Polyethylene oxide

Aqueous solution properties of polyethylene oxide–block-polypropylene oxide–block-polyethylene oxide TBP [(PEO)103(PPO)39(PEO)103] were studied in the presence of sodium salts with different anions (NaI, NaBr, NaCl, NaF, Na2SO4, Na3PO4) to investigate unimer-to-micelle transition [critical micelle concentration (CMC), critical micellization temperature (CMT)], micelle size and the phase separation (cloud point). This TBP, due to its very hydrophilic (80% PEO) nature does not form micelles at ambient temperatures. Micellization can be induced much below its CMT in water on addition of sodium salts having different anions. Analytical methods viz. fluorescence, FTIR and dynamic light scattering (DLS) were used to monitor the salt-induced micellization. The hydration of respective anion and resultant contribution to its salting-out effect was found to be the governing factor in promoting micellization. The presence of salt decreases the CMC, CMT and phase separation temperature. The salts affect the aggregation process in agreement with an order mentioned in Hofmeister series.

This parametric study links the molecular structure of a carboxylate-type of superplasticizer with their performance in cement pastes with different C3A-contents. Beside the variation of the C3A-content, the experimental synthesized superplasticizers have been varied by polyethylene-oxide side chain density and length. The connection between the superplasticizers, their effect on workability properties and retardation phenomenon and the dependency of C3A-content in the cement paste has been investigated.The characteristic interaction phenomenons between different PCE-architectures and different C3A-contents have been examined by calorimetric, rheological, adsorption, and zeta potential measurements. This study shows that with decreasing side chain density the PCE molecules adsorb stronger and thus, lower the yield stress of a cement paste by steric stabilization. It is also shown that PCE molecules with long side chains delaying the setting of the cement paste to less extend than PCE molecules with shorter side chains. Consequently, in terms of optimization of the molecular architecture, good workability can be achieved by addition of highly charged PCE with long side chains. The latter minimizes undesired retardation phenomena.

In this paper, a mathematical model is developed to study the performance of a parabolic trough collector (PTC). The proposed model consists of three parts. The first part is a solar radiation model that used to estimate the amount of solar radiation incident upon Earth by using equations and relationships between the sun and the Earth. The second part is the optical model; This part has the ability to determine the optical efficiency of PTC throughout the daytime. The last part is the thermal model. The aim of this part is to estimate the amount of energy collected by different types of fluids and capable to calculate the heat losses, thermal efficiency and the outlet temperature of fluid. All heat balance equations and heat transfer mechanisms: conduction, convection, and radiation, have been incorporated. The proposed model is implemented in MATLAB. A new nanofluids like Water+PEO+1%CNT, PEO+1%CNT and PEO+0.2%CUO where tested and were compared with conventional water and molten salt during the winter and the summer to the city of Basra and good results were obtained in improving the performance of the solar collector. The results explained both the design and environmental parameters that effect on the performance of PTC. Percentage of improvement in the thermal efficiency at the summer when using nanofluids (Water+PEO+1%CNT, PEO+1%CNT and PEO+0.2%CUO) Nano fluids are (19.68%, 17.47% and 15.1%) respectively compared to the water and (10.98%, 8.93% and 6.7%) respectively compared to the molten salt, as well as the percentage decreases in the heat losses by using the Nano fluids through the vacuum space between the receiver tube and the glass envelope compared with water (86 %, 76 % and 66 %) and molten salt (79.15 %, 64.34 % and 48.47 % ) . As final a Water+PEO+1%CNT nanofluid gives the best performance

The aim of this study was to characterize the delivery of diclofenac sodium from hydrophilic, swellable polyethylene oxide matrix tablets. Matrix tablets can be manufactured relatively simple, e.g. by direct compression. Mathematical modeling has been employed to describe the process of drug diffusion from the polyethylene matrix coupled to the process of polymer dissolution.

... 3D printing offers several unique built strategies for obtaining zero order release kinetics. Different diffusion gradients may be printed at any location within the device, either by changing the binder composition or by varying the microstructure of the diffusion barriers. ...

The microphase structure of a series of polystyrene-b-polyethylene oxide-b-polystyrene (SEOS) triblock copolymers with different compositions and molecular weights has been studied by solid-state NMR, DSC, wide and small angle X-ray scattering (WAXS and SAXS). WAXS and DSC measurements were used to detect the presence of crystalline domains of polyethylene-oxide (PEO) blocks at room temperature as a function of the copolymer chemical composition. Furthermore, DSC experiments allowed the determination of the melting temperatures of the crystalline part of the PEO blocks. SAXS measurements, performed above and below the melting temperature of the PEO blocks, revealed the formation of periodic structures, but the absence or the weakness of high order reflections peaks did not allow a clear assessment of the morphological structure of the copolymers. This information was inferred by combining the results obtained by SAXS and 1H NMR spin diffusion experiments, which also provided an estimation of the size of the dispersed phases of the nanostructured copolymers. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 55–64, 2010

Drilling is a most important and crucial operation in the excavation industries. With the objective of looking into the enhancement of diamond drilling performance detailed laboratory investigations were carried out on phosphate rock. The effect of Poly (Ethylene Oxide) (PEO) added to the drilling water was studied by varying machine parameters and PEO concentration. The responses were rate of penetration and torque at the bit rock interface. Slake durability tests were also performed to understand the slaking behavior of phosphate rock in PEO solutions.

The electro-spinning process and morphology of electro spun nanofibers depend on many processing parameters. These parameters can be divided into three main groups: a) solution properties, b) processing conditions, c) ambient conditions. In this paper, we report the results of a comprehensive investigation of the effects of changing the conductivity of poly ethylene oxide (PEO) water solution on electro-spinning process and fiber morphology. The effects of the conductivity of PEO solution on jet current and jet path are discussed. Furthermore, fiber diameter and fiber uniformity are investigated by using scanning electron microscopy (SEM) techniques. It was found that the fiber diameter decreases with increasing solution conductivity at first, reaches a minimum value and it increases again.

In this paper, a mathematical model is developed to study the performance of a parabolic trough collector (PTC). The proposed model consists of three parts. The first part is a solar radiation model that used to estimate the amount of solar radiation incident upon Earth by using equations and relationships between the sun and the Earth. The second part is the optical model; This part has the ability to determine the optical efficiency of PTC throughout the daytime. The last part is the thermal model. The aim of this part is to estimate the amount of energy collected by different types of fluids and capable to calculate the heat losses, thermal efficiency and the outlet temperature of fluid. All heat balance equations and heat transfer mechanisms: conduction, convection, and radiation, have been incorporated. The proposed model is implemented in MATLAB. A new nanofluids like Water+PEO+1%CNT, PEO+1%CNT and PEO+0.2%CUO where tested and were compared with conventional water and molten salt during the winter and the summer to the city of Basra and good results were obtained in improving the performance of the solar collector. The results explained both the design and environmental parameters that effect on the performance of PTC. Percentage of improvement in the thermal efficiency at the summer when using nanofluids (Water+PEO+1%CNT, PEO+1%CNT and PEO+0.2%CUO) Nano fluids are (19.68%, 17.47% and 15.1%) respectively compared to the water and (10.98%, 8.93% and 6.7%) respectively compared to the molten salt, as well as the percentage decreases in the heat losses by using the Nano fluids through the vacuum space between the receiver tube and the glass envelope compared with water (86 %, 76 % and 66 %) and molten salt (79.15 %, 64.34 % and 48.47 % ) . As final a Water+PEO+1%CNT nanofluid gives the best performance

This study quantifies degradation of polyethylene oxide (PEO) and polyacrylamide (PAM) polymer solutions in large diameter (2.72 cm) turbulent pipe flow at Reynolds numbers to 3 × 105 and shear rates greater than 105 1/s. The present results support a universal scaling law for polymer chain scission reported by Vanapalli et al. (2006) that predicts the maximum chain drag force to be proportional to Re 3/2, validating this scaling law at higher Reynolds numbers than prior studies. Use of this scaling gives estimated backbone bond strengths from PEO and PAM of 3.2 and 3.8 nN, respectively. Additionally, with the use of synthetic seawater as a solvent the onset of drag reduction occurred at higher shear rates relative to the pure water solvent solutions, but had little influence on the extent of degradation at higher shear rates. These results are significant for large diameter pipe flow applications that use polymers to reduce drag.

In this study, the ionic conductivity of a nanocomposite polymer electrolyte system (PEO-LiPF6-EC-CNT), which has been produced using solution cast technique, is obtained using artificial neural networks approach. Several results have been recorded from experiments in preparation for the training and testing of the network. In the experiments, polyethylene oxide (PEO), lithium hexafluorophosphate (LiPF6), ethylene carbonate (EC) and carbon nanotubes (CNT) are mixed at various ratios to obtain the highest ionic conductivity. The effects of chemical composition and temperature on the ionic conductivity of the polymer electrolyte system are investigated. Electrical tests reveal that the ionic conductivity of the polymer electrolyte system varies with different chemical compositions and temperatures. In neural networks training, different chemical compositions and temperatures are used as inputs and the ionic conductivities of the resultant polymer electrolytes are used as outputs. The experimental data is used to check the system's accuracy following the training process. The neural network is found to be successful for the prediction of ionic conductivity of nanocomposite polymer electrolyte system.

We investigate the dynamics of the capillary thinning and break-up process for low viscosity elastic fluids such as dilute polymer solutions. Standard measurements of the evolution of the midpoint diameter of the necking fluid filament are augmented by high speed digital video images of the break up dynamics. We show that the successful operation of a capillary thinning device is

Hollow-fiber membranes were prepared by the dry/wet spinning technique from polyvinylidene fluoride (PVDF) dope solutions containing the solvent N, N-dimethylacetamide and the non-solvent additive 1,2-ethanediol. Ethanol aqueous solution, 50% by volume, was used as internal and external coagulants. The effect of the non-solvent additive concentration on the morphological properties of the hollow fibers was studied in terms of atomic force microscopy (AFM) and scanning electron microscopy (SEM). The pore size, the nodule size and the roughness parameters at the inner and outer surfaces of the hollow fibers were studied by AFM. The liquid entry pressure of water (LEPw) and the porosity of the hollow fibers were evaluated. The pore size was also determined by the gas permeation test and by the solute transport using ultrafiltration of polyethylene glycol (PEG) and polyethylene oxides (PEO). A comparative study was made between the membrane characteristics parameters obtained from the different characterization techniques.