User talk:RFZYNSPY
Appearance
Index
|
|
This page has archives. Sections older than 90 days may be automatically archived by ClueBot III when more than 4 sections are present. |
The Signpost: 16 May 2024
- News and notes: Democracy in action: multiple elections
- Special report: Will the new RfA reform come to the rescue of administrators?
- Arbitration report: Ruined temples for posterity to ponder over – arbitration from '22 to '24
- Comix: Generations
- Traffic report: Crawl out through the fallout, baby
The Signpost: 8 June 2024
- Technology report: New Page Patrol receives a much-needed software upgrade
- Deletion report: The lore of Kalloor
- In the media: National cable networks get in on the action arguing about what the first sentence of a Wikipedia article ought to say
- News from the WMF: Progress on the plan — how the Wikimedia Foundation advanced on its Annual Plan goals during the first half of fiscal year 2023-2024
- Recent research: ChatGPT did not kill Wikipedia, but might have reduced its growth
- Featured content: We didn't start the wiki
- Essay: No queerphobia
- Special report: RetractionBot is back to life!
- Traffic report: Chimps, Eurovision, and the return of the Baby Reindeer
- Comix: The Wikipediholic Family
- Concept: Palimpsestuous
Please revise thymol biosynthesis scheme
The last step should have a simple arrow. --Smokefoot (talk) 11:20, 3 July 2024 (UTC)
- @Smokefoot: I changed the image to have an equilibrium arrow instead of a resonance arrow. The reason I chose a resonance arrow is that it was what was used in the referenced article. I appreciate the attention to my image, but if in the future I make harmless typographical errors please consider keeping the image up while it's discussed. RFZYNSPY talk 07:29, 4 July 2024 (UTC)
- Why suggest that an alkyl phenol exists in significant equilibrium with the enone? Smokefoot (talk) 11:10, 4 July 2024 (UTC)
- I think that's a question for the authors of the original article. I'm reluctant to change the arrow further because if the only justification for doing so is that Wikipedia editors predict I don't think we'd be following WP:NOR. RFZYNSPY talk 20:57, 4 July 2024 (UTC)
- Really? Our phenol article say K = 10-13 for typical phenols. Furthermore, the authors of that lovely PNAS paper are probably biochemists after all. Almost always they are mediocre at chem (after all, they were the ones that used the awful double arrow implying resonance!). Enough, good luck. --Smokefoot (talk) 21:07, 4 July 2024 (UTC)
- One guess is maybe they were trying to leave open the possibility of an enzymatic effect stabilizing the enone? But that seems like a further leap than the case in which they just recognized it as tautomerization and slapped on a double headed arrow. I agree with you on the chemistry, though, and I appreciate the attention to detail. RFZYNSPY talk 21:25, 4 July 2024 (UTC)
- Really? Our phenol article say K = 10-13 for typical phenols. Furthermore, the authors of that lovely PNAS paper are probably biochemists after all. Almost always they are mediocre at chem (after all, they were the ones that used the awful double arrow implying resonance!). Enough, good luck. --Smokefoot (talk) 21:07, 4 July 2024 (UTC)
- I think that's a question for the authors of the original article. I'm reluctant to change the arrow further because if the only justification for doing so is that Wikipedia editors predict I don't think we'd be following WP:NOR. RFZYNSPY talk 20:57, 4 July 2024 (UTC)
- Why suggest that an alkyl phenol exists in significant equilibrium with the enone? Smokefoot (talk) 11:10, 4 July 2024 (UTC)
The Signpost: 4 July 2024
- News and notes: WMF board elections and fundraising updates
- Special report: Wikimedia Movement Charter ratification vote underway, new Council may surpass power of Board
- In focus: How the Russian Wikipedia keeps it clean despite having just a couple dozen administrators
- Discussion report: Wikipedians are hung up on the meaning of Madonna
- In the media: War and information in war and politics
- Sister projects: On editing Wikisource
- Opinion: Etika: a Pop Culture Champion
- Gallery: Spokane Willy's photos
- Humour: A joke
- Recent research: Is Wikipedia Politically Biased? Perhaps
- Traffic report: Talking about you and me, and the games people play
The Signpost: 22 July 2024
- Discussion report: Internet users flock to Wikipedia to debate its image policy over Trump raised-fist photo
- News and notes: Wikimedia community votes to ratify Movement Charter; Wikimedia Foundation opposes ratification
- Obituary: JamesR
- Crossword: Vaguely bird-shaped crossword
The Signpost: 14 August 2024
- In the media: Portland pol profile paid for from public purse
- In focus: Twitter marks the spot
- News and notes: Another Wikimania has concluded.
- Special report: Nano or just nothing: Will nano go nuclear?
- Opinion: HouseBlaster's RfA debriefing
- Traffic report: Ball games, movies, elections, but nothing really weird
- Humour: I'm proud to be a template