Abstract
Spin-transfer torque magnetoresistive random access memory (STT-MRAM) is a non-volatile memory technology with a unique combination of speed, endurance, density and ease of fabrication, which has enabled it to recently replace embedded Flash as the embedded non-volatile memory of choice for advanced applications, including automotive microcontroller units. In this Review, we describe the working principles of STT-MRAM, and provide a brief history of its development. We then discuss the requirements, product status and outlook for four key STT-MRAM applications: stand-alone, embedded non-volatile memory, non-volatile working memory and last-level cache. Finally, we review potential future directions beyond STT-MRAM, including spin–orbit torque MRAM (SOT-MRAM) and voltage control of magnetic anisotropy MRAM (VCMA-MRAM), with an emphasis on their technological potential.
Key points
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All advanced foundries now offer embedded spin-transfer torque magnetoresistive random access memory (STT-MRAM) as a replacement for embedded Flash below the 28 nm node, where embedded Flash does not exist.
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Embedded STT-MRAM is planned to be used in the next generation of automotive microcontroller units.
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In the near term, STT-MRAM is being developed for use as a non-volatile working memory for ultra-low-power, low-performance edge and Internet of Things applications, replacing both eFlash and SRAM.
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Longer term, STT-MRAM research is focused on reducing the write current to enable last-level cache.
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Areas of research to improve MRAM beyond STT include spin–orbit torque and voltage control of magnetic anisotropy.
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Introduction
Spin-transfer torque magnetoresistive random access memory (STT-MRAM) is an emerging memory technology that stores information in a magnetic tunnel junction (MTJ)1. STT-MRAM provides a unique combination of non-volatility, high write endurance and high speed. Furthermore, this technology can be easily integrated into a standard semiconductor back-end-of-line process flow, enabling a wide range of applications.
STT-MRAM has a long history in research and development since the invention of the MTJ in the 1970s (refs. 2,3) (see Box 1). An earlier version of magnetic field-switched MRAM, Toggle MRAM4, was successfully commercialized but has a limited market, due to the lack of scalability and high cost. Despite promising research results, until recently it was not clear whether STT-MRAM would be a commercial success. However, in recent years, STT-MRAM has replaced embedded Flash as an embedded non-volatile memory (eNVM), laying a solid foundation for the future of STT-MRAM technology.
Samsung started selling its first embedded STT-MRAM (eMRAM) products in 2019. All advanced semiconductor foundries, including TSMC, GlobalFoundries and Samsung, have announced their plans to replace embedded Flash with eMRAM beyond the 28 nm node, to reduce cost and complexity. eMRAM is poised to make a major impact on the world, for example, in automotive microcontroller units, driven by the adoption of hybrid, electric and self-driving vehicles. Having emerged from research and development into manufacturing, this use of STT-MRAM as eNVM is expected to grow steadily as new microcontroller unit circuit designs are migrated to advanced nodes in the next few years. Furthermore, a wide range of research directions promise even more advanced applications in the future, such as non-volatile working memory and last-level cache.
In this Review, we elaborate on the basic device physics behind STT-MRAM operation and review the history of its development. We discuss the different types of STT-MRAM applications, as well as current products and near-term directions towards more advanced STT-MRAM. Finally, we summarize the latest research trends and potential future directions, with a critical eye for those topics most likely to be of practical use.
STT-MRAM operation
STT-MRAM stores information in the magnetization direction of a free layer in an MTJ (Fig. 1a). The information is read out using the magnetoresistance of the tunnel junction, with the resistance of the junction being several times higher when the free and reference layer magnetizations are antiparallel compared with parallel (Fig. 1b). Reading is performed at a lower voltage than that used for writing, because stochastic read disturb errors can occur if the read voltage is too high. Information is written to the junction via STT (Box 2), by driving an electric current either up or down through the junction, to write ‘1’ or ‘0’. The electrons are spin-polarized by the reference layer, and as they traverse the tunnel barrier, spin angular momentum is transferred to the free layer, causing its magnetization to switch to the reverse direction5. Data retention is ensured by an energy barrier, Eb (Fig. 1c), separating the parallel and antiparallel states, created by perpendicular magnetic anisotropy (Box 3). Accurately measuring Eb requires bake retention measurements on arrays of bits at elevated temperatures6. Retaining data at higher temperatures requires higher Eb, which in turn increases the switching current (Fig. 1d).
STT switching is thermally activated for long write pulses at lower currents, where the effective Eb is partly reduced (Fig. 1e). At short write pulses with larger currents, where the effective Eb is reduced to zero, the switching current is inversely proportional to the pulse length, due to conservation of angular momentum7. In this Review, we use the single-domain model for approximating switching currents and activation energies. The threshold switching current, Ic0, is defined as the thermally activated write current extrapolated back to the thermal activation attempt time τ0 = 1 ns. All bits have an intrinsic write-error rate, caused by the STT vanishing when the free and reference layers are parallel or antiparallel (Box 2). Therefore, a sufficiently large thermal fluctuation is required to initiate every write. Hence, bits must be engineered carefully to achieve steep write-error rate slopes free of anomalies (Fig. 1f). Accurately evaluating the write-error rate requires measuring down to an error floor of 10–6 errors per write or below, ideally on hundreds of junctions. Data reported on a linear scale instead of a logarithmic scale are not sufficient to evaluate the write-error rate. Both the write-error rate slope (the slope of the curve in Fig. 1f) and bit-to-bit distributions (the variation in switching current from bit to bit) determine Iwrite, the current which will reliably write all the bits in the memory (Fig. 1f). Write endurance is limited by MgO tunnel barrier reliability; although there is no magnetic wear-out mechanism, the write voltage across the MgO barrier can move oxygen ions over time within the barrier and into the neighbouring metal layers, reducing the MgO, leading to shorted bits. Endurance is evaluated using time-dependent dielectric breakdown measurements on arrays of devices at high write voltage to accelerate the failure mechanism8. Measurements of individual bits surviving 1010 write pulses are not sufficient to evaluate endurance.
Each memory cell contains one MTJ and one access transistor, which is used to select the junction for reading and writing (Fig. 2a). STT-MRAM contains an array of junctions, with the word lines orthogonal to the bit lines, to allow selection of a single bit at the intersection of the selected word and bit lines (Fig. 2b). The read or write current is returned through source lines, which can be oriented parallel to either the bit lines (to maintain constant bit line plus source line resistance for all bits in the array, with the source line on the same metal level as the bit line) or word lines (for maximum density) (Fig. 2b,c). Cell density (Fig. 2d) is a critical consideration for STT-MRAM technology. Today’s STT-MRAM cell area is not limited by the size of the MTJ but, rather, by the size of the access transistor (Fig. 2c), which must be designed to be large enough to deliver the required write current. Hence, reducing the switching current, Ic, is critical for advanced MRAM. With the current progress in transistor scaling, the STT-MRAM cell size can be reduced by moving to a more advanced technology node, because more advanced transistors can deliver the required current in a smaller area. For example, as Everspin’s products moved from the 40 nm to 28 nm node, the cell area was reduced from 0.156 µm2 to 0.041 µm2. Most of this approximately four times area decrease is due to improved transistor performance. In addition to the array, the STT-MRAM macro contains significant peripheral circuitry (Fig. 2e), including many sense amplifiers enabling reading of the small read signals.
Applications
STT-MRAM applications can be divided into four broad categories: stand-alone, eNVM, non-volatile working memory and last-level cache. Stand-alone memory is a general-purpose memory chip that contains only memory, whereas embedded memory means that the STT-MRAM is fabricated on a custom-designed chip along with logic and, potentially, other functions (such as wireless communications, analogue circuitry and sensors) at a foundry. Non-volatile working memory and last-level cache are also examples of embedded applications.
Regardless of the type of application, common STT-MRAM technology challenges, associated, for example, with MTJ deposition and ion beam etching, must be addressed. The deposition tool vendors Applied Materials, TEL, Canon-Anelva and Singulus have overcome numerous fundamental product challenges to enable reliable deposition of the MTJ9,10,11. Maintaining stability of the resistance–area product of the MgO tunnel barrier in the deposition process is challenging, and even small fluctuations of a few per cent from run to run can reduce manufacturing yields. MgO deposited by depositing magnesium metal followed by oxidation in an O2 ambient tends to produce a more stable resistance–area product and fewer particles than MgO deposited by radio-frequency sputtering. However, radio-frequency sputtering tends to give higher magnetoresistance and tighter resistance distributions from bit to bit. Further progress in both methods will be important for future products. The target purity requirements for some materials have pushed vendors to develop high purity targets, with purity of MgO reaching 99.9999%.
High deposition throughput has always been challenging for MRAM stacks, due to multiple individual layers (Fig. 1a). Moreover, some of the deposition steps involve cryo-cooling to obtain smoother layers or heating to improve crystalline quality, both of which take additional time to reach the deposition temperature, and in some cases return to room temperature for subsequent layers11. Typical deposition throughput, lower than five wafers per hour, is still low compared with standard complementary metal oxide semiconductor (CMOS) process steps. A related challenge is to arrange the targets and chambers so that the wafer does not pass through the same chamber twice, a basic contamination requirement in modern semiconductor fabrication. This typically involves the use of two chambers with MgO targets, one for the MgO barrier and the other for the MgO cap; each chamber may have multiple MgO targets to increase throughput, especially important due to the very low sputter rate of MgO, <0.01 nm s–1 for a single target.
For years, etching MTJs was a major roadblock to advanced products. Reactive ion etching of cobalt, iron and many other elements in the complex MTJ stack is difficult, due to the challenge of forming volatile etch products without chemically attacking the remaining junction material12. The most successful reactive ion etching system, methanol, oxidizes the edges of the MTJs and so cannot be used in junctions with diameters below about 100 nm. This edge damage shows up as an increase of device resistance–area product and switching voltage at smaller diameter. In well-prepared junctions, both should be constant with the device diameter. Ion beam etching has been developed as an effective solution for MTJ etching in advanced MRAM, and is universally used in advanced products. Here the cobalt, iron and other hard to etch materials are physically sputtered away using argon instead of chemically aggressive etch gases. Care must be taken to avoid redeposition of this material on the sidewall of the tunnel junction, where it can cause an electrical short if it bridges the MgO tunnel barrier. Typically, a sequence of high-angle (near-normal) etches to remove material in the field and low-angle etches to remove redeposited material on the junction sidewall are used to achieve short rates of less than 1 bit per million. LAM13 and Canon-Anelva14 offer 300 mm ion beam etch tools, using ion beam etch technology acquired from Veeco and Nordiko, respectively.
Stand-alone applications
Today, two companies offer stand-alone STT-MRAM products: Everspin and Avalanche. Everspin started selling the first STT-MRAM product, a 256 Mb, 40 nm node DDR3 chip, in 2017 (ref. 15), and a 1 Gb, 28 nm node DDR4 chip in 2019 with a 220 nm × 180 nm memory cell16,17, both manufactured by GlobalFoundries. The specifications of the 1 Gb chip are shown in Table 1. Data retention of 3 months at 70 °C is sufficient for normally-on data centre applications (disaster recovery efforts typically conclude within 3 months, if the data are not destroyed in the disaster). Recently, Everspin started selling 8–64 Mb xSPI STT-MRAM chips with more than 1014 write endurance and magnetic field immunity during read/write of 300 Oe (ref. 18). The higher endurance is achieved by greatly reducing the bit density; the total number of bits on the die is increased by roughly ten times over the nominal bit count, and presumably a combination of error correction code and active redundancy is used to handle endurance fails. Also, the resistance–area product of the tunnel barrier is reduced to increase the window between writing and breakdown, and the resulting increase in time-zero shorts is handled by the increase in redundancy19. The xSPI chips offer 10-year data retention, at temperatures up to 105 °C. These chips serve as a high-performance replacement for stand-alone NOR Flash, offering 500–1,000 times faster write, 10,000 times lower energy write and 10–100 times higher endurance18. Avalanche introduced their highest capacity 32 Mb, 40 nm node chip in 2021, using a 324 nm × 204 nm memory cell with 1014 write endurance, 10-year data retention and magnetic field immunity during read/write of 350 Oe (ref. 17). This chip also serves as a NOR Flash replacement, is manufactured by Sony and is also sold under the Renesas brand. Here, the high endurance is also achieved by greatly reducing the bit density.
In general, stand-alone STT-MRAM represents a small market today, due to the low bit density of STT-MRAM. For example, as of October 2023, the largest capacity commercially available stand-alone STT-MRAM is Everspin’s 1 Gb (priced around US$100), compared with 128 Gb for DRAM (around US$75) and 2 Tb for NAND Flash (around US$80; prices from www.digikey.com in October 2023), making STT-MRAM 128 times lower capacity than DRAM and 2,000 times lower capacity than NAND Flash at the package level (the DRAM and NAND Flash packages contain multiple die). For most stand-alone applications, the other advantages of STT-MRAMs — such as non-volatility compared with DRAM, or more than 104 times faster write speed and more than 106 times higher write endurance compared with NAND Flash — are not enough to justify the use of STT-MRAM at the system level. However, IBM used Everspin’s 1 Gb STT-MRAM chips in the IBM FlashCore Module, an enterprise-grade solid-state drive, to provide high reliability. The STT-MRAM is used as a write buffer to store data as they are being encrypted and compressed, before being written to NAND Flash. If the power is interrupted, in-progress STT-MRAM writes can be completed quickly using power stored in a small number of tantalum capacitors, without the need for large-area and unreliable super-capacitors or batteries that would be required if a DRAM-based write buffer was used. Another use case is space applications, where the natural radiation hardness of the MTJ enables radiation-hard STT-MRAM20, with the use of standard radiation-hard CMOS circuit design. To this end, Avalanche proposed an 8 Gb MRAM package, composed of eight 1 Gb chips, with sufficient radiation hardness for use in low earth orbit applications, and potential use in geostationary orbit applications21.
Short-term future directions for stand-alone STT-MRAM include improving write endurance by 10–100 times (without decreasing density) to relax system wear-levelling requirements, reducing the bit error rate to enable less system-level error correction code overhead and reducing cost. Additional input/output interfaces using the same underlying MTJ technology are another potential direction, for example Everspin’s recent expansion beyond DDR4 to xSPI18, and Avalanche’s offering of serial D-QSPI and parallel interfaces. STT-MRAM with improved read schemes has also been proposed. For example, Everspin’s 256 Mb and 1 Gb STT-MRAM use a self-reference read scheme, wherein bits are read, then written to the ‘1’ state, read again and if their resistance changed, written back to the ‘0’ state. This change in resistance is used to determine the initial state. This self-reference read relaxes requirements on the magnetoresistance and distribution of resistance from bit to bit. However, it comes at the cost of a longer read cycle, higher read power, limited read endurance (limited by the write endurance) and volatility if the power is interrupted during the read cycle before the bits are written back to the ‘0’ state. In contrast, in a mid-point reference read scheme, the bits are simply read once and their resistance is compared with a reference, set near the mid-point of low and high resistances. The smaller capacity Everspin 64 Mb and Avalanche 32 Mb stand-alone chips already use a mid-point reference read, and future high-capacity chips may adopt it. Samsung demonstrated a 40 ns mid-point reference read, 160 ns write and 1014 write endurance on a 28 nm node stand-alone memory chip designed by Netsol, with initial data at the 14 nm node showing 15 ns read and plans for 50 ns write22.
Although it is unlikely that STT-MRAM will replace DRAM, owing to the continued density scaling of DRAM, multiple research and development programmes aim at developing denser stand-alone STT-MRAM. Kioxia and Hynix have had a long-standing partnership to develop a 4 Gb stand-alone STT-MRAM, using a 90 nm × 90 nm (9 F2) memory cell23. They demonstrated fewer than five errors in a write/read test of the 4 Gb chip, after redundancy repair and with 1-bit error correction code turned on. Recently, Kioxia demonstrated 14 nm diameter bits with good data retention of 10 years at 90 °C, with initial data showing 5 ns switching on individual bits, using a CoFeB/CoPt free layer24.
Western Digital recently launched a project to develop STT-MRAM for storage-class memory applications. Dense storage-class memory requires storing multiple bits per cell, which could potentially be achieved in STT-MRAM by using multiple layers of MTJs and two-terminal back-end selectors. This is a challenging approach, because the back-end selector must not limit the endurance or write speed of the STT-MRAM, which could prevent the use of selectors involving atomic motion during switching. For example, Avalanche reported initial results using a doped-HfOx selector25 with an on/off ratio of 107. Kioxia and Hynix reported STT-MRAM arrays with 4 F2 cells at 45 nm pitch and 20 nm diameter MTJs, using an arsenic-doped SiO2 back-end selector26. A single cell was written 1,000 times with a write pulse in the range 30–200 ns. A major challenge at these tight pitches is to etch away the material between the junctions without redepositing it on the sidewall of the junctions. Using ion beam etch, Western Digital demonstrated 22 nm diameter junctions on a 50 nm pitch, with electrical measurements showing that individual junctions were not shorted27.
Embedded non-volatile memory
STT-MRAM for eNVM has recently replaced embedded Flash at all advanced nodes in foundries. This type of memory, used to store code and data in microcontroller units, is ubiquitous in electronic equipment, ranging from automobiles and factory robots to appliances, and everything in between. Traditionally, embedded NOR Flash (eFlash) was used for eNVM, but it became too expensive to develop and manufacture, and so all advanced foundries developed eMRAM as an alternative starting at the 28 nm node, where they offered both eMRAM and eFlash. eFlash required expensive development of specialized floating gate transistors, in addition to the standard logic transistors, at every new node, plus the use of high voltages for writing. Manufacturing the floating gate transistors required more than 12 additional masks, with even more masks predicted at future nodes. By comparison, once the MTJ for eMRAM is developed, it can be used at any node, can be fabricated with only two or three additional masks and can be written with standard transistors and voltages. For this reason, eFlash will not be offered below the 28 nm node at any foundry, and all advanced applications will use eMRAM.
Samsung was the first to enter volume manufacturing of eMRAM, in early 2019 at the 28 nm node, demonstrating a technology operating in the range −40 °C to 125 °C, with write endurance of 106 writes, solder reflow retention at 260 °C for 90 s and magnetic field immunity during write of 550 Oe (refs. 28,29). Commercial applications include a Sony global positioning system receiver chip containing 8 Mb of eMRAM with a 190 nm × 190 nm memory cell used in smartwatches, including the Huawei GT2 (ref. 17). The ultra-low power of the STT-MRAM helps the smartwatch have a 2-week battery life, compared with a few days for previous models. Samsung demonstrated a denser 28 nm node eMRAM (13.9 Mb mm–2) for use as a frame-buffer memory in CMOS image sensor applications, a very different application to eNVM, with 1010 write endurance over the operating range −20 °C to 85 °C, and a fast write of 50 ns relative to 200 ns for eNVM for standard eFlash replacement. The trade-off is that only 1 s retention at 85 °C is needed for this application30. Sony has also demonstrated a 40 nm node eMRAM for use as a buffer memory for CMOS image sensor applications31. Samsung is now developing eMRAM for eNVM at the 14 nm node, with a focus on automotive applications32. Samsung has demonstrated more than 90% yield at the 14 nm node, with an operating temperature range of –40 °C to 125 °C and 106 write endurance, and promising results for both 160 °C operation (11 ns read, 200 ns write) and a sub-10 nm node technology32. Samsung also demonstrated 18.1 Mb mm–2 density at the 14 nm node, with an operating range of −40 °C to 150 °C (ref. 33). Although Samsung offered both eFlash and eMRAM at the 28 nm node, at the 14 nm node and below eFlash will no longer be offered, and only eMRAM will be offered. Samsung recently announced plans for eMRAM manufacturing at the 14 nm node in 2024, 8 nm in 2026, and 5 nm in 2027.
TSMC manufactures eMRAM at the 22 nm node34, using a 220 nm × 210 nm memory cell, for use in Ambiq’s Apollo4 Blue system-on-chip for low-power applications, used in the Fitbit Luxe17. Available with up to 16 Mb of eMRAM, the Apollo4 provides low-power compute for battery-powered edge devices, including controlling the sensors on the Fitbit Luxe. Renesas used TSMC’s 22 nm process to demonstrate 5.9 ns read access time at 150 °C in a 32 Mb eMRAM macro for use in microcontroller units, using a 500 ns write/verify scheme in which bits are first written with a 250 ns write pulse, then read to verify their state and then written a second time with a higher voltage 250 ns write pulse if needed35. NXP has announced that TSMC will manufacture their latest automotive microcontroller unit, the S32 automotive processor, using eMRAM at the 16 nm node36. The S32 is a substantial processor with four cores that will be used as a zonal controller to enable software-defined vehicles requiring regular over-the-air software updates. This function was not possible with eFlash, due to the long write times (~100 µs) resulting in unacceptably long software update times. With eMRAM, software updates will download in only a few seconds, due to the faster (5.5 µs) write cycle, which uses a write/verify scheme37. TSMC will not offer eFlash below the 28 nm node. In addition to eMRAM, TSMC is offering embedded RRAM at advanced nodes, as a lower cost, lower performance alternative to eMRAM. The embedded RRAM has six times lower bandwidth and ten times lower write endurance than eMRAM.
GlobalFoundries has also developed eMRAM at the 22 nm node, and does not plan to offer eFlash below the 28 nm node. GlobalFoundries demonstrated a 40 Mb, 22 nm node eMRAM macro operating in the range −40 °C to 125 °C, with 106 write endurance and 260 °C, 90 s solder reflow compatibility, plus promising results for future qualification at 150 °C (ref. 38). GlobalFoundries manufactures an ultra-low-power Sony global navigation satellite system receiver, containing 16 Mb of 22 nm node eMRAM using a 224 nm × 208 nm memory cell, for use in wearables and vehicle tracking. Using their 22 nm eMRAM technology, GlobalFoundries demonstrated 10-year standby magnetic immunity (while not reading or writing) to more than 1,500 Oe external magnetic fields39. In addition to eMRAM, GlobalFoundries is also developing eRRAM, licensed from Renesas, as a lower cost but lower endurance and lower bandwidth alternative to eMRAM at advanced nodes.
Intel demonstrated a 7.2 Mb, 22 nm node eMRAM with a 216 nm × 225 nm memory cell, 106 write endurance, 10 ns read and operation up to 105 °C (ref. 40). UMC has partnered with Avalanche to develop eMRAM at the 28 nm node.
eNVM requires several features beyond what are required for stand-alone MRAM. As the eNVM macro is fabricated on the same chip as other circuit blocks using the same process flow for the metal levels, no customization of the metal levels in the MRAM array is allowed. This means that the MTJ must fit vertically in between two standard metal levels. At advanced nodes below 14 nm this presents a challenge, so care must be taken to minimize the thickness of the MTJ stack and the metal hard mask used to etch it. One option at very advanced nodes is to skip a metal level inside the MRAM array, and have the MTJ fit vertically between, say, metal levels 1 and 3. In addition, all embedded applications also require that the MTJs are compatible with the standard CMOS back-end-of-line processing temperature of 400 °C, with exposure for at least an hour. This requirement was first satisfied in the demonstration by TDK41. Finally, in comparison with stand-alone applications, the yield requirements for embedded applications are much stricter, as the MRAM circuit is only a small fraction of the entire chip area, and potentially several other foundry technologies are also included in the same chip. Hence, all of the technologies must individually have high yields, so that the overall yield is sufficient. This places strict requirements on both time-zero fails, the fraction of bits in the array that fail when the chip is tested at the beginning of its life, and reliability fails during the lifetime of the chip. Time-zero fails are typically shorts, either due to pinholes in the MgO barrier or redeposition during ion beam etching of the junction. Foundries have improved time-zero fails to sub-parts per million levels by careful optimization of both the MgO deposition process and the junction etch process32,36,39.
The majority of eNVM applications require solder reflow retention, meaning that the eMRAM must retain data when the packaged chip is soldered to a board, typically at 260 °C for 30 s, with up to three solder attempts. Developing eMRAM that stores data for 90 s at 260 °C requires thicker free layers, larger-area junctions and larger write currents. The resulting eMRAM also reliably stores data for 10 years at temperatures around 200 °C. Solder reflow retention allows data (for example, chip ID, redundancy addresses, trim settings and program code) to be stored in the eMRAM inexpensively at wafer-level test, without the need for tracking each chip during dicing and packaging, and expensive programming at board level. When higher temperature retention is needed in a small number of bits, individual MTJs can intentionally be electrically broken down by applying ~ 2 V to permanently create a short in the MgO tunnel barrier, enabling a one-time programmable memory42.
eNVM applications require a wide operating temperature range, for example from −40 °C to 125 °C or 150 °C for automotive applications. At high temperatures, reading becomes a significant challenge due to the drop in magnetoresistance. This means that tighter resistance distributions, higher magnetoresistance and a lower temperature-dependence of magnetoresistance are required (mid-point reference read is used for eNVM applications, to provide fast read times similar to eFlash). Writing, on the other hand, is more challenging at lower temperatures because the switching voltage increases slightly faster than the breakdown voltage. However, even considering the higher Eb required for retention, writing is significantly easier than for stand-alone applications, due to greatly relaxed requirements on write endurance and write pulse width for eFlash replacement.
A large externally applied magnetic field can erase information in an STT-MRAM chip, or prevent it from being accurately read or written. Magnetic field immunity, or magnetic immunity, refers to the largest field the chip can reliably withstand. This metric is typically reported for operating conditions (active reading and writing) and is considerably higher on standby43. Despite some user concerns, magnetic immunity is not a practical limitation for almost all applications. This is because magnetic fields encountered in common situations are small and drop off rapidly with distance. For example, the magnetic field 1 mm from the tip of a magnetic screwdriver is well below 250 Oe (1 mm represents the thickness of a package separating the eMRAM chip from the screwdriver tip); the field 2 cm away from the end of a fairly large cylindrical NdFeB magnet (1 cm diameter and 4 cm long) is less than 200 Oe; and the field 1 cm away from a wire carrying 100 A is 20 Oe. Although Toggle MRAM4 has a magnetic field immunity of only 100–150 Oe, it has established itself as a highly reliable product for more than 17 years in various harsh environments in industrial, military and space applications. Recent STT-MRAM products have even higher magnetic field immunity. Although Everspin’s 256 Mb and 1 Gb parts have 25 Oe magnetic immunity, the Everspin xSPI and Avalanche parts have 300 Oe and 350 Oe active immunity, respectively. eMRAM for eNVM is offered with an active magnetic immunity of more than 300 Oe, and magnetic shielding in the package can substantially increase the immunity44,45,46. Another strategy for enhancing magnetic immunity is to develop new free layers with larger magnetic anisotropy than the typical 0.5 T used today. For example, perpendicularly magnetized Heusler alloys47 can have magnetic anisotropy of the free layer Hk > 7 T. Samsung28 and TSMC44 have already demonstrated 550 Oe active magnetic immunity, and this is expected to improve further over the next few years. However, many applications do not require high magnetic immunity. For example, for automotive applications, the eMRAM chip can be easily placed a few centimetres away from any sources of large magnetic fields and the exterior of the car. The fact that hard disk drives have been widely used for more than 60 years with typical magnetic field immunity of only 5 Oe shows that concerns over STT-MRAM magnetic field immunity are not technically substantiated.
Non-volatile working memory
Non-volatile working memory is a potential killer application for STT-MRAM where it can replace both SRAM and eFlash in embedded applications48,49,50. Initially, 5–10 ns reads and writes may be used in extremely power-sensitive, normally off applications, where performance is not critical. SRAM and eFlash are not suitable for an ultra-low-power, normally off device if data must be frequently written to the eFlash, owing to its high write energy resulting from the high voltage and long write pulses. In the case of SRAM and eFlash, on wake-up the device would need to write data into the SRAM, complete its operating task and then write data back to the eFlash before powering down. In contrast, with an eMRAM working memory, the device can simply wake up, operate and then power down, without the need for writing data back and forth between cache and storage. Furthermore, eMRAM offers greatly reduced standby power dissipation compared with SRAM, affected only by the leakage of peripheral circuitry. This type of non-volatile working memory opens entirely new types of ultra-low-power applications and devices which were not possible before. Applications may include wearables, implantables, co-processors, Internet of Things and edge devices — where low power is the dominant factor over high performance. For example, a cell phone could have a low-power eMRAM-based co-processor, which runs when the phone is in a sleep mode, in addition to its usual high-performance and power-hungry processor. The co-processor monitors various inputs, including listening for audio instructions, which can prompt it to wake up the main processor, thus greatly extending battery life.
Although no commercial non-volatile working memory is available today, the specifications are almost within reach using existing CoFeB-based materials, and initial products may be expected in the next few years. Very few data showing reliable writing at and below 10 ns have been published to date. Intel explored STT-MRAM for cache applications and demonstrated a good write-error rate curve of a single bit down to 1 × 10–4 errors per write using 10 ns write pulses51. Avalanche demonstrated initial results of array-level writing using 10 ns write pulses on a 22 nm node test vehicle fabricated at UMC52. Steep write-error rate curves on a single bit using 10 ns write pulses, down to a write-error rate floor of 10–6, were also reported53. Kioxia demonstrated 5 ns switching of a 14 nm diameter bit, with the write-error rate plotted on a linear scale24. IMEC published data on a thousand junctions written with 5 ns pulses54, with many junctions reaching the write-error rate floor of 10–4. Toshiba demonstrated reliable writing with 3 ns pulses on a single junction55 down to a write-error rate of 10–4. TDK showed an 8 Mb array written once without errors using 3 ns write pulses56, corresponding to an array-level write-error rate floor of 1.2 × 10–7. The IBM–Samsung MRAM Alliance presented reliable writing with 2 ns write pulses on hundreds of junctions57, with steep write-error rate slopes and tight bit-to-bit distributions, down to a write-error rate floor of 10–6.
Last-level cache
The most challenging goal for STT-MRAM is to make it fast and dense enough for use as last-level cache in high-performance applications, in place of SRAM. Here, last level means L3 cache, or L4 cache in some high-performance systems. eDRAM has been used as last-level cache in high-performance systems since the 90 nm node; however, the challenge of scaling the deep trench capacitor at advanced nodes has resulted in discontinuation of its use below the 14 nm node. In today’s advanced processor chips, if data cannot be found in the SRAM cache, the system must go to off-chip stand-alone DRAM to retrieve the data, a round-trip cost of roughly 50 ns. If, instead, some of the SRAM cache was replaced with eMRAM which would be twice as dense, fewer uses of the stand-alone DRAM would be required. Even at eMRAM’s read and write cycle times of 2–3 ns, slower than sub-nanosecond SRAM times, the advantage at the system level would still be significant.
Despite the stringent requirements for last-level cache (Table 1), great progress has been made over the last 5 years in demonstrating fast and highly reliable switching, as well as fast reading. Fast reading down to 4 ns has already been demonstrated51. Further improvements can be made by increasing magnetoresistance, decreasing resistance distributions and designing smaller arrays to reduce the resistor-capacitor time constant for charging read lines. As mainstream cache applications are read-intensive in nature, reading at least as fast as writing is required.
Additionally, STT-MRAM must be at least twice as dense as SRAM at the macro level. The macro is composed of the array of bits and the peripheral circuitry (Fig. 2e). STT-MRAM entails more peripheral circuitry compared with SRAM, due to the small read signal, which necessitates the use of multiple sense amplifiers. Taking this into account, the STT-MRAM cell must be at least three times denser than that of SRAM to provide the desired two times density improvement at the macro level. For that, the STT-MRAM switching current must be reduced by about two times. In addition to solving the density problem, this will also solve the write endurance problem, as reducing the write current automatically reduces the write voltage.
The IBM–Samsung MRAM Alliance has demonstrated reliable 500 ps STT-MRAM switching in a hundred junctions with tight bit-to-bit distributions down to a write-error rate of 10–6, and initial results at 250 ps (ref. 58). This was achieved using a double spin-torque MTJ that had a second reference layer above the free layer, separated by a non-magnetic, low-resistance spacer, so that the free layer received STT from both top and bottom interfaces. By doubling the torque, the switching current was reduced by a factor of two. Due to the use of a low-resistance spacer instead of a second tunnel barrier, the magnetoresistance was not diluted. Intriguingly, theory predicts that a factor of three or four reduction in switching current may be realistically possible with slightly higher spin polarization59. With further improvements in switching efficiency, activation energy and magnetoresistance, the double spin-torque MTJ may be a viable path to last-level cache.
Future directions
Spintronics devices utilizing switching mechanisms other than STT have been explored extensively for memory applications and beyond60,61,62,63,64. In this section we discuss the device and technology aspects of these approaches, targeting last-level cache applications.
Spin–orbit torque MRAM
Among the various alternative spintronics device concepts, spin–orbit torque (SOT) MRAM (Fig.3) is the most studied and mature. In an SOT-MRAM device, the MTJ is written by passing an electrical current through a metal SOT wire underneath the free layer (Fig. 3a). The magnetization of the free layer is manipulated by STT originating from the spin–orbit interactions in the adjacent SOT material65,66. The read operation is performed by passing the current through the MTJ, as in STT-MRAM.
Compared with STT-MRAM, SOT-MRAM devices are expected to show improved endurance, read disturb, switching speed and switching energy. In SOT-MRAM devices, the read and write paths are separated, so that the endurance issue of STT-MRAM, related to MgO barrier breakdown, is mitigated (Fig. 3a,b). This type of device is expected to operate at a higher speed with a larger write current, compared with STT-MRAM. The three-terminal structure also addresses the read disturb problem found in STT-MRAM, when the devices can be accidentally written during the read process.
For STT and SOT-MRAM devices, the free-layer magnetization is switched by the spin current generated from the charge (electrical) current. A key metric that determines the device switching efficiency is the charge current to spin current conversion efficiency. In an STT device, the same electrons in the charge current passing through the MTJ form the spin current; the conversion efficiency is determined by the spin polarization of the reference layer material, \({P}_{{\rm{Ref}}}\), which is no greater than 100%:
Here, \(\hbar /2e\) simply converts units from charge to spin. In an SOT device, the spin current density flowing vertically into the free layer is proportional to the charge current density flowing laterally through the SOT wire:
where \({\Theta }_{{\rm{SH}}}\) is the spin Hall ratio (also called the spin Hall angle), \({T}_{{\rm{int}}}\le 1\) is the interfacial spin transparency, which takes into account spins that are reflected or flipped at the interface between the SOT wire and the free layer, and \({\rm{\xi }}={T}_{{\rm{int}}}{\Theta }_{{\rm{SH}}}\) is the SOT efficiency. There are two factors that can increase the charge current to spin current conversion efficiency of SOT devices with respect to STT devices. First, when converting the current densities (Eq. 2) to currents, as the charge and spin currents flow through different areas, SOT devices pick up a geometric advantage of d/t, where d is the lateral dimension of the free layer and t is the thickness of the SOT wire, with d on the order of 50 nm and t on the order of 5 nm. Hence, each electron in the charge current can contribute to the spin current multiple times as it passes laterally under the free layer. Second, \({\Theta }_{{\rm{SH}}}\), and hence \(\xi \), can be larger than one, due to intrinsic band-structure effects. For example, \(\xi > 2\) was demonstrated at room temperature in the topological insulators Bi2Se3, BixSe1–x and BiSb67,68,69, and \(\xi \, > 100\) was reported at low temperature in a topological insulator bilayer70. These two effects make SOT-MRAM a promising candidate to achieve more energy-efficient switching than STT-MRAM.
However, to date there has been no clean demonstration of the superiority of SOT-MRAM over STT-MRAM in terms of switching speed or switching efficiency58. Today’s SOT devices suffer from impractical materials, large switching currents due to inefficient spin polarization direction, large memory cells due to multiple and large transistors, and processing challenges.
Large SOT efficiency has only been observed in unconventional materials, including topological insulators and two-dimensional materials, which have high resistivity and are not compatible with the standard CMOS process. Technology-related demonstrations have been limited to conventional heavy metal SOT materials, including platinum, tantalum and tungsten, where \(\xi \) is in the order of 0.1–0.4 (ref. 71).
Conventional polycrystalline SOT materials can only generate in-plane spin polarization (Fig. 3d,e), constrained by symmetry (Box 4), which limits the switching efficiency. For SOT devices with in-plane magnetized tunnel junctions (Fig. 3d), the polarization of the spin current is collinear with the magnetization of the free layer, and so the spin torque only needs to overcome the damping torque to induce switching, as in STT72,73. However, due to the in-plane magnetic anisotropy, the critical switching current is proportional to α(Hk + ½Hp), where α is the magnetic damping constant with a typical value of 0.01, Hk is the magnetic anisotropy of the free layer and Hp is the large easy-plane anisotropy field (see Box 3). For perpendicularly magnetized tunnel junctions (Fig. 3e), the polarization of the incoming spins is orthogonal to the magnetization of the free layer. As such, the spin torque must overcome the full Hk value of the free layer to induce switching. Therefore, the critical switching current is proportional to Hk, making the switching current large73. If asymmetric materials are used to generate perpendicular spin polarization (see Box 4) in perpendicularly magnetized tunnel junctions, then the polarization of the spin current is collinear with the magnetization of the free layer (Fig. 3f), and the spin torque only needs to overcome the damping torque. Hence, the switching current is proportional to αHk, resulting in efficient switching. To be technologically useful, SOT devices have to be sufficiently dense, which will likely require perpendicular spin polarization and perpendicularly magnetized tunnel junctions (Fig. 3f).
Both in-plane SOT-MRAM and STT-MRAM devices have the same disadvantages in terms of switching efficiency, density and scaling potential compared with perpendicular devices (Box 3). Due to the limitations of SOT-MRAM devices with in-plane magnetization, perpendicular SOT devices have been studied extensively, despite the large switching current needed to overcome the full Hk value of the free layer. For perpendicular SOT devices, an external in-plane field is required to break the symmetry and enable deterministic switching. This adds new challenges to the technology development of perpendicular SOT devices. To this end, field-free switching of perpendicular SOT devices was achieved through incorporation of exchange bias in the SOT stack74, utilizing a magnetic hard mask75 and combining STT with SOT76,77,78. Despite the demonstration of deterministic field-free switching in perpendicular SOT devices, all approaches add complexity and, potentially, new failure mechanisms to device operation. Although both in-plane SOT79,80,81,82 and perpendicular SOT83,84,85 devices are being actively pursued, it is unlikely for in-plane devices to be technologically useful, due to inefficient switching (owing to large Hp) and large dipole fields that prevent them from being densely packed (see Box 3). Ultimately, combining perpendicularly spin-polarized spin current with perpendicularly magnetized SOT devices is the most promising path to harness the potential of SOT-MRAM. This has led to great efforts in pursuing spin current generation with perpendicular spins. The challenge is that fundamental symmetry considerations forbid perpendicular spin polarization in symmetric materials (see Box 4). Some form of asymmetry is required. There have been demonstrations of spin current with perpendicular spins in several types of asymmetric SOT materials systems, including WTe2 and MoTe2 with low crystal symmetry86,87,88, epitaxial design of moderate crystal symmetry IrO2 (ref. 89), magnetic asymmetry in antiferromagnetic RuO2 (ref. 90) and magnetic asymmetry in a ferromagnet91,92,93.
For memory applications, the biggest disadvantage of three-terminal SOT-MRAM devices is their low density relative to two-terminal STT-MRAM devices. Based on a design technology co-optimization study from IMEC94, the optimized bit cell area of SOT-MRAM is roughly twice the size of STT-MRAM at the 5 nm node, due to the second transistor and an additional via in each memory cell connecting the top of each MTJ with the read transistor. Approaches to address the density challenge of SOT-MRAM devices include two-terminal SOT devices that combine the STT and SOT effects95, and SOT devices with a shared SOT wire, to amortize the write transistor over multiple junctions96 (Fig. 3g). The results from both approaches are preliminary at this point and more work is needed to demonstrate their technological potential.
The fabrication process of SOT-MRAM is also more challenging than that of STT-MRAM, due to stringent requirements on the MTJ etch. The etch stop needs to be controlled within the SOT layer, with a typical thickness of ~5 nm. Under-etched devices will have an extended free-layer area with compromised switching performance, whereas over-etched devices will have high-resistance SOT wires. To date, most publications on SOT-MRAM focus on single-device performance without addressing the fabrication challenges of large arrays across a wafer. To date, only Intel and TSMC have reported yield learning data on SOT-MRAM arrays77,79.
For SOT-MRAM to become a competitive technology for last-level cache applications, the gaps need to be addressed, including generation of perpendicular spins through materials and device structure innovation with \(\xi \) > 0.3 (ref. 97), demonstration of comparable density with two-terminal STT-MRAM and demonstration of array-level performance with tight distribution and decent yield.
Voltage-controlled magnetic anisotropy MRAM
Voltage control of magnetism has been realized in many materials systems with different characteristics and mechanisms62,63,98,99. Among them, the discovery of voltage-controlled magnetic anisotropy (VCMA) in 3d metal (Fe, CoFe, CoFeB)|MgO systems has had the most impact on memory applications100,101,102. Here, we focus on MRAM devices that utilize the VCMA effect in CoFe(B)|MgO-based MTJs.
VCMA-MRAM adopts the same memory cell architecture as STT-MRAM (Fig. 2a) but with high resistance–area product (>100 Ω·μm2) MTJs. The read process is the same as that of STT-MRAM. When a large voltage is applied during the write process it modifies the magnetic anisotropy of the free layer and induces switching, with minimal electrical current flowing through the MTJ. In VCMA-MRAM, when a voltage is applied across the MTJ, the electric field across the MgO tunnel barrier modulates the orbital occupancy of the electrons at the CoFeB|MgO interface, thus modulating the interface perpendicular magnetic anisotropy63,101 (Box 3). Two opposite voltage polarities either enhance the interface anisotropy or weaken it, allowing for magnetization to be switched from perpendicular to in plane, but not from up to down. The VCMA coefficient is defined as the change in the magnetic anisotropy energy areal density per unit electric field, in femtojoules per volt-metre. Typical VCMA coefficients of the sputtered 3d metal|MgO system are on the order of tens of femtojoules per volt-metre up to hundreds of femtojoules per volt-metre (refs. 102,103,104,105). Substantially larger VCMA coefficients on the order of 1,000 fJ V–1m–1 have been reported for some 3d transition metal|oxide systems, where the VCMA effect was dominated by charge trapping and/or ionic migration106,107. However, in this type of device, the response time is too slow for last-level cache applications.
VCMA-MRAM has the potential to operate at high speed and extremely low energy108,109,110. Two types of VCMA-MRAM devices have been pursued in the field: precessional-switching VCMA-MRAM102,103,111,112 and VCMA-assisted SOT/STT-MRAM113,114. Precessional-switching VCMA-MRAM utilizes the VCMA effect solely in the presence of an external in-plane magnetic field. During the write process, the energy barrier (Fig. 1c) is lowered to close to zero under the applied voltage, and the free-layer magnetization precesses around the external in-plane field. By applying voltage pulses with duration at the half precession period of the free layer, the device can be toggled between the high and low resistance states in both directions using the same polarity and amplitude voltage pulse (a pre-read before write is required, to determine whether writing is needed, as the writing is not directional). For VCMA-MRAM devices, the precession frequency of the magnetization can be on the order of gigahertz, and sub-nanosecond switching has been demonstrated experimentally103,112,115. One major challenge of this device concept is the reliability of the write process, where a precisely controlled voltage pulse duration, tuned for the precession frequency of the device, is required to achieve successful switching. This requires extremely tight control of the precession frequency and its device to device distribution. To date, the best write-error rate demonstrated in single devices is about 10–6 errors per write116 and is expected to worsen substantially for an array, considering the device to device variation. Therefore, write reliability for precessional-switching VCMA-MRAM has to be significantly improved to meet the last-level cache application requirement.
The second type of VCMA-MRAM device relies on the combination of VCMA with STT or SOT switching113,117,118, where the VCMA effect is utilized to lower the energy barrier and assist the STT or SOT switching. VCMA-STT switching devices showed an improved switching speed compared with STT-only devices, and an improved switching reliability compared with VCMA-only devices113. The VCMA effect was also utilized to assist SOT switching with four to eight MTJs sitting on a shared SOT wire, with VCMA applied individually to each junction through its own transistor117,118. A 25% SOT switching current reduction was demonstrated at a write pulse width of 0.4 ns with conventional CoFeB|MgO-based MTJs and a tungsten SOT wire118, limited by the small VCMA coefficient of the free-layer material (~15 fJ V–1m–1). Although a large VCMA coefficient, up to 1,000 fJ V–1m–1, was reported in strained CoFe grown on single crystal MgO substrates119, practical free-layer materials grown on standard substrates with a much improved VCMA coefficient (300–800 fJ V–1m–1) are needed to make VCMA-MRAM a competitive candidate for last-level cache applications118.
Outlook
Several exploratory scientific ideas have been proposed to further improve MRAM in the future. For example, thermal magnons could generate STT ten times more efficiently than electrically driven STT120,121. Ultrafast sub-picosecond optical switching has been demonstrated using laser pulses122, but optics are challenging to integrate into dense memory technology123. Racetrack memory, using STT to move multiple domain walls in three-dimensional racetracks, has been proposed to improve density; however, domain walls are hard to manipulate in practical applications124. Chiral materials have been predicted to generate spin polarization parallel to the direction of current125, a potential path to reducing the switching current. Remarkably, antiferromagnetic tunnel junctions have been demonstrated to produce magnetoresistance126,127 and can be switched by SOT128,129, which may enable faster switching. Overall, spintronics remains an active field generating a steady stream of new and innovative ideas for future STT-MRAM technologies.
Change history
15 November 2024
A Correction to this paper has been published: https://doi.org/10.1038/s44287-024-00123-9
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Worledge, D.C., Hu, G. Spin-transfer torque magnetoresistive random access memory technology status and future directions. Nat Rev Electr Eng 1, 730–747 (2024). https://doi.org/10.1038/s44287-024-00111-z
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DOI: https://doi.org/10.1038/s44287-024-00111-z