Entropy Effects in Intermolecular Associations of Crown-Ethers and Cyclodextrins with Amino Acids in Aqueous and in Non-Aqueous Media
Abstract
:1. Introduction
2. Results and Discussion
2.1. Thermodynamic Enthalpy–Entropy Compensation Effect in the Complexation of Cyclodextrins with Amino Acids in Water
2.2. Thermodynamic Enthalpy–Entropy Compensation Effect in the Complexation of Crown Ethers in Water and in Water-Organic Solvents
2.3. Entropy Characteristics of Reagents and Reactions of Formation of Complexes of Amino Acids and Peptides with 18-Crown-6 in Aqueous Organic Solvents
2.4. Thermodynamic Enthalpy–Entropy Compensation Effect in the Complexation of Cyclodextrins and 18-Crown-6 with Amino Acids in Water
3. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Usacheva, T.; Terekhova, I.; Alister, D.; Agafonov, M.; Kuranova, N.; Tyurin, D.; Sharnin, V. Entropy Effects in Intermolecular Associations of Crown-Ethers and Cyclodextrins with Amino Acids in Aqueous and in Non-Aqueous Media. Entropy 2022, 24, 24. https://doi.org/10.3390/e24010024
Usacheva T, Terekhova I, Alister D, Agafonov M, Kuranova N, Tyurin D, Sharnin V. Entropy Effects in Intermolecular Associations of Crown-Ethers and Cyclodextrins with Amino Acids in Aqueous and in Non-Aqueous Media. Entropy. 2022; 24(1):24. https://doi.org/10.3390/e24010024
Chicago/Turabian StyleUsacheva, Tatyana, Irina Terekhova, Diana Alister, Mikhail Agafonov, Natalya Kuranova, Dmitry Tyurin, and Valentin Sharnin. 2022. "Entropy Effects in Intermolecular Associations of Crown-Ethers and Cyclodextrins with Amino Acids in Aqueous and in Non-Aqueous Media" Entropy 24, no. 1: 24. https://doi.org/10.3390/e24010024