Search Results (319)

This study examines arsenic contamination in the Caplina Basin, Tacna, Peru, focusing on arsenic speciation and associated risks in surface waters. Arsenic concentrations were quantified using inductively coupled plasma mass spectrometry (ICP-MS) and high-performance liquid chromatography (HPLC). Total arsenic levels ranged from 0.0304 mg/L to 0.0730 mg/L across all monitoring points, exceeding the World Health Organization (WHO) limit of 10 µg/L (0.01 mg/L) for drinking water. Arsenite (As(III)), the most toxic and mobile species, reached levels up to 0.0154 mg/L, posing a significant concern at Point 7, characterized by acidic pH (3.82) and high conductivity (1456 µS/cm). Arsenate (As(V)), less toxic but predominant under alkaline conditions, peaked at 0.0260 mg/L at Point 6 (pH 8.42). Organic species such as dimethylarsenic acid (DMA) and monomethylarsenic acid (MMA) were also detected, indicating active methylation processes and anthropogenic influences. The risk assessment revealed carcinogenic risk values ranging from 2.56 × 10⁻⁵ to 6.28 × 10⁻⁵, below the USEPA threshold (1 × 10⁻⁴), but significant for prolonged exposure. Non-carcinogenic hazard quotient (HQ) values ranged from 0.09 to 0.21. These findings highlight severe public health implications and emphasize the urgent need for comprehensive strategies, including continuous monitoring, targeted treatment technologies, and community education, in order to guarantee water quality in vulnerable areas. Full article

Pollution is one of the most important issues currently affecting the global population and environment. Therefore, determining the zones where stringent measures should be taken is necessary. In this study, Principal Component Analysis (PCA), Factor Analysis (FA), and t-distributed Stochastic Neighbor Embedding (t-SNE) were utilized for dimensionality reduction and clustering of data series containing the concentration of 10 heavy metals collected at 14 locations. The Hazard Quotient (HQ) and Hazard Index (HI) were utilized to determine the non-carcinogenic risk to the population in the studied zones. The highest concentrations of metals in the samples were those of Fe, Zn, Mn, and Cr. PCA indicated that Fe and Zn (Co and Cd) had the highest contribution on the first (second) Principal Component (PC). FA showed that the three-factor model is adequate for explaining the variability of pollutant concentrations. The factor loadings revealed the strength of association between variables and factors, e.g., 0.97 for Zn, 0.83 for Cr, and 0.99 for Co. HQ for ingestion, HQing, was the highest for Fe (between 6.10 × 10⁻⁵ and 2.57 × 10⁻⁴). HQ for inhalation, HQinh, was the biggest for Mn (from 1.41 × 10⁻³ to 1.95 × 10⁻³). HI varied in the interval [0.172, 0.573], indicating the absence of a non-carcinogenic risk. However, since values above 0.5 were determined at four sites, continuous monitoring of the pollution in the sampling locations is necessary. Full article

This study examines the spatio-temporal variations of ambient air pollution from fine particulates below 2.5 µm (PM_2.5) and particulate matter below 10 µm (PM₁₀) in three of the most polluted provinces in Iran, namely Tehran, Isfahan, and Khuzestan, over a 6-year period (2016–2021). The results reveal distinct patterns of PM₁₀ and PM_2.5 concentrations since in Tehran, the highest PM₁₀ and PM_2.5 levels occur in winter, while PM_2.5 is lowest from March to May. Khuzestan experiences the highest pollution levels in summer due to dust storms, while Isfahan exhibits pollution levels and annual patterns similar to Tehran. Strong correlations are observed between PM₁₀ and PM_2.5 concentrations at stations in Tehran and Khuzestan Provinces, suggesting common sources and variation in both coarse and fine PM, with average PM_2.5/PM₁₀ ratios of 0.39–0.42, suggesting the dominance of dust. Furthermore, the analysis identifies the role of atmospheric stability, wind speed, and dust storms in controlling the PM levels in the three provinces. Lifetime cancer risks have been identified as unacceptably high, exceeding the threshold limit of 10⁻⁴, while Hazard Quotient (HQ) values above 1 indicate a high non-carcinogenic potential risk, particularly at stations in Khuzestan Province. The Excess Lifetime Cancer Risk (ELCR) values for PM_2.5 exposure in the most populated Tehran Province range from 139.4 × 10⁻⁶ to 263.2 × 10⁻⁶, underscoring significant cancer risks across various monitoring sites. This study emphasizes the urgent need for targeted pollution control measures in each province to effectively mitigate the adverse health effects associated with high PM concentrations. Full article

Chocolate is one of the most popular and widely consumed confectionery products. However, elevated cadmium (Cd) content in this commodity threatens food safety and human health. It is crucial to monitor the presence of Cd in chocolate and to evaluate its associated health risks. This study assessed the Cd levels in milk and dark chocolates from the Serbian market (n = 155). Cadmium concentrations varied between 0.010 and 0.29 mg/kg. The obtained values were used to evaluate the hazard quotient (HQ) and cancer risk (CR). The estimated weekly intakes (EWIs) were below the tolerable limits for all samples. However, in some samples, the EWI reached 60.9% and 63.5% of the tolerable limit for toddlers and other children, respectively. No health risk was found based on the HQ. On the other hand, based on CR values, all chocolate products can be classified as posing a moderate risk. The Monte Carlo simulation indicated that toddlers and other children were more exposed to non-carcinogenic risk, whereas vegetarians, adults, pregnant women, and other children were more exposed to cancer risk. Sensitivity analysis indicates that body weight, exposure frequency, and ingestion rate are the most influential factors for non-cancer and cancer health risks. Full article

In this study, gaseous element mercury (GEM) and gaseous oxidized mercury (GOM) in the atmosphere were continuously observed at a minute resolution from 1 April 2019 to 31 December 2020 in urban Xi’an, the largest central city in Northwestern China. The concentrations of GEM and GOM drastically fluctuated within the ranges of 0.022–297 ng/m³ and 0.092–381 pg/m³, showing average values of 5.78 ± 7.36 ng/m³ and 14.2 ± 20.8 pg/m³, respectively. GEM and GOM showed a decreasing trend of 0.121 ng/m³ and 0.472 pg/m³ per month, respectively, which we believe was mainly caused by anthropogenic sources, especially by a reduction in coal-fired emissions, rather than meteorological factors. The significant positive correlation between GEM and PM_2.5, SO₂, NO₂, and CO, as well as Cr, As, and Pb in PM_2.5 also proves that. GEM showed a higher concentration at nighttime than daytime, while an M-shaped diurnal trend was observed for GOM. The hazard quotient of GEM for both males and females decreased at a rate of 0.003 per month, and children aged 2–5 were more sensitive to non-carcinogenic health risks. The changing trends, controlling factors, and human health risks of Hg in the atmosphere are necessary and crucial to study for improving our understanding of the impacts of Hg in Northwestern China. Full article

Background: In recent years, the consumption of energy drinks (EDs) by adolescents and young adults has increased significantly, so concerns have been raised about the potential health risks associated with excessive ED consumption. Most analyses on EDs focus on the caffeine content. Research on the content of minerals (essential and toxic) in energy drinks can be considered scarce. Therefore, there is a need for research stating the actual status of heavy metal content in commercially available energy drinks. Methods: This research presents the determination of the total concentrations of macro-elements and trace elements (TEs), such as Na, K, Mg, Ca, Al, Cr, Co, Cu, Fe, Mn, Ni, B, Zn, V, Sr, Ba, Pb, Cd, and As in nine samples of energy drinks using inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma mass spectrometry (ICP-MS) techniques. Results: The order in the content of macro-minerals in the EDs was as follows: Na > K > Mg > Ca. The results showed that ED 1, ED 3, and ED 7 samples had the highest micro-mineral concentrations. All the samples had a hazard quotient and hazard index < 1, indicating no non-carcinogenic risk from exposure to single or multiple heavy metals in both the adolescent and adult age groups. Some samples exceeded the threshold limit of acceptable cancer risk for As, Ni, and Cr in both adolescents and adults. Conclusions: This assessment showed that in addition to health implications based on the caffeine content of EDs, there might be a carcinogenic risk associated with the toxic element content of these beverages. This research also highlights notable differences in the TE levels among various ED brands, which may have important implications for consumer well-being and health. Full article

Groundwater is essential for water resources, serving as a key drinking source in China. It supports daily needs for urban and rural residents, aids development, and maintains ecological balance. This study conducted a sampling survey of groundwater in the Wen River basin (WRB), assessing hydrochemical features, genesis mechanisms, water quality, and health risks. The findings reveal that groundwater in the WRB is weakly alkaline, with an average total dissolved solids (TDS) concentration of 755.24 mg/L. Freshwater constitutes approximately 81.48% of the groundwater, with the following order of concentration for cations: Ca²⁺ > Na⁺ > Mg²⁺ > K⁺, and for anions: HCO₃⁻ > SO₄²⁻ > NO₃⁻ > Cl⁻. The predominant hydrochemical types are SO₄·Cl-Ca·Mg and HCO₃-Ca·Mg. The chemical composition of the groundwater is primarily influenced by silicate rock weathering, dissolution processes, cation exchange, and human activities. The average Environmental Water Quality Index (EWQI) value of 74.65 for the WRB signifies that the overall quality of the groundwater is quite good, indicating that the majority of the groundwater is suitable for drinking purposes. Notably, the inferior quality water is predominantly found downstream of the Wen River. Calculations of the sodium adsorption ratio (SAR), residual sodium carbonate (RSC), and percentage of sodium (%Na) indicate that groundwater at most sampling points is suitable for irrigation. Furthermore, the human health risk assessment (HRA) reveals that oral intake presents a greater health risk to individuals than dermal contact. The mean Hazard Index (HI) for children is 3.24, with a staggering 79.89% of non-carcinogenic health risk (NHR) values surpassing the acceptable standards. For adults, the mean HI is 1.39, with 53.44% of NHR values exceeding the standards. These data indicate that children are more susceptible to health risks than adults and that the midstream and downstream of the river exhibit higher health risks compared to the upper reaches. These findings can provide critical data for groundwater quality assessment and risk management in the WRB and offer guidance for future groundwater resource management and pollution control efforts. Full article

The production of titanium dioxide in China generates substantial waste acid and ferrous sulfate, which are repurposed into polyferric sulfate for industrial wastewater treatment. However, this water purification agent contains heavy metals like Ti, V, Mn, Cr, Co, Cu, Ni, Zn, Ba, and Pb, posing unrecognized environmental risks. This study identified these risks through pollutant screening and the process analysis of a Jiangsu-based titanium dioxide enterprise, evaluating the potential impacts on water quality and worker health. The results show that concentrations of manganese and titanium in the polyferric sulfate reached up to 163 mg/L and 631 mg/L, respectively. Notably, the non-carcinogenic hazard quotients (HQs) for cobalt, vanadium, and manganese were 307, 5.6, and 2.6, all exceeding the safe limit of 1, with cobalt presenting a particularly significant risk due to its low reference dose (RfD) of 0.0003 mg/kg-d. This study concludes that national standards should be revised to include limits for these pollutants to ensure safer practices in industrial wastewater treatment. Full article

In the shipbuilding industry, during the painting process, workers are exposed to various substances in paint, including organic solvents that can adversely affect their health. Most workplace exposures to organic solvents involve mixtures of organic compounds. Therefore, in this study, the hazard quotient (HQ) and hazard index (HI) were derived using data from the Workplace Environmental Monitoring Program in Korea for six organic solvents (xylene, n-butanol, ethylbenzene, isobutyl alcohol, toluene, and methylisobutyl ketone [MIBK]) commonly used in the steel shipbuilding industry. The non-carcinogenic risk was assessed using Monte Carlo simulations, and sensitivity analysis was performed using the Spearman rank correlation coefficient with the R program. The HI for neurotoxicity and developmental toxicity exceeded 1 in the 25th and 75th percentile, respectively. According to the sensitivity analysis, the HI for neurotoxicity was correlated with the concentration of xylene and its exposure duration, whereas that for developmental toxicity was correlated with the concentration of ethylbenzene and MIBK and their exposure duration. This study investigated the health risks posed by organic solvents among workers involved in the painting process of shipbuilding. Additional research on percutaneous exposure to organic solvents and a detailed process analysis are needed. Full article

Groundwater nitrate pollution is a pressing threat to public health. To analyze the chemical properties of groundwater across various sources, samples from 15 groundwater outlets within the Tailai Basin were collected during both the dry and wet seasons. An assessment of human health risks based on drinking water habits and skin contact with various water sources was conducted to provide a foundation for the rational development and utilization of groundwater. The results revealed that the main source of chemical components in the groundwater in the study area was evaporite dissolution. Rock weathering and cation exchange predominantly affected the chemical composition of groundwater. The groundwater samples primarily contained Ca²⁺ cations and HCO₃⁻ anions. The concentration of groundwater nitrate at each water source was relatively high. The single-factor water quality evaluation demonstrated that SO₄²⁻, NO₃⁻, and TDS exceeded the standard, where NO₃⁻ severely exceeded the standard. The water supply and dry seasons were more than 10 times higher than the standard. The HI exceeded 1 for most water sources, and the non-carcinogenic risk index for children significantly surpassed that for adults. This high hazard quotient suggests that groundwater from the majority of sources in the Tailai Basin may adversely affect residents’ health. Water resource management authorities should address groundwater nitrate pollution to ensure the residents’ health and safety. Meanwhile, efforts should focus on preventing and controlling nitrogen pollution in groundwater to support its sustainable development. Full article

This research aims to investigate the heavy metals (i.e., Cd, Cr, Cu, Ni, and Pb) in the fruiting bodies of six indigenous wild edible mushrooms including Agaricus bisporus, Agaricus campestris, Armillaria mellea, Boletus edulis, Macrolepiota excoriate, and Macrolepiota procera, correlated with various factors, such as the growth substrate, the sampling site, the species and the morphological part (i.e., cap and stipe), and their possible toxicological implications. Heavy metal concentrations in mushroom (228 samples) and soil (114 samples) were determined by Inductively Coupled Plasma—Mass Spectrometry (ICP-MS). In the first part of the study, the soil contamination (index of geo-accumulation, contamination factor, and pollution loading index) and associated risks (chronic daily dose for three exposure pathways—ingestion, dermal, and inhalation; hazard quotient of non-cancer risks and the carcinogenic risks) were calculated, while the phytoremediation capacity of the mushrooms was determined. At the end of these investigations, it was concluded that M. procera accumulates more Cd and Cr (32.528% and 57.906%, respectively), M. excoriata accumulates Cu (24.802%), B. edulis accumulates Ni (22.694%), and A. mellea accumulates Pb (18.574%), in relation to the underlying soils. There were statistically significant differences between the stipe and cap (i.e., in the cap subsamples of M. procera, the accumulation factor for Cd was five times higher than in the stipe subsamples). The daily intake of toxic metals related to the consumption of these mushrooms with negative consequences on human health, especially for children (1.5 times higher than for adults), was determined as well. Full article

Food packaging plays an essential role in preserving food quality. However, heavy metals found in packaging materials—whether intentionally incorporated or not—can migrate into food. This study aims to evaluate the migration of specific heavy metals (Ba, Co, Cu, Zn, Al, Ni, Li, Fe, Pb, Cd, Cr, Sb) from plastic food packages (films and bags) obtained from various materials (PE, PP, PVC, composite materials) into food simulant B (3% acetic acid) using inductively coupled plasma mass spectrometry (ICP-MS). Migration tests was conducted according to EU regulations, using OM2 conditions (10 days at 40 °C). The obtained results were lower than the specific migration limits set by EU Regulation no. 10/2011 (Annex II). Both carcinogenic and non-carcinogenic risk assessments were carried out based on the specific migration data, estimating the exposure, average daily dose (ADD), hazard quotient (HQ), hazard index (HI), cancer risk (CR), and total cancer risk (TCR). The exposure values were found to be below the recommended tolerable daily intake (TDI) levels for each metal tested. Both HQ and HI values were under the limit value of 1. The average total cancer risk was 1.73 × 10⁻⁴, indicating that approximately 1.73 consumers out of 10,000 may develop a type of cancer due to chronic exposure to the tested metals. These results highlight the importance of continuous monitoring of chemical migrants from food contact materials. Full article

Increased levels and detrimental effects of volatile organic compounds (VOCs) on air quality and human health have become an important issue in the environmental field. Benzene is classified as one of the most hazardous air pollutants among non-halogenated aromatic hydrocarbons with toxic, carcinogenic, and mutagenic effects. Various technologies have been applied to decrease harmful emissions from various sources such as petrochemistry, steel manufacturing, organic chemical, paint, adhesive, and pharmaceutical production, vehicle exhausts, etc. Catalytic oxidation to CO₂ and water is an attractive approach to VOC removal due to high efficiency, low energy consumption, and the absence of secondary pollution. However, catalytic oxidation of the benzene molecule is a great challenge because of the extraordinary stability of its six-membered ring structure. Developing highly efficient catalysts is of primary importance for effective elimination of benzene at low temperatures. This review aims to summarize and discuss some recent advances in catalyst composition and preparation strategies. Advantages and disadvantages of using noble metal-based catalysts and transition metal oxide-based catalysts are addressed. Effects of some crucial factors such as catalyst support nature, metal particle size, electronic state of active metal, redox properties, reactivity of lattice oxygen and surface adsorbed oxygen on benzene removal are explored. Thorough elucidation of reaction mechanisms in benzene oxidation is a prerequisite to develop efficient catalysts. Benzene oxidation mechanisms are analyzed based on in situ catalyst characterization, reaction kinetics, and theoretical simulation calculations. Considering the role of oxygen vacancies in improving catalytic performance, attention is given to oxygen defect engineering. Catalyst deactivation due to coexistence of water vapor and other pollutants, e.g., sulfur compounds, is discussed. Future research directions for rational design of catalysts for complete benzene oxidation are provided. Full article

To assess the contamination levels, sources, and ecological health risks of potentially toxic elements (PTEs) in the sediments of Al Lith on the Saudi Red Sea coast, 25 samples were collected and analyzed for Zn, V, Cr, Cu, Ni, As, Pb, and Fe using inductively coupled plasma-atomic emission spectrometry. The average concentrations of PTEs (μg/g) were obtained in the following order: Fe (14,259) > V (28.30) > Zn (22.74) > Cr (16.81) > Cu (12.41) > Ni (10.63) > As (2.66) > Pb (2.46). The average values of enrichment factor were in the following order: As (1.12) > Zn (0.75) > V (0.70) > Cr (0.69) > Cu (0.69) > Pb (0.67) > Ni (0.46). This indicated that the Al Lith sediments exhibited either no or minimal enrichment of PTEs, with concentrations below the low effect range. This suggests that the primary source of these PTEs is the minerals associated with the basement rocks of the Arabian Shield (sphalerite, vanadiferous magnetite, chromite, pentlandite, arsenopyrite, and galena) and that they are unlikely to pose a substantial risk to benthic communities. The hazard index (HI) values for the PTEs in both adults and children were below 1.0, indicating no significant non-carcinogenic risk. The lifetime cancer risk (LCR) values for Pb, As, and Cr in both adults and children were within acceptable or tolerable levels, posing no significant health threats. However, a few samples showed LCR values exceeding 1 × 10⁻⁴, which may indicate potential risks. Full article

The aim of the present study was to evaluate the contamination state of the surface soil from 10 parks from Galati, Romania, and the health hazards of the soil. The soil samples, collected in each site from the playing ground and from the edge of the park, were analyzed by using combined Wavelength- (WDXRF) and Energy-Dispersive (EDXRF) X-ray fluorescence techniques. A total number of 27 chemical elements (Ag, Al, As, Ba, Ca, Cd, Cr, Co, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, P, Pb, Rb, Sb, Sc, Sn, Sr, Ti, V, Zn and Zr) were quantified in the urban soils, and the results were compared to the normal and alert values from Romanian legislation for toxic trace elements, as well as with European and world average values of element concentrations. The mineralogical analyses were performed by Scanning Electron Microscopy with Energy-Dispersive X-ray Analysis (SEM-EDX) and the Attenuated Total Reflectance–Fourier Transform Infrared technique (ATR-FTIR). To assess the soil contamination and the impact on human health of the presence of potential toxic elements and heavy metals in the soil, a series of pollution and health risk indices were used. All the results indicated an unpolluted to moderately polluted soil. The soil samples collected from the edge of the parks presented higher values for the specific pollutants, which originated from heavy traffic, such as Cu, Cr, Zn and Pb. The non-carcinogenic and carcinogenic risk to children was assessed using estimated daily intake (EDI) in relation to the pathways whereby pollutants can enter the human body, such as ingestion, dermal contact, inhalation and vaporization. Using the obtained values for EDI, the hazard quotient and hazard index were determined, which strengthen the formerly issued presumption that soil pollution is moderate and, by itself, does not present any threat to children’s health. Full article