Jump to content

Grove cell: Difference between revisions

From Wikipedia, the free encyclopedia
Content deleted Content added
Citation bot (talk | contribs)
Alter: url. URLs might have been anonymized. | Use this bot. Report bugs. | Suggested by AManWithNoPlan | #UCB_CommandLine
 
(27 intermediate revisions by 23 users not shown)
Line 1: Line 1:
[[Image:Groove'sches Element.png|thumb|Grove cell (1897)]]
[[Image:Groove'sches Element.png|thumb|Grove cell (1897)]]
{{No footnotes|date=April 2022}}
The '''Grove cell''' was an early electric [[primary cell]] named after its inventor, [[United Kingdom|British]] chemist [[William Robert Grove]], and consisted of a [[zinc]] [[anode]] in dilute [[sulfuric acid]] and a [[platinum]] [[cathode]] in concentrated [[nitric acid]], the two separated by a porous ceramic pot.
The '''Grove cell''' was an early electric [[primary cell]] named after its inventor, [[Wales|Welsh]] physical scientist [[William Robert Grove]], and consisted of a [[zinc]] [[anode]] in dilute [[sulfuric acid]] and a [[platinum]] [[cathode]] in concentrated [[nitric acid]], the two separated by a porous ceramic pot.


==Cell details==
==Cell details==
The Grove cell voltage is about 1.9 volts and arises from the following reaction:
The Grove cell voltage is about 1.9 volts and arises from the following reaction:
:: Zn + H<sub>2</sub>SO<sub>4</sub> + 2HNO<sub>3</sub> <big><big>→</big></big> ZnSO<sub>4</sub> + 2 H<sub>2</sub>O + 2 NO<sub>2</sub><big><big>↑</big></big>
: Zn + H<sub>2</sub>SO<sub>4</sub> + 2 HNO<sub>3</sub> {{eqm}} ZnSO<sub>4</sub> + 2 H<sub>2</sub>O + 2 NO<sub>2</sub>↑


==Use==
==Use==
The Grove cell was the favoured power source of the early American [[telegraph]] system in the period [[1840]] - [[1860]] because it offered a high current output and higher [[voltage]] than the earlier [[Daniell cell]] (at 1.9 volts and 1.1 volts, respectively).
The Grove cell was the favored power source of the early American [[telegraph]] system in the period 1840 1860 because it offered a high current output and higher [[voltage]] than the earlier [[Daniell cell]] (at 1.9 volts and 1.1 volts, respectively).


==Disadvantages==
==Disadvantages==
Line 13: Line 14:


==See also==
==See also==
* [[List of battery types]]

*[[History of the battery]]
* [[History of the battery]]
* [[Bunsen cell]], Using cheaper carbon instead of platinum.

{{GalvanicCells}}


==Notes==
==Notes==
*{{cite book | last = Stillman | first = Benjamin | authorlink = | coauthors = | title = Principles of Physics | publisher = Theodore Bliss | date = 1861 | location = | url = http://books.google.co.uk/books?id=da4IAAAAIAAJ&pg=PA577&dq=zamboni+cell&lr=&as_brr=1 | doi = | id = | isbn =| page = 578 }}
* {{cite book | last = Stillman | first = Benjamin | title = Principles of Physics | publisher = Theodore Bliss | year = 1861 | url = https://books.google.com/books?id=da4IAAAAIAAJ&dq=zamboni+cell&pg=PA577 | page = 578 }}
*{{cite book | last = Ayrton | first = W.E.| coauthors = | authorlink = | title = Practical Electricity | publisher = Cassell and Company | date = 1911 | location = | pages = 183–185 | url = | doi = | id = | isbn = }}
* {{cite book | last = Ayrton | first = W.E.| title = Practical Electricity | publisher = Cassell and Company | year = 1911 | pages = 183–185 }}


{{Galvanic cells}}


[[Category:Battery (electricity)]]
[[Category:Disposable batteries]]
[[Category:Electrochemistry]]


{{analytical-chemistry-stub}}


{{Analytical-chemistry-stub}}
[[bg:Елемент на Гроув]]
[[nl:Grove-element]]

Latest revision as of 09:57, 27 March 2023

Grove cell (1897)

The Grove cell was an early electric primary cell named after its inventor, Welsh physical scientist William Robert Grove, and consisted of a zinc anode in dilute sulfuric acid and a platinum cathode in concentrated nitric acid, the two separated by a porous ceramic pot.

Cell details

[edit]

The Grove cell voltage is about 1.9 volts and arises from the following reaction:

Zn + H2SO4 + 2 HNO3 ⇌ ZnSO4 + 2 H2O + 2 NO2

Use

[edit]

The Grove cell was the favored power source of the early American telegraph system in the period 1840 – 1860 because it offered a high current output and higher voltage than the earlier Daniell cell (at 1.9 volts and 1.1 volts, respectively).

Disadvantages

[edit]

By the time of the American Civil War, as telegraph traffic increased, the Grove cell's tendency to discharge poisonous nitrogen dioxide (NO2) fumes proved increasingly hazardous to health, and as telegraphs became more complex, the need for constant voltage became critical. The Grove cell was limited in this respect, because as the cell discharged, voltage reduced. Eventually, Grove cells were replaced in use by Daniell cells.

See also

[edit]

Notes

[edit]
  • Stillman, Benjamin (1861). Principles of Physics. Theodore Bliss. p. 578.
  • Ayrton, W.E. (1911). Practical Electricity. Cassell and Company. pp. 183–185.