Search Results (190)

The electrical explosive fragmentation technique has attracted widespread attention due to its environmental friendliness and high efficiency. However, the mechanism by which dielectrics influence rock fragmentation remains unclear. This study innovatively selected seven types of environmentally friendly dielectrics to systematically investigate their roles in the metallic wire electrical explosive rock fragmentation process. By precisely characterizing the crack morphology of concrete blocks, shock wave–strain responses, and discharge signal characteristics, the diverse mechanisms by which different dielectrics modulate rock fragmentation were revealed. The results indicate that oxide dielectrics release energy continuously through thermochemical reactions, highly conductive solutions accelerate energy deposition, and reductant suspensions generate strong secondary shock waves—all significantly outperforming tap water in terms of rock fragmentation performance. Notably, the energy deposition efficiency shows a nonlinear relationship with fragmentation effectiveness, influenced by factors such as energy release modes, dielectric composition, and bubble dynamics. The energy conversion mechanism of the electrical explosive rock fragmentation process studied in this paper provides a theoretical foundation for the fine-tuning, customization, and greening of electrical explosive rock fragmentation strategies in engineering practice. Full article

The dissolution of dolomite can not only provide the chemical components in hot springs but also provide a high-quality reservoir for geothermal resources. However, there is still debate about the main controlling factors and mechanisms of the dissolution process of dolomite. The Shuijing hot springs in Guizhou Province are rich in SO₄²⁻ and the geothermal reservoir is dolomite, which provides an excellent opportunity to understand the role of SO₄²⁻ in the dissolution process of dolomite. In this paper, water–rock interaction experiments were conducted at different temperatures to study the effects of SO₄²⁻, pH, and CO₂ on the dissolution of dolomite from the Shuijing hot springs geothermal reservoir. The results indicate that temperature is a significant factor affecting the chemical composition of hot springs water, with higher temperatures having a more pronounced effect on the dissolution of dolomite. At lower temperatures of 25 °C and 90 °C, the molar ratio of the released Ca²⁺ and Mg²⁺ during the dissolution of dolomite in the initial reaction stage generally approaches the Ca/Mg molar ratio of dolomite, exhibiting congruent dissolution. However, at elevated temperatures of 150 °C, the released Ca/Mg molar ratio surpasses the Ca/Mg molar ratio of dolomite, demonstrating an incongruent dissolution characteristic with Ca²⁺ being preferentially released over Mg²⁺. Additionally, the relative importance of CO₂, SO₄²⁻ and pH on the dissolution degree of dolomite is CO₂ > SO₄²⁻ > pH = 4 > pH = 7 > pH = 10. The promotion effect of SO₄²⁻ on dolomite dissolution indicates that the greater the SO₄²⁻ concentration, the stronger the dissolution of dolomite, and its dissolution ability is enhanced with the increase in temperature. Furthermore, the effect of CO₂ on the dissolution of dolomite is stronger than that of SO₄²⁻, leading to the oscillating fluctuation trend of the released Ca²⁺ and Mg²⁺. Full article

Efflorescence, a time-dependent and water-driven phenomenon, is a major concern in alkali-activated materials (AAMs), impacting their practical use and preservation in a time-frozen state for post-characterisation. Although a method for stopping chemical reactions in conventional cements exists, it is time-consuming and not chemical-free. Therefore, this study explored the effects of low-power microwave-induced dehydration on efflorescence, mechanical performance, and structural integrity in AAMs, to create an alternative and more “user-friendly” dehydration method. For this purpose, several mixtures based on secondary raw (slag, fly ash, glass wool, and rock wool) and non-waste (metakaolin) materials were activated with a commercial Na-silicate solution in ratios that promoted or prevented efflorescence. Characterisation techniques, including Fourier-transform infrared spectroscopy and X-ray diffraction, showed that microwave dehydration effectively removed water without altering crystallinity, while mercury intrusion porosimetry and compressive strength tests confirmed increased porosity. In addition to being an efficient, time-saving, and solvent-free manner of stopping the reactions in AAMs, microwave irradiation emerged as an innovative, chemical-free method for evaluating curing finalisation and engineering foams in a stage when all other existing methods fail. However, the artificially provoked efflorescence in aged dehydrated AAMs connected the slipperiness of AAM with the instant extraction of Na, which raised the need for further research into alternative alkali replacements to evaluate the practical use of AAM. Full article

Acid mine drainage (AMD), wherein acidic water is generated from pyrite-containing waste rock, can be mitigated by encapsulating pyritic waste rock with cover materials to restrict the inflow of oxygen and water. However, acidic water inevitably forms during the construction of waste rock dumps before applying cover materials. Considering that the presence of waste rock containing carbonate minerals contributes to acid neutralization, a mixture of carbonate minerals and pyritic waste rock can be utilized to reduce AMD generation before the completion of the cover system as a temporary management strategy. This paper examines waste rock management using blending scenarios. Kinetic NAG and column leaching tests were employed to evaluate the blending ratio necessary to prevent acidic water generation. Geochemical analyses were conducted on rock and leachate samples, including pH and temperature measurements, XRD and XRF analyses, and Ion Chromatography. Consequently, the pH and temperature measurement results obtained during the kinetic NAG test are valuable for expressing the balance between acid generation and acid neutralization by the mixture material. Furthermore, the column leaching test demonstrated that the pH of the leachate remained neutral when the acid generation and acid neutralization reactions were well balanced. Blending waste rocks is an effective method for AMD reduction during the construction of waste rock dumps. Full article

The effect of the dry–wet cycle, characterized by periodic water level changes in the Three Gorges Reservoir, will severely degrade the bearing performance of rock formations. In order to explore the effect of the dry–wet cycle on the mesoscopic damage mechanism of jointed sandstone, a list of meso-experiments was carried out on sandstone subjected to dry–wet cycles. The pore structure, throat features and mesoscopic damage evolution of jointed sandstone with the action of the dry–wet cycle were analyzed using a-low-field nuclear magnetic resonance (NMR) technique. Subsequently, the impact on the mineral content of dry–wet cycles was studied by small angle X-ray scattering (SAXS). Based on this, the mesoscopic damage mechanism of sandstone subjected to dry–wet cycles was revealed. The results show that the effects of the drying–wetting cycle can promote the development of porous channels within sandstone, resulting in cumulative damage. Besides, with an increase in dry–wet cycles, the proportion of small pores and pore throats decreased, while the proportion of medium and large pores and pore throats increased. The combined effects of extrusion crush, tensile fracture, chemical reaction and dissolution of minerals inside the jointed sandstone contributed to the development of mesoscopic pores, resulting in the increase of porosity and permeability of rock samples under the dry–wet cycles. The results provide an important reference value for the stability evaluation of rock mass engineering under long-term dry–wet alternation. Full article

Serpentine (Mg₃Si₂O₅(OH)₄), like quartz, dolomite and magnesite minerals, is a versatile mineral group characterized by silica and magnesium silicate contents with multiple polymorphic phases. Among the phases composed of antigorite, lizardite, and chrysotile, lizardite and chrysotile are the most prevalent phases in the serpentinites studied here. The formation process of serpentinites, which arise from the hydrothermal alteration of peridotites, influences the ratio of light rare earth elements (LREE) to heavy rare earth elements (HREE). In serpentinites, the ratio of light rare earth elements (LREE)/heavy rare earth elements (HREE) provides insights into formation conditions, geochemical evolution, and magmatic processes. The depletion of REE compositions in serpentinites indicates high melting extraction for fore-arc/mantle wedge serpentinites. The studied serpentinites show a depletion in REE concentrations compared to chondrite values, with HREE exhibiting a lesser degree of depletion compared to LREE. The high ΣLREE/ΣHREE ratios of the samples are between 0.16 and 4 ppm. While Ce shows a strong negative anomaly (0.1–12), Eu shows a weak positive anomaly (0.1–0.3). This indicates that fluid interacts significantly with rock during serpentinization, and highly incompatible elements (HIEs) gradually become involved in the serpentinization process. While high REE concentrations indicate mantle wedge serpentinites, REE levels are lower in mid-ocean ridge serpentinites. The enrichment of LREE in the analyzed samples reflects melt/rock interaction with depleted mantle and is consistent with rock–water interaction during serpentinization. The gradual increase in highly incompatible elements (HIEs) suggests that they result from fluid integration into the system and a subduction process. The large differential thermal analysis (DTA) peak at 810–830 °C is an important sign of dehydration, transformation reactions and thermal decomposition, and is compatible with H₂O phyllosilicates in the mineral structure losing water at this temperature. In SEM images, chrysotile, which has a fibrous structure, and lizardite, which has a flat appearance, transform into talc as a result of dehydration with increasing temperature. Therefore, the sudden temperature drop observed in DTA graphs is an indicator of crystal form transformation and CO₂ loss. In this study, the mineralogical and structural properties and the formation of serpentinites were examined for the first time using thermo-gravimetric analysis methods. In addition, the mineralogical and physical properties of serpentinites can be recommended for industrial use as additives in polymers or in the adsorption of organic pollutants. As a result, the high refractory nature of examined serpentine suggests that it is well-suited for applications involving high temperatures. This includes industries such as metallurgy and steel production, glass manufacturing, ceramic production, and the chemical industry. Full article

In this paper, well Keshen 221 was taken as the research object. The stagnant water–rock static experiment showed that, after 8 weeks of the residual water–rock static reaction, the pore size of the inner profile of the rock slice increased from 5 μm to 90 μm, and calcium carbonate crystals were deposited in the hole. Combined with the microscopic visualization model, it is observed that the reservoir blockage mostly occurs at the pore throat diameter, and the small fracture (30 μm) is blocked first, then the large fracture (50 μm). So, it is inferred that the blockage of the reservoir flow channel is caused by the migration of the crystals precipitated by the interaction between the stagnant water and the reservoir rock. On this basis, the TOUGHREACT reservoir model was further constructed to simulate the scaling of the stagnant water in the reservoir matrix and used to compare the scaling of the fractures with 7% and 30% porosity and the retained water at 0.658 m and 768 m. The pre-results of reservoir scaling show that the scaling is more serious when the fractures occur in the far well zone than when the fractures occur in the well entry zone. At the same location, the deposition of large fractures is six times that of small fractures, and the scaling is more severe in large fractures. Full article

Reinjection is thought to be the most effective way to maintain reservoir pressure and production capacity for hydrothermal resources. The use of external water injection to replenish deep geothermal reservoirs is a new approach in China to addressing the problems of declining groundwater levels and energy depletion caused by the excessive and uneven exploitation of geothermal resources. However, the key challenge and focus of the feasibility assessment of this method lies in the chemical compatibility of the external water with the native geothermal reservoir water and surrounding rocks. In this paper, we discuss the geochemical response of a dolomite reservoir to lake water injection based on experiments on water–rock interaction in the Wumishan formation in the Dongli Lake area of Tianjin. The results show that after reactions with dolomite, the TDS of the reacted water decreases, indicating the occurrence of precipitation. According to the calculation results obtained using the PHQREEC program, the precipitation amount is found to be quite limited. Geochemical analysis indicates that at the initial stage of the reactions, plagioclase dissolves and releases alkaline metals like Ca-, Na-, SiO₂- and Al-bearing compositions, leading to the oversaturation and precipitation of dolomite and calcite. As the reaction progresses, a portion of the dolomite dissolves, while the calcite continues to precipitate at a later stage. Illite precipitates and its effects on reservoir structure depend on its shape. Based on the experimental data, it can be concluded that the dolomite reservoir will be slightly affected by the reinjection of lake water; however, it is still a good method for the sustainable development of geothermal resources. Full article

CO₂–water–rock interactions have an important impact on the stability and integrity of the caprock in CO₂ geological storage projects. The injected CO₂ in the reservoir enters the caprock via different mechanisms, leading to either the dissolution or precipitation of minerals. The mineral alterations change the porosity, permeability, and mechanical properties of the caprock, affecting its sealing capability. To evaluate the sealing effectiveness of overlying caprock and identify the influencing factors, numerical simulations and experiments were carried out on the mudstone Dongying Formation in Dezhou, China. Based on high-temperature and high-pressure autoclave experiments, batch reaction simulations were performed to obtain some key kinetic parameters for mineral dissolution/precipitation. Then, they were applied to the following simulation. The simulation results indicate that gaseous CO₂ has migrated 7 m in the caprock, while dissolved CO₂ migrated to the top of the caprock. Calcite is the dominant mineral within 1 m of the bottom of the caprock. The dissolution of calcite increases the porosity from 0.0625 to 0.4, but the overall porosity of the caprock decreases, with a minimum of 0.054, mainly due to the precipitation of montmorillonite and K-feldspar. A sensitivity analysis of the factors affecting the sealing performance of the caprock considered the changes in sealing performance under different reservoir sealing conditions. Sensitivity analysis of the factors affecting the sealing performance of the caprock indicates that the difference in pressure between reservoir and caprock affects the range of CO₂ transport and the degree of mineral reaction, and the sealing of the caprock increases with the difference in pressure. Increasing the initial reservoir gas saturation can weaken the caprock’s self-sealing behavior but shorten the migration distance of CO₂ within the caprock. When the content is lower than 2%, the presence of chlorite improves the sealing performance of the caprock and does not increase with further chlorite content. This study elucidates the factors that affect the sealing ability of the caprock, providing a theoretical basis for the selection and safety evaluation of CO₂ geological storage sites. Full article

The Qinglian River plays a significant role in China’s national water conservation security patterns. To clarify the relationship between hydrogeochemical properties and groundwater quality in this karst-fissure aquifer system, drilling data, hydrochemical parameters, and δ²H and δ¹⁸O values of groundwater were analyzed. Multiple indications (Piper diagram, Gibbs diagram, Na⁺-normalized molar ratio diagram, chloro-alkaline index 1, mineral saturation index, and principal component analysis) were used to identify the primary sources of chemicals in the groundwater. Silicate weathering, oxidation of pyrite and chlorite, cation exchange reactions, and precipitation are the primary sources of dissolved chemicals in the igneous-fissure water. The most relevant parameters in the karst water are possibly from anthropogenic activities, and other chemicals are mostly derived from the dissolution of calcite and dolomite and cation exchange reactions. Notably, the chemical composition of the deep karst water from the karst basin is mainly influenced by the weathering of carbonate and cation exchange reactions and is less affected by human activities. The hydrogeochemical properties of groundwater in the karst hyporheic zone are influenced by the dissolution of carbonates and silicates, evaporation, and the promotion effect of dissolution of anorthite or Ca-containing minerals. Moreover, the smallest slope of the groundwater line from the karst hyporheic zone among all groundwater groups revealed that the mixing effects of evaporation, isotope exchange in water–rock interaction or deep groundwater recharge in the karst hyporheic zone are the strongest. The methods used in this study contribute to an improved understanding of the hydrogeochemical processes that occur in karst-fissure water systems and can be useful in zoning management and decision-making for groundwater resources. Full article

The Tibetan Plateau is the “Asia Water Tower” and is pivotal for Asia and the whole world. Groundwater is essential for sustainable development in its alpine regions, yet its chemical quality increasingly limits its usability. The present research examines the hydrochemical characteristics and origins of phreatic groundwater in alpine irrigation areas. The study probes the chemical signatures, quality, and regulatory mechanisms of phreatic groundwater in a representative alpine irrigation area of the Tibetan Plateau. The findings indicate that the phreatic groundwater maintains a slightly alkaline and fresh status, with pH values ranging from 7.07 to 8.06 and Total Dissolved Solids (TDS) between 300.25 and 638.38 mg/L. The hydrochemical composition of phreatic groundwater is mainly HCO₃-Ca type, with a minority of HCO₃-Na·Ca types, closely mirroring the profile of river water. Nitrogen contaminants, including NO₃⁻_, NO₂⁻, and NH₄⁺, exhibit considerable concentration fluctuations within the phreatic aquifer. Approximately 9.09% of the sampled groundwaters exceed the NO₂⁻ threshold of 0.02 mg/L, and 28.57% surpass the NH₄⁺ limit of 0.2 mg/L for potable water standards. All sampled groundwaters are below the permissible limit of NO₃⁻ (50 mg/L). Phreatic groundwater exhibits relatively good potability, as assessed by the entropy-weighted water quality index (EWQI), with 95.24% of groundwaters having an EWQI value below 100. However, the potential health risks associated with elevated NO₃⁻ levels, rather than NO₂⁻ and NH₄⁺, merit attention when such water is consumed by minors at certain sporadic sampling locations. Phreatic groundwater does not present sodium hazards or soil permeability damage, yet salinity hazards require attention. The hydrochemical makeup of phreatic groundwater is primarily dictated by rock–water interactions, such as silicate weathering and cation exchange reactions, with occasional influences from the dissolution of evaporites and carbonates, as well as reverse cation-exchange processes. While agricultural activities have not caused a notable rise in salinity, they are the main contributors to nitrogen pollution in the study area’s phreatic groundwater. Agricultural-derived nitrogen pollutants require vigilant monitoring to avert extensive deterioration of groundwater quality and to ensure the sustainable management of groundwater resources in alpine areas. Full article

Possible deterioration of a rock’s structure and mechanical properties due to chemical reactions between the host rock, formation water, and CO₂ requires due attention. In this study, cylindrical sandstone specimens obtained from the Hanna Formation, Wyoming, were prepared under three treatment conditions: dry, submerged in water, and treated with water + CO₂ for one week at a pressure of 5 MPa and room temperature. Specimens were subjected to three effective confining pressures of 5, 15, and 25 MPa. The mechanical test results show that water + CO₂ treatment, on average, decreases the peak strength and elastic modulus of the specimens by 36% and 20%, respectively, compared to dry specimens. For all three effective confining pressures, the dry specimens exhibited higher compressive strengths, larger Young’s moduli, and more brittle behavior. CO₂-treated specimens showed significantly lower calcite contents. Full article

Zuogong County is located in the southeast of Tibet, which is rich in hot spring geothermal resources, but its development and utilization degree are low, and the genetic mechanism of the geothermal system is not clear. Hydrogeochemical characteristics of geothermal water are of great significance in elucidating the genesis and evolution of geothermal systems, as well as the sustainable development and utilization of geothermal resources. The hydrogeochemical characteristics and genesis of the geothermal water in Zuogong County were investigated using hydrogeochemical analysis, a stable isotope (δD, δ¹⁸O) approach, and an inverse simulation model for water–rock reactions using the PHREEQC. The results indicated that the Zuogong geothermal system is a deep circulation heating type without a magmatic heat source. The chemical types present in the geothermal water from the Zuogong area are HCO₃ and HCO₃·SO₄, and the main cations are Na⁺ and Ca²⁺. The groundwater is replenished by atmospheric precipitation and glacier meltwater. The salt content of geothermal water mainly comes from the interaction between water and surrounding rocks during the deep circulation process. The reservoir temperature of geothermal water in Zuogong is 120–176 °C before mixing with non-geothermal water and drops to 62–98 °C after mixing with 58 to 79% of non-geothermal water. According to the proposed conceptual model, geothermal water mainly produces water–rock interaction with aluminosilicate minerals in the deep formation, while in shallow areas it interacts mainly with sulfate minerals. These findings contribute to a better understanding of the geothermal system in Zuogong County, Tibet. Full article

Carbonate rocks are highly reactive and exhibit higher ratios of chemical weathering compared to most other rock types. A chemo-mechanical mechanism, which is particularly effective in groundwater due to higher ion concentrations, is common in fine-grained carbonates at the nanoscale. As a result, the weathering of carbonate aquifers produces a substantial number of carbonate nanoparticles (CNPs). In this study, we utilized high-resolution transmission electron microscopy (HRTEM) to analyze CNPs formed by water–rock reactions in two types of groundwater from Shandong Province, China. Our findings reveal a significant presence of naturally occurring CNPs in groundwater. The HRTEM results show that CNPs display spherical, cubic, hexagonal, and irregular shapes, with some forming aggregates. Energy-dispersive spectrometry indicates that most nanoparticles contain O, C, Ca, and Fe, with some also containing Si, Mg, S, Sr, and Cl. Selected area electron diffraction (SAED) patterns show that CNPs are mainly amorphous, with some crystalline forms. The diverse shapes and complex compositions of these CNPs suggest that they are not man-made but formed through the weathering of carbonate minerals via chemo-mechanical mechanisms. This discovery provides new insights into carbonate mineral evolution and mineralization during weathering. Given their widespread presence, CNPs in groundwater could represent the transportation of elements in the form of particles. Full article

The geochemical properties of fracturing flowback fluids indirectly indicate the fracturing efficiency of the reservoir, the interaction between the reservoir and injected water, and the preservation of oil and gas, thereby offering robust data support for identifying fracturing flowback fluid sources, assessing fracturing effects, and proposing stimulation strategies. In this study, the ion characteristics, total salinity, and stable isotope ratio of fracturing flowback fluids of the Z202H1 and Z203 wells in Western Chongqing were measured. The findings suggest that with the extension of flowback time, the geochemical properties of fracturing flowback fluids evolve toward higher salinity and heavier stable isotope ratios, ultimately stabilizing. Upon comparing the water–rock reaction intensity and the rate of total salinity increase in the fracturing flowback fluids, it is concluded that fracturing flowback fluids contain a mixture of formation water. Because water–rock reactions elevate the total salinity of fracturing flowback fluids, we introduce the Water–Rock Reaction Intensity Coefficient (I_R) to denote the intensity of these reactions. Based on the I_R value, the binary mixture model for fracturing fluids in fracturing flowback fluids was adjusted. With the increase in flowback time, the content of fracturing fluids in fracturing flowback fluids of Z202H1 and Z203 stabilized at about 55% and 40% respectively. During the same flowback period, the fracturing flowback fluids of the Z203 well exhibit a higher total salinity, a heavier stable isotope ratio, a greater I_R, and a lower fracturing fluid content in fracturing flowback fluids. This suggests that the fracturing effect of the Z203 well is superior to that of the Z202H1 well, leading to a higher production capacity of the Z203 well. Full article