and Criteria
Methods for processing and disposing of residuals from a water treatment plant should be
investigated early in the planning phase. Sludge disposal may represent a substantial portion
of the investment and operating costs of providing treated water and may influence the source
water selection and the method of treatment. Following factors should be considered while
evaluating design of alternative processes:
Normal ranges of solid concentration of by various processes are shown in Table 5-47. The
processes generally achieve a higher percentage of solids content for lime sludge than for
metal hydroxide sludge. For example, a centrifuge may dewater metal hydroxide sludge to
15% while lime sludge is dewatered to 50%.
Table 5-47: Normal ranges of solid content by various residual treatment processes
Solids concentration
Process
alum or metal hydroxide sludge Lime sludge process
Thickening <- 8% < 25%
Dewatering 8% to 35% 25% to 60%
Drying > 35% > 60%
Natural dewatering refers to those methods of sludge dewatering that remove moisture by
natural evaporation, gravity or induced drainage. These processes are less complex, are easier
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to operate, and require less energy to operate than mechanical systems. However, they require
a large land area, the operation depends on climatic conditions and they are labour-intensive.
Natural dewatering typically uses the following mechanisms for the concentration of the
solids stream:
• Sedimentation
• Drainage, or percolation
• Evaporation
• Decanting
5.14.4.3. Drying
Drying of water treatment plant residuals has historically revolved on the issue of economics,
how to reduce disposal transportation costs through reducing solid volume. Drying to solids
concentrations greater than 35% is becoming a regulatory issue in many countries. Similar to
the dewatering process, the drying process may be carried out either through open-air means
or through mechanical devices. Solar drying or lagoon processes may be used for sludge
drying. Drying depends only on evaporation, so it may require years to achieve the desired
solid concentrations. Mechanical or thermal drying provides an alternative to open air-drying
in locations where space is limited or environmental concerns are prohibitive.
The velocity with which solids settle out will depend on the concentration of solids (refer
Figure 5-109). Right after time zero, there are two interfaces moving towards each other. One
from the bottom up due to the building up layers of sludge from the bottom, the other
interface is moving down- from top to bottom; this is the blanket of settling sludge, settling
velocity v, at time t2, these will meet and settling will slow down. Then the settling will cease
over time and compaction begins. Figure 5-110 shows the illustration of interfaces during
settling test.
Heigh of interface
Heigh of interface
Zone settling
Transition settling
Compression settling
t1 t2 Time
Figure 5-110: Illustration of interfaces during settling test
The Figure 5-111 and the procedure are given below to select the required area of the
thickener.
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Height
Point 1
Hu
Time
Tu
Figure 5-111: Graph to select the required area according to Talmage and Fitch
procedure
Symbols
Co - Original sludge concentration
Cu - Thickener underflow sludge concentration
Ho - Original sludge height
H1 - Intercept on ordinate by tangent to the critical point
Hu - Height of thickened sludge at underflow concentration
Tu - Time of thickening
Procedure
1. Determine the slope of the Zone Settling Velocity (ZSV) (this is the settling velocity
for clarification).
2. Extend the tangents from the ZSV region and compression region and bisect the angle
formed to locate point 1.
3. Draw a tangent to the curve at point 1.
4. Known: Co, Ho, and select Cu, then make a mass balance Cu.Hu = Co.Ho, calculate Hu
from Co, Ho.
5. Draw a horizontal line from Hu until it intersects with the tangent line and determine
tu. This is the time required to reach an underflow concentration.
6. Determine the area required for thickening (At) = 1.5 Q /tu where Q = flow rate to the
tank 1.5 = scale-up factor
7. Determine the area required for clarification (Ac) = 2.0 Q / ZSV
Thickener Design
1. Characteristic of the solid reaching the gravity thickener
The gravity thickener solid include sludge form the sedimentation basin and if any
from backwash recovery basin.
It is calculated that the 5000 m3/d plant produces
Total solid – 231.3 kg/d
Total volume – 11.43 m3/d
2. Gravity thickener design
a. Calculate the dimensions of the thickener
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Based on the solid loading of 80 kg/m2. /d, the required area is as follows;
Total required area is
= 1.1 m
b. Check the hydraulic loading
Hydraulic loading =
= 3.81 m3/m2d
This nearly satisfies the minimum hydraulic loading of 4 m3/m2d. (Hydraulic
loading is 4 ~ 10 m3/m2/day, Qasim, 2007).
The major advantage of sludge thickening is the cost saving in sludge handling processes. The
design and operation as well as the performance of several subsequent processes are
positively affected by a higher solid content of the input sludge. Stabilization as well as
dewatering processes is improved at higher sludge concentrations.
Gravity sludge thickening is the method commonly adopted. Slope of the bottom of the
gravity thickeners should be carefully selected in order to facilitate flow of thickened sludge
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 5-183
towards the centre/collection pit. Gravity thickeners are usually circular in shape and provided
with pickets or rakes to improve dewatering of sludge. A dry solids content of 2-2.5% can be
expected from gravity thickening.
Polymer dosing to enhance performance of thickening process can increase the dry solids
content at least to 4% and it will improve the efficiency of dewatering processes such as
sludge drying beds, or centrifuge which would follow thereafter. The centrate resulting from
dewatering should not be recycled back into the water treatment plant. Instead, it can be sent
back to the sludge regulation tank under gravity to undergo thickening process.
The thickener supernatant can be discharged to the environment if it complies with the CEA
regulations or else suitable pre-treatment should be provided. Progressive cavity pumps can
be used to transfer the thick slurry to an appropriate sludge dewatering process depending on
the hydraulic profile of the treatment plant.
As a rule, where sludge can be lagooned to a depth of 3 m a land area of 1.2 -2.0 ha for 4000
m3/day capacity plant will be adequate. If the sludge is applied to a depth of 1 m, the berms
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shall be built 1-1.5 m above the maximum sludge level when filled. The berms should be 3.0-
3.5 m wide to
1. permit operation of drag line
2. Permit raising their top elevation
3. Facilitate driving of service vehicles
Sludge dried to 50% moisture is easy to handle and makes excellent material to burn.
Where sufficient land is available, lagooning may be a satisfactory and an economical sludge
drying and disposal method. In view of the cost of the land and the equipment and of the
operation and maintenance cost of a lagoon, a careful evaluation must be made for process
selection and design.
Lagoons may be the cheapest method of sludge dewatering but large land area is required
compared to mechanical dewatering techniques. However, compared to conventional sludge
drying beds, lagoons require considerably lesser land extent. Lagoons can be lined or unlined
or can be provided with under drain arrangement for better dewatering requirements.
5.14.7.1. Operation
Lagoons are generally operated in a cyclic fashion fill, settle, decant. This cycle is repeated
until the lagoon is full or the decant can no longer meet discharge limitations. The solids are
then removed for final disposal. The standing water is removed by decanting or pumping to
facilitate drying. To recover the water, the decant is often returned to the head end of the
plant. As noted for thickening, this may be a problem because it increases the concentration of
Cryptosporidium and Giardia.
Dewatering lagoons, which are generally earthen basins, have no size limitations but have
been designed with surface areas from 2,000 to 60,000 m2, and depths ranging from 2 to 10
m. typically; several lagoon cells are provided to allow for a drying period after the lagoon is
full. Dewatering lagoons should be equipped with inlet structures designed to dissipate the
velocity of the incoming sludge. This minimizes turbulence in the lagoons and helps prevent
carryover of solids in the decant. The lagoon outlet structure is designed to skim the settled
supernatant.
When land is readily available, lagoons may serve as both thickeners with continuous
decanting and drying beds. A common approach for coagulant sludge is to provide sufficient
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volume for three months of filling and three months of dewatering. Provide stop log
arrangements at the outlet to decant the standing water permanently by the remaining logs.
Raw Sludge
Sludge settles
Water is Removed
(Decanting)
Dried Sludge
Unlined earthen sludge lagoons are more effective in dealing with large volumes of sludge
from water treatment plants of higher capacity. However due consideration should be given to
the following during planning of the water treatment plant layout to locate sludge lagoons,
Fluctuation of groundwater table and flood level (seasonal high groundwater table
should be sufficiently below the bottom of the lagoon preferable below 2.5 m)
Underlying soil characteristics should be investigated to see its suitability, soil
percolation rate between 25 to 150 mm/hr being preferred
Annual precipitation preferably to be below 3000mm
Access ramps to be provided for dumper/tractor/mini loader to collect dried sludge
from the lagoon and final disposal
The area of the lagoon is based on the area required for the dewatering layer. It is calculated
as
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The preferred depth for filling is 1.2 m with a recommended maximum of 1.8 m (Kawamura,
2000). In locations with a wet climate, these depths should probably be lower.
Typical solid loading rates range from 40 to 80 kg dry solids/m2 of surface area, with the
lower value being applied in wet regions and the higher value in dry regions. In the absence of
specific geometric design, a multiplier of 1.5 times the area (As) is used to account for berms
and access roads in estimates of the required land.
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Figure 5-114: Sand Drying Bed
For mechanical sludge removal, the dimensions should be selected to accommodate the
removal equipment, that is, multiples of the loader bucket width. In a typical design, 0.3 to
0.46 m of sand is placed over 0.3 to 0.46 m of graded gravel or stone.
The sand is specified with an effective diameter that ranges from 2.0 to 3.0 mm and a
uniformity coefficient from 3.5to 5.0. Gravel is normally graded from 3 to 25 mm in effective
diameter.
Drying beds consists of perforated under drainpipes, gravel, and sand. The sludge is applied in
a depth ranging from 0.3 to 1.0 m. Greater sludge depth require longer drying times. Solid
concentrations of from 15 – 30 percent can be attained with alum sludge. The drying time
may vary from five to seven days depending on the climate. Field tests must be conducted to
develop design information. Solid loading rate can range from 100 to 300 kg of dry solids per
m2 per year. The estimated number of beds uses depends upon climate, solid concentration in
the sludge and sludge conditions applied. Multiple beds must be provided to allow
application, drainage and drying and sludge removal cycle. The bed is usually considered
dewatered when sludge can be removed by earth removing equipment.
Experience in water treatment plants in Sri Lanka reveals that sludge emanating from
dissolved air floatation technique, which contain considerable amount of algae retard the
drying process of the sludge drying beds. In such situations, it may be more appropriate to
adopt mechanical dewatering techniques such as centrifuge with polymer dosing. Such
process selection may have to be verified through research. User-friendly arrangement is to be
provided to collect dried sludge from sludge drying beds.
5.14.8.2 Operation
Sludge is dewatered on a sand drying bed by three mechanisms, drainage, decanting, and
evaporation. First, the water is drained from the sludge, into the sand, and out the underdrains.
This process may last a few days until the sand is clogged with fine particles or until all the
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free water has drained away. Decanting can occur once a supernatant layer has formed.
Decanting for removal of rainwater can also be particularly important with sludge that does
not crack.
The water that does not drain or decant, must evaporate. Climate plays a significant role in the
feasibility of using this drying technique.
The time required for evaporating the water remaining after percolation and decanting is the
controlling factor in determining the bed size required. Therefore maximizing the removal of
water prior to evaporation will maximize the bed yield. The solid that remained after drainage
and decanting are referred to as drained solid. The value of drained solid concentration is
dependent on upon the initial solid concentration, the use of conditioning agent such as
polymer, the applied depth and the efficiency of the water removal system. A series of pilot
tests can be conducted to determine the combination of loading depth, initial concentration
and polymer use that maximize the drained solid concentration.
The capital cost of roofing over a sand drying bed of any appreciable size probably
precludes it from being built. The cost of labour is such that mechanical sludge removal
will, be more economical than manual removal.
Operational procedures common to all types of drying beds involve the following steps:
1. Pump sludge onto the drying bed surface.
2. Add chemical conditioners continuously by injection into the sludge as it is pumped
onto the bed. Anionic, cationic, and non-ionic polymer have all been used successfully
in individual application. However, a combination of polymers may give the best
dewatering characteristics.
3. Polymer doses fall in the range of 1 to 10 g/kg of sludge solids (MWH, 2005).
4. When the bed is filled to the desired level, allow the sludge to drain and dry to the
desired final solids concentration. This concentration can vary from 15 to 30 percent
for coagulant sludge and 50 to 70 percent for lime sludge.
5. Remove the dewatered sludge either mechanically or manually.
6. Repeat the cycle.
Periodically, sand that is inadvertently picked up when the dewatered sludge is removed must
be replaced. The filtrate from the sand drying beds can be recycled, treated, or discharged to a
watercourse depending on its quality.
Ideally, pilot testing is conducted prior to design of the sand drying bed. The pilot tests
provide data on the loading depth, initial solids concentration, and polymer use that
maximizes the drained solids concentration. Some example data are available in textbooks.
Although similar data for lime sludge are not available, typical loading depths of 0.3 to 1.2 m
have been reported (ASCE, 1990). From the data trends, it is apparent that there is a general
trend of diminishing return in drained solids concentration with increased loading. Laboratory
testing of the filtrate from the pilot tests provides data for the decision on the final disposition
of the filtrate and decant.
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5.14.9. Belt Filter Press (BFP)
The belt filter press operates on the principle that bending a sludge cake contained between
two filter belts around a roll introduces shear and compressive forces in the cake, allowing
water to work its way to the surface and out of the cake, thereby reducing the cake moisture
content. The device employs double moving belts to continuously dewater sludge through one
or more stages of dewatering. Typically, the BFP includes the following stages of treatment:
Design Considerations
The design and selection of a belt filter press is often based on the ―throughput‖ of the press.
Throughput is the rate at which residuals can be dewatered. The throughput can be either
hydraulically or solids limited. A belt press having a particular type and width of belt has a
maximum loading capacity for a given type of residual. The solid loading is considered the
most critical factor, and throughput is expressed in terms of solids loading, kg/meter of belt
width per hour. For coagulant sludge, the typical loading rate is about 150 kg/m・h, but
sludge thickened to 4 percent may be loaded at a rate of 400 to 570 kg/m・h (Cornwell,
2006).
Lime sludge up to 30 percent solids has been dewatered to 60 percent solids (MWH, 2005).
Typical belt widths are 1.0, 1.5, 2.0, and 3.0 m. Discharge from the press may be directly to a
truck. Other options include conveyors and hoppers or roll-off boxes.
The belt press has a relatively low energy requirement compared to other mechanical
dewatering devices. To achieve acceptable solids concentrations, the sludge fed to the BFP
must be conditioned. Polymers are often used for conditioning. In addition, belt wash water
must be provided. This wash water represents another disposal issue as it will be high in
suspended solids.
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Operation
The process of a belt filter press involves three basic operational stages.
1. Chemical conditioning
2. Gravity draining of excess water
3. Compaction of pre-dewatered sludge
A continuous belt filter press applied to coagulation sludge result in cake solids from 15 – 20
percent. Typically 1-2 min is required for drainage of excess water. Polymer dosage ranges
from 0.5 to 1 percent of the solids. Filter yield is 0.8 – 4.0 kg/m2.h and filter belt speed is 0.2-
0.5 rpm. The solid capture efficiency is 90-99 percent.
The diaphragm filter press yields higher cake solids and has a shorter cycle time than the
standard plate and frame press. Although the filter press may be highly automated, the
operation will require significant operator attention. Current models are provided with ―cake
breakers‖ to dislodge the cake from the press. These may need operator attention to ensure
that the cake is completely dislodged.
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5.14.10.1. Operation
In a fixed volume filter press, the sludge is pumped under high pressure (350- 1575 kN/m2) in
to the chamber. The water passes through the cloth, while solids are retained and form the
cake on the surface of the cloth. The sludge filling continues until the press is effectively full
of cake. The entire filling operation takes up to 0-30 mins. The pressure at this point is
generally at the design maximum and is maintained at for several hours. During this time,
more filtrate is removed and desired solid level in the cake is reached. Filter press can achieve
40% solid. The filter is then mechanically opened and the dewatered cake drops from the
chamber on to the conveyor. Typical cycle time is 8 hours. Sludge conditioned with polymers
increases the yield.
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Figure 5-117: Centrifuging
Therefore the process is usually attractive only in large sludge dewatering facilities with
incoming flow > 0.3m3/s (25,920m3/day). As such correct assessment of sludge generation
and selection of the capacity of each unit is very important.
After mechanical dewatering, the sludge is generally directed through a conveyer into a skip
or a hopper. The filtrate from mechanical dewatering facility can be directed back to the
sludge regulation tank. Most mechanical dewatering equipment can achieve 15-20% DS
content but the actual performance needs to be verified from manufacturers.
In this context, reuse of thickener supernatant is not recommended as about 95% of the
contaminants in raw water are removed from the sedimentation process and hence may
contain pathogenic organisms such as Cryptosporidium and Giardia Lamblia, which is
resistant to chlorination. The presence of these organisms in major rivers in Sri Lanka has
not been investigated yet.
It is advantageous to reuse the backwash water in order to conserve energy by minimizing the
utilization of low lift pumps and to recover 2-5% of water. Backwash water recovery has
many advantages. However, the introduction of backwash water recovery needs careful
evaluation of the raw water quality, the proposed treatment process and the cost-benefits.
Therefore the recommended unit processes for backwash water recovery to be incorporated in
the sludge treatment stream are as follows;
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Backwashed water is first directed to backwash recovery tank (minimum two tanks each
having capacity at least to hold two backwashes) where it is allowed to settle for a selected
time. After allowing for sedimentation, supernatant is gravity fed to backwash recirculation
tank which is constructed with common wall to the backwash recovery tank to minimize
construction cost. The gravity feeding system should comprise of pontoon attachment at the
surface of the inlet pipe (which needs to be covered with suitable mesh to prevent escaping of
floating debris) and the bottom end supported by a hinged bend in order to facilitate rotation
of the pontoon attached inlet pipe as water level drops up to the sludge thickening zone of the
backwash recovery tank. Moving inlet pipe with pontoon with hinged bend (Kalatuwawa
WTP: 1954)
Backwash recirculation tank should be equipped with two wet well submersible pumps, one
duty one standby, to pump the supernatant from backwash recovery tank to the raw water
regulation tank. The submersible pumps should be equipped with float switches suitable for
automatic operation and will be provided with guide rails and lifting chains to facilitate
maintenance. The pumping rate should be decided by giving due consideration to the
hydraulic capacity of the treatment units.
After supernatant (clear water) in the backwash water recovery tank is completely
transferred to backwash recirculation tank, the sludge from the backwash recovery tank is
then pumped to sludge regulation tank using submersible wet well pumps similar to the
operation of backwash recirculation pumps.
Sludge emanating from the sedimentation tank can be directly sent to sludge regulation
tank. The mixer equipped inside the sludge regulation tank will agitate and mix the sludge
from sedimentation and backwash recovery tanks to achieve homogeneous concentration
and to keep the sludge under suspension.
Two wet well submersible pumps, one duty one standby, to be provided to lift sludge from
the sludge regulation tank to the gravity thickener.
From the gravity thickener, the sludge is directed to ultimate disposal, which could be
either sludge drying beds, sludge lagoons or mechanical dewatering facility preferably by
utilizing progressive cavity pumps, one duty one standby operation.
Burial in a landfill
Reuse of all or a portion of the wastes
Discharge to a sanitary sewer system
Discharge to a natural waterway or lagoons
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Each of these disposal methods involves different regulatory requirements and may require
varying levels of pretreatment before disposal.
The addition of alum sludge to soils could also change the soils, physical structure, or bulk
density. A soil with a high-bulk density is more compact, which is unfavourable to plant
growth because root penetration is restricted. A low-bulk density (less compacted soil) has
more pore space for air and water, which is beneficial for plant growth. It is found that soil
mixed with alum residuals increased soil aggregation and moisture retention and, as a result,
increased the dry yield of maize. It is demonstrated that improvements in aeration and
moisture retention, promoted by the addition of alum residuals, were made to offset the
phosphorus deficiency in lettuce.
Because water plant solids are usually not hazardous, the last category is not used. Codisposal
into a municipal or industrial waste landfill is a matter of contacting the available landfills in
the area and determining these requirements and their tipping fee. Generally landfills will
require that the sludge be tested to prove it is nonhazardous and it must be of a high enough
solids concentration that there is no free water. Due to the costs of codisposal landfills, some
utilities are building monofills. Monofills are disposal sites specifically constructed to hold
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water plant residuals. The two major types of sludge monofills are trench filling and area
filling.
In trench landfills, sludge is placed entirely below the original ground surface.The trench
depth is dependent typically on the depth to groundwater and bedrock to maintain sufficient
soil buffers between the sludge and substrata. Trench depth is a function of sidewall stability
and equipment limitations as well.
Unlike the trench landfilling technique, in which sludge is placed below ground, in the area
filling technique sludge is generally placed above the original surface. Area filling may be
accomplished in one of three ways,
1. Area mound, where sludge is mixed with soil such that it becomes stable enough to be
stacked in mounds
2. Area layer, in which sludge is spread evenly in layers over a large tract of land
3. Diked containment, where earthen dikes are constructed above ground to form a
containment structure into which the sludge can be disposed
The requirement that sludge must be capable of supporting equipment due to the lack of
sidewall containment necessitates reasonably good sludge stability and bearing capacity.
These characteristics are typically achieved through good dewatering, dewatering followed by
air drying, freeze-thaw dewatering, or mixing sludge with bulking agents. A combination of
these methods can also be employed. Areas with high water tables and those with bedrock
close to the surface are particularly amenable to area fill methods of sludge monofilling.
The options available for disposal of sludge can be Land Disposal for Forest or Land
Reclamation, Incineration or Melting, Brick and roof tile construction (after mixing with other
constituents to obtain the desired consistency.
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5.14.13.4. Disposal of Supernatant or Concentrate water In to Surface Water
Disposal of water treatment sludge in surface water has the advantage of relatively low capital
and operational cost, however, it can be discharged to water bodies only if the water
complying to the effluent standards. The outfall must be properly located and designed to
minimize potential water pollution problem.
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Figure 5-118: Process flow diagram for sludge management in water treatment plant
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CHAPTER 6
Most of the water treatment plants use a variety of chemical engineering processes to produce
large quantities of safe drinking water within a short period. Therefore, the design of the
chemical feed system, including handling, storing, feeding, and mixing, requires special
attention. A properly designed chemical feed system can improve treatment efficiency and
thereby reduce operation and maintenance costs. Three basic forms of chemicals are used in
water treatment: dry, liquid, and gas. It therefore follows that the basic types of chemical
feeders are dry, liquid, and gas feeders. Liquid volumetric feeders are preferred because of
their compact size, accuracy, and convenience in handling. Generally, chemical feeders must
have a feeding capacity that is broad enough to accommodate the variations in plant flow rate
and chemical dosages.
Algaecides
Algaecides are chemicals that kill algae (blue or green algae), when they are added to water.
Examples are copper sulphate, iron salts, rosin amine salts and benzalkonium chloride.
Algaecides are effective against algae, but are not usable for algal blooms for environmental
reasons. The problem with most algaecides is that they kill all algae present, but they do not
remove the toxins released by the algae.
Coagulants
The following chemicals are used as primary coagulants, or in some cases, coagulant aids.
These coagulants cause the suspended matter in water to clump together due to either a
physical texture of the chemical, or through the electrical charges of the coagulant and the
colloidal particles. There are many factors in choosing a coagulant, such as its effectiveness
on pH and alkalinity of raw water, the cost of the coagulant and any supporting chemicals it
may require, and the method of delivery.
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Dry Aluminium sulphate (alum) is commonly used as a coagulant and it should be stored in a
dry location, and should be handled with care (i.e. rubber gloves and protective clothing) due
to corrosive properties.
Polyaluminum chloride (PACL), is a blend of chemicals that can achieve the same (or better)
coagulant results as alum. It is manufactured to eliminate some of the pH and alkalinity
adjustments that are necessary when using traditional coagulants. The cost of the PACL blend
is lower than the combined cost of alum, soda ash (Na2CO3), and lime. Similar to alum, PACl
should be stored in dry place and handle with care.
There can be several charges on one flocculent. There are cationic polymers, based on
nitrogen, anionic polymers, based on carboxylate ions and polyampholytes, which carry both
positive and negative charges.
Oxidants
Chemical oxidation processes use (chemical) oxidants to reduce COD/BOD levels, and to
remove both organic and oxidisable inorganic components such as iron, manganese or
arsenic. The processes can completely oxidise organic materials to carbon dioxide and water,
although it is often not necessary to operate the processes to this level of treatment. Oxidized
contaminants form precipitates, which can be removed by sedimentation or filtration.
A wide variety of oxidation chemicals is available. Examples are Hydrogen peroxide; Ozone;
Combined ozone & peroxide, Oxygen, Potassium permanganate, bleaching powder and
Chlorine.
Chlorine (as an oxidant), most commonly known for its disinfecting abilities, is also used as
an oxidizing agent. Chlorine can oxidize and precipitate out iron, manganese and hydrogen
sulphide. Using chlorine as an oxidizer helps avoid ―dirty water‖ complaints and problems
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with taste and odour. The forms of chlorine most commonly used by small water treatment
plants are chlorine gas, sodium hypochlorite or calcium hypochlorite.
Neutralizing agents (alkalinity control)
In order to neutralize acids and bases we use either sodium hydroxide solution (NaOH),
calcium carbonate, or lime suspension [Ca(OH)2] to increase pH levels. We use diluted
sulphuric acid (H2SO4) or diluted hydrochloric acid (HCl) to decline pH levels. The dose of
neutralizing agents depends upon the pH of the water in a reaction basin. Neutralization
reactions cause a rise in temperature.
pH conditioners
Drinking water is often pH-adjusted, in order to prevent corrosion from pipes and to prevent
dissolution of lead into water supplies. During water treatment, pH adjustments may also be
required. The pH is brought up or down through addition of bases or acids. An example of
lowering the pH is the addition of hydrogen chloride, in case of basic water. An example of
bringing up the pH is the addition of Lime [Ca(OH)2 or CaO], in case of an acidic water.
Lime, or calcium hydroxide, is used as both pre-dose and post-dose depending on water
quality available.
The pH will be converted to approximately 7 to7.5, after addition of certain concentrations of
acids or basics. The concentration of the substance and the kind of substance that is added,
depend upon the necessary decrease or increase of the pH.
6.1.2. Chemical Preparation for coagulation
Alum, usually in lump form, is the most common coagulant. The dosage is in the range of 20-
100mg/L. Lime is added when pH and alkalinity are low. The required dosages are
determined through jar tests. The density of alum and lime are 980 kg/m3 and 670 kg/m3
respectively.
It is essential to know the strength of the chemical solution in order to set the dosage to be
applied. All chemical preparation tanks therefore should be carefully measured and volumes
calculated. A water flow meter reading in the water feeding line can be used to prepare the
required strength of solution. In addition, a measuring stick or level sensor can be used to
measure the volume at any depth.
For the preparation of coagulant solution, for example, the exact amount of dry alum cake or
ferric chloride and the exact amount of water should be known. In most plants a 10% solution
in the day tanks will be satisfactory. Day tanks are those, which supply the originally mixed
chemical and water. A 10% solution requires 100g of chemical and 900 g of water (10% of
the total is chemical). The strength then is 100,000 mg of chemical in each litre of solution,
which is a relatively strong solution and very stable. The material is weighed at the desired
rate into a solution basin where it is dissolved by the stirring action of propeller type mixer.
The alum solution is slightly acidic.
It is important that the dilution water used for chemical preparation have the lowest possible
pH. If lime is being added, this water should be taken from the filter outlet before the addition
of lime. Water from the clear water tank after addition of lime has a higher pH.
Ferric chloride is a highly acidic compound and must be shipped, stored and dosed using
corrosion resistant equipment. It is convenient to have each tank supply enough chemical for
24 hours. This makes the operation simpler and a basin of chemical is prepared each day.
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6.1.3. Chemical Dosing
Once the chemical solution has been prepared, it is necessary to pipe it to the point of
application, such as a weir or a Parshall flume as described in chapter 5.5.
The stock solution from the day tank should be as nearer as possible to the diffuser. The
strength of the solution being applied to the raw water should be about 1% or as low as 0.5%.
To reduce the 10% solution to 1% requires 100mL of the stock solution and 900mL of water
to make up one litre.
The dosage may be based on the amount of the 10% strength stock solution. If the raw water
flow is 10m3/min and the required dose is 10mg/L (or 10ppm) it is necessary to apply 10g of
chemical to the water each minute. In a 10% strength solution, this means one litre of stock
solution per minute. The total solution dosed, however, is much more. If for example, 100mL
of stock coagulant is diluted with 900mL of water just before application then the amount
applied is 10 L/min at a strength of 1%, which is satisfactory for good coagulation.
The system at each plant should be to mix stock solution of 2 to 10% strength and dilute to
1% or less at the diffuser. This will give good coagulation and economize on coagulant. A
frequent problem is that of getting a known amount of stock solution into the raw water. Most
existing plants have some kind of dosing pumps, which are not usually working properly. It is
strongly recommended that if possible the chemicals be applied by gravity through a constant
head basin, controlled by a float valve. The system should be reasonably accurate and it
should be easy to set constant dosing rate only in small WYP <10,000 m3/day.
Such dosing systems exist on the market, but it would be preferable for NWSDB to fabricate
its own with valves and small basins purchased specifically for the purpose. The chemical
transport from the day basins to the point of application should provide a constant dosing
flow, preferably by gravity feed system. The strength of solution used for manual feed and
mechanical feed is given in Table 5-11 in CHAPTER 5.
• The inside walls of the batch tank shall be smooth, so that no accumulation of chemical
precipitate occurs on the internal tank walls, ribs or bends;
• The tank shall include an overflow pipe fitted at the high-high (HH) alarm level and
installed such that excess liquids drain away from traffic areas and to the bund sump;
• A water fill lines into the batching tank shall be provided with a flow meter. They shall
enter directly into the top of the batch tank.
• The dilution water solenoid shall be made of materials compatible with magnesium
hydroxide dosing, and set to open on low-level alarm from the level sensor. It shall be set
to close on level sensor high alarm;
• A transfer pump shall be provided to transfer concentrated chemical from the preparation
tank to the batching tank if such arrangement is preferred (especially for lime batching). It
will be PLC controlled, started on low alarm from the level sensor and stop on a timer.
The pump shall be identical to the dosing pumps used in the unit, and set at a constant
speed.
• A level sensor shall be provided to control the batching process. A high-level alarm (H)
shall stop the dilution water by closing the dilution water solenoid. A low-level alarm (L)
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shall be used to alarm the batching process. A low-low level alarm (LL) shall inhibit
dosing pump.
• A batching tank mixer shall be provided. The batching tank mixer shall comply with the
requirements of the chemical.
A typical liquid feed system consists of a storage tank and/or a day tank, pump, meter, and
distribution system as shown in Figure 6-1.
FM Perforated basket
Water
Alum
Calibrating cylinder
Agitator
Piston and Diaphragm Pumps are used for alum dosing. The capacity of these pumps depends
on the stroking speed and the length of the stroke. In the piston pump, the piston is in direct
contact with the chemical, in contrast diaphragm pumps, as the name implies, use the
movement of a diaphragm to move the fluid.
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6.1.6. Preparation and Dosing of Lime Suspensions
Lime used in water treatment, is normally in the form of Slaked or Hydrated Lime [Ca(OH)2],
and quicklime (CaO), which must be slaked before application. Calcium hydroxide is only
slightly soluble in water, to the extent of 1.85 g/L at 0C, decreasing to 1.65 g/L at 20C.
Lime solutions are referred to as ―Milk of Lime‖, but lime is normally dosed as a suspension
in supersaturated lime water. The suspension of lime tends to clog pumps and pipelines and
constant attention is necessary to maintain correct dosage.
Quick lime is used in water treatment and mainly as a powder. It has the following advantages
over slaked lime:
less expensive;
greater CaO content than slaked lime, higher apparent density, resulting in lower
transport and storage costs (quick lime: apparent density: 0.7 to 1.2, slaked lime:
apparent density: 0.3 to 0.6).
However, quick lime does have two drawbacks:
additional investment in order to guarantee a proper level of slaking;
quick lime quality is often far more variable than that of slaked lime.
The following reaction applies to the slaking of quick lime:
Cao + H2O Ca(OH)2
This is an exothermic reaction and the heat released at 25°C will be 275 kcal per kg CaO. The
chemical reactivity of lime slurry along with the fineness of the suspension will depend on the
slaking temperature. This temperature must be as high as possible and, therefore, involve a
minimum amount of added water.
Paste slaking (with high mixing energy): three to four parts water are mixed with one part
lime producing maximum temperature increase and short slaking time. The amount of water
used will depend on the paste‘s viscosity (mixer torque) and/or temperature;
Suspension slaking: the target lime slurry Ca(OH)2 concentration ranges from 50 to 200 g /L
; the temperature probe is used as a safety measure on the lime inlet. This type of installation
(Figure 6-2), although less efficient, can be automated more easily and more simply, thus
reducing operating, safety and maintenance requirements.
6.1.6.4.Dispensing
Lime powder: The quantity of powdered lime delivered to dilution tanks is metered out either
using volumetric feeders (rotary vane or screw feeders) or gravimetric feeders (weighing
hoppers).
Lime slurry : Lime slurry is prepared at a virtually constant concentration in dilution tanks
with mechanical agitation from water of moderate calcium carbonate alkalinity (scale
forming).
The slurry is delivered by pumps:
positive displacement pumps (dispensing or eccentric rotor pumps);
centrifuges, preferably dispensing a distribution loop equipped with automatic
injection valves operated in "on/off" mode. In this case, feed is often regulated by the
opening frequency of these valves, e.g. based on the information supplied by a pH
meter.
Screw Type
feeder
water vapour
extractor-fan
Flow
Assister
Injector
To feeder and
Injection point
Process Water
using pipes made of flexible materials (rubber) or that can easily be dismantled;
pipe diameters providing a compromise between:
o an adequate passage section (blockages);
o an appropriate circulation velocity (deposits);
using clean water to flush through after each shutdown.
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6.1.6.6. Stabiltiy at Saturation pH
To a given amount of calcium and magnesium bicarbonate corresponds a concentration of
free carbon dioxide which is the amount of carbon dioxide required to prevent break down of
the bicarbonates and precipitation of the corresponding carbonates. This amount is known as
―Saturation carbon dioxide‖
If the water contains an amount of carbon dioxide higher than Saturation value, the excess
amount is known as the ―agressive carbon dioxide‖. The amount of half bound CO2 (HCO3 of
the bicarbonates) is equal to the amount of bound CO2. The water containing agressive CO2
solution the carbonate in the form of bicarbonates; therefore, a fortion, they are incabable of
causing the formartion of a precipitation of protective cabonate film on the surface in contact
with them.
In contrast, the water which contain less free CO2, then the theoritical amount of saturation
CO2
Precipatate CaCO3 which are scale forming. The pH depend on the ratio:
Consequently, a so called ―Saturation pH” corospondant to each vslue of the alkanity. When
the pH of water is below the saturation pH, this water is considered as aggressive.
Aggressiveness is assed by measuring the pH and alkanity after a cetain contact time with
marble (kown as ―Marble test‖). Neutralisation can be performed by several methods and in
particular for the plant injection of saturated lime water to obtain the saturtion pH as given by
the marbl test.
6.1.6.7.Lime Water
Lime water (lime saturated solution) is often used in drinking water plants. Its titer, depending
on dissolution temperature, will be approximately 220°F of TAC at 20°C, This is equivalent
to a 220 × 7.4 mg / L concentration of Ca(OH)2, i.e. 1.6 g / L.
6.1.6.8.Turbine Saturator
For the same surface area, this appliance can be used to produce a higher output of lime water
than the static saturator, i.e. 3.2 to 4 kg of Ca(OH)2 per hour and per square metre of area. The
lime slurry is prepared continuously or intermittently but distribution must be continuous. It is
gravity injected or pumped into the sludge recycling nozzle or into the dissolution water
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delivery pipe. The Schematic diagram and photo of Lime turbine saturator in Ambathale WTP
is shown in Figure 6-3 and Figure 6-4 respectively.
This comprises:
a cylidroconical saruration tank,
a draft tube for recirculation of the lime and sludge,
an adjustable speed tubine located at the upper end of the draft tube,
A baffle placed around the draft tube in which the lime water saturation process is
completed,
A lime slurry inlet in the upper third of the draft tube
Inlet of water to be saturated half way down the draft tube, with a setting flowmeter
A concentrator for the sludge from the slurry
Automatic sludge drawoff
A main drain valve
Saturated limewater surface collection channel
A contiounos or dicontionous lime slurry preperation unit
Water
Lime slurry
Propeller
inlet
Overflow Operated mixer
Saturated
water
outlet
Sludge Extraction
Drainage
Pressurised Water
inlet
Figure 6-3: Schematic diagram of Lime turbine saturator
6.1.6.9.Operation
Lime slurry is injected into the recirculation draft tube and the warer to be saturated in the
upper third of the draft tube. The water, lime slurry and carbonate sludge drawn up the draft
tube are thoroughly mixed by the propeller-operated mixer placed in the top section of the
nozzle. The saturated lime water and carbonate sludge are seperated by settling at the base of
the circular baffle around the draft tube.
The saturator operates with a lime sludge blanket, level of which is adjusted by the weirs of
the concentrator into which this sludge is discharged. This sludge is normally extracted
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through the concentrator which receive the sludge formed. The sludge is discharged by
automatic draw off controlled by an adjustable timer. The flow rate of the lime water is
adjusted according to the readout from the water to be saturated flow meter.
It should be noted that adding very small amounts of ferric chloride increases the CaO content
of lime water even more.
The general layout of a complete lime water and slurry preparation unit (mixing tank and
saturator) often found in small to medium size drinking water installations (lime in sacks and
debagger or big-bag). Piston and Diaphragm Pumps can be used for lime dosing in case where
boosting arrangements are required. The injection can also be through venturi eductor where
a stream of water passing through a venturi in the eductor creates a vacuum that draws the
liquid chemical into the eductor. Because the eductor is incapable of flow rate control, the
chemical must be metered in some fashion. This system has found success in moving lime
slurry from a slacker to a mixing system.
Based on a research study it conclude that PACls is found to be the most effective coagulants
for both high turbidity waters (high turbidity, low TOC river) and low turbidity waters (low
turbidity, high TOC, colour reservoir and low turbidity, low TOC, high alkalinity reservoir).
Even for the high turbidity, low TOC River, which had widely ranging raw water turbidity,
PACls were the most effective.
For proper sedimentation, precipitation of a dense, rapidly settling floc is required. PACls
with added sulphate were found to form the best settling floc for all waters treated by
sedimentation. This effect was seen with both medium- and high-basicity PACls. The settling
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performance of alum was poor for cold-water temperatures. For some waters, however, high-
basicity PACls were found to be effective at lower doses and/or over a broader dosage range
than alum or the other PACls. Clarification performance in DAF was relatively insensitive to
coagulant selection.
The operating costs associated with coagulation include chemical costs, sludge disposal costs
and the cost savings associated with improved plant performance. Chemical costs include the
cost of the coagulant itself, any flocculent-aid or filter-aid polymers, and acid or base used for
pH adjustment. In practice, PACl dosing is usually expressed on a product basis. Because they
are available at various strengths, often stronger than alum, their cost must be assessed and
compared to alum and to other PACls on an Al basis. Generally, polyaluminium coagulants
are more costly than alum on an equivalent Al basis. On the other hand, PACls are pre-
neutralized and are less acidic than alum. For low alkalinity waters, lower amounts of base
would be used to control coagulation pH, thus reducing costs. This may also be true for
moderate alkalinity waters requiring moderate to high coagulant doses.
6.1.7.2. Disadvantages
1. The cost of Poly Aluminium Chloride is twice/thrice of Alum.
2. One possible disadvantage in using Poly Aluminium Chloride (PAC) relates to the
removal of dissolved organic carbon (DOC) from water. It is well documented that
effective DOC removal is possible with alum, particularly when coagulating at lower
pH values using so-called ―enhanced coagulation‖
3. Highly corrosive as a powder and need dust extractor to prevent damage to other
equipment.
The selection of coagulant chemicals and flocculation aids for use in a particular plant is
generally based on economic considerations along with reliability, safety, and chemical
storage considerations. The best method of determining treatability, the most effective
coagulants, and the required dosages is to conduct bench-scale tests and, in some cases, pilot
tests. Jar tests can be used to determine treatability and estimate chemical dosages. If possible,
testing should cover all critical seasonal conditions.
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6.1.7.3. Key points to be considered in chemical feeding
• Once it is determined what chemical is needed for treatment, it must be determined how
much chemical must be applied.
• A calibration cylinder is used to determine the pumps feed rate.
• The amount of chemical applied to a treatment system over a given period is called the
feed rate.
• The most common types of positive displacement pumps are peristaltic and diaphragm.
• In order to calculate feed rate, unit conversions may be necessary. Unit conversion is the
process of standardizing values in a calculation.
• Whether the chemical is a solid, liquid, or gas a feed rate can be determined.
• The output of a chemical feed pump is controlled by the length of the plunger stroke and
the number of repetitions of the stroke (speed and stroke).
• An ejector system uses the Venturi effect to create a vacuum and move solution into the
main water flow.
• A volumetric dry feeder uses a rotating feed screw to deliver a consistent volume of dry
chemical into a dissolving tank; varying the speed of the rotating feed screw changes the
feed rate.
• A gravimetric dry feeder uses a belt to deliver a certain weight of material with each
revolution of a conveyor belt.
• A pump calibration curve shows chemical Feed Rates vs. Pump Settings.
• It is important to consult with your engineer, manager, or chemical vendor to determine
the active strength of the chemical. This information may also be on the MSDS.
• Suction assembly consist of a suction strainer (used to protect the internal parts of a pump)
and a foot valve (used to prevent the pump from losing prime).
Regular cleaning with high pressure, adequate pipeline size to avoid blocking and minimum
number of bends, provision of cleaning points and ―y‖ strainers for cleaning purposes are to
be in place for smooth operations.
It is convenient to have each tank supply enough chemical for 24 hours. This makes the
operation simpler and a tank of chemical is prepared each day. A typical dry feed system with
dissolving tank is shown in Figure 6-5
Gravimetric Feeders are of two types: loss-in-weight and belt-type. The loss-in-weight type
uses a feed hopper suspended from scale levers; a material feed control mechanism, and a
scale beam with a motorized counterpoise. The rate of weight loss of the hopper equals the
weight loss equivalent of a travelling counterpoise when the feeder is in balance. If it does
not, the scale beam deflects and the feed mechanism adjusts the feed rate.
A feed hopper and control gate regulate the flow and depth of material on the belt-type feeder.
A scale counterpoise is adjusted to establish the desired belt loading. The gate releasing
material and the speed of the belt are adjusted to produce the desired flow of material. The
loss-in-weight type feeder capacity is limited to about 400–500 kg/h. The belt-type feeders
have capacities of 225 Mg/h and up.
The volumetric feeders provide good overall performance at low feed rates and acceptable
accuracy for materials with stable density and uniformity. They do not perform well when the
density of the material is not stable or is hygroscopic. They must be calibrated frequently.
In either case, standby feed capacity must be provided in case of breakdown and there should
be at least one-month chemical storage capacity adjacent to the feeders. Problems have been
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 6-13
reported with lime and alum dosing equipment in treatment plants in Sri Lanka from which
the following conclusions may be drawn.
• Proportional feed dosing pumps have been commonly used, but are unreliable and gravity
feed system via pipes of steady gradient should be utilized whenever possible. Actually
metering dosing pumps are more reliable for alum and ejector system is best for lime
dosing.
• Solution tanks are sometimes some distance from the point of chemical dosing, requiring
long feeding pipes, as well as blocking of lines more frequently (specially for lime).So
solution preparation, dosing and flocculation should be as close as possible.
• The amount and concentration of the solution must be known for optimum coagulation
and economy of coagulant use.
Many characteristics influence the adsorptive trends of activated carbon and not all carbons
have the same affinity to taste and odour compounds. Activated carbon is derived from a
variety of sources such as coal, wood and coconut. The base raw material and the method of
activation are two of the influencing factors on the surface chemistry and consequently the
character of the PAC. To evaluate the adsorption capacity of PAC a number of parameters
should be examined such as pore structure – macropores, micropores and mesopores, surface
area, bulk density, particle size, raw material, and activation process.
The detail description of taste and odour removal by activated carbon is given in chapter 7.3
and the dosing arrangement is depicted in Figure 6-6.
PAC is normally added early in the treatment process and is subsequently removed either by
sedimentation or by the filter beds during backwashing. The PAC application point should
allow for (1) an adequate contact time between the PAC and organics, and (2) avoid coating
PAC particles with other water treatment plant chemicals. A minimum contact time of about
15 minutes is required for most taste and odour compounds; however, significantly longer
contact times may be required for MIB and geosmin removal. The PAC should not be coated
with coagulants or other water treatment chemicals before the PAC has had sufficient contact
time with the source water. In addition, PAC should not be added concurrently with chlorine
or potassium permanganate as these chemicals will adsorb to the PAC. PAC is usually added
at the head of the plant to provide the longest contact time possible before applying other
treatment chemicals. Higher PAC dosages may be necessary if PAC is added later in the
treatment process to account for reduced contact times and interference with other treatment
chemicals.
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Figure 6-6: Dry feed system for PAC (Source: Konduwatuwana)
Dosages of 1 to 20 mg/L are typical for nominal taste and odour control. Application of PAC
generates additional sludge which cannot be regenerated as is spent GAC. PAC sludge will
contain elevated concentrations of the contaminants removed and must be disposed in
accordance with state laws; however, it is not likely to be classified as a hazardous waste.
6.1.10.1. Powdered Activated Carbon Application Equipment
A key advantage of PAC is that it can easily be added to an existing treatment facility. New
PAC storage, dosing, and mixing facilities are needed, but existing sedimentation basins and
filters can remove PAC from water. PAC is available in 20 -25 kg bags and 400-500 kg
jumbo bags.
PAC can be fed as a powder using dry feed equipment or as a slurry by mixing with water. A
dry feed system should be considered if the PAC is fed infrequently and the maximum feed
rate is less than a few hundred kilogram per hour. Dry feed systems typically include a bag-
loading hopper, an extension hopper, a dust collector, a dissolving tank, and an eductor.
Slurry systems usually include a storage tank, day tank, and a chemical feeder (either a
diaphragm pumps or rotary feeders).
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6.1.10.3. Slurry PAC system
A slurry PAC system usually includes a PAC slurry storage tank and either a hydraulic
diaphragm pump or a hose pump, rotary volumetric feeder. The carbon and water mixture in
the slurry tank must be kept continuously stirred to keep the carbon in suspension.
Activated carbon whether wet or dry, removes oxygen from the air. As a result, slurry tanks or
enclosed spaces containing carbon may have seriously reduced oxygen levels. Personnel
entering the space must follow oxygen deficiency regulation.
Table 6-1: Lime – Jumbo bags + Dry lime feeder versus Manual addition to batching
tanks + Dosing pumps
Jumbo bag unloader + Dry lime screw Manual addition of lime bags to batching
Parameters
feeder tanks + Dosing pumps
Concept Lime from a jumbo bag is fed from a hopper Bags of lime are manually added to a known
through a dry screw feeder continuously into volume of water in slurry tanks, which
a mixed slurry tank. Slurry is sucked through operate in duty/standby batch mode. Slurry is
an ejector from the slurry tank by dedicated pumped to dosing point. Pump rate, by stroke
motive service water and dosed to filtered setting or VSD, is used to adjust lime dose.
water. Water level in the slurry tank is
maintained at a constant level. Screw feeder
speed is used to adjust lime dose.
Dosing High. Screw feeder provides constant and Moderate. Depends on batching accuracy
accuracy accurate flow of lime. and pump and line scaling/blockage.
Manual Low. Some required at the time of bag High. Time consuming. Individual bags must
labour changing. Bag changing is assisted by be transferred and cut. Time allowed for
electric hoist adequate mixing. High labour input and
potential effects of lime dust must be
managed.
Footprint Small. Continuous feed system with small Large. Batch system. Large slurry tank x 2
slurry tank. No standby system required (just with full standby required.
critical parts)
Lime transfer Ejector. Low concentration lime <2.5%. Pump. Lime concentration dependent on
Venturi effect of water flow with no moving batch concentration. Low concentration
parts exposed to lime. No lime pump increases batch tank size (or frequency of
required, only motive water (no pump batching). Pump and line blockage common.
breakage or wear).
Flushing Required. Automatic valves assisted Required. After each time switching batch
flushing when plant is stopped. Flushing tanks and at plant stop. Flushing water comes
water comes from dedicated service water from plant service water. System requires
system. frequent flushing, occasional chemical (acid)
flushing, and replacement of (often long)
lime lines.
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Jumbo bag unloader + Dry lime screw Manual addition of lime bags to batching
Parameters
feeder tanks + Dosing pumps
Location Can be located close to lime dosing location, Usually located in a separate chemical
eg. within filter building due to small building. Pumping with long lime lines is a
footprint. Short lime dosing lines is an common result. Pump and line blockages and
advantage by minimising operational issues. scaling are common operational problems
with long lime lines/high
concentrations/pumping. Line flushing and
replacement requirements are higher.
Mixing 1 x smaller mixer in smaller slurry tank. 2 x larger mixers in 2 x larger slurry tanks to
Continuous. keep lime particles suspended and dissolve
lime. Continuous mixing for active batch.
Offline tank may suffer from lime
compaction and build-up of lime in tank if
offline mixer is switched off.
Height Floor to ceiling height of ~6m to 8m Level difference required for lime batching
requirements required for jumbo bag unloader and in large slurry tanks. Usually achieved with 2
monorail. storey or split level building. Floor to ceiling
height typically 4 to 8m.
Feed system Jumbo bag is suspended above jumbo bag Individual bags 25 kg or 50 kg loaded.
unloader, sitting on top of lime hopper. Bag splitter is common. Operator adds
known quantity (number of bags) of lime to
pre-measured/known volume of water. Open
to operator error and inconsistent lime
concentration.
Dose Screw feeder mechanical speed variation. Pump setting (Stroke setting, VSD, other)
adjustment
Dust Well controlled with covered screw and Slurry tanks should be covered to prevent
slurry tank, and dust extractor. Lime dust is dust. Closed bag splitters assist in keeping
generally only an issue when loading or dust low. Dust extractor attached to lime
(more commonly) removing empty jumbo slurry tanks is required. Lime loading by
bag. manually dropping/pouring lime into tanks
should be discouraged.
Effect of poor If lime quality is poor, quality changes If lime quality is poor, quality changes
lime quality significantly between batches, or lime in significantly between batches, or lime in
jumbo bags is affected by moisture, lime jumbo bags is affected by moisture, lime
dose rate by screw is affected. dose rate by pump is affected. Batch
Screw feeder may be damaged by solid concentration accuracy is affected.
foreign objects introduced by poor quality Similarly affected by changing lime quality
lime. and impurities.
Pumps may be damaged by solid foreign
objects introduced by poor quality lime.
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6.2. Disinfection
Pathogens (disease causing organisms) are present in both groundwater and surface water
supplies. This organism under certain conditions, are capable of surviving in water supply for
weeks near 21C and for months in colder temperature. Destruction of these organisms is
essential in providing safe and palatable water supply. Some Bacteria, viruses, Protozoa, and
large organisms in water cause disease from mild to life threatening illness.
The goal of disinfection is to destroy or inhibit the activity of microbes (Bacteria, viruses
Protozoa, and Fungus) in water, using two primary treatments, including (1) physical methods
- boiling of water, ultraviolet light and filtration, and (2) chemical methods – by adding
chlorine, chlorine solution, ozone, potassium permanganate, iodine, some metals (copper,
silver), alkalinity and acidity.
The eradication of water borne pathogens to protect the public health is the most important
step in treatment of water. Hence, the disinfection is required for all public water supplies
with a chlorine residual within the distribution system. The efficiency of disinfection depends
on several factors, as follows:
Temperature, affects the rate of disinfection reactions and the pH of the disinfectant solution
affects the reaction kinetics. Other factors that influence microbial sensitivity to disinfection
include attachment to surfaces, encapsulation, aggregation and low-nutrient growth. Increased
resistance to disinfection may result from attachment or association of microorganisms to
various particulate surfaces, including:
Pathogen kill efficiency is not the only consideration in selecting a disinfectant. The
characteristics of a good disinfectant are:
1. Effective kill of pathogenic microorganism
2. Non-toxic to humans or domestic animals
3. Non-toxic to fish or aquatic species
4. Easy and safe to store, transport, and dispense
5. Low cost
6. Easy and reliable analysis of disinfectant in water
7. Provides residual protection in drinking water
Boiling is one of the oldest and most simple methods of disinfecting water. Boiling water for
15 to 20 minute eradicates pathogenic microorganism but it is too energy intensive to be used
for disinfection. However, when water treatment works fail to produce water of suitable
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microbiological quality, orders are immediately to be issued to the public to use boil water,
―boil water Notices‘.
The water temperature is increased to the boiling point by directly heating it, using either
conventional (gas, fuel) or unconventional (solar energy) energy sources. With the use of
solar energy, the water is kept in transparent glass or food-grade plastic containers so that
sunlight will pass through it and eventually heat the water to a level that will destroy microbes
contained in it.
The various microorganisms in the raw water are affected to differing degrees, dependent on
the specific disinfection process. Chlorine is one of the most commonly used disinfecting
materials, due primarily to its low cost and the simplicity of its use. The next most commonly
used disinfectants are ozone and ultraviolet light.
The most common chemical disinfectant for water treatment, and the one that has historically
made the greatest contribution to the prevention of waterborne disease worldwide, is chlorine.
However, the protozoan such as Giardia lamblia cysts and Oocsysts are more resistant to
chlorine. Regulatory implications for the use of chlorine relate primarily to by-products. The
most well-known of these are the trihalomethane (THM) compounds, although another group
of by-products of increasing concern in water supply are the Haloacetic Acids (HAAs).
Chlorine is used not only as a primary disinfectant in water treatment, but is also added to
provide a disinfectant residual to preserve the water in distribution, where the chlorine is in
contact with the water for much longer than during treatment. In the presence of organics in
water, this is a more significant factor in terms of organochlorine by-product formation, and is
a driver in the implementation of chloramination. In chloramination, chlorine is normally
added first as the primary disinfectant for treatment, followed by ammonia after the chlorine
contact tank to form monochloramine prior to distribution. Monochloramine is less effective
as a disinfectant than chlorine, but provides a much more stable residual in distribution, and
has the added benefit that it does not produce THMs or HAAs.
Chlorine dioxide is used as a primary disinfectant and in distribution worldwide, but there are
limitations to its use because of the inorganic by-products chlorite and to a lesser extent
chlorate. Where these chlorite by-products are elevated consequent to high ClO2 doses, an
additional chemical dosing process is required involving the addition of ferrous salts to reduce
levels to below the WHO guideline limit of 0.7mg/l. Excess chlorine in ClO2 will produce
THMs. If excess chlorine is controlled, the formation of chlorinated organic compounds is
reduced significantly.
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Ozone is a very effective disinfectant, and where it is used for other purposes, usually for
removal of organic micropollutants such as pesticides, it provides benefits in terms of
reducing the microbiological challenge to downstream disinfection. However, ozone also
forms by-products, particularly bromate. Ozone does not allow a residual and need low dose
of chlorine to maintain a residual.
In addition to chemical disinfectants, UV irradiation has been used for many years for
disinfection in water treatment. Its usage is increasing worldwide, partly to reduce the amount
of chlorine used and minimise the potential for by-product formation, but also because of
recent recognition that it provides effective inactivation of Cryptosporidium and other
pathogenic protozoa. Cryptosporidium is a protozoan organism, which causes the parasitic
infection, Cryptosporiosis. Symptom includes diarrhoea, abdominal cramps, fever, nausea,
and vomiting. The principal source of Cryptosporidium is believed to be livestock (cattle,
sheep, or pig) some wild animals, and waste water treatment plants.
Similar to ozonation, UV does not provide a residual for distribution and it will principally be
used in conjunction with a residual generating chemical disinfectant.
Many of these disinfectants are also employed as oxidation agents to improve the efficiency
of coagulation/filtration, reduce iron and manganese, remove taste and odour and control algal
growth. The possible cumulative effect of these oxidants on by-product formation in
combination with their use for disinfection purposes also needs to be understood and risk
assessed.
There is now international recognition within the water industry that this approach to
safeguarding the quality of water may not always be sufficient and that development and
adoption of risk management plans offer improved protection. In 2008, the EPA adopted the
WHO Drinking Water Safety Plan (DWSP) approach for ensuring drinking water is ―safe‖
and ―secure‖. A drinking water supply is deemed safe if it meets quality standards each time
the supply is tested. A drinking water supply is deemed secure if there is in place a
management system that has identified all potential risks and reduction measures to manage
these risks.
The benefits of the risk-based approach are as follows:
It puts greater emphasis on prevention through good management practice and so less
reliance is placed on end product testing of treated water where the opportunity for
corrective action is limited
It offers a systematic approach to managing the quality of drinking water at all stages
from source to tap
It provides transparency to increase trust and confidence in water supplies
The World Health Organisation (WHO) has promoted this risk-based approach through
guidance for Water Safety Plans accepted worldwide as providing an integrated framework
for operation and management of water supply systems. This involves an assessment of how
particular risks can be managed by addressing the whole process of water supply from source
to tap. Water treatment is a key barrier within the WSP approach to prevent the transmission
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of waterborne pathogens. The WSP approach requires that the range of pathogens likely to be
present is identified and that treatment processes known to be capable of eliminating these
organisms are applied. The assessment must take into account extreme events (e.g. heavy
rainfall causing run-off from grazing land) which can increase the microbial burden in the
source water.
The physical removal and chemical oxidation of organic and inorganic impurities in
water and the consequent reduction in pathogens
The control of residual organic or inorganic compounds in treated water as a means of
limiting regulated disinfection by-products in final drinking water to consumers
The chemical disinfection of drinking water following its physical and chemical
treatment as a means of primary disinfection to effect inactivation of residual
pathogens in the final drinking water e.g. the use of Contact Time (Ct) appropriate to
the verification of disinfection efficacy using chlorination, ozonation, chlorine dioxide
and other chemical disinfectants
The non-chemical disinfection of drinking water following treatment as a means of
primary disinfection in the final drinking water e.g. UV treatment for full spectrum
inactivation of pathogens, verifiable by water quality tests
The maintenance of a disinfectant residual within the distribution system for quality
assurance with the wholesomeness and cleanliness of drinking water to the consumer
tap e.g. using chlorination, chloramination and chlorine dioxide
Following physical treatment of water, primary disinfection describes the main disinfection
method employed to inactivate waterborne pathogenic microorganisms. Primary disinfection
is often supplemented by downstream secondary disinfection to maintain a residual level of
disinfectant within the distribution system in order to assure the drinking water quality at the
last consumer‘s tap. Assuming that the efficacy of primary disinfection has been verified,
secondary disinfectants are added as the final element of a treatment process or at a re-
chlorination booster station to protect against re-contamination and control the growth of
microorganisms in the storage reservoirs and distribution network. As the purpose of primary
and secondary disinfection differs, a particular disinfection technology may or may not be
appropriate to fulfil both disinfection roles.
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The preceding treatment processes
The overall cost of disinfection
The specific objectives of disinfection for all public water supply system are as follows:
Assure 99.9% (3 log) and 99.99% (4 log) inactivation of Giardia lamblia cyst and
enteric viruses respectively as specified in the Surface Water Treatment Rule (SWTR)
in USA. The SWTR is based on Chick-Watson disinfection model i.e. the Ct concept
Do not impart toxicity, taste and odour to the disinfected water
Minimise the formation of disinfection by products
Meet the maximum guideline value for the disinfection and the by-product that can
form
The disinfection contact time is based on the time that water with 10% of approximate tracer
concentration takes to appear at the sampling point at the peak hourly flow. The determination
of T10 is based on two methods: (1) dye-tracer to simulate actual flow conditions, (2)
theoretical method which involves the use of rule-of-thumb.
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6.2.5.2. Contact time in real systems
Such ideal flow is never observed in real systems. The residence time of individual sub-
volumes of water passing through a system is not equal. In the case of a disinfection contact
tank, a proportion of the water may short-circuit in the tank and thus have a residence time
less than ; another proportion of the water may re-circulate, or get caught in quiescent zones,
and have a residence time greater than .
The true situation with regard to flow in a system is characterised by the distribution of
residence times: generally known as the residence time distribution (RTD). A common
approach to dealing with the non-ideality of flow in disinfection systems is to consider tx,
defined as the time in which the fastest flowing x % of water passes through the tank.
Conversely, tx is the minimum residence time of the remaining (100-x) % of the water.
The relationship between tx and the HRT, is: tx = (tx/)* where (tx/) = correction factor. In
a perfect Plug Flow Reactor (PFR), residence time is uniform, and hence (tx/) = 1.0. The
further away from plug flow, the smaller the correction factor for a given value of x, and
hence the smaller tx will be relative to the HRT. The CT (i.e. Ctx) value will therefore be
lower for a given concentration of chlorine.
USEPA guidance for disinfection is based on x = 10 i.e. t10 value, which is associated with
90% of the water passing the contact volume having a greater residence time than this value.
The RTD, and therefore tx can be readily determined by means of tracer tests.
In the absence of tracer test data, an initial estimate of non-ideality can be made by
consideration of the clear water tank design, in particular provision of baffling. Values of t 10/
suggested by USEPA are shown in Table 6-2 below. The baffle is generally utilised to reduce
short circuiting reducing dead space areas, the effect of wind, temperature, density currents
and influent and effluent turbulence.
Table 6-2: Suggested values for t10/ in respect of different baffling arrangements
Condition t10/ Description Graphic
Unbaffled 0.1 None agitated basin, very low length to width ratio, high inlet
and outlet flow velocities.
Poor 0.3 Single or multiple unbaffled inlets and outlets, no intra-basin Figure 6-7
baffles.
Average 0.5 Baffled inlet or outlet with some intra-basin baffles. Figure 6-8
Superior 0.7 Perforated inlet baffle, serpentine or perforated intra-basin Figure 6-9
baffles, outlet weir or perforated launders.
Perfect 1.0 Very high length to width ratio (pipeline flow).
Source: USEPA, LT1ESWTR Disinfection Profiling and Benchmarking Technical Guidance Manual 2003
For a poorly baffled tank, the contact time used for calculation of CT using the t10 value
would be less than one-third of that derived from dividing the tank volume by flow rate.
Submerged pipe inlet with no break plate or other means of preventing jetting
Outlet weirs or launders that are not full width
Bell-mouth outlets in the main body of the contact tank
For newly build contact tanks, it is now common practice to test the proposed design with
Computational Fluid Dynamics (CFD) analysis, from which the RTD and tx can be predicted.
The incorporation of structures within a tank to promote even flow distribution carries a
capital cost.
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6.2.5.3. The Use Of Service Reservoirs For Chlorine Contact
The principal functions of service reservoirs include the provision of a buffer volume to
equalise water production facilities with peak system demands and a storage volume for fire-
fighting and emergency use. However, the design of the service reservoirs often gives little
consideration to the flow patterns formed within the tank, other than using top water inlets to
limit loss from the reservoirs in the event of pumping main leakage and placing inlet and
outlet at opposite sides of the reservoir.
Consequently, these storage reservoirs can be hydraulically very inefficient, with large areas
of tanks containing very slow moving or stagnant water making them unsuitable for use as
contact tanks. However, if there is a dedicated main to the service reservoir without any
consumer connections, this would provide effective contact time to be taken into account in
the CT calculations.
Computational Fluid Dynamics (CFD) analysis of such reservoirs particularly those with low
length to width ratios show that short-circuiting of the flow occurs with subsequent formation
of dead zones in the flow field, which can have a detrimental effect on the quality of the water
discharged to the distribution network. Increased length to width ratios and the inclusion of
baffle walls in the design of such reservoirs can increase their efficacy for chlorination
contact.
In addition, changes in operation, which affect the ratio of inflows, outflows and operating
levels, can significantly change the flow profile through the tank. The shape of the diurnal
curve of water demand can vary significantly between different supply areas because of
differences in water use. These differences should be taken into account in determining the
impact of such daily usage patterns on the effectiveness of service reservoirs for chlorine
contact.
∑
Where
= CT calculated (C in mg/L, and T= T10 in min)
= CT obtained from SWTR tables
WHO guidelines (2004) include recommendations for chlorine Ct values for different types of
microorganisms. Table 6-3 sets out Ct values for 99% inactivation of common waterborne
pathogens. The virus data are for Coxsackie A2 which have a high resistance to chlorine
compared with other viruses, and therefore would provide a conservative indicator for design
of chlorination systems.
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10 7 – 7.5 8
0.5 7 – 7.5 230
Giardia 10 7 – 7.5 100
25 7 – 7.5 41
Values for the inactivation of Giardia lamblia cysts and viruses for disinfection by free
chlorine, chlorine dioxide, Ozone, chloramines, and UV are provided in Table 6-4 to Table
6-6.
Table 6-4: CTTab Values for achieving inactivation Giardia lamblia cysts by free chlorine
residual
pH Temperature Free chlorine, 1 mg/L Free chlorine, 2 mg/L Free chlorine, 3 mg/L
C 0.5 log 1 log 2 log 0.5 log 1 log 2 log 0.5 log 1 log 2 log
5 18 35 70 19 39 77 21 42 84
pH 10 13 26 53 15 29 58 16 32 63
6 20 7 13 26 7 15 29 8 16 31
25 4 9 17 5 10 19 5 11 21
5 25 50 99 28 55 110 30 61 121
pH 7 10 19 37 75 21 41 83 23 46 91
20 9 19 27 10 21 41 11 23 45
25 6 12 25 7 14 27 8 15 31
5 36 72 144 41 81 162 45 89 179
pH 8 10 27 54 108 30 61 121 34 67 134
20 14 27 54 15 30 61 17 34 67
25 9 18 36 10 20 41 11 22 45
5 52 104 208 59 118 235 65 130 259
pH 9 10 39 78 156 44 88 177 49 97 195
20 20 39 78 22 44 88 24 49 97
25 13 26 52 15 29 59 16 32 65
Table 6-5: CTTab Values for achieving inactivation viruses by free chlorine residual
Temperature pH =6-9 pH =10
C 2-log 4-log 4-log 2-log 4-log 4-log
5 6 9 12 45 66 90
10 4 6 8 30 44 60
20 3 4 6 22 33 45
25 1 1 2 7 11 15
For the designing of a disinfection facility, SWTR require that disinfection credit for the
treatment process used in the process train should also be given. For example, a 2.5 log
removal of Giardia lamblia cysts can be achieved in well-operated conventional treatment
plant. Table 6-7 provide the required primary disinfection needed for the entire treatment
process to meet overall treatment requirement.
Table 6-6: CTTab Values for achieving inactivation Giardia lamblia cysts and viruses by
chlorine dioxide, Ozone, chloramines, and UV
Disinfectants Temperature Giardia lamblia cysts Viruses
C 0.5 log 1 log 2 log 0.5 log 1 log 2 log
5 4.3 8.7 17 5.6 17.1 33.4
chlorine 10 4.0 7.7 15 4.2 12.8 25.1
dioxide 20 2.5 5 10 2.3 6.4 8.4
25 2 3.7 7.3 1.4 4.3 8.4
5 0.32 0.63 1.3 0.6 0.9 1.2
Ozone 10 0.23 0.48 0.95 0.5 0.8 1.0
20 0.12 0.24 0.48 0.25 0.4 0.5
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25 0.00 0.16 0.32 0.15 0.25 0.3
5 365 735 1470 857 1423 1988
10 310 615 1230 643 1067 1491
Chloramines
20 185 370 735 321 534 746
25 125 250 500 214 356 497
UV 21 36
Table 6-7: Recommended disinfection credits for entire treatment process to meet
SWTR requirements
Expected log removal Recommended log removal by
Process Train Primary Disinfection
Giardia lamblia Viruses Giardia lamblia Viruses
Conventional filtration 2.5 2 0.5 2
Direct filtration 2 1 1 3
Slow sand filtration 2 2 1 2
Diatomaceous earth filtration 2 1 1 3
Treatment without filtration - - 3 4
The original WHO recommendations for the use of chlorine as a disinfectant stipulated a
minimum free chlorine concentration of 0.5 mg/l (C) after 30 minutes contact time (t) at a pH
of less than 8, provided that the turbidity is less than 1 NTU.
The product of these two values C x T is the commonly used term to describe the efficacy of
chemical disinfection systems that form residual concentrations in the water following
chemical dosing.
The levels of contamination with pathogens expected, and any specific pathogens of
concern for the site (catchment risk)
The extent and performance of treatment prior to final disinfection
The design of the contact tank, in relation to short-circuiting
Expected variations in temperature and pH
These generic recommendations are based on inactivation data that show that microorganisms
vary markedly in their susceptibility to disinfection. The ascending order of resistance is from
bacteria, viruses, bacterial spores to protozoa (e.g. Giardia, Cryptosporidium). Protozoa are
not readily inactivated by chlorination conditions generally used in water treatment,
particularly Cryptosporidium, and their removal must be achieved primarily by optimisation
of other treatment processes.
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6.2.7. Secondary Disinfection
The requirement to achieve adequate CT for inactivation of waterborne microorganisms in
drinking water is only important at the location of primary disinfection installations i.e.
locations following treatment where the necessary microbial inactivation of microorganisms
in water is affected.
High residual of primary disinfection residuals >1.0 mg/L at WTP will create a corrosive
environment and could be avoided. In general, a very high rate at WTP to ensure 0.2 mg/L in
extreme point of distribution system is not practical and should not be promoted.
Every free chlorine residual analyser must be installed for the purpose of monitoring a
primary disinfection process utilizing free chlorine residual, must be calibrated at a frequency
necessary to ensure appropriate operation of the analyser within a quality control band of
plus/minus 0.05 mg/L at a chlorine concentration up to and including 1.0 mg/L or plus/minus
5.0% at a chlorine concentration greater than 1.0 mg/L.
6.3. Chlorination
The primary objectives of the chlorination process are:
disinfection, taste and odour control in the system
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preventing the growth of algae and other microorganisms that might interfere with
coagulation and flocculation
keeping filter media free of slime growths and mud balls and preventing possible built
up of anaerobic bacteria in the filter media
destroying hydrogen sulphide and controlling sulphurous taste and odour in the
finished water
removing iron and manganese
bleaching of organic colour
It can also be used for flushing pipelines before it is brought into operation and after carrying
out repairs etc. All the water-retaining structures shall be disinfected before they are brought
into operation. Disinfection of structures and pipelines are described in construction
specification or in D2 Manual.
Chlorine is usually the most satisfactory disinfectant for water supplies, although in situations
where cheap electricity is available, ozone treatment may be competitive particularly if colour
removal is also required.
This free available chlorine can react with compounds such as ammonia, proteins, amino
acids and phenol, which may be present in the water, forming chloramines and chloro-
derivatives, which constitute the combined chlorine.
Chlorination in presence of humic acid and fulvic acid forms Trihalomethane (THM)
which is a health hazard.
The combined available chlorine has less disinfecting properties as compared to available
free chlorine.
To understand this fact, it is convenient to mention that chlorine aqueous solutions contain
two species in equilibrium, as it is represented in the above equations: hypochlorous acid
(HClO) and hypochlorite ion (ClO-).
Hypochlorous acid and hypochlorite ion are both strong oxidizing agents, but HOCl should be
the strongest from these two. The relative amount of the two species strongly depends on pH,
as it is shown in Figure 6-10. Hypochlorous acid is the predominant species between pH 1
and pH 7, the species are at equal concentrations at a pH of 7.5 and hypochlorite ion is
predominant at high pH values. Considering pH 8.5 as a reasonable approach to pH of a
concrete wall, the chlorine solution will have a mere superficial action, because the abundant
species is hypochlorite ion.
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Figure 6-10: pH and temperature dependency of HOCl ↔ OCl– equilibrium
The rate of reaction depends on temperature and pH as given in Figure 6-10. One practical
consequence of the reactions is that the chlorine vapour pressure over a solution depends on
solution pH, decreasing as pH increases (because of the increased formation of nonvolatile
hypochlorite acid). Therefore, the addition of an alkaline material such as lime or sodium
bicarbonate will reduce the volatility of chlorine from accidental spills or leaks and thus
minimize danger to exposed personnel.
Just after the chlorine has been added to the water to check that the chlorination
process is working.
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At the outlet of the consumer nearest to the chlorination point to check that,
residual chlorine levels are within acceptable levels.
At the furthest points in the network where residual chlorine levels are likely to be
at their lowest.
If chlorine levels are found to be below minimum levels, it might be necessary to add more
chlorine at an intermediate points in the network.
The higher the residual chlorine levels in the supply, the better and longer the chemical will
be able to protect the system from contamination. However, high levels of chlorine make the
water smell and give it a bad taste, which will discourage people from drinking it. For normal
domestic use, residual chlorine levels at the point where the consumer collects water should
be between 0.2 and 0.5 mg/l. The higher level will be close to the disinfection point and the
lower level at the far extremities of the supply network.
The following minimum free chlorine residuals are recommended at different locations in the
water system.
Clear Water / Chlorine contact basin - 0.5 to 0.8 mg/L
Stand posts/ consumer taps - 0.2 mg/L
Distribution dead – ends - 0.1 mg/L
Other uses of chlorine are shown in Table 6-8 and it includes oxidation of iron, manganese
and hydrogen sulphide, destruction of taste and odour causing compounds, and control of
algae and slime growth at treatment plants.
Table 6-8: Chlorine used for various treatment processes other than Disinfection
Chlorine Residual Amount of
Chlorine Contact pH Recommended Alkalinity
Treatment
Dosage Time Range Consumed as
Type (mg/L)
Ca2+
AMMONIA
REMOVAL 5 times NH3 1.22 per mg/L
> 20 min 8.5 Free 0.1
Monochloramine (as mg/L) Cl2
formation
Dichloramine 10 times NH3 1.22 per mg/L
formation (as mg/L) > 20 min 4.4-5.0 Free 0.1 Cl2
TASTE & ODOUR
10 times NH3
CONTROL > 20 min 1.22 per mg/L
(as mg/L) plus Free 1.0
Cl2
1 to 5mg/L
Phenol destruction 6 to 20 times 1.5 to 5 hours
phenol content (step wise) 7.0 Free Variable
HYDROGEN
SULPHIDE
REMOVAL 2.2 times H2S Instant Free or 0.1 2.6 per mg/L
5 – 9 (9
Oxidation to sulphur content combined H2S
optimum)
Oxidation to sulphate 8.3 times H2S Instant 6.5 - 9 (9 Free or 10 per mg/L
optimum) combined H2S
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MANGANESE 1.3 times Mn Up to 3 hr 7-10 (10 Free 0.5 3.4 per mg/m
REMOVAL content (variable) optimum) Mn oxidized
ALGAE CONTROL 1-10 mg/L Variable Free > 0.5
For design purposes, a chlorine dosage of 2 mg/L may be used for clear water (i.e. turbidity <
2 NTU) containing little organic and suspended matter, and with iron and manganese
concentrations of less than 0.3 mg/L. The total chlorine requirements, recognizing all the
above variables, should be determined by performing a chlorine demand test as a part of the
pre-design investigations. A minimum contact time of 20 minutes should be provided either in
the pump sump, reservoir and /or in the pipeline before reaching the nearest consumer.
The concept of break point chlorination is important for the operator to understand and
described in Figure 6-11. The breakpoint chlorination is disinfection when near-complete
oxidation of nitrogen compound is reached. Any residual beyond breakpoint is mostly free
chlorine. When chlorine is added the chlorine starts acting on organisms in water thus
reducing its volume in water. Once all the organisms are killed there will be residual amount
of chlorine left in the water even though there are no organisms in water. This residual
chlorine available in water after killing all bacteria in the well is called ―Free Residual
Chlorine‖. Break-point is the point where all bacteria are killed and sufficient chlorine is
utilized for this activity.
When chlorine is added it reacts first with the reducing compounds such as Fe2+, Mn2+,
NO2‐ and the chlorine will be reduced to the none effective Fe, Mn, NO, and chloride ion
Cl‐ (from zero to point A on figure)
When adding more chlorine it will react with NH3 to produce combined chlorine residual
(chloramines) and this increase to maximum level (from point A to B).
When adding more chlorine some chloramines are oxidized to nitrogen gas and the
chlorine is reduced to non-effective Cl- ion (from point B to C).
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Continued addition of chlorine will produce free available chlorine (at point C which is
called the ―Break point‖).
chloromine
Chlorine and chloro-
Demand organic Break Point
0.3
Formation of chloro-organic compound
compound and chloromine B
0.2 Free residual
Reactions with Ammonia: In the presence of certain dissolved constituents in water, each of
the disinfectants may react and transform to less biocidal chemical forms. In the case of
chlorine, these principally involve reactions with ammonia and amino nitrogen compounds. In
the presence of ammonium ion, free chlorine reacts in a stepwise manner to form
chloramines.
One possible reaction during breakpoint is: 2 NH3 + 3 HOCl = N2 + 3H+ + 3 Cl− + 3 H2O.
This reaction also may be used as a means to remove ammonia nitrogen from water. Finally,
after the ammonia nitrogen has been completely oxidized, the residual remaining consists
almost exclusively of free chlorine. The minimum in the chlorine residual–versus–dose curve
(in this case Cl2:NH4+ − N weight ratio of 7.6:1) is called the breakpoint and denotes the
amount of chlorine that must be added to a water before a stable free residual can be obtained.
Chlorine being a gas is unstable and as such it is mixed with lime to retain its strength for a
longer period, as far as possible. The bleaching powder is hygroscopic in nature. It loses its
chlorine strength rapidly due to storage and hence should not be stored for more than three
months. The method of chlorination by bleaching powder is known as hypo-chlorination.
The general reaction of ionisation of bleaching powder when mixed with water is as follows:
The calcium hydroxide settles as precipitate. The combined action of hypochlorous acid and
hypochlorite ion brings about the disinfection of water. Hypochlorite solution may be useful
for small installations since it avoids the use of toxic gas. It is available as:
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Although bleaching powder (chloride of lime) normally contains 35-60 available chlorine, for
design purposes the lower figure is recommended. It is always recommended to verify the
strength before using a particular batch of bleaching powder. Solutions up to 5% may be
prepared but a 1% solution is recommended to minimize problems caused by sediment and
clogging of the delivery system. A separate mixing basin should be provided with only the
supernatant transferred to the feed basin. Feeding equipment, generally of the constant head
gravity drip feed type, should be readily dismantleable for cleaning purposes. In general, it
can be considered that the practical limit for hypochlorisation is up to about 42 L/hr (1%
solution) of gravity or pumped supply. For greater flows, gas chlorination is appropriate.
Sufficient shelf space should be provided to store bleaching powder containers.
In Fe, Mn removal filters, the backwashing water shall be free from chlorine, in
such situation a separate storage shall be kept for backwashing for all new plants.
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Mixer
Solution tank
Washout
Ball Valve
Constant level
Diaphragm
Head
valve
Micro meter
To Chlorine dosing
point
Orifice
Figure 6-13: Typical Bleaching Powder Solution Dosing System
This arrangement shall be installed at nearest location of the feeding point to avoid clogging
of pipelines.
6.4.4. Safety Precaution
Chlorine is a hazardous substance. In solution, it is highly corrosive and splashes can cause
burns and damage the eyes.
• The operating personnel should use hand gloves, aprons and other protective apparel,
while handling and mixing.
• In the event of splashes and especially to the eyes it is important immediately to rinse
thoroughly with water. Therefore, safety eyewash, emergency shower should be provided.
• All containers in which chlorine is stored should be labelled, identifying the contents and
with a hazard warning in a form that is readily understood locally.
• Storage site for chlorine in any form should be secured against unauthorized access and
especially against access for children
• The valves, stirrer, basins, plumbing arrangements require renovation at every 6 months or
so.
The physiological effects of chlorine are summarized below:
Table 6-9: Physiological Effects of Chlorine
Concentration by Volume in Air mg /L Physiological Effect
3.5 Just detectable by odour
30 Produces coughing
40-60 Dangerous for 30 min exposure
1,000 Rapidly fatal
6.4.5. Pre-chlorination
The purposes are as follows:
to reduce taste and odour producing substances
to prevent algal growth in raw water
for oxidation of iron, manganese and hydrogen sulphide
to aid coagulation when high algal counts exists
To minimise post chlorination dosage, the total dosage (usually 2 to 5 mg/l depending on the
degree of pollution) is applied to leave 0.2 to 0.5 mg/l free residual chlorine in the final
delivered water. For further information, see Reference 5.
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6.4.6. Disinfection of Drinking Water Systems after Construction or Repairs
All parts of drinking water systems in contact with drinking water which are taken out of
service for inspection, repair or other activities that may lead to contamination before they are
put back in service, must be disinfected in accordance with the provisions of the AWWA
Standard for Disinfecting Water Mains (C651), AWWA Standard for Disinfection of Water
Storage Facilities (C652), AWWA Standard for Disinfection of Water Treatment Plants
(C653), and AWWA Standard for Disinfection of Wells (C654) or an equivalent procedure
that ensures the safety of drinking water that is delivered to consumers.
The standard ANSI/AWWA C651 describes the methods of disinfecting newly constructed
potable-water mains; mains that have been removed from service for planned repairs or for
maintenance that exposes them to contamination; mains that have undergone emergency
repairs because of physical failure; and mains that, under normal operation, continue to show
the presence of coliform organisms. The disinfecting agents discussed in this standard are
chlorine solutions that may be derived from liquid chlorine (Cl2), calcium hypochlorite
[Ca(OCl], or sodium hypochlorite (NaOCI).
Three methods of disinfecting newly constructed water mains are described in this standard:
the tablet method, the continuous-feed method, and the slug method. The engineer should
decide which of these methods is most suitable for a given situation. Factors to consider when
choosing a method should include the length and diameter of the main, type of joints present,
availability of materials, equipment required for disinfection, training of the personnel who
will perform the disinfection, and safety concerns.
The purpose of all three chlorination methods is to disinfect water lines, resulting in an
absence of coliforms as confirmed by laboratory analysis. As noted above, the three methods
attempt to provide flexibility in responding to specific situations. The tablet and continuous-
feed methods both have initial chlorine concentrations of 25 mg/L and a minimum contact
time of 24 hr. Because the tablet method cannot be flushed and cleaned prior to disinfection,
the required free chlorine residual must be detectable after 24 hr. Because the continuous-feed
method can be used to flush particles and prechlorinate with calcium hypochlorite granules, a
higher free chlorine residual of 10 mg/L is required after 24 hr. To meet the needs of
situations requiring reduced contact times, the slug feed method allows only a 3-hr contact
time, but requires a 100 mg/L initial chlorine dosage. While the contact time of each method
may not be identical, the end result, absence of coliforms, is the same for all three methods.
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Disinfection of water storage facilities is done in accordance with AWWA – C652 that refers
the use of these traditional solutions as a cleaning measure of water storage-facilities. First,
they flush the surfaces with abundant water (maximum pressure: 10 bars). Following this
preliminary cleaning, they pulverize all surfaces with scale removing agents in a generalized
way. These products remove iron and manganese incrustations which are present in water
distribution systems, removing seaweed and calcareous as well. After the cleaning operation
has been completed, disinfection proceeds.
Despite chlorine is a good disinfecting agent for water, the same is not true for reservoir
surfaces, once biofilm growth occurs, even when residual chlorine is present. This is because
of the surface wall pH. The amount of bleaching powder required for disinfection of mains
and storage basins based on a dose of 50 mg/L available is given in Table 6-10.
Table 6-10: Bleaching powder requirements for disinfection of mains and storage basins
Storage
Pipes Diameter (mm) in kg/1000m
Components Basins in
50 65 80 100 150 200 kg/10m3
Amount of Bleaching Powder
0.5 0.8 1.2 1.9 4.3 7.4 2.4
Required
Note: Amount of Bleaching Powder is based on a Dose of 50 mg/L available
The conventional chlorination facility i.e. adding chlorine for disinfection of water treatment
consists of six essential parts:
1. Chlorine supply
2. Storage and handling
3. Safety provision
4. Chlorine feed and application
Chlorine withdrawal (as gas or liquid chlorine)
Evaporator for liquid chlorine withdrawal only
Automatic changeover
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Vacuum regulator
Chlorinator
Injector system
5. Diffusion, mixing and contact
6. The control systems
The design consideration for each system is described below.
Selection of size of containers depends on the quantity of chlorine used, the vehicle access to
the water treatment plant, the turn over time of the cylinders with maximum of 3 months as
recommended by the gas supplier. The cylinders are most likely applied to small water supply
schemes. Care should be taken when transporting chlorine gas in vehicle and special
precautions and arrangements has to be provided in the transporting vehicle. Further, the
driver has to be trained on safety arrangements.
Special care should be taken to protect outsiders especially if the WTP is closer to the
residential area and when located in a higher elevation of the residential area. In such
situation, the scrubber system is essential.
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1. Breathing apparatus
2. Emergency repair kit
3. Leak detectors combined to siren system and where preferable to an automatic
scrubber system
4. Neutralisation basin
5. Display of boards in local language for the operator cautioning, first aid and list of
different authorities with phone numbers
6. Communication system
7. Tagging system for equipment
8. First aid including tablets and cough mixtures
9. Testing of pressure vessels, chlorine lines etc. every year as per factory ordinance
10. Frequent Training and mock drill
11. Safety showers and Eye fountain
12. Personal protective equipment with easy and safe access
13. Protecting hoods for ton-containers
14. Fire extinguishers
15. Wind cock
16. Two entrance door with both side swing
Sodium Hydroxide solutions are the most commonly used chemical for typical scrubbing
applications. However, the other chemicals listed above have been successfully used in many
applications where they may be readily available, less expensive or satisfy the specific
application.
The information in this document is primarily for sodium hydroxide solutions and their
reactions with chlorine. All chlorine-scrubbing applications are chemical processes requiring
detailed knowledge of the reactions, including heat generated, end-products, disposal of the
finished products, and safe handling of all the chemicals involved in the reaction. Chemicals
other than sodium hydroxide for chlorine scrubbing are outside the scope of this document
and have not been addressed.
On a weight basis, one kg of chlorine plus 1.13 kg of sodium hydroxide will produce 1.05 kg
of sodium hypochlorite.
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6.5.5. Gas Feed and Applications
Solubility of chlorine gas in water varies with temperature and given below:
Temperature 0C 0 20 33
Chlorine solubility (mg/L) 14,600 7,000 5,000
The simple arrangement of chlorine gas feeding system using 68 kg cylinder is shown in
Figure 6-14.
The significant disadvantages of liquid withdrawal from ton container include the following:
1. Evaporators are required
2. The risk of injury or off-site impact can be significantly higher by accidental release
between the container and evaporators
3. Highly corrosive possibility to consider the liquid chlorine
6.5.5.2. Evaporators
Evaporators are generally used when the chlorine withdrawal exceed 680 kg/day. Evaporators
capacity ranges from 180 to 4500 kg/day. the Evaporator receives the chlorine from container
and vaporises it to chlorine gas in a sealed pressurised chamber. The chamber is heated to
provide heat for vaporization. All evaporators should be equipped with a pressure reducing
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automatic shut-off valve on the discharge line from the evaporators to prevent liquid chlorine
entering the gas chlorine piping.
6.5.5.4. Chlorinator
The chlorinator receives chlorine from the container or evaporator and regulates the flow to
the injector. Different types of chlorinators are given in Table 6-11. A conventional
chlorinator consist of the following units: an inlet pressure reducing valve, a rotameter, a
metering control orifice and a vacuum –differential regulating valve. The driving force comes
from the vacuum created by the chlorine injector.
A chlorinator is a device for feeding chlorine to a water supply. It also serves as gas metering
device. Chlorinators are classified into two categories such as Pressure type and Vacuum type.
In Vacuum type of chlorinator, chlorine is handled below the atmospheric pressure. This will
minimize the risk and consequences of chlorine leaks. The vacuum system has several
advantages:
It consists of a gas filter, pressure regulating valve, variable area flow meter (Rotameter),
vacuum regulating valve, and pressure vacuum relief valve, drain valve and injector.
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6.5.5.6. Rotameter
The gas feeders may be by direct feed pressure injection of gas metered under a constant
positive pressure or by solution feed in which the gas is metered through an orifice or
rotameter under vacuum by an ejector drawing gas through the feeder into the solution line.
This is the most accurate way of metering chlorine gas since a constant density is maintained
under vacuum and it is not affected by ambient temperature changes.
• Operation under vacuum is safer than operating under pressure.
• A metering system can be easily designed to stop automatically if the vacuum should
fail.
In gas supply system if the header run passes through an area where ambient temperature may
fall below the temperature of the gas leaving the supply containers, it is necessary to install a
pressure reducing valve in the gas supply system. This valve prevents re-liquefaction of the
gas downstream of it. It is also a good practice to install liquid chemical trap upstream of the
valve. The trap will serve to prevent liquid chemical from entering and flashing across the
valve seat resulting in poor pressure regulation.
In vacuum feed system, a specified vacuum is created at the injector gas inlet. This voccum is
applied to suck chlorine gas from storage to the chlorinator and then through vacuum piping
system to the injector. A vacuum regulator, which is typically an integral part of the
chlorinator is utilised to control the chlorine gas withdrawal rate under the condition.
The amount of water supply must be enough to (1) to maintain chlorine concentration in the
solution below 3500 mg/L and (2) to create the required amount of vacuum in the line to the
chlorinator and in all the components of the chlorinator system. Manufacturers of chlorination
system provide injector-operating curves that specify the amount of water and pressure
required for a given amount of chlorine to be applied against a given backpressure.
Gas chlorinators have practical limitations as to minimum feed rates. Consistent with good
accuracy of metering and minimum maintenance, the minimum feed rate is about 0.25 kg/day.
However, chlorinator with rotameters can be obtained with as low capacity as 0.05 kg/day.
Normally for chlorinator up to 4.5 kg/day capacity, injectors require water at a minimum
pressure of 0.8-1.33 kg/cm2 above the pressure at the point of application with a minimum
flow rate of 9-22.5 L/m. Water from the pumping main or from a storage basin can usually be
used to operate injectors. Booster pumps for injector supply are required when chlorine
solution has to be injected into a pressure main.
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6.5.6. Diffusion, Mixing and Contact
Rapid mixing of chlorine into water, followed by a contact period, is essential for effective
disinfection. The chlorine solution is provided through a diffusor system as shown in Figure
6-15. It is then mixed rapidly either (1) mechanical means, (2) a baffle arrangements, or (3) a
hydraulic jump created downstream of a weir, Venturi flume, or Pharshall flume as shown in
Figure 6-15.
Single injector for small pipes Double injector for small pipes Multi injector for medium pipes
Single vertical diffusor for open channel Multiple hanging diffusor along the length of an
open channel
Figure 6-15: Typical Chlorine Diffusors
A velocity gradient of about 400 per second is sufficient to provide the desired mixing. Rapid
mixing of chlorine at the point of application is important. Chlorine should be added with a
large amount of dilution water through a full channel or pipe diameter diffuser submerged to
the maximum depth available.
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Pharshall flume Over and under baffles in a basin
Chlorine applied prior to a weir will only be driven off by the aeration effect of the hydraulic
jump. Chlorine added to the suction side of a pump or the upstream side of a value can cause
severe corrosion problems to brass unless applied a sufficient distance upstream to obtain full
dissolution.
At large facilities, complex automatic proportioning systems with recorders are used. Signals
from flow meter transmitter and chlorine residual analyser are transmitted to the chlorinator to
adjust the chlorine feed (Figure 6-17) and to maintain constant chlorine residual.
Several alarms are also considered an essential part of the control system. These include high
and low pressure in storage vessels, liquid or gas chlorine lines, high and low injector vacuum
lines, high and low temperatures for evaporator water bath, high and low chlorine residuals.
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In order to save space and for ease of maintenance, wall mounted chlorinators are
recommended. Two units should be installed to provide standby capacity, and to
maintain flow during changeover of cylinders or drums.
A weighing balance should be provided in the chlorinator room for checking the
quantity of gas used.
The chlorinator room should be separate with no interconnecting doors to any
adjacent room. The floor level should be at or below the other floors of the plant to
minimize the effects of gas leaks.
Air outlets from the room shall be near the floor and air inlets near the ceiling. Where
this is not possible, mechanical ventilation with a capacity of one complete air
change per minute should be installed. Fan and light switches should be located
outside the room. Doors should open to the exterior of the building. Careful attention
should be paid to location of windows and doors to keep cylinders out of the sun.
Chlorination room should contain only the connected cylinders. Separate cylinder
storage facilities should be provided. All cylinders, connected or stored, should be
protected from direct sunlight, rain or collected water and be properly restrained to
prevent tipping, falling, or any excessive movement, especially the connected
cylinders. A guide to cylinder requirements and storage is given in Table 6-12.
Chlorine gas and chlorine solutions are highly corrosive and should be conveyed in
plastic pipelines.
Gas masks must be provided adjacent to the chlorinator room door.
Table 6-12 shows possible chemicals, which could be used with the amount of water,
required to make neutralizing solution. A pool for the disposal of leaking cylinders should be
located adjacent to the chlorination room.
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Figure 6-17: Sophisticated Gas Chlorine Feed Systems
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Table 6-12: Chlorine Cylinder Inventory
Anticipated Volume of water No. of chlorine cylinders
Chlorine Use treated Daily (m3) 98 kg size 900 kg size
(kg/day) In Use Reserve In use Reserve
0.50 250 1 1 1 1
1.00 500 1 1 1 1
2.00 1000 1 1 1 1
4.00 2000 1(2*) 3(2*) 1 1
6.00 3000 1 (2*) 5(4*) 1 2
8.00 4000 1(3*) 7(5*) 1(2*) 3(2*)
10.00 5000 1(3*) 9(7*) 1(2*) 4(3*)
Note: Minimum Supply for 30 days for 2 mg/L and Dosage for 8 to 20 hours daily operation
(*) for 8 hrs /day operation
Table 6-13: Chemical and Water requirements for Chlorine Absorption in Alkaline
Solution
Cylinder Option-1 Option-2 Option-3
Capacity 100% Caustic Water (L) Soda Ash Water (L) Hydrated Water (L)
Soda (kg) (kg) Lime (kg)
67 kg 85 225 205 565 85 720
98 kg 125 375 300 930 125 1060
6.6. Chloramines
Chloramines have been used as a disinfectant in drinking water treatment since the beginning
of the 20th century. Chloramines are produced when chlorine is added to water containing
nitrogen compounds such as ammonia nitrogen. This reaction is detailed above in the
breakpoint chlorination example. There are three types of chloramines that are produced.
Desired form of chloramine is monochloramine because of its biocidal properties and minimal
taste and odour production. Dichloramine and trichloramines are less desirable because of the
chlorinous tastes and odours that they produce and Chloramines is not used in Sri Lanka yet.
The major benefits of monochloramines include their tendency to produce fewer disinfection
by – products such as THMs and HAAs, minimal chlorinous tastes and odours, persistence to
reach distant areas of the distribution system, and effectiveness as a secondary disinfectant in
penetrating biofilms in distribution system.
Chloramines are less effective as a biocide than free chlorine for inactivating pathogenic
microorganisms. For this reason, chloramines are generally not used as a primary disinfectant.
Chloramines are, however, an excellent secondary or final disinfectant because they form a
very stable and persistent residual.
6.6.1. Monochloramine
6.6.1.1. Mode of action
In dilute aqueous solutions (1–50 mg/l), chlorine reacts with ammonia in a series of
bimolecular reactions: HOCl + NH3 → NH2Cl (monochloramine) + H20
These competing reactions are dependent upon pH and the relative chlorine to nitrogen
concentration (expressed as Cl2: N) to a lesser degree they are also dependent upon
temperature and contact time. The reaction of HOCl and ammonia will convert all the free
chlorine to monochloramine at pH 7–8 when the Cl2: N ratio is equimolar (5: 1 by weight) or
less.
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6.6.2. Chloramination Equipment
The equipment required to produce chlorimines is essentially the same equipment required for
chlorination systems. Chlorine can be injected as a gas or a liquid. In addition, both chlorine
and ammonia are also available in liquid form or in granular form that can be dissolved in
water. Great care must also be taken to ensure that concentrated chlorine and ammonia are
never mixed together because they will form nitrogen trichloride, a potentially explosive
compound.
However, in practice, chlorine dioxide is rarely reduced completely to chloride ion. Chlorine
dioxide is thought to inactivate microorganisms through direct oxidation which interferes with
important structural regions of metabolic enzymes or membrane proteins. In water treatment,
chlorine dioxide has the advantage of being a strong disinfectant, but not forming THMs or
oxidizing bromide to bromate.
Table 6-14 below provides a summary of USEPA Ct credits for Cryptosporidium, Giardia
and viruses using ClO2-. These Ct values are also quoted in the latest WHO Guidelines.
Different viruses also have different sensitivity to ClO2 and the Ct values proposed by the US
EPA probably provide a margin of safety.
Generally, chlorine dioxide is more effective as a disinfectant than chlorine at higher pH but
similar or poorer at lower pH; chlorine dioxide performance is generally quoted as not being
pH sensitive in the range experienced in water treatment, whereas chlorine is much more
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effective at lower pH. There could be some pH sensitivity for chlorine dioxide, but this varied
between the viruses examined.
Table 6-15 provides a summary of USEPA Ct values for Cryptosporidium, Giardia and
viruses using ClO2, Cl2 and O3 at 10°C and pH 6-9.
Ozone (O3) is a colourless gas with a characteristic odour reminiscent of a lightning storm.
Ozone is established and proven disinfectant as well as a pre-oxidant for the control of THM
and HAAs precursor. It has the ability to oxidize proteins and enzymes, thereby being
effective against microbes, viruses, odours and some micro-pollutants. Although not as
efficient as chlorine for residual effect, it is nevertheless used to disinfect potable or treated
water. Because of the reactivity of ozone, residuals cannot be maintained for more than a few
minutes. As a result, ozone is considered to be primary disinfectant and requires the use of
chlorine or chloramines as a secondary disinfectant.
Ozone is used in water treatment for disinfection and oxidation. Early application of ozone in
the United States was primarily for non-disinfection purposes such as colour removal or taste
and odour control. However, since the implementation of the SWTR and proposal of the DBP
rule, ozone usage for primary disinfection has increased in the United States.
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Disinfection: Ozone is a powerful oxidant able to achieve disinfection with less contact time
and concentration than all weaker disinfectants, such as chlorine, chlorine dioxide, and
monochloramine. However, ozone can only be used as a primary disinfectant since it cannot
maintain a residual in the distribution system. Thus, ozone disinfection should be coupled
with a secondary disinfectant, such as chlorine, chloramine, or chlorine dioxide for a complete
disinfection system.
Ozonation also has the added benefits of
1. oxidation and volatilization of organics
2. control of algae and associated taste and odour producing compounds
3. destabilization (micro flocculation) of certain type of turbidity
4. Removal of colour causing compounds
5. Oxidation of Iron and manganese
Ozone reacts with inorganic compounds such as nitrates, ferrous, manganese, sulphide, and
ammonium ions. The oxidation of these inorganic substances by ozonation process is very
fast and complete. Ozone being a powerful and effective oxidant destroys many organic
compounds that produce colour, taste or odour in portable water. Therefore, it is widely used
in taste and odour control, colour removal, Iron and manganese removal.
The concentration and reaction times are substantially lower than those required for free
chlorine. Required CT values for inactivation of Giardia by ozone are on the order of 1/10 th of
those required for free chlorine.
A special apparatus (ozonizer) is used to generate the ozone. Because ozone production
decreases as the gas temperature increases, a cooling system is also usually provided to ensure
a low temperature.
Because of its extreme reactivity, ozone gas must be produced onsite. It is a product of the
action of electrical fields on oxygen. The oxygen can be derived from air or pure oxygen in
compressed gas cylinders. After the ozone is generated, it is piped to a contactor. Ozone is
then injected at the bottom of the contactor basin into a diffuser, and the fine bubbles rise
through the water as the water flows downward in to the basin. Ozone is transferred from the
gas phase in to the water though this process where it is free to react with the contaminants.
The air is fed to the ozonizer through an air compressor, in which the air is passed through a
dryer. The feed air pressure is related to the pressure at the point of contact with the water to
be disinfected, allowing pressure losses to be taken into account. The typical pressure is about
0.7 Bars, thereby requiring an air blower since the feed air range is between 5 and 10 Bar
(refer Figure 6-18).
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Atmosphere
Off-Gas Ozone Generator
Influent
Effluent
Ozone
Quench
(Option)
The UV dosages required to inactive viruses are substantially higher that those required to
inactive protozoa (Cryptosporidium and Giardia). UV leaves no residual and thus requires the
addition of chlorine or some other secondary disinfectant to maintain a residual in the system.
The effectiveness of a UV disinfection system depends on the characteristics of the water, the
intensity of UV radiation, the amount of time the microorganisms are exposed to the
radiation, and the reactor configuration. For any singletreatment plant, disinfection success is
directly related to the concentration of colloidal and particulate constituents in the water.
UV is a proven and safe alternative for primary disinfection as it is free of the harmful by-
products associated with chemical disinfection. UV also has the added benefit of not
compromising the taste, colour or odour of water.
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6.9.1. UV Disinfection Requirements
EPA developed UV dose requirements to receive credit for inactivation of Cryptosporidium,
Giardia, and viruses (Table 6-16). The UV dose values in Table 6-16 are applicable only to
post-filter applications of UV disinfection in filtered systems and to unfiltered systems.
Unlike chemical disinfectants, UV leaves no residual that can be monitored to determine
The UV dose depends on the UV intensity (measured by UV sensors), the flow rate, and the
UV transmittance (UVT). A relationship between the required UV dose and these parameters
must be established and then monitored at the water treatment plant to ensure sufficient
disinfection of microbial pathogens.
The UV dose requirements in Table 6-16 account for uncertainty in the UV dose-response
relationships of the target pathogens but do not address other significant sources of
uncertainty in full-scale UV disinfection applications. These other sources of uncertainty are
due to the hydraulic effects of the UV installation, the UV reactor equipment as shown in
Figure 6-19 (e.g., UV sensors), and the monitoring approach.
UV reactors must consistently deliver the dosage of UV radiation necessary to inactivate the
target pathogens. Factors that interfere in the delivery of the proper dosage include poor water
quality such as high turbidity, absorbance of the light by organics, low bulb light output
(Caused by slim build-up or bulb degradation), or an increase in the water flow rate past the
light source. To ensure proper treatment, commercial UV reactors are equipped with UV
sensors, temperature sensors, flow meters, and cleaning mechanisms for the bulbs.
Chamber UV Rays
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Water flows through the stainless steel chambers in which nine lamps are installed. Each lamp
is housed in a transparent, waterproof quartz sleeve. The sleeves are submerged in the
chambers. As the water flows through the chambers, the microorganisms are exposed to the
UV light rays. There is one sensor outside each sleeve to ensure that an adequate UV light
intensity is applied. The water needs only a few seconds of exposure to the light to inactivate
microorganisms.
As much as the perfect indicator organism does not exist, each of the commonly used
disinfectants has its advantages and disadvantages in terms of cost, efficacy, stability, ease of
application and formation of by-products. Disinfection by-products forms when the
Disinfectants are added to drinking water react with naturally occurring organic and inorganic
matter in water.
The concentration of chlorine dose can affect THM formation. Changes in the chlorine dose
are typically more significant at primary disinfection stage than at secondary stage, due to the
higher chlorine doses required at primary stage to achieve appropriate disinfection. THM
formation can be minimised by avoiding the use of pre-chlorination.
The use of booster chlorination, to maintain an adequate residual in the distribution system,
can also increase the formation process, as THMs can continue to form within the network
where organic matter has not been removed or organic sediments exist within the reservoirs
and pipelines. THM formation becomes disinfectant limited, within the network, when the
free chlorine residual typically drops to 0.3mg/l (Ryan Hanley, 2012).
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6.10.1.1. Reactivity of NOM
The organic matter in surface and ground waters is predominantly natural organic matter
(NOM). NOM is derived from living or decayed vegetation. It is present in particulate,
dissolved and colloidal forms. NOM fractions can also be described in terms of those, which
are water repelling (hydrophobic) or water absorbing (hydrophilic).
The water repelling or hydrophobic fractions are aromatic compounds and are composed of
primarily humic material. Humic material is formed by decaying vegetative matter, such as
lignin. Lignin is found in plants and is quite resistant to biodegradation yet it is reactive to
oxidants, such as chlorine. These characteristics of the aromatic hydrophobic humic material
tend to form higher THM levels.
The water absorbing or hydrophilic fraction of organic matter is composed of primarily fulvic
material, carbohydrates and sugars, and is a relatively poor THM precursor.
Rapid gravity filtration or slow sand filtration on their own is unable to fully remove the THM
precursor. Oxidation processes, such as ozonation, used upstream of disinfection, do not
remove organic matter but instead break it down to smaller, more bio-degradable compounds
which can lead to an increase in disinfection by-products, such as THMs if there is no
subsequent removal stage. These more reactive forms of organic carbon can be effectively
removed / reduced using granular activated carbon (GAC) or biological filtration. However,
early exhaustion of the GAC layer, in its adsorption phase, may occur where high TOC levels
exist in the water prior to the GAC layer. This may make the GAC layer uneconomical as
frequent replacement may be required.
Reactions between chlorine and DOC with a high hydrophobic (aromatic) content generally
result in higher levels of THMs. UV254 is generally linked to the hydrophobic (aromatic) and
reactive DOC components of NOM, and is considered a good indicator of the potential of
water to form THMs.
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While UV absorbance reflects the bulk concentration of precursors in water, the nature and
reactivity of the precursor is best assessed using a parameter called specific UV absorbance
(SUVA). SUVA correlates well with the aromaticity and the hydrophobicity of the organic
carbon and hence its potential to form THMs
( )
( )
SUVA values less that 2 generally indicate a high fraction of hydrophilic non-humic matter
with low UV absorbance, a low chlorine demand and low THM formation potential. SUVA
values between 2 and 4 are indicative of a mixture of hydrophobic humic and hydrophilic
non-humic matter, with medium UV absorbance a higher chlorine demand and higher THM
formation potential. SUVA values in excess of 4 are indicative of the presence of humic
highly aromatic hydrophobic matter associated with high UV absorbance, high chlorine
demand and a high THM formation potential.
6.10.1.5. Investigations into the cause of Disinfection By-product exceedance
The main causes of failures are most likely to be one of the following, (this list is not
exhaustive);
No treatment stage capable of removing organic matter (e.g. no filters, rapid gravity
filters with no coagulation or slow sand filters on a highly coloured water)
Coagulation or filtration stage bypassed
Filtration rate too high (i.e. overloaded filters)
Breakthrough of filters (due to poor media quality)
Poor filter management (e.g. filters not being run to waste)
An extreme weather event (such as flooding or an exceptional storm)
Accumulation of sediments in the network or reservoirs
Ingress into reservoirs or distribution network (more likely to be the former)
Long residence time in the distribution network
The cause should be investigated and identified by the operator and this information should be
used to determine appropriate measures to reduce the concentrations of disinfection by-
product. It is proposed that investigations should involve the following;
1. Develop a monitoring program for each stage of the process to evaluate critical
parameters in THM formation. A monitoring program will help identify areas of THM
formation and help in the implementation of effective corrective actions.
2. Evaluate operational practices of the treatment process and the distribution system.
3. Investigations should be conducted at each stage of the process and should be
examined as follows;
4. Stage 1 – Efficacy of treatment plant: Determine the TOC removal efficiency
upstream of disinfection process by analysing raw and treated water sampling results.
Determine the nature and reactivity of the THM precursor in the treated water by
determining the SUVA.
5. Stage 2 – Storage: Evaluate the potential for THM formation in the storage facilities
following disinfection. The Water Service Authority (WSA) should establish
operational limits for at TTHM and HAAs after storage, such as < 80 μg/L and <60
μg/L respectively. This should ensure that the parametric value for THM will not be
exceeded prior to distribution.
6. Stage 3 – Distribution System: Identify specific areas where THMs are formed by
carrying out monitoring at various locations within the distribution system. TTHM for
drinking water in the distribution system should not exceed 100 μg/and 80 μg/L for
HAA5.
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For THM investigative purposes only, the number of monitoring sites on a distribution
network should be based on the population size served by the water supply systems, (see
Table 6-17). This monitoring procedure does not apply to compliance monitoring.
The selection of these monitoring sites should take account of historical THM exceedance
data, high water age, and the disinfectant residual gradient and geographic coverage of
distribution system.
Monochloramine is about 2000 and 100,000 times less effective than free chlorine for the
inactivation of E. coli and rotaviruses, respectively. Monochloramine cannot therefore be
relied upon as primary disinfectant. It is useful for maintaining a residual disinfectant in
distribution systems. The shift to monochloramine to control THM formation may thus
compromise disinfection and the Guidelines caution against such procedure. Organic
chloramines are even less effective disinfectants than monochloramine.
Chlorine dioxide is more effective towards inactivation of Giardia cysts than free chlorine, but
less effective towards rotavirus and E. coli. Unlike chlorine, the disinfection efficiency of
chlorine dioxide is independent of pH and the presence of ammonia.
A provisional Guideline Value (GV) was recommended for chlorite while no adequate data
were available to recommend a GV for chlorate. No GV has been recommended for chlorine
dioxide per se because of its rapid breakdown in aqueous solutions and the chlorite GV is
adequately protective for potential toxicity from chlorine dioxide. Furthermore, the taste and
odour threshold for chlorine dioxide in water is 0.4 mg/litre which constitute a limiting factor
and a signal for its presence at higher concentrations in drinking water.
Ozone is the most efficient disinfectant for all types of microorganisms. Disadvantages
include lack of disinfectant residual, biological regrowth problems in distribution systems,
high cost, and limited information on the nature and toxicity of its by-products.
As water travels through the distribution system, chlorine continues to react with NOM to
form DBPs. The longer the travel time or water age, the more likely it is that water quality
will degrade, chlorine residual effectiveness will be reduced and TTHM and HAA
concentrations will be increased. Because of this, the supplier should endeavour to manage
water age within the distribution system.
Some methods to reduce water age within the distribution system include (USEPA, 2008);
Eliminating dead ends: Excessive hydraulic residence time at dead ends can provide for long
contact times for DPB formation.
Managing valves: Intentionally or unintentionally closed valves in a distribution system may
create areas of stagnant water. A comprehensive valve inventory and maintenance program
can help to determine the status of valves and find improperly positioned and broken valves.
Bypassing or replacing oversized pipes: In oversized pipes water velocity is lower and water
residence times are longer than is necessary. The supplier should evaluate if oversized pipes
exists within the distribution system and whether these can be replaced without influencing
downstream areas.
Improving tank mixture and turnover: Improving mixing within tanks can reduce the
average water age and minimise stagnant zones within a tank.
Eliminating excess storage: Oversized tanks may have inadequate turnover or poor mixing.
Supplier should examine the option of increasing hydraulic turnover, mixing or where
possible decommission oversized tanks.
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Figure 6-20: Risks and benefits of water chlorination (Morris, 1978)
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CHAPTER 7
In ground waters, iron and manganese are found particularly in wells that draw their waters
from underground formations comprised of shale, sandstone, and alluvial deposits. In the
reducing environment often found in a deep well supply, that is, one which is devoid of
oxygen and which possesses a low pH, the iron and manganese will exist in their divalent
soluble forms. The concentration of iron may range from less than 1 mg/L to over 40 mg/L,
although the majority of well waters will contain less than 5 mg/L of iron. Manganese
generally occurs at concentrations of less than 1 mg/L but has also been found in
concentrations as high as 5 mg/L. Occasionally one may encounter even higher concentrations
of manganese.
In a surface water supply iron and manganese may be present due to their dissolution from the
associated geologic formations and/or from the decomposition of organic materials. For
example, anaerobic conditions on a reservoir bottom may cause the dissolution of iron and
manganese from the bottom sediments. When seasonal overturns occur due to temperature
gradients, this dissolved iron and manganese will be distributed throughout the water supply.
Although increased levels of iron and manganese may occur during periods associated with
overturns, it is also very likely that these elements will be found at objectionable
concentrations throughout the year.
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• Household fixtures such as porcelain basins, bathtubs, glassware, and dishes are
stained
• Clothes may stain a yellow or brown-yellow colour
• Iron precipitates, clog pipes and promote the growth of gelatinous masses of iron
bacteria. These bacteria slough off and create ―red water‖ (Regrowth inside the
distribution pipelines system)
• Iron bacteria may cause odour and taste problems, particularly, when the flow in
pipes is low
The problems caused by the presence of manganese are similar to those of iron:
• High concentrations of manganese may produce taste problems
• Manganese may cause a discoloration of industrial products similar to that caused by
iron
• Household fixtures may be stained a brown or black colour (Regrowth inside the
distribution pipelines system)
• Clothes may be stained and become dingy or greyish
When exposed to air, they are oxidized to ferric iron Fe3+ and manganic manganese Mn4+,
which are:
• insoluble
• visible
Iron (Fe) and manganese (Mn) can be present in water in one of three basic forms:
1. Dissolved: ferrous (Fe2+) and manganous (Mn2+) states
2. Particulate: ferric (Fe3+) and manganic (Mn4+) states
3. Colloidal: very small particles (difficult to settle and filter)
Knowledge of the forms or states of iron and manganese can help to fine-tune a given
treatment practice for these metals. The predominance of one form over another is dependent
on:
• pH
• Eh (redox potential),
• alkalinity
• organic content
• presence of oxidizing agents and
• temperature of the water
The Oxidation of Iron and Manganese with Oxygen, Chlorine, Chlorine Dioxide, and
Potassium permanganate are shown in Table 7-1.
Table 7-1: Oxidation of Iron and Manganese with Oxygen, Chlorine, Chlorine Dioxide
and Potassium Permanganate
Reaction Oxidant, mg/mg Fe2+ Solids,* (kg/kg) Fe2+
4Fe +O2 + 10H2O 4Fe(OH)3 + 8H+
2+
0.14 1.9
4Fe2+ +Cl2 + 6H2O 2Fe(OH)3 + 2Cl- + 6H+ 0.64 1.9
4Fe2+ +ClO2 + 13H2O 5Fe(OH)3 + Cl- + 11H+ 0.24 1.9
4Fe2+ + KMnO4 + 7H2O 3Fe(OH)3 + MnO2 + 5H+ 0.94 2.4
+ K+
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Reaction Oxidant, mg/mg Fe2+ Solids,* (kg/kg) Fe2+
4Fe + O3 + 5H2O 2Fe(OH)3 + O2 + 4H+
2+
0.43 1.9
Mn2+ + O2 + 2H2O 2MnO2(s) + 4H+ 0.29 1.58
Mn2+ + Cl2 + 2H2O MnO2(s) + 2Cl- + 2H+ 1.29 1.58
Mn2+ + 2ClO2 + 2H2O MnO2(s) + 2ClO2- + 4H+ 2.46 1.58
Mn2+ + 2KMnO4 + 2H2O 5MnO2(s) + 4H+ +2K+ 1.92 2.64
Mn2+ + O3 + H2O MnO2(s) + O2 + 2H+ 0.87 1.58
7.1.4.1.Health Effects
Manganese effects occur mainly in the respiratory tract and in the brains. Symptoms of
manganese poisoning are hallucinations, forgetfulness and nerve damage. Manganese can also
cause Parkinson, lung embolism and bronchitis. When men are exposed to manganese for a
longer period they may become impotent. A syndrome that is caused by manganese has
symptoms such as schizophrenia, dullness, weak muscles, headaches and insomnia.
According to results from a 2010 study, higher levels of exposure to manganese in drinking
water are associated with increased intellectual impairment and reduced intelligence quotients
in school-age children.
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before filtration should be at least 20 minutes, more if possible. The pH of the water
influences how much time is needed for the reaction to be completed. For the complete
oxidation of soluble manganese (without the addition of a strong oxidant) the pH would have
to be increased to 9.5 or above. Iron, if not present as a complex, can usually be oxidized
completely by aeration in the 7.0-8.0 pH range. Oxygen is not a strong enough oxidizing
agent to break the strong complexes formed between iron and manganese with large organic
molecules.
However, the aeration process is most successful in removing iron and manganese when the
pH of the solution is above 8.5 and stacked-tray aerators as shown in Figure 5-18 with coke
beds are employed.
Aeration (air oxidation) is the simplest treatment in removing iron. The reaction that takes
place is in the form of:
Fe2+ (ferrous) + oxygen FeOx (ferric oxide)
Soluble iron Insoluble iron
The oxidation of manganese by oxygen is very slow and the aeration process is not practical
at the normal pH conditions in natural waters. Therefore, strong oxidants are needed for
manganese removal. If manganese is not effectively removed from the water, it can cause
problems with post-chlorination. When oxidized:
• it can clog the solution-feed chlorinator
• it cause a staining water
• there is a possibility of regrowth in the distribution system
7.1.5.3.Water Softening
Lime softening is also an effective way of removing iron and manganese. Again the reduced
forms are oxidized to insoluble precipitates, which are removed along with the lime softening
solids. The chemical reaction that describes this oxidation process is as follows.
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can be manganese greensand, which is a purple-black granular material processed form
glauconitic greens, and/or a synthetic formulated product. Both of these compositions are
sodium compounds treated with a manganous solution on exchange manganese for sodium
and then oxidized by KMnO4 to produce an active manganese dioxide. The greensand grains
in the filter become coated with the oxidation products. The oxidized from of greensand then
adsorbs soluble iron and manganese, which are subsequently oxidized with KMnO4. One
advantage is that the greensand will adsorb the excess KMnO4 and result any discoloration of
the water.
Regenerative – Batch process: The regenerative – batch process uses manganese treated
greensand as both the oxidant source and the filter medium. The manganese zeolite is made
from KMnO4 treated greensand zeolite. The chemical reaction can be expressed as follows
(Humphrey and Eikleberry, 1962; wilmarth, 1968):
Where NaZ is greensand zeolite and Z.MnO2 is manganese zeolite. As the water passes
through the mineral bed, the soluble iron and manganese are oxidized (degeneration).
Regeneration is required after the manganese zeolite is exhausted.
One of the serious problems with the regenerative – batch process is the possibility of soluble
manganese leakage. In addition, excess amounts of KMnO4 are wasted, and the process is not
economical for water high in metal content. Manganese zeolite has an exchange capacity of
0.18 kg of iron or manganese per cubic foot of material, and the flow rate to the exchanger is
usually 0.4 m3/min/m3 (3.0 gpm/ft3). Regeneration needs approximately 0.36 kg KMnO4 per
cubic foot of zeolite.
Continuous Process: For the continuous process, 1-4% KMnO4 solution is continuously fed
ahead of a filter containing anthracite bed (150-225 mm thick), manganese - treated greensand
(300-450mm), and gravel. The system takes full advantage of the higher oxidation potential of
the KMnO4 as compared to manganese dioxide. In addition, the greensand can act as a buffer.
The KMnO4 oxidize iron, manganese, and hydrogen sulphide to the insoluble state before the
water reaches the manganese zeolite bed.
Greensand grain has a smaller effective size than silica sand used in filters and can result in
comparatively higher head loss. Therefore, a layer of anthracite is placed above the greensand
to prolong filter runs by filtering out the precipitate. The upper layer of anthracite operates
basically as a filter medium. When iron and manganese deposits build up, the system is
backwashed like an ordinary sand filter. Then manganese zeolite not only serves as a filter
medium but also as a buffer to oxidize any residual soluble iron and manganese and to
remove any excess unreacted KMnO4. Thus a KMnO4 demand test should be performed. The
continuous system is recommended for groundwater where manganese predominates
(inversand Co., 1987).
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Manganese green sand Antracite
Figure 7-1: Filtration Media
The use of biological treatment, either in situ or ex situ, has gained popularity over the last
twenty years due to the presence of certain advantages over the conventional physicochemical
treatment methods (Bouwer and Crowe 1988). Biological treatment uses microorganisms to
reduce, oxidize or eliminate groundwater contaminants, either as the sole treatment technique,
or combined with other conventional physicochemical processes, such as sorption, filtration,
etc.
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Fe and Mn removal by biological processes are based on different stages of biofiltration
where beds are colonized by Fe–Mn oxidizing bacteria. In nature, Iron Oxidizing Bacteria
(IOB) and Manganese Oxidizing Bacteria (MnOB) are widespread. They are prevalent in
groundwater, swamps, and ponds in the hypolimnion of lakes, in sediments, soils, wells and
water-distribution systems. In the latter they can cause significant clogging problems
(Ghiorse, 1984). These bacteria which are present in raw water can multiply in sand filters
under appropriate conditions and are able to oxidize divalent ions Fe(II), Mn(II) and
precipitate them under their oxided forms Fe(III) and Mn(IV).
The main groups of IOB are (Czekalla et al., 1985; Mouchet, 1992):
stalked bacteria, e.g. Gallionella sp., which are chemolithotrophic and
microaerophilic,
sheathed bacteria, e.g. Leptothrix sp., Sphaerotilus, etc., which are facultative
autotrophic-heterotrophic,
unicelular bacteria, e.g. Siderocapsa, Siderocystis, etc., which are heterotrophic and
more difficult to recognize by microscopic observation than the previous ones.
With the exception of the stalked bacteria (Gallionella), which oxidizes only Fe, MnOB
include the major groups reported for the IOB. Some of the species of the genera Leptothrix,
Crenothrix, Hyphomicrobium, Siderocapsa, Siderocystis, and Metallogenium can even
oxidize Fe or Mn indifferently. Other bacteria oxidize only Mn, e.g. Pseudomonas
manganoxidans (Mouchet, 1992). The bacteria involved in biological Fe and Mn removal
need different pH and redox potential (Eh) conditions for each metal, as is shown in Figure
7-2, a Pourbaix diagram.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-7
Thus these microorganisms, formerly considered only as a source of problem (clogging wells,
causing corrosion, deteriorating water supply quality) have now been ―domesticated‖. Their
use in biological iron and manganese removal plants has revealed the many advantages of
biological processes over conventional processes for the upgrade of existing units or the
design of new projects.
In existing plants, physical – chemical units can be converted to biological treatment through
the implementation of one or more of the following measures: modification of pH; change in
aeration conditions; elimination of a powerful oxidant or more generally, any regents added at
the head of the treatment line; postponement of chlorination until the end of the treatment
line; change in the filter media and/or the nozzles. These simple modifications, when
performed under appropriate conditions, have always produced spectacular improvement in
treatment efficiency in terms of product water quality, operating costs (longer filter runs,
decreased labour requirement, savings on backwash water, partial or total reduction in the use
of costly reagents), or both. Operating costs can be cut by as much as 50 to 80 percent.
Once a biological iron or manganese removal plant is constructed, the system must be given
time to ‗seed‘ with bacteria naturally present in the water source. This seeded biomass is
naturally and continuously regenerated during the life of the plant and is periodically partially
removed through backwashing. For iron removal plants, the seeding period is quite short
requiring anywhere from a day to about one week. For manganese removal, plants the seeding
time can be considerably longer, anywhere from 3 weeks to 3 months. At the end of the
seeding period, the metal concentration in the effluent falls to near detection levels. The
seeding period is affected by the temperature of the water source, and is generally longer for
cold water sources.
Iron bacteria are generally robust, and because of the variety of species involved, one type or
another is able to thrive under most environmental conditions. Given the correct pH, between
6 – 8, and Eh, the bacteria are normally able to oxidize iron at temperatures ranging from 5oC
to 50oC. Inhibition of the biological process can however be caused by the presence of H 2S,
Chlorine, NH4+, and some heavy metals normally not present in water sources. Under certain
conditions of alkalinity and hardness, it can also be impossible to raise the Oxidation
Reduction Potential (ORP) sufficiently for biological manganese removal even with a
theoretically sufficient quantity of dissolved oxygen. It is therefore critical to have a complete
and accurate analysis of the influent water because a biological removal system will only be
effective if the proper water conditions are present (Gage B. et.al, 2001).
Example is given below.
Table 7-2: Optimum Parameters for Biological Removal
Optimum Parameters for Biological Removal
Parameter
Manganese Iron
Dissolved oxygen > 5 mg/L 0.2 – 0.5 mg/L
pH >7.0 >6
Redox potential 400 – 600mV 0 – 200 mV
Hydrogen sulphide < 0.01 < 0.01
Heavy metals, Ammonia, Chlorine Nil Nil
Iron
Manganese
Source: Sheppard M. et al: Biological Removal of manganese in Community water Supply
According to the attached paper on ‗Removal of Iron and Manganese Using Biological
Roughing up flow filtration Technology (Pacini et.al:2005)‖ the concept of biological
filtration has been improved more user friendly. As the paper describes the process is carried
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-8
out at natural pH and Eh without using special devices to control Dissolve Oxygen (DO).
Hence the biological filtration method described using vertical flow roughing filter will be
applicable in Sri Lanka successfully.
In concentrations above 3-5 mg/L, however, mottling of teeth occurs, and a reduction in the
level of fluorides is desirable.
High concentrations of fluoride are toxic and can cause fluorosis, mottled tooth and enamel,
kidney and thyroid injury, and death. So fluorides can be removed by various granular
insoluble media which remove fluoride as the water percolates through them and which are
periodically regenerated by chemical treatment. Suitable treatment processes are:
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-9
• Filtration through bone char
• Filtration through activated alumina
Filtration through activated alumina: Adsorption onto activated alumina can reduce fluoride
levels to below drinking water standards. Probably best for large scale removal, water
percolates through a bed of granular media of grain size 0.3-0.5 mm. Bed regeneration is
necessary with weak caustic soda, followed by neutralization. Further details of fluoride
removal methods are in Table 7-4.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-10
u
d
o
o
e
s
l
Table 7-4: Fluoride removal methods (based on Heidweiller, 1990; Pickard and Bari, 2004 and BGS, 2003; cited in Feenstra, et al., 2007)
sm
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Capacity/ dose
Community
efficiency (%)
Interferences
Operator skill
Relative costs
Household
Working pH
WHO-level
Techniques
Water Loss
Removal
feasible
level
Precipitation
Alum (aluminium X x >90% Yes 1-2% 150mg/mgF non-specific - low medium-high
sulphate)
Lime X x >90% Yes 1-2% 30mg/mgF non-specific - low medium-high
Alum + Lime (Nalgonda) X x 70-90% possible 1-2% 150mgalum+7mglime/mg non-specific - low medium-high
F optimum pH6.5
u
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Gypsum +fluorite X x ? no 1-2% 5mggypsum + < non-specific - medium low-medium
2mgfluorite/mgF
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efa v
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/%
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W t
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pn
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Calcium chloride X x >90% possible 1-2% 3mgCaCl2/mg F 6.5-8
H
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tc
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Adsorption/ion exchange
Activated carbon x x >90% yes 1-2% variable <3 many medium high
Plant carbon (carbon in x x >90% ? 1-2% 300mgF/kg 7- medium low-medium
plants)
zeolites x x? >90% yes 1-2% 100mgF/kg non-specific - medium high
defluoron 2 x x >90% 1-2% 360gF/m3 non-specific alkalinity medium medium
Clay pots x 60-70% possible 1-2% 80 mgF/kg non-specific - low low
Activated alumina x x 85-95% yes 1-2% 100mg alumina/mg F 5.5 alkalinity low medium
(1200gF/m 3)
bone x x Low? possible 1-2% 900gF/m3 >7 arsenic low low
Bone char x x possible 1-2% 1000gF/m3 >7 arsenic low low
Other
Electro dialysis x 85-95% yes 20-30% high non-specific turbidity medium very high
Reverse osmosis x 85-95 yes 40-60% high non-specific turbidity medium very high
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-11
7.3. Removal of Colours, Tastes and Odours
These characteristics are often the cause of a majority of consumer complaints about water
quality.
Colour in water is usually due to:
organic matter
biological growths and algae
colloidal iron / manganese
True colour is that imparted to water by soluble matter. It is measured against standard
solutions of a platinum salt in distilled water. Apparent colour is due to suspended matter such
as ferric hydroxide (red or yellow) or algae (green).
Conventional water treatment processes such as oxidation, coagulation, and filtration are
effective in removing colour. Adsorption and ion exchange can also be employed. In practice,
colour is usually removed to acceptable levels by normal water treatment operations. Each of
these colour removal processes is briefly discussed below.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-12
growths of algae etc.
treatment processes, e.g. chlorination, which may accentuate some tastes and odours,
particularly in the presence of phenols
Odour is measured by Threshold Odour Number (TON), which indicates the intensity of the
odour in water. It is the dilution, with odour-free water, required to dilute the odorous water to
the point where the odour is just detectable. Prevention of tastes and odours occurring is the
best solution and some strategies are given below:
Prevent pollution of source by sewage, industrial wastes, etc.
Control biological growths in reservoirs, tanks and filters e.g. algae, fungi
Careful chlorination, and use of ammonia or dechlorination agents if necessary
cover distribution reservoirs
Avoid dead-ends in distribution, flush mains regularly; use material linings and
protective paints of good quality
7.3.1. Aeration
Not particularly effective in removing tastes and odours due to organic matter, biological
growths or chlorination since substances causing such problems usually have low volatility.
Aeration is effective in reducing free carbon dioxide and hydrogen sulphide.
Powdered activated carbon is more effective and efficient for removing tastes and odours than
the granule form. It is mixed into slurry and fed at a constant rate to the water. Contact time
should be a minimum of 15 minutes to 1 hour. Removal is usually on the bed of rapid or slow
sand filters. In rapid filters, the carbon is washed to waste in the backwashing process; in slow
sand filters, the material accumulates on the bed, and should not affect the length of filter run.
Maximum efficiency is obtained when the carbon is applied to clarified water, normal doses
being in the range of 5-20 mg/L. Efficiency of removal of tastes and odours is much better at
lower pH values.
For slow sand filters, a larger initial dose of 40-50 mg/L could be applied to build up an
effective concentration throughout the water on the filter, and then reduced to a nominal
amount of say 2 mg/L.. Tastes and odours are normally a seasonal phenomenon, and therefore
the required dose is likely to be intermittent and variable.
The application point may be at the plant inlet, or after clarification, or both. Sufficient
contact time must be allowed prior to coagulation, when the efficiency of absorption will be
reduced due to sealing of the carbon surface, as it binds with the coagulant.
Granular activated carbon is usually used for removal of free chlorine, by passing water
through a bed of the substance, at a similar flow rate to that of rapid sand filtration - the
units are therefore of similar size. In this case the carbon requires periodic regeneration.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-13
Powered activated carbon requires special care in handling, storage and feeding due to its
highly corrosive nature in the presence of water; it is also combustible and should be stored
separately from other chemicals, and equipment for handling the dry material should be
sealed to confine the dust. See reference 6 for additional information on this subject.
It should be noted that when using chlorine for this purpose, there is a danger of forming new
taste and odour causing compounds, which may aggravate the problem. Sufficient oxidant
must be used, therefore, to eliminate the original taste and odour causing compounds. Ozone
is probably the most effective taste and odour oxidant available but suffers from high cost and
is therefore seldom used.
In certain cases treatment may be required for the removal of hardness. Since hardness is not a
health hazard, this form of treatment may only be necessary to reduce the operational issues
like scaling in the conveyance systems and for specialised industrial uses where scaling may
be a problem either by chemical precipitation or by ion exchange. Generally, ion exchange is
the more suitable method, being simpler in operation and maintenance.
Certain natural materials, such as zeolites (complex sodium alumina-slicates) and greensand
have the property of exchanging one ion in their structure for another ion in solution. Thus
natural zeolites will exchange their sodium ions with calcium and magnesium ions in water,
thus softening the water completely. The finished water is high in sodium but unless it was
originally very hard water, the sodium level is not harmful.
Softening
Na2R Ca (HCO3)2 CaR 2 NaHCO3
+ Mg SO4 MgR + Na2SO4
Fe (Cl)2 FeR 2 NaCl
Since ion exchange treatment produces effluent with zero hardness it is usually sufficient for
domestic supply purposes to treat a portion of the water only which can then be blend with
unsoften water to produce a final hardness of 20-50 mg/L.
To allow production of satisfactory softened water by sodium cycle treatment the water
should have a composition such that after treatment the water does not contain more than 900
mg/l sodium. To prevent damage to the ion exchange material the raw water should not
contain more than 1.5 mg/L iron and manganese or more than 5 units of turbidity unless
suitable pre-treatment can be provided.
Ion exchange beds may be gravity or pressure type and are operated in much the same way as
a rapid filter.
Further details of design and operation of ion exchange plants are given in relevant references.
There are several factors need to be evaluated before determining the best method. These
factors include raw water characteristics such as source type, source conditions, rainfall in
each month, water quality goals, and existing infrastructure. As first step, a complete water
quality survey at water source(s) must be conducted before deciding on a treatment approach
to address algae/cyanobacteria removal. The next step is to decide the treatment goal by
considering source water fluctuations, seasonal changes in algae population and type, and
other possible water quality problems (such as lower DO, high colour, taste and odour, Fe and
Mn etc.). The last step is to select available technology, which is the best fit for the water
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-15
quality goals. If possible, bench-scale and pilot testing should be performed before full-scale
implementation to determine the efficacy of the chosen process.
Micro strainer, Sonicator, prechlorination with limited dose to avoid THM formation, and
DAF with PAC dosing or GAC filters are the selected treatment options used to remove
algae/cyanobacteria in Sri Lankan water treatment plants in Pollnnaruwa, Thuruvila and
Konduwatuwana. For more detail on algae and its removal refer the annexure on algal
treatment.
Permeate
Feed (Qf, Cf) (Qp, Cp) Cc = Concentration of concentrate
Cf = Concentration of feed
Cp = Concentration of permeate
Qc = Water flow of concentrate
Concentrate Qf = Water flow of feed
(Qc, Cc) Qp = Water flow of permeate
Figure 7-3: Schematic diagram of separation process through a semipermeable membrane
There are four types of pressure driven membranes used in the current water treatment market
namely, microfiltration (MF), ultrafiltration (UF), nano-filtration (NF) and reverse osmosis
(RO) filtration. The distinction among the four membrane types is not very clear and depends
on different interpretations. However, they are roughly identified according to the types of
materials rejected, operating pressures and nominal pore sizes. Membranes used for drinking
water treatment are mainly categorized as low pressure membranes and high pressure
membranes. Microfiltration and ultrafiltration membranes are the low pressure membranes
while nano-filtration and reverse osmosis membranes are categorized as high pressure
membranes. Figure 7-4 shows the hierarchy of pressure driven membranes.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-16
Figure 7-4: Particle rejection (approximate) in different membrane process (Crittenden
J.C. et. al., 2012)
Table 7-6 illustrates the differences of membrane filtration with reverse osmosis process
characteristics.
Table 7-6: Comparison of membrane filtration and reverse osmosis (Water Treatment
Principles and Design)
Process Characteristic Membrane filtration Reverse Osmosis
Objectives Particle removal, microorganism NOM removal to control DBP,
removal softening, seawater and brackish
water desalination, specific
contaminant removal
Target contaminants Particles Dissolved solutes
Membrane types Ultra filtration, Micro filtration Nanofiltration, Reverse osmosis
Typical source water Fresh surface water (TDS < 1000 Ocean or seawater, brackish
mg/L) groundwater (TDS = 1000 - 20,000
mg/L), colored groundwater (TOC >
10 mg/L)
Membrane structure Homogeneous or asymmetric Asymmetric or thin film composite
Most common membrane Hollow fibre Spiral wound
configuration
Dominant exclusion Straining Differences in solubility or
mechanism diffusivity
Removal efficiency of Frequently 99.9999% or greater Typically 50 - 90%, depending on
targeted impurities the objective
Most common flow pattern Dead end Tangential / cross flow
Operation includes backwash Yes No
cycle
Influenced by osmotic No Yes
pressure
Influenced by concentration No Yes
polarization
Noteworthy regulatory issues Challenge testing and integrity Concentrate disposal
monitoring
Typical transmembrane 0.2 - 1 bar (keeping pressure below 5 - 85 bar
pressure 1bar helps less membrane fouling)
Typical permeate flux 30 - 170 L/m2h 1 - 50 L/m2h
Typical recovery >95% Approximately 50% (for seawater) to
90% (for colored groundwater)
Competing process Granular filtration Carbon adsorption, ion exchange,
precipitative softening, distillation
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-17
7.6.2. Design of Low Pressure Membrane Treatment Systems (Microfiltration and
Ultrafiltration)
MF and UF membranes are used in drinking water production plants as well as wastewater
treatment plants. They are used in drinking water production to remove suspended and
colloidal matters, algae and microbes such as Cryptosporidium, bacteria and viruses. Also
they are used as pre-treatment techniques in reverse osmosis and nano-filtration drinking
water plants.
The dominant mechanism of MF and UF is sieving i.e. size exclusion. However, In addition
to the particle size and pore size of the membrane which affects straining effect, pore size
distribution, flexibility of particles, electrical charge of the membrane pores, nature of
membrane material, electrical charge of particles, diffusion coefficient of particles and
process conditions such as temperature, salinity and filtration rate (flux) affect the filtration
process of the membranes.
Molecular weight cut-off (MWCO – 95% target compound removal) is a measure of the
removal characteristic of membranes in terms of molecular mass rather than its size. This is
due to the difficulty in measuring and defining smaller size particles morphologically. For
example, MWCO of 100 000 Dalton means that the membrane rejects 95% of 100 000 Dalton
molecular weight particles.
Water flux (L/m2h or m3/m2h or m/h) is the per area water flow or the filtration rate and is
given by,
(7.2)
Permeability of membranes depends on the viscosity of water and as a result depends on the
temperature.
( )( )
Permeability of the membrane at temperature t Kt
Permeability of the membrane at 20oC K20c
Temperature t (oC)
Normalized permeability and normalized clean water flux which are measured at 20oC and 1
bar are commonly used in characterizing MF and UF membranes.
Pore blocking
When the entrance to a pore is blocked by particles pore blocking occurs. Still flow can occur
due to open pores and they are interconnected at the pore depth. This occurs initially with a
rapid drop of flux.
Cake Filtration
Cake filtration will follow pore blocking and results a slower rate of flux decline. This
formation of cake layer is caused by deposition of particles and / or organic polymers on the
membrane surface. The formed cake will retain smaller particles that can be passed through
the pores of the membrane, and hence acts as a ‗dynamic filtration medium‘.
The cake can be classified as compressible or incompressible. This depends on the nature of
the particles such as shape, particle size and rigidity. Incompressible cake can withstand
cumulative drag stresses or any other external stresses without any significant structural
changes. Therefore, specific cake resistance remains constant over time and the porosity is
time and pressure independent. In compressible cakes the drag forces will lead to
rearrangement of particles within the cake as internal stresses increase and hence the porosity
will be at its minimum value.
If we assume that pore blocking does not play a major role in membrane fouling (in a certain
stage), then fouling is mainly due to cake filtration. Then,
( ) (7.6)
(7.7)
Where I is a measure of fouling characteristics of the particles in the water and I is given by,
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-19
(7.8)
2
rk resistance of cake per mg cake per m membrane (m/kg)
V/A total filtered volume per m2
c concentration of suspended /colloidal matter in feed water (kg/m3)
The effect of particle size on cake resistance of a spherical particle is given by the Carman -
Kozeny equation.
( )
(7.9)
Where
ε cake porosity
ρ particle density
d particle diameter
(7.10)
Hence this results,
(7.11)
( )
Or
(7.12)
Adsorption
During early stage of filtration, that is with a clean membrane, adsorption (soluble material
like natural organic matter) plays a role in rejection mechanism. However, it is not effective in
long term filtration because the adsorption capacity is quickly exhausted.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-20
Microbial fouling
Microbial fouling greatly depends on the following characteristics of feed water.
In the microbial fouling, a formation of biofilms on the membrane surface occurs. This is due
to formation of biofilms on the membrane surface. When microbes attach to the membrane
they start growing and produce extracellular polymeric substances (EPS). EPS is viscous and
slimy hydrated gel. This gel prevents bacterial cells from hydraulic shearing and chemical
attacks such as by chlorine.
Organic Fouling
Highly problematic and least controllable membrane fouling mechanism is organic fouling
due to the adsorption of NOM or DOM to the membrane surface. Fouling mainly depends on
characteristics of DOM, the material of the membrane, properties of the solute, size and
stability of DOM. Pretreatment methods such as coagulation is used to reduce fouling by
NOM. However, NOM or DOC is an indicator only for organic fouling. It is neither proper
nor adequate for considering as organic fouling.
CIP includes membranes soaking in one or more solutions containing surfactants, acids or
bases for several hours as provided by the manufacturers. High pH is normally effective in
removing organic foulants and low pH is effective in removing inorganic fouling. Cleaning
frequency varies from few days to several months and it depends on the membrane material,
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-21
raw water quality and operating conditions. Membrane replacement may be needed in 5 to 10
years.
Inside out (dead – end mode) Less costly than inside out Large solids in feed water can
in cross flow mode clog the lumen
Less amount of water can be
treated because inside of fibre
has less surface area
Inside out (cross - flow mode) Since the cross flow Large solids in feed water can
velocity flushes solids on clog the lumen
membrane, this can be Can treat less amount of water
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-22
operated at higher flux with at same flux due to less inside
high turbid feed water surface area
Pumping cost for recirculating
feed water can be expensive
Concentrate
Product
Figure 7-6: Schematic diagram of cross flow filtration
Product
Figure 7-7: Schematic diagram of dead end filtration
During dead end filtration, feed water flow is perpendicular to the membrane surface. In dead
end filtration all rejected suspended / colloidal matter is deposit on the membrane surface.
Fouling is mainly controlled by frequent backwashing. Energy consumption is less in dead
end filtration compared to cross flow filtration.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-23
Figure 7-8: Pressure vessel configuration (Crittenden J.C. et. al., 2012)
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-24
7.6.8.1. Material Chemistry
Cellulose acetate (CA) and polypropylene (PP) are currently not used much. Recently,
polyvinylidene fluoride (PVDF), polysulfone (PS), and polyethersulfone (PES) are used
commonly. Ceramic membranes too are becoming popular.
7.6.9.2. Rejection
It is the fraction of material that does not pass through the membrane in the filtering process.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-25
7.6.9.4. Removal of protozoa and helminthes
Giardia lamblia and Criptosporidium parvum which are very resistant to disinfectants, are at
least 10 times larger than the retention ratings of MF and UF membranes. LRV greater than 7
is observed.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-26
1. Additional processes can remove contaminants which cannot be used with membrane
filtration. Some contaminants are dissolved contaminants such as arsenic which can be
partly removed by coagulation and GAC which is used to remove taste and odour.
2. Reduce the influent water particle amounts and hence decrease the membrane fouling rate.
High turbid waters can be treated prior to membranes with coagulation, flocculation and
sedimentation to reduce the load.
It is recommended to assess and evaluate the impact of chemicals on membranes with pilot
tests. Sometimes chemicals used in pilot plants can damage the membranes or can foul
membranes.
Table 7-8: Operating characteristics of MF and UF membrane and rapid sand filters
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-27
1. A Dow filmtec SFX - 2860 membrane module contains 5760 fibres. The fibres are
1.87m long with an outside diameter of 1.3 mm and inside diameter of 0.7 mm.
Calculate the water production from one module if the flux is 75L/m2h and the flow
direction is (1) outside in and (2) inside out. Compare the two answers.
R = ( )
= 1-(13mL-1/107mL-1)
= 0.9999987
LRV = log( )
= log (107mL-1/13mL-1)
= 5.89
3. Calculation of membrane resistance coefficient
An MF membrane is tested in a laboratory by filtering clean, deionized water and the
flux is found to be 850L/m2.h at 20oC and 0.9 bar. Calculate the membrane resistance
coefficient.
Solution:
Dynamic viscosity of water at 20oC is 1*10-3kg/ms
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-28
( )( )( )
( )
Reverse osmosis membrane treatment process is used to separate dissolved solutes from
water. It uses preferential diffusion for separation. Generally RO membranes are
semipermeable membranes. These are permeable to some components in the feed water but
impermeable to other components and the overall thickness is less than 1mm. Reverse
osmosis is a continuous separation process in which the plant does not interrupt for periodic
backwashing.
Nano-filtration membranes remove divalent anions (hardness) and natural organic matter and
it has a separation cut off of about 1nm.
7.7.3. Applications of RO
Desalination of ocean water or seawater
Salinity of seawater ranges from 34,000 to 38,000mg/L as total dissolved solids (TDS)
and Na+ and Cl- are the main constituents. However, World Health Organization
(WHO) has a limitation of 1000mg/L for drinking water.
Desalination of brackish groundwater
Brackish groundwater with TDS 1000 to 5000 mg/L range is common. Brackish water
desalination is not as costly as seawater desalination. However, disposal of the
concentrate is challenging.
Wastewater reuse
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 7-29
People live in water scarce areas try to use recycled treated wastewater. For
nonpotable water usages such as irrigation of municipal green areas and some
industrial uses wastewater reusing has become popular.
Softening and natural organic matter (NOM) removal
Nanofiltration can remove 80 to 95% of divalent ions such as calcium and magnesium
with low removal range in monovalent ions such as sodium and chloride.
Specific contaminant removal
RO can be used for removal of number of inorganic contaminants such as antimony,
fluoride, barium, nitrate, nitrite and selenium and also organic contaminants such as
pesticides.
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7.7.5.2. Water Flux (Qw)
Per area of water flow or flow rate in the membrane is given by:
( ) (7.17)
Where
Jw - water flux [m3/m2s) = Qw/A
ΔP - Hydraulic pressure differential (bar)
Δπ - Osmotic pressure differential (bar)
Kw - membrane permeability coefficient for water [m3/(m2 s bar)]
Since Cp is small compared to Cf, Cp/Cf << 1, the salt transport (Qs) is constant at a certain Cp
and is independent of the pressure. Due to that, the salt passage (SP) is lower at a higher
pressure and vice versa. The reason is that the same quantity of salt (Qs) will be diluted in a
larger amount of product water and vice versa.
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7.7.5.7. Water Balance Equations in a Reverse Osmosis System
Considering the flow rate,
(7.22)
Considering the mass balance in the system,
( ) (7.23)
where
Q - flow (m3/s)
C - concentration (kg/m3)
f,p,c - feed, permeate, concentrate
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ne - number of elements
A - total required membrane area
Ae - membrane area per element (according to manufacturer‘s product data)
Qp - permeate flow
Jw - flux
Two types of membranes are manufactured that is, one polymer or two or more polymers.
Both have an asymmetric structure with an ultra-thin active layer and one or more support
layers. In order to withstand high pressures four configurations are used in practice namely,
tubular, hollow fibre, spiral wound and plate and frame. For desalination hollow fibre and
spiral wound are mainly used.
Figure 7-12: Typical hollow fiber membrane module (US AID, 1980)
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Figure 7-13: Sketch of a spiral wound RO membrane element (Source: U.S. AID, 1980)
Equations describing concentration polarization can be derived using film theory and mass
balance. According to film theory, a boundary layer is formed at the membrane surface. As
water is passing water and solutes move towards the membrane surface through the boundary
layer which leads to higher concentration of solutes at the membrane surface. This
concentration gradient in the boundary layer leads to diffusion of solutes back to the bulk feed
water. In the continuous operation a steady state is reached where the solute concentration at
the membrane surface is constant over time.
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(7.30)
where
M - mass of solute (g)
t - time (s)
D - diffusion coefficient for solute in water (m2/s)
x - distance perpendicular to membrane surface (m)
A - surface area of membrane (m2)
C - Concentration at the boundary layer
This equation is applicable not only at the surface of the membrane but at any plane in the
boundary layer.
Rearranging and integrating across the thickness of the boundary layer with the limits of
At x = 0, C = Cm (concentration at membrane surface)
At x= δ, C = Cb (concentration of the bulk)
Or
( )
(7.31)
The ratio of the diffusion coefficient (D) and the thickness of the boundary layer (δ) is called
the mass transfer coefficient, k.
(7.32)
(7.33)
Where Rint is the intrinsic retention on the membrane
Then,
( )
( ) ( )
The ratio Cm/Cb is called the concentration polarization factor.
Concentration polarization factor increases with increasing flux, with increasing retention and
with decreasing mass transfer coefficient.
When the solute is completely retained by the membrane
( )
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Concentration polarization can be reduced by
Decreasing the flux
Increasing the mass transfer coefficient, k (since the diffusivity of solutes cannot be
controlled) by increasing the feed velocity along the membrane or by changing the
module shape and dimensions.
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Presence of bacteria leads to biofouling. These bacteria produce extra cellular polymeric
substances (EPS) and this is sticky. However, in general almost all membrane systems carry
biofilms. When nutrients are available bacteria number multiplies. Bacteria and EPS form thin
layers on spacers, woven fabric and membrane surface and this process is called biofilm
formation. When biofilm or biomass is accumulated to such a level that it gives operational
problems is called biofouling.
where t1 is the time taken to filter the initial 500 mL of filtrate volume, tT is the time taken to
collect 500 mL of filtrate after 15min of starting the initial measurement and T is 15 min. It is
recommended that the SDI value should be less than 3 for reverse osmosis and nanofiltration
pretreatment systems.
%P30 is called the plugging ratio. If the plugging ratio exceeds 75% for the type of water that
is being experimented, then T can be taken a smaller time such as 10, 5 or 2 minutes (Alhadidi
et al., 2011).
However, there are some obvious deficiencies in this index: it has no relationship with the
concentration of colloidal matter. There is no correction for temperature. This index is not
based on any filtration mechanism. Also it does not give an accurate value when particle sizes
are smaller than membrane pore size that is 0.45 μm (Hong et al., 2009). Moreover,
biofouling, scaling and organic fouling are not considered in the silt density index.
It takes into account the observation that pore blocking is followed by cake filtration. By
rearranging the general equation describing the cake filtration mechanism the following
equation can be obtained.
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(7.38)
Where t is the time (s), V is the accumulated filtrate volume (m3), η is the water viscosity
(Pa.s), Rm is the clean membrane resistance (m-1), P is the applied pressure (Pa), A is the
membrane area (m2) and I is the fouling potential (m-2).
MFI0.45 is derived from the gradient of the t/V versus V of the above equation in the cake
filtration stage. It is the lowest gradient obtained from this curve when it is corrected to a
temperature of 20oC, pressure of 207 kPa and membrane surface area of 13.8 * 10-4 m2 (47
mm diameter membrane filter). The above Equation shows the temperature and pressure
correction for the MFI0.45. Therefore MFI0.45 is independent of both temperature and pressure.
Figure 7-16: Calculation of tgα from the t/V versus V curve (Alhadidi et al., 2011)
Where P is the pressure (Pa), η is the viscosity (Ns/m2) and A is the area of the membrane
(m2). I can be obtained using the expression,
(7.40)
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In which C is the concentration of colloids (kg/m3) and α is the cake resistance per mg cake
per m2 membrane (m3/kgm2). The temperature effect for MFI is incurred in the viscosity term
and the concentration of colloids is in the fouling index.
The modified fouling index (MFI) still uses the microfiltration membrane with 0.45 μm pore
size.
( ) (7.41)
Where η20 is the water viscosity at 20oC (Pa.s), AMO is the reference membrane area i.e. 13.8 *
10-4 m2 and dPo is the reference applied pressure which is 2.04 * 105 (Pa).
Figure 7-18: Scheme of filtration setup for MFI measurements at constant flux (Salinas
Rodriguez, 2011)
The MFI assumes that the particle retention on the membrane is constant and the permeability
of the cake resistance is time independent and also that the cake porosity is uniform
throughout the full depth of the cake that is incompressible cake. The specific cake resistance
is calculated using the Carmen - Kozeny equation for spherical particles and is as follows.
( )
(7.42)
Where ρp is the particle density of the forming cake (kg/m3), ε is the porosity of the cake and
the dp is the diameter of the particle (m).
MFI-UF was also measured under constant pressure conditions, but due to longer test run
time, MFI-UF constant flux has been introduced by Boerlage et al. in 2004. With this finding
the duration of MFI-UF test time has been shortened (Sim et al., 2011).
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7.7.9.4. Modified Fouling Index Using Ultra Filtration (MFI-UF) Membranes at Constant
Pressure
MFI-UF is a further development of MFI. Fouling due to the colloidal particles of less than
0.45 μm cannot be captured with MFI and hence not measured in the test of MFI.
Cake filtration is based on Darcy's equation,
(7.43)
Where J is the flux (m3/m2s), dV/dt is the filtration rate (m3/s), A is the area of the membrane
(m2), t is the time (s), K is the permeability of the membrane, ΔP is the transmembrane
pressure (Pa), η is the dynamic viscosity of fluid (Ns/m2) and L is the thickness of the
membrane (m). The reciprocal of K/L gives the membrane resistance. The above equation can
also be written as,
(7.44)
( )
Where Rm is the membrane resistance (m-1) and Rc (m-1) is the resistance due to cake
formation. It is assumed that the resistance due to pore blocking is not dominant and fouling is
mainly due to cake formation.
(7.46)
(7.47)
Where ΔP is the pressure gradient (Pa), η is the viscosity of water (Ns/m2), J is the flux
(m3/m2s), Rm is the membrane resistance (m-1), t is the time (s). The pressure increase is
linearly proportional with the time and square of flux when no cake compression occurs. The
fouling index (I) can be calculated from the slope of the linear section of the plot of ΔP with
time. MFI can be calculated using I from the slope of the equation above for standard
reference conditions.
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SDI < 6
Media filtration such as rapid sand filtration or dual media filtration such as anthracite and
sand.
SDI > 50
Coagulation, sedimentation (or flotation) and rapid sand filtration. In any case cartridge filters
(5 -20 μm) should just precede the high pressure pump. Microfiltration or ultrafiltration can
be used as a polishing treatment step after conventional treatment or appropriately considering
raw water quality.
Post Treatment
Removal of dissolved gasses, alkalinity and pH correction are to be carried out in RO plants.
Energy recovery devices such as running wheels, pressure exchangers, electric motor drives
and Pelton wheels are used in the industry to recover the energy in the concentrate. The
residual pressure reused is generally used to pressurize the feed. More than 90% of the energy
expended to pressurize the concentrate can be recovered. In addition to use the recovered
energy to pressurize the feed, another application is to use the recovered energy to add
pressure between stages. By this, booster pumps installed between the stages can be
eliminated.
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5. Presence of municipal and wastewater discharge points within 1km radius from the
intake point should be avoided
6. Size of waves and depth of wave impacts
7. Shipping routes and boat traffic should be avoided
8. Tide and wind characteristics in the intake area
Since the concentrate is 1.5 to 2.5 concentrated than the ambient seawater, aquatic
environment near the discharge point may be negatively affected. This effect is site specific
and depends on the marine organisms inhabiting. Usually the concentrate is discharged to the
same source so that the environmental effect is somewhat similar to natural evaporation.
The maximum TDS concentration that can be tolerated by the marine organisms living in the
discharge point area is known as salinity tolerance threshold. This depends on the type of
marine organisms living in the area and the time period that they are exposed to the elevated
salinity.
Concentrate discharge methods used in USA as per a survey done during year 2000 – 2003 is
as follows.
However, tidal zone has a limited capacity to transport and dissipate the saline effluent into
the open ocean. Therefore, it is necessary to check whether the concentrate can be treated by
natural tides using hydrodynamic modelling. The concentration disposal to this zone is
preferable only if the TDS of the concentrate is lower than the tidal zone threshold mixing
capacity. For small plants having capacities up to 400 m3/day this method can be used. An
open ended pipe of 300 feet is used as the ocean outfall.
For large desalination plants diffusers are used after extending the outfall beyond tidal zone.
Length, size and configuration of the outfall and diffuser structures are designed after
hydrodynamic or physical modeling is completed for site specific conditions.
An example for an ocean outfall situated in Perth, Australia (38 MGD plant) is shown below.
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Diameter of the plant outlet – 1.2m
Length of the plant output – 160m
40 port diffuser (ports are spaced at 5m intervals with 0.22m nominal port diameter
Location – 470m offshore at a depth of 10m
Discharge angle of diffuser – 60o
The design was adopted expecting that the plume would rise to a height of 8.5m before
starting to sink due to its elevated density.
Plume thickness at the edge of mixing zone – 2.5m
From the diffuser to the edge of the mixing zone – 40m
The discharge permit for the Perth desalination plant requires that certain dissolved oxygen
levels are met in order for the plant to operate. Furthermore, a minimum of 45 to 0ne dilution
must be achieved at the edge of the mixing zone, defined in terms of a 50m distance from the
diffuser.
The key feature of the colocation concept is the direct connection of the membrane
desalination plant intake and discharge facilitation to the discharge outfall of an adjusently
located coastal power generation plant.
In this method power plant cooling water can be used to dilute the concentrate and also as the
source water to the desalination plant. One example of using the power plant discharge to
dilute the concentrate to environmentally safe levels is (121 MLD) Carboneras desalination
plant in Spain. Carboneras plant uses separate open intake on its own, independent of the
power plant.
Using of a power plant in combination with desalination plant has following benefits.
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Reduction of cost due to the use of the existing outfall
Reduction of the salinity in the desalination plant discharge at the outfall
Thermal discharge load of the power plant is reduced due to blending
Beach well disposal is an alternative concentrate disposal method. In beach well injection,
concentrate is discharged into a relatively shallow unconfined coastal aquifer and it finally
conveys the discharge into the open ocean through the ocean bottom. These are used only for
small and medium seawater desalination plants.
Major concerns in disposing concentrate into deep wells are:
Site specific confined aquifers of large storage capacity that have good soil
transmissivity
Elevated seismic activity areas or near geologic faults are not feasible (to avoid direct
connection of discharge aquifer and a water supply aquifer)
Discharge aquifer should be adequately separated from water supply aquifers to avoid
contamination of groundwater with concentrated pollutants
Potential leakage from the wells
Potential scaling and decrease of well discharge capacity over time
A backup concentrate disposal method is needed for the time period when the
injection wells are tested and maintained
High costs for construction of wells and maintenance
Two cities Marina and Sand City in California have used shallow well discharge technique.
Marina well is a conventional well and Sand City well is a horizontal well. The salinity range
of them is between 30,000 and 43,000 mg/L of TDS and fed into shallow dune sand aquifers.
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CHAPTER 8
Stabilization problems involve calculating the chemical dosages to adjust the chemical state
of a water (condition the water) to meet the guidelines. That is
Alkalinity and calcium concentrations each to exceed about 50mg/L as CaCO3, and a
pH in the range 6.5< pH < 8.5;
The water to be supersaturated with respect to CaCO3, with the precipitation potential
of about 4mg/L CaCO3;
The ratio (Cl- + So42-)/ Alkalinity ≤ 0.2 (where species concentrations are expressed on
the equivalent scale); and/or the concentrations of each Cl- + So42- must not exceed
50mg/L (Corrosion protection guideline);
The sulphate species concentration to be less than about 350 mg/L So42- /L
(Aggression protection guideline);
The dissolved oxygen concentration should be greater than about 4 mg/L.
All the guidelines usually can be satisfied by appropriate chemical addition and aeration.
However, satisfaction of corrosion protection guideline may not be practical if either, or both
of So42- and Cl- concentrations are high, because either, the commercial dosing costs are too
high, or the water will be too hard after stabilization. In this event, lined metal pipes and
plastic pipes can be used.
The pH of the water can be calculated using Equation (1) which applies for waters with a pH
of between 4.5 and 8.5, at 25°C.
pH = log{2.2X106*[ALK]/[CO2]} (8.1)
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Localized deterioration of pipes resulting in leakage ; complete or partial blockage
of pipes by corrosion
Dissolution of metal causing possible toxicity or other water quality problems
Discolouration of water due to corrosion products ; failure of equipment due to
weakening or corrosive products
Escape of chlorine gas to the air in WTP premises causes corrosion to the metal
and equipment, more importantly when steel package WTP and steel storage tanks
are used
Effect of leaching cement lining causing high Aluminium
To understand these effects and to design suitable protective measures, some understanding of
the process of corrosion is necessary.
Galvanic or bimetallic corrosion arises from the contact of metals with very different
electrochemical potentials. The electropositive metal is cathodic to the electronegative metal
and promotes its corrosion. For example, graphite is cathodic to cast iron and is present as
inclusions in cast iron pipe. Galvanic corrosion promotes the dissolution of the iron leaving
the graphite as the only structural material. Table 8-1 shows the electrochemical series for
metals in seawater. The motion of oxygen, fortunately the corrosion products inhibit the
transfer of oxygen to the pipe surface and so tend to reduce the rate of dilapidation.
The more noble metals and alloys more resistant to corrosion are at the top of the list.
Generally, if two metals widely separated on this list are used in contact with one another the
less noble may suffer accelerated corrosion, and reduce the rate of corrosion of the more
noble.
Other factors could also help to inhibit corrosion. For example, during the corrosion process
local increases in pH can cause precipitation of calcium carbonate from water saturated with
calcium carbonate. Under suitable conditions, this will form a scale on the pipe surface and
inhibit oxygen transfer. However, serious problems usually occur when localized corrosion
proceeds under special conditions. More often than not such problems are usually associated
with damage to the oxide film which is naturally produced on the pipe wall at the
manufacturing stage. Damage at a particular points leads to the establishment of a localized
corrosion cell and is accompanied by a concentrated attack on the small anodic site, which
leads to a localized corrosion pit.
Corrosion cells can also be established under a variety of special conditions involving
galvanic action, differential cells, stress corrosion, microbial corrosion and stray electric
currents.
Different permeability of soils in trenches or where debris present inside pipelines can cause
differences in oxygen concentration. Localized differences in dissolved oxygen meet the
metal surface can then establish corrosion cells and lead to localized corrosion.
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Anodic reaction can arise in the presence of sulphate reducing bacteria. This type of corrosion
is common in water-logged soils where oxygen diffusion is poor. Black ferrous sulphide is
precipitated and is an indication of microbial corrosion. Similar reactions can occur on the
internal surfaces of pipes but require anaerobic conditions for sulphate reducing bacteria to
survive. This is unlikely under reasonable water quality and flow conditions but can arise in
certain circumstances. Bacterial slimes or other growths on the interior surface can also create
these conditions.
Induced direct currents can cause external pipe corrosion at the point where the current leaves
the pipes. These should be aggravated when metal service pipes are used to earth domestic
electrical appliances.
Table 8-1: Electrochemical series for Common Metals and Alloys in Sea Water
Austenitic stainless steel (passive)
Magnesium alloys
Lead-tin solders
Nicle (passive)
Nickel (active)
Silver solder
Magnesium
Aluminium
Cadmium
Cast iron
Platinum
Graphite
Bronzes
Brasses
Copper
Monel
Silver
Gold
Lead
Steel
Zinc
Tin
Although a number of indices have been developed, none has demonstrated the ability to
accurately quantify and predict the corrosivity or aggressiveness of water. They can only give
a probable indication of the potential corrosivity of water. Experience has shown that if
conditions encourage the formation of a protective calcium carbonate film, then corrosion will
generally be minimized. Several models and indices are available that use calcium carbonate
chemistry to evaluate water stability (Rossum and Merrill, 1983).
A commonly used index is the Langelier Saturation Index (LSI). This index provides a
measure of the stability of water with respect to its degree of CaCO3 saturation. If water has a
negative LSI value, it is under-saturated with respect to calcium carbonate and is potentially
corrosive. Conversely, for waters with a positive LSI, a protective layer of calcium carbonate
can form as the water is oversaturated with CaCO3 and the water is scaling. Saturated water
has a LSI of zero (refer Table 8-3).
The pH at which water is saturated with CaCO3 is known as the pH of saturation or pHs. At
25°C and TDS less than 500 mg/L (the case for most Victorian surface waters), the LSI can
be calculated from Equations (8.2) and (8.3):
LSI = pH – pHs (8.2)
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pHs = 11.5 -log[Cai] –log[ALK] (8.3)
In practice, water is considered to be potentially aggressive if it has a LSI of less than –1.5.
The Rochester water has a pH of 7.6, Ca of 7.9 mg/L ―as is‖ and an alkalinity of 15 mg/L as
CaCO3. By substitution, we can calculate the LSI to be –1.8. We can therefore say that this
water is potentially mildly corrosive.
Another related parameter is the Ryznar Stability Index, which is given by:
RSI = 2pHs - pH (8.4)
The RSI value of water should be less than 10 for it to be considered to be stable and non-
corrosive. For the Rochester water, the RSI value is 11.2; again suggesting this water is
mildly corrosive.
The Calcium Carbonate Precipitation Potential (CCPP) is a more reliable water stability index
to use since this index provides a quantitative measure of the calcium carbonate deficit or
excess of the water, giving a more accurate guide as to the likely extent of CaCO3
precipitation. Previously, CCPP has been less frequently applied because the longhand
calculation procedure is time-consuming and quite tedious. The AWWA (1996) released a
PC-based spreadsheet program based on the Rothberg, Tamburini and Winsor Model, which
allows speedy calculation of a number of corrosivity indices, including CCPP. The program
also allows calculation of the effects of various chemical additions to water. A measure of the
corrosivity of water for different values of CCPP is presented in Table 8-2.
Table 8-2: Corrosivity State of Water for Different CCPP Values
Corrosivity State Of Water CCPP Value, mg/L CaCO3
Scaling (protective) >0
Passive 0 to –5
Mildly Corrosive -5 to –10
Corrosive (aggressive) < -10
Another method of determining the CCPP value is a graphical procedure involving the use of
water conditioning diagrams originally developed by Caldwell and Lawrence (1953). These
diagrams can also be used to solve a wide range of water treatment and conditioning problems
(including lime and lime-soda softening).
Figure 8-1 is part of a C-L Diagram drawn for water at 25°C with a TDS of 40 mg/L.
Although a unique C-L Diagram should be used for the temperature and TDS of the water in
question, in practice Figure 8-1 can be used over a range of conditions without serious error.
Equation (8.5) is valid for water at 25°C, with a TDS of up to 200 mg/L. C2 and ACIDITY
are expressed as calcium carbonate.
(ALK-Ca) and ACIDITY are plotted on the C-L Diagram and at the point of intersection, it
can then be read off the Ca concentration at saturation. The CCPP value is then found from
Equation 8.6:
CCPP = ([Ca] – [Casat]) (8.6)
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Figure 8-1: Caldwell-Lawrence Diagram: 25°C, 40 mg/L TDS
Table 8-3 summarizes the various water corrosivity indices with accepted values for stable,
non-corrosive water.
Table 8-3: Stability Indices with Typical Values for Stable Water
Stability Index Acceptable Value
Langelier Saturation Index -1.8 > -1.5
Ryznar Stability Index 11.2 < 10
Calcium Carbonate Precipitation Potential - 4.7 > -5
Aggressiveness Index 10.3 > 10
In addition to the corrosivity at any one location as indicated by the soil resistivity, much
corrosion is due to change in soil resistivity along the pipe line. The greater and more abrupt
the change, the greater the corrosivity in the low resistance soil immediately adjacent to the
high resistivity soil.
A relatively simple soil resistivity survey over the route of any pipeline will indicate all areas
likely to be corrosive in accordance with the following guide.
Values below 2000 ohm-cm are usually corrosive except when they lie between areas of
lower value, or when they comprise the highest value in a long section of line. Values
below 1000 are sure to be corrosive; below 500 severe and rapid corrosion is almost
inevitable.
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Values above 12,000 ohm-cm are almost never corrosive, except occasionally when a
short section lies between much higher resistivity soil, but even then the corrosion is
usually mild.
Values between 2000 and 12,000 ohm-cm must be assessed for corrosivity by comparison
with adjacent sections ; relatively low areas will tend to be corrosive as well areas of rapid
and large change in soil resistivity ; again the areas of low resistivity will be the corrosive
areas.
Coating must be properly applied to dry, corrosion free metal, and must be free from pinholes
or damage to be effective. They should bond with the metal and give insulation against
electrical current. Common materials available are.
Cement mortar – suitable for internal lining of ductile, cast iron and galvanized
steel pipe
Epoxy – highly resistant, durable and suitable for internal and external use
Polyethylene sleeving – required external protection for ductile pipe in the US
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Zinc coating (galvanizing) – commonly applied as protection for steel and ductile
pipe at manufacturing stage
Bitumen and coal tar – commonly used for internal and external coatings
protective paints and sheathing : care must be taken to ensure that internal use will
not result in objectionable tastes
Wrapping tapes – these are available in a variety of materials and forms for factory
or site application
Care must be taken to ensure that any damage to protective coatings or linings during
transport or installation are thoroughly repaired to the specified standard. Particularly
attention should be paid to pipe joints.
Steel pipes tend to be of large diameter and are usually of strategic importance and bitumen
sheathed. It is essential for the sheathing to be thick and continuous in order to afford
adequate protection but where soils are corrosive an added safeguard is introduced in the form
of cathodic protection which would continue to give shielding in the event of the sheathing
becoming damaged. This will inevitably set up a galvanic cell with the bare metal forming an
anode at which localized pitting would develop.
―Long-line‖ corrosion cells can also occur where sections of the pipeline run through
aggressive low- resistivity soil which form anodic areas relative to parts of the pipeline
passing through soils of higher resistivity.
There are two methods of applying cathodic protection, namely by installing sacrificial
anodes or by introducing impressed current to the pipeline. The sacrificial anode is made of a
metal with greater negative potential than that of the pipeline. It is submerged in electrolyte
and connected externally to the pipelines to from a galvanic cell under, which the protective
or ―sacrificial‖ anode corrodes in preference to the cathodic pipeline. Specially formulated
alloys of magnesium, zinc and aluminium are used for making sacrificial anodes.
In the case of the impressed current system, the protective current is not derived from the
potential difference between dissimilar metals. Instead, Protective anodes are energies, current
flows from these anodes through an external connection to the negative terminal of the DC
power sources.
Deciding which type of protective system to adopt depends on many factors. Size and
complexity of structure, nature of the electrolyte and the environment, availability of power
supply, proximity of ―foreign‖ structures which may affect or be affected by the flow of
current etc. all figure in the decision . A detailed technical evaluation should be carried out.
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8.7. Prevention of Corrosion within Treatment Plant
Corrosion in a pipe, acts in the same manner as a battery. A negative area of metal (the anode)
is connected to a positive area (the cathode) by the pipe wall itself as shown in Figure 8-2. As
a result, electrons can flow from the anode to the cathode.
Additional design consideration includes the use of insulation flanges in case where dissimilar
metal pipes must be connected and in situations where the pipeline exits a concrete wall to
enter the ground or a water tank. Further stray current electrolysis type of corrosion may
occur in areas near Direct Current (DC) transit systems.
As long as a treatment plant is characterized by poor design and/or has deposits of debris on
the metal surfaces, concentration cell corrosion may occur at any plant site. These factors
create a localized concentration of a specific element such as oxygen, sulphate, or chloride,
which is significantly different from other portions of the water. For instance, the oxygen
concentration beneath the deposits of the debris is less than the surrounding water; thus this
portion of the metal becomes anodic and acts as the starting point for corrosion. This type of
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concentration is called as Oxygen differential cell. Coexisting with most oxygen cells are the
corresponding sulphate and chloride concentration cells.
When metal surface has deposits of debris or when alum floc or lime particles create non-
aerated zones( after precipitated) beneath the deposits, corrosion begins in this anodic region.
Other chemicals that could contribute to corrosion of metals within the treatment plant include
chlorine and coagulants received in powder form.
Chlorine leaks or chlorinated motive water leaks during handling and dosing causes
significant corrosion to metal structures and coagulants in powder form the fly during the
chemical batching and settle on iron truss, pump and motor bodies causing damages to them.
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CHAPTER 9
An example of typical design criteria for a full treatment works is given in Table 9.1.
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Table 9-1: Typical Design Criteria for a full treatment works
Item Criteria
Intake Capacity
Design flow for treatment 555 L/s (48000m3/d)
Grit removal
Number of channels 2
Width (each) 3.5 m
Length 22.0 m
River level 3.0 m above MSL
Velocity (horizontal @555 L/s) 0.16 m/s
Velocity (setting @555 L/s) 7.2 mm/s
Detention time (@555 L/s) 2.3 min
Travelling Screens*
Number 2
Width 2.0 m
River Level 3.0 m
Velocity 0.45 m/s
Plant Capacity
Design flow, raw water in 555 L/s (4.7% allowance for loss through works)
Design flow, treated water out 530 L/s (46000 m3/d)
Wet Well
Number 1
Volume 69.5 m3
River level 3.0 m above MSL
Detention time 2.09 min
Flocculation Basins
Number 2
Width (each) 3.962 m
Length (each) 81.65 m
Volume (each) 333.6 m3
Detention time 23 min
Setting Basins
2
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Item Criteria
Number 13.9 m
Width (each) 45.0 m
Length (each) 2.438 m
Side water depth (each ) 1.6 m/h
Up flow rate 1.5 h
Detention time 2.89 L /s/m
Weir overflow rate 96 m
Weir length (each basin)
Filters 8
Number Gravity sand downflow
Type 69.3 L/s
Flow (each) 7.3 m/h
Filtration rate 34.4 m2
Surface area (each) 4.3m
Width (each) 8.0 m
Length (each) 1.8 to 2.5m
Headloss 35 to 50 m/h
Backwash rate 5 to 10 m/h
Surface wash rate
Chemical Systems:
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Design and Construction of a water treatment plant involves the following four steps.
1. Site selection
2. Development of a cost effective treatment process.
3. Sizing the individual treatment units and placing them in the available area to achieve
proper sequence and hydraulics, to provide access for operation and maintenance of
equipment and to minimize the total space requirement.
4. Connecting pipes are tied down with topography of process units, buildings, chemical
feeding lines, roads and pumping needs.
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Screening No screening Screening required
Water treatment plants are rarely relocated because of the huge investments in land, treatment
basins, reservoirs, source water mains and finished water transmission mains when water
treatment plant equipment and structures reach the end of their useful life, they are typically
rehabilitated upgraded or rebuilt at the same location. It is important then to provide ample
room at the plant site for future expansion, not only according to the projected increase in
treatment capacity but also if possible for expansion beyond the immediate planning period
and for unanticipated plant improvements such as additional treatment processes required to
meet future regulators.
In uncertain situations of likely future water quality deteriorations, the water treatment
hydraulics should allow for advanced / additional treatment units and necessary land
requirements should be accommodated for structures and connecting pipelines.
The main sources of noise from routine operations at WTPs are pumps, generators,
compressors and blowers. Following controlling techniques can be used to reduce the
operational noise.
Using low noise emission equipment
Enclosing the equipment in a sound attenuating enclosure
Erecting a sound wall, berm or heavy landscaping between the source of noise and the
neighbours.
Noise level shall be below the CEA specified noise level.
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It is most appropriate to locate the WTP near the raw water source, using low-head pumps to
lift the source water to the plant and high-head pumps to deliver the treated water to the
service area.
A plant must be accessible throughout the year under all weather conditions. Therefore the
plant access road should not have low-level river crossing or stretches subjected to flooding.
Sites with available rail road facilities is an important consideration to lower the unit cost of
bulk deliveries in WTPS with high chemical usage.
Sites with steep-slops also have the problem of potential landslides, particularly in view of the
fact that cleaning process basins or yard piping can saturate surrounding soils and increase the
tendency for slope failures. Where soil conditions and topography are conducive to landslides,
mitigation measures such as horizontal drainage, retaining wall, buttress fills and tiebacks can
be used. The cost of these migratory measures should be factored into the site selection.
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9.2.10. Site Drainage and Flooding
Sites that receive storm water run off from a large upstream catchment require a more
extensive site drainage system and structures to ensure the slope stability of the area than
those where only a small amount of storm water drains onto the site. Wherever possible and
where slope stability is not critical the storm water drainage can be designed to provide
infiltration into the ground.
Many water treatment plants are located adjacent to a lake or river because this provides close
proximity to the source water. The disadvantage of siting a plant near a river is the risk of
flooding. Sites well above the 100-year flood level offer increased reliability. It is important
to select the intake site where pumps and motors to be installed above the high flood level.
Even though Sri Lanka is located outside the severe seismic activity region, it is prudent to
consider at least minimum precautionary measures in structural designs against seismic
activity.
If the treatment plant is located with the city limit, conformity of construction (COC) shall be
obtained from local authorities for all structures, office buildings and quarters.
It is better to avoid areas vulnerable for bird, wild animals, especially monkeys and elephants.
If site is selected in areas prone to them, site should be provided with, elephant fence and nets,
screens etc. to be provided to the pigeons and other birds. Buffer zone may be provided
depending on the available extent of the site. CCTV cameras shall be provided at treatment
plants and other places as appropriate.
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9.3. Arrangement of Water Treatment Plant Facilities
While site arrangement must be considered and evaluated during the site selection process,
once the plant site has been selected the next step is to optimize the arrangement of the
treatment process units on the site. Design Engineer has to visit the WTP site essentially many
times and be very familiar with the site.
By this stage unit treatment process should have been identified, hydraulic grade line has been
finalized, and specific unit sizing of them shall be computed. Full consideration must be given
to proper layout and arrangement of the process units, buildings and roads as well as other
supporting facilities. The plant layout must be planned to set out according to the hydraulic
profile to match with the topography. A poor plant layout can have a negative impact on the
effectiveness of treatment plant, maintenance operations, construction and operating costs,
ease of future plant expansion and plant appearance.
Advantages
If the plant must be enlarged in future, this is favourable
It is conceptually simple
Disadvantages
Location of chemical feed points and mechanical equipment are unfavourable.
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9.3.4. Compact Layout
The primary goal of the compact layout, also called the cluster layout (Kawamura, 2000) or
integrated layout (Corbin et al., 1992), is to consolidate areas requiring frequent operator
attention. The compact plant layout, shown schematically in fig. 9.1 accomplishes the
clustering of chemical feed points and mechanical equipment by locating filters and clear
wells near the head of the plant.
By moving filters from the outlet end of the sedimentation basins to a location near the rapid
mix basins and routing the settled water to the filters using a channel or pipe facilities needing
frequent operator attention are clustered together. Filters are positioned adjacent to the rapid
mix basins, sedimentation basins, and filters in close proximity to the operations building.
Another characteristic of the compact layout is that the major process units and plant facilities
are normally integrated in to a single, compact structure with common wall construction
rather than having separate structures as in the campus layout. In this compact arrangement,
rapid mix basins, flocculation basins, sedimentation basins, filters, clear well, chemical
facilities, operations building, and administration building may all be grouped in to a single
complex.
Convenient location for routing piping and electric cables incorporating administration offices
and operations facilities into a single building immediately adjacent to the filters means that
maintenance facilities are central to major equipment items.
The advantage and disadvantages of the compact layout are summarized in Table 9.2. One of
the disadvantages of the compact layout is that the settled water must be transferred from the
outlet end of the sedimentation basin back to the filters located near the inlet end of the
sedimentation basin. One option to do this is to construct a settled water return channel from
the outlet end of the sedimentation basins back down to the filters. This channel can be made
with an intermediate floor to provide an access tunnel running the full length of the
sedimentation basin underneath the settled water channel.
Another frequent criticism of compact plant layouts is the difficulty of making plant
expansions. The integrated nature of the compact layout means that modifications are more
difficult and disruptive than for a linear or campus layout. However, if the initial design
includes adequate provisions for future modifications and expansion, this is not a major
limitation.
Structural
Reduced excavation volumes Larger slab penetrations because electrical conduits
Reduced concrete quantities because of common- are concentrated in a smaller area.
wall construction. Extra provisions may be required for concrete
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shrinkage and expansion and for soil movement.
Consideration required for cross-connection of
treated vs. non-treated water in common wall
construction areas.
Advantages Disadvantages
Electrical
Reduced lengths of electrical and instrumentation Careful planning is critical because of the
conduits. concentration of cables into a smaller area
Smaller cable size because of shorter cables Greater potential for conflicts between disciplines
because other service (e.g. plumbing, HVAC) are
also crowded into a smaller area.
Cables can be installed in cost-efficient cable
trays instead of in buried conduits.
Cables routed indoors are more accessible.
Hydraulic
Reduced hydraulic losses caused by less Long channel or pipe may be required to convey
connecting piping between basins. settled water to filters.
Architectural
May be easier to develop an attractive Mixed use of building (operations and
architectural theme for a single mass than for administration) complicates building design.
several separate structures.
General
Less land area required More difficult to comply with fire code requirements
Fewer internal access roads and less paving. for access/egress because of the increased number of
hallways, stairways, etc.
Less underground piping.
Increased need for safety precautions arising from
Smaller area for security measures.
close proximity of bulk chemical storage to
administration building.
Environmental
Generally more opportunities for buffering Impacts affect large area
Source: Adapted from D.J.Corbin et al: Journal – AWWA 84(8):36. 1992
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Compact Plant Lay
out
Operational Factors
Redundancy
Flexibility of operations
Convenience of routine operations
Access for equipment maintenance
Control of noise
Internal roads and parking
Chemical delivery
Plant visitors
Site security
Technical Factors
Hydraulic profile
Conveyance of water between process units
application points for chemicals
Separation of filtered water and unfiltered water
Finished water storage
Source water storage
Lagoons
Locating hazardous chemicals
Flooding
Climate conditions
Architectural Factors
Building orientation
Security
Landscaping
Provisions For Future Plant Design
Capacity Expansion
Future process additions
Support Facilities
Maintenance facilities
Laboratory facilities
Construction Factors
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Construction staging
Start-up testing
9.4.1. Redundancy
Redundancy can be provided by adding standby units or by adding more treatment capacity.
Typically, redundancy for equipment items such as pumps is obtained by installing standby
units. Treatment redundancy is usually achieved by providing multiple treatment units sized
so that, when one unit is out of service, the remaining units can handle the total flow. When
incorporating the required redundancy during plant arrangement, it is important to include
sufficient space for the piping or channels connecting process units with associated valves and
gates to isolate individual units to be removed from service while the other units are kept in
operation.
A special concern in compact plant layouts is how to handle media replacement in sand filters
and GAC filters. Where the campus layout typically has room for vacuum trucks to drive up
to one side of the filters or GAC contactors, the process units in compact layouts of larger
treatment plants are often difficult to access.
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9.4.5. Noise Control
Aside from reducing the impact of noise on adjacent properties as discussed earlier, measures
to control noise within the plant must be undertaken to avoid occupational health problems for
plant employees. The best way to deal with noise is to isolate noisy equipment from routine
work areas. Available plant layout and measures to reduce the sound level for plant personnel.
Include:
Locate noise-generating equipment as far away as possible from routine work areas.
Erect sound walls, berms, and heavy landscaping in the area surrounding outside noise
areas.
Install sound-attenuating enclosures around pumps, blowers, compressors, generators,
ejectors, and other types of equipment that operate at high speeds
Locate blowers, compressors, and generators in separate rooms where sound
attenuation measures can be implemented and special protective gear to be provided
for staff.
9.4.6. Internal Roads and Parking
Site layout should include permanent roadway access to all points in the plant where
deliveries are made or where materials or equipment are loaded on to or unloaded from
trucks. Adequate parking space should also be provided for employees and visitors.
Internal roads to be used by chemical delivery trucks must provide an adequate turning radius
and permanent width.
The designer should keep in mind that visitors who are not familiar with plant layout can
easily become confused about where to go if roads and parking areas are not clearly
designated. The best approach is for the administration building to have an obvious main
entrance and for it to be located close to the front gate. Sign boards are important.
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processes, keeping neighbourhood children off the property is necessary to safeguard against
injuries to visitors.
Protection against vandalism, terrorism and sabotage is required primarily to avoid loss of the
drinking water supply resulting from equipment damage and secondarily to prevent deliberate
contamination of the drinking water supply. Security measures that should be considered
includes perimeter fencing, motorized gates, security lighting, closed-circuit video cameras,
motion detection systems, and telephone communications with the front gate.
The more treatment processes required, the greater the total head loss across the plant. If
intermediate pumping is to be avoided, a site is needed with adequate slope to allow flow to
occur by gravity. If necessary upstream processes can be raised out of the ground to generate
the necessary hydraulic head, but this makes maintenance operations less convenient, and can
have a negative impact on the external aesthetics of the plant.
Optimum elevation of structures relative to ground level depends on the site topography soil
conditions, and hydraulic profile. Placing treatment units approximately one-half underground
and one-half above ground tends to balance cut and fill, reducing overall construction costs.
When process basins are located largely underground, operators can see what is going on in
the basins without having to climb stairs. However, the excavation costs, buoyancy problems,
and depth of yard piping all increase. Where basins are mostly above ground, access onto the
basins becomes inconvenient, connecting piping becomes shallow, and basins become much
more aesthetically obtrusive.
It should be emphasized that at plant sites with a steep grade, it is wasteful to provide large
elevation drops between process units. The usual rationalization is that, because the site has
plenty of grade, the large drop between basins does not matter. However, every meter that
waterfall through the plant represents another meter of pumping head, either at the low service
pump station or at the high-service pump station. Even for a plant that receives raw water by
gravity, each additional meter of drop between process basins means another meter of head at
the high-service pump station. Therefore, the hydraulic profile through the plant should be
kept as flat as possible, even if the site has a steep grade, to keep the total pumping energy
costs as low as possible.
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The hydraulic profile should also consider the potential addition of future process units that
may be necessary due to changing source water quality or more stringent water quality
regulations. The initial planning stage for a water treatment plant is the time to consider and
accommodate these issues, as it is much more difficult and costly to accommodate future
changes if not planned in advance.
Many old plants use pipes or channels to convey water form flocculation basins to
sedimentation basins. When water velocity in these pipes and channels is relatively high
[greater than 90 cm/s). The turbulence created at entrances, exits, and bends tends to break up
the floc. When water velocity is maintained too low (less than 15 cm/s), large floc may have a
tendency to settle out. Wherever possible, connecting pipes and channels should be
eliminated, and flocculated water transferred directly through a common wall baffle. If
integrated basins are not feasible, open channels should be used to allow easy access for
cleaning settled floc.
Complying with this requirement sometimes becomes a challenge in compact plant layout
design. It is not as severe constraint in linear and campus layouts where common wall
construction is not used to the same degree.
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Smaller treatment plants located within the service area and with sufficiently high elevation
are sometimes designed with finished water storage reservoirs at the plant site. In that case,
additional land area is necessary to accommodate the reservoirs.
Plants designed to use an elevated tank for supplying filter backwash water should have the
tank located as close as possible to the filters because large-diameter piping is typically
required to accommodate the required backwash flow and large diameter piping is expensive.
9.5.7. Lagoons
If the residual handling system includes sludge lagoons or drying beds, they should be located
where they cause the least aesthetic concern. Where possible, they should also be located at
the lowest part of the site to minimize pumping. Lagoons and drying beds are generally
feasible only when the site has a large expanse of flat land and the climate is appropriate. As
they are loaded in the lowest elevation, possibilities for loading during flood or high water
level situations should be verified.
If chemicals storage tanks are visible from the street, serious consideration should be given to
constructing a wall or berm to screen the tanks from view, particularly for the case of pressure
vessels. Screens improve aesthetics, protect the tanks from drive-by vandalism, and increase
security.
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The long-range master plan for the plant site should allow space for future expansion up to
and beyond the projected long-term treatment needs. Leaving space for expansion beyond the
projected needs is prudent because long-term demand projections typically look ahead 20 to
50 years, but most water treatment plants will be in use more than 100 years after original
construction.
The space allowance for future structures should account for not just the structure footprints
but also the construction activities. There should be adequate space to excavate down to
foundation level of the new structures without affecting the existing foundations and piping.
In addition to space allowances, the initial plant structures should be designed with provisions
to aid in the construction of future expansions, for example, blind flanges on the end of piping
runs, knockout walls, reinforcing bar extensions, and similar provisions can be easily
provided during original construction and will be of great assistance during future expansion.
Channels to be extended should be constructed with stop plank grooves in the channel walls,
so that the plant can be operated during construction of the expansion. Rock that may need to
be removed to permit future expansion should be removed during initial construction to avoid
blasting near existing facilities, or more costly excavation, in the future.
Another key consideration in providing for future plant expansions and process additions is
consideration of piping, chemical systems, electrical, and other support facility corridors.
Since the basic plant layout is established at the outset of the plant construction, future plant
expansions will likely not replicate facilities such as chemical buildings and electrical
substations. Therefore, it is essential that adequate utility corridors be reserved in the original
plant layout to facilitate future expansions to avoid costly construction and operationally
difficult plant shutdowns. The ease and cost of future plant expansions will depend upon the
visionary thinking of the original treatment plant design team.
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of maintenance tools and equipment in the workshop should be designed in detail with the
O&M service before finalizing the designs.
The laboratory should be at a convenient, central location because operating personnel will be
using the laboratory many times each day. To save time and for convenience, sample piping
from various plant locations may be extended into the laboratory providing a continuous
source of water for testing. However, this arrangement should not prevent the designer from
providing the essential sample points with suitable access and openings.
Laboratory equipment such as analytical balances is sensitive to vibration, and the laboratory
should not be located near large pumps or other heavy operating equipment. In addition,
heating and air conditioning systems for the laboratory should be independent of the main
plant systems to prevent process area gases and fumes from being circulated into the
laboratory and vice versa. Particular attention needs to be paid to fume hood discharge points.
The size and layout of plant laboratories vary considerably. Depending on the type of analyses
to be performed on site, the laboratory could be quite small to relatively large. An alternative
approach used in some large plants is to have two laboratories on the site: a small one located
central to plant operations for conducting routine plant process control tests, and a full-service
laboratory for complex analytical work and outside testing services located elsewhere on the
site. The recommended minimum laboratory equipment required to WTP operations are given
in Table 9-3.
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S/ No Discription Unit Qty
15 Bunsen burner with Air Regulator Nos 1
16 LP Gas Cylinder Nos 1
17 Ultra Clean Sounder Nos 1
18 BOD Incubater Nos 1
19 LED Digitel Sounder Nos 1
20 COD Measurment Station(COD Apperatus) Nos 1
21 Portable Digital Rsidual Chlorine meter Nos 1
22 Trinocular Microscope - with image Analyzer Nos 1
23 UPS (Power Controler) Nos 2
24 Computer Sets Nos 1
25 Printer Nos 1
26 Air Conditioner Nos 1
27 Centrifuge Nos 1
28 Distilation Plant (WSQSXL) Nos 1
29 Depth Sampler Nos 1
30 Sedgewick Rafter Counting Cell Nos 1
31 LDO Meter Nos 1
32 Secchi Disc Nos 1
33 GPS Nos 1
34 Micro Plate Reader with Note Book (MULTISKAN EX.) Nos 1
35 Plankton Net Nos 1
36 Laminar Flow Fume Hood Nos 1
37 Ice Box-50 l Nos 2
38 Chlorophyill Meter Nos 1
39 Single Channel Pippete Nos 1
40 Multy Channel Pipette Nos 1
41 Digitel Stop Watch Nos 2
42 Single Channell Counter Nos 1
43 5-Channel Counter Nos 1
44 Filtration Unit Set Nos 1
45 Thermometer (0-1100C) Nos 3
46 Thermomete(0-4000C) Nos 3
47 Turbidity meter 1
48 Motor & Pastle Porcelain -(125mm) Nos 2
49 Hot Plate /Magnetic Stirrer Nos 1
50 Evoporating Dish Porclain -(150ml) Nos 2
51 Test Tube Medium wall Rim Size 16x150mm Nos 50
52 Test Tube Medium wall Rim Size 24x200mm Nos 50
53 Watch Glass dia 80mm Nos 10
54 Watch Glass dia 100mm Nos 10
55 Test Tube Holder- (Nickel Plated) Nos 5
Pipettes
56 01-mL(Glass) Nos 10
57 05- mL (Glass) Nos 10
58 10- mL (Glass) Nos 10
59 25- mL (Glass) Nos 10
60 02- mL (Glass) Nos 10
61 20- mL (Glass) Nos 10
Measuring Cylinder (Glass)
62 10 mL Nos 10
63 25 mL Nos 10
64 50 mL Nos 10
65 100 mL Nos 10
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S/ No Discription Unit Qty
66 250 mL Nos 10
67 500 mL Nos 10
68 1000 mL Nos 10
Volumetric Flask (Glass)
69 50- mL Nos 10
70 100- mL Nos 10
71 250- mL Nos 10
72 500- mL Nos 10
73 1000- mL Nos 10
74 Funnel Nos 10
Conical Flask(Glass)
75 250- mL Nos 10
76 500- mL Nos 10
77 300- mL Nos 10
Filter Flask (Glass)
78 100- mL Nos 5
79 250- mL Nos 5
80 500- mL Nos 5
81 Beaker (Glass)
82 100- mL Nos 20
83 250- mL Nos 20
84 500- mL Nos 20
85 800- mL Nos 20
86 1000- mL Nos 20
87 Burett (glass) - 50-ml Nos 3
88 Petri Dish Nos 50
Wash Bottle
89 250 mL Nos 5
90 500- mL Nos 5
Reagent Bottle (clear glass)
91 250- mL Nos 25
92 500- mL Nos 25
Screw Cup Glass Bottle
93 100- mL Nos 10
94 250- mL Nos 10
95 500- mL Nos 10
96 1000 mL Nos 10
97 2000 mL Nos 10
98 500- mL Amber Colour Nos 10
99 Reagent Bottle Conical Amber Colour 250 ml Nos 25
100 Desicator Nos 1
101 Burett Stand Nos 3
102 Separation Funnel Nos 2
103 Pippette Container Nos 5
Buchner Funnel
104 90 mm Nos 3
105 110 mm Nos 3
10 mL squir sample cell for DR/5000 20
Standard Method Book for water & wast water analysis Nos 1
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9.8. Instrumentation and Control
Complete Process and Instrumentation Diagram (P&ID) of treatment plant describe the
complete process, instrumentation and control arrangement. It shall include a complete set of
legends describing the identification number, tag number and all the symbols used in P&ID.
For further details of the control arrangement; the control philosophy has to be described in
detail and control philosophy (P&ID) are a joint output of WTP team of civil and M&E
Engineers.
Instrumentation required for control of the process is as follows:
9.8.1. Measuring Instruments
Measurement of rate of flow and total flow of water.
Measurement of filter head loss.
Measurement of chemical and chlorine dosage.
Measuring of Water Levels. (Towers, Sumps)
Measuring of hydraulic pressure.
Measuring of electrical parameters.
Measurement of Safety arrangements.
Measurement of water quality parameters of raw water; each intermediate unit
treatment and post treatment.
Measure as filter air backwash and DAF system. Flow / pressure
All the automatic control would at least consist of Auto/ Manual/ Stop. For further details,
refer the D5 manual.
Proper chlorine leak detection system for chlorine room and chlorine storage area shall be
installed at the strategic locations.
Neutralization pit and scrubber systems can be used as chlorine neutralization facility. In
addition to the neutralization system, personal protection arrangement can be facilitated
outside the building at quickly accessible points. Eyewash, shower arrangement and
respiratory protective devices can be recommended. For further details, refer the P9 & D5
manual.
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The P&ID and control philosophy should be an output of the detail design and the basis for
the construction and development, install the instrumentation, and control system for the
WTP.
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CHAPTER 10
10.1 Introduction
The O&M Manual, typically prepared by the project team consisting design team, O & M
staff and contractor which provides complete guidance to the NWSDB‘s operation and
maintenance staff on the design intent of the facility operation, with content to meet the needs
of technical staff and managers. This dual audience, with its diversity of technical background
and needs, imposes a challenge for the project team to prepare the O&M manual which is
both technically complete and comprehensive. It shall be clear to understand the operation
and maintenance staff with simple language without harming the content.
Use of high quality equipment and computer based instrumentation and control does not
guarantee the continuous production of safe water; the plant must be operated by qualified
and well trained personnel. Manual also shall describe the operation and maintenance staff
and their duties.
4. Maintenance
Equipment manufacturers‘ literature and Manufacture‘s recommendations and
their contact details
Asset Management and Maintenance system
Operations Procedures
Maintenance of each treatment component and maintenance frequencies
Lubrication and other maintenance requirements of M&E equipment, Pumps
etc. and their frequencies
Maintenance management system (work orders, maintenance history records,
schedule, inventories, purchase orders)
Warranties
Maintenance Management Plan
6. Laboratory
Monitoring program
Quality assurance / quality control and chain of custody procedures
List of analytical procedures and references
Safety and Material Safety Data Sheets (MSDSs) for laboratory chemicals
Inventories
Ordering information and procedures, based on the storage capacities
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Landscaping & House keeping
Control of animal, birds & rats which are hindering the operation of WTP
8. Safety
Supervisory and staff responsibilities
Safety equipment (PPE and other) safety equipment for chlorinators etc.
Plant-wide safety procedures
Confined –space entry procedures
MSDS for process chemicals and chemicals used for maintenance
Security arrangement with fencing, boundary walls & gates
9. Utilities
Electrical, gas and water service maintenance
Heating, ventilating, and air conditioning systems maintenance
Computer network and other communication system operation and
maintenance
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The preventive maintenance programme for M&E equipment and pumps should be prepared
in consultation with the manufacturer‘s recommendations and the industry best practices. For
other structures, treatment process etc. shall be based on the designer‘s design concepts and
criterion adopted in the design and the industry best practices adopted by the reliable similar
industries and the NWSDB best practices. This is to be written with careful consideration of
all factors mentioned above. This may be refurbished or reviewed after a trial operation and
maintenance during the initial stages of operation of the treatment plant.
An effective job plan shall be prepared by the O&M section to cover all steps of the job plan
together with the material, staff and tools etc. it is important to assign a team to carryout
preventive maintenance programme and should be maintained by superiors.
Asset management is a process of water utilities that can be used to make sure that planned
repairs, replacement or upgrading can be done on time. Enough money for these repairs,
replacement or upgrading shall be included in the annual budget.
Prolonging asset life and improving decisions about asset rehabilitation, repair, and
replacement
Meeting consumer demands with a focus on system sustainability
Setting rates based on sound operational and financial planning
Budgeting focused on critical activities for sustained performance
Meeting service expectations and regulatory requirements
Improving responses to emergencies
Improving the security and safety of assets
Reducing overall costs for both operations and capital expenditures
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 10-4
Data collection
Maintenance and update of database system
1. INTRODUCTION (Background, The Need of Water Safety Plan, Main risks in the
System)
2. WATER SAFETY PLAN TEAMS (Members of WSP team and their roles,
Assembling the WSP team, (Core Team, Supportive team, Specialists, Reviewers,
Stakeholder).
3. DATA COLLECTION (Collection of Water Quality Test Reports and other relevant
data)
4. DESCRIPTION OF WATER SUPPLY SYSTEM (System components such as Water
Source, Intake, Water Treatment Processes, Profile, Raw water & Treated Water
Quality, Water Storage, Transmission & Distribution pipes fittings, specials and
valves, coverage areas, Water quality standards, Users and uses, Delivery point,
Connection Details, Existing Monitoring Parameters, Resource constraints, Condition
of infrastructure, Operation & Maintenance Frame work).
5. IDENTIFICATION OF HAZARDS AND RISK ASSESSMENT (Identification of
Catchment Boundary, Catchment survey, Hazards in Source, Critical Activities in the
Catchments, Hazards in Water Treatment, Hazards in Water Transmission,
distribution & Storage, Hazards in premises of Consumers, Initial Risk Assessment,
Determination and validation of the effectiveness of control measures and Risk Re-
assessment, Prioritizing the identified risks).
6. IMPROVEMENT PLANS (Improvements in Water Catchments & Source, Water
Treatment plants, storage & distribution network, Consumer premises, short term,
medium term, long term measures).
7. OPERATIONAL MONITORING AND VERIFICATION (Operational Monitoring,
monitoring of the control measures, Verification of the effectiveness of the WSP,
Compliance monitoring, Internal and external auditing of WSP, Customer satisfaction)
8. Management Procedures & Supporting Programs (Creating a Management Plan,
Standared Operating Procedures (SOPs), Delivering the Actions, Management
Procedures, Supporting Programs, Emergency management procedures).
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 10-5
9. Review and Incidents (Review of WSP Procedure, Checklist for WSP review, Regular
WSP Review Meeting, Quality Assurance & tools, Incident Response Plans).
1. Create an outline of all of the standard operating procedures (SOPs) that are required to be
included in operations.
2. Write an introduction which includes a brief description of what the manual includes,
what readers can expect to gain by using the manual and the best way to use.
3. List the tasks. To complete an entire manual, it is need to start with one task at a time.
Outline the steps involved in completing the task, then go back and write out the details
for each step. Make sure each step is clear and concise, but provide enough details that
can be followed by anyone.
4. Give the SOP to someone else to read. Have an employee or someone else to read through
and follows the instructions. They can provide valuable feedback if there are steps they
could not complete or do not understand.
5. Refine the SOP based on the feedback.
6. Write the next SOP, repeating Steps 3 to 5 for each.
7. Compile all of the SOPs into a binder or bound manual. Include a cover sheet with the
name of the manual, a table of contents, the introduction and the SOPs in the order of the
table of contents.
8. Make copies and distribute to employees. Encourage regular feedback, and update when
necessary.
Emergency response plan shall be prepared under water safety plan. The ERP frame work
shall consist of levels of responsibility, reporting format and calculation of damages and
losses under Post Disaster Needs Assessment (PDNA). Refer NWSDB website under WSP
for details. Emergency recovery shall be based on climate resilience and Build Back Better
(BBB) principles as per the proposed emergency recovery policy of the Disaster Management
Center.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 10-7
10.5 Important Forms under O & M Manual
Supplier Address
Manufacture
Model No
Serial No
Installation Code
Component Code
Drive Motor
Supplier Address
Manufacture
Model No
Serial No
Installation Code
Component Code
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 10-8
Table 10-2 Operations Checklist
Operations Checklist
Date
Operation
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 10-9
Table 10-3 Problem Identification form
Problem Identification Form
Problem Statement
Observer Date
Subject
Description of Problem (Attach sketches or additional sheets if needed)
Supported solution
Distribution
Sup. Sen. Engineer Plant Superintendent (JMM/OCI)
Project Coordinator
Plant Superintendent
References
Annexes (List of Standard Operating Procedures, Catchment Survey, Standard Forms used for
Monitoring, Audited Reports et
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019) 10-10
REFERENCES
1. Alhadidi, A., Kemperman, A.J.B., Blankert, B., Schippers, J.C., Wessling, M., & vender
Meer, W.G.J. (2011). Silt Density Index and Modified Fouling Index relation, and effect
of pressure, temperature and membrane resistance. Desalination, 273, 48 - 56.
2. ASTM D 4189-07. (2007). Standard Test Method for Silt Density Index (SDI) of water,
1-3.
3. AWWA, Water Treatment Plant Design, 5th Edition, 2012.
4. AWWA, Water Quality and Treatment, 6th Edition, 2011.
5. AWWA, M20 Water Chlorination and Chloramination Practices and Principles, Second
Edition, 2006.
6. AWWA, External Corrosion: Introduction to Chemistry and Control, Manual M27, 2004.
7. Boerlage, S.F.E., Kennedy, M., Tarawnch, Z, Faber, R.D., & Schippers, J.C. (2004).
Desalination, 161, 103 -113.
8. Brock McEwen J. - 1998 , Treatment Process Selection for Particle Removal, Cooperate
Research Report, American Water Works Association Research Foundation, International
Water Supply Association, USA
9. Crittenden, J.C., Trussell, R.R., Hand, D.W., Howe, K.J., & Tchobanoglous, G. (2012).
3rd Edition. Water Treatment Principles & Design. John Wiley & Sons Inc.
10. Design Manual (D3), Water Quality and Treatment, Water Supply and Sanitation Sector
Project (USAID-Sri Lanka Project 383-0088), NWSDB, Ratmalana, March 1989.
11. Dijk, J.C and J Oomen, Slow Sand Filtration for Community Water Supply in
Developing Countries – A Design and Construction Manual, IRC Technical Paper No.11
December 1978.
12. ENSIC, Water Treatment Plant Design, 1969.
13. Holden, W.S., Water Treatment and Examination, London 1970.
14. Hong, K., Lee, S., Choi, S., Yu, Y., Hong, S., Moon, J., Sohn, J., & Yang, J. (2009).
Assessment of various membranes fouling indexes under seawater conditions.
Desalination, 247, 247 – 259.
15. Huiseman, L and Wood W.E. Slow Sand Filtration, WHO, Geneva, 1974.
16. Kennedy, M.D., Rodriguez, S.G.S., & Schippers, J.C. (2013). Desalination & membrane
related technology. UNESC-IHE Institute for water education.
17. Lecture Notes, Water Supply Engineering, UNESCO-IHE, Delft, the Netherlands,
October 2011.
18. Lewangamagea C. S. and Jayasinghe M. T. R., Report on recent development of wind
code in Sri Lanka.
19. NWSDB/USAID Project, Analytical Quality Assurance Manual, Water Quality Section,
1988.
20. Okun.A.Daniel, Christopher R. Schulz.,1984, Surface Water Treatment for Comunities in
Developing Countries.
21. Pescod, M.B., Slow Sand Filtration – A Low-Cost Treatment for Water Supplies in
Developing Countries, WRC/IRC, 1985.
22. Perara SKH, et.al. A study on addition of Ferric Chloride as a Coagulant instead of alum
in Major Water Supply Schemes, Research Unit, NWSDB, 1984.
23. Rodriguez, S.G.S. (2011). PhD thesis on particulate and organic matter fouling of
seawater reverse osmosis systems: characterization, modelling and applications. Delft
University of Technology and UNESCO-IHE Institute for water education.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019)
24. Seidel, H.F, Construction and Rehabilitation Assessment, USAID project OTD 138,
March 1984.
25. Schippers, J.C., & Verdouw, J. (1980). The modified fouling index, a method of
determining the fouling characteristics of water. Desalination, 32, 137-148.
26. Schippers, J.C., Hanemaayer, J.H., Smolders, C.A., & Kostense, A. (1981). Predicting
flux decline of reverse osmosis membranes. Desalination, 38, 339-348.
27. Sim, L.N., Ye, Y., Chen, V., Fane, A.G. (2011). Comparison of MFI-UF constant
pressure, MFI-UF constant flux and cross flow sampler- modified fouling index
ultrafiltration (CFS-MFIUF). Water Research, 45,1639-1650.
28. Visscher, J.T and Veenstra, A., Slow Sand Filtration: Manual for Caretakers, IRC
Training Series No.1 1985.
29. Water Research Centre, Performance Specification for Water and Sewage Treatment
Processes: Guidelines, October 1985.
30. Wagner, E.G (1983) Upgrading of water treatment plants in Sri Lanka Assignment
Report, UNDP/WHO Project.
31. Wagner E.G (1983) Simplifying Design of Water Treatment Plants for Developing
Countries, AWWA Journal, WEDC, Developing World Water, Grosvenor Press
International, 1986.
32. Wegelin, M. (1996). Surface Water Treatment by Roughing Filters - A Design,
Construction and Operation Manual. SANDEC Report No. 02/96.
33. Wegelin, M. (1986). Horizontal-Flow Roughing Filtration - A Design, Construction and
Operation Manual. IRCWD Report No. 06/86, October 1986.
34. Wegelin, Martin (1984), Horizontal-flow Roughing Filtration: An Appropriate Pre-
Treatment for slow Sand Filters in Developing Countries, IRCWD News.
35. Wegelin, M., Schertenleib, R., Boller, M. (1991). The decade of roughing filters -
Development of a rural water treatment process for developing countries. J. Water Supply
Research and Technology - Aqua, 40, 304-316.
36. Kawamura. S., – Integrated Design of Water Treatment Facilities.
37. R. Qasim, Edward M. Motley, Guang Zhu – Water Work Engineering Planning Design &
Operation.
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019)
ANNEXES
Annex - A
It is required to design the unit processes of water treatment plant for capacity of 15,000
m3/day. The following design calculations are based on the above capacity.
The water treatment plant is to be designed for 24 hours continuous operations. The back
washing can be carried out during off peak for electricity and water where high lift pump is
shut down or lesser amount of water pumping.
B
B = 1.000 m
D = 0.467 m
V = 0.4000 m/s
Free board = 0.300 m
H = 0.800 m
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Annex - A
3
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019)
Annex - A
Note: The screen efficiency factor and the Effective areas of the opening in the fine screen can
be obtained by referring the manufacturers’ data. Otherwise, the Effective areas of the
opening in the fine screen can be estimated.
4
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Annex - A
30 20
5
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019)
Annex – B1
Efficiency of Aerator
For single free fall in weir aeration (Page No. 5-30)
Efficiency coefficient for weir height h<=0.7 m K = 0.45(1+0.046T)
Temperature in C T = 28.0 0
C
Water fall height h = 0.75 m
K = 0.45(1+0.046×28)×0.75
= 0.77
IN D1
H1
H2
D2
H3
H4
D3
D4 OUT
Estimation of O2 Requirements
O2 requirement for removal of Fe2+ and Mn3+ are
1 mg of Fe2+ = 0.14 mg/l
1 mg of Mn3+ = 0.27 mg/l
6
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Annex – B1
For 50 years return period for Zone 1 Vb, zone = 28.0 m/s
7
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Annex – B1
Design of Aerator
Flow rate over a weir is given by Q = 671.88 /60
8
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Annex – B1
= 11.20 m3/min
Assume Cascade area = 1.75 m2 / m3/ min
Note: higher area is considered for maximum addition of oxidation
9
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Annex – B1
= 1.92 m/s
10
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Annex – B1
n = 0.013
S = (0.524 × 0.013 / R2/3)2
= 0.000377
Provide, slope as 1 : 2600
Velocity v = 0.530 m/s
SUMMARY
Number of Drops N = 3 Nr
Height of Drops H = 0.75 m
Internal Dimensions
Diameter of Aerator tray No 1 D1 = 2.60 m
Diameter of Aerator tray No 2 D2 = 4.20 m
Diameter of Aerator tray No 3 D3 = 5.60 m
Diameter of Aerator tray No 4 D4 = 7.00 m
11
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Annex – B1
12
D3- Water Quality & Treatment Manual/ NWSDB/ Revision – 01 (July 2019)
Annex – B2
Flow velocity
Flow = 672.0 m3/h
Flow rate over weir Q = 1.833 B H3/2
So, flow over weir H0 = (Q/ 1.833 B)2/3
= (0.187 / 1.833 ×20.7)2/3
= 0.03 m
13
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Annex – B2
n = 0.013
S = (0.7×0.013 / R2/3 )2
= 0.00085
Provide, slope as 1 : 1200
v = R2/3 S1/2 /n
Velocity v = 0.69 m/s
SUMMARY
Number of Drops N = 3 Nr
Height of Drops H/N = 40 cm
Cascade Area per unit flow rate A/Q = 2 m2 / (m3/min) of flow
Internal Dimensions
Length of Aerator L = 20.7 m
Width of Aerator B = 0.90 m
Height of the Aerator H = 1.20 m
14
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Annex – B2
0.3 m
0.4 m
1.2 m
0.9 m
15
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Annex – C1
STILLING WELL
THROAT
Ha Hb
S=2/3A H
A 1
6
D W C
5
1
Coagulant diffuser
STILLING WELL DETAIL
PLAN
B F G
Coagulant diffuser
FLOW K=75mm
T Ha E
Hb
Hd
1 N M
1
4
2.67
SECTIONAL ELEVATION
Figure A. 0-3: Parshall flume rapid mixer
Table A. 0-2: Dimensions and Capacities of the Parshall Flume for Various Throat Widths
(D.A. Okun, pp 91-104)
W E F G Q /(m3/day)
A (mm) B (mm) C (mm) D (mm)
(mm) (mm) (mm) (mm) Min. Max.
150 620 600 390 400 600 300 600 122 9,550
300 1,370 1,340 600 850 900 600 900 274 39,500
460 1,450 1,420 750 1,030 900 600 900 367 60,200
610 1,530 1,500 900 1,210 900 600 900 1,030 81,100
910 1,680 1,650 1,200 1,570 900 600 900 1,500 123,000
1,220 1,830 1,790 1,520 1,940 900 600 910 3,190 166,000
1,520 1,860 1,940 1,830 2,150 900 600 910 3,920 210,000
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Annex – C1
H = 920 mm
K = 75 mm
M = 375 mm
N = 225 mm
S = 1,020 mm
T = 100 mm
The flow capacity of the Parshall flume rapid mixer as per Table A. 0-3
Minimum flow rate Qmin = 1,030 m3/day
Maximum flow rate Qmax = 81,100 m3/day
A Parshall flume is used as accurate flow measurement and control device if discharge from
unrestricted or under free-fall conditions.
The depth in the converging section = Ha
The depth near the end of the throat = Hb
The unrestricted flow condition is commonly determined by Hb/Ha.
= ( )
= 252 mm
If the ratio Hb/Ha exceeds the limit given above, the Parshall flume is operating under the
submerged condition. The discharge will be retarded under this flow condition. The flow can
be obtained only from both Ha and Hb readings by using calibration curve that must be
developed.
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Annex – C1
0.80
Water Depth ( Ha Hb ), m
0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00
0.00 0.20 0.40 0.60 0.80 1.00
Flow (Q), m3/s
Figure A-4: Calibration curve of the 0.3m throat Parshall flume rapid mixer
Velocity at throat
Hb = 0.70*Ha
0.7*252 = 176.4 mm
Velocity at Critical point
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Annex – C2
Coagulant dose
Plate
Impeller
Baffle
Basin
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Annex – C2
Power Requirement
Velocity Gradient, G = 950 s-1
Viscosity at 200 c = 0.0010 Ns/m2
Power Requirement P = G2 V
9502*4.39*0.0010 = 3,962 Nm/s
Check on GT
Velocity Gradient, G = 950 s-1
Detention time T = 47 s
Detention time GT = 950 × 47= 44,733
Recommended range GT = 30,000-60,000
Hence, ok.
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Annex – C2
21
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Annex – D1
Geometrical variables are required to define the plan layout of the flocculator:
N = number of channels, thereby fixing the number of baffles at (N − 1)
Let the channel width between baffles B = 0.15 m
(Table 5-14)
The baffle thickness w = 0.04 m
Size of Flocculator
Provide no. of tanks in parallel (process trains) = 3 Nos
Flow rate per process train Qd = 0.187/3
= 0.062 m3/s
Also not that the width of the flocculation basin should be equal to the width of the
sedimentation basin
The width of the sedimentation basin B = 6.0 m
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Annex – D1
Baffle Spacing
Let minimum baffle spacing at basin entrance. Smin = 0.120 m
Velocity gradient, √ √
G = 100.85 s -1 (OK)
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Annex – D1
= 0.00053 m
Velocity gradient, √ √
G = 10.49 s -1 (OK)
Leave the last 1.2m as a transition section into the sedimentation basin (see Figure B.1).
Baffles should be adjustable in order to be able to adjust the spacing for best flocculation.
Wooden (12 mm thick or above) or plastic (10 mm) baffle boards could be installed in to
grooves made in the concrete wall. After final adjustment, the edge of the baffles could be
filleted with grout to prevent solid deposits (a gap should be left in the grouting for drainage
purposes). Basins should be designed to drain easily.
24
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Annex – D1
INLET D=3.0, d=1.820, w=0.04 D=3.0 d=1.700, w=0.04 D=3.0 d=1.625, w=0.040
08 baffles 10 baffles 06 baffles 0.20 m
A A
2.0 m
B D=3.0 d=1.355, w=0.040
B
D=3.0 d=1.535, w=0.040
06 baffles 08 baffles
OUTLET to
sedimentation tank
D
D d
W W
W W
Removable wooden Baffles
SECTION - A- A
Slots for Baffles to Extend to
Channel Floor
W = Baffle Openings
0.30
D = Baffle Depth (From Surface) W
d = Baffle Depth (From Bottom) D
NOTE: d
1. Dimensions are in meter W
2. Tank corners rounded for smooth flow
W 1.20
SECTION - B- B
Figure A-6: Hydraulic Flocculator (Conceptual Design)
25
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Annex – D1
G Din
120 3.1
3.0
100
Hydraulic Gradient (1/s)
3.0
80
40
2.8
20
2.8
0 2.7
1 3 5 7 9 11 13 15 17 19 21 23 2 4 6 8 10 12 14 2 4 6 8 10 12
Baffle No.
Figure A. 0-7: The variation of Hydraulic Gradient and water depth
Note:
Arrangement of baffles with equal space is easier for the construction and design even
though G value is increased as shown in the figure.
As design to satisfy the depth ratio, overlap ratio and slot width ratio are not
economical design was carried out without consideration of those parameters.
26
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Annex – D2
Vertical
Horizontal
shaft
Parameters shaft with
with
paddle
turbine
Velocity gradient, G (s-1) 50 - 10 70 - 10
Detention time, t (min) 30 - 40 20 - 40
Flocculation stage 3-6 2-4
Maximum flow velocity (m/s) 1 2-3
Paddle area (%) 5-20 0.1 - 0.2
Blade diameter/ Tank with, D/L 0.5 - 0.75 0.2 - 0.4
Speed of shaft, (rpm) 1-5 8-25
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Annex – D2
L=3m
L = 3.1 m
Depth D = 3.1 m
L1
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Annex – D2
P = 324.68 W
29
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Annex – D2
L/W 5 20
Cd 1.2 1.5 1.9
By interpolation Cd = 1.5
𝝆 = 1000 N/m4
30
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Annex – D2
Note : The peripheral speed of a paddle wheel mixer should be limited to 0.40 m/s for alum
coagulation and 0.50 m/s for lime softening flocculation
Note: that slow mixing can be provided at low intensity in order to form smaller flocs for
flotation techniques used in DAF system.
31
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Annex – E1
1. Design of Tank
Assume the detention time T = 3 hrs
So, volume of the basin V = Q×T
= 672×3
V = 2,016 m3
2. Sludge Storage
For manual cleaning bottom slope = 10 %
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Annex – E1
LF L1 L2
L2/L1 = 2.0
h3' = 4.80 m
h4
h1 h2
h2‘ = 3.90m
h3 h1' = 3.75 m
Baffle wall
h4' = 3.00 m
L1 = 9.0 m
L2 = 18.0 m
4. Inlet Baffle
Consider a perforated baffle wall at 1.0 m away from inlet point, LF = 1 m.
Velocity through perforated baffle = 0.2 - 0.3 m/s
Assume port velocity (Vp) = 0.3 m/s
Required port area = Q/Vp
AT = 0.031/0.3= 0.10 m2
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Annex – E1
No. of ports
Horizontally = x 1 / 4 of the water depth
Vertically = y
Half of the water depth
The height between first row and last raw of opening is restricted to half of the water depth.
Water depth h2‘ = 3.9 m
So, Let Spacing between ports
No. of column of ports @ 450 = 12
No. of rows of ports @ 400 = 5
No. of ports provided 12*5 = 60 53 Nos.
5. Outlet Arrangement
Flow per basin (Q) = 168 m3/h
Length of weir (w) = 3 m
Weir loading rate = q/w
= 168/3 = 56 m3/m/h
Recommended weir loading rate < 18 m3/m/h
Not Satisfied, Additional length has to be provided.
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Annex – E1
150.78 mm
H0 Trough
DT
h2 h1
LT Collecting
D D Channel D
W
Figure A-10: Detail of Collecting Channel
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Annex – E1
V = 621 m3
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Annex – E2
In practice, the plate area would be increased to allow for entry and exit effects, typically by
25% to of the actual requirement of plates.
Accordingly,
Total nos of plates = (1042 × 1.25) Plates = 1302.5 Plates
Length of the tank = [No. of Plates per Tank x (Spacing between the Plates + Plate
Thickness) /Cos 300 +z
Length of the tank = 435 × ( 50 + 10) × 103 / Cos(900 - 600) + 1 × Cos( 600)
Length of the tank = 30.141 + 0.5 = 30.641
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Annex – E2
= 3.4 m/h
Height of a Tank = 1 × Sin 600 = 1 × 0.866m
= 0.866m
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Annex – E2
Design Data
Recommended surface loading (m3/hr /m2) = 1.25 - 2.50
Recommended weir loading per weir length ≤ 215 m3/day/m
Required detention time = 2 hrs
Not usually used as a criteria
1. Hydraulic Sizing
Provided No. of clarifier units N = 6 Nr
Flow through single unit q = 16,125 / 6
(112.0 m3/hr) = 0.031 m3/sec
But V = Q×T
Hence detention time provided T = V/Q
= 218 / 112
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Annex – E2
T = 1.95 hrs
Inlet
Settled water channel Decanting trough
Sludge
concentrator
Sludge
concentrator
Bottom sludge
extractor pipe
2. Inlet Arrangements
Inlet Channel
This channel will carry the total flow
Qdesign = 0.187 m3/sec
Assume breadth of channel B = 0.60 m
Recommended maximum velocity in m/s = 0.20 - 0.40
Assume flow velocity v = 0.40 m/s
This is to avoid disturbance of flocs
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hw = 0.306 m
Inlet Pipe
Single pipe is provided per a tank
Diameter of the pipe = 250 mm
Velocity of the flow = Q/A
= 0.031 / 0.049
= 0.634 m/s
Recommended maximum velocity in m/s = 0.60 - 1.80
Length of pipe = 10 m
( )
Hazen William Coefficient C = 130
( ) = 1.81 mm/m
Hf = 1.81×10 = 18.1 mm
3. Outlet Arrangement
Design of Collecting Channel
Weir Length L = 8.0 m
No. of collecting channel per tank N = 4 Nr
Flow through a collecting channel Qc = 0.031 / 4
= 0.008 m3/s
Design of Slot
No. of slots per side of a collecting channel = 12 Nr
Since slots are provided both sides N = 24 Nr
Flow through a collecting channel Q = 0.008 / 24
= 0.0003 m3/sec
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hw = 0.023 m
Assume depth of a slot as Ds = 0.06 m
Available free board 0.06 – 0.023 = 0.037 m
Vc = 0.25 m/s
Recommended maximum velocity in m/s = 0.20 - 0.40
Outlet Channel
This channel will carry the total flow
Qdesign = 0.187 m3/sec
Assume breadth of channel Bo = 0.6 m
Recommended maximum velocity in m/s = 0.20 - 0.40
Assume flow velocity Vo = 0.4 m/s
Normal depth in the channel
= 0.778 m
Assume channel depth as Do = 1.10 m
Available free board 1.10 – 0.778 = 0.322 m
( ) ( )
ho
S
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Length of pipe = 6 m
( )
( ) = 2.54 mm/m
H = 2.54×6 = 15.24 mm
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Design Data
(page 5 – 86)
Daily Demand = 15000 m3/day
Wash water consumption = 1-6%
Recommended range of Filtration = 120 -360 m3/m2 day
Required Length : Width ratio = 1.25 -1.33
Uniformity Coefficient of Sand = 1.5 - 2.0
Effective Size of Sand = 0.4 - 1.2 mm
Thickness of Sand Layer = 0.6 - 1.0 m
Effective Size of Gravel = 2 - 50 mm
Thickness of Gravel Layer = 0.3 - 0.6 m
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= 194.7 m3/m2/day
3 2
Filtration rate is between 120 to 360 m /m /day
Hence, Satisfied
When one filter is out of order, Overloading Factor = Total filter beds/(Total
filter bed-1)
= 4/(4-1)
= 1.25
Overloading Filtration rate = 194.7 x 1.25
= 243.4 m /m2/day
3
Filtration rate of declining rate filters varies from 50 % to 150 % of the average filtration rate
(WTPD Sanks)
Average filtration rate = 194.7 m3/m2 day
= 2.254 mm/sec
Maximum filtration rate = 3.381 mm/sec
Minimum filtration rate = 1.127 mm/sec
Sand
Gravel
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(ii) When filters are operating at maximum filtration rate = 3.381 mm/sec
(h/l )/Sum(xi/di2) = 0.626 m/m
Total head loss through gravel media at maximum filtration rate = 6.3 mm
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(iii) When filters are operating at minimum filtration rate = 1.127 mm/sec
(h/l )/Sum(xi/di2) = 0.2087 m/m
Sum
Layer h/l l (mm) h (mm)
(xi/di2)
Layer 1 (3 to 10 mm) 0.050 0.010 200 2.1
2.1
Total head loss through gravel media at minimum filtration rate = 2.1 mm
Head Loss in Filter Media for Various Filtration Rates during Filtration
Head loss in filter media is proportional to the rate of flow
(B) Head Loss through Under drain System (Through Nozzles) during Filtration
Head Loss in Nozzles
Nozzle spacing should be limmitted to 125 - 150 mm for minimizing dead areas during back
washing
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Grave
l
(i) When filters are operating at average filtration rate,
Average filtration rate = 2.254 mm/sec
= 8.114 m/hr
No. of Nozzles per m2 = 65.2
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Head Loss through Under drain System (Through Nozzles) for Various Filtration Rates
during Filtration
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= 0.200 m
Head Loss in Filtered Water Exit Pipe from Filter Beds to Filtered Water Collecting
Channel for Various Filtration Rates during Filtration
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Detail of Filter
L
.
T
Sand
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(B) Head Loss through Under drain System (Through Nozzles) during Backwashing
Back wash rate = 831.43 lpm/m2
= 831.43 * 1.44
Ave. Filtration rate = 195 m3/m2 day
H.L. in under drain system at ave.filtration rate
H2 = 5.00 mm
HL in Under drain during Backwashing = 0.12 m
= 120.00 mm
(C) Head Loss in Filtered Water Exit Pipe from Filter Beds to Filtered Water
Collecting Channel, during Backwashing
Similaryly as in Under drains system, H is proportional to Q2
H1 = H2* Q12/Q22
H2 = 200 mm
H1 = 139*11972/1712
HL in Exit Pipe during Backwasing, H1 = 7546 mm
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The lower part of the channel that enters the water in to the filter, is the backwash water
discharge channel
Dimensions of Drain
D = 374 mm
W = 748 mm
Assume Free Board = 150 mm
Therefore take
D = 524.00 = 525 mm
W = 750 mm
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Design Data
Design Capacity of Treatment Plant (Daily Demand) Q = 15000 m³/day
Recommended range of filtration (m3/m2 day) = 120 – 360 m³/m²/day
Maximum Area for a filter unit = 140 m²
Required Length : Width Ratio = 1.25 - 1.33
Uniformity Coefficient of Sand = 1.5 - 2.0
Effective Size of Sand
Effective Size of Sand = 0.4 - 1.2 mm
Thickness of Sand Layer = 0.6 - 1.0 m
Effective Size of Gravel = 2 – 50 mm
Thickness of Gravel Layer = 0.3 - 0.6 m
1. HYDRAULIC CALCULATION
Design Capacity of Treatment Plant Q = 15,000 m²/day
Losses ΔQ = 7.5 %
= 15,000 x 7.5/100
= 1,125
Design flow through filters
2. DIMENSION OF FILTERS
As the filter is for declining rate, lower Filtration rate is assumed.
Assumed Average Filtration Rate = 140 m³/m²/day
Required Number of Filters – N = 1.2 (Qmgd)1/2
Where - mgd - Million Gallions per Day
01 mgd = 3785 m³/day
Qmgd = 4.26
N = 2.48
Therefore Number of Beds required to provided
Area of a Filter Bed = (16,125/4)/140
< 140 m²
Hence, The Maximum Unit Area is Satisfactory.
Area per unit L x W = 28.8 m²
Assume Length : Width Ration L:W = 1.30
L2 = 28.79 x 1.30
Hence L = 6.12 m
W = 4.71 m
Selected Dimensions L x W = 6.25 x 4.75
ok
L/W = 1.32
Value of L/W is between 1.25 to 1.33
ok
Flow through a single filter
= 4,031 m³/day
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= 0.047 m³/s
Actual average filtration rate
= 135.8 m³/m²/day
Filtration rate is between 120 to 360
ok
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< 60
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where k = 0.5
Assume Length of pipe (from filter to clear water tank) L = 10 m
h = 0.717 × 10
= 7.2 mm
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DA = 75 mm
DT = 350 mm
DL = 500 mm
D1 = 1300 mm
DS = 600 mm
DG =500 mm
DF = 3250 mm
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= 167.7 d m/s
Diameter of particle (60% passing) in mm = d60% = U.C × D10
Effective size x Uniformity coefficient d60% = 0.50 × 1.5
D60 = 0.75 mm
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Where
Density of filter media rm = Specific Gravity x Density of water
= 2650 kg/m3
Diameter of particle (60% passing) in mm d60% = 0.75 mm
Dynamic Viscosity of the fluid µ = 0.001 Ns/m2
rate Vmf = 0.0058 m/s
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= 0.11
= 15%
> 15% - 30%
Selected backwash rate is satisfied
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50mm
Head loss in gravel media 11.1
H2 = 82 mm
head loss at Back wash rate
H1 = 4775 mm
= 9.72 m
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= 12.60 min
= 4031 m3/day
% of water consumption = 4.56%
Hence, Satisfied < 6.00% .
Q = 0.012 m3/s
X= B = 0.4 m
Assume No. Of troughs = 2 Nos.
Flow in one tough = 0.01 m3/s
D = 0.049 m
Allow free board = 50 - 100 mm
= 0.1 mm
P = 0.170 m
The following two basic type "V" or "U" shaped (shallow but wide cross section) are used
Flat bottom are not preferred as solid matters, foams are trapped and may never be washed
out.
Selected Cross section Type (1/2) = 1
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P = 11.17 kW
D = (Q/1.38 B)2/3
ead
1
Recovered
Hw-HF1 = 0.28 B = 0.40 m
D = 0.75 m
= 0.20 m
H = 0.95 m
Head losses
At maximum filtration rate
Total H.L through filter media = 519 mm
Total H.L. in under drainage system = 178 mm
Total loss in the effluent pipes = 78 mm
Total Head Loss = 775 mm
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1 : 1800
Velocity v = 0.578 m/s
DESIGN SUMMARY
a) Decline rate rapid sand fitter
b) Design flow = 16125 m3/day
c) Average filtration rate = 136 m3/m2 day
Maximum filtration rate = 204 m3/m2 day
Minimum filtration rate = 68 m3/m2 day
d) Filter dimensions
No. Of filters = 4 Nos.
Dimensions of Single filter
Length = 6.25 m
Width = 4.75 m
Depth = 3.5 m
e) Filter media
Sand layer = 600 mm
Gravel layer = 500 mm
f) Under drain system
Lateral diameter = 90 mm
Lateral spacing = 250 mm
Slot diameter = 12 mm
Manifold width = 0.55 mm
Control orifice diameter = 0.5 mm
Thickness of orifice plate = 5 mm
g) Filter operation data
High water level = 1.8 m above effluent weir
Low water level = 1.3 m above effluent weir
Effluent weir = 0.075 m above filter media
in the C.W. Tank
h) Backwash system
Air scour rate = 24.74 m3/min
Air scour duration = 5.0 min
Air scour pressure = 0.5 bar
Backwash flow rate = 0.356 m3/s
Backwash pumps Q = 0.356 m3/s
Backwash duration = 8.6 min
Pump Head H = 13 m
Pump Power P = 70 kW
I) Wash water troughs and drain
No. of troughs = 2 Nos.
Width of troughs = 0.400 m
Depth of troughs = 0.17 m
Height of troughs above media at rest = 0.90 m
Spacing of troughs c/c = 2.38 m
Width of wash water drain = 0.40 m
Depth of wash water drain = 0.95 m
J) Inlet channel
Width of inlet channel = 0.5 m
Depth of wash water drain = 0.75 m
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3. Preparation of Sand :
Natural sand may be too coarse or too fine for filtration. If filter sand is specified in ES
and US a sieve analysis of the stock sand has been made. The ―too coarse‖ and ―too
fine‖ portions to be wasted from the stock can be determined.
The percentage of usable sand, pu = 2 (P60 – P10) where P60 and P10 are the percentages
corresponding to d60 and d10.
The percentage of sand below which the stock sand is too fine to use is:
pf = P10 – 0.1Pu
= P10 – 0.2 (P60 – P10)
= 1.2 P10 – 0.2 P60
The percentage of sand above which the stock sand is too coarse to use is:
Pc = P60 + 0.4Pu
= P60 + 0.4 x 2(P60 – P10)
= 1.8 p60 – 0.8 P10
From the cumulative size frequency curve, the sizes of stock sand corresponding to P f
and above dc will have to be separated out from the stock sand to bring it to the desired
specification.
The percentage of sand which is too coarse is screened out and wasted. In practice, it
seldom pays to remove or waste more than 10% of fine sand or more than 50% of
coarse sand (nor to use sand coarser than 2mm). The percentage of sand which is too
fine can be washed out through a grit or sand washer (similar to an up flow setting
basin).
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0.75
50%
40%
30%
20%
0.28
10%
0.3
0%
0.1 1
Particle sioze (mm)
Figure A. 0-12: Stocked Sand Analysis
The following formula (by Hazen) for 75% removal of particles by washing related the
washing rate to particle size removed:
( )
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As a thumb rule, the limits of size of filter sans may be assumed as:
Rapid Sand Filter : ES = 0.35 - 0.5mm
UC = 1.3 - 1.7
Standard British Sieve numbers and sizes between
16 (1.003 mm) and 52 (0.295 mm)
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The filterability depends on the characteristics of the turbidity in the raw water and the
coagulant added. In Sri Lanka, the coagulants, which may be used, are locally produced ferric
chloride and imported aluminium sulphate. Polymers, while very effective, are also imported
and are not very practical for this country because of their high cost.
The first step in this test is to filter the raw water with no coagulant added. This gives a good
indication of the size of the size of the turbidity particles. If the turbidity is substantially
reduced with filter paper only, then the water is a good candidate for direct filtration. The
paper used is whatman No.40. The results obtained from this paper are comparable to that of a
plant filter.
The second step is to does a series of one-litre jars with various dosages of coagulant
beginning with very low dosages and working up to higher ones. Mix these with the jar test
maxing machine. Add the close with the machine at maximum rotation. Good, quick
coagulant dispersion is essential. Apply the coagulant at a dilution of 1mg/L. For example in a
four-jar series, the first trial might be 0.5, 1.0, 1.5 and 2.0mg/L respectively in the jars. After
20 or 30 seconds of maximum rotation, it is reduced to about 40 rpm for 2 or 3 more minutes.
A sample at each jar then is filtered through the No.40 paper and turbidity read.
An example of a test on Ambalanthota water is shown in Figure A. 0-13. The raw water had a
turbidity of 25 NTU but when filtered without coagulant the turbidity was reduced to 5. This
indicated that the water was an excellent for direct filtration. Testing was continued with
polymer, FeCl3 and Al2(So4)3. The results are clear: the polymer is most effective but FeCl3 is
also very good. Alum was the least effective.
Figure A. 0-14 shows the results of a test at Matara. The results are quite difference than those
at Ambalanthota. In this case FeCl3 was not very effective while 5 to 6 mg/L of alum gave a
satisfactory result again the polymer was most effective. Here alum is the preferred coagulant.
It is important that the coagulant does be relatively low for direct filtration, high dosages of
alum or iron coagulant produce large amounts of floc which quickly clog the filter, if more
than 10 to 12mg/L is required to obtain destabilisation then it is doubtful that direct filtration
is possible.
Once the filter paper test is completed and the results analysed, the next step is to further test
with a pilot filter. This would be those cases where there is a good possibility of success with
direct filtration, in Galle, Matara, Ambalanthota, Kandy, Kegalle and Kurunagala.
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Note:
(i) Always use fresh bleaching powder. Preferably, within a week from the date the
sealed drum is opened. The chlorine content in bleaching powder (strength) drops
very rapidly with time. 9fresh bleaching powder contains 25 to 37% chlorine content.
(ii) Quantity of bleaching powder and/or dosage rate of solution will need to be increased
according to its life and strength, controlled by the test results or residual chlorine
after 30 minutes contact period.
(iii) If there is no equipment to measure the residual chlorine readily available, the dosage
rate should be such that there is a slight but distinctly detectable smell of chlorine in
the water after the 30-minute contact period.
b) Usually 1-2% solution of available chlorine is used for drip-feeding purposes. Some of
the NWS & DB scheme use up to 5% strength, depending on the size of the scheme.
c) Estimate the daily requirement of bleaching powder at about 2-ppm dosage rate or
more to begin with and dissolve this quantity in water to get a concentrated solution of
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d) Allow this solution to stand for about one hour to let the white lime particles settle
down. Decant the slightly milky solution gently into another container or it may be
used directly in the drip feeder. If the solution is used after, less than an hour of settling
further settlement of fine powders can accumulate in the feeder in the form of sludge.
To prevent clogging of the feeder in the form of sludge. To prevent clogging of the
feeder, frequent cleaning is advisable.
e) The choice of the type of feeder will depend on the availability suitability and
convenience of operation for each system (see the example attached)
f) The point applicant of the chlorine solution should be such that it will have a chance of
being thoroughly mixed into the water supply and have a contact time of 30 minutes
before it reaches the first consumer. If such a situation is not possible, the consumers
concerned should be warned to consume water only after a strong of 30 minutes or
more and should be ready to accept the use of water with higher dosed of chlorine.
g) The amount of the 1% chlorine solution used should be adjusted to such a rate that
there is at least 0.3-ppm residual chlorine at the end of the distribution system. Make
sure that there is a slight but distinctly noticeable smell of chlorine at that point if there
is no means of means of measuring the ppm content.
h) At the initial stage, it may not be possible to achieve this situation even with 10 times
increased dosage rates, but this situation will improve if the maximum tolerable rate of
dosage is kept up.
Warning
Handle bleaching powder and the 1% chlorine solution with great care.
It irritates sensitive areas of skin. Use rubber gloves where necessary. It is highly
corrosive to metals. It will bleach coloured clothing white. Rinse thoroughly with
water if affected.
Table A. 0-6 shows bleaching powder and water requirements to make 1% chlorine
solutions at a dosage rate of 2 ppm for different rates of water supply in gallons per
unit time (per hour or per day)
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The central 3mm-O.D tube with a nylon string passing through it serves to position the bowl
in the centre of the basin and to avoid the risk of its tipping over. Placing stones in the bowl
helps to keep it upright.
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While glass tubing, 3mm and 6mm outer diameter (0.D), can be obtained from dealers in
medical and laboratory supplies, ballpoint pen casing could also serve the purpose.
The two tubes on either side of the central guide-tube can be moved by sliding to a desired
height above the rubber bung. The rate of drip feed is controlled by the difference in height
―H‖ between the outlets of the 3mm – outer diameter tube and the level of the liquid in the
basin. The outlet of this tube may be narrowed down, if necessary, to reduce the rate of flow
of the solution of the solution to convenient levels.
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Construction
Any suitable, can or bucket made of plastic or non-corrodible material is satisfactory. Other
components should also be of non-corrodible material while the tube inside the container
needs to be very flexible, the outlet tube may be of a sturdier material. Styrofoam, certain
packing materials or even certain types of soft wood can be used for the float (certain
materials may, however decompose in a short time).
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The following design parameters are adapted to calculate the residuals quantity from
sedimentation process.
( )
= 21.58 kg/d
= 10.33 kg/d
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( )
= 65.37 kg/d
= 3.59 kg/d
= 80.62 kg/d
Because of many uncertainties associated with raw water quality, chemical dosage, and
the amount of bound water, it is common practice to increase this value by 20-60 percent. By
increasing this quantity by 40%, the total sludge solids production is adjusted to 786.0 kg/d
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= 34.95 m3/d
= 43.87 kg/1000 m3
It has been reported in the literature that total solid from an alum coagulation facility may be
8-200 kg per 1000 m3 of raw water treated
Thickener Design
= 8.84 m2
= 3.95 m3/m2d
This satisfies the minimum hydraulic loading of 4 m3/m2d
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The total side water depth of the gravity thickener is composed of three separate items;
the clear water zone, the settling zone, and thickening zone. Generally, in a gravity thickener,
a clear water zone of 1.0 m, and settling zone of 1.5 m and thickening zone of 3.0 m are
considered sufficient.
Total side water depth = 1.0+1.5+3.0 = 5.5 m
A free board of 0.6 m is also provided.
h. Compute the depth of central hopper
The bottom of the thicker is sloped at 20 cm/m
The depth of the hopper = 20 cm/100 cm × 3.35 /2 = 0.33 m
Total water depth = 5.5+0.33 = 5.83 m
(This satisfy the typical value between 4.5 -6.5 m)
i. Design of influent and effluent structure.
The influent and effluent structure of the thickener consists of a central well and 90°- V
notch weirs around the peripheral.
4. Thickening Period
The volume of the thickener is as follows
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T γ ρ μ ν σ E Pv
(×10−6
(◦C) (kN/m3) (kg/m3) (×10−3 kg/m·s) (N/m) (×109 N/m2) (kN/m2)
m2/s)
0 9.805 999.8 1.781 1.785 0.0765 1.98 0.61
5 9.807 1000 1.518 1.519 0.0749 2.05 0.87
10 9.804 999.7 1.307 1.306 0.0742 2.1 1.23
15 9.798 999.1 1.139 1.139 0.0735 2.15 1.7
20 9.789 998.2 1.002 1.003 0.0728 2.17 2.34
25 9.777 997 0.89 0.893 0.072 2.22 3.17
30 9.764 995.7 0.798 0.8 0.0712 2.25 4.24
40 9.73 992.2 0.653 0.658 0.0696 2.28 7.38
50 9.689 988 0.547 0.553 0.0679 2.29 12.33
60 9.642 983.2 0.466 0.474 0.0662 2.28 19.92
70 9.589 977.8 0.404 0.413 0.0644 2.25 31.16
80 9.53 971.8 0.354 0.364 0.0626 2.2 47.34
90 9.466 965.3 0.315 0.326 0.0608 2.14 70.1
100 9.399 958.4 0.282 0.294 0.0589 2.07 101.33
a At atmospheric pressure.
b In contact with the air.
Source: Water Treatment Principles and Designs – Third Edition, John C. Crittenden , R. Rhodes, David
W. Hand, J. Howe, George Tchobanoglous,
With Contributions By: James H. Borchardt P.E., Table c 2, page 1862
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Annex – J
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Glossary
The terms used throughout this Manual are defined as follows:
Term Definition
Coagulation The process in which chemicals are added to water, causing a reduction of the forces tending
to keep particles apart. Particles in source water are in a stable condition and the purpose of
coagulation will destabilize particles and enable them to become attached to other particles so
that they may be removed in settling processes. Particulates in source waters that contribute to
color and turbidity are mainly clays, silts, viruses, bacteria, fulvic and humic acids, minerals
(including asbestos, silicates, silica, and radioactive particles), and organic particulates. At pH
levels above 4.0, particles or molecules are generally negatively charged. The coagulation
process physically occurs in a rapid mixing process.
Coagulant The inorganic or organic chemicals that, when added to water at an optimum dosage, cause
chemicals particle destabilization. Most coagulants are cationic when dissolved in water and include
chemicals such as alum, ferric salts, lime, and cationic organic polymers.
Direct filtration The treatment train that includes coagulation, flocculation, and filtration, but excludes a
separate sedimentation process. With direct filtration, all suspended solids are removed by
filtration. In the process sometimes called in-line filtration, flocculation occurs in the conduit
between the rapid mixing stage and the filter, in the volume above the filter media, and within
the filter media.
Enhanced A phrase used by the USEPA in the Disinfectants and Disinfection By-products Rule. The
coagulation rule requires that the coagulation process of some water supplies be operated to remove a
specified percentage of organic material from the source water, as measured by total organic
carbon (TOC). Enhanced coagulation (removal of TOC) can be achieved in most cases by
either increasing coagulant chemical dosage or adjusting the pH during the coagulation
reaction.
Flocculation The agglomeration of small particles and colloids to form settleable or filterable particles
(flocs). Flocculation begins immediately after destabilization in the zone of decaying mixing
energy following rapid mixing, or as a result of the turbulence of transporting flow. In some
instances, this incidental flocculation may be an adequate flocculation process. A separate
flocculation process is most often included in the treatment train to enhance contact of
destabilized particles and to build floc particles of optimum size, density, and strength.
Flocculation Chemicals used to assist in forming larger, denser particles that can be more easily removed
aids by sedimentation or filtration. Cationic, anionic, or non-ionic polymers are most often used in
dosages of less than 1.0 mg/L.
Flow Diagram A systematic representation of the sequence of steps or operations used in the production or
manufacture of a particular water item.
Hazard A biological, chemical, physical or radiological agent in, or condition of water, with the
potential to cause an adverse health effect. Another word for hazard includes ―contaminant‖.
Low-pressure The hollow-fiber membrane systems that provide micro- or ultrafiltration. These systems have
membranes pore sizes that are 10 to 100 times smaller than those of primary protozoa of concern (i.e.,
Cryptosporidium and Giardia lamblia). The membrane is a thin layer of polymer capable of
separating materials based on size and chemical properties. These membrane systems
typically operate in the range of - 83 kPa vacuum to 276 kPa pressure.
Mixing Commonly referred to as flash mixing, rapid mixing, or initial mixing. The purpose of rapid
mixing is to provide a uniform dispersion of coagulant chemical throughout the influent water.
Monitor The act of conducting a planned sequence of observations or measurements of control
parameters to assess whether a control point is under control or whether the water meets
quality criteria.
Risk For the purposes of this Manual, risk assessment has the same meaning as hazard analysis.
Assessment
Solids contact The proprietary devices that combine rapid mixing, flocculation, and sedimentation in one
clarifiers unit. These units provide separate coagulation and flocculation zones and are designed to
cause contact between newly formed floc and settled solids.
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