We present results of the energies of formation and hydration of small clusters and rings containing Si and Al; the results provide a rationalisation of Lowenstein's rule in terms of the energetics of species containing Al–O–Al bridges.
C. R. A. Catlow, A. R. George and C. M. Freeman, Chem. Commun., 1996, 1311 DOI: 10.1039/CC9960001311
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